HomeMy WebLinkAbout0069 BARNSTABLE ROAD - Health 69 BARNSTABLE RD. , Hyannis
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LIMITED REMOVAL ACTION COMPLETION STATEMENT
UIC Closure Assessment
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' 65 Barnstable Road_ -,
Hyannis, MA
B099-2558
January 20, 2000
II 1
1 ENN ET TO'REILL , Inc.
Engineerin Environmental & SurveyingServices 1573 Main Street
g
Sanitary 2 1 E/Site.Remediation Property Line PO Box 1667
Site Development Hydrogeologic Survey Subdivision ?, Brewster,MA 02631
' Waste Water Treatment Water Quality Monitoring Land Court 508-896-6630
Water Supply Consulting Trial Court Witness 508-896-4687 Fax
BENNETT & O'REILLY, INC.
Engineering & Environmental Services L ETrE R OF
1573 Main Street,P. O. Bog 1667
Brewster,MA 02631
(508) 896-6630
FAX(508) 896-4687
TO: DATE: JOB NUMBER:
Mr. Mark Dakers 1/24/00 B099-2558
MA DEP(SERO) REGARDING:
Division of Water Supply-Cape Cod Basin Team 65 Barnstable Road
20 Riverside Drive Hyannis,MA
Lakeville,MA 02347
We are sending you:
COPIES DATE DESCRIPTION
1 1/20/00 Limited Removal Action-UIC Closure
For review and comment: ❑ For approval: As requested: XD For your use:
Other:
REMARKS:
cc: Helen George,c/o Diana Panesis
Barnstable Board of Health
Barnstable Plumbing Inspector-Richard Burnham
Liam Managhan
signed: Kara Shumway,ES
If enclosures are not as noted kindly notify us at once.
1
BENNETT A 'REILLY, Inc.
Engineering, Environmental & Surveying Services 1573 Main Street
' Sanitary 21E/Site Remediation Property Line
PO Box 1667
Site Development Hydrogeologic Survey Subdivision Q Brewster,MA 02631
Waste Water Treatment Water Quality Monitoring Land Court 508-896-6630
1 Water Supply Licensed Site Professional Trial Court Witness 508-896-4687 Fax
' January 20, 2000
Underground Injection Control Program Attn: Mark Dakers
' MA DEP (SERO)
Division of Water Supply, Cape Cod Basin Team
' 20 Riverside Drive
Lakeville, MA 02347
' RE: LIMITED REMOVAL ACTION COMPLETION STATEMENT
UIC Closure Assessment
65 Barnstable Road
1 Hyannis, MA
Dear Mr. Dakers:
1 BENNETT & O'REILLY, INC., has the following Limited Removal Action
prepared g
Completion Statement (LRAC) Report as documentation of the environmental assessment and
1 remedial response activities conducted at the subject property, in association with the Underground
Injection Control closure requirements, pursuant to current MA DEP policies as they apply to 310
CMR 40.000. Remedial response activities included the excavation,oil site transport and recycling
1 of some 3.7 yards of contaminated soil at a licensed facility under an approved Bill of Lading.
Laboratory analysis of soil samples collected at the extent of excavation shows that low level residual
' impact is well below the most restrictive S-1/GW-1 Method 1-Risk Characterization standards, and
the most sensitive RCS-1 Reportable Concentrations, in support of project closure. This document
serves as the technical justification and rationale for the LRAC represented herein. It further serves
as documentation of the environmental assessment and construction activities conducted for the
abandonment of floor drains at the subject property. These activities were conducted in accordance
with the provisions ofthe MA DEP"Closure Requirements for Shallow Injection Wells"UIC Closure
' Guidance, 1995, as consistent with the MA Contingency Plan (MCP), 310 CMR 40.000.
This project has proceeded with my oversight in a manner consistent with the MCP Response
Action Performance Standards (RAPS) pursuant to 310 CMR 40.0191 and QA/QC policies of
BENNETT&O'REILLY,INC. The facts and statements herein are,to the best of our knowledge,
a true and accurate representation of the site activities,remedial response actions and environmental
' conditions associated with the project.
1
JANUARY 20,2000 GEORGE RESIDENCEB099-2558
PAGE 2 OF 8 UIC CLOSURE ASSESSMENT
SITE DESCRIPTION/ENVIRONMENTAL CONDITIONS [Refer to Appendix A]
The subject site, 65 Barnstable Road, is developed by a conventional style three bedroom,
wood framed residential dwelling containing 1,800 SF believed to have been built in 1840 and a two
bay 5,600 SF+/-warehouse structure built in 1950. The warehouse has historically housed various
commercial and industrial uses throughout the years. These activities have included the use of the
building as cold storage for a wholesale produce distributer(1956's to 1960's), a soda manufacturing
' and bottling plant (1960's) and various dry goods warehousing including Colonial Candle and
Manning Auction House (1970's to present).
The surrounding area is highly developed by commercial use buildings mixed with residential
dwellings toward the west. Mid-Cape Septic garage is locatedno
rth of the subject site at 15 Louis
Street, as owned by John&Marina Atsalis. Northwest of the site (25 Louis Street)is a residential
' home, as owned by Eli & Cecille Cohen Trust. Abutting the subject site to the northeast (75
Barnstable Road) is the Clothesline Laundry facility, as owned by Clothesline Laundry, Inc. A
Sunoco Service Station(Barnstable Road Auto Repair)is located beyond the laundry facility, some
' 0.15 miles north of the site. The Hyannis Travel Inn, as owned by Mr. Liam Monaghan, is located
at 16 North Street, abuts the western property line. The Briar Hollow Antique Shop located at 6.1
Barnstable Road, as owned by Louis Panesis, is an abutter to the south. Also abutting the southern
property line is a parcel of land, approximately.06 acres,known as the"back driveway". It is shown
on Barnstable Assessor's Map 327 as Parcel 259, as owned by Louis & Mary Panesis. A small
cottage was in existence on this parcel until it was removed in September of 1985. Abutting the
subject site to the east, across Barnstable Road is J.J. Auto Sales, as owned by Katina Atsalis.
' The subject site is highly developed by the two existing structures and a paved driveway area
along the south side ofthe property from Barnstable Road to the front ofthe warehouse area. Access
to the property is unrestricted. The site is relatively flat with little variation in topography at
' approximately 30'+/-NGVD. Site specific groundwater contouring indicates groundwater flow is
southeasterly,toward Hyannis Harbor and Nantucket Sound,as consistent with regional groundwater
contours. Groundwater was located on-site at approximately 25'+/-below.grade. According to the
' MA DEP, Bureau of Waste Site Cleanup maps, the'site lies within a Non-Potential Drinking Water
Source Area(NPDWSA), as consistent with the degree of commercial development within the area.
' The nearest municipal wellhead area is located some 0.5 miles north-northeast of the site. Hyannis
Inner Harbor is considered the nearest wetland to the subject site. Based upon the enviroronmental
sensitivity and use of the property, the S-3/GW-3 Method 1-Risk Characterization soil category is
reviewed as applicable to remedial response obligations,for exposures associated with contaminated
soils in the dry well. By default proximity ofthe residential dwelling at the site,however, the RCS-1
Reportable Concentrations are applied to Limited Removal Action Cleanup standards, pursuant to
310 CMR 40.0360.
JANUARY 20,2000 GEORGE RESIDENCEB099-2558
PAGE 3 OF 8 UIC CLOSURE ASSESSMENT
BACKGROUND/ENVIRONMENTAL ASSESSMENT [Refer to Appendix Cl
' In September 1999, BENNETT & O'REILLY, INC., was retained by Cape Cod Bank &
Trust, as the fiduciary secured by the porspective buyer of the subject property, to conduct an
' Environmental Site Assessment - Transaction Screen (ESA-TS) investigation. The purpose of the
ESA-TS was to identify any release of oil and/or hazardous materials that may have occurred on or
adjacent to the property,and/or to determine if there was a potential for such a release to occur under
' the jurisdiction of the MA Oil and Hazardous Material Release Prevention Act, Chapter 2 1 E of the
MA General Laws.
' On September 23, 1999,a site walkover and inspection of the subject property was conducted
by BENNETT & REILLY, INC., personnel (David C. Bennett-LSP, Kara Shumway-ES). The
inspection was concentrated within the warehouse as the center of the former industrial activities
conducted on the property. In the course of the inspection,one floor drain which discharged directly
to the subsurface was noted within a former chiller unit. Several others were indicated by the owner's
representative as located within the former bottling room. Upon further investigation, it was noted
that six floor drains in the former bottling room were plumbed to a dry well also discharging directly
to the subsurface.
Assessment activities, pursuant to the Underground Injection Control program, began on
October 7, 1999 with the physical testing of soils within the chiller room floor drain. BENNETT&
' O'REILLY,INC.,personnel(Kara Shumway-ES)conducted one hand boring,BB-1,within the drain,
collecting continuous soil samples at two foot intervals. Soil samples were placed in a sealed 300
milliliter glass jar with an aluminum septum. The jars were agitated to develop organic vapors. The
' soil samples were then screened with a photoionization detector (PID) meter (HNU PI 101, 10.2
electron volt lamp)by"jar headspace" analysis, as consistent with MA DEP"Interim...Soils Policy"
W SC-94-400. PID screening did not indicate the presence of significant contamination at any of the
test boring locations with all PID responses at Below Detectable Limits. The soil sample,BB-1:0-6,
was then preserved and forwarded to Groundwater Analytical of Buzzard Bay, MA for Total
' Petroleum Hydrocarbon (TPH ASTM D3328-90), Volative Organic Compounds (EPA 5035) and
trace metal (ICP-AES and CVAA) analysis, as consistent with UIC Closure sampling procedures.
' Laboratory results received October 22, 1999 reported VOCs and heavy metals as below the
RCS-1 Reportable Concentrations standards. TPH analysis, however, identified lubricating oil
contamination at 1,400 mg/Kg, well above the RCS-1 Reportable Concentration standards (200
mg/Kg), as well as the most restrictive S-1/GW-1 Method 1 -Risk Characterization standards(800
' mg/Kg). As such, a 120 day Notification Requirement and remedial response actions appeared
necessary in support of UIC Closure.
BENNETT & O'REILLY, INC., met with the prospective buyer and seller's representative
on October 22, 1999 to review these findings and the application of fractional Extractable Petroleum
' JANUARY 20,2000 GEORGE RESIDENCEIB099-2558
PAGE 4 OF 8 UIC CLOSURE ASSESSMENT
Compounds(EPH)with target analytes to qualify RCS-1 Reportable Concentrations and Method 1 -
Risk Characterization criteria, pursuant to 310 CMR 40.0360(2). BENNETT&O'REILLY,INC.,
was subsequently authorized to conduct an additional hand boring, HB-IA,in the cold storage floor
drain at the HB-1 location. A second hand boring,HB-2, was also conducted at this time within the
' dry well located in the former bottling room to evaluate for the presence of OHM. Soil samples were
collected at T intervals and field screened for headspace. PID screening did not indicate the presence
of significant contamination at either of the hand boring locations with all PID responses at or below
0.6 parts per million (ppm). Soil samples HB-lA:0-6' and BB-lA:6-8' were submitted to the
laboratory for Extractable Petroleum Hydrocarbon(EPH)analysis. HB-2: 2-8'was submitted to the
laboratory for VOCs, TPH, and RCRA metals analysis, and HB-2:8-10' was submitted for EPH
analysis.
Laboratory results received November 11, 1999 reported fractional EPH for HB-1 A:0-6'and
6-8' as Below the Reportable Limit (BRL). This additional data represented a preponderance of
evidence to absolve notification issues and remedial response actions in the area of the cold storage
' room floor drain as part of the UIC Closure requirements. Concentrations of TPH and lead
(590mg/Kg, 920 mg/Kg, respectively) were identified, however, as being above the RCS-1 (200
mg/Kg, 300 mg/Kg, respectively) and applicable S-3/GW-3 Method 1 - Risk Characterization
' standards(5,000 mg/Kg, 600 mg/Kg,respectively)at HB-2:2-8'. TPH was identified as a petroleum
product in the Lubricating Oil range. Fractional EPH and VOC results for HB-2: 8-10' were
reported as Below the Reportable Limit (BRL).
Based upon the identification of lead in the HB-2:2-8', BENNETT & O'REILLY, INC.
requested the laboratory to screen the HB-2:8-10' soil sample for lead. Laboratory analytical
' reported lead at a level in the 8-10' interval well below the RCS-1 and Method 1 - Risk
Characterization standards establishing a discrete area of lead and TPH impact. In an attempt to
characterize background conditions(ie. leaching of lead based paint)related to the presence of lead,
' an additional hand boring,HB-3,was conducted at the northern property line, adjacent to the former
bottling room . A 1' soil sample was collected, preserved and submitted to Groundwater Analytical
' on November 4, 1999. Laboratory analytical received November 22, 1999 reported lead at the BB-3
location as well below the RC S-1 and strictest Method 1 -Risk Characterization standards. As such,
background concentrations of lead were not sufficient to absolve the issues of notification and
' remedial response for lead at the site.
Based upon the data gathered,remedial response activities for the excavation ofimpacted soils
' to mitigate the potential human health and/or environmental hazards identified were deemed necessary
in support of UIC Closure to absolve 21E liabilities identified. A 120 day Notification Requirement
with exposure risks for concentrations of TPH and lead was apparent at the floor drain location in
' the bottling area of the building. At the request of BENNETT & O'REILLY, INC., soil samples
collected from within the dry well(HB-2)were screened for MA Hazardous Waste Characterization
for disposal at a licensed recycling facility. Laboratory analytical received November 11, 1999
JANUARY 20,2000 GEORGE RESIDENCE/13099-2558
PAGE 5 OF 8 UIC CLOSURE ASSESSMENT
revealed soils within the dry well from 0-8' contained levels of PCBs, in addition to TPH and lead,
' which exceeded both the RCS-1 Reportable Concentrations and the Method 1-Risk Characterization
standards.
' REMEDIAL RESPONSE [Refer to Appendix C]
' LIC Closure activities began on January 3,2000 with the issuance of a plumbing permit form
the Town of Banstable [Refer to enclosed WS-1 Form]. EnviroSafe, Corp., as the environmental
contractor, cleaned, filled and sealed the chiller room floor drain, as well as the six drains in the
bottling room. These activities were initiated with the removal of metal grates which covered the
floor drains. Grit/sludge was removed from within the drains and loaded into metal Department of
Transportation (DOT) drums for off-site disposal as solid waste debris under a uniform hazardous
waste manifest. All seven floor drain areas were then backfilled with clean material and sealed with
a concrete cap.
' Soil removal activities within the dry well commenced on January 4, 2000. The concrete
surrounding the dry well was broken apart with the use of a jackhammer and removed from the area.
A bob cat was then used to excavate some 6 yards of impacted soils and sludge from a T diameter
' area to a depth of 8'. Discreet sidewall and bottom of hole samples were collected for field PID
screening in accordance with MA DEP Policy WSC-94-400. "Jar Headspace" analysis reported
sidewall areas below detectable limits for volatile organics. Soil samples from the four sidewa.11s and
' bottom of hole area were assembled and forwarded to Groundwater Analytical for TPH, lead and
PCB analyses. VOC analysis was not conducted in this sampling as initial analysis and MA Disposal
Characterization reported all compounds as BRL. The excavation was left open and secured by
' EnviroSafe, Corp. pending receipt of laboratory analytical.
RISK CHARACTERIZATION
For the purpose of risk characterization, in consideration of remedial response liability and
review of project closure objectives,the RCS-1 Reportable Concentration criteria was applied in the
' evaluation of closure objectives. Additionally, the Method 1 - Risk Chatacterization standards for
the S-1/GW-3 soil category was used assuming dermal contact,inhalation and ingestion. Laboratory
analytical received January 11, 2000, reported all sidewall and bottom of hole samples below the
' RCS-1 Reportable Concentrations, as well as the strictest S-1/GW-1 Method 1 - Risk
Characterizations,with the exception of SW-S:0-8,which reported a TPH concentration of 330ppm.
' This sample was subsequently re-submitted for EPH analyses with target analytes. Laboratory results
received January 14, 2000 reported all EPH fractions and target PAHs well below both the RCS-1
Reportable Concentrations and Method 1 -Risk Characterization standards. As such,LRA Closure
' objectives were met and a condition of "No Significant Risk" has been achieved through the
excavation of some 3.7 yards of impacted soil.
' JANUARY 20,2000 GEORGE RESIDENCEB099-2558
PAGE 6 OF 8 UIC CLOSURE ASSESSMENT
TABLE 1: SUMMARY OF TPH, EPH, LEAD AND PCB ANALYSIS - SOIL
' Sample TPH Results Lead Results PCBs Reportable Concentration Method 1 Risk
Location (mg/kg-ppm) (mg/kg-ppm) (mg/kg-ppm) Standards Characterization Standards
EPA 418.1 EPA 8082 (mg/kg-ppm) (mg/kg-ppm)
310 CMR 40.1600 310 CMR 40.975
' RCS-1 S-1/GW-1,S-1/GW-3
TPHf`Lead/PCBs TPH/Lead/PCBs
SW-N:0-8' 120 76 Aroclor 1016 BRL 200/300/2 5,000/600/2
' Aroclor 1221 BRL
Aroclor 1232 BRL
Aroclor 1242 BRL
Aroclor 1248 BRL
' Aroclor 1254 BRL
Aroclor 1260 .089
SW-S:0-8 330 110 Aroclor 1016 BRL 200/300/2 5,000/600/2
Aroclor 1221 BRL
' Aroclor 1232 BRL
Aroclor 1242 BRL
Aroclor 1248 BRL
Aroclor 1254 BRL
' Aroclor 1260 .140
EPH 8260B Analysis
C9-C-18 BRL EPH
C19-36 130 1000/2500/200
C-11-C22 42
' Target PAHs All BRL
SW-E:0-8' 180 92 Aroclor 1016 BRL 200/300/2 5,000/600/2
' Aroclor 1221 BRL
Aroclor 1232 BRL
Aroclor 1242 BRL
Aroclor 1248 BRL
Aroclor 1254 .120
' Aroclor 1260 .210
SW-W:0-8' 76 38 Aroclor 1016 BRL 200/300/2 5,000/600/2
Aroclor 1221 BRL
' Aroclor 1232 BRL
Aroclor 1242 BRL
Aroclor 1248 BRL
Aroclor 1254 BRL
Aroclor 1260 BRL
' BOH:8' BRL 33 Aroclor 1016 BRL 200/300/2 5,000/600/2
Aroclor 1221 BRL
Aroclor 1232 BRL
1 Aroclor 1242 BRL
Aroclor 1248 BRL
Aroclor 1254 BRL
Aroclor 1260 BRL
' EPH=Extractable Petroleum Hydrocarbons
TPH=Total Petroleum Hydrocarbons
BRL=Below Reportable Limits
JANUARY 20,2000 GEORGE RESIDENCE/13099-2558
PAGE 7 OF 8 UIC CLOSURE ASSESSMENT
Residual contamination is well below the RCS-1 Reportable Concentrations, as well as the
' most stringent Method 1- Risk Characterization. It should be noted that the Reportable
Concentration and Method 1 Risk Characterization standards used in evaluating closure performance
were stricter than the applicable S-3/GW-3 Method 1 -Risk Characterization standards. Cost to
' benefit analysis to meet background conditions was considered. Based upon the threat to the
structural integrity of the building, space limitations and worker safety, further soil excavation was
deemed unnecessary as financially impractical and with no significant reduction in risk based on the
' most restrictive S-1/GW-3 standards.
This work was conducted as a Limited Removal Action (LRA) in accordance with the
' provisions of 310 CMR 40.0318. Laboratory analyses received for the sidewall and bottom of hole
samples reported for TPH, lead, and PCB concentrations as below the most stringent RCS-1
' Reportable Concentrations and S-1/GW-3 Method 1 - Risk Characterization standards, within the
120 day Notification period. As such, soil conditions at the extent of excavation represent a condition
of"No Significant Risk" without restriction of activity or use and the objectives of the Limited
' Removal Action are met, in accordance with the provisions of 310 CMR 40.0318.
CONCLUSIONS
An evaluation of laboratory results received January 11 and January 14, 2000, revealed that
each of the discreet sidewall and bottom of hole areas of the dry well location are below the most
stringent RCS-1 Reportable Concentration Standards, as set forth in 310 CMR 40.1600. Laboratory
analyses further indicate that strictest Method 1 -Risk Characterization standards for the S-1/GW-1
soil category have been achieved. These standards are significantly stricter than the S-1/GW-3
' standards and demonstrate a condition of"No Significant Risk"for soil in the dry well of the former
bottling area, without restriction of activity or use of the property.
' Therefore, in accordance with the Response Action Performance Standards as described in
310 CMR 40.0191, and the provisions of 310 CMR 40.0318, as set forth by the documentation
represented within, this Limited Removal Action has been completed and the project is considered
tclosed. Furthermore,this UIC Closure Assessment has been conducted in accordance with the UIC
Closure Guidance Document, as consistent with the MA DEP Contingency Plan, 310 CMR 40.000.
Should you have any questions or require any further information, please contact me directly.
Very truly yours,
' BENNETT& O'REILLY, INC.
ara Shu ay, ES B ett P
Project Manager Director of Environmental Services
' JANUARY 20,2000 GEORGE RESIDENCEB099-2558
PAGE 8 OF 8 UIC CLOSURE ASSESSMENT
t
cc: Helen George - Owner
Barnstable Board of Health
Richard Burnham-Barnstable Plumbing Inspector
Liam Monaghan-Prospective Buyer
encl: Site Plan"George Property-UIC Closure/Limited Removal Action"for 65 Barnstable Road,
Hyannis, MA, by BENNETT & O'REILLY, INC.
UIC Notification Form
tForm WS-1 Notice of Plumbing Inspector Approval to Seal Floor Drain
Bill of Lading
Laboratory Analytical
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PROJECT
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TITLE
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BENNETT A O'REILLY Inc.
Engineering & Environmental Services --
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1573 Main Street Route 6A
P.O. Box 1667
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508-896.6630 Office Brewster, MA 02631 509-896-4687 lax
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DATE SCALE:y BY: CHECK: JOB NUMBER
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' Commonwealth of Massachusetts .
Executive Office of Environmental Affairs .
Department of
' Environmental Protection
William F, Weld
Daniel S.Greenbaum
commbsbrwr
' UIC NOTIFICATION FORM
DIVISION OF WATER SUPPLY
1
The Underground Injection Control (UIC) program protects drinking water
' by regulating discharges to the ground via injection wells such as dry
wells and septic systems. Pursuant to UIC regulations (310 CMR 27. 00) ,
the discharge of pollutants via a floor drain to such a well must cease.
' This notification form is to be used to report which of the options
under I below (per DEP regulations) your facility will follow regarding
your floor drain(s) . Supply all information and attachments for that
option. Supply all information for II and III as noted.
X I. Option chosen for floor drain upon closure of injection well:
' x A. Plug the floor drain, if applicable (see 248 CMR 2. 09) .
X 1. Copy of Form WS1: Notice of Plumbing Inspector
Approval to Seal Floor Drain (where applicable) ,
and Plumbing Permit Number: #
2 . Date of plugging:
B. Connect floor drain to a holding tank/containment basin that
' meets all appropriate DEP regulations and policies.
1. Floor plan with tank location
2 . Type of tank:
3 . DEP Permit #, where applicable
' 4 . Containment Basin Notification &
required attachments, where applicable
5. Date of connection:
' C. Connect floor drain to municipal sewer (only allowed per
DEP regulation 314 CMR 7.00 re. sewer discharge permits) .
' 1. DEP sewer discharge permit &
permit/transmittal number: #
2 . Waste Water Treatment Plant permit
& permit number: #
' 3 . Date of hookup:
D. Close and remove entire service bay.
ERS
................_.................................__. .
.......................................................................
One Winter Street 0 Boston,Massachusetts 02108 0 FAX(617)556-1049 9 Telephone (617)292-5500
r
NA II. Waste Management Plan (methods to be used to properly collect,
Dry storage only store, and dispose of all potentially hazardous wastes) must be
' supplied by all facilities generating, managing, or disposing
of hazardous materials and/or wastes.
X III. Sampling Results., where required, must be supplied with this
'See attached LRAC form. Any abandoned separator must be pumped empty and
cleaned..
Name of Business: NA
' Mailing Address: 51 Joyce Ann Road, Centerville, MA 02632
Location: 65 Barnstable Road Hyannis , MA 02601
Facility Owner: Helen George hone: (508 ) 775 - 0542
Nature of Business: Vacant warehouse
EPA Hazardous Waste Generator ID Number:
Number of Floor Drains at facility: before closure: 10 after:-
Previous Final Point of Discharge of Floor Drain: One drain discharging
' directly to the soil below. Eight drains discharging to one dry
well/leaching area.
I HEREBY CERTIFY UNDER PENALTY OF LAW THAT I HAVE PERSONALLY EXAMINED
AND AM FAMILIAR WITH THE INFORMATION SUBMITTED IN THIS DOCUMENT AND ALL
' ATTACHMENTS AND THAT; BASED ON MY INQUIRY OF THOSE INDIVIDUALS IMMEDIATE-
LY RESPONSIBLE FOR OBTAINING THE INFORMATION, I BELIEVE THAT THE
INFORMATION IS TRUE, ACCURATE, AND COMPLETE. I AM AWARE THAT THERE ARE
' SIGNIFICANT PENALTIES FOR SUBMITTING FALSE INFORMATION, INCLUDING
POSSIBLE FINES AND IMPRISONMENT.
I UNDERSTAND THAT I MUST HANDLE, STORE, AND DISPOSE OF ALL HAZARDOUS
WASTES IN AN ENVIRONMENTALLY SOUND MANNER IN ACCORDANCE WITH ALL
' APPROPRIATE REGULATIONS.
SIGNATURE OF OWNEA DATE
' Any questions may be directed to the UIC Program at (617) 292-5770.
Submit this form and all required attachments. for I (only the attachments
for the option chosen) , II, and III to the following address:
Underground Injection Control Program
DEP/Division of Water Supply
One Winter Street, 9th floor
Boston, MA 02108
' Send duplicate copies of all forms to: Local Board of Health
Local Plumbing Inspector
' 03/18/93 P:\jmoss\uicforms\ntfction.fm5
tCommonwealth of Massachusetts
Executive Office of Environmental Affairs
Department of
r Environmental Protection
' William F.Weld
Governor
Trudy Coxe
Secretary,EOEA
Thomas B. Powers FORM WS1
Acting Commissioner
Notice of Plumbing Inspector Approval to Seal Floor Drain
April 1992
Note: This Application Does Not Apply To Any Facility Whose Floor Drain Is Connected To A
Municipal Sewer System.
' To: Plumbing Inspector for the City/Town of Hyannis
Company Name: Enviro-Safe Corporation
' Nature of Business: Environmental Contractor
Mailing Address: PO Box 810 East Sandwich, MA 02537
Location: 65 Barnstable Road Hyannis, MA
Phone Number: ( 508 ) 896 -- 6630
Facility Owner: Helen Georae
requests to sea] j7 a floor drains.
# of drains
Any additions or alterations to the system are not permissible A thout the approval of the local
plumbing inspector. All seals must be in compliance with.248 CMR.. This form must show both
signatures before copy may be filed with DEP. .
Upon approval, a completed copy of this notice shall be filed immediately with the DEP Under-
ground Injection Control Program (((i•617/556-1165) at the address below. Upon completion of
all work, the applicant shall file the DEP UIC Notification Form to the same address.
' Signature of Facility Owner Date
' Approval/Signature of Local Plumbing Inspector Date Plumbing Permit #
' Owner shall send a completed DEP/Division of Water Supply
copy of this form to: Underground Injection Control Program
One Winter Street, 9th floor
tBoston, MA 02108
One Winter Street • Boston,Massachusetts 02108 • FAX(617)556-1049 • Telephone(617)292.5500
p:�yumr.uvfurm.',fnrnt•ua rre
Massachusetts Department of Environmental Protection EWSC-012A
Bureau of Waste Site Cleanup
Release TraMng NumOer*
• BILL OF LADING (pursuant to 310 CMR 40.00:30) ❑- LRA
A. LOCATION OF SITE OR DISPOSAL SITE WHERE REMEDIATION WASTE WAS GENERATED:
' Release Name(optional): George Property
Street: 65 Barnstable Road Location Aid: Map 327 , Parcel 18
City/Town: Hyannis Zip Code: 02601 - 0000
' Date/Pericd of Generation: 1 / 3 /00 to 1 / 5 / 00
Additional Release Tracking Numbers Associated with this Sill of Lading:
' *Note: If this Bill of Lading is the result of a Limited Removal Action (LP-4) taken prior to
Notification,a Release Tracking Number is not needed.
' B. PERSON CONDUCTING RESPONSE ACTION ASSOCIATED WITH BILL OF LADING:
Name of Organization:
Name ofContac: Helen George T,tIe: Owner
Street 51 Joyce Ann Road
' City/Town: Centerville State: MA TrpCode: 02632 - 0000
Telephone: 5 0 8 - 7 7 5 - 0524 Ext.
' C. RELATIONSHIP TO RELEASE OR THREAT OF RELEASE OF PERSON CONDUCTING RESPONSE ACTION
ASSOCIATED WITH BILL OF LADING.
(check one/specfij)
EF RP Specify(circle one): Owner Operator Generator Transporter Other RP:
' ❑ PRP Specify(circle one): Owner Operator Generator Transporter Other PRP:
❑ Fiduciary/Secured Lender
❑ Agency/Public Utility on a Right of Way
❑ Other Person:
If an owner and/or operator is not conducting the response action associated with the Bill of Lading,provide on an attachment the name,
contact person,address and telephone number,including any area code and extension,for each,if known.
D. TRANSPORTER/COMMON CARRIER INFORMATION:
iTransporter/Common Carrier Name: Env i r o S a f e, Corp.
Contact Person: Heather Atwood Title: President
Street: P.O. BOX 810
City/Town: East Sandwich state: MA Zip Code. 02537 - 0000
Telephone: 5 0 8 - 888 - 5478 Ext.
E. RECEIVING FACILITY/TEMPORARY STORAGE LOCATION:
' Operator/Facility Name: E S M I
Contact Person: Laura Bvacqua Title:' Manager
Street: 6.7 International Drive
City/Town: Loudon State: NH Zip Code: 03301 - 0000
Telephone: 6 0 3 - 7 8 3- 0228 E
Type of Facility: ❑ Asphalt Batch/Cold Mix ❑ Landfill/Disposal ❑ Incinerator
(check one) Asphalt Satch/Hot Mix ❑ Landfiil/Oaily Cover ❑ Temporary Storage
Thermal Processing ❑ Landfill/Structural Fill ❑ Other:
Division of Hazardous Division of Solid Waste DES-SWSPQ6002
' waste/Class A Permit#: Management Permit#: EPA Identification #: NH5986485852
Actual/Anticipated Period of Temporary Storage(specify dates if applicable): _ /— /— to �—
' Reason for Temporary Storage(if applicable):
Revised 10/1/93 This form is pnnrec on recycled paper. Page 1 of 2
' Massachusetts Department of Environmental Protection BWSC-012A
Bureau of Waste Site Cleanup
Release Tracking Number:
BILL OF LADING (pursuant to 310 CMR 40.0030) FT1 LRA
E. RECEIVING FACILITY/TEMPORARY STORAGE LOCATION (continued):
' Temporary Storage Address:
Street:
City/Town: State: Zip Code: —
' F. DESCRIPTION OF REMEDIATION WASTE:
(check all that apply)
® Contaminated Media(circle all that apply): Soil Groundwater Surface Water Other:
' ❑ Contaminated Debris(circle all that apply): Demolition/Construction Waste Vegetation/Organic Materials
Inorganic Absorbant Materials Other:
❑ Non-hazardous Uncontainerized Waste(circle all that apply): Non-aqueous Phase Liquid Other:
❑ Non-hazardous Containerized Waste(circle all that apply): Tank Bottoms/Sludges Containers Drums
Engineered Impoundments Other:
Type of Contamination(circle all that apply): Gasoline Diesel Fuel #2 Oil #4 Oil #6 Oil Waste Oil
' Kerosene Jet Fuel Other: Lead, TPH, PCBs
Estimated Volume of Materials: Cubic Yards: 8 Tons: 12 Other:
Contaminant Source(check one/specify): ❑ Transportation Accident ❑ Underground Storage Tank [�Other: , Unknown
' Response Action Associated with Bill of Lading(circle one): R s onse Action Release Abatement Measure
Utility-Related Abatement Measure Limited Removal Action(LRA) Comprehensive Response Action
' Other(specify):
Remediation Waste Characterization Support Documentation attached:
Site History Information [Sampling and Analytical Methods and Procedures 3 Laboratory Data ® Field Screening Data
If supporting documentation is not appended, provide an attachment stating the date and in connection with what document such
information was previously submitted to DER
G. LICENSED SITE PROFESSIONAL(LSP) OPINION:
' Name of organization: BENNETT & 0'REILLY, INC.
LSP Name: David C. Bennett Title: President
Telephone: 5 0 8 — 8 9 6 — 6 6 3 0 Ext.
I have personally examined and am familiar with the information contained on and submitted with1his form.:Based on this information,it is my
Opinion that the ing and assessment actions undertaken were adequate to characterize the Aterrre�3tigb:Waste,in accordance with 310
CM 40.0030, d th f r location can accept remediation wastes with the characteristics described'in:-this_submittal. I am aware
that significant enalti in d g, ut not limited to,possible fines and imprisonment may result" I wif"'Il ibmilihTormation which I know to
be false,inacc t ri lete. o CS Er'!;
EEI ETT
Signature: S":f No.
0
<..,�
— 1
Date:
`'�. iS'� GlSTEK 5/tom
License Number: 4303 �}r..�SITE p 0 •v'
H. CERTIFICATION OF PERSON CONDUCTING RESPONSE ACTION ASSOCIATED WITH THIS
BILL OF LADING:
I certify under penalties of law that I have personally examined and am familiar with the information contained in this submittal,including any
and all documents accompanying this certification,and that, based on my inquiry of those individuals immediately responsible for obtaining
the information,the material information contained herein is,to the best of my knowledge and belief,true,accurate and complete. I am aware
' that there are significant penalties, including, but not limited to, possible fines and imprisonment, for wilfully submitting false, inaccurate, or
incomplete information. p�
Signature: Date:
Name of Person(print): Helen George
Revised 10/1/93 This form is printed on recycled paper. Page 2 of 2
JAN-17-00 MON 03:56 PM ESMI NH FAX NO. 6037830104 P. 02
' i_'�'�F..',`1Ja`1 1:: '1+� Fi�•L13'3ai563 REAL ESTATE BOOK PAGE 08
of Atli vironmerstal Froteollo+n BWse-012B
Bureau at Waste Site Clearlup
BILL OF LADING (p,,,,,Ow jv?10 CLM1140.Wdoi 11r�ee fraekr+p wraps.:
LOO SWEET----OF
' 1. LOAD SETS INFOi MAT
�isinctLu• PT Aeyrasgn;sttva• t
_ .(°_(.t qr� -�•�•'���-�,r Y' ? Floceiving FnGi0li arty Stoage F1epra0onlntiva:
0�;r�'c•!Mier S:".trr:; IiniE rat yhiF,•, �'- t
Date of Rec ipt: Ti�te of,4ecalot:
Trailer Rttgiatratlon (If any): I (eye*ono) pm
_L�.=-�
$,'
5nalwJ tit Trarspererr R4prtt,;ehLrhvri: Loan,Size(cu.yds ona am/
iflotoivir9 Facility/Temporary St(Ur49M Ropfo3entYtivg•
au?u Gf T.'aniprl:unt:----^• � --.—..... F ,•
___•• Ur5-Vf SnfprttedL 1 - '
Date of Rscsipt: Time of Receipt
(rircin ong)err./pm
T ruc;i?factor
T,a�it,t Ravlshatlon(If nnyp , (t arc s onal arrJprn
Load 5iU(cu.yas.,Ronap
LOAD 3: SI{;nat re!rat'Ransf,,rfo�•Aepfeasmativo: _- - j Receiving faciJltyltempofat
t y$Wrdge Aa?rMintative:
Mali :ihium�rrt: Tim+l Of Sntprnanr: f pate of fnoccipt Time of Aecelot:
(sircie crm)am/pm
' Yr�ct:i ra: :rr Pc. ialrt a,s: Trwfof*Ad9istraoon(it any): i (ciro a orte)3 nlpm
I Load Size(eu.yda Hona): _
of Tran-.crior Hapresantative' ns": ,;rag P¢:iiitY/T9mparary 3tclape Aspraeentetive:
' .Gt0 c;Rhtpn,SlnL' Time ul SttipmCnt:
Oats of 144*40tc Tirre a Roceept
--.
TrucWt'r I.1,nr tta, :rslb�: ~
Trailer Aeg6trstion(if any): ; (c•rclo one)am/pm
' __—. __._., _ - -- r Load Size(cu.yde.Awsp
LOAILJ 51. 2l0 nahj,ti t:J Trarspvner Repr9nantaWe; Rscelvinp Facilltyrternporary 5taraSs Reprnaaruawe:
Tinto ci Sniprrlart: , oats of Fxo art' Tims of Aweip•:
' ....._•. i ...__ / �. ,. (011e;10 une)am/pm -
t
Trtr t/T roctc r I1)�yiytrili i:n r I
Trailer R@gietratian(if arty): I (cir_lo aft}arnlprti+
Load Wo(su,ydeatons):
d.a3 61: igntlhu s of Tr.araporror Aopras4nt6tive: Rscaaivinp Facility/7amporary Starnga Aapreten:ativs:
of Ch,prnmt, Ttenu of C."nmGnt i Date of A c. ./__ / - ocsi0 Time of Racciot:
- (circis one;smipm i /,-- /, 1. _
T rucf;r/I ator Trader FlagiValion(if anyy: i Mimi&on®)QrNpm
t_aael Size(ow y6s.Aar s):
L,CItD 7: �%nruurre pt Trantapt+nen FeaprasrntatiY3: -FleceNing FBo9itVffapaary Storage hpresanwivo:
Dsi.:of r.;prrti;tt: Tar-aa al V�nlpmonv bate of Ascalpt' Ti fin of ftcelpt:
/— /... (cgcJW ona)3m/om
Tn�or/Trr:,,:nr tic, tint!p:•4rt: Trttttor Ngwratlon(it SAy)t (circle onrs}arn;pm
1 --- -- ; Load Sss(cu.ydo Abney
rote!Yolums This Page(ru.yd Aons).• t S: L �� �_.
TOW Carrhid Forward(cu.ycs.Aona}:
Total Garriod Forward Wd Yh;a Pjtgs(cu.ydsJ!ona):
Kn�i ,� ;cb"U:'•i y °` re arm rs prinred onrocych0 pswr Fapr t of 7
JAN-17-00 MON 03:56 PM ESMI NH FAX NO. 6037830104 P. 03
12: I(d REAL ESTATE BOOK FACE 99
Dopartrnen#of Envlranme
ELlrebtu or`Wasic Site Cloanup nla/Ptdfec#on BW=-o120
' 'NJ" OF IADING &urg"nt a 3to c"40.cwol
SU11MI(Y "Y SHEjgT.. OF _r( -_ ❑- LR
iL 3fiMMANY Opt anlpmBNt_S:
DA7E r_lF:,-Ht1'Tvt �'T C?A1'E OF FlFI Ip'1; NUMgfR OF LOADS SH)PPED; DAILY VOLUME SHIPPED(CU,YD /t
-1 xl L)jr ----- -------------�----_-__--- -- _, ----_-__ 1e1�---_..,----
..n.r.._---------af __-__---w-.- ..-------------r rr..w------- +--�wa- -----------------
---------------
---- - ----_.__1 ----------------------------------------- ------------------------------
------r--------
r-a---------- ------ ----•--- --------------------
--- �---w---rr .-..- T----__-•-- wrrrr rr---_-_--♦Y rarrr a---_ -••__-_------r--- ..--_-r--rr-
w __ ________
-
w ----------
• .... •--r---- ------rrr------ ---^ r.
-w _w_----rw-_--_-_--__i---------•�-----..war--r---_--
-----------�-----rrr------�-- --- -------
-------------- -w--------•---------------- -------------------- wrrr r
_.....--......_-...-•.-.-- --------- .----- -------------rr_. -------- -----------------------------
.. _.-. --------- ----------------------Hew--- --- ------------------------
..
' ---=_ --• -
_-----rr ---------------- ---------'--�------------------
--------------- -------------.------------ -------------_--_----•---- --
--- --------�w�wr r.._-•--r-••---- ----------------------r--r--
-- --------------` w-- --------
-- ---wr------- ---w - --------------r---ICY- -•---------------------------
_r_rri rrwr•.---- ---------r-T_r.-rrr--..------- ---------�---r----------------
.yl.U.rlWAY SH'=;"f TUYAL SHIPPED:
' + UILL 0;;LAOINC( 1'0TA_9HIf'PCLI(pNY 7 dtffeeanQ,
tiov Qurf i!i/i�1� —" ."._,. YJlis tcr�+f It pnnled on nocy�ldds�. Page t of 2
JAN-17-00 MON 03:67 PM ESMI NH FAX NO, 6037830104 P, 04
' j1'-2/2'6I193 REAL ESTATE 50o
f'AfaE 16
3 a�xa�iia�t#� Deparh"d#2t Of Eriviranrnental Prafect/on OW30-012C
Bureau of Waste Site Cle$nup
SILL OF LADING (pumuswt la$10 cup' 40.06M, p+twa.ri.ownONtmtrt!r:a '�iaAl4 MANY S H "�' ❑-t
L. ACiCfitlW 9ONirtl1911141T OF ftl6fi IPT Ofi<ltMEDIATION WASTE AT ReCQIVIN&MAGILITV OR
'1i"�RJi►t�A�!'Y'tfTOi{/1lOR LOG�ITIONrt
' Rm�;ri•ri:1p r�►cthtYfT•Orn r:a
Title-
Date::
S,,yr•i,turrr: t �� .LL: r—L,•!�-...,,,w....,.�.,.,,.■,,,� ....�
' •,fha�IlPIttllVtiLJlFB►dl!!MOicMT QP SHIPMARN7 AND R=CfIDT Orr REMIMIATION WASTE OT'FRAON
trill tO4iCTIFII� RXXPC SV ACTION ASSOCIATED WITH THIS 1"I.L OF LADING:
f ca.t.;y unrtar pary�;oQ o .a at A have per Ih bltatnirted and am familiar with th4;ntorrnQbon contained in thin evi:.mlitai,fneludinp'any'
unu t; CnCu,v+ontz arc= par. In this", tion and that, based on my Inquiry Of lhpae 1ndNiduato immediately teVorulbia for abta;ninq
trio uvrorntattnrt.ter,+nht W informMric
in is,to the bast e!my knawtadp4 and belief,true,is=urats and oomptate, I a,n*warp
th,aF teary Cry aignilit.%rtt en iMned to,posa:bta fines and Imprittonment. for wilfully submitting falso,Inuoautdte.or
i'fGCtxl�',I�t�1,9f:1rtY1a'.IUn.
�.pnatura' Date:
Nurrio M Pstrx:hn(print): t President -w
BENNETT & O'REI"UY, INC.
' for
Helen George
Property Owner
tn,'s AYYn 14 NrZra on rocyclea pow.
rage a or a
1
JAN-17-00 MON 03:57 PM ESMI NH FAX NO. 6037830104 P. 05
ESMI
' 67 INTERNATIONAL. DR.
LOUDON NH 03307
t 6 OZ) 783--0e28
ttns,nctiou `4o. 13811s Time In i3:o8 Time Omt 13: 13 Date 01-04-00
usl;Quer Narie :F.:NVYR0--SAFE COOP Gross: 0265201b INB
AO BOX 810 Tare : 0153201b
EP..23T SANDWICH, MA
Net s 1 12001 b
luck, f•!u. ;ENVIRSPF Net Tans : 5. 60
NnQr• ,
N Running Tonnage 5. 60
E : T l-,IC: G;EORGG PROPERTY Est. Total Job Ton s 12
Jdr-e s s :SS ROAD
Y :HYFINNIs Max. Acceptable Soil : 200
1
1
1
1
1
1 i
i
I GROUNDWATER Groundwater Analytical, Inc.
P.O. Box 1200
ANALYTICAL 228 Main Street
Buzzards Bay,MA 02532
Telephone(508)759-4441
FAX(508)759-4475
' October 22, 1999
Ms. Kara Shumway
Bennett & O'Reilly, Inc.
P.O. Box 1667
Brewster, MA 02631
Project: George/13099-2511
Lab I D: 29360
Sampled: 10-07-99
' Dear Kara:
' Enclosed are the Volatile Organics, Hydrocarbon Fingerprint and Metals Analyses performed for
the above referenced project. This project was processed for Standard Two Week turnaround.
This letter authorizes the release of the analytical results, and should be considered a part of this
report. This report contains a project narrative indicating project changes and non-conformances, a
brief description of the Quality Assurance/Quality Control procedures employed by our laboratory,
' and a statement of our state certifications.
I attest under the pains and penalties of perjury that, based upon my inquiry of those individuals
immediately responsible for obtaining the information, the material contained in this report is, to
the best of my knowledge and belief, accurate and complete.
' Should you have any questions concerning this report, please do not hesitate to contact me.
Sincerely,
i
' Jonathan R. Sanford
President
J RS/awc
Enclosures
GROUNDWATER
ANALYTICAL
' EPA Method 8260B
Volatile Organics by GC/MS
Field ID: HB-1 Composite(0-6) Laboratory ID: 29360-01
Project: George/6099-2511 QC Batch ID: VM4-1173-S
Client: Bennett&O'Reilly Sampled: 10-07-99
Container: 40mL VOA Vial Received: 10-07-99
Preservation: NaHSO4/Cool Analyzed: 10-09-99
' Matrix: Soil Dilution Factor: 1
% Moisture: 11 Page: 1 of 2
CAS Numb
�.
er ."r �,' Analyte °' F Coricentrafion. ;.x Units Reportmg;lmif
75-71-8 Dichlorodifluoromethane BRL ug/Kg 20
74-87-3 Chloromethane BRL ug/Kg 20 !
75-01-4 Vinyl Chloride BRL ug/Kg 20
t ! 74-83-9 Bromomethane BRL — ug/Kg 20
75-00-3 Chloroethane BRL ug/Kg 20
75-69-4 Trichlorofluoromethane BRL ug/Kg 20
60-29-7 Diethyl Ether BRL ug/Kg 20
75-354 1,1-Dichloroethene BRL ug/Kg 10
67-64-1 Acetone BRL ug/Kg 100
! 75-15-0 Carbon Disulfide BRL ug/Kg 100
75-09-2 Methylene Chloride _ BRL ug/Kg 20
156-60-5 � trans-1,2-Dichloroethene BRL ug/Kg 10 j
1634-04-4 Methyl tert-butyl Ether(MTBE) BRL ug/Kg 10
75-34-3 1,1-Dichloroethane �— BRL uglKg j 10 1
' 59�0-20-7 2,2-Dichloropropane BRL ug/Kg 10
156-59-2 cis-1,2-Dichloroethene BRL ug/Kg 10
78-93-3 2-Butanone(MEK) _ BRL ug/Kg 100
74-97-5 Bromochloromethane _ BRL ug/Kg 10 j
109-99-9 Tetrahydrofuran (THF) i BRL ug/Kg 100
67-66-3 Chloroform BRL ug/Kg 10
71-55-6 1,1,1-Trichloroethane BRL ug/Kg 10
' 56-23-5 Carbon Tetrachloride BRL ug/Kg 10
563-58-6 1,1-Dichloropropene BRL ug/Kg 10 !
7143-2 Benzene BRL ug/Kg 10
' 107-06-2 1,2-Dichloroethane BRL ug/Kg 10 !
79-01-6 Trichloroethene BRL ug/Kg 10
78-87-5 1,2-Dichloropropane BRL ug/Kg 10
74-95-3 Dibromomethane BRL ug/Kg 10
' 75-274 I Bromodichloromethane BRL ug/Kg 10
10061-01-5 cis-1,3-Dichloropropene BRL ug/Kg 10
108-10-1 4-Methyl-2-Pentanone(MIBK) BRL ug/Kg 100
' J 108-88-3 Toluene BRL ug/Kg 10
10061-02-6 trans-1,3-Dichloropropene BRL ug/Kg 10
79-00-5 1,1,2-Trichloroethane BRL ug/Kg 10
127-184 Tetrachloroethene BRL ug/Kg 10
' 142-28-9 1,3-Dichloropropane BRL ug/Kg 10
591-78-6 2-Hexanone BRL ug/Kg 100
124-48-1 Dibromochloromethane BRL ug/Kg 10
106-93-4 1,2-Dibromoethane(EDB) BRL ug/Kg 10
108-90-7 Chlorobenzene BRL ug/Kg 10
630-20-6 1,1,1,2-Tetrachloroethane BRL ug/Kg 10
' 100-41-4 Ethylbenzene BRL ug/Kg 10
Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532
' GROUNDWATER
ANALYTICAL
' EPA Method 8260B (Continued)
Volatile Organics by GC/MS
Field ID: HB-1 Composite((1-6') Laboratory ID: 29360-01
' Project: George/B099-2511 QC Batch ID: VM4-1173-S
Client: Bennett&O'Reilly Sampled: 10-07-99
Container: 40mL VOA Vial Received: 10-07-99
' Preservation: NaHSO4/Cool Analyzed: 10-09-99
Matrix: Soil Dilution Factor: 1
% Moisture: 11 Page: 2 of 2
1Vumber =Analyte Concentrations .Units ' R ' rtn Limit
. .. g,.
108-38-3/10642-3 meta-Xylene and para-Xylene BRL ug/Kg 10
95-47-6 ortho-Xylene BRL ug/Kg 10
100-42-5 Styrene _ BRL ug/Kg 10
' 75-25-2 Bromoform j BRL ug/Kg 10
98-82-8 Isopropyl benzene _ _ BRL ug/Kg 10
108-86-1 Bromobenzene BRL I ug/Kg 10
79-34-5 1,1,2,2-Tetrachloroethane BRL ug/Kg 10
96-18-4 1 2 3 Trichloro ro ane BRL ug/Kg 10
P P I i � � g
' 103-65-1 n-Pro (benzene BRL ug/Kg 10
I --
9549-8 2-Chlorotoluene BRL _ ug/Kg 10
' 108-67-8 1,3,5-Tri methyl benzene _ BRL ug/Kg 10
�106-43-4 4-Chlorotoluene BRL ug/Kg i 10
98-06-6 tert-Butylbenzene BRL WK/ 10
95-63-6 1,2,4-Tri methyl benzene BRL ug/Kg 10
' 135-98-8 sec-Butyl benzene BRL ug/Kg 10
541-73-1 1,3-Dichlorobenzene BRL ug/Kg i 10
99-87-6 4-Isopropyltoluene BRL ug/Kg i 10
' 10646-7 1,4-Dichlorobenzene _ BRL ug/Kg j 10
95-50-1 1,2-Dichlorobenzene BRL ug/Kg j 10
I J
104-51-8 n-Butylbenzene BRL ug/Kg 10
' 96 12-8 1,2-Dibromo-3 chloropropane -- BRL ug/Kg — 10 —
120-82-1 1,2,4-Trichlorobenzene BRL ug/Kg 10
87-68-3 Hexachlorobutadiene BRL ug/Kg 10
91-20-3 Naphthalene BRL ug/Kg 10
' 87-61-6 1,2,3-Trichlorobenzene BRL ug/Kg 10
ra.QC.Surro0WCom0unds,_ -?� -:r a' "' a ."�Q LIm1tS :
Dibromofluoromethane 101 % 80-120%
' 1,2-Dichloroethane-d4 102 % 80-120 %
Toluene 100 % 81 -117%
4-Bromofluorobenzene 113 % 74-121 %
' Method Reference: Test Methods for Evaluating Solid Waste,US EPA,SW-846,Third Edition, Update III 0996). Analyte list
as specified in Tables 6 and 7 of the method,and additional analytes as specified by MA DEP Method 1
Standards(310 C.M.R.40.0973)and recommended by NH DES for initial waste site investigations,
effective 12/1/97. Results are reported on a dry weight basis.
' Report Notations: BRL Indicates concentration, if any, is below reporting limit for analyte: Reporting limit is the lowest
concentration that can be reliably quantified under routine laboratory operating conditions.
Reporting limits are adjusted for sample dilution,percent moisture and sample size.
Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532
GROUNDWATER
' ANALYTICAL
' ASTM Method D3328-90 (Modified)
Hydrocarbon Fingerprinting by GC/FID
' Field ID: HB-1 (0-0 Laboratory ID: 29360-02
Project: George/B099-2511 QC Batch ID: HF-1223-M
Client: Bennett&O'Reilly Sampled: 10-07-99
' Container: 250mL Glass Received: 10-07-99
Preservation: Cool Extracted: 10-12-99
Matrix: Soil Analyzed: 10-13-99
9/6 Moisture: 8 Dilution Factor: 1
Quahtatrve Identif�cat�on,
' This sample has GGFID characteristics that are similar to:
1. Lubricating Oil in the n-C18 to n-36 range.
Analyte r r Concentration , Umts Reporting Limtt'
Total Petroleum Hydrocarbons 1,400 mg/Kg 64
' QC SurrogA eW,Compound Recovery " k `QC Limits
,..
ortho-Terphenyl 90 % 60-140 %
' Method Reference: Comparison of Waterbome Petroleum Oils by Gas Chromatography,Volume 11.02,Water,American
Society for Testing and Materials(1990). Analytical protocol modified by use of an internal standard.
Results are quantified on the basis of 5a—androstane. Sample preparation protocol modified by use
of microwave accelerated solvent extraction. Results are reported on a dry weight basis.
' Report Notations: BRL Indicates concentration, if any,is below reporting limit for analyte. Reporting limit is the lowest
concentration that can be reliably quantified under routine laboratory operating conditions.
Reporting limits are adjusted for sample dilution and sample size.
1
' Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532
GROUNDWATER
ANALYTICAL ASTM METHOD D3328-90(Modified)
Hydrocarbon Fingerprinting (GC/FID)
' Lab ID: 29360-02 HYDROCARBONS LABORATORY
,
i r
1 4,
ME
1
1 _
5 10 15 20 25 30 35 40 45 50
' Retention time (minutes)
II
'x
GROUNDWATER
ANALYTICAL
Trace Metals by ICP-AES and CVAA
Field ID: HB-11 (0-6') Laboratory lb: 29360-03
Project: George/13099-2511 Sampled: 10-07-99
Client: Bennett&O'Reilly Received: 10-07-99
Container: 250rnL Glass % Solids 100
Preservation: Cool
Matrix: Soil
I ' p oil
-'
q-,AtA Concentration Jnil ` Li An 'C
Methoda�
._:,
7440-38-2 Arsenic,Total 2.1 mg/Kg 1.0 10-13-99 MM-0851-S 601 OB
7440-39-3 Barium,Total 24 mg/Kg 20 10-13-99 MM-0851-S 601 OB
7440-43-9 Cadmium,Total 4.2 mg/Kg 0.50 10-13-99 MM-0851-S 601 OB
7440-47-3 Chromium,Total 3.9 mg/Kg 0 10-13-99 MM-0851-S 601 OB
7439-92-1 Lead,Total 280 mg/Kg 10 10-13-99 MM-0851-S 601 OB
7439-97-6 Mercury,Total 0.10 mg/Kg 0.056 10-13-99 MP-0665-S 7471 A
7782-49-2 Selenium,Total BRL mg/Kg 0.50
1 10-13-99 MM-0851-S I 6010E
7440-224 1 Silver,Total BRL mg/Kg 5.0 10-13-99 MM-0851-S 601 OB
Method Reference: Test Methods for Evaluating Solid Waste, US EPA,SW-846,Third Edition, Update Ill(1996).
Kesuits are reportea on a dry weignt basis.
Report Notations: BRL Indicates concentration, if any, is below reporting limit for analyte. Reporting limit is the lowest
concentration tnat can be reliably quantitieci uncier routine laboratory operating conditions.
Keporting limits are aalustea tor sample dilution and sample size.
1
1
1
1 .
1
1
1
1
Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532
GROUNDWATER
' ANALYTICAL
ASTM Method D3328-90 (Modified)
Hydrocarbon Fingerprinting by GC/FID
Field ID: Sump Laboratory ID: 29360-04
Project: George/B099-2511 QC Batch ID: HF-0954-F
Client: Bennett&O'Reilly Sampled: 10-07-99
' Container: 1 L Amber Glass Preserved: 10-07-99
Preservation: H2SO4/Cool Received: 10-07-99
Matrix: Aqueous Extracted: 10-12-99
Analyzed: 10-15-99
uor DiI tin Factor:F t 1
Qualitative Identi i afion ! A a. E
No petroleum product was identified for this sample.
r
Analyte , Concentration^`
Total Petroleum Hydrocarbons ( BRL mg/L 0.3
' QC'Surrogate Compound r Recovery , QC Limits _
ortho-Terphenyl 94 % 60-140%
' Method Reference: Comparison of Waterbome Petroleum Oils by Gas Chromatography,Volume 11.02,Water,American
Society for Testing and Materials(1990). Analytical protocol modified by use of an internal standard.
Results are quantified on the basis of 5a—androstane.
Report Notations: BRL Indicates concentration, if any, is below reporting limit for analyte. Reporting limit is the lowest
concentration that can be reliably quantified under routine laboratory operating conditions.
Reporting limits are adjusted for sample dilution and sample size.
' Groundwater Analytical, Inc., P.O: Box 1200, 228 Main Street, Buzzards Bay, MA 02532
GROUNDWATER
ANALYTICAL ASTM METHOD D3328-90(Modified)
Hydrocarbon Fingerprinting (GC/RD)
' Lab ID: 29360-04 HYDROCARBONS LABORATORY
,
5 10 15 20 25 30 35 40 45 50
' Retention time (minutes)
I
GROUNDWATER
' ANALYTICAL
Project Narrative
Project: George/BO99-2511 Lab ID: 29360
Client: Bennett&O'Reilly� Y Received:e ed. 10-07-99
A..:Physical Condition rof Samples)
This project was received by the laboratory in satisfactory condition. The sample(s) were received
undamaged in appropriate containers with the correct preservation.
B: Project Documentation
This project was accompanied by satisfactory Chain of Custody documentation. The sample container
label(s) agreed with the Chain of Custody.
I
C: Analysis of Sample(s)' "
x
No analytical anomalies or non-conformances were noted by the laboratory during the processing of these
sample(s). All data contained within this report are released without qualification.
II
1
' Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532
EN
GROUNDWA 228 Main Street,P.O.Box 1200
Buzzards Bay,MA02532 CHAIN-OF-CUSTODY RECORD
ANALYTIC Telephone(sob)759-4441 AND WORK ORDER N4 37561
FAX(508)759-4475
Project Name: Firm:
C I TURNAROUND
K ,, nI/• , l I1 ANALYSIS REQUEST
` Volatles Semivolatiles Pest/Nere/PCes Motels Nedaum II srowrsen He,. General Chemistry Otaer
p4 STANDARD 00 Business Days) _ reelable al. a waste
Project Nu ber: Address: ❑ PRIORITY(5 Business Days)
TOG ❑ RUSH(RAN- j s a
_ a o
(Rush requires Rush Authorization Number)
Sampler Name: City/State/ZipA.
ryy ^ Please FAX C*ES���--❑r NO i
FAX Numbe: 4�b'CI(,> ''"'• 1 W
Project Mana er: Telephone: s
BILLING = a „
c x p
l(a(G- ;L(C:� ��(� , SCr(G���,3T1 Purchase Order No.: GWA Reference No.: c o e m s
ll� o 9 z
INSTRUCTIONS:Us.sLp-,;,tplgj for each container(except replicates).
Sampling Matriz Type Containers ii 3 $ $ s - 5 a E S
( ► Preservation rivaree - - ra �, e
SAMPLE _ S = LABORATORY W kt7Ox0 „ q _'- 0 8 0 9 - " - s a
IDENTIFICATION R `� a - - NUMBER $ a
F F S W > S a 5 a 5 a �_ g E (Lab Use Only)
0 1= 3 o E e a 11
$ $ 3 s c a 0 3 7i
rr /1 e
- �i n n r:� n :� r_ r_: - - - - - -
®r,
� ,-I 0 -1 I.
REMARKS SPECIAL INSTRUCTIONS DATA QUALITY OBJECTIVES CHAIN-OF-CUSTODY RECORD
Regulatory Program Project Specific OC NOTE:All samples submitted subject to Standard Terms and Conditions on reverse hereof.
❑Safe Drinking Water Act Many regulatory programs and EPA methods require project Relin uished b Sampler: Date Time Received by: Receipt Temperature:
❑MA DEP Form q y p
specific OC.Project specific OC includes Sample Duplicates, r
❑NPDES/Clean Water Act Matrix Spikes,and/or Matrix Spike Duplicates.Laboratory OC is �(!, ,(-r}'Ll.[r �U •C�_3n ^/1 .�
Specify Slate: not project specific unless prearranged.Project specific OC L�
RCRA/Haz.Waste Char. samples are charged on a per sample basis.For water samples, Relinquish by: Date Time elv V by:, Shipping/Airbill
v1A MCP(310 CMR 40) each MS,MSD and Sample Duplicate requires an additional Number:
Reportable Concentrations sample aliquot. ,tiX j /o4G /3_3 �/ -
RCG W-t >(RCS-1 Project Specific OC Required Selection of OC Sample relinquished Date Time Recei by L�b r t ry: Custody Seal/
❑RCGW-2❑RCS-2 ❑Sample Duplicate ❑Selected by laboratory ` ( vG� _ Cooler Serial
Cl MA Dredge Disposal ❑Matrix Sp ike Number:
❑NH❑RI❑CT[I ME Please use sample: Method of Shipment�G WA Courier ❑Express Mail'ClFederal Express
Specify Category: ❑Matrix Spike Duplicate
0
UPS [I Hand O
LFRCIUN13WATER
ANALYTICAL
I ' Quality Assurance/Quality Control
A.;Program Overview
Groundwater Analytical conducts an active Quality Assurance program to ensure the pr
oduction oduction of h'Q tY p g p high
' quality, valid data. This program closely follows the guidance provided by Interim Guidelines and
Specifications for Preparing Quality Assurance Project Plans, US EPA QAMS-005/80 (1980), and Test
Methods for Evaluating Solid Waste, US EPA, SW-846, Update III (1996).
I ' Quality Control protocols include written Standard Operating Procedures (SOPS) developed for each
analytical method. SOPS are derived from US EPA methodologies and other established references.
Standards are prepared from commercially obtained reference materials of certified purity, and documented
' for traceability.
Quality Assessment protocols for most organic analyses include a minimum of one laboratory control sample,
one method blank, one matrix spike sample, and one sample duplicate for each sample preparation batch.
' All samples, standards, blanks, laboratory control samples, matrix spikes and sample duplicates are spiked
with internal standards and surrogate compounds. All instrument sequences begin with an initial calibration
verification standard and a blank; and excepting GUMS sequences, all sequences close with a continuing
calibration standard. GUMS systems are tuned to appropriate ion abundance criteria daily, or for each 12
hour operating period, whichever is more frequent.
Quality Assessment protocols for most inorganic analyses include a minimum of one laboratory control
sample, one method blank, one matrix spike sample, and one sample duplicate for each sample preparation
' batch. Standard curves are derived from one reagent blank and four concentration levels. Curve validity is
verified by standard recoveries within plus or minus ten percent of the curve.
' B. Definitions
' Batches are used as the basic unit for Quality Assessment. A Batch is defined as twenty or fewer samples of
the same matrix which are prepared together for the same analysis, using the same lots of reagents and the
same techniques or manipulations, all within the same continuum of time, up to but not exceeding 24 hours.
Laboratory Control Samples are used to assess the accuracy of the analytical method. A Laboratory Control
Sample consists of reagent water or sodium sulfate spiked with a group of target analytes representative of the
method analytes. Accuracy is defined as the degree of agreement of the measured value with the true or
' expected value. Percent Recoveries for the Laboratory Control Samples are calculated to assess accuracy.
a
Method Blanks are used to assess the level of contamination present in the analytical system. Method Blanks
consist of reagent water or an aliquot of sodium sulfate. Method Blanks are taken through all the appropriate
' steps of an analytical method. Sample data reported is not corrected for blank contamination.
Surrogate Compounds are used to assess the effectiveness of an analytical method in dealing with each
sample matrix. Surrogate Compounds are organic compounds which are similar to the target analytes of
interest in chemical behavior, but which are not normally found in environmental samples. Percent
Recoveries are calculated for each Surrogate Compound..
' Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532
GROUNDWATER
ANALYTICAL
' Quality Control Report
Laboratory Control Sample
' Category: EPA Method 8260B
QC Batch ID: VM4-1173-SL
Matrix: Soil
Units: ug/Kg
- CAS;Number, �:" ':Anal,' e,: > ' ,i; x
yt . ; - Spiked Measured ,Recovery QC'Lmits,m.
75-35-4 1,1 Dichloroethene 50 46 92% 70-130 %
7143-2 Benzene 50 46 96% 70- 130 %
79-01-6 1 Trichloroethene 50 46 91 % 70- 130 %
108-88-3 Toluene 50 45 89% 70- 130 %
108-90 7 Chlorobenzene 50 46 92 % 70- 130 %
' ;'QC'SulrrogateCompounls ecovery
Dibromofluoromethane 100 80- 120 %
1,2-Dichloroethane-d4 11 103 % 80-120 %
' Tol uene-d8 100 % 81 -117%
4-Bromofluorobenzene 98 % 74-121 %
Method Reference: Test Methods for Evaluating Solid Waste, US EPA,SW-846,Third Edition, Update III (1996).
Report Notations: All calculations perf6rmed prior to rounding. Quality Control Limits are defined by the methodology,
or alternatively based upon the historical average recovery plus or minus three standard deviation units.
i.
1
' Groundwater Analytical, In P. . Box 1 Main
yt Inc., P.O. 200, 228 ain Street, Buzzards Bay, MA 02532
GROUNDWATER
' ANALYTICAL
' Quality Control Report
Method Blank
' Category: EPA Method 82608
QC Batch ID: VM4-1173-SB
Matrix: Soil
Page: 1 of 2
CAS'-N"umbers n Aria l`yte ::Concentration .Units Reporting;,limit e, ..
75-71-8 DichIorodifluoromethane BRL ug/Kg 10
74-87-3 Chloromethane BRL ug/Kg 10
' 75-014 Vinyl Chloride BRL ug/Kg 10
74-83-9 Bromomethane BRL ug/Kg 10
75-00-3 Chloroethane BRL ug/Kg 10
' 75-69-4 Trichlorofluoromethane BRL ug/Kg 10
60-29-7 Diethyl Ether BRL ug/Kg 10
75-35-4 1,1-Dichloroethene BRL ug/Kg 5
67-64-1 Acetone BRL o ug/Kg 50
75-15-0 Carbon Disulfide BRL ug/Kg 50
75-09-2 Methylene Chloride BRL ug/Kg _ 10
15 60-5 trans-1,2-Dichloroethene BRL ug/Kg 5
1634-04-4 Methyl tert-butyl Ether(MTBE) BRL ug/Kg 5
75-34-3 1,1-Dichloroethane BRL ug/Kg 5
590-20-7 2,2-Dichloropropane BRL ug/Kg 5
156-59-2 cis-1,2-Dichloroethene BRL ug/Kg 5
78-93-3 2-Butanone(MEK) BRL ug/Kg 50
74-97-5 Bromochloromethane BRL ug/Kg _ 5
109-99-9 Tetrahydrofuran(THF) BRL ug/Kg 50
67-66-3 Chloroform BRL ug/Kg 5
71-55-6 1,1,1-Trichloroethane BRL ug/Kg 5
56-23-5 Carbon Tetrachloride BRL ug/Kg 5
563-58-6 1,1-Dichloropropene BRL ug/Kg 5
' 7143-2 Benzene BRL ug/Kg 5
107-06-2 1,2-Dichloroethane BRL ug/Kg 5
79-01-6 Trichloroethene BRL ug/Kg 5
' 78-87-5 1,2-Dichloropropane BRL ug/Kg 5
74-95-3 Dibromomethane BRL ug/Kg 5
75-274 Bromodichloromethane BRL ug/Kg 5
' 10061-01-5 cis-1,3-Dichloropropene BRL ug/Kg 5
108-10-1 4-Methyl-2-Pentanone(MIBK) BRL ug/Kg 50
108-88-3 Toluene BRL ug/Kg 5
10061-02-6 trans-1,3-Dichloropropene BRL ug/Kg 5
' 79-00-5 1,1,2-Trichloroethane BRL ug/Kg 5
127-184 Tetrachloroethene BRL ug/Kg 5
142-28-9 1,3-Dichloropropane BRL ug/Kg 5
' 591-78-6 2-Hexanone BRL ug/Kg 50
124-48-1 Dibromochloromethane BRL ug/Kg 5
106-93-4 1,2-Dibromoethane(EDB) BRL ug/Kg 5
108-90-7 Chlorobenzene BRL ug/Kg 5
630-20-6 1,1,1,2-Tetrachloroethane BRL ug/Kg 5
100-41-4 Ethylbenzene BRL ug/Kg 5
' Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532
GROUNDWATER
ANALYTICAL
' Quality Control Report
Method Blank
' Category: EPA Method 8260B
QC Batch ID: VM4-1173-SB
Matrix: Soil
' Page 2 of 2
CAS Number Analyte „Concenfrafion r „Units` f.Reporting.Limif
108-38-3/106-42-3 meta-Xyleneandpara-Xylene BRL ug/Kg 5
95-47-6 ortho-Xylene BRL ug/Kg 5
' 100-42-5 Styrene BRL ug/Kg 5
75-25-2 Bromoform BRL ug/Kg 5
98-82-8 1 sop ropylbenzene BRL ug/Kg 5
' 108-86-1 Bromobenzene BRL ug/Kg 5
79-34-5 1,1,2,2-Tetrachloroethane BRL ug/Kg 5
1 96-18-4 1,2,3-Trichlor6propane BRL ug/Kg 5
103-65-1 n-Propylbenzene BRL ug/Kg 5
' 9549-8 2-Chlorotoluene _ BRL j ug/Kg 5
108-67-8 1,3,5-Trimethylbenzene BRL ug/Kg 55 i
106-43-4 4-Chlorotoluene BRL ug/Kg 5
98-06-6 tert-Butylbenzene BRL ug/Kg i 5
95-63-6 1,2,4-Tri methyl benzene BRL ug/Kg 5
135-98-8 sec-Butylbenzene BRL ug/Kg 5
541-73-1 1,3-Dichlorobenzene _ BRL ug/Kg 5
' 99-87-6 44sopropyltoluene BRL _ ug/Kg r 5
10&46-7 1,4Dichlorobenzene BRL ug/Kg j 5
95-50-1 1,2-Dichlorobenzene BRL ug/Kg 5
104-51-8 n-Butylbenzene BRL ug/Kg 5
96-12-8 1,2-Dibromo-3-chloropropane I BRL ug/Kg 5
120-82-1 1,2,4-Trichlorobenzene BRL ug/Kg 5
87-68-3 Hexachlorobutadiene BRL ug/Kg 5
' 91-20-3 Naphthalene BRL ug/Kg 5
87-61-6 1,2,3-Trichlorobenzene BRL ug/Kg 5
QC Su0ogate Gompoun`ds. ,� r ,'Recovery �.M. QC Limits y
Dibromofluoromethane 96 % 80-120
1,2-Dichloroethane-d4 98 % 80-120%
Toluene-d8 100 % 81 - 117
4-Bromofluorobenzene 110 % 74- 121 %
Method Reference: Test Methods for Evaluating Solid Waste, US EPA,SW-846,Third Edition, Update III(1996). Analyte list
as specified in Tables 6 and 7 of the method,and additional analytes as specified by MA DEP Method 1
Standards(310 C.M.R.40.0973)and recommended by NH DES for initial waste site investigations,
' effective 12/1/97. Results are reported on a dry weight basis.
Report Notations: BRL Indicates concentration,if any, is below reporting limit for analyte. Reporting limit is the lowest
concentration that can be reliably quantified under routine laboratory operating conditions.
' Reporting limits are adjusted for sample dilution,percent moisture and sample size.
Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532
GROUNDWATER
ANALYTICAL
Quality Control Report
Laboratory Control Sample
Category: ASTM Method D3328-90(Modified)
QC Batch ID: HF-1223-M
Matrix: Soil
Units: rng/Kg
Method Reference: Comparison of Waterbome Petroleum Oils by Gas Chromatography,Volume 11.02,Water,American
Society for Testing and Materials(1990). Analytical protocol modified by use of an internal standard.
Results are quantified on the basis of 5a—androstane. Sample preparation protocol modified by use
of microwave accelerated solvent extraction. Results are reported on a dry weight basis.
Report Notations: All calculations performed prior to rounding. Quality Control Limits are defined by the methodology,
or alternatively based upon the historical average recovery plus or minus three standard deviation units.
Groundwater Analytical, |nc, P.C). Box 1ZUU 228 Main Street, Buzzards Bay, k»AO2S32
U
'
GROUNDWATER
' ANALYTICAL
' Quality Control Report
Method Blank
' Category: ASTM Method D3328-90(Modified)
QC Batch ID: HF-1223-M
Matrix: Soil
Concentrations Units' Reporting
Total Petroleum Hydrocarbons BRL mg/Kg 60
q C'Surro te.:Com and .rc
�eCOVer)+
ortho-Terphenyl 82 % 60-140 %
' Method Reference: Comparison of Waterborne Petroleum Oils by Gas Chromatography,Volume 11.02,Water,American
Society for Testing and Materials(1990). Analytical protocol modified by use of an internal standard.
Results are quantified on the basis of 5a—androstane. Sample preparation protocol modified by use
of microwave accelerated solvent extraction. Results are reported on a dry weight basis.
on a dry weight basis.
Report Notations: BRL Indicates concentration, if any, is below reporting limit for analyte. Reporting limit is the lowest
concentration that can be reliably quantified under routine laboratory operating conditions.
Reporting limits are adjusted for sample dilution and sample size.
' Groundwater Analytical, Inc. P.O. Box 1200 228 Main Street, z r yt Buzzards ds Bay, MA 02532
GROUNDWATER
' ANALYTICAL
QUALITY ASSURANCE
' Laboratory Control Sample Recovery
Category: Trace Metals
Matrix: Soil
Units: mg/Kg
Laboratory Control Sample
SPIKE SPIKED PERCENT QC
' ANALYTE BATCH ID ADDED RESULT RECOVERY LIMITS
Barium MM-0851-SLI 100 95 95 % 75-12
Cadmium MM-0851-SLI 100 94 94 % 75-125
' Chromium MM-0851-SLI 100 93 93 % 75-125
Lead MM-0851-SLI 100 92 92 % 75-125
Silver MM-0851-SLI 100 92 92 % 75-125
Arsenic MM-0851-SLF 5.0 4.8 97 % 75-125
Selenium MM-0851-SLF 5.0 4.8 97 % 75-125
' Mercury MP-0665-SL 0.250 0.210 86 % 75-125
' Quality Control Limits are defined by the methodology, or alternatively based upon the historical average
recovery plus or minus three standard deviation.units.
GROUNDWATER
ANALYTICAL
QUALITY ASSURANCE
' Method Blank
Category: Trace Metals
Matrix: Soil
' REPORTING EPA
PARAMETER CONCENTRATION LIMIT BATCH ID METHOD
(mg/Kg) (mg/Kg)
' Barium BRL 20 MM-0851-SB 6010
Cadmium BRL 0.50 MM-0851-SB 6010
' Chromium BRL 1.0 MM0851SB 6010
Lead BRL 10 MM-0851-SB 6010
Silver BRL 5.0 MM 0851 SB 6010
Arsenic BRL 1 .0 MM-0851-SB 6010
Selenium BRL 0.50 MM-0851-SB 6010
Mercury BRL 0.050 MP-0665-SB 7471
BRL = Below Reporting Limit. Method References: Test Methods for Evaluating Solid Waste, US EPA SW-846,
Third Edition (1986). Graphite Furnace analyses performed with Zeeman background correction and Lvov
platform technique.
GROUNDWATER
' ANALYTICAL
' Quality Control Report
Laboratory Control Sample
' Category: ASTM Method D3328-90(Modified)
QC Batch ID: HF-0954-F
Matrix: Aqueous
Units: mg/L
Analyte �'
Spiked Measured Recovery QC Limits
Fuel Oil No. 2 2.0 2.2 109% 60- 140 %
' `QC Surrogate:Gompound Recovery QC LImItS F
ortho-Terphenyl 98 % 60-140 %
' Method Reference: Comparison of Waterbome Petroleum Oils by Gas Chromatography,Volume 11.02,Water,American
Society for Testing and Materials(1990). Analytical protocol modified by use of an internal standard.
Results are quantified on the basis of 5a—androstane.
' Report Notations: All calculations performed prior to rounding. Quality Control Limits are defined by the methodology,.
or alternatively based upon the historical average recovery plus or minus three standard deviation units.
1
{
' Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532
GROUNDWATER
ANALYTICAL
' Quality Control Report
Method Blank
' Category: ASTM Method D3328-90 (Modified)
QC Batch I D: H F-0954-F
Matrix: Aqueous p
R,epOf'ting;"
Ar18lyte Rc e
ntlatlOnUnit3:
w mu CO .i
Total Petroleum Hydrocarbons BRL mg/L 0.2
QC.$arrogdtemCOmpound zr zy d Y x Recovery t QC Ir171tS +
ortho-Terphenyl 91 % 60-140 %
Method Reference: Comparison of Waterbome Petroleum Oils by Gas Chromatography,Volume 11.02,Water,American
Society for Testing and Materials(1990). Analytical protocol modified by use of an internal standard.
Results are quantified on the basis of 5a—androstane.
Report Notations: BRL Indicates concentration, if any,is below reporting limit for analyte. Reporting limit is the lowest
' concentration that can be reliably quantified under routine laboratory operating conditions.
Reporting limits are adjusted for sample dilution and sample size.
' Groundwater Analytical, Inc. P.O. Box 1200 228 Main Street Buzzards Ba MA 02532 .
Yt Y,
GROUNDWATER
' ANALYTICAL
tCertifications and Approvals
CONNECTICUT,;Department of Health Service§; `PH=0586
M
Potable Water,Wastewater/Trade Waste,Sewage/Effluent,and Soil
pH,Conductivity,Acidity,Alkalinity,Hardness,Chloride,Fluoride,Ammonia,Kjeldahl Nitrogen,Nitrate,Nitrite,Orthophosphate,Total Dissolved
' Solids,Cyanide,Aluminum,Antimony,Arsenic,Barium,Beryllium,Cadmium,Total Chromium,Hexavalent Chromium,Cobalt,Copper,Iron,Lead,
Magnesium,Manganese,Mercury,Molybdenum,Nickel,Potassium,Selenium,Silver,Sodium,Thallium,Tin,Titanium,Vanadium,Zinc,Purgeable
Halocarbons,Purgeable Aromatics,Pesticides,PCBs,PCBs in Oil,Ethylene Dibromide,Phenols,Oil and Grease.
MAINE;;Department of Human Services; MA103
Drinking Water
Reciprocal certification in accordance with Massachusetts certification for drinking water analytes.
' Waste Water
Reciprocal certification in accordance with Massachusetts certification for waste water analytes.
' MASSACHUSETTS, Department of-EnvironmentalTrotection M MA'103
Potable Water
Antimony,Arsenic,Barium,Beryllium,Cadmium,Chromium,Copper,Lead,Mercury,Nickel,Selenium,Thallium,Nitrate-N,Nitrite-N,Fluoride,
' Sodium,Sulfate,Cyanide,Turbidity,Residual Free Chlorine,Calcium,Total Alkalinity,Total Dissolved Solids,pH,Trihalomethanes,Volatile Organic
Compounds,1,2-Dibromoethane,1,2-Dibromo-3-chloropropane,Total Coliform,Fecal Coliform,Heterotrophic Plate Count,E-Coli
Non-Potable Water
' Aluminum,Antimony,Arsenic,Beryllium,Cadmium,Chromium,Cobalt,Copper,Iron,Lead,Manganese,Mercury,Molybdenum,Nickel,Selenium,
Silver,Strontium,Thallium,Titanium,Vanadium,Zinc,pH,Specific Conductance,Total Dissolved Solids,Total Hardness,Calcium,Magnesium,
Sodium,Potassium,Total Alkalinity,Chloride,Fluoride,Sulfate,Ammonia-N,Nitrate-N,Kjeldahl-N,Orthophosphate,Total Phosphorus,Chemical
Oxygen Demand,Biochemical Oxygen Demand,Total Cyanide,Non-Filterable Residue,Total Residual Chlorine,Oil and Grease,Total Phenolics,
Volatile Halocarbons,Volatile Aromatics,Chlordane,Aldrin,Dieldrin,DDD,DDE,DDT,Heptachlor,Heptachlor Epoxide,Polychlorinated
' Biphenyls(water),Polychlorinated Biphenyls(oil).
MICHIGAN, Department oUEnvironmental`Quality
' Drinking Water
Trihalomethanes,Regulated and Unregulated Volatile Organic Compounds by EPA Method 524.2;1,2-Dibromoethane,1,2-Dibromo-3-
chloropropane by EPA Method 504.1
' ,NEW'HAMPSHIRE, Department of Environmental Services, 202798
Drinking Water
Metals by Graphite Furnace,Metals by ICP,Mercury,Nitrite-N,Orthophosphate,Residual Free Chlorine,Turbidity,Total Filterable Residue,Calcium
' Hardness,pH,Alkalinity,Sodium,Sulfate,Total Cyanide,Insecticides,Herbicides,Base/Neutrals,Trihalomethanes,Volatile Organics,Vinyl
Chloride,DBCP,EDB,Nitrate-N.
Wastewater
' Metals by Graphite Furnace,Metals by ICP,Mercury,pH,Specific Conductivity,TDS,Total Hardness,Calcium,Magnesium,Sodium,Potassium,
Total Alkalinity,Chloride,Fluoride,Sulfate,Ammonia-N,Nitrate-N,Orthophosphate,TKN,Total Phosphorus,COD,BOD,Non-Filterable Residue,
Oil&Grease,Total Phenolics,Total Residual Chlorine,PCBs in Water,PCBs in Oil,Pesticides,Volatile Organics,Total Cyanide.
z-RHODE ISLAND, Department of Health, 54
a � w
717
Surface Water,Air,Wastewater, Potable Water,Sewage
Chemistry: Organic and Inorganic
' Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532
GROUNDWATER Groundwater Analytical,Inc.
P.O.Box 1200
ANALYTICAL 228 Main Street
Buzzards Bay,MA 02532
' Telephone(508)759-4441
FAX(508)759-4475
' November 1, 1999
' Mr. David Bennett
Bennett & O'Reilly, Inc.
' P.O. Box 1667 .
Brewster, MA 02631
Project: George/113099-2511
Lab ID: 29624
Sampled: 10-22-99
' Dear Dave:
Enclosed are the Volatile Organics, Extractable Petroleum Hydrocarbons, Hydrocarbon Fingerprint
and Metals Analyses performed for the above referenced project. This project was processed for
Priority One Week turnaround.
' This letter authorizes the release of the analytical results, and should be considered a part of this
report. This report contains a project narrative indicating project changes and non-conformances, a
brief description of the Quality Assurance/Quality Control procedures employed by our laboratory,
and a statement of our state certifications.
I attest under the pains and penalties of perjury that, based upon my inquiry of those individuals
' immediately responsible for obtaining the information, the material contained in this report is, to
the best of my knowledge and belief, accurate and complete.
' Should you have any questions concerning this report, please do not hesitate to contact me.
Sincerely,
3414!
' Jonathan R. Sanford at . Sa fo d
President
J RS/awc
Enclosures
GROUNDWATER
ANALYTICAL
EPA Method 8260B
Volatile Organics by GCIMS
Field ID: HB-2:2-8' Laboratory ID: 29624-01
Project: George/B099-2511 QC Batch ID: VM4-1185-S
Client: Bennett&0 Reilly Sampled: 10-22-99
Container: 40mL VOA Vial Received: 10-25-99
Preservation: NaHSO4 Cool Analyzed: 10-27-99
Matrix: Soil Dilution Factor: 1
%Moisture: 17 Page: 1 of 2
'k!CA t-'16 1 "1 I;_,__ -
',�.x�oricenraiqnl
09,
,,�_nayt p
75-71-8 Dichlorodifl yoromethane BRL uWKg 10
74-87-3 Chloromethane BRL ug/Kg 10
75-01-4 Vinyl Chloride BRL ug/Kg 10
74-83-9 Bromomethane BRL ug/Kg 10
75-00-3 Chloroethane
BRL ug/Kg 10
75-69-4 Trichlorofluoromethane BRIL ug/Kg 10
60-29-7 Diethyl Ether BRIL ug/Kg 10
75-35-4 1,1-Dichloroethene
BRIL ugtKg 5
67-64-1 Acetone BRIL ug/Kg 50
75-15-0 Carbon Disulfide ug/Kg 50 -7
BRIL
ug/Kg 10
75-09-2 Methylene Chloride BRIL
156-60-5 trans-1,2-Dichloroethene BRIL ug/Kg 5
1634-04-4 Methyl tert-butyl Ether(MTBE) BRIL ug/Kg 1 5
75-34-3 1,1-Dichloroethane BRIL u Kg 5
590-20-7 2,2-Dichloropropane BRIL ug/Kg 5
156-59-2 cis-1,2-Dichloroethene BRL ug/Kg 5
78-93-3 2-Butanone(MEK) BRIL ug/Kg 50
74-97-5 Bromo hloromethane BRIL ug/Kg 5
109-99-9 Tetrahydrofuran(THF) BRL ug/Kg 50
67-66-3 Chloroform BRL ug/Kg 5
71-55-6 1,1,1-Trichloroethane BRL I ug/Kg 5
56-23-5 Carbon Tetrachloride BRL ug/Kg 5
563-58-6 1,1-Dichloropropene BRL ug/Kg 5
7143-2 Benzene BRL ug/Kg 1 5
107-06-2 1,2-Dichloroethane BRL ug/Kg 5
79-01-6 Trichloroethene BRIL ug/Kg
5--------
78-87-5 1,2-Dichloropropane BRL ug/Kg 5 -1
74-95-3 Dibromomethane BRL uWKg 5
75-274 Bromodichloromethane BRL uWKg 5
10061-01-5 cis-1,3-Dichloropropene BRL ug/Kg 5
108-10-1 4-Methyl-2-Pentanone(MIBK) BRL ug/Kg 50
108-88-3 Toluene BRL ug/Kg 5
10061-02-6 trans-1,3-Dichloropropene BRL ug/Kg 5
79-00-5 1,1,2-Trichloroethane BRIL ug/Kg 5
127-184 Tetrachloroethene BRIL ug/Kg 5
142-28-9 1,3-Dichloropropane BRIL ug/Kg 5
591-78-6 2-Hexanone BRIL ugtKg 50
124-48-1 Dibromochloromethane BRIL ug/Kg 5
106-934 1,2-Dibromoethane(EDB) BRIL ug/Kg 5
108-90-7 Chlorobenzene BRIL ug/Kg 5
630-20-6 1,1,1,2-Tetrachloroethane BRL ug/Kg 5
100-41-4 Ethylbenzene BRIL ug/Kg 5
Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532
GROUNDWATER
ANALYTICAL
' EPA Method 8260B (Continued)
Volatile Organics by GC/MS
Field ID: HB-2:2-8' Laboratory ID: 29624-01
' Project: George/BO99-2511 QC Batch ID: VM4-1185-S
Client: Bennett&O Reilly Sampled: 10-22-99
Container: 40mL VOA Vial Received: 10-25-99
' Preservation: NaHSO4/Cool Analyzed: 10-27-99
Matrix: Soil Dilution Factor: 1
% Moisture: 17 Page: 2 of 2
' :CAS Numbers w „ E A`nalyte,, - „;Gonceritat�oq r z Units Reporting limit
108 38-3/106-42-3 j meta Xylene and para-Xylene BRL ug/Kg 5
95-47-6 1 ortho-Xylene BRL 1 ug/Kg 5
10042-5 Styrene BRL ug/Kg 5
' 75-25-2 Bromoform BRL -- ug/Kg 5
j 98-82-8 I sop ropyl benzene
_ BRL ug/Kg 5 _!
108-86-1 Bromobenzene ? _ BRL ug/Kg T5
j 79-345 1,1,2,2-Tetrach loroethane BRL I _ ug/Kg —L_ 5
' 96-184 1,2,3-Trichloropropane BRL _ ug/Kg 1 _ 5
103-65-1 n-Propyl benzene ! _ BRL I ug/Kg _ 5
95-49-8 2-Chlorotoluene BRL g/ 5 j
j 108-67-8 1,3,5-Tri methyl benzene BRL ug/Kg S
10643-4 4-Chlorotoluene BRL ug/Kg _ 5
98-06-6 tert-Butyibenzene j BRL ug/Kg 5
195-63-6 1,2,4-Trimethylbenzene BRL 1 ug/Kg 5_
135-98-8 sec-Butyibenzene BRL _ ug/Kg _ 5-
541-73-1 1,3-Dichlorobenzene BRL _ ug/Kg5
99-87-6 4-Isopropyltoluene BRL ug/Kg _ 5
' 106-46-7 1,4-Dichlorobenzene — BRL ug/Kg — 5
95-501 1,2-Dichlorobenzene BRL ug/Kg 5
—�----—
104-51-8 n-Butylbenzene —L _ BRL ug/Kg 5
96-12-8 1,2-Dibromo-3-chloropropane � _— BRL ug/Kg 5_-
120-82-1 1,2,4-Trichlorobenzene BRL ug/Kg 5
87-68-3 Hexachlorobutadiene BRL ug/Kg 5 j
91-20-3 Naphthalene BRL ug/Kg 5
' 87 61 6 1,2,3 Trichlorobenzene BRL ug/Kg 5 J
Dibromofluoromethane 108 % 80-120 %
' 1,2-Dichloroethane-d4 103 % 80-120 %
Toluene-de 98 % 81 - 117%
4-Bromofluorobenzene 104 % 74-121 %
' Method Reference: Test Methods for Evaluating Solid Waste, US EPA,SW-846,Third Edition, Update III(1996). Analyte list
as specified in Tables 6 and 7 of the method,and additional analytes as specified by MA DEP Method 1
Standards(310 C.M.R.40.0973)and recommended by NH DES for initial waste site investigations,
effective 12/1/97. Results are reported on a dry weight basis.
Report Notations: BRL Indicates concentration,if any, is below reporting limit for analyte. Reporting limit is the lowest
concentration that can be reliably quantified under routine laboratory operating conditions.
Reporting limits are adjusted for sample dilution,percent moisture and sample size.
'I
l
Groundwater Analytical, Inc. P.O. Box 1200 228 Main Street, Buzzards B yt e , ay, MA 02532
GROUNDWATER
' ANALYTICAL
Massachusetts DEP EPH Method
' Extractable Petroleum Hydrocarbons by GC/FID
Field ID: HB-lA:2-6' Laboratory ID: 29624-03
Project: George/B099-2511 QC Batch ID: EP-0780-M
Client: Bennett&O'Reilly Sampled: 10-22-99
Container: 250mL Glass Received: 10-25-99
Preservation: Cool Extracted: 10-26-99
' Matrix: Soil Analyzed: 10-27-99
% Moisture: 6 Dilution Factor: Aliphatic:1 Aromatic:1
;EPHPRanges'f a .y'r �. ', ,.'Concentrationx �...f �UmtS< 'Reporttng.Eimt
n-C9 to n-C18 Aliphatic Hydrocarbons BRL mg/Kg 32
n-C19 to n-C36 Aliphatic Hydrocarbons BRL mg/Kg 32
n-C11 to n-C22 Aromatic Hydrocarbons BRL mg/Kg 32
' Un d u n C11 to n-C22 Aromatic Hydrocarbons} BRL mg/Kg 32
waW Number „ ` q,,Target Analytes'A ,t r s, ', . Concentration � ,,Units:.,,-., ,Reportmg�fimit-
91-20-3 Naphthalene BRL mg/Kg 0.51
' 91-57-6 2-Methyl naphthalene BRL I mg/Kg 0.51
85-01-8 j Phenanthrene BRL mg/Kg 0.51
83-32-9 Acenaphthene BRL mg/Kg 0.51
208-96-8 Acenaphthylene BRL mg/Kg 0.51
' 86-73-7 Fluorene BRL mg/Kg 0.51
120-12-7 Anthracene BRL mg/Kg 0.51
206-44-0 Fluoranthene BRL mg/Kg 0.51
129-00-0 j Pyrene BRL mg/Kg 0.51 1
56-55-3 Benzo[ajanthracene BRL mg/Kg 0.51
218-01-9 1 Chrysene _ BRL mg/Kg 0.51
205-99-2 I Benzo[b]fluoranthene BRL mg/Kg 0.51
207-08-9 ! Benzo[klfluoranthene BRL mg/Kg 0.51
50-32-8 Benzo[a]pyrene BRL mg/Kg 0.51
193-39-5 Indeno[1,2,3-c,d]pyrene BRL mg/Kg 0.51
' 53-70-3 Dibenzo[a,h]anthracene BRL mg/Kg 0.51
191 24-2 Benzo[g,h,i]perylene BRL mg/Kg 0.51
- QC SurrogateKCompounds ecovery a , QC Limits' _ '
Fractionation: 2-Fluor biphenyl 76 % 40- 140 %
' 2-Bromonaphthalene 73 % 40- 140 %
Extraction: Chloro-octadecane 70 % 40-140 %
1 ortho-Terphenyl 76 % 40-140%
1. Were all QA/QC procedures required by the method followed? Yes
2. Were all performancelacceptance standards for the required QA/QC procedures achieved? Yes
' 3. Were any significant modifications made to the method,as specified in Section 11.3.1.1? Yes
Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative
and project quality control report. Release of this data is authorized by the accompanying signed project cover letter.
The accompanying cover letter,project narrative and quality control report are considered part of this data report.
Method Reference: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998). Results are calculated
on a dry weight basis. Method modified by use of microwave accelerated solvent extraction technique.
Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest
concentration that can be reliably quantified under routine laboratory operating conditions.
Reporting limits are adjusted for sample dilution,percent moisture and sample size.
t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting it
that range.
' 0 n-C11 to n-C22 Aromatic Hydrocarbons range data excludes the method target analyte concentrations.
Groundwater Analytical, Inc., P.O. Box 1200 228 Main Street Buzzards Ba MA 02532
Yt Y,
GROUNDWATER
ANALYTICAL
Massachusetts DEP EPH Method
Extractable Petroleum Hydrocarbons by GC/FID
Field ID: HB-lA:6-8' Laboratory ID: 29624-04
' Project: George/B099-2511 QC Batch ID: EP-0780-M
Client: Bennett&O'Reilly Sampled: 10-22-99
Container: 250mL Glass Received: 10-25-99
Preservation: Cool Extracted: 10-26-99
' Matrix: Soil Analyzed: 10-28-99
%Moisture: 1 Dilution Factor: Aliphatic:1 Aromatic:1
EPH'Ranges x `" 'Concerifrafwn -rUriits .M Reporting Limit- .,..y
n-C9 to n-C18 Aliphatic Hydrocarbons BRL mg/Kg 30
n-C19 to n-C36 Aliphatic Hydrocarbons BRL mg/Kg 30
n-C11 to n-C22 Aromatic Hydrocarbons BRL mg/Kg 30
' Unadjusted n-C11 ton C22 Aromatic Hydrocarbons f BRL mg/Kg 30
`.QC Surrogate'Cori-pounds-` . ,,Recove x +,ry Q,C.L�mits �.
Fractionation: 2-Fluorobiphenyl 81 % 40-140 %
2-Bromonaphthalene 74 % 40-140 %
Extraction: Chloro-octadecane 75 % _40- 140
ortho-Terphenyl j _ 81 % 40-140 %
,QA/QC'CCrtificdton r-41
1. Were all QA/QC procedures required by the method followed? Yes
2. Were all performancelacceptance standards for the required QA/QC procedures achieved? Yes
3. Were any significant modifications made to the method,as specified in Section 11.3.1.1? Yes
' Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative
and project quality control report. Release of this data is authorized by the accompanying signed project cover letter.
The accompanying cover letter,project narrative'and quality control report are considered part of this data report.
Method Reference: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998). Results are calculated
' on a dry weight basis. Method modified by use of microwave accelerated solvent extraction technique.
Report Notations: BRL Indicates concentration, if any,is below reporting limit for analyte. Reporting limit is the lowest
concentration that can be reliably quantified under routine laboratory operating conditions.
Reporting limits are adjusted for sample dilution,percent moisture and sample size.
' t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting it
that range.
0 n-C11 to n-C22 Aromatic Hydrocarbons range data excludes the method target analyte concentrations.
i
Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532
GROUNDWATER
ANALYTICAL
Massachusetts DEP EPH Method
' Extractable Petroleum Hydrocarbons by GC/FI D
Field ID: 1-118-2:8-10 Laboratory.ID: 29624-05
Project: George/B099-2511 QC Batch ID: EP-0780-M
Client: Bennett&O'Reilly Sampled: 10-22-99
Container: 250ml-Glass Received: 10-25-99
Preservation: Cool Extracted: 10-26-99
' Matrix: Soil Analyzed: 10-28-99
%Moisture: 4 Dilution Factor: Aliphatic:1 Aromatic:1
EPH Ranges " _ 4 s s ,Concentratton w ram?, Units' Reporting limit
n-C9 to n-C18 Aliphatic Hydrocarbons BRL mg/Kg 30
n-C19 to n-C36 Aliphatic Hydrocarbons BRL mg/Kg 30
n-C11 to n-C22 Aromatic Hydrocarbons BRL mg/Kg 30
Unadjusted n-C11 to n-C22 Aromatic Hydrocarbons t BRL I mg/Kg I30
4 t QC,SUrrogate?COmpoUnds
QC llfllltSz.
a
Fractionation: 2-Fluorobiphenyl 81 % 40- 140%
' 2-Bromonaphthalene 82 % 40-140%
Extraction: Chloro-octadecane 68 % 40-140% I
ortho-Terphenyl�p 77 % 40-140 %
catona
a.:. .
1. Were all QA/QC procedures required by the method followed? Yes~
2. Were all performance/acceptance standards for the required QA/QC procedures achieved? Yes
3. Were any significant modifications made to the method,as specified in Section 11.3.1.1? Yes
' Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative
and project quality control report. Release of this data is authorized by the accompanying signed project cover letter.
The accompanying cover letter,project narrative and quality control report are considered part of this data report.
Method Reference: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998). Results are calculated
' on a dry weight basis. Method modified by use of microwave accelerated solvent extraction technique.
Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest
concentration that can be reliably quantified under routine laboratory operating conditions.
Reporting limits are adjusted for sample dilution,percent moisture and sample size.
' t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting it
that range.
0 n-C11 to n-C22 Aromatic Hydrocarbons range data excludes the method target analyte concentrations.
Groundwater Analytical, Inc., P.O. Box 1200 228 Main Street Buzzards Bay,Y, MA 02532
GROUNDWATER
ANALYTICAL
ASTM Method D3328-90 (Modified)
Hydrocarbon Fingerprinting by GC/FID
Field ID: HB-2:2-8' Laboratory ID: 29624-06
Project: George/13099-2511 QC Batch ID: HF-1231-M
Client: Bennett&O'Reilly Sampled: 10-22-99
Container: 210ml Glass Received: 10-25-99
Preservation: Cool Extracted: 10-28-99
Matrix: Soil Analyzed: 10-29-99
%Moisture: 18 Dilution Factor: 1
Qualitative Idiniffic-atio"n"
Z-z
This sample has GC/FID characteristics that are similar to:
1. Petroleum products in the Lubricating Oil (n-C1 8 to n-C36) range.
In Fil
Co
irti g1i it'
A
Total Petroleum Hydrocarbons 590 mg/Kg 71
ecovery QC'Lin Y]
e Conripoiiijd:. R ' i
ifts
9c,$.
ortho-Terphenyl 84 % 60-141_ %
Method Reference: Comparison of Waterborne Petroleum Oils by Gas Chromatography,Volume 11.02,Water,American
Society for Testing and Materials(1990). Analytical protocol modified by use of an internal standard.
Results are quantified on the basis of 5a—androstane. Sample preparation protocol modified by use
of microwave accelerated solvent extraction. Results are reported on a dry weight basis.
Report Notations: BRL Indicates concentration, if any, is below reporting limit for analyte. Reporting limit is the lowest
concentration that can be reliably quantified under routine laboratory operating conditions.
Reporting limits are adjusted for sample dilution and sample size.
Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532
GR OUNDWATER
ANALYTICAL ASTM METHOD D3328-90(Modified)
Hydrocarbon Fingerprinting (GC/FID)
Lab ID: 29624-06 HYDROCARBONS LABORATORY
1
1 '
5 10 15 20 25 30 35 40 45 50
Retention time (minutes)
GROUNDWATER
ANALYTICAL
' Trace Metals by ICP-AES and CVAA
Field ID: HB-2:2-8' Laboratory ID: 29624-02
Project: George/13099-2511 Sampled: 10-22-99
' Client: Bennett&O'Reilly Received: 10-25-99
Container: 250mL Glass % Solids 83
Preservation: Cool
' Matrix: Soil .
r 4, Reportng
CAS Number t h 3 Analyte Concentration y Umts Analyzed QC Batch Method'
7440-38-2 Arsenic,Total 3.0 mg/Kg 1.2 10-27-99 MM-0858-S 601013
' 7440-39-3 Barium,Total 90 mg/Kg I 24 10-27-99 MM-0858-S 60106
7440-43-9 Cadmium,Total 3.9 mg/Kg 0.60 10-27-99 MM-0858-S 6010B
' 7440-47-3 Chromium,Total 11 mg/Kg 1.2 10-27-99 MM-0858-S 601013
7439-92-1 Lead,Total 920 mg/Kg 12 10-27-99 MM-0858-S 6010E
7439-97-6 Mercury,Total 0.79 mg/Kg 0.068 10-27-99 MP-0669-S 7471A
' 778249-2 Selenium,Total BRL mg/Kg 0.60 10-27-99 MM-0858-S 60106 i
7440-224 Silver,Total BRL mg/Kg 6.0 10-27-99 MM-0858-S 601013
' Method Reference: Test Methods for Evaluating Solid Waste, US EPA,SW-846,Third Edition, Update III(1996).
Kesuits are reported on a dry weignt basis.
Report Notations: BRL Indicates concentration, if any, is below reporting limit for analyte. Reporting limit is the lowest
Concentration[nat can be reliably quantltled under routine laboratory Operating Conditions.
' Keporting limits are adjusted for sample duution and sample size.
' Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532
GROUNDWATER
' ANALYTICAL
Project Narrative
Project: George/13099-2511 Lab ID: 29624
Client: Bennett &O'Reilly Received: 10-25-99
A. Physical;Condition of Samples)
This project was received by the laboratory in satisfactory condition. The sample(s) were received
undamaged in appropriate containers with the correct preservation.
r , B. Project Documentation,
This project was accompanied by satisfactory Chain of Custody documentation, with the following
' amendment(s) or correction(s):
1. Sample 29624-04 was reported as "HB-1.A:6-8"', per Dave Bennett, 11-01-99.
-- --
C. Analysis of Sample(s)
' No analytical anomalies or non-conformances were noted by the laboratory during the processing of these
sample(s). All data contained within this report are released without qualification.
i
1
Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532
GROUNDWATER Buz Main Street,P.O.Box 1200
Buzzards bay,MA02532 CHAIN-OF-CUSTODY RECORD
ANALYTICAL Telephone(508)759-4441 AND WORK ORDER N2 37592
FAX(508)759-4475
Project Name: Firm:
^ 'K��\• •-Q.7,1�_ fC �r �� ���, , TURNAROUND ANALYSIS REQUEST
V ❑STANDARD 00 Business Days) voWSas [r�i
rsirolaelas Pest/Ifero/PCSs Metals Petroleum momoe Her. General Chemistry Mitt,
Project Nu ber: Address: at a abl
J I I -Fo p All
I l� LL�yPRIORITY(5 Business Days) z a
�C_JI u`RUSH(RAN-
(Rush requires Rush Authorization Number) n n 3 �� ❑
Sampler Name: Ci /State/zip:
V n Q �� l/ _ 2L O I Please FAX YES O NO 3
I-I'>J/ t J41� �(�CJ J FAX Number: S e s
Project Manager: T lephone: BILLING gg
n F) o a o $ g
Purchase Order No.: GWA Reference No.:
a�(�iq z5 i I ti o g W o
INSTRUCTIONS:Use separate line for each container(except replicates). W 9 o s r
Sxx
ampling Matrix s 3 = e °
TYPe Contalner(s) Preservation Filtered o e n n ❑ ❑ n n ❑ e _ ❑ °
e Jt E $ -
SAMPLE
i 7a w FCATON ( ' 9 9 e qLABORATORY
z S a s CiE a 9 ;e
NUMBERlYIa a Uef (Lab On '"IDE
u30 - ; '2 A Sga a
NTI
Wn $❑ _# - ❑ ❑ 12
❑ s 8s _
- - _
j 1
lyl
REMARKS/SPECIAL INSTRUCTIONS DATA QUALITY OBJECTIVES CHAIN-OF-CUSTODY RECORD
Regulatory Program Project Specific OC NOTE:All samples submitted subject to Standard Terms and Conditions on reverse hereof.
❑Safe Drinking Water Act Temperature:
Receipt Many regulatory programs and EPA methods require project Relinquished b Time ampler: Date me Received b .
❑MA DEP Form specific OC.Project specific OC includes Sample Duplicates, r Y' p mperature:
❑NPDES/Clean Water Act Matrix Spikes,and/or Matrix Spike Duplicates.Laboratory OC is 4
Specify State: not project specific unless prearranged.Project specific OC
❑RCRA/Haz.Waste Char. samples are charged on a per sample basis.For water samples, a inqul he b a e Time Receiy d byyy Shipping/Airbill
�MA MCP(310 CMR 40) each MS,MSD and Sample Duplicate requires an additional Number:
Reponable Concentrations- sample aliquot.
ElRCGW-1 RCS-1 Project Specific OC Required selection of OC Sample elin ishe y: to Time Received by boratory: ' Custody Seal/
❑RCGW-2 O RCS-2 Sample Duplicate i Selected by laboratory �V1 /U` Cooler Serial
❑MA Dredge Disposal - �Y/J N mber:
NH❑RI CT El ME Matrix Spike _7 Please use sample: Method hipment GWA Courier❑Expres jail ❑Federal Expres -
Specify Category: :Matrix Spike Duplicate - __
❑UPS ❑Hand ❑
GROUNDWATER
' ANALYTICAL
' Quality Assurance/Quality Control
r A Program Overview-
raw
Groundwater Analytical conducts an active Quality Assurance program to ensure the production of high
' quality, valid data. This program closely follows the guidance provided by Interim Guidelines and
Specifications for Preparing Quality Assurance Project Plans, US EPA QAMS-005/80 (1980), and Test
Methods for Evaluating Solid Waste, US EPA, SW-846, Update III (1996).
' Quality Control protocols include written Standard Operating Procedures (SOPS) developed for each
analytical method. SOPs are derived from US EPA methodologies and other established references.
Standards are prepared from commercially obtained reference materials of certified purity, and documented
for traceability.
Quality Assessment protocols for most organic analyses include a minimum of one laboratory control sample,
one method blank, one matrix spike sample, and one sample duplicate for each sample preparation batch.
' All samples, standards, blanks, laboratory control samples, matrix spikes and sample duplicates are spiked
with internal standards and surrogate compounds. All instrument sequences begin with an initial calibration
verification standard and a blank; and excepting GC/MS sequences, all sequences close with a continuing
calibration standard. GUMS systems are tuned to appropriate ion abundance criteria daily, or for each 12
' hour operating period, whichever is more frequent.
Quality Assessment protocols for most inorganic analyses include a minimum of one laboratory control
' sample, one method blank, one matrix spike sample, and one sample duplicate for each sample preparation
batch. Standard curves are derived from one reagent blank and four concentration levels. Curve validity is
verified by standard recoveries within plus or minus ten percent of the curve.
B. Definitions
}
Batches are used as the basic unit for Quality Assessment. A Batch is defined as twenty or fewer samples of
the same matrix which are prepared together for the same analysis, using the same lots of reagents and the
same techniques or manipulations, all within the same continuum of time, up to but not exceeding 24 hours.
' Laboratory Control Samples are used to assess the accuracy of the analytical method. A Laboratory Control
Sample consists of reagent water or sodium sulfate spiked with a group of target analytes representative of the
method analytes. Accuracy is defined as the degree of agreement of the measured value with the true or
' expected value. Percent Recoveries for the Laboratory Control Samples are calculated to assess accuracy.
Method Blanks are used to assess the level of contamination present in the analytical system. Method Blanks
consist of reagent water or an aliquot of sodium sulfate. Method Blanks are taken through all the appropriate
' steps of an analytical method. Sample data reported is not corrected for blank contamination.
Surrogate Compounds are used to assess the effectiveness of an analytical method in dealing with each
sample matrix. Surrogate Compounds are organic compounds which are similar to the target analytes of
' interest in chemical behavior, but which are not normally found in environmental samples. Percent
Recoveries are calculated for each Surrogate Compound.
' Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532
GROUNDWATER
ANALYTICAL
Quality Control Report
Laboratory Control Sample
Category: EPA Method 8260B
QC Batch ID: VM4-1185-SL
Matrix: Soil
Units: ug/Kg
' AS Number ;; Analyte„ .e k e ' Spiked ~ `' Measured' ;,w Recovery ;. QC Limits ,
75-354 1,1-Dichloroethene 50 53 107% 70-130%
71-43-2 Benzene 50 48 96% 70-130
' 79-01-6 Trichloroethene 50 1 47 94% 70-130 %
108-88-3 Toluene 50 42 83 % 70- 130 %
108-90-7 Chlorobenzene 50 48 96% 1 70- 130%
QC`SurrogateCom'pounds ,,.. ,; Recovery„„ �s QCil�mtts„
Dibromofluoromethane 107 % 80- 120%
1,2-Dichloroethane-d4 105 % 80-120%
' Toluene-d8 86 % 81 -117%
4-Bromofluorobenzene 105 % 74- 121 % j
Method Reference: Test Methods for Evaluating Solid Waste,US EPA,SW-846,Third Edition, Update III(1996).
1 Report Notations: All calculations performed prior to rounding. Quality Control Limits are defined by the methodology,
or alternatively based upon the historical average recovery plus or minus three standard deviation units.
' Groundwater Analytical, Inc. P.O. Box 1200 228 Main Street Buzzards Bay,y, MA 02532
GROUNDWATER
' ANALYTICAL
Quality Control Report
Method Blank
' Category: EPA Method 8260B
QC Batch ID: VM4-1185-SB
Matrix. Soil
Page: 1 of 2
' ,CAS.Number Anal e", � ,
yt .Concentration, _ Units 'r: Reporting liiriif
75-71-8 Dichlorodifluoromethane BRL ug/Kg 10
74-87-3 Chloromethane BRL ug/Kg 10
' 75-01-4 Vinyl Chloride BRL ug/Kg 10
74-83-9 Bromomethane BRL ug/Kg 10
75-00-3 Chloroethane BRL ug/Kg 10
' 75-69-4 Trichlorofluoromethane BRL ug/Kg 10
60-29-7 Diethyl Ether BRL ug/Kg 10
75-354 1,1-Dichloroethene BRL ug/Kg 5
67-64-1 Acetone BRL ug/Kg 50
75-15-0 ___� Carbon Disulfide _ _ ,_ BRL _ _ _ ug/Kg 50
75-09-2 Methylene Chloride BRL ug/Kg 10
156-60-5 trans-1,2-Dichloroethene BRL ug/Kg 5
1634-04-4 Methyl tert-butyl Ether(MTBE) BRL ug/Kg 5
' 75-34-3 1,1-Dichloroethane BRL ug/Kg 5
590-20-7 2,2-Dichloropropane BRL ug/Kg 5
156-59-2 cis-1,2-Dichloroethene BRL ug/Kg 5
' 78-93-3 2-Butanone(MEK) BRL I ug/Kg 50
74-97-5 Bromochloromethane BRL ug/Kg 5
109-99-9 Tetrahydrofuran(THF) BRL ug/Kg 50
' 67-66-3 ° Chloroform BRL — ug/Kg 5
71-55-6 1,1,1-Trichloroethane BRL ug/Kg 5
56-23-5 Carbon Tetrachloride BRL ug/Kg 5
563-58-6 1,1-Dichloropropene BRL ug/Kg 5
' 71-43-2 Benzene BRL ug/Kg 5
107-06-2 1,2-Dichloroethane BRL ug/Kg 5
79-01-6 Trichloroethene BRL ug/Kg 5
' 78-87-5 1,2-Dichloropropane BRL ug/Kg 5
74-95-3 Dibromomethane BRL ug/Kg 5
75-27-4 Bromodichloromethane BRL ug/Kg 5
10061-01-5 cis-1,3-Dichloropropene BRL ug/Kg 5
' 108-10-1 4-Methyl-2-Pentanone(MIBK) BRL ug/Kg 50
108-88-3 Toluene BRL ug/Kg 5
10061-02-6 trans-1,3-Dichloropropene BRL ug/Kg 5
' 79-00-5 1,1,2-Trichloroethane BRL ug/Kg 5
127-184 Tetrachloroethene BRL ug/Kg 5
142-28-9 1,3-Dichloropropane BRL ug/Kg 5
591-78-6 2-Hexanone BRL ug/Kg 50
124-48-1 Dibromochloromethane BRL ug/Kg 5
106-93-4 1,2-Dibromoethane(EDB) BRL ug/Kg 5
108-90-7 Chlorobenzene BRL ug/Kg 5
' 630-20-6 1,1,1,2-Tetrachloroethane BRL ug/Kg 5
100-41-4 Ethylbenzene BRL ug/Kg 5
Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532
GROUNDWATER
' ANALYTICAL
' Quality Control Report
Method Blank
' Category: EPA Method 8260B
QC Batch ID: VM4-1185-SB
Matrix: Soil
Page: 2 of 2
' - GAS;NumberAnalyte Concentration :: Units„, ;Report,og"limit
108-38-3/106-42-3 meta-Xylene and para-Xylene BRL ug/Kg 5
95-47-6 ortho-Xylene BRL ug/Kg 5
100-42-5 Styrene BRL ug/Kg 5
75-25-2 Bromoform BRL ug/Kg 5
98-82-8 I sop ropylbenzene BRL ug/Kg 5
108-86-1 Bromobenzene BRL ug/Kg 5
79-34-5 1,1,2,2-Tetrachloroethane _ BRL _—_ ug/Kg j 5
96-18-4 7 1,2,3-Trichloropropane BRL ug/Kg 5
103-65-1 n-Propyl benzene BRL ug/Kg 5
' 95-49-8 2-Chlorotoluene 1 ug/Kg 5
r - --T-- g—
108-67-8 I 1,3,5-Tri methyl benzene BRL � ug/K ----5--
10643-4 4-Chlorotoluene BRL _ _—j ug/Kg 5
98-06-6 ; tert-Butylbenzene BRL r ug/Kg 5
' 95-63-6 1,2,4-Tri methyl benzene BRL ug/Kg 5
135-98-8 sec-B utyl benzene BRL _ug/Kg 5
541-73-1 1,3-Dichlorobenzene BRL ug/Kg 5
' 99-87-6 4-Isopropyltoluene BRL ug/Kg �_ 5
i 106-46-7 1,4-Dichlorobenzene BRL _ug/Kg 5
I
95-50-1 1,2-Dichlorobenzene BRL ug/Kg 5
104-51-8 n-Butylbenzene _ BRL ug/Kg
96-12-8 1,2-Dibromo-3-chloropropane BRL ug/Kg T 5
120-82-1 1,2,4-Trichlorobenzene BRL ug/Kg— 5
87-68-3 Hexachlorobutadiene BRL ug/Kg 5
' 91-20-3 Naphthalene BRL ug/Kg 5
87-61-6 1,2,3-Trichlorobenzene BRL ug/Kg 5
'it's
urro ate Com unds "''
- g Po ?, , .� ", Recove`ry',,- 4. '� "tr a.:,�QC Limits
Dibromofluoromethane 109 % 80- 120%
1,2-Dichloroethane-d4 110 % 80- 120 %
Toluene-d8 91 % 81 -117%
' 4-Bromofluorobenzene 106 % 74- 121 %
Method Reference: Test Methods for Evaluating Solid Waste, US EPA,SW-846,Third Edition, Update III(1996). Analyte list
as specified in Tables 6 and 7 of the method,and additional analytes as specified by MA DEP Method 1
Standards(310 C.M.R.40.0973)and recommended by NH DES for initial waste site investigations,
' effective 12/1/97. Results are reported on a dry weight basis.
Report Notations: BRL Indicates concentration, if any, is below reporting limit for analyte. Reporting limit is the lowest
concentration that can be reliably quantified under routine laboratory operating conditions.
Reporting limits are adjusted for sample dilution,percent moisture and sample size.
' Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532
GROUNDWATER
' ANALYTICAL
' Quality Control Report
Laboratory Control Sample
' Category: MA DEP EPH Method
QC Batch ID: EP-0780-M
Matrix: Soil
Units: mg/Kg
' ;'CAS Number . ` Analyte; Spiked Measured Recovery QC Ltnits
111-842 n-Nonane(C9) 5.0 2.4 48% 40-140 %°
629-594 n-Tetradecane(C14) 5.0 3.5 71 % 40- 140%
' 629-92-5 n-Nonadecane(C19) 5.0 3.9 77% 40- 140%
112-95-8 n-Eicosane(C20) 5.0 4.2 83% 40- 140
630-024 n-Octacosane(C28) 5.0 4.0 79% 40-140%
' 91-20-3 Naphthalene 5.0 2.9 58% 40-140%
83-32-9 Acenaphthene 5.0 3.8 77% 40-140%
120-12-7 Anthracene 5.0 4.1 82 % 40-140%
129-00-0 Pyrene 5.0 4.1 81 % 40-140%
' 218-01 9 Chrysene 5.0 4 5 90% 40 140%
Surrogate Compounds Limits
Fractionation: 2-Fluorobiphenyl 75 % 40-140 %
' 2-Bromonaphthalene 47 % 40-140 %
Extraction: Chloro-octadecane 77 % 40-140 %
ortho-Terphenyl 76 % _ 40-140 %
' Method Reference: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998).
Report Notations: All calculations performed prior to rounding. Quality Control Limits are defined by the methodology,
or alternatively based upon the historical average recovery plus or minus three standard deviation units.
' Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street Buzzards Bay, MA 02532
GROUNDWATER
' ANALYTICAL
' Quality Control Report
Method Blank
' Category: MA DEP EPH Method
QC Batch ID: EP-0780-M
Matrix: Soil
n-C9 to n-C18 Aliphatic Hydrocarbons BRL mg/Kg 30 Y
n-C19 to n-C36 Aliphatic Hydrocarbons BRL mg/Kg 30
n-C11 to n-C22 Aromatic Hydrocarbons BRL mg/Kg 30
' Unadjusted n-C11 to n C22 Aromatic Hydrocarbons t BRL mg/Kg 30
�fAS Number Repo rting-L_
91-20 3 Naphthalene BRL mg/Kg 0.50
' 91-57-6 2-Methyl naphthalene 'BRL mg/Kg 0.50
85-01-8 Phenanthrene BRL mg/Kg 0.50
83-32-9 Acenaphthene BRL mg/Kg 0.50
' 208-96-8 Acenaphthylene BRL mg/Kg 0.50
86-73-7 Fluorene BRL mg/Kg 0.50
120-12-7 Anthracene BRL mg/Kg 0.50_�
206-44-0 Fluoranthene BRL mg/Kg 0.50
129-00-0 Pyrene BRL mg/Kg 0.50
56-55-3 Benzo[a]anthracene BRL mg/Kg 0.50
218-01-9 Chrysene BRL mg/Kg 0.50
' 205-99-2 _ Benzo[b]fluoranthene BRL mg/Kg 0.50
207-08-9 Benzo[k]fluoranthene BRL mg/Kg 0.50
50-32-8 Benzo[a]pyrene BRL mg/Kg 0.50
' 193-39-5 Indeno[1,2,3-c,d]pyrene BRL mg/Kg 0.50
53-70-3 Dibenzo[a,h]anthracene BRL mg/Kg 0.50
191-24-2 Benzo[g,h,i]perylene BRL mg/Kg 0.50
QC:Suirogalle{Compounds" , ' :.,"Recovery
Fractionation. 2-Fluorobiphenyl 82 % 40-140%
2-Bromonaphthalene 73 % 40-140%
' Extraction: Chloro-octadecane 74 % 40-140%
ortho-Terphenyl 85 % 40-140%
Method Reference: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP.(1998).
Report Notations: BRL Indicates concentration, if any, is below reporting limit for analyte. Reporting limit is the lowest
concentration that can be reliably quantified under routine laboratory operating conditions.
Reporting limits are adjusted for sample dilution,percent moisture and sample size.
t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting it
' that range.
0 n-C11 to n-C22 Aromatic Hydrocarbons range data excludes the method target analyte concentrations.
' Groundwater Analytical, Inc., P.O. Box 1200 228 Main Street Buzzards Ba MA 02532
Yt Y,
GROUNDWATER
' ANALYTICAL
' Quality Control Report
Laboratory Control Sample
' Category: ASTM Method D3328-90(Modified)
QC Batch I D: H F-1231-M
Matrix: Soil
Units: mg/Kg
7 `
Analyte Spiked 4 easured RecoveryQC Limas
Fuel Oil No. 2 130 120 93 % 60-140%
16
' 't .QC Surrogate Compoun0474Recovery �QC Ltm�ts� `
z y.
ortho-Terphenyl 88 % 60-140
' Method Reference: Comparison of Waterborne Petroleum Oils by Gas Chromatography,Volume 11.02,Water,American
Society for Testing and Materials(1990). Analytical protocol modified by use of an internal standard.
Results are quantified on the basis of 5a—androstane. Sample preparation protocol modified by use
of microwave accelerated solvent extraction. Results are reported on a dry weight basis.
' Report Notations: All calculations performed prior to rounding. Quality Control Limits are defined by the methodology,
or alternatively based upon the historical average recovery plus or minus three standard deviation units.
1
' Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532
f
GROUNDWATER
ANALYTICAL
' Quality Control Report
Method Blank
Category: ASTM Method D3328-90(Modified)
QC Batch ID: HF-1231-M
Matrix: Soil
<kk
m •. ,�.t ;.'` �'ss.n'`�kda%v "R�, .r w"^ ��a +ae .aa'.; `+rt^. d c ""l Lk e � eporting .
' Anal ; Concentration , Units
Total Petroleum Hydrocarbons y BRL mg/Kg 60
Y ✓. ,fry, 1 ze i' Y' f
QC SurrogateCompound
x: �, Recovery z QC?Um�ts "
», �: .� ,
, .,,
ortho-Terphenyl 90 % 60 140
Method Reference: Comparison of Waterbome Petroleum Oils by Gas Chromatography,Volume 11.02,Water,American
Society for Testing and Materials(1990). Analytical protocol modified by use of an internal standard.
Results are quantified on the basis of 5a—androstane. Sample preparation protocol modified by use
of microwave accelerated solvent extraction. Results are reported on a dry weight basis.
on a dry weight basis.
' Report Notations: BRL Indicates concentration,if any, is below reporting limit for analyte. Reporting limit is the lowest
concentration that can be reliably quantified under routine laboratory operating conditions.
Reporting limits are adjusted for sample dilution and sample size.
1
Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532
GROUNDWATER
' ANALYTICAL
QUALITY ASSURANCE
' Laboratory Control Sample Recovery
Category: Trace Metals
Matrix: Soil
Units: mg/Kg
' Laboratory Control Sample
SPIKE SPIKED PERCENT QC
ANALYTE BATCH ID ADDED RESULT RECOVERY LIMITS
Barium MM-0858-SLI 100 90 90 % 75-12
Cadmium MM-0858-SLI 100 92 92 % 75-125
' Chromium MM-0858-SLI 100 91 91 % 75-125
Lead MM-0858-SLI 100 90 90 % 75-125
Silver MM-0858-SLI 100 85 85 % 75-125
' Arsenic MM-0858-SLF 5.0 4.5 89 % 75-125
Selenium MM-0858-SLF 5.0 4.3 86 % 75-125
' Mercury MP-0669-SL 0.250 0.220 87 % 75-125
' Quality Control Limits are defined by the methodology, or alternatively based upon the historical average
recovery plus or minus three standard deviation units.
GROUNDWATER
' ANALYTICAL
QUALITY ASSURANCE
' Method Blank
' Category: Trace Metals
Matrix: Soil
' REPORTING EPA
PARAMETER CONCENTRATION LIMIT BATCH ID METHOD
(mg/Kg) (mg/Kg)
Barium BRL 20 MM-0858-SB 6010
Cadmium BRL 0.50 MM-0858-SB 6010
Chromium BRL 1.0 MM-0858-SB 6010
' Lead BRL 10 MM-0858-SB 6010
Silver BRL 5.0 MM-0858-SB 6010
Arsenic BRL 1.0 MM-0858-SB 6010
' Selenium BRL 0.50 MM-0858-SB 6010
Mercury BRL 0.050 MP-0669-SB 7471
t
' BRL = Below Reporting Limit. Method References: Test Methods for Evaluating Solid Waste, US EPA SW-846,
Third Edition (1986). Graphite Furnace analyses performed with Zeeman background correction and Lvov
platform technique.
1
GROUNDWATER
t ANALYTICAL
' Certifications and Approvals
CONNECTICUT, Department of Health Services, �PH-0586
Potable Water,Wastewater/Trade Waste,Sewage/Effluent,and Soil
pH,Conductivity,Acidity,Alkalinity,Hardness,Chloride,Fluoride,Ammonia,Kjeldahl Nitrogen,Nitrate,Nitrite,Orthophosphate,Total Dissolved
' Solids,Cyanide,Aluminum,Antimony,Arsenic,Barium,Beryllium,Cadmium,Total Chromium,Hexavalent Chromium,Cobalt,Copper,Iron,Lead,
Magnesium,Manganese,Mercury,Molybdenum,Nickel,Potassium,Selenium,Silver,Sodium,Thallium,Tin,Titanium,Vanadium,Zinc,Purgeable
Halocarbons,Purgeable Aromatics,Pesticides,PCBs,PCBs in Oil,Ethylene Dibromide,Phenols,Oil and Grease.
MAINS,=Department of Human Services, MA103" _
Drinking Water
Reciprocal certification in accordance with Massachusetts certification for drinking water analytes.
' Waste Water
Reciprocal certification in accordance with Massachusetts certification for waste water analytes.
4 9
' MASSACHUSETTS,'Department of Environmental Protectwn, M MA 103= "
Potable Water
Antimony,Arsenic,Barium,Beryllium,Cadmium,Chromium,Copper,Lead,Mercury,Nickel,Selenium,Thallium,Nitrate-N,Nitrite-N,Fluoride,
' Sodium,Sulfate,Cyanide,Turbidity,Residual Free Chlorine,Calcium,Total Alkalinity,Total Dissolved Solids,pH,Trihalomethanes,Volatile Organic
Compounds,1,2-Dibromoethane,1,2-Dibromo-3-chloropropane,Total Coliform,Fecal Coliform,Heterotrophic Plate Count,E-Coli
Non-Potable Water
Aluminum,Antimony,Arsenic,Beryllium,Cadmium,Chromium,Cobalt,Copper,Iron,Lead,Manganese,Mercury,Molybdenum,Nickel,Selenium,
' Silver,Strontium,Thallium,Titanium,Vanadium,Zinc,pH,Specific Conductance,Total Dissolved Solids,Total Hardness,Calcium,Magnesium,
Sodium,Potassium,Total Alkalinity,Chloride,Fluoride,Sulfate,Ammonia-N,Nitrate-N,Kjeldahl-N,Orthophosphate,Total Phosphorus,Chemical
Oxygen Demand,Biochemical Oxygen Demand,Total Cyanide,Non-Filterable Residue,Total Residual Chlorine,Oil and Grease,Total Phenolics,
Volatile Halocarbons,Volatile Aromatics,Chlordane,Aldrin,Dieldrin,DOD,DDE,DDT,Heptachlor,Heptachlor Epoxide,Polychlorinated
' Biphenyls(water),Polychlorinated Biphenyls(oil).
MICHIGAN,-Departmerit of EnvAronmental.Quality x`
' Drinking Water
Trihalomethanes,Regulated and Unregulated Volatile Organic Compounds by EPA Method 524.2;1,2-Dibromoethane,1,2-Dibromo-3-
chloropropane by EPA Method 504.1
1 NEW HAMPSHIRE Departmentfof EnM�ronmental Services, 202798 �
Drinking Water
Metals by Graphite Furnace,Metals by ICP,Mercury,Nitrite-N,Orthophosphate,Residual free Chlorine,Turbidity,Total Filterable Residue,Calcium
' Hardness,pH,Alkalinity,Sodium,Sulfate,Total Cyanide,Insecticides,Herbicides,Base/Neutrals,Trihalomethanes,Volatile Organics,Vinyl
Chloride,DBCP,EDB,Nitrate-N.
Wastewater
' Metals by Graphite Furnace,Metals by ICP,Mercury,pH,Specific Conductivity,TDS,Total Hardness,Calcium,Magnesium,Sodium,Potassium,
Total Alkalinity,Chloride,Fluoride,Sulfate,Ammonia-N,Nitrate-N,Orthophosphate,TKN,Total Phosphorus,COD,BOD,Non-Filterable Residue,
Oil&Grease,Total Phenolics,Total Residual Chlorine,PCBs in Water,PCBs in Oil,Pesticides,Volatile Organics,Total Cyanide.
;RHODEISLAND;Department of Health, 54 J1 x ps
Surface Water,Air,Wastewater, Potable Water,Sewage
Chemistry: Organic and Inorganic
Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532
GROUNDWATER Groundwater Analytical, Inc.
P.O.Box 1200
ANALYTICAL 228 Main Street
Buzzards Bay,MA 02532
Telephone(508)759-4441
FAX(508)759-4475
November 4, 1999
Mr. David Bennett
Bennett & O'Reilly, Inc.
IP.O. Box 1667
Brewster, MA 02631
Project: George/13099-2511
Lab I D: 29624
Sampled: 10-22-99
Dear David:
I Enclosed is the Metals Analysis performed for the above referenced project. This project was
processed for Rush turnaround.
This letter authorizes the release of the analytical results, and should be considered a part of this
report. This report contains a project narrative indicating project changes and non-conformances, a
brief description of the Quality Assurance/Quality Control procedures employed by our laboratory,
and a statement of our state certifications.
I attest under the pains and penalties of perjury that, based upon my inquiry of those individuals
immediately responsible for obtaining the information, the material contained in this report is, to
the best of my knowledge and belief, accurate and complete.
' Should you have any questions concerning this report, please do not hesitate to contact me.
Sincerely,
' Jonathan R. Sanford
President
' J RS/myr
Enclosures
GROUNDWATER
' ANALYTICAL
' Trace Metals by ICP-AES.
Field ID: HB-2:8-10 Laboratory ID: 29624-05
Project: George/13099-2511 Sampled: 10-22-99
Client: Bennett&O'Reilly Received: 10-25-99
Container: 250 mL Glass % Solids 96
Preservation: Cool
' Matrix: Soil ry
4eportmg f °�
CAS Number Analyteg , Concentration Units x AnalyzedF d QCBatch Method
', _ �k^z,,. ,e ,.,c't./ 'I *:.,a--._.-'°a ?#;r n, Irlllt, {3'
7439-92-1 Lead,Total 18 mg/Kg 10 11-03-99 MM-0861-S 6010E
' Method Reference: Test Methods for Evaluating Solid Waste, US EPA,SW-846,Third Edition, Update III (1996).
Kesuits are reported on a dry weight basis.
' Report Notations: BRL Indicates concentration, if'any, is below reporting limit for analyte. Reporting limit is the lowest
concentration that can be reliably quantmeo under routine laboratory operating conortions.
Keportmg limits are aalusteo for sample cioution and sample size.
1
i
Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532
GROUNDWATER
' ANALYTICAL
' Project Narrative
Project: George/BO99-2511 Lab ID: 29624
' Client: Bennett &O'Reilly Received: 10-25-99
Ai Pliysrcal Conditiotn of Samples)
This project was received by the laboratory in satisfactory condition. The sample(s) were received
undamaged in appropriate containers with the correct preservation.
L rvB Protect Documentation •' '
This project was accompanied by satisfactory Chain of Custody documentation, with the following
' amendment(s) or correction(s):
1. . Project 29624 was processed for Rush Turnaround. The project was given a due date of 11-04-99,
per Dave Bennett, 11-02-99.
' 2. Sample 29624-05 was analyzed for Total Lead, per Dave Bennett, 11-02-99.
' C Analysis of Sarriple(s)
No analytical anomalies or non-conformances were noted by the laboratory during the processing of these
' sample(s). All data contained within this report are released without qualification.
�I
' Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532
07 �1�JNL0 228 Meet,P.".99111n 200
ANALYTICAL Buzzards Bay.MA 02532 CHAIN-OF-CUSTODY RECORD
; Telephone(508)759.4441 AND WORK ORDER
FAX(508)759.4475 N2 37592
Pr Name: Firm: _
�1�� " /\r ( TURNAROUND
`tu��y � v 1C� ANALYSIS REQUEST
Project Nu bar: ❑STANDARD(10 Business Days) WWI. aerni.mealee PeeuNemmces I fn PmWeoo mourooe Nu. Genml Lliemmry
Address: r r PH Wfei
�(?/ — PRIORITY(5 Business Days) TPH
RUSH(RAN-
Sampler Name: Cit /Stat@/Zlp: (Rush requires Rush Aulhorizatron Number)MS7
n j ,' �Z� I Please FAX YES ❑NO
oFAX y Number: t `3e -
Project Mana er: Telephone: W $
BILLING
Purchase Order No.: GWA Reference No.: & f
INSTRUCTIONS:Use separate line for each container( ���j'- ZS� ' W e o i _except replicates). o 5 i
Sampling `_ ., a a $ -
Matrix TYPe Container(s) 5 $ § $ 9 n $ g - ;a € u € 3
Preservation Ru.rea - -
SAMPLE 3 Y gg _ 'a 3
IDENTIFICATION ... i " d = LABORATORY - 9 8 8 a
w w = a a a a a n NUMBER
(Lab Use Only) g g 5 a
lil
IL 1 I,��-_�() _ Z_/ t - s" R _ �f C 5 9 $ a 9 9 s - _
to -
9PH ow
i
!0
EJTFTT
-11
TFTT
I
i
REMARKS/SPECIAL INS
TRUCTIONS I
DATA QUALITY OBJ
ECTIVES
ECTIVES
Project Specific OC CHAIN-OF-CUSTODY RECORD
Regulatory Program
Safe Drinking Water Act NOTE:All samples submitted subject to Standard Terms and Conditions on reverse nereot.
-MA DEP Form Many regulatory programs and EPA methods require project Relinquished b ampler: Date Time Received by: Receipt Tempera:;,ra
NPDES:Clean Water Act specific CC.Project specific OC includes Sample Duplicates.
Matrix Spikes.and pr Matrix Spike Duplicates.Laboratory OC is S 1 )
Specify State: not project speafic unless prearranged.Project specific OC
RCRA-Haz.Waste Char. samples are charged on a per sample basis.For water samples. etinqu ed b: ate Time Receiv d b Shl
�JMA MCP(310 CMR 401 each MS.MSD and Sample Duplicate requires an additional Y ppmo.Airbdl
/ Reportable Concentrations sample aliquot. / � J �, Number:
... RCGW.1 /ARCS-1 ',pied Specific OC Required Selection of OC Sample `_.:RCGW-2/-RCS-2 edn ishe y: to Time Received by boratory: Custody Seal
MA Dredge Disposal Sample Duplicate of
by laboratory w �/ /� /�/1/) /( •9 Cooler Serial
Matrix Spike Pleasa use sample: y ` l"""/// 1'' N mber:
pe RI CT ME _ Method VShipmem: GWA Courier Express Mail --Federal Expres Y/
Speedy Category: _ !Aatnx So�ke Duol�pte __ __ ✓
_UPS :'Hand
�, - oy 1 - vz
' GROUNDWATER
ANALYTICAL
' Quality Assurance/Quality Control
a res l� .'Program Overview,
Groundwater Analytical conducts an active Quality Assurance program to ensure the production of high
quality, valid data. This program closely follows the guidance provided by Interim Guidelines and
Specifications for Preparing Quality Assurance Project Plans, US EPA QAMS-005/80 (1980), and Test
Methods for Evaluating Solid Waste, US EPA, SW-846, Update III (1996).
Quality Control protocols include written Standard Operating Procedures (SOPS) developed for each
analytical method. SOPS are derived from US EPA methodologies and other established references.
Standards are prepared from commercially obtained reference materials of certified purity, and documented
' for traceability.
Quality Assessment protocols for most organic analyses include a minimum of one laboratory control sample,
one method blank, one matrix spike sample, and one sample duplicate for each sample preparation batch.
' All samples, standards, blanks, laboratory control samples; matrix spikes and sample duplicates are spiked
with internal standards and surrogate compounds. All instrument sequences begin with an initial calibration
verification standard and a blank; and excepting GUMS sequences, all sequences close with a continuing
calibration standard. GUMS systems are tuned to appropriate ion abundance criteria daily, or for each 12
hour operating period, whichever is more frequent.
Quality Assessment protocols for most inorganic analyses include a minimum of one laboratory control
' sample, one method blank, one matrix spike sample, and one sample duplicate for each sample preparation
batch. Standard curves are derived from one reagent blank and four concentration levels. Curve validity is
verified by standard recoveries within plus or minus ten percent of the curve.
,B Definitions
Batches are used as the basic unit for Quality Assessment. A Batch is defined as twenty or fewer samples of
the same matrix which are prepared together for the same analysis, using the same lots of reagents and the
same techniques or manipulations, all within the same continuum of time, up to but not exceeding 24 hours.
' Laboratory Control Samples are used to assess the accuracy of the analytical method. A Laboratory Control
Sample consists of reagent water or sodium sulfate spiked with a group of target analytes representative of the
method analytes. Accuracy is defined as the degree of agreement of the measured value with the true or
expected value. Percent Recoveries for the Laboratory Control Samples are calculated to assess accuracy.
Method Blanks are used to assess the level of contamination present in the analytical system. Method Blanks
consist of reagent water or an aliquot of sodium sulfate. Method Blanks are taken through all the appropriate
' steps of an analytical method. Sample data reported is not corrected for blank contamination.
Surrogate Compounds are used to assess the effectiveness of an analytical method in dealing with each
sample matrix. Surrogate Compounds are organic compounds which are similar to the target analytes of
interest in chemical behavior, but which are not normally found in environmental samples. Percent
Recoveries are calculated for each Surrogate Compound.
' Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532
GROUNDWATER
ANALYTICAL
Quality Control Report
Laboratory Control Sample
Category: Trace Metals
Matrix: Aqueous
CAS'Numbei Analyte Measured Recovery,4C Baick', nits Spiked red ecovery
r
U,
7439-92-1 Lead 60106 MM-0749-TL mg/L 1.00 1.06 106% 75-125 %
Method Reference: Test Methods for Evaluating Solid Waste, US EPA,SW-846,Third Edition, Update 111(1996).
Report Notations: All calculations performed prior to rounding. Quality Control Limits are defined by the methodology,
or alternatively based upon the historical average recovery plus or minus three standard deviation units.
Groundwater Analytical, Inc., P.O. Box 12001- 228 Main Street, Buzzards Bay, MA 02532
' GROUNDWATER
ANALYTICAL
1 Quality Control Report
Method Blank
1 Category: Trace Metals
Matrix: Aqueous
-CAS-Number Analyte Concentration' Uni Reporting Limit QC Batch ;Method "'
,
1 7439-92-1 Lead BRL �tss
0.1 MM-0749-TB 6010E
Method Reference: Test Methods for Evaluating Solid Waste,US EPA,SW-846,Third Edition, Update III (1996).
1 Report Notations: BRL Indicates concentration, if any, is below reporting limit for analyte. Reporting limit is the lowest
concentration that can be reliably quantified under routine laboratory operating conditions.
Reporting limits are adjusted for sample dilution and sample size.
1
1
1
1
i
i
1
1
1
1
1
1
' Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532
GROUNDWATER
' ANALYTICAL
Quality Control Report
Laboratory Control Sample
Category: EPA Method 8082
' QC Batch ID: PB-0934-M
Matrix: Soil
Units: ug/Kg
' CAS Number w r . < Anal"yte Spiked. Measured° Recovery " ._"QC;Limits- '.
11097-69-1 Aroclor 1254 ( 330 350 106% 60-140%
;QC-Surrogate'Compour d w' Recovery ` QC Cimits.
z>.Tetrachloro-m-xylene 81% 25-121
Decachlorobiphenyl 98% 28- 138
Metnoa Kererence: . i est Memoas ror tvaivanng z)ona waste, uzo trH,Jw-64b, I nlra taltion, upoare III (I yyb). Kesuits
' are caicwatea on a ary weignt basis.
Keport Notations: Hn caicwaaons perrormea prior to rounamg. tluanty uontroi Limits are aenneo oy the metn00016gy,
or aitemauveiy oasea upon the nistoncai average recovery plus or minus tnree stanaara aeviation units.
' Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532
GROUNDWATER
ANALYTICAL
' Quality Control Report
Method Blank
Category: EPA Method 8082
' QC Batch ID: PB-0934-M
Matrix: Soil
CAS'Nu'mber- Analyte Concentration` Units', Reporting,Limit
12674-11-2 Aroclor 1016 BRL ug/Kg 80
1 1 1 04-28-2 Aroclor 1221 BRL ug/Kg 80
1 1 1 41-1 6-5 Aroclor 1232 BRL ug/Kg 80
53469-21-9 Aroclor 1242 BRL ug/Kg 80
12672-29-6 Aroclor 1248 BRL L ug/Kg 80
1 1 09 7-69-1 Aroclor 1254 BRL I ug/Kg 80
11096-82-5 Aroclor 1260 BRL T ug/Kg 80
j QC Surrogate:Compound Recovery QC Limits'
Tetrachloro-m-xylene 94 % i 25-121
Decachlorobiphenyl ! 100 % 28-138 %
' Metnoa Keterence: lest Metnoas rot tvaivanng�)oiia waste, u�P trA,JVV-a4b, i nira taition, update m t 1 VVb). Anaiyte list
as Aroclor anaiytes tormeriy specitiea by trA metnoa MJUA. Kesuits are reported on a city weignt basis.
Keport Notations: bKL tnoicates concentration, it any, is beiow reporting limit tor anaiyre. Keporting limit is the lowest
concentration tnat can oe renamy quantities under routine iaboratory operating conaitions.
' Keportmg limits are aaiustea ror sample dilution,percent moisture ana sample size.
Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532
GROUNDWATER
' ANALYTICAL
' Certifications and Approvals
CONNECTICUT;Department of Health Services, PH 0586
.� .
�.4.
Potable Water,Wastewater/Trade Waste,Sewage/Effluent,and Soil
pH,Conductivity,Acidity,Alkalinity,Hardness,Chloride,Fluoride,Ammonia,Kjeldahl Nitrogen,Nitrate,Nitrite,Orthophosphate,Total Dissolved
Solids,Cyanide,Aluminum,Antimony,Arsenic,Barium,Beryllium,Cadmium,Total Chromium,Hexavalent Chromium,Cobalt,Copper,Iron,Lead,
' Magnesium,Manganese,Mercury,Molybdenum,Nickel,Potassium,Selenium,Silver,Sodium,Thallium,Tin,Titanium,Vanadium,Zinc,Purgeable
Halocarbons,Purgeable Aromatics,Pesticides,PCBs,PCBs in Oil,Ethylene Dibromide,Phenols,Oil and Grease.
MAINE, Department of Human-Services, MA103 f
�. _.. �=
Drinking Water
Reciprocal certification in accordance with Massachusetts certification for drinking water analytes.
' Waste Water
Reciprocal certification in accordance with Massachusetts certification for waste water analyzes.
MASSACHUSETTS, Department.iof°Environmental-Protection,M=MA 1'03 K
j.
Potable Water
Antimony,Arsenic,Barium,Beryllium,Cadmium,Chromium,Copper,Lead,Mercury,Nickel,Selenium,Thallium,Nitrate-N,Nitrite-N,Fluoride,
Sodium,Sulfate,Cyanide,Turbidity,Residual Free Chlorine,Calcium,Total Alkalinity,Total Dissolved Solids,pH,Trihalomethanes,Volatile Organic
Compounds,1,2-Dibromoethane,1,2-Dibromo-3-chloropropane,Total Coliform,Fecal Coliform,Heterotrophic Plate Count,E-Coli
Non-Potable Water
Aluminum,Antimony,Arsenic,Beryllium,Cadmium,Chromium,Cobalt,Copper,Iron,Lead,Manganese,Mercury,Molybdenum,Nickel,Selenium,
' Silver,Strontium,Thallium,Titanium,Vanadium,Zinc,pH,Specific Conductance,Total Dissolved Solids,Total Hardness,Calcium,Magnesium,
Sodium,Potassium,Total Alkalinity,Chloride,Fluoride,Sulfate,Ammonia-N,Nitrate-N,Kjeldahl-N,Orthophosphate,Total Phosphorus,Chemical
Oxygen Demand,Biochemical Oxygen Demand,Total Cyanide,Non-Filterable Residue,Total Residual Chlorine,Oil and Grease,Total Phenolics,
Volatile Halocarbons,Volatile Aromatics,Chlordane,Aldrin,Dieldrin,DDD,DDE,DDT,Heptachlor,Heptachlor Epoxide,Polychlorinated
Biphenyls(water),Polychlorinated Biphenyls(oil).
°:MICHIGAN,,'Department of Environmental Quality: �,�'" 7
Drinking Water
' Trihalomethanes,Regulated and Unregulated Volatile Organic Compounds by EPA Method 524.2;1,2-Dibromoethane,1,2-Dibromo-3-
chloropropane by EPA Method 504.1
;NEW HA11%IPSHIRE wDwait men t_of Environmental Services, 202798
Drinking Water
Metals by Graphite Furnace,Metals by ICP,Mercury,Nitrite-N,Orthophosphate,Residual Free Chlorine,Turbidity,Total Filterable Residue,Calcium
Hardness,pH,Alkalinity,Sodium,Sulfate,Total Cyanide,Insecticides,Herbicides,Base/Neutrals,Trihalomethanes,Volatile Organics,Vinyl
Chloride,DBCP,EDB,Nitrate-N.
Wastewater
Metals by Graphite Furnace,Metals by ICP,Mercury,pH,Specific Conductivity,TDS,Total Hardness,Calcium,Magnesium,Sodium,Potassium,
Total Alkalinity,Chloride,Fluoride,Sulfate,Ammonia-N,Nitrate-N,Orthophosphate,TKN,Total Phosphorus,COD,BOD,Non-Filterable Residue,
Oil&Grease,Total Phenolics,Total Residual Chlorine,PCBs in Water,PCBs in Oil,Pesticides,Volatile Organics,Total Cyanide.
RHO DE ISLAND, Departrnentof Health;54, is ,�
Surface Water,Air,Wastewater, Potable Water,Sewage
Chemistry: Organic and Inorganic
i
II
' Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532
RED.E lv`E D
I Groundwater Analytical,Inc.
GROUNDWATER
P.O.Box 1200
ANALYTICAL Buzzards
Main Street
Buzzards Bay,MA 02532
Telephone(508)759-4441
FAX(508)759-4475
' November 11, 1999
Mr. David Bennett
Bennett & O'Reilly, Inc.
' P.O. Box 1667
Brewster, MA 02631
' Project: George Panesis/13099-2511
Lab I D: 29857
Sampled: '10-22-99
' Dear Dave:
t Enclosed are the PCBs, TCLP Lead, Reactivity, Corrosivity and Ignitability Analyses performed for
the above referenced project. This project was processed for Priority One Week turnaround.
' This letter authorizes the release of the analytical results, and should be considered a part of this
report. This report contains a project narrative indicating project changes and non-conformances, a
brief description of the Quality Assurance/Quality Control procedures employed by our laboratory,
' and a statement of our state certifications.
I attest under the pains and penalties of perjury that, based upon my inquiry of those individuals
' immediately responsible for obtaining the information, the material contained in this report is, to
the best of my knowledge and belief, accurate and complete.
Should you have any questions concerning this report, please do not hesitate to contact me.
Sincerely,
Jonathan R. Sanford
President
JRS/myr
Enclosures
GROUNDWATER
' ANALYTICAL
' EPA Method 8082
Polychlorinated Biphenyls (PCBs) by GGECD
Field ID: HB-2:2-8' Laboratory ID: 29857-01
' Project: George Panesis/B099-2511 QC Batch ID: PB-0934-M Client: Bennett&O Reilly, Inc. Sampled: 10-22-99
Container: 250mL Glass Received: 10-25-99
Preservation: Cool Extracted: 11-05-99
' Matrix: Soil Analyzed: 11-10-99
% Moisture: 18 Dilution Factor: 5
CAS,Number - `Analyte ; :,Concentration. Units ,s Reporting.limif
1 2674-1 1-2 Aroclor 1016 BRL ( ug/Kg 540
1 1 1 04-28-2 Aroclor 1221 BRL ug/Kg 540
1 1 1 41-1 6-5 Aroclor 1232 BRL ug/Kg 540
' 53469-21-9 Aroclor 1242 BRL ug/Kg 540
12672-29-6 Aroclor 1248 BRL ug/Kg 540
1 1 09 7-69-1 Aroclor 1254 1,900 ( ug/Kg 540 1
11096-82-5 Aroclor 1260 3,900 ug/Kg 540
I 'QC Surrogate Compound :- Recovery ~.QC:Liin�ts
Tetrachloro-m-xylene 97 % 25- 121
Decachlorobiphenyl 162 % m� 28-138 %
Method Reference: Test Methods for Evaluating Solid Waste, US EPA,SW-846,Third Edition, Update Pl(1996). Analyte list
as Aroclor analytes formerly specified by EPA Method 8080A. Results are reported on a dry weight basis.
Report Notations: BRL Indicates concentration, if any, is below reporting limit for analyte. Reporting limit is the lowest
' concentration that can be reliably quantified under routine laboratory operating conditions.
Reporting limits are adjusted for sample dilution,percent moisture and sample size.
m Surrogate recovery outside recommended limits due to sample matrix interference.
' Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532
' GROUNDWATER
ANALYTICAL
' Toxicity Characteristic Leaching Procedure (TCLP)
EPA Methods 1311 and 6010B
Trace Metals by ICP-AES
Field ID: HB-2:2-8' Laboratory ID: 29857-02
Project: George Panesis/B099-2511 Sampled: 10-22-99
Client: Bennett&O'Reilly Received: 10-25-99
' Container: 250 mL Glass Leached: 11-09-99
Preservation: Cool TCLP Fluid: 1
Matrix: Solid
Reporting RCRA
CAS Number Analyte Concentration. Units. .Analyzed QC Batch " Method
Limit; Limit
7439-92-1 I Lead 4.0 mg/L 0.25 5.0 11-11-99 MM-0749-T 6010B
Method Reference: Test Methods for Evaluating Solid Waste, US EPA,SW-846,Third Edition, Update III (1996). Sample
prepared in accordance with EPA Method 1311 prior to determinative analysis.
Report Notations: BRL Indicates concentration, if any, is below reporting limit for analyte. Reporting limit is the lowest
' concentration that can be reliably quantified under routine laboratory operating conditions.
Reporting limits are adjusted for sample dilution and sample size.
RCRA Limit indicates maximum concentration of contaminant under the TCLP Rule,as specified
at 40 C.F.R.261.24,Table 1.
II
' Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532
GROUNDWATER
' ANALYTICAL
Quality Control Report
TCLP Matrix Spike
Field ID: HB-2:2-8' Category: TCLP Metals
' Project: George Panesis/B099-2511 Laboratory ID: 29857-02
Client Bennett&O'Reilly Sampled: 10-22-99
Matrix: TCLP Leachate Received: 10-25-99
' Units: mg/L
CAS Number Analyte.r Sample,Concentrat�on Spiked, Measured`; Recovery ��s QC.Batch Method
7439-92-1 Lead 4.0 1.00 5.0 98% MM-0749-T 6010E
I
' Method Reference: Test Methods for Evaluating Solid Waste, US EPA,SW-846,Third Edition, Update III (1996). Sample
prepared in accordance with EPA Method 1311 prior to determinative analysis. All calculations performed
prior to rounding.
Report Notations: BRL Indicates concentration, if any, is below reporting limit for analyte. Reporting limit is the lowest
concentration that can be reliably quantified under routine laboratory operating conditions.
Reporting limits are adjusted for sample dilution and sample size.
' Groundwater Analytical, Inc. P.O. Box 1200 228 Main Street Buzzards
yt za ds Bay, MA 02532
GROUNDWATER
' ANALYTICAL
RCRA Hazardous Waste Characterization
Field ID: HB-2:2-8' Laboratory ID: 29857-02
Project: George Panesis/BO99-2511 Sampled: 10-22-99
Client: Bennett&O'Reilly Received: 10-25-99
Container: 250 mL Glass
Preservation: Cool
' Matrix: Solid
Analyte t `Result w Units— Reporting RCRA Limit . Analyzed.f �' Method:':
.. ,^r, s, Limit
Corrosivity(as pH) 6.2 pH 2.0 >2.0 and <1z.s 11-11-99 EPA 9045C
Ignitability(as Flashpoint) > 165 OF 70 t 11-11-99 EPA 1010-Mod
Reactive Cyanide BRL mg/Kg 5 250 °_ 11-11-99 SW-846Chp.7.3.1
Reactive Sulfide BRL mg/Kg 25 500 ° 11-11-99 SW-846 Chp.7.3.4
Method References: Test Methods for Evaluating Solid Waste, US EPA,SW-846,Third Edition, Update III(1996).
Report Notations: BRL Indicates result,if any, is below reporting limit for analyte. Reporting limit is the lowest
value that can be reliably quantified under routine laboratory operating conditions.
Reporting limits are adjusted for sample dilution and sample size.
t When ignited,bums so vigorously and persistently that it creates a hazard(40 C.F.R.261.22).
' 0 Current EPA guidance level(SW-846).
' Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532
GROUNDWATER
' ANALYTICAL
1 Project Narrative
Project: George Panesis/B099-2511 Lab ID: 29857
' Client: Bennett&O'Reilly Received: 10-25-99
A.'physical Condition of Samples)
This project was received by the laboratory in satisfactory condition. The sample(s) were received
' undamaged in appropriate containers with the correct preservation.
B. Project Documentation
This project was accompanied by satisfactory Chain of Custody documentation, with the following
amendment(s) or correction(s):
1. Sample 29857-01 was analyzed by EPA Method 8082 and extracted only for EPA Method 8270 as
per Dave Bennett, 11-04-99.
2. Sample 29857-02 was analyzed for TCLP Lead, Ignitability, Reactivity and Corrosivity as per Dave
Bennett, 11-04-99.
3. Project 29857 was processed for Priority One Week turnaround as per Dave Bennett, 11-04-99.
' 4. Project 29857 was reported with project name"George Panesis" as per Dave Bennett, 11-04-99.
5. Samples 29674-02 and —06 were reassigned laboratory number 29875-01 and —02.
C. Analysis of Sample(s)
The followinganalytical anomalies or non-conformance were
y s e e noted by the laboratory during the processing
of these sample(s):
1. Sample 29857-01 for analysis by EPA Method 8082 had a surrogate recovery outside recommended
limits due to sample matrix interference.
1
' Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532
228 Main Street,P.O.Box 1200
1ROUNDWATER Buzzards Bay,MA 02532 CHAIN-OF-CUSTODY RECORD
ANALYTICAL Telephone(508)759-4441 AND WORK ORDER N2 37592
FAX(508)759-4475
Project Name:
TURNAROUND
ANALYSIS REQUEST
Project Nu ber: Address:
❑ STANDARD(10BusinessDays) Volatiln Selnirol,lile, P1ratMeePco, Megh PeE ImP emuroel. waste Ge.—Iceerei,try other
//��� /, // PRIORITY(5 Business Days) a o o E
2511 �V I�lo� L] RUSH(RAN- - o
Sampler Name: Cjt /State/zip: (Rush requires Rush Authorization Number) N 3 >
y sl l�/'Q � l/ _ 62t S Please FAX YES ❑ NO n
F-t 1 n'/ CJ4V �(� J � o s
'M I,/• (� / FAX Number:
Project Mana e:
sC Telephone: BILLING n 9 3 g 8
C
�P Purchase Order No.: GWA Reference No.: 'y 4 M
INSTRUCTIONS:Use separate line for each container(except replicates). I- ZS I I R ism m =_
Sampling Malrlx T e g 3 3 $ ^s
YP Containeq ) Preservation Filleted _ -i n-----------------
SAMPLE 11 n _ ,9", _ _ _ LABORATORY s - ' F ' - -
IDENTIFICATION "' g " §.i e _ - NUMBER - J r = - _ a B s ' - a - g
F o W 5 a 2 S a 5 5.e y o m (Lab Use Only) < 3 m m c `e a e s`_
E S 2 e i7 S3 $ 2 — is' o s _ _
7.
m € 3 9 a 3 a
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-------------------
-------------------------
--------------------------
IT, I I lit
REMARKS/SPECIAL INSTRUCTIONS DATA QUALITY OBJECTIVES CHAIN-OF-CUSTODY RECORD
Regulatory Program Project Specific OC NOTE:All samples submitted subject to Standard Terms and Conditions on reverse hereof.
❑Safe Drinking Water Act Man regulatory q p
❑MA DEP Form Y 9 yprograms and EPA methods require project Relinquished b ampler Date Time Received by: Receipt Temperature:
specific OC.Project specific OC includes Sample Duplicates, r
O Specify
Clean Water Act Matrix Spikes.and/or Matrix Spike Duplicates.Laboratory OC is 4 1 )
Specify Slate: not project specific unless prearranged.Project specific OC
G RCRA/Haz.Waste Char. samples are charged on a per sample basis.For water samples. efihGui h to : a e Time Receiv d byyy Shipping,Airbill
rMA MCP(3T0 CMR 40) each MS.MSD and Sample Duplicate requires an additional /l� / /' Number:
Reponable Concentrations sample aliquot.
// RCGW.t rARCS 1 Project Specific OC Required Selection of OC Sample elfin It y: to Time Received by boratory: Custody Seal
RCGW-2 j RCS-2 Sample Duplicate Selected by laboratory �j �) yJ1 Cooler Serial
MA Dredge Disposal G(/ ZL.,'1.(/.'./ j ��y� - v NVVVmber:
, ease use sample:
NH!=RI n CT r7 ME Matrix Spike Please
p Method t5hipment GWA Courier 0 Express Mail 7i Federal Expres o
Specify Category: - Matrix Spike Duplicate .--- ✓ -
❑UPS ❑Hand ❑
GROUNDWATER
ANALYTICAL
Quality Assurance/Quality Control
y A Program OVervieW
Groundwater Analytical conducts an active Quality Assurance program to ensure the production of high
' quality, valid data. This program closely follows the guidance provided by Interim Guidelines and
Specifications for Preparing Quality Assurance Project Plans, US EPA QAMS-005/80 (1980), and Test
Methods for Evaluating Solid Waste, US EPA, SW-846, Update III (1996).
' Quality Control protocols include written Standard Operating Procedures (SOPS) developed for each
analytical method. SOPS are derived from US EPA methodologies and other established references.
Standards are prepared from commercially obtained reference materials of certified purity, and documented
' for traceability.
Quality Assessment protocols for most organic analyses include a minimum of one laboratory control sample,
one method blank, one matrix spike sample, and one sample duplicate for each sample preparation batch.
' All samples, standards, blanks, laboratory control samples, matrix spikes and sample duplicates are spiked
with internal standards and surrogate compounds. All instrument sequences begin with an initial calibration
verification standard and a blank; and excepting GUMS sequences, all sequences close with a continuing
calibration standard. GC/MS systems are tuned to appropriate ion abundance criteria daily, or for each 12
hour operating period, whichever is more frequent.
Quality Assessment protocols for most inorganic analyses include a minimum of one laboratory control
sample, one method blank, one matrix spike sample, and one sample duplicate for each sample preparation
batch. Standard curves are derived from one reagent blank and four concentration levels. Curve validity is
verified by standard recoveries within plus or minus ten percent of the curve.
B 'Definitions
' Batches are used as the basic unit for Quality Assessment. A Batch is defined as twenty or fewer samples of
the same matrix which are prepared together for the same analysis, using the same lots of reagents and the
same techniques or manipulations, all within the same continuum of time, up to but not exceeding 24 hours.
' Laboratory Control Samples are used to assess the accuracy of the analytical method. A Laboratory Control
Sample consists of reagent water or sodium sulfate spiked with a group of target analytes representative of the
method analytes. Accuracy is defined as the degree of agreement of the measured value with the true or
' expected value. Percent Recoveries for the Laboratory Control Samples are calculated to assess accuracy.
Method Blanks are used to assess the level of contamination present in the analytical system. Method Blanks
consist of reagent water or an aliquot of sodium sulfate. Method Blanks are taken through all the appropriate
' steps of an analytical method. Sample data reported is not corrected for blank contamination.
Surrogate Compounds are used to assess the effectiveness of an analytical method in dealing with each
sample matrix. Surrogate Compounds are organic compounds which are similar to the target analytes of
interest in chemical behavior, but which are not normally found in environmental samples. Percent
Recoveries are calculated for each Surrogate Compound.
' Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532
i
GROUNDWATER
' ANALYTICAL
QUALITY ASSURANCE
Laboratory Control Sample Recovery
i Category: Trace Metals
Matrix: Soil
Units: mg/Kg
iLaboratory Control Sample
SPIKE SPIKED PERCENT QC
ANALYTE BATCH ID• ADDED RESULT RECOVERY LIMITS
Lead MM-0861-SLI 100 97 97 % 80-120
1
1
i
Quality Control Limits are defined by the methodology, or alternatively based upon the historical average
recovery plus or minus three standard deviation units.
GROUNDWATER
' ANALYTICAL
QUALITY ASSURANCE
Method Blank
' Category: Trace Metals
Matrix: Soil
' REPORTING EPA
PARAMETER CONCENTRATION LIMIT BATCH ID METHOD
(mg/Kg) (mg/Kg)
' Lead BRL 10 MM-0861-SB 6010
i
BRL = Below Reporting Limit. Method References: Test Methods for Evaluating Solid Waste, US EPA SW-846,
Third Edition (1986). Graphite Furnace analyses performed with Zeeman background correction and Lvov
' platform technique.
GROUNDWATER
' ANALYTICAL
' Certifications and Approvals
CO NNECTICUT,.Department of'Health Services, PH=0586 H
Potable Water,Wastewater/Trade Waste,Sewage/Effluent,and Soil
pH,Conductivity,Acidity,Alkalinity,Hardness,Chloride,Fluoride,Ammonia,Kjeldahl Nitrogen,Nitrate,Nitrite,Orthophosphate,Total Dissolved
' Solids,Cyanide,Aluminum,Antimony,Arsenic,Barium,Beryllium,Cadmium,Total Chromium,Hexavalent Chromium,Cobalt,Copper,Iron,Lead,
Magnesium,Manganese,Mercury,Molybdenum,Nickel,Potassium,Selenium,Silver,Sodium,Thallium,Tin,Titanium,Vanadium,Zinc,Purgeable
Halocarbons,Purgeable Aromatics,Pesticides,PCBs,PCBs in Oil,Ethylene Dibromide,Phenols,Oil and Grease.
MAINE, Department of Human:Services, MA103
Drinking Water
Reciprocal certification in accordance with Massachusetts certification for drinking water analytes.
' Waste Water
Reciprocal certification in accordance with Massachusetts certification for waste water analytes.
' MASSACHUSETTS Department'of Environmental Protection, M-MA 1.03
Potable Water
Antimony,Arsenic,Barium,Beryllium,Cadmium,Chromium,Copper,Lead,Mercury,Nickel,Selenium,Thallium,Nitrate-N,Nitrit�- ,'Fluoride,
' Sodium,Sulfate,Cyanide,Turbidity,Residual Free Chlorine,Calcium,Total Alkalinity,Total Dissolved Solids,pH,Trihalomethanes,Volatile Organic
Compounds,1,2-Dibromoethane,1,2-Dibromo-3-chloropropane,Total Coliform,Fecal Coliform,Heterotrophic Plate Count,E-Coli
Non-Potable Water
' Aluminum,Antimony,Arsenic,Beryllium,Cadmium,Chromium,Cobalt,Copper,Iron;Lead,Manganese,Mercury,Molybdenum,Nickel,Selenium,
Silver,Strontium,Thallium,Titanium,Vanadium,Zinc,pH,Specific Conductance,Total Dissolved Solids,Total Hardness,Calcium,Magnesium.
Sodium,Potassium,Total Alkalinity,Chloride,Fluoride,Sulfate,Ammonia-N,Nitrate-N,Kjeldahl-N,Orthophosphate,Total Phosphorus,Chemical
Oxygen Demand,Biochemical Oxygen Demand,Total Cyanide,Non-Filterable Residue,Total Residual Chlorine,Oil and Grease,Total Phenolics,
Volatile Halocarbons,Volatile Aromatics,Chlordane,Aldrin,Dieldrin,DOD,DOE,DDT,Heptachlor,Heptachlor Epoxide,Polychlorinated
' Biphenyls(water),Polychlorinated Biphenyls(oil).
MICHIGAN Department of Environ"mental Quality $
r. .
' Drinking Water
Trihalomethanes,Regulated and Unregulated Volatile Organic Compounds by EPA Method 524.2;1,2-Dibromoethane,1,2-Dibromo-3-
chloropropane by EPA Method 504.1
NEW HAMPSHIRE, Department of Environmental Services, 202798 s
., 4
Drinking Water
' Metals by Graphite Furnace,Metals by ICP,Mercury,Nitrite•N,Orthophosphate,Residual Free Chlorine,Turbidity,Total Filterable Residue,Calcium
Hardness,pH,Alkalinity,Sodium,Sulfate,Total Cyanide,Insecticides,Herbicides,Base/Neutrals,Trihalomethanes,Volatile Organics,Vinyl
Chloride,DBCP,EDB,Nitrate-N.
Wastewater
' Metals by Graphite Furnace,Metals by ICP,Mercury,pH,Specific Conductivity,TDS,Total Hardness,Calcium,Magnesium,Sodium,Potassium,
Total Alkalinity,Chloride,Fluoride,Sulfate,Ammonia-N,Nitrate-N,Orthophosphate,TKN,Total Phosphorus,COD,BOD,Non-Filterable Residue,
Oil&Grease,Total Phenolics,Total Residual Chlorine,PCBs in Water,PCBs in Oil,Pesticides,Volatile Organics,Total Cyanide.
' RHOUEY ISLAND;rD3epartment of Health,54
ZAM
Surface Water,Air,Wastewater, Potable Water,Sewage
Chemistry: Organic and Inorganic
' Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532
REECE1VirD NOV 1y99
GROUNDWATER Groundwater Analytical, Inc.
P.O.Box 1200
ANALYTICAL 228 Main Street
Buzzards Bay,MA 02532
' Telephone(508)759-4441
FAX(508)759-4475
November 22, 1999
' Ms. Kara Shumwa
Y
Bennett & O'Reilly, Inc.
P.O. Box 1667
Brewster, MA 02631
Project: George/13099-2558
Lab I D: 29916
Sampled: 11-04-99
Dear Kara:
' Enclosed is the Metals Analysis performed for the above referenced project. This project was
processed for Standard Two Week turnaround.
This letter authorizes the release of the analytical results, and should be considered a part of this
report. This report contains a project narrative indicating project changes and non-conformances, a
brief description of the Quality Assurance/Quality Control procedures employed by our laboratory,
' and a statement of our state certifications.
I attest under the pains and penalties of perjury that, based upon my inquiry of those individuals
' immediately responsible for obtaining the information, the material contained in this report is, to
the best of my knowledge and belief, accurate and complete.
Should you have any questions concerning this report, please do not hesitate to contact me.
Sincerely,
' Jonathan R. Sanford
President
' J RS/awc
Enclosures
GROUNDWATER
' ANALYTICAL.
' Trace Metals by ICP-AES and CVAA
Field ID: HB-3:1-2' Laboratory ID: 29916-01
Project: George/B099-2558 Sampled: 11-04-99
' Client: Bennett&O'Reilly Received: 11-08-99
Container: 250ml-Glass % Solids 96
Preservation: Cool
' Matrix: W Soil
CAS Number "Analyte Concentration Units
Reporting Analyzed ,�QC%Batch,x' Method
, limit .Y -
r
7439-92-1 Lead,Total 65 mg/Kg 10 11-09-99 MM-0863-S 60106
' Method Reference: Test Methods for Evaluating Solid Waste, US EPA,SW-846,Third Edition, Update III(1996).
Kesults are reporteo on a dry weight basis.
Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest
concentration that can be reliably quantities under routine laboratory operating conditions.
Keporting limits are adjusted for sample dilution and sample size.
i
i
1
' Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532
1
GROUNDWATER
ANALYTICAL
' Project Narrative
Project: George/6099-2558 Lab ID: 29916
' Client: Bennett&O'Reilly Received: 11-08-99
A.,,Physical Condition of Sample(s)"
This project was received by the laboratory in satisfactory condition. The sample(s) were received
undamaged in appropriate containers with the correct preservation.
B -Project Documentation
This project was accompanied by satisfactory Chain of Custody documentation. The sample container
' label(s) agreed with the Chain of Custody.
C:'Analysis'of Samples)
No analytical anomalies or non-conformances were noted by the laboratory during the processing of these
sample(s). All data contained within this report are released without qualification.
' Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532
228 Main Street,P.O.Box 1200
GROUNDWATER Buzzards Bay,MA 02532 CHAIN-OF-CUSTODY RECORD
ANALYTICAL Telephone(508)759-4441 AND WORK ORDER N4 38643
FAX(508)759-4475
X
t Name: F�r1
',(O 4 /�j TURNAROUND ANALYSIS REQUEST
J� 0 ILL-�C IL Vo1a1ilas semlvolalller �eW""b/Pcea y Pokoleom aouNoo Naz.
Meu General Lhemirey other
Xf ANDARD(10 Business Days) t n I vol. wa:Ie Project Nu ber:L (AJd�dr//e��ss: /J r ❑ PRIORITY(5 Business Days)
�� I l.'l� I IGtC 7 ❑ RUSH(RAN ) L a z� _
3 m -
(Rush requires Rush Authorization Number)
Sampler Name: City/State/Zip: �
Please FAX YES ❑NO o
FAX Number: ��5> C � o g
Project Manager: Telephone: BILLING a ? 3 z^ tI nn u rt ❑ r.� r. A
Purchase Order No.: GWA Reference No.: c c
INSTRUC NS:Use separat l e for each container(except replicates). 1.` �J €- � e o a
. 05 5 d o k,' a 3 S 2 '� a 5 € _
Sampling Matriz Type Container s c $ $ e m =8 - 5
( 1 Preservation Fdieree n n n ❑ c u _ ii m e u _ g
SAMPLE ,�, g _ W LABORATORY r _ e $ e $ ' 3❑ 2 M n �
IDENTIFICATION "� a z NUMBER 5 F -� i< 7 a
w w W > - ' (Lab Use Only)
m s s s a z a o m , _ o
o 3 E $ � � S S - a�S�G 's s m � _ � = $ a g s t sue = '
21
n ❑ ❑ r_ ra ❑ ❑ ❑ ❑ _ o ❑ ❑ ❑
-3; 1 - _� a
REMARKS/SPECIAL INSTRUCTIONS DATA QUALITY OBJECTIVES CHAIN-OF-CUSTODY RECORD
Regulatory Program Project Specific QC NOTE:All samples submitted subject to Standard Terms and Conditions on reverse hereof.
❑Safe Drinking Water Act - Many regulatory programs and EPA methods require project Rejin ufshed b Sampler: Date Time Received b : Receipt Te
❑MA DEP Form specific OC.Project specific OC includes Sample Duplicates. Y t p mperature:
❑NPDES/Clean Water Act Matrix Spikes,and/or Matrix Spike Duplicates.Laboratory OC is (•, �• �f G�
S ecify Slate: not project specific unless prearranged.Project specific OC
CRA/Haz.Waste Char. samples are charged on a per sample basis.For water samples, Relinquish y: Date Time Received b�v ShippingrAirbill
CI A MCP(310 CMR 40) each MS,MSD and Sample Duplicate requires an additional / '+ �,��- f YC 7 Number:
Reportable Concentrations sample aliquot /
t
❑RCGW-1 ❑RCS-1 Project Specific OC Required Selection of OC Sample Relinquish by: Dal Time Received bwLaboratory: Custody Seal/
❑RCGW-2 U RCS-2 ❑Sample Duplicate ❑Selected b laberalo ) ' - Cooler Serial
❑MA Dredge Disposal ❑Matrix Spike Y rY �; ' yr, / 'r rt�� r �' •' 0.!.. Number:
❑NH❑RI❑CT EI ME p ❑Please use sample: Method otr$hipment: ❑GWA Courier E;Express Mail El Federal Express
Specify Category: Ci Matrix Spike Duplicate ❑UPS EI Hand
1
GROUNDWATER
' ANALYTICAL
Quality Assurance/Quality Control
A:,Program Overview '
Groundwater Analytical conducts an active Quality Assurance program to ensure the production of high
' quality, valid data. This program closely follows the guidance provided by Interim Guidelines and
Specifications for Preparing Quality Assurance Project Plans, US EPA QAMS-005/80 (1980), and Test
Methods for Evaluating Solid Waste, US EPA, SW-846, Update III (1996).
' Quality Control protocols include written Standard Operating Procedures (SOPS) developed for each
analytical method. SOPS are derived from US EPA methodologies and other established references.
Standards are prepared from commercially obtained reference materials of certified purity, and documented
' for traceability.
Quality Assessment protocols for most organic analyses include a minimum of one laboratory control sample,
one method blank, one matrix spike sample, and one sample duplicate for each sample preparation batch.
' All samples, standards, blanks, laboratory control samples, matrix spikes and sample duplicates are spiked
with internal standards and surrogate compounds. All instrument sequences begin with an initial calibration.
verification standard and a blank; and excepting GC/MS sequences, all sequences close with a continuing
' calibration standard. GUMS systems are tuned to appropriate ion abundance criteria daily, or for each 12
hour operating period, whichever is more frequent.
Quality Assessment protocols for most inorganic analyses include a minimum of one laboratory control
' sample, one method blank, one matrix spike sample, and one sample duplicate for each sample preparation
batch. Standard curves are derived from one reagent blank and four concentration levels. Curve validity is
verified by standard recoveries within plus or minus ten percent of the curve.
' B. Definitions
' Batches are used as the basic unit for Quality Assessment. A Batch is defined as twenty or fewer samples of
the same matrix which are prepared together for the same analysis, using the same lots of reagents and the
same techniques or manipulations, all within the same continuum of time, up to but not exceeding 24 hours.
' Laboratory Control Samples are used to assess the accuracy of the analytical method. A Laboratory Control
Sample consists of reagent water or sodium sulfate spiked with a group of target analytes representative of the
method analytes. Accuracy is defined as the degree of agreement of the measured value with the true or
' expected value. Percent Recoveries for the Laboratory Control Samples are calculated to assess accuracy.
Method Blanks are used to assess the level of contamination present in the analytical system. Method Blanks
consist of reagent water or an aliquot of sodium sulfate. Method Blanks are taken through all the appropriate
' steps of an analytical method. Sample data reported is not corrected for blank contamination.
Surrogate Compounds are used to assess the effectiveness of an analytical method in dealing with each
sample matrix. Surrogate Compounds are organic compounds which are similar to the target analytes of
interest in chemical behavior, but which are not normally found in environmental samples. Percent
Recoveries are calculated for each Surrogate Compound.
' Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532
GROUNDWATER
' ANALYTICAL
QUALITY ASSURANCE
' Laboratory Control Sample Recovery
' Category: Trace Metals
Matrix: Solid
Units: mg/Kg
' Laboratory Control Sample
SPIKE SPIKED PERCENT QC
tANALYTE BATCH ID ADDED RESULT RECOVERY LIMITS
Lead MM-0863-SLI 100 85 85 % 75-125
' Quality Control Limits are defined by the methodology, or alternatively based upon the historical average
recovery plus or minus three standard deviation units.
GROUNDWATER
ANALYTICAL
QUALITY ASSURANCE
' Method Blank
' Category: Trace Metals
Matrix: Solid
' REPORTING EPA
PARAMETER CONCENTRATION LIMIT BATCH ID METHOD
(mg/Kg) (mg/Kg)
' Lead BRL 10 MM-0863-SB 6010
' BRL = Below Reporting Limit. Method References: Test Methods for Evaluating Solid Waste, US EPA SW-846,
Third Edition (1986). Graphite Furnace analyses performed with Zeeman background correction and Lvov
platform technique.
GROUNDWATER
ANALYTICAL
' Certifications and Approvals
CONNECTICUT ,Department'of Health Services; PH=0586
Potable Water,Wastewater/Trade Waste,Sewage/Effluent,and Soil
pH,Conductivity,Acidity,Alkalinity,Hardness,Chloride,Fluoride,Ammonia,Kjeldahl Nitrogen,Nitrate,Nitrite,Orthophosphate,Total Dissolved
' Solids,Cyanide,Aluminum,Antimony,Arsenic,Barium,Beryllium,Cadmium,Total Chromium,Hexavalent Chromium,Cobalt,Copper,Iron,Lead,
Magnesium,Manganese,Mercury,Molybdenum,Nickel,Potassium,Selenium,Silver,Sodium,Thallium,Tin,Titanium,Vanadium,Zinc,Purgeable
Halocarbons,Purgeable Aromatics,Pesticides,PCBs,PCBs in Oil,Ethylene Dibromide,Phenols,Oil and Grease.
MAINE, Department of Human Services; MA103 LL
t Drinking Water
Reciprocal certification in accordance with Massachusetts certification for drinking water analytes.
' Waste Water
Reciprocal certification in accordance with Massachusetts certification for waste water analytes.
MASSACHUSETTS, Department of Environmental'Protection, M=MA=1"03
Potable Water
Antimony,Arsenic,Barium,Beryllium,Cadmium,Chromium,Copper,Lead,Mercury,Nickel,Selenium,Thallium,Nitrate-N,Nitrite-N,Fluoride,
' Sodium,Sulfate,Cyanide,Turbidity,Residual Free Chlorine,Calcium,Total Alkalinity,Total Dissolved Solids,pH,Trihalomethanes,Volatile Organic
Compounds,1,2-Dibromoethane,1,2-Dibromo-3-chloropropane,Total Coliform,Fecal Coliform,Heterotrophic Plate Count,E-Coli
NowPotable Water
Aluminum,Antimony,Arsenic,Beryllium,Cadmium,Chromium,Cobalt,Copper,Iron,Lead,Manganese,Mercury,Molybdenum,Nickel,Selenium,
' Silver,Strontium,Thallium,Titanium,Vanadium,Zinc,pH,Specific Conductance,Total Dissolved Solids,Total Hardness,Calcium,Magnesium,
Sodium,Potassium,Total Alkalinity,Chloride,Fluoride,Sulfate,Ammonia-N,Nitrate-N,Kjeldahl-N,Orthophosphate,Total Phosphorus,Chemical
Oxygen Demand,Biochemical Oxygen Demand,Total Cyanide,Non-Filterable Residue,Total Residual Chlorine,Oil and Grease,Total Phenolics,
Volatile Halocarbons,Volatile Aromatics,Chlordane,Aldrin,Dieldrin,DDD,DOE,DDT,Heptachlor,Heptachlor Epoxide,Polychlorinated
Biphenyls(water),Polychlorinated Biphenyls(oil).
MICHIGAN, Department of Environmental Quality
' Drinking Water
Trihalomethanes,Regulated and Unregulated Volatile Organic Compounds by EPA Method 524.2;1,2-Dibromoethane,1,2-Dibromo-3-
chloropropane by EPA Method 504.1
NEW HAMPSHIRE. Department of.Environmental Services, 202798
Drinking Water
' Metals by Graphite Furnace,Metals by ICP,Mercury,Nitrite-N,Orthophosphate,Residual Free Chlorine,Turbidity,Total Filterable Residue,Calcium
Hardness,pH,Alkalinity,Sodium,Sulfate,Total Cyanide,Insecticides,Herbicides,Base/Neutrals,Trihalomethanes,Volatile Organics,Vinyl
Chloride,DBCP,EDB,Nitrate-N.
Wastewater
Metals by Graphite Furnace,Metals by ICP,Mercury,pH,Specific Conductivity,TDS,Total Hardness,Calcium,Magnesium,Sodium,Potassium,
Total Alkalinity,Chloride,Fluoride,Sulfate,Ammonia-N,Nitrate-N,Orthophosphate,TKN,Total Phosphorus,COD,BOD,Non-Filterable Residue,
Oil&Grease,Total Phenolics,Total Residual Chlorine,PCBs in Water,PCBs in Oil,Pesticides,Volatile Organics,Total Cyanide.
1
RHODE ISLAND, Department of Health, 54
Surface Water,Air,Wastewater, Potable Water,Sewage
Chemistry: Organic and Inorganic
1
1
' Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532
RECEIVED JAO'N 1 2 2?30
' GROUNDWATER Groundwater Analytical,Inc.
P.O. Box 1200
ANALYTICAL Buzzards
Main Street
Buzzards Bay,MA 02532
Telephone(508)759-4441
FAX(508)759-4475
' January 11, 2000
Ms. Kara Shumway
Bennett & O'Reilly, Inc.
P.O. Box 1667
Brewster, MA 02631
Project: George/13099-2558
LAID: 30877
Sampled: 01-04-00
' Dear Kara:
Enclosed are the PCBs, Metals and Total Petroleum Hydrocarbons Analyses performed for the
above referenced project. This project was processed for Priority One Week turnaround.
' This letter authorizes the release of the analytical results, and should be considered a part of this
report. This report contains a project narrative indicating project changes and non-conformances, a
brief description of the Quality Assurance/Quality Control procedures employed by our laboratory,
' and a statement of our state certifications.
I attest under the pains and penalties of perjury that, based upon my inquiry of those individuals
' immediately responsible for obtaining the information, the material contained in this report is, to
the best of my knowledge and belief, accurate and complete.
Should you have any questions concerning this report, please do not hesitate to contact me.
Sincerely,
' Jonathan R. Sanford
President
JRS/myr
Enclosures
1
' 1
GROUNDWATER
' ANALYTICAL
' Trace Metals by ICP-AES
Field ID: SW-E:0-8' Laboratory ID: 30877-01
' Project: George/B099-2558 Sampled: 01-04-00
Client: Bennett&O'Reilly Received: 01-04-00
Container: 250 mL Glass %Solids 91
Preservation: Cool
' Matrix Soil
CAS Number£s $ Ariatyte Concentration Units Reporting 'Analyzed QCBatch �arMetFoct
vfl
L..
' 7439-92-1 Lead,Total 92 mg/Kg 11 01-09-00 MM-0896-S 60106
Method Reference: Test Methods for Evaluating Solid Waste, US EPA,SW-846,Third Edition, Update III(1996).
Kesults are reported on a dry weight basis.
Report Notations: BRL Indicates concentration,if any, is below reporting limit for analyte. Reporting limit is the lowest
Concentration that can be reliably quanutied under routine laboratory operating Conditions.
Keporting limits are adjusted for sample auution and sample size.
c
I
i
f �
a
i
1
Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532
GROUNDWATER
' ANALYTICAL
' Trace Metals by ICP-AES
Field ID: SW-W:0-8' Laboratory ID: 30877-02
' Project: George/B099-2558 Sampled: 01-04-00
Client: Bennett&O'Reilly Received: 01-04-00
Container: 250 mL Glass %Solids 91
Preservation: Cool
' Matrix Soil
Ortin
CAS Number Analyte zw t� :Concentratio n Units g Analyzed �QC�Batch Method
LI(nit"-
' 7439-92-1 Lead,Total 38 mg/Kg 11 01-09-00 MM-0896-S 6010E
Method Reference: Test Methods for Evaluating Solid Waste,US EPA,SW-846,Third Edition, Update III (1996).
Kesuits are reporteo on a ory weight basis.
' Report Notations: BRL Indicates concentration, if any,is below reporting limit for analyte. Reporting limit is the lowest
concentration that can be reliably quantitieo under routine laboratory operating conortions.
Keporting limits are agjusted for sample otlution ano sample size.
Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532
' GROUNDWATER
ANALYTICAL
' Trace Metals by ICP-AES
Field ID: SW-S:0-8' Laboratory ID: 30877-03
' Project: George/B099-2558 Sampled: 01-04-00
Client: Bennett&O'Reilly Received: 01-04-00
Container: 250 mL Glass % Solids 89
Preservation: Cool
' Matrix Soil
Reporting
CAS Number '. Analyte Concentration Unrts x Analyzed: ' QC Batch MetF>iod
�n Limd
7439-92-1 Lead,Total 110 mg/Kg 11 01-09-00 MM-0896-S 6010B
Method Reference: Test Methods for Evaluating Solid Waste, US EPA,SW-846,Third Edition, Update III(1996).
Kesults are reported on a dry weignt basis.
' Report Notations: BRL Indicates concentration, if any, is below reporting limit for analyte. Reporting limit is the lowest
concentration tnat can be reliably quantities under routine laboratory operating conditions.
Keporting limits are adjusted for sample oilution and sample size.
1
Groundwater Analytical, Inc., P.O. Box.1200, 228 Main Street, Buzzards Bay, MA 02532
GROUNDWATER
' ANALYTICAL
Trace Metals by ICP-AES
Field ID: SW-N:0-8' Laboratory ID: 30877-04
' Project: George/B099-2558 Sampled: 01-04-00
Client: Bennett&O'Reilly Received: 01-04-00
Container: 250 mL Glass % Solids 93
Preservation: Cool
' Matrix Soil
r.;,; .Reporting .� < .
CAS Nu mber AnalyteConcentration Umts* Analyzed` QC Batch = Method
7439-92-1 Lead,Total 76 mg/Kg 11 01-09-00 MM-0896-S 6010B�
Method Reference: Test Methods for Evaluating Solid Waste, US EPA,SW-846,Third Edition, Update III(1996).
Kesults are reported on a dry weignt basis.
Report Notations: BRL Indicates concentration, if any,is below reporting limit for analyte. Reporting limit is the lowest
concentration tnat can be reliably quantities under routine iaboratory operating conditions.
Keporting limits are adjusted for sample dilution and sample size.
P
Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532
GROUNDWATER
ANALYTICAL
Trace Metals by ICP-AES
Field ID: BOH:8' Laboratory ID: 30877-05
' Project: George/13099-2558 Sampled: 01-04-00
Client: Bennett&O'Reilly Received: 01-04-00
Container: 250 mL Glass % Solids 96
Preservation: Cool
' Matrix: Soil
sReportmg «, � ��J
CAS QG
Number Analyte Concentration 'Umtsf Analyzed ` :Batch Method
ease as LlRllt+
n
7439-92-1 Lead,Total 33 mg/Kg 11 01-09-00 MM-0896-S 6010B
Method Reference: Test Methods for Evaluating Solid Waste, US EPA,SW-846,Third Edition, Update III (1996).
Keswts are reported on a ary weight basis.
' Report Notations: BRL Indicates concentration, if any,is below reporting limit for analyte. Reporting limit is the lowest
concentration that can be reliably quantified under routine laboratory operating conditions.
Keporting emits are adjusted for sample dilution and sample size.
Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532
GROUNDWATER
ANALYTICAL
EPA Method 8082
' Polychlorinated Biphenyls (PCBs) by GGECD
Field ID- SW-E:0-8' Laboratory ID: 30877-01
' Project: George/BO99-2558 QC Batch ID: PB-0973-M
Client: Bennett&O'Reilly Sampled: 01-04-00
Container: 250mL Glass Received: 01-04-00
' Preservation: Cool Extracted: 01-05-00
Matrix: Soil Analyzed: 01-07-00
%Moisture: 9 Dilution Factor: 1
„CA$;NU(nber COrlCentration t .,,Uf11tS" " 'fteporG�$"Li(Itlf
.. ., . ,
�. .,.
12674-11-2 Aroclor 1016 _ BRL ug/Kg 85
1 1 1 04-2 8-2 Aroclor 1221 BRL ug/Kg 85
1 1 1 41-1 6-5 Aroclor 1232 BRL ug/Kg _ 85
' 53469-21-9 Aroclor 1242 BRL ug/Kg — 85
12672-29-6 Aroclor 1248 BRL ug/Kg 85
11097-69-1 Aroclor 1254 120 ug/Kg 85
' 11096-82 5 Aroclor 1260 210 ug/Kg 85 4
Recovery . QC Limas: "°'
urro te:Com and , ti _
Tetrachloro-m-x lene _ _ _ 82 % _ _ _25-121 %
Decachlorobiphenyl _ 96 % 28-138 %
Method Reference: Test Methods for Evaluating Solid Waste, US EPA,SW-846,Third Edition, Update III(1996). Analyte list
as Aroclor analytes formerly specified by EPA Method 8080A. Results are reported on a dry weight basis.
Report Notations: BRL Indicates concentration, if any, is below reporting limit for analyte. Reporting limit is the lowest
' concentration that can be reliably quantified under routine laboratory operating conditions.
Reporting limits are adjusted for sample dilution,percent moisture and sample size.
F
Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532
GROUNDWATER
ANALYTICAL
EPA Method 8082
Polychlorinated Biphenyls (PCBs) by GGECD
Field ID: SW-W:0,81 Laboratory ID: 30877-02
Project: George/B099-2558 QC Batch ID: PB-0973-M
Client: Bennett&O'Reilly Sampled: 01-04-00
Container: 250ml.Glass Received: 01-04-00
Preservation: Cool Extracted: 01-05-00
Matrix: Soil Analyzed: 01-07-00
% Moisture: 9 Dilution Factor: 1
. CA-S;NUmb'
C 0 6ficekiixtio
12674-11-2 Aroclor 1016 BRL ug/Kg 86
1 1 1 04-28-2 Aroclor 1221 BRL I ug/Kg 86
1 1 1 41-1 6-5 Aroclor 1232 BRL ug/Kg 86
53469-21-9 Aroclor 1242 BRL ug/Kg 86
12672-29-6 Aroclor 1248 BRL ug/Kg 86
11097-69-11 Aroclor 1254 BRL ug/Kg 86
ug/Kg
11096-82-5 Aroclor 1260 BRL
e, ornpouri&�,�J"" Lim,i&,
Tetrachloro-m-xylene 79 j 25- 121 %
Decachlorobiphenyl 86 % 28-138 %
Method Reference: Test Methods for Evaluating Solid Waste, US EPA,SW-846,Third Edition, Update 111 (1996). Analyte list
as Aroclor analytes formerly specified by EPA Method 8080A. Results are reported on a dry weight basis.
Report Notations: BRL Indicate,concentration,if any, is below reporting limit for analyte. Reporting limit is the lowest
concentration that can be reliably quantified under routine laboratory operating conaitions.
Reporting limits are adjusted for sample dilution,percent moisture and sample size.
Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532
I
GROUNDWATER
ANALYTICAL
EPA Method 8082
Polychlorinated Biphenyls (PCBs) by GGECD
Field ID: SW-S:0-8' Laboratory ID: 30877-03
' Project: George/BO99-2558 QC Batch ID: PB-0973-M
Client: Bennett&O'Reilly Sampled: 01-04-00
Container: 250m1 Glass Received: 01-04-00
' Preservation: Cool Extracted: 01-05-00
Matrix: Soil Analyzed: 01-07-00
%Moisture: 11 Dilution Factor: 1
:CAS Number `= : ; Analyte .x ;_.. '"Concentration Units Reporting:limit
12674-11-2 Aroclor 1016 BRL ug/Kg w 87
1 1 1 04-28-2 Aroclor 1221 BRL ug/Kg 87
1 1 1 41-1 6-5 Aroclor 1232 BRL ug/Kg 87
' 53469-21-9 Aroclor 1242 BRL ug/Kg 87
12672-29-6 Aroclor 1248 ( BRL ug/Kg 87
1 1 09 7-69-1 Aroclor 1254 BRL _ ug/Kg 87
11096-82-5 Aroclor 1260 -� 140 _ _ug/Kg 87
sQC.Su to Com, and a `, Recove x.. . . Limits Aga Po .-• �. , rY . .. QC
Tetrachloro-m-xylene _ 80 % _ _ 25- 121 %
Decachlorobiphenyl _ 87 % __ _ 28- 138 % J
' Method Reference: Test Methods for Evaluating Solid Waste, US EPA,SW-846,Third Edition, Update lil(1996). Analyte list
as Aroclor analytes formerly specified by EPA Method 8080A. Results are reported on a dry weight basis.
Report Notations: BRL Indicates concentration, if any, is below reporting limit for analyte. Reporting limit is the lowest
' concentration that can be reliably quantified under routine laboratory operating conditions.
Reporting limits are adjusted for sample dilution,percent moisture and sample size.
Groundwater.Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532
GROUNDWATER
ANALYTICAL
EPA Method 8082
Polychlorinated Biphenyls (PCBs) by GGECD
Field ID: SW-N:0-8' Laboratory ID: 30877-04
Project: George/13099-2558 QC Batch ID: PB-0973-M
Client: Bennett&O'Reilly Sampled: 01-04-00
Container: 250m1 Glass Received: 01-04-00
Preservation: Cool Extracted: 01-05-00
Matrix: Soil Analyzed: 01-07-00
% Moisture: 7 Dilution Factor: 1
AS`NUM -Ana yW� C0 'etiat U
nits Report
ing 1
12674-11-2 Aroclor 1016 BRL ug/Kg 83
1 1 1 04-28-2 Aroclor 1221 BRL ug/Kg 83
1 1 1 41-1 6-5 Aroclor 1232 BRL ug/Kg 83
53469-21-9 Aroclor 1242 BRL ug/Kg 83
12672-29-6 Aroclor 1248 BRL ug/Kg 83
1 1 09 7-69-1 Aroclor 1254 j BRL ug/Kg 83
11096-82-5 Aroclor 1260 89 ug/Kg 83
Lh�iti�
-R, 'move ry. (�c
�.`
5",
Tetrachloro-rn-xylene 84 % 25-121 %
Decachlorobiphenyl 87 % 28-138 %
Method Reference: Test Methods for Evaluating Solid Waste,US EPA,SW-846,Third Edition, Update 111(1996). Analyte list
as Aroclor analytes formerly specified by EPA Method 8080A. Results are reported on a dry weight basis.
Report Notations: BRL Indicates concentration, if any,is below reporting limit for analyte. Reporting limit is the lowest
concentration that can be reliably quantified under routine laboratory operating conditions.
Reporting limits are adjusted for sample dilution,percent moisture and sample size.
1
1
1
i "
1
1 r
1
Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532
GROUNDWATER
' ANALYTICAL
' EPA Method 8082
Polychlorinated Biphenyls (PCBs) by GC/ECD
Field ID: BOH:8' Laboratory ID: 30877-05
' Project: George/13099-2558 QC Batch ID: PB-0973-M
Client: Bennett&O'Reilly Sampled: 01-04-00
Container: 250mL Glass Received: 01-04-00
Preservation: Cool Extracted: 01-05-00
Matrix: Soil Analyzed: 01-07-00
%Moisture: 4 Dilution Factor: 1
°'CAS"Number Analyte F, Conceritratzon.,„, ` units iteporting L- it
12674-11-2 Aroclor 1016 BRL ug/Kg 81
1 1 1 04-28-2 Aroclor 1221 BRL ug/Kg 81
1 1 1 41-1 6-5 Aroclor 1232 BRL ug/Kg 81
53469-21-9 Aroclor 1242 BRL ug/Kg 81
12672-29-6 Aroclor 1248 BRL ug/Kg 81
11097-69-1 Aroclor 1254 BRL ug/Kg 81
11096-82-5 Aroclor 1260 BRL ug/Kg 81
.;Qc sdirogate Compound ', := J Recovery QC"Limits
Tetrachloro-m-xylene 83 % 25- 121 %
Decachlorobiphenyl 85 % 28- 138
' Method Reference: Test Methods for Evaluating Solid Waste, US EPA,SW-846,Third Edition,Update III(1996). Analyte list
as Aroclor analyzes formerly specified by EPA Method 8080A. Results are reported on a dry weight basis.
Report Notations: BRL Indicates concentration, if any,is below reporting limit for analyze. Reporting limit is the lowest
concentration that can be reliably quantified under routine laboratory operating conditions.
Reporting limits are adjusted for sample dilution,percent moisture and sample size.
i
Groundwater Analytical, Inc. P.O. Box.1200 228 Main Street Buzzards Ba MA yt y, 02532
GROUNDWATER
' ANALYTICAL
EPA Method 8100 (Modified)
Total Petroleum Hydrocarbons by GC/FID
' Field ID: SW-E:0-8' Laboratory ID: 30877-01
Project: George/B099-2558 QC Batch ID: HF-1262-M
Client: Bennett 8,O'Reilly Sampled: 01-04-00
Container: 250mL Glass Received: 01-04-00
Preservation: Cool Extracted: 01-05-00
Matrix: Soil Analyzed: 01-06-00
% Moisture: 9 Dilution Factor: 1
7Cndlyte � + %COflCentratlOn UnItS R � 1tlnllmlt
" :`,
Total Petroleum Hydrocarbons 180 mg/Kg 65
y,.
'fix r as x
QC SurrogateK;Compound ; Recovery ( QC Lrmrts
-x
ortho-Terphenyl 84 % _60- 140 %
I ' Method Reference: Test Methods for Evaluating Solid Waste, US EPA,SW-846,Third Edition, Update III(1996).. Analytical
protocol modified to quantify total petroleum hydrocarbons. Results are quantified on the basis
of 5a—androstane. Results are reported on a dry weight basis.
Report Notations: BRL Indicates concentration, if any,is below reporting limit for analyze. Reporting limit is the lowest
concentration that can be reliably quantified under routine laboratory operating conditions.
Reporting limits are adjusted for sample dilution and sample size.
1
Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532
1
' GROUNDWATER
ANALYTICAL
' EPA Method 8100 (Modified)
Total Petroleum Hydrocarbons by GC/FID
' Field ID: SW-W:0-8' Laboratory ID: 30877-02
Project: George/B099-2558 QC Batch ID: HF-1262-M
Client: Bennett&O'Reilly Sampled: 01-04-00
' Container: 250mL Glass Received: 01-04-00
Preservation: Cool Extracted: 01-05-00
Matrix: Soil Analyzed: 01-06-00
9/6 Moisture: 9 Dilution Factor: 1
: y,,.. AnalyteL ta, Concentration N:, DintsReporhng Limit
V °
�
Total Petroleum Hydrocarbons 76 mg/Kg 63
w
QC Surrogate Compound Y b
r Recovery QC Grill �F
�.
� +
:. ._. _.
ortho-Terphenyl 87 % _60-140%
' Method Reference: Test Methods for Evaluating Solid Waste, US EPA,SW-846,Third Edition, Update III(1996). Analytical
protocol modified to quantify total petroleum hydrocarbons. Results are quantified on the basis
of 5a—androstane. Results are reported on a dry weight basis.
' Report Notations: BRL Indicates concentration, if any, is below reporting limit for analyte. Reporting limit is the lowest
concentration that can be reliably quantified under routine laboratory operating conditions.
Reporting limits are adjusted for sample dilution and sample size.
Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532
GROUNDWATER
ANALYTICAL
' EPA Method 8100 (Modified)
Total Petroleum Hydrocarbons by GC/FID
' Field ID: SW-S:0-8' Laboratory ID: 30877-03
Project: George/6099-2558 QC Batch ID: HF-1262-M
Client: Bennett&O'Reilly Sampled: 01-04-00
' Container: 250mL Glass Received: 01-04-00
Preservation: Cool Extracted: 01-05-00
Matrix: Soil Analyzed: 01-06-00
0/6 Moisture: 11 Dilution Factor: 1
"ter Y Analyte a Concentration Umts`, Reportmg fi6k,
Total Petroleum Hydrocarbons 330 mg/Kg 67
r QC
S urrog ,,..: ,.. oue, —p
ortho-Terphenyl nd u^ c84
v.,em ry 60
C-s�1L�4iamdd0� ; E 9' Method Reference: Test Methods for Evaluating Solid Waste, US EPA,SW-846,Third Edition, Update III(1996). Analytical
protocol modified to quantify total petroleum hydrocarbons. Results are quantified on the basis
of 5a—androstane. Results are reported on a dry weight basis.
' Report Notations: BRL Indicates concentration, if any, is below reporting limit for analyte. Reporting limit is the lowest
concentration that can be reliably quantified under routine laboratory operating conditions.
Reporting limits are adjusted for sample dilution and sample size.
i
Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay,MA 02532
GROUNDWATER
ANALYTICAL
I ' EPA Method 8100 (Modified)
Total Petroleum Hydrocarbons by GORD
' Field ID: SW-N:0-8' Laboratory ID: 30877-04
Project: George/13099-2558 QC Batch ID: HF-1262-M
Client: Bennett&O'Reilly Sampled: 01-04-00
' Container: 250mL Glass Received: 01-04-00
Preservation: Cool Extracted: 01-05-00
Matrix: Soil Analyzed: 01-06-00
0/6 Moisture: 7 Dilution Factor: 1
a AnalyteConcentratron Units Reportmg Limrt
h
._7fi:
Total Petroleum Hydrocarbons 120 mg/Kg 62
'fa� ,i4 ...'*s aS a
SUITOgate:COmp0Und r Recovery it > QC LI(I11tS ry
ortho-Terphenyl 86 % 60-140%
' Method Reference: Test Methods for Evaluating Solid Waste,US EPA,SW-846,Third Edition, Update III(1996). Analytical
protocol modified to quantify total petroleum hydrocarbons. Results are quantified on the basis
of 5a—androstane. Results are reported on a dry weight basis.
' Report Notations: BRL Indicates concentration, if any, is below reporting limit for analyte. Reporting limit is the lowest
concentration that can be reliably quantified under routine laboratory operating conditions.
Reporting limits are adjusted for sample dilution and sample size.
' Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532
r
GROUNDWATER
' ANALYTICAL
' EPA Method 8100 (Modified)
Total Petroleum Hydrocarbons by GC/FID
' Field ID: BOH:8' Laboratory ID: 30877-05
Project: George/B099-2558 QC Batch ID: HF-1262-M
Client: Bennett&O'Reilly Sampled: 01-04-00
' Container: 250mL Glass Received: 01-04-00
Preservation: Cool Extracted: 01-05-00
Matrix: Soil Analyzed: 01-07-00
9/6 Moisture: 4 Dilution Factor: 1
v X .ta
Analyte, a r Concentration p rtF„ Umts w Reportmg Lima`
Total Petroleum Hydrocarbons BRL mg/Kg 60
QC Surrogate Compound Recovery QC Limitsa.ss'
ortho-Terphenyl 87 % 60-140%
' Method Reference: Test Methods for Evaluating Solid Waste, US EPA,SW-846,Third Edition, Update III(1996). Analytical
protocol modified to quantify total petroleum hydrocarbons. Results are quantified on the basis
of 5a—androstane. Results are reported on a dry weight basis.
' Report Notations: BRL Indicates concentration, if any,is below reporting limit for analyte. Reporting limit is the lowest
concentration that can be reliably quantified under routine laboratory operating conditions.
Reporting limits are adjusted for sample dilution and sample size.
i
i
4
Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532
f
GROUNDWATER
ANALYTICAL
I ' Project Narrative
Project: George/13099-2558 Lab ID: 30877
' Client: Bennett &O'Reilly Received: 01-04-00
k Physical Condition of Samples)
This project was received by the laboratory in satisfactory condition. The sample(s) were received
undamaged in appropriate containers with the correct preservation.
B Project Documentation"
This project was accompanied by satisfactory Chain of Custody documentation, with the following
amendment(s) or correction(s):
1. Samples 30877-01 through —05 were received in one 250mL glass container each.
2. Samples 30877-01 through —05 were sampled on 01-04-00.
C. Analysis of Sample(s)
f
No analytical anomalies or non-conformances were noted by the laboratory during the processing of these
sample(s). All data contained within this report are released without qualification.
If
Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532
AM VIIIIIIIIIIIIIIIII
228 Main Street,P.O.Box 1200
GROUNDWATER Buzzards Bay,MA 02532 CHAIN-OF-CUSTODY RECORD
ANALYTICAL FAX(508)759-49-4 Telephone(5475 08)759-4441 AND WORK ORDER N4 39447
roject Name: Firm: TURNAROUND
(' pail
,'/j ANALYSIS REQUEST
�/e-�XS� YoraBlea Semlrolalllea Per erENCB. M.V1. Pow— roweoa Nat GaneMl ceemiatry Ww,
❑STANDARD(10 Business Days) waste
Project N(�,ber: Ads: '��� PRIORITY(5 Business Days) xx
TO" ❑ RUSH(RAN- 1 7z
Sampler Name; city/State/Zip: (Rush requires Rush Authorization Number) ❑ ❑ ❑ n ❑ €
/�/ .`z Please FAX YES ❑NO g =
0-S � �/� A. b'J/ FAX Number: o s 3
e
Project Ma Telephone: BILLING # $ a
n ❑ Vol 1�0 ❑ 9❑ ❑ g a g a
Purchase Order No.: GWA Reference No.: ❑
e m $ g o s INSTRUCTIONS:Use separatefline for each container(except replicates). —Z` xx
e i ; s a ❑ - gs$
Sampling Matrix o 's § a p ! § = a ° 8
�YPe Containers ❑ ❑ ❑ ❑ ❑ ❑ ❑ ❑ ❑ ❑ o ❑ _ $
l ) Preservation Fmerea @@
11 .
SAMPLE - o a e W LABORATORY
IDENTIFICATION W < a a 1 u e 1 a NUMBER W W - • ❑ p o
w F3 w a S a a in (Lab Use Only) m tdt �" �/ 3 6 2 ❑ x _ s
E ' - >: E $ S �e tl $ Z @ $ W S 2 at ❑ C ❑
R § a 3 a 8 2
Tim 3 > oO a o 0 0 6 0 o N o ❑ o ❑ o ❑ ❑ ❑ ❑ ❑ e ❑ ❑ ❑ ❑
� �C '� tf i / Ix x = - =
Fit-
1 —
�i l
REMARKS/SPECIAL INSTRUCTIONS DATA QUALITY OBJECTIVES CHAIN-OF-CUSTODY RECORD
Regulatory Program Project Specific QC NOTE:All samples submitted subject to Standard Terms and Conditions on reverse hereof.
❑Safe Drinking Water Act❑MA DEP Form Many regulatory programs and EPA methods require project Rel' uished Sampler: Date Time R eive�
� Receipt Temperature:
specific OC.Project specific OC includes Sample Duplicates.
❑NPDES/Clean Water Act Matrix Spikes,and/or Matrix Spike Duplicates.Laboratory OC is
Specify State: not project specific unless prearranged.Project specific OC .�
❑ CRA/Haz.Waste Char. samples are charged on per sample basis.For water samples, Relinquishe y: Date Time Received by: Shipping/Airbill
A MCP(310 CMR 40) each MS,MSD and Sample Duplicate requires an additional Number:
Reportable Concentrations sample aliquot.
❑RCGW-1,6RCS-1 Project Specific OC Required Selection of OC Sample R i ished ate Time R by Lab story: Custody Seal/
❑RCGW-2❑RCS-2 Cooler Serial
❑Sample Duplicate O Selected by laboratory 7/� / QO /�/o l j-y Number:
❑MA Dredge Disposal ❑Matrix Spike _-- '
❑NH❑RI❑CT❑ME p ❑Please use sample: Method of ipment: WA Courier❑Express Mail [I Federal Express
Specify Category: 0 Matrix Spike Duplicate ❑UPS 0 Hand 0
GROUNDWATER
' ANALYTICAL
Quality Assurance/Quality Control
' A Program Overview
Groundwater Analytical conducts an active Quality Assurance program to ensure the production of high
' quality, valid data. This program closely follows the guidance provided by Interim Guidelines and
Specifications for Preparing Quality Assurance Project Plans, US EPA QAMS-005/80 (1980), and Test
Methods for Evaluating Solid Waste, US EPA, SW-846, Update III (1996).
' Quality Control protocols include written Standard Operating Procedures (SOPS) developed for each
analytical method. SOPS are derived from US EPA methodologies and other established references.
Standards are prepared from commercially obtained reference materials of certified purity, and documented
' for traceability.
Quality Assessment protocols for most organic analyses include a minimum of one laboratory control sample,
one method blank, one matrix spike sample, and one sample duplicate for each sample preparation batch.
' All samples, standards, blanks, laboratory control samples, matrix spikes and sample duplicates are spiked
with internal standards and surrogate compounds. All instrument sequences begin with an initial calibration
verification standard and a blank; and excepting GUMS sequences, all sequences close with a continuing
' calibration standard. GUMS systems are tuned to appropriate ion abundance criteria daily, or for each 12
hour operating period, whichever is more frequent.
Quality Assessment protocols for most inorganic analyses include a minimum of one laboratory control
' sample, one method blank, one matrix spike sample, and one sample duplicate for each sample preparation
batch. Standard curves are derived from one reagent blank and four concentration levels. Curve validity is
verified by standard recoveries within plus or minus ten percent of the curve.
B. Definitions
' Batches are used as the basic unit for Quality Assessment. A Batch is defined as twenty or fewer samples of
the same matrix which are prepared together for the same analysis, using the same lots of reagents and the
same techniques or manipulations, all within the same continuum of time, up to but not exceeding 24 hours.
Laboratory Control Samples are used to assess the accuracy of the analytical method. A Laboratory Control
Sample consists of reagent water or sodium sulfate spiked with a group of target analytes representative of the
method analytes. Accuracy is defined as the degree of agreement of the measured value with the true or
' expected value. Percent Recoveries for the Laboratory Control Samples are calculated to assess accuracy.
Method Blanks are used to assess the level of contamination present in the analytical system. Method Blanks
consist of reagent water or an aliquot of sodium sulfate. Method Blanks are taken through all the appropriate
steps of an analytical method. Sample data reported is not corrected for blank contamination.
Surrogate Compounds are used to assess the effectiveness of an analytical method in dealing with each
sample matrix. Surrogate Compounds are organic compounds which are similar to the target analytes of
' interest in chemical behavior, but which are not normally found in environmental samples.. Percent
Recoveries are calculated for each Surrogate Compound.
I
Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532
GROUNDWATER
ANALYTICAL
Quality Control Report
Laboratory Control Sample
Category: EPA Method 8082
QC Batch ID: PB-0973-M
Matrix: Soil
Units: ug/Kg
'•fAS"Number "'�ry „,"�<~".Anal a '=�� ...�;�,_," eked�«�z.,'"�� Measured ." ,�Recove �'
yt, SP� ry';' �'QC Limits�r
1 1 09 7-69-1 Aroclor 1254 330 310 92% 60- 140%
"o->' _,;".,QGSurrogate Compound a Recoverya
Tetrachloro-m-xylene 87% 25- 121 %
Decachlorobiphenyl 86% 28-138 %
Metnoa Keterence: jest metnoas Tor tvaivaung Bona waste, ua trA,Jw-640, Intro taition, upaate III l vvbl• Kesuits
are caicuiatea on a ary weight oasis.
Keport notations: tw caicwations perrormea prior to rounaing. tluanry uontroi LIMITS are aennea oy the metnoaoiogy,
or anemanvoy oasea upon the nistoricai average recovery plus or minus three stanaara aevlatlon units.
I
Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532
GROUNDWATER
' ANALYTICAL
I ' Quality Control Report
Method Blank
Category: EPA Method 8082
QC Batch ID: PB-0973-M
Matrix: Soil
,GAS Number Analyte, « Co tcentcatton Units `Repor-ng,L mit
12674-11-2 Aroclor 1016 BRL ug/Kg 80
11104-28-2 Aroclor 1221 BRL ug/Kg 80
1 1 1 41-1 6-5 Aroclor 1232 BRL ug/Kg 80
1 53469-21-9 Aroclor 1242 BRL ug/Kg 80
12672-29-6 Aroclor 1248 BRL ug/Kg 80
11097-69-1 Aroclor 1254 BRL ug/Kg 80
' 11096-82 5 Aroclor 1260 BRL ug/Kg 80
,.... . 4.. , , A imQG " ,GLu CmouS o
�.._
Tetrachloro-m-xylene 82 % 25-121 %
Decachlorobiphenyl 85 % 28- 138%
Metnoa Keterence: i est Metnoas tor tvaivaung Bona waste, u�p trA,Jw-64b, i nira taition, upaate m t 1 yyb!• Anaiyte ust
as Aroclor anaiytes tormeny specitiea oy trA metnoa twauA. Kesutts are reportea on a ary weignt oasis.
Kepo"Notations: 11KL maicates concentration, it any, is ae,ow reporting umn for anaiyte. Kepomng nm,t is the lowest
concentration tnat can oe reiiamy quantinea unaer routine iaooratory operating conaitions.
Keportmg limits are aajustea tor sample aiiution, percent moisture ana sample size.
Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532
GROUNDWATER
' ANALYTICAL
' Quality Control Report
Laboratory Control Sample
' Category: EPA Method 8100(Modified)
QC Batch ID: HF-1262-M
Matrix: Soil
Units: mg/Kg
a, w a
q � Analyte xr � k...... „ Measured Recovery.0141 f r rQC Ltmtts�
... rsr.;
�e
Fuel Oil No.2 130 110 82 % 60-140%
C Surr to Com....� ; Ltmtts °
wm wQ Po. Recoveryo :. M�,
ortho-Terphenyl 89 % 60-140
' Method Reference: Test Methods for Evaluating Solid Waste, US EPA,SW-846,Third Edition, Update III(1996). Analytical
protocol modified to quantify total petroleum hydrocarbons. Results are quantified on the basis
of 5a—androstane. Results are reported on a dry weight basis.
Report Notations: All calculations performed prior to rounding. Quality Control Limits are defined by the methodology,
or alternatively based upon the historical average recovery plus or minus three standard deviation units.
s
' Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532
' GROUNDWATER
ANALYTICAL
' Quality Control Report
Method Blank
Category: EPA Method 8100(Modified)
QC Batch ID: HF-1262-M
Matrix: Soil
rt
dd '>.�, m
on v
Analyte;` Ccentrations g
Total Petroleum Hydrocarbons BRL mg/Kg 60
�QCSurrogateCompoundf '_ Recovery " ;QClImits�
ortho-Terphenyl 85 % 60- 140 %
Method Reference: Test Methods for Evaluating Solid Waste, US EPA,SW-846,Third Edition, Update III(1996). Analytical
' protocol modified to quantify total petroleum hydrocarbons. Results are quantified on the basis
of 5a—androstane. Results are reported on a dry weight basis.
Report Notations: BRL Indicates concentration, if any, is below reporting limit for analyte. Reporting limit is the lowest
' concentration that can be reliably quantified under routine laboratory operating conditions.
Reporting limits are adjusted for sample dilution and sample size.
' Groundwater Analytical, Inc. P.O. Box 1200 228 Main Street Buzzards Ba MA 02532
Yt Y,
GROUNDWATER
ANALYTICAL
QUALITY ASSURANCE
' Laboratory Control Sample Recovery
' Category: Trace Metals
Matrix: Soil
Units: mg/Kg
' Laboratory Control Sample
SPIKE SPIKED PERCENT QC
ANALYTE BATCH ID ADDED RESULT RECOVERY LIMITS
Lead MM-0896-SLI 100 93 93 % 80-120
Quality Control Limits are defined by the methodology, or alternatively based upon the historical average
recovery plus or minus three standard deviation units.
GROUNDWATER
ANALYTICAL
QUALITY ASSURANCE
' Method Blank
' Category: Trace Metals
Matrix: Soil
' REPORTING EPA
PARAMETER CONCENTRATION LIMIT BATCH ID METHOD
(mg/Kg) (mg/Kg)
' Lead BRL 10 MM-0896-SB 6010
1
BRL = Below Reporting Limit. Method References: Test Methods for Evaluating Solid Waste, US EPA SW-846,
Third Edition (1986). Graphite Furnace analyses performed with Zeeman background correction and Lvov
platform technique.
7 -
GROUNDWATER
ANALYTICAL
' Certifications and Approvals
CONN EC-Ti CPT, Department'of"Health Services, PH-0586 `
_ ;.
Potable Water,Wastewater/Trade Waste,Sewage/Effluent,and Soil
pH,Conductivity,Acidity,Alkalinity,Hardness,Chloride,Fluoride,Ammonia,Kjeldahl Nitrogen,Nitrate,Nitrite,Orthophosphate,Total Dissolved
' Solids,Cyanide,Aluminum,Antimony,Arsenic,Barium,Beryllium,Cadmium,Total Chromium,Hexavalent Chromium,Cobalt,Copper,Iron,Lead,
Magnesium,Manganese,Mercury,Molybdenum,Nickel,Potassium,Selenium,Silver,Sodium,Thallium,Tin,Titanium,Vanadium,Zinc,Purgeable
Halocarbons,Purgeable Aromatics,Pesticides,PCBs,PCBs in Oil,Ethylene Dibromide,Phenols,Oil and Grease.
' MAINE;Department of"Human,Services;.,MA103
Drinking Water
Reciprocal certification in accordance with Massachusetts certification for drinking water analytes.
Waste Water
Reciprocal certification in accordance with Massachusetts certification for waste water analytes.
MASSACHUSETTS Department of Environmental Pr M-MA-103
Potable Water
Antimony,Arsenic,Barium,Beryllium,Cadmium,Chromium,Copper,Lead,Mercury,Nickel,Selenium,Thallium,Nitrate-N,Nitrite-N,Fluoride,
' Sodium,Sulfate,Cyanide,Turbidity,Residual Free Chlorine,Calcium,Total Alkalinity,Total Dissolved Solids,pH,Trihalomethanes,Volatile Organic
Compounds,1,2-Dibromoethane,1,2-Dibromo-3-chloropropane,Total Coliform,Fecal Coliform,Heterotrophic Plate Count,E-Coli
Non-Potable Water
' Aluminum,Antimony,Arsenic,Beryllium,Cadmium,Chromium,Cobalt,Copper,Iron,Lead,Manganese,Mercury,Molybdenum,Nickel,Selenium,
Silver,Strontium,Thallium,Titanium,Vanadium,Zinc,pH,Specific Conductance,Total Dissolved Solids,Total Hardness,Calcium,Magnesium,
Sodium,Potassium,Total Alkalinity,Chloride,Fluoride,Sulfate,Ammonia-N,Nitrate-N,Kjeldahl-N,Orthophosphate,Total Phosphorus,Chemical
Oxygen Demand,Biochemical Oxygen Demand,Total Cyanide,Non-Filterable Residue,Total Residual Chlorine,Oil and Grease,Total Phenolics,
Volatile Halocarbons,Volatile Aromatics,Chlordane,Aldrin,Dieldrin,DOD,DOE,DDT,Heptachlor,Heptachlor Epoxide,Polychlorinated
' Biphenyls(water),Polychlorinated Biphenyls(oil).
MICHIGAN, Department of Environmental Quality.
Drinking Water
' Trihalomethanes,Regulated and Unregulated Volatile Organic Compounds by EPA Method 524.2;1,2-Dibromoethane,1,2-Dibromo-3-
chloropropane by EPA Method 504.1
NEW,HAMPSHIRE Department of Environmental`Services, 202798 a
Drinking Water
Metals by Graphite Furnace,Metals by ICP,Mercury,Nitrite•N,Orthophosphate,Residual Free Chlorine,Turbidity,Total Filterable Residue,Calcium
Hardness,pH,Alkalinity,Sodium,Sulfate,Tota'I Cyanide,Insecticides,Herbicides,Base/Neutrals,Trihalomethanes,Volatile Organics,Vinyl
Chloride,DBCP,EDB,Nitrate-N.
Wastewater
' Metals by Graphite Furnace,Metals by ICP,Mercury,pH,Specific Conductivity,TDS,Total Hardness,Calcium,Magnesium,Sodium,Potassium,
Total Alkalinity,Chloride,Fluoride,Sulfate,Ammonia-N,Nitrate-N,Orthophosphate,TKN,Total Phosphorus,COD,BOD,Non-Filterable Residue,
Oil&Grease,Total Phenolics,Total Residual Chlorine,PCBs in Water,PCBs in Oil,Pesticides,Volatile Organics,Total Cyanide.
r
RHODE ISLANfD, Department of Health, 54�
Surface Water,Air,Wastewater, Potable Water,Sewage
Chemistry: Organic and Inorganic
1
' Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532
GROUNDWATER Groundwater Analytical,Inc.
P.O.Box 1200
ANALYTICAL 228 Main Street
Buzzards Bay,MA 02532
Telephone(508)759-4441
FAX(508)759-4475
January 14, 2000
i
' Ms. Kara Shumwa
Y
Bennett & O'Reilly, Inc.
P.O. Box 1667
Brewster, MA 02631
' Project: George/B099-2558
Lab I D: 30877
Sampled: 01-04-99
Dear Kara:
Enclosed is the Extractable Petroleum Hydrocarbons Analysis performed for the above referenced
project. This project was processed for Rush turnaround.
This letter authorizes the release of the analytical results, and should be considered a part of this
report. This report contains a project narrative indicating project changes and non-conformances, a
brief description of the Quality Assurance/Quality Control procedures employed by our laboratory,
and a statement of our state certifications.
I attest under the pains and penalties of perjury that, based upon my inquiry of those individuals
immediately responsible for obtaining the information, the material contained in this report is, to
the best of my knowledge and belief, accurate and complete.
Should you have any questions concerning this report, please do not hesitate to contact me.
Sincerely,
Jonathan R. Sanford
President
J RS/awc
Enclosures
I
GROUNDWATER
ANALYTICAL
' Massachusetts DEP EPH Method
Extractable Petroleum Hydrocarbons by GC/FID
Field ID: SWS:0-8' Laboratory ID: 31012-01
Project: George/B099-2558 QC Batch ID: EP-0833-M
Client: Bennett&O'Reilly Sampled: 01-04-00
Container: 250m1 Glass Received: 01-04-00
Preservation: Cool Extracted: 01-11-00
' Matrix: Soil Analyzed: 01-13-00
% Moisture: 11 Dilution Factor: Aliphatic: 1 Aromatic:1
Concentration', �„Units'.. Reporting 7L*=t
3
n-C9 to n-C18 Aliphatic Hydrocarbons BRL mg/Kg 32
' n-C19 to n-C36 Aliphatic Hydrocarbons 130 mg/Kg 32
n-C11 to n-C22 Aromatic Hydrocarbons 42 mg/Kg 32
Unadjusted n-C11 to n-C22 Aromatic Hydrocarbons r 43 mg/Kg 32
' "CAS-Number,. Target Analytes_, +°w; Concentration ; ,;, Units{• Reporting;limit
,, ".
91-20-3 Naphthalene BRL mg/Kg 0.54 .
91-57-6 2-Methyl naphthalene BRL mg/Kg 0.54
85-01-8 Phenanthrene BRL mg/Kg 0.54�
83-32-9 Acenaphthene BRL mg/Kg 0.54
208-96-8 Acenaphthylene BRL mg/Kg 0.54 j
' 86-73-7 Fluorene BRL mg/Kg 0.54
120-12-7 T7Tnthracene BRL mg/Kg 0.54
206-44-0 Fluoranthene BRL mg/Kg 0.54
129-00-0 Pyrene BRL mg/Kg 0.54
56-55-3 Benzo[a]anthracene BRL mg/Kg 0.54
218-01-9 Chrysene BRL mg/Kg 0.54
205-99-2 Benzo[b]fluoranthene BRL mg/Kg 0.54
' 207-08-9 Benzo[k]fluoranthene BRL mg/Kg 0.54
50-32-8 Benzo[a]pyrene BRL mg/Kg 0.54
193-39-5 Indeno[1,2,3-c,d]pyrene BRL mg/Kg 0.54
' 53-70-3 Dibenzo[a,h]anth race ne BRL mg/Kg 0.54
191 24-2 Benzo[g,h,i]perylene BRL mg/Kg 0.54
QC'Sur'rogate:Compounds Recovery., QC.Limits • ,,.
Fractionation: 2-Fluorobiphenyl 84 % 40- 140%
' 2-Bromonaphthalene 64 % 40- 140
Extraction: Chloro-octadecane 71 % 40- 140%
ortho-Terphenyl 77 % 40-140
�,.:QA/QG:Certification '. . ✓, f
1. Were all QA/QC{procedures required by the method followed? Yes
2. Were all performance/acceptance standards for the required QA/QC procedures achieved? Yes
' 3. Were any significant modifications made to the method,as specified in Section 11.3:1.1? Yes
Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative
and project quality control report. Release of this data is authorized by the accompanying signed project cover letter.
The accompanying cover letter,project narrative and quality control report are considered part of this data report.
' Method Reference: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998). Results are calculated
on a dry weight basis. Method modified by use of microwave accelerated solvent extraction technique.
Report Notations: BRL Indicates concentration, if any, is below reporting limit for analyte. Reporting limit is the lowest
concentration that can be reliably quantified under routine laboratory operating conditions.
Reporting limits are adjusted for sample dilution,percent moisture and sample size.
t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting it
that range.
' 0 n-C11 to n-C22 Aromatic Hydrocarbons range data excludes the method target analyte concentrations.
Groundwater Analytical,Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532
I -
GROUNDWATER
ANALYTICAL
Project Narrative
Project: George/13099-2558 Lab ID: 31012
' Client: Bennett&O'Reilly Received: 01-04-00
..,' A., Physical Condition..of'Sample(s)
This project was received by the laboratory in satisfactory condition. The sample(s) were received
undamaged in appropriate containers with the correct preservation.
B. Project Documentation..
This project was accompanied by satisfactory Chain of Custody documentation, with the following
ollowing
' amendment(s) or correction(s):
1. Project 31012 was processed for Rush Turnaround. The project was given a due date of 01-14-00,
per Kara Shumway, 01-11-00.
2. Sample 31012-01 was analyzed by MA DEP Method for the Determination of Extractable Petroleum
Hydrocarbons, per Kara Shumway, 01-11-00.
3. Sample 30877-03 was reassigned laboratory number 31012-01.
C. Analysis of Sample(s)
1
No analytical anomalies or non-conformances were noted by the laboratory during the processing of these
sample(s). All data contained within this report are released without qualification.
Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532
ov
' euuards Bay,Mno 532 CHAIN-OF-CUSTODY RECORD
ANALYTICAL TelepnDne(soa>759 seat AND WORK ORDER N" 39447
FAX 508)759 4475
roJeq Name: ,�^� Firm:
f�lf✓� V�IGL,�AS� TURNAROUND ANALYSIS REQUEST
❑STANDARD(10 Business Days) rd nRcss rsda ~� e¢ Gavel d""h► om.
ProAjec�t N bar: Address: >< ws"
PRIORITY(5 Business Days)
❑RUSH(RAN-
1 gg
Sampler Name: City/State/Zip: (Rush requires Rush Authonzation Number) n 0 0 0 f ❑ ❑
Please FAX YES ❑NO
FAX Number: o 0
Project Ma at: elt4phone: � lil-olio� BILLING
❑ 0 o �O ❑ s a
Purchase No.: GWA Reference No.: ❑ It
INSTRUCTIONS:Use separate inefor each container(except replicates). ta ta 3 I @ o ❑ 8 =
Sampling Matrix Pe Contalner(a) Preservation ntt.rra $ $ $ = - _
❑ ❑ ❑ ❑ ❑ ❑ ❑ ❑ ❑ ❑ o n ❑ _ 3 ❑SA PLE € S
IDENTIMICATION LABORATORY s q J1 ag ° t2
NUMBER
Lab a❑ ❑ ❑ ❑ ❑ ❑ ❑ o ❑7
v os ❑ ❑ ° ❑a B❑ ❑ o❑ ❑ S❑ ❑° ❑ ❑UseOnl
- e
_
-----------------
I _ i
---------------------------
-----------------
REMARKS/SPECIAL INSTRUCTIONS DATA QUALITY OBJECTIVES
CHAIN-OF-CUSTODY RECORD
Regulatory Program Project Specific OC
❑Safe Drinking Water Act NOTE:All samples submitted subject to Standard Terms and Conditions on reverse hereof.
❑MA DEP Form Many regulatory programs and EPA methods require project Re4 quished Sampler: Date Time R etved by: Receipt Temperature:
❑NPDES/Clean Water Act specific OC.Project Programs
OC includes Sample Duplicates, (� P
Sped State: Matrix Spikes,andlor Matrix Spike Duplicates.Laboratory OC is 1
h not project specific unless prearranged.Project specific OC
❑ CRA/P- Waste Char. samples are charged on a per sample basis.For water samples, Re§nW sh y: Date Time Received by: ou ShippinglAirbill
MA MCP(310 CMR 40) each MS,MSD and Sample Duplicate requires an additional U Number:
Reportable Concentrations sample aliquot.
❑RCGW-1):fRCS-1 Pro)eot Specific OC Required Selection of OC Semple mpaw;z
ate Time R by l.abo story: Custody Seal/
❑RCGW-2❑RCS-2❑MA C -) O Sample Duplicate ❑Selected h laborato / ' LCooler Serial
edgeDis sal 0MatrixSpike y rY �.?io -= ///' Number.
❑NH❑RI❑CT❑ME ❑Please,use sample: Method of i ment: WA Courier❑Express Mail❑Federal Express
Specify Category: G Matrix Spike Duplicate P P P
❑UPS ❑Hand❑
.30 77 -o3 6t�o��ca � 3)01 z -o 11 r�l� d{la
1
GROUNDWATER
ANALYTICAL
' Quality Assurance/Quality Control
A. 'Program Overview
Groundwater Analytical conducts an active Quality Assurance program to ensure the production of high
quality, valid data. This program closely follows the guidance provided by Interim Guidelines and
Specifications for Preparing Quality Assurance Project Plans, US EPA QAMS-005/80 (1980), and Test
Methods for Evaluating Solid Waste, US EPA, SW-846, Update III (1996).
' Quality Control protocols include written Standard Operating Procedures (SOPS) developed for each
analytical method. SOPS are derived from US EPA methodologies and other established references.
Standards are prepared from commercially obtained reference materials of certified purity, and documented
for traceability.
Quality Assessment protocols for most'organic analyses include a minimum of one laboratory control sample,
one method blank, one matrix spike sample, and one sample duplicate for each sample preparation batch.
' All samples, standards, blanks, laboratory control samples, matrix spikes and sample duplicates are spiked
with internal standards and surrogate compounds. All instrument sequences begin with an initial calibration
verification standard and a blank; and excepting GUMS sequences, all sequences close with a continuing
calibration standard. GUMS systems are tuned to appropriate ion abundance criteria daily, or for each 12
hour operating period, whichever is more frequent.
Quality Assessment protocols for most inorganic analyses include a minimum of one laboratory control
sample, one method blank, one matrix spike sample, and one sample duplicate for each sample preparation
batch. Standard curves are derived from one reagent blank and four concentration levels. Curve validity is
verified by standard recoveries within plus or minus ten percent of the curve.
' B. Definitions
' Batches are used as the basic unit for Quality Assessment. A Batch is defined as twenty or fewer samples of
the same matrix which are prepared together for the same analysis, using the same lots of reagents and the
same techniques or manipulations, all within the same continuum of time, up to but not exceeding 24 hours.
' Laboratory Control Samples are used to assess the accuracy of the analytical method. A Laboratory Control
Sample consists of reagent water or sodium sulfate spiked with a group of target analytes representative of the
M method analytes. Accuracy is defined as the degree of agreement of the measured value with the true or
expected value. Percent Recoveries for the Laboratory Control Samples are calculated to assess accuracy.
Method Blanks are used to assess the level of contamination present in the analytical system. Method Blanks
consist of reagent water or an aliquot of sodium sulfate. Method Blanks are taken through all the appropriate
' steps of an analytical method. Sample data reported is not corrected for blank contamination.
Surrogate Compounds are used to assess the effectiveness of an analytical method in dealing with each
' sample.matrix. Surrogate Compounds are organic compounds which are similar to the target analytes of
interest in chemical behavior, but which are not normally found in environmental samples. Percent
Recoveries are calculated for each Surrogate Compound.
' Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532
L�_
1 GROUNDWATER
ANALYTICAL
Quality Control Report
Laboratory Control Sample
' Category: MA DEP EPH Method
QC Batch ID: EP-0833-M
Matrix: Soil
Units: mg/Kg
CAS`Number_ Anal . e" ro�:x ��. Y."=:S eked .Measured ,
yt p' Recovery~ � ,.QC�Eimits"=�r
111-84-2 n-Nonane(C9) 5.0 2.0 41 % 40- 140%
629-59-4 n-Tetradecane(C14) 5.0 3.2 65 % 40- 140 %
629-92-5 n-Nonadecane(C19) 5.0 3.4 68% 40-140
112-95-8 n-Eicosane(C20) 5.0 3.4 69% 40-140 %
630-02-4 n-Octacosane(C28) 5.0 3.4 68% 40- 140 %
91-20-3 Naphthalene 5.0 3.1 63 % 40-140 %
83-32-9 Acenaphthene 5.0 3.6 71 % 40-140 %
120-12-7 Anthracene 5.0 3.9 _ 77% 4 0
129-00-0 ; Pyrene _ 5.0 4.1 j 81 % 40- 140%
' 218-01-9 Chrysene 5.0 4.2 1_ 84% 40-140
:QC Surrogate:'Compounds , >.Recovery y' QC Luriiis4;: r
Fractionation: 2-Fluorobiphenyl 82 % ' 40- 140%
' 2-13romonaphthalene 72 % _ 40- 140%
Extraction: Chloro-octadecane 62 % 40- 140%
ortho-Terphenyl 80 % 40- 140% _J
' Method Reference: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998).
Report Notations: All calculations performed prior to rounding..Quality Control Limits are defined by the methodology,
or alternatively based upon the historical average recovery plus or minus three standard deviation units.
M
Ii
1
1 Groundwater Analytical, Inc. P.O. Box 1200 228 Main Street Buzzards Bay
,.y,.MA 02532
GROUNDWATER
' ANALYTICAL
Quality Control Report
Method Blank
Category: MA DEP EPH Method
QC Batch ID: EP-0833-M
Matrix: Soil
EPH.Ranges Concentration Units' Reporting,Cimit
n-C9 to n-C18 Aliphatic Hydrocarbons BRL mg/Kg 30
n-C19 to n-C36 Aliphatic Hydrocarbons BRL mg/Kg 30
n-C11 to n-C22 Aromatic Hydrocarbons BRL mg/Kg 30
' Unadjusted n-C11 to n-C22 Aromatic Hydrocarbons f BRL mg/Kg 30
CAS`Number =''-TargetAnalytes w= _., " •• ,.Concentration -., ., M. - Units [Reporting Limit
' 91-20-3 Naphthalene BRL mg/Kg 0.50
91-57-6 2-Methyl naphthalene BRL mg/Kg 0.50
85-01-8 ( Phenanthrene _ BRL mg/Kg 1 0.50 j
83-32-9 ( Acenaphthene _ _ BRL _ mg/Kg 0.50
208-96-8 Acenaphthylene BRL mg/Kg 0.50
86-73-7 Fluorene BRL mg/Kg 0.50
120-12-7 Anthracene BRL mg/Kg 0.50
206-44-0 Fluoranthene _ BRL _ mg/Kg 0.50
129-00-0 Pyrene BRL mg/Kg 0.50
56-55-3 Benzo[a]anthracene BRL mg/Kg 0.50
218-01-9 Chrysene _ BRL mg/Kg 0.50
' 205-99-2 Benzo[b]fluoranthene BRL mg/Kg j 0.50
207-08-9 Benzo[k]fluoranthene BRL mg/Kg 0.50 j
j 50-32-8 Benzo[a]pyrene _ BRL I mg/Kg_ 0.50
193-39-5 Indeno[1,2,3-c,d]pyrene BRL mg/Kg 0.50
53- 00-3 Dibenzo[a,h]anthracene BRL mg/Kg 0.50
191- 44-2 Benzo[g,h,i]perylene BRL �_ mg/Kg 0.50
QC`Surrogate Compounds Recovery ;;`QG Limits
' Fractionation: 2-Fluorobiphenyl 82 % 40-140%
2-13romonaphthalene 75 % 40- 140%
Extraction: Chloro-octadecane 58 % 40- 140%
ortho-Terphenyl 82 % 40-140 %
Method Reference: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998).
' Report Notations: BRL Indicates concentration, if any, is below reporting limit for analyte. Reporting limit is the lowest
concentration that can be reliably quantified under routine laboratory operating conditions.
Reporting limits are adjusted for sample dilution,percent moisture and sample size.
t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting it
' that range.
0 n-C11 to n-C22 Aromatic Hydrocarbons range data excludes the method target analyte concentrations.
' B 2
Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards ay, MA 0253
i
GROUNDWATER
' ANALYTICAL
tCertifications and Approvals
' CONNECTICUT, Department of'Health Services,. PH-0586
Potable Water,Wastewater/Trade Waste,Sewage/Effluent,and Soil
pH,Conductivity,Acidity,Alkalinity,Hardness,Chloride,Fluoride,Ammonia,Kjeldahl Nitrogen,Nitrate,Nitrite,Orthophosphate,Total Dissolved
Solids,Cyanide,Aluminum,Antimony,Arsenic,Barium,Beryllium,Cadmium,Total Chromium,Hexavalent Chromium,Cobalt,Copper,Iron,Lead,
Magnesium,Manganese,Mercury,Molybdenum,Nickel,Potassium,Selenium,Silver,Sodium,Thallium,Tin,Titanium,Vanadium,Zinc,Purgeable
Halocarbons,Purgeable Aromatics,Pesticides,PCBs,PCBs in Oil,Ethylene Dibromide,Phenols,Oil and Grease.
MAINE,.,Department of Human Services,.-MA103
Drinking Water
Reciprocal certification in accordance with Massachusetts certification for drinking water analytes.
' Waste Water
Reciprocal certification in accordance with Massachusetts certification for waste water analytes.
MASSACHUSETTS; Department of Environmental Protection, M-MA-103
Potable Water
Antimony,Arsenic,Barium,Beryllium,Cadmium,Chromium,Copper,Lead,Mercury,Nickel,Selenium,Thallium,Nitrate-N,Nitrite•N,Fluoride,
Sodium,Sulfate,Cyanide,Turbidity,Residual Free Chlorine,Calcium,Total Alkalinity,Total Dissolved Solids,pH,Trihalomethanes,Volatile Organic
Compounds,1,2-Dibromoethane,1,2-Dibromo-3chloropropane,Total Coliform,Fecal Coliform,Heterotrophic Plate Count,E-Coli
Non-Potable Water
' Aluminum,Antimony,Arsenic,Beryllium,Cadmium,Chromium,Cobalt,Copper,Iron,Lead,Manganese,Mercury,Molybdenum,Nickel,Selenium,
Silver,Strontium,Thallium,Titanium,Vanadium,Zinc,pH,Specific Conductance,Total Dissolved Solids,Total Hardness,Calcium,Magnesium,
Sodium,Potassium,Total Alkalinity,Chloride,Fluoride,Sulfate,Ammonia-N,Nitrate-N,Kjeldahl-N,Orthophosphate,Total Phosphorus,Chemical
Oxygen Demand,Biochemical Oxygen Demand,Total Cyanide,Non-Filterable Residue,Total Residual Chlorine,Oil and Grease,Total Phenolics,
Volatile Halocarbons,Volatile Aromatics,Chlordane,Aldrin,Dieldrin,DDD,DDE,CDT,Heptachlor,Heptachlor Epoxide,Polychlorinated
' Biphenyls(water),Polychlorinated Biphenyls(oil). --
MICHIGAN,.Department of Environmental Quality
' Drinking Water
Trihalomethanes,Regulated and Unregulated Volatile Organic Compounds by EPA Method 524.2;1,2-Dibromoethane,1,2-Dibromo-3-
chloropropane by EPA Method 504.1
' NEW HAMPSHIRE' Department of Environmental Services, 202798
Drinking Water
Metals by Graphite Furnace,Metals by ICP,Mercury,Nitrite-N,Orthophosphate,Residual Free Chlorine,Turbidity,Total Filterable Residue,Calcium
Hardness,pH,Alkalinity,Sodium,Sulfate,Total Cyanide,Insecticides,Herbicides,Base/Neutrals,Trihalomethanes,Volatile Organics,Vinyl
Chloride,DBCP,EDB,Nitrate-N.
Wastewater
Metals by Graphite Furnace,Metals by ICP,Mercury,pH,Specific Conductivity,TDS,Total Hardness,Calcium,Magnesium,Sodium,Potassium,
Total Alkalinity,Chloride,Fluoride,Sulfate,Ammonia-N,Nitrate-N,Orthophosphate,TKN,Total Phosphorus,COD,BOD,Non-Filterable Residue,
Oil&Grease,Total Phenolics,Total Residual Chlorine,PCBs in Water,PCBs in Oil,Pesticides,Volatile Organics,Total Cyanide.
' RHODE ISLAND,,Department of Health,54
Surface Water,Air,Wastewater, Potable Water,Sewage
' Chemistry: Organic and Inorganic
Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532