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0686 IYANNOUGH ROAD/RTE 28 - Health (2)
686A RD. /RT. 132,HYANNIS r nn dv _.. _ I u f i TOWN OF BARNSTABLE BAR-W 4532 Ordinance or Regulation WARNING NOTICE Name of Offender/Manager SCo�'� eve-e-k Address of Offender $r'O �n4y�i►w 9 /l /Zvi MV/MB Reg.# Village/State/Zip LY�v`� g 1K ©2-(0 Business Name 16Go+t-i 'L'5 CJ5ioaL, Ao--e _____ 10'00 pm, o // Zo 20 i3 Business Address (o3 C, A,r, Signature . nforcing Office Village/State/Zip oy'uNv►c s, } e)2(' ! Location of Offense Enforcing. Dept/Division Offense o V0 a� a,V\_ �,A, 0 Ma'��C,AAS (ie-e A4 ovL aLca��ar�e4�' Facts co I w� This will serve only as a warning. A this time no legal action has been taken. It is the goal of Town agencies to achieve voluntary compliance of Town Ordinances, Rules and Regulations. Education efforts and warning notices are [attempts to gain voluntary compliance. Subsequent violations will result in It legal action by the Town. WHITE-OFFENDER CANARY-ORD./REG.-PROG. PINK-ENFORCING OFFICER GOLD-ENFORCING DEPT. Town of Barnstable Hazardous Materials On-Site Inventory and Inspection FACILITY INFORMATION: Business Name: ;; 4Cc V 0L/C.S W,4 �-� Business Location: 16'f(� yi4�y td®ll��t/ &P. �yi�i�1N�S Mailing Address: A+-1-30VW- Telephone Number: 57,f Contact Person: �/fv�� Emergency Contact Telephone Number: Type of Business: / "70 HAZARDOUS MATERIALS (CHAPTER 108) Virgin Product Total Quantity Container Size(s) Storage Location Major Materials Gallons or Pounds Quarts,gallons, Shed,retail store, drums,tank,etc... cabinet,closet,etc I 6-OQ 6h"W,460v-- VVV C?/��E 04Y `� r 57v ��0/1 V W 5 fbc kS WIN&Wlab (/)/7_1-GAzaaAJ Wlf5 A�:Lui' 4Att_L0/JS P"dM_ .W-,,Vl( ®ter 6.+41-ors e0,fJ7 farG72s 1.u461V1661 t-z- ;)4RTS %P.�N�iy/SS✓o,��ur0 ��Z ��v�s Cd�uT4�,�t'�S �..�. /C UZI�t/C� �,4re rS 1-- v cr^1-0,Us CaN fu s CP7 C,+,v5 A-NA ,04#t- 5 PA L 7DOL 7W67ily "IbuAD �fCt-1y:4t1�cJS �ivCi4-AJ9 O;vE �i4cS� y - 1 - Misc. Combustibles Misc. Corrosives Misc.Reactive Misc.Toxics Inventory Total Amount: t�/O lV PovNoS Hazardous Materials License Posted es No Contingency Plan Posted? Yes 0 Fire District: YA-AI IS Fire Extinguisher Service Date: 4Low-ago Metal Covered Rag Bin: 6) No Absorbent Material Available? es No Type of Absorbent: Speedy Dry ads Pigs Other: MSDS on site? es No Hard Cop Computer Access Hazardous Waste Handling Hazardous Waste Generator Identification Number: X 4f-b 6 413�10 Types) of hazardous waste product(s): 14� , tic �t/.I7Z /.rTlt 0/4-VIA-5 rc Date of last haz dous waste shipment,type of waste and quantity: , /6, .Z0/k- 6/t/144JVfS - G Hazardous Waste Transporter(s): � ,4��'t� J C-�i�J 0" Designated Hazardous Waste Facility: 57PZI4h"A Hazardous Waste Storage Area Description: If/--'�O v 4-'QV1t AJ© ZaLAA1 1N Gu1Y,yt-2 fJG 4A-XAJ E" /3Ai OAJ d0 N CA&-&C' Is hazardous waste storage area labeled:C9 No Are tanks/drums/containers labeled with the words "Hazardous Waste",the type of waste and the associated hazard (i.e. ignitable,corrosive,reactive or toxic)0 No If hazardous waste is stored out of doors is it covered from the elements? Yes No Is it in 110% containment? Yes No A//A If hazardous waste is stored indoors is it on an impervious floor es No - 2 - 4 • Jr FLOOR DRAINS (Chapter 381) Town Sewer Account Number: Indoor floor drains: No If yes,circle one,does it discharge to a: holding tank d well on site septic. lb 01,VAI -fur— r i-�� r' -5' 6'V C60 �N '�� a 4Mb - rY p 4ub1 (i,,#&4cE BAY) Outdoor surface drains: Yes No If yes,circle one,does it discharge to a: holding tank dry well on site septic. FUEL AND CHEMICAL STORAGE TANKS (Chapter 326) Underground Storage.Tank(s) on site? Yes Age: Is removal required? Yes No If yes,when? Is testing required? Yes No If yes,when? Out of doors above ground storage tank on site? Yes o If yes,is it protected from the elements? Yes No If yes,how? Is it on a foundation larger in size than the tank? Yes No COMMENTS/RECOMMENDATIONS/CORRECTIVE ACTIONS 45 84A / RIS6D Cr- gOTf/ 77fE Vb L-&J W.4 4&—IJ .4&4!� +Ubl e4-POW& 6 -DES Awl) A i v.4,yll .s oAc7p+ZZI i tl A- G/�A-.o �AJb OielJ429W ,414-1VAI&IF. �Ao k,-601--e"E2d-+770A S fT 77&,S 771-e& I, Public Health Inspector: Facility Representative: - 3 - I P 0 Date: TOWN OF BARNSTABLE TOXIC AND HAZARDOUS MATERIALS ON-SITE INVENTORY NAME OF BUSINESS: -7;?_A� Va KS WA G" BUSINESS LOCATION: 61 1i AW 0 AJ J/.S INVENTORY MAILING ADDRESS: o✓E TOTAL AMOUNT: TELEPHONE NUMBER: J4",0d'-- 30 L CONTACT PERSON: -76H i✓16 De, EMERGENCY CONTACT TELEPHONE NUMBER: MSDS ON SITE? TYPE OF BUSINESS: 4U TU YES INFORMATION/RECOM MEN DATIONS:SPIu.- 4-yewst=r# Fire District: srX-nonJ VAI SI rE_ EX 771U4U1SWCr_s' up ra 8As S &C l AA1b 1711,S , ,V3PCC770Ai /N&-ab D &ipTw 1/ot-sty_—N A-db Aaw �?c��r�2 G4�cES • 22�� AdeC— 7E .�s 6.v� Waste Transportation: Last shipment of hazardouswaste: Name of Haule C ©c Destination: A Waste Product: a Licensed? es o NOTE: Under the provisions of Ch. 111, Section 31, of the General Laws of MA, hazardous materials use, storage and disposal of 111 gallons or more a month requires a license from the Public Health Division. LIST OF TOXIC AND HAZARDOUS MATERIALS The Board of Health and the Public Health Division have determined that the following products exhibit toxic or hazardous characteristics and must be registered regardless of volume. Observed/Maximum Observed/Maximum Antifreeze (for gasoline or coolant systems) Misc. Corrosive 0 NEW BUSED Cesspool cleaners 5 S Automatic transmission fluid Disinfectants Engine and radiator flushes Road Salts (Halite) Hydraulic fluid (including brake fluid) Refrigerants Motor Oils (7J5-064At USA Pesticides NEW 6-n USED (insecticides, herbicides, rodenticides) God. 4tSt7� OIL Gasoline, Jet fuel, Aviation gas Photochemicals (Fixers) Diesel Fuel, kerosene, #2 heating oil NEW USED vL26Misc. petroleum products: grease, Photochemicals (Developer) lubricants, gear oil NEW USED Degreasers for engines and metal Printing ink Degreasers for driveways &garages Wood preservatives (creosote) Caulk/Grout Swimming pool chlorine Battery acid (electroly /Batteries Lye or caustic soda Rustproofers Misc. Combustible 2)SS—GkC-haeu.tif s � 41 Car wash detergents /� �uDr �,i},�,44E Leather dyes Car waxes and polishes s Yop(3) / 6A(- Fertilizers Asphalt & roofing tar o�rz� PCB's Paints, varnishes, stains, dyes Other chlorinated hydrocarbons, Lacquer thinners (inc. carbon tetrachloride) NEW USED _Any other-products with "poison" labels- Paint &varnish removers, deglossers (including chloroform, formaldehyde, Misc. Flammables ,q&7eosoc-�,vs o` f&u:-7t-u&-Xs /w p4,n-� hydrochloric acid, other acids) D -Pr: Floor&furniture strippers Other products not listed which you feel Metal polishes cry y� toxic or s�a us (please list): Laundry soil & stain removers (including bleach) OLA 51e-?_-Z PARRS A-Alb TlRcs A-rz,— o�e_L. Spot removers &cl ning fl 'ds ,QcGyG�E� (dry cleaners � �°� 4&U"uS PA-RTS CeEkAJ X /5 6A) 5 i/-r- Other cleaning solvents -/k/Am 7Aj A-t1 46 fjt"nai2Tz-D( Bug and tar removers pISc/,F-4142 9 70 4 T/tMK P�%o/2 r� 7h E s" e Windshield wash{AAL.Lv t IAI v TD rr4IAIOl.f /��7Ar� !3 bis� /d WHITE COPY-HEALTH DEPARTMENT/CANARY COPY BUS MAP. PURp� gY 6(-uEw*1�4�• �Ua- 03 - G�S/S M Town of Barnstable OF THE r, Regulatory Services Thomas F. Geiler,Director Public Health Division * BARNSTABLE, * Thomas McKean,Director �00 639. ��� 200 Main Street, Hyannis,MA 02601 ArFD MA'l�" Phone: 508-862-4644 Email: healthQtown.bamstable.ma.us Fax: 508-790-6304 Office Hours: M-F 8:00—4:30 March 5, 2007 Mr. John Medeiros Tracy Volkswagen 686 Iyannough Road Hyannis, MA 02601 Dear Mr. Medeiros: Thank you for your time and cooperation during the hazardous materials inventory and site visit at Tracy Audi on January 31, 2007. This letter contains information from that visit that will help you become compliant and remain compliant with Chapter 108 of the Town of Barnstable Ordinance: Hazardous Materials. Enclosed are copies of the Chapter 108: Hazardous.Materials ordinance and a copy of the Toxic and Hazardous Materials On-Site Inventory form from the visit. Please note the observations identified at your place of business during the hazardous materials inspection listed below: OBSERVATIONS: • New oil and waste oil tanks on site. The 500 gallon tanks are upright—allowing more space and a cleaner facility. • Fire extinguishers in the facility need to be serviced. . • Metal cans with lids are available for soiled rags. • Oil filters are stored in two 55 gallon drums. • Vehicle washing facility is hooked into an oil water separator. On Site Inventory Total The Toxic and Hazardous Materials On-Site Inventory from January 31, 2007 shows that you have approximately 1,752 gallons of toxic and hazardous materials being used, stored, generated and disposed of at Tracy Volkswagen, 686 Iyannough Road,Hyannis,MA(Please see enclosed Toxic and Hazardous Materials On Site Inventory sheet). If you have any questions about these problems,the orders and recommendations, or you need further information, guidance or assistance,please do not hesitate to contact the Public Health Division. f Sincerely, �J& Alisha.L. Parker Hazardous Materials Specialist All orders to correct violations of Chapter 108 of the Town of Barnstable Ordinance: Hazardous Materials shall be completedupon receipt of this letter. Thomas A. McKean,RS, CHO Director of Public Health Enc. Chapter 108 (copy) On-Site Inventory(copy) f ' HAZARD COMMUNICATION PROGRAM 'RACY VOLKSWAGEN 686 Iyanough Road, Route 132 Hyannis, MA 02601 508-775�3049 C _ I • t ' i COMPANY POLICY The purpose of this notice is to inform you that our company is complying with the OSHA Hazard Communication Standard, Title 29 Code of Federal Regulations 1910.1200 and the Massachusetts Right-To-Know Law Section 11, Chapter 111 F, M.G.L., by compiling a hazardous chemical list, by using MSDS's, by ensuring that containers are labeled, and b providing y p g you with training. This program applies to all work operations in our company where you may be exposed to hazardous substances under normal working conditions or during an emergency situation. Under this ro ram you will be inform f p g , y informed o the contents of the Hazard Communication Standard and the Right-To-Know Law, the hazardous properties of chemicals with which you work, safe handling procedures, and measures to take to protect yourselves from these chemicals. You will also be informed of hazards associated with non- routine tasks, and hazards associated with chemicals in unlabeled pipes. Copies of the written program and MSDS's may be obtained from the program coordinator, who,has overall responsibility for the program. The Program Coordinator is John Mederios. INTRODUCTION On July 4, 1966, the Freedom of.Information Act addresses the facts to ensure that safety was signed into law for all citizens of the United aspects of handling chemicals are evaluated. States. This act was the forerunner of several The law is to ensure that this information is laws that were passed in recent years making available to employers and employees. information available to the public except where The Hazard Communication Standard allows an individual's right to privacy would be violated you to get information about hazardous or when confidential business is involved. chemicals. Your employer provides safety In 1970,the Occupational Safety and Health equipment and information so that you can take Act was passed by the U.S. Congress to assure all the necessary steps to protect yourself safe and healthful working conditions for working against exposure. You are responsible for your men and women. More recently, a new law was own safety and protection as well as those passed requiring employers to provide around you. The purpose of the standard is to information about potential hazardous chemicals establish uniform requirements to make sure that to the people who handle them in the workplace. the hazards of all chemicals produced, imported, This law is called the Hazard Communication or used within the United States are evaluated Standard . and that this information is transmitted to the The understanding of these laws provides you people who use them. and your community the opportunity to learn It is important that everyone who works with or about the nature of substances that you may comes in contact with chemicals be provided. E become exposed to. proper training.This training is required as part of Think for a moment about the tens of the Hazard Communication Standard. thousands of chemicals and the millions of As part of the training program,this manual will chemical mixtures in use today. Many have been provide you with information for dealing with, '- around for a long time and will continue to be chemicals.The manual will identify sources of. used for a long time. People have worked with information about the chemicals you may come chemicals and chemical substances safely for . in contact with, ways to reduce or eliminate risks centuries. Used safely and sensibly, chemicals to chemical exposure, and methods of and modern chemistry are a gift to us all. controlling exposure to chemical hazards: Synthetic fibers for clothes that won't wrinkle, The text of the law and this manual include chlorine to purify our drinking water, chemicals certain key words that are listed in the Appendix. -- for our health and welfare such as aspirin-all are This glossary will help you understand all of the chemical compounds. information that is available to you. The law does not restrict or ban the use of any substance whether it is hazardous or toxic, but EMPLOYEE RIGHTS UNDER EMPLOYEE TRAINING THE LAW Tracy Volkswagen in its interest of employee health and safety has developed a training The Hazard Communication Standard extends to program. anyone who works for an employer on or after The training program will be presented on your the law's effective date, Nov. 25, 1986. starting date of employment. When new Management-level employees, independent information is received, you will be given this contractors, government employees, as well as data as quickly as possible. plant personnel are covered under the law. All employees will be trained before their initial These rights are permanent even if the assignment to work with a hazardous chemical employee leaves the job. Each state may have and whenever a new hazard is introduced. its own version, as a rewrite, of the federal Right- The training program, as an integral part of to-Know law.Therefore, it is advisable to consult Tracy Volkswagen's on-going safety concerns, on the specifics of your local requirements. will include the following important information: *Summary of the standard and this written RIGHTS THE LAW GRANTS TO program. EMPLOYEES ' Chemical names of listed chemicals used and the place in the facility where normally kept or As an employee, you have the following rights: used. *The Right to certain kinds of information about *Chemical and physical properties of hazardous ; specific health and safety aspects of materials(e.g..flash point, reactivity)and chemicals you handle or are exposed to in methods that can be used to detect the the workplace.This information can be in presence or release of chemicals. written or oral form but should be in a * Work procedures to follow to assure protection language that is generally in nontechnical when dealing with hazardous chemical spills .. terms and understandable to those employed and leaks. in this industry.The information must contain: "A review of the toxic or hazardous conditions a)container labels of these chemicals(HMIS-ID system). b)on-the-job training *Explanation of the Material Safety Data Sheets c)Material Safety Data Sheets(MSDS) (MSDS)and how they relate to your safety in the workplace. *The Right,as an incapacitated employee, to * Health hazards, including signs and symptons - have a third party exercise your rights under of exposure, associated with exposure to the law.This designated representative may chemicals and any medical condition known to be a spouse,guardian, executor,or certified be aggravated by exposure to the chemical union agent. Your physician, under certain * Information and proper use and maintenance - conditions, may obtain information on your of safety and personal protection equipment behalf. required. Information on first aid procedures, and The Right to examine any Material Safety Data emergency response. Sheet(MSDS)upon request. The Material ' Explanation of chemical substances in special Safety Data Sheets must be readily accessible categories: to you or be shown that diligent efforts have a)flammable(NFPA) e) poison been made to obtain the Material Safety Data b)corrosive f)carcinogen Sheet(MSDS)from the supplier of the c)oxidizer g) mutagen chemical. When employees must travel d)explosive h) teratogen between workplaces during the shift, they are i) neurotoxin to have access to the MSDS'prior to leaving * Information and explanation of container labels the primary worksite, and when they return. and how they provide safe working conditions.. The Right to be free of discrimination or We will maintain a central file of all of the above retaliation for exercising your rights under the information for your review.This file will be law. revised and updated as any new information is obtained. If knowledge is obtained that unlawful discrimination has taken place,you may file a complaint with the U.S. Department of Labor, Occupational Safety and Health Administration. NON ROUTINE TASKS OUTSIDE CONTRACTORS Occasional or"non routine tasks"are jobs that John.Mederios will be responsible for providing are outside of your normal work scope and information to Outside Contractors. Such training. Training for these tasks will be provided information will include a briefing on the by John Mederios or a trained and experienced HAZARD COMMUNICATION STANDARD as co-worker whom John assigns to work with you. presented in this written program, hazardous This type of training is normally given orally and materials and processes on site, applicable involves on the job instruction. Instruction on company safety procedures and the location of more complex non routine tasks requiring safety equipment and Material Safety Data detailed procedures may be provided in a written Sheets. form. When appropriate or upon request John, or his representative, will also provide copies of written This information will include: procedures such as'this written program, the 'Specific hazards Lock Out/Tag Out Procedure and appropriate Protective and safety measures the employee Material Safety Data Sheets. can take Following this briefing the Outside Contractor *Measures we have taken to lessen the hazard will be required to complete a copy of the acknowledgment form provided on the next Example of non-routine task of an employee of page. this company: TASK: Applying surface coating to concrete floor TOXIC AND HAZARDOUS SUBSTANCES: Two Part Epoxy Floor Coating . OUTSIDE CONTRACTOR INFORMATION ACKNOWLEDGMENT FORM I, (name)of (company) acknowledge that (host company)provided information on chemical safety as required by the Hazard Communication Standard on , 20 This information included; review of this requirement of-the Hazard Communication Law; review of MSDS'for inventoried;regulated substances; information on the proper handling and potential exposure to inventoried and regulated substances. (name) (title) I m I w . f LABELING * U.S. Department of Transportation(DOT) regulations applicable to hazardous transported in interstate substances trans All questions regarding container p labeling can be directed to John commerce; Medeiros, or his designee, who is *the Federal Insecticide, Fungicide, and responsible for all in-coming containers Rodenticide Act as applicable to pesticides; and all secondary containers (those ' the Atomic Energy Act; containers other than the original). *the Food, Drug, and Cosmetic Act. WHAT MUST BE LABELED FORMAT OF LABELS Any material that contains one percent of a listed Labels should be legible, in English, unless substance(two percent if present.as an impurity) otherwise specified, and in a visible.location on must be labeled. the container. Labels must be weatherproof if the container The Hazard Communication Standard requires will be exposed to outside conditions. that manufacturers, importers, and distributors Labels must be in boldface letters on a label each chemical when it leaves their control. _ distinctly contrasting background. The labels must include the identity of the chemical, appropriate hazard warnings(including routes of entry), and the name and address of NFPA (NATIONAL FIRE PROTECTION the manufacturer or importer. ASSOCIATION) CODES Labeling is also required of employers covered The NFPA codes are an approved method of by the standard, as follows rating the hazard level of chemicals.This provides an easy way to identify the hazardous CONTENT OF LABELS properties of the chemical under normal and emergency situations. The code, using a four- All required labels must show the following color, diamond-shaped symbol, has numbers information:Chemical name, NFPA code(if from zero through four and specific hazard published), and must bear the letters "C,"limit, identification abbreviations. Each color has a "T", or"N"if the substance is classified by the special hazard meaning:red at the top(fire), Department of Health as a carcinogen, mutagen, yellow(reactivity), white(specific hazard), blue teratogen, or neurotoxin. The routes of entry (health)with the level of the hazard, indicated by'. and target organs are also required. a number from zero to four, printed in the color box referring to the type of hazard. Containers should be considered to include all The general meaning of the numbers is shown pipes, stationary containers, and every type of in the label on the next page. portable device. Tanks, drums, bags, boxes, bottles; and every type of containment should be included in the labeling process. EXCEPTIONS TO LABEL REQUIREMENTS Exceptions include transfer containers of less than 10 gallons or 15 pounds intended for immediate use by that employee making the transfer(It is advisable, though,to label con- tainers for immediate use to avoid any problems if the employee is distracted for any reason and puts the container down without a label. This can cause a problem for those in the surrounding areas)and containers that are already labeled pursuant to certain federal requirements, specifically: HMIS and MFPA labels also include letters and/or symbols a— � to designate the types of personal protective equipment 2 v200F employees must use when handling chemicals.. Vffi � �j - ems®F It is the responsibility of each employee to heed the f z ° '° ' warnings and use any and all protective equipment that is � arF r. y indicated. j5'M1 § The chart below explains-the symbols related to each > rt letter: y. 4 A ,1 ara�a aRc R BI S XWh" oX`J 3— aged h�8 fir® Add " '.. aaRry GLOOM A&MAfllC 2o1rti MR . i Radiaffo ft wars ®� t� HMIS CODE The HMIS--Hazard Materials Identification System—label is ra rectangular in shape and comes in a number of formats. in urr.k G vra P arIX.i all cases, the label includes three colors of bands to identify different hazards. The colors correspond to the NFPA (National Fire Protection Associations) standards noted- above: blue means a health hazard; red means a fire a� ou3r�.T hazard, and yellow means a reactivity hazard. The label also includes space for the name of the hazardous material and the type of protective equipment necessary. For each type of hazard,manufacturers must also indicate e.Of araim amaa cu-rrmff the degree of hazard for each material. The numbers usedu�" to denote this degree also correspond to NFPA standards: ° • 0 means minimal hazard, 9,2tFM 1 means slight hazard, z2 means moderate hazard, G Galf �R • 3 means serious hazard, and - 4 means severe hazard. & M1.1 ry A sample of one label format is shown below: C Equ_jM, a Pl:�,ma GO 1 - , &ArlV GW^JE aa'rV2FII'1 t _ }ram y ryu �y P at e t Y �rale [w �'V , J�eS . '�'� F 1 S s �& &7FErr elSgiSc9 11Pi,.!'it aU97f�P3aa' Ke.M 2 ra gg- - - % UM M10 yCTIVIT EA X7 JAO'k YOUT supervoum f0F ap@cl2l laanr�flr 0 f j°'� PERSONAL PROTECTION . HEALTH HAZARD FIRE HAZARD 4-DEADLY (FLASH POINTS' 3-EXTREME DANGER 4-BELOW 73"F 2-DANGEROUS 3-BELOW 100°F 1-SLIGHT HAZARD 2-BELOW 200°F 0-NO HAZARD „ z 1 -ABOVE 200°F SAE^. 0-WILL NOT BURN r .w HAZARD SPECIAL HAZARD �� REACTIVITY W-WATER REACTIVE 4*MAY DETONATE OX-OXIDIZER 3-EXPLOSIVE -RADIOACTIVE 2-UNSTABLE CIA=CORROSIVE 1-NORMALLY STABLE ACD-ACID 0-STABLE ALK-ALKALI SPECIFIC PRODUCT IMFORMATION (EFFECTS.OF EXPOSURE) t , a x ® r y HAZARDOUS MATERIAL IDENTIFI-CATI 1 D E ON GU LU I T- 1- Y - LU 0 PROTECTIVE EQ,UlPle ENT, mint I w. WIN IN I 'M ca -.-W W9 ma slow w i t I .' s . � I I i mperatnre 4 . 3 Serious May explode If Du ® 54u ear - UMAUAR OIA�U RM IW TO - 2Y FlLG7Efl pIP3fP DIU;Its flAFEl9 /c$ AP30N CUOOt M OI1FY� APRON OUMNAFOO GVev�O .C4�1PaN eEePl:aa9an W.W.Ui a413aL4atcA Ca e G11 . _ ® slumOIL'M0. APOOkI rVAFG;l aU AOi OWUE7 PLLL OOOM .L'Y�:iZ1q CYnlF.2'AH � Fl25PIRATOA r PP°JEO r2'rli.PA7t7A SU7 p H Aoft your m�rparulaor `ors nomlban�llln. Ef7aiwnm al milts APRON FM OE&M ARM VAPOR O. lr��flr��3l�rv�. r'0O7�;ON C�i16"tR z, FlC'u71Ps170O a CHEMICAL HAZARDS . PHYSICAL HAZARDS ACUTELY TOXIC CHRONICALLY TOXIC OXIDIZERS FLAMMABLEICOMBUSTIBLE CARCINOGENIC MUTAGENIC EXPLOSIVE UNSTABLE (REACTIVE) TERAT®GENIC SENSITIZING AGENT WATER-REACTIVE PYROPHORIC CORROSIVE IRRITANT 7�I D1 n6, ? 4 is I 7�\I�i SJCVI 2 REE e7 5 Av' CO REACTNI _ o.xIL 1z CC = CURRosivpp ACD = AU AL m f��• t I HAZARDOUS MATERIALS LABELING CHART CLASS 1 Explosive CLASS 1 Explosive 1.4 CLASS 1 Explosive 1.5 CLASS 1 Explosive 1.6 CLASS 2 Division 2.1 CLASS 2 Division 2.2 1.1 1.2 � r t 'Include appropriate division number 'Include appropriate compatibility *Include appropriate compatibility 'Include appropriate compatibility Flammable gas Non-flammable gas and compatibility group. group. - group. group. CLASS 2 Division 2.2 CLASS 2 Division 2.3 CLASS 3 CLASS 4 Division 4.1 CLASS 4 Division 4.2 CLASS 4 Division 4.3 V�`' �a_F INHALATION _/ s OXYGE R HAZARD FLAMMAB LE LIQU D",._ A AB E S t e fbMBUST161�1 �. � 2 3 e� Oxygen Poison gas Flammable liquid - Flammable solid Spontaneously combustible Dangerous when wet CLASS 5 Division 5.1 CLASS 5 Division 5.2 CLASS 6 Division 6.1 CLASS 6 Division 6.1 CLASS 6 Division 6.1 CLASS 6 Division 6.1 Inhalation Other Than Other Than Other Than Hazard InhalationInhalation Inhalation Hazard � Hazard Hazard I � I-f4 f.. T • �1 INHALATION g OXIDIZER jj" ORGANIC PEROXIDE HAZARD POISON TOXIC PG III 6 6 6 6 - Toxic Packing Group III Oxidizer Organic peroxide Poison inhalation hazard Poison The word"TOXIC"is allowed to be used The text"PG III"is allowed to be used See Toxic and PG III labels. in place of the ward"POISON." in place of the word"POISON.' CLASS 6 Division6.2 CLASS 6 Division6.2 CLASS 7 CLASS 7 CLASS 7 CLASS 8 INFECTIOUS SUBSTANCE .....d..�,.--." � '" •' RADIOACTIVE @ RADIOACTIVE 01 RADIOACTIVE IH l •I _ .�........................ �....................... �....................... _y6�� The Etiologic Agents label may be 7 7'q 7m required for packages of infectious - substances(42 CFR 72.3). Infectious substance Radioactive I Radioactive II Radioactive III - Corrosive CLASS 9 SUBSIDIARY RISK EMPTY FOR AIRCRAFT I I I EMPTY s MA GNETIZED Ml ••Y•y x.-".�. t•", KEFPAWY AWRCfECOMttSSe�iECtOH WR ,Unnumbered Miscellaneous Numbered Allowed until October 1,2005. For Class 7 packagings that meet the Cargo aircraft only - Magnetized material See§172.402(b). requirements in§173.428. GENERAL GUIDELINES ON USE OF HAZMAT LABELS 1. The shipper must attach the appropriate label(s) to each package of hazardous material offered for shipment unless excepted from labeling requirements.(§172.400) 2. If the material in a package has more than one hazard classification,the package must be labeled for each hazard.(§172.402) 3. When two or more hazardous materials of different classes are packed within the same packaging or outer enclosure,the outside of the package or enclosure must be labeled for each class of hazardous material involved.(§172.404) 4. Radioactive materials requiring labeling,must be labeled on two opposite sides of the package.(§172.403) 5. A label should only be applied to a package containing a hazardous material if it represents the hazard inside.(§172.401) 6. No one may offer or transport a package bearing any marking or label which by its color, design, or shape could be confused with a hazardous materials label.This does not prohibit the use of labels in conformance with U.N. Recommendations, IMDG Code, ICAO Technical Instructions,orTDG Regulations.(§172.401) I©Copyright 2002 J.J.KELLER&ASSOCIATES,INC.,Neenah,WI•USA•(800)327-6868•www.ijkeller.com•Printed in the United States 38-FB(Rev.9/02)1116 HAZARDOUS MATERIALS LABELING CHART §172.400 General labeling requirements. (3)A package containing a hazardous material other with subsidiary hazard labels in accordance with the (a)Except as specified in§172.400a,each person who than ammunition that is- following table: offers for transportation or transports a hazardous (i) Loaded and unloaded under the supervision of SUBSIDIARY HAZARD LABELS material in any of the following packages or DOD personnel,and Subsidiary Subsidiary Hazard(Class or Division) containment devices, shall label the package or (ii)Escorted by DOD personnel in a separate vehicle. hazard level containment device with labels specified for the (4)A compressed gas cylinder permanently mounted group] 3 4.1 4.2 4.3 5.1 6.1 8 material in the§172.101 Table and in this art:sub in or on a transport vehicle. P I ................ X •.. ... X X X X (1)A non-bulk package; (5)A freight container, aircraft unit load device or II X X X X X X X (2)A bulk packaging, other than a cargo tank, Portable tank,which- III ........... X X X X X X portable tank,or tank car,with a volumetric capacity W Is placarded in accordance with subpart F of this "" of less than 18 m3(640 cubic feet),unless placarded in Part,or X-Required for all modes. accordance with subpart F of this part; . (ii)Conforms to paragraph(a)(3)or(b)(3)of§172.512. . -Required for all modes,except for a material with- (3)A portable tank of less than 3785 L(1000 gallons) (6)An overpack or unit load device in or on which a flash point at or above 38°C(100'F)transported by capacity,unless placarded in accordance with subpart labels representative of each hazardous material in rail or highway. F of this part; the overpack or unit load device are visible. •••-Impossible as subsidiary hazard. (4)A DOT Specification 106 or 110 multi-unit tank (7)A package of low specific activity radioactive material and surface contaminated objects,when (b)Display of hazard class on labels.The appropriate_ car tank,unless placarded in accordance with subpart transported under §173.427(a)(6)(vi) of this hazard class or division number must be displayed in F of this part;and the lower corner of a primary hazard label and a (5)An overpack,freight container or unit load device, subchapter. subsidiary hazard label.A subsidiary label meeting of less than 18 m3(640 cubic feet),which contains a (b) Certain exceptions to labeling requirements are the specifications of this section which were in effect package for which labels are required, unless Provided for small quantities and limited quantities on September 30,2001,such as,a label without the- placarded or marked in accordance with§172.512 of in applicable sections in part 173 of this subchapter. hazard class or division number displayed in the this part. (c)Notwithstanding the provisions of§172.402(a),a lower corner of the label,may continue to be used as a (b) Labeling is required for a hazardous material subsidiary hazard label is not required on a package subsidiary label in domestic transportation by rail or which meets one or more hazard class definitions,in containing a Class 8(corrosive)material which has a highway until October 1, 2005,provided the color accordance with Column 6 of the§172.101 Table and subsidiary hazard of Division 6.1 (poisonous) if the tolerances are maintained and are in accordance with the following table: toxicity of the material is based solely on the the display requirements in this subchapter. corrosive destruction of tissue rather than systemic (c)Cargo Aircraft Only label. Each person who offers Label design for transportation or transports b aircraft a package Hazard class or poisoning. division Label name or section P P Y P g reference (d)A package containing a material poisonous by containing a hazardous material which is authorized. 1.1.............................. EXPLOSIVES 1.1..................... 172.411 inhalation(see§171.8 of this subchapter)in a closed on cargo aircraft only shall label the package with a 1.2.............................. EXPLOSIVES 1.2..................... 172.411 transport vehicle or freight container may be excepted CARGO AIRCRAFT ONLY label specified in§172.448 1.3.............................. EXPLOSIVES 1.3..................... 172,411 from the POISON INHALATION HAZARD or of this subpart. 1.4.............................. EXPLOSIVES 1.4..................... 172.411 POISON GAS label or placard,under the conditions. (d) Class 7 (Radioactive) Materials. Except as 1.5...........................-.. EXPLOSIVES 1.5..................... 172.411 set forth in§§171.12 and 171.12a of this subchapter. otherwise provided in this paragraph,each package 1.6 EXPLOSIVES 1.6................ ... 172.411 21 containing a Class.7 material that also meets the ............... FLAMMABLE GAS........... .. 172.417 §172.401 Prohibited labeling. 2.2 NONFLAMMABLE GAS... ... 172.415 definition of one or more additional hazard classes, "" (a)Except as provided inparagraph(c)of this section, 2.3.............................. POISON GAS........................ 172.416 P P must be labeled as a Class 7 material as required by 3(flammable liquid) FLAMMABLE LIQUID............. 172.419 no person may offer for transportation or no carrier. §172.403 of this subpart and for each additional Combustible liquid (none)................................... may transport any package bearing a label specified hazard.A subsidiary hazard label is not required on a 4.1.............................. FLAMMABLE SOLID......... .. 172.426 in this subpart unless- package containing a Class 7 material.that conforms 4.2............................. SPONTANEOUSLY................ .172.422. (1) The package contains a material that is a to criteria specified in §173.4 of this subchapter, 1. .COMBUSTIBLE hazardous material,and 4.3..........I................... DANGEROUS WHEN WET..... 172.423 except§173.4(a)(1)(iv)of this subchapter. 5.1.............................. OXIDIZER............................... 172.426 (2)The label represents a hazard of the hazardous (e) Class 1 (explosive)Materials. In addition to the- . 5.2.............................. ORGANIC PEROXIDE........... 172.427 material in the package. label specified in Column 6 of the §172.101 Table, 6.1(nholaflon POISON INHALATION........... 172.429 (b)No person may offer for transportation and no each package of Class 1 material that also meets the hazard.Zone A HAZARD carrier may transport a package bearing any marking definition for: or B). or label which b its color,design, 6.1(other than POISON................................. 172.430 Y gn,or shape could be (1) Division 6.1, Packing Groups I or II, shall be Inhalation hazard, confused with or conflict with a label prescribed by labeled POISON or POISON INHALATION Zone A or B). this part. HAZARD,as appropriate. 6.2.............................. INFECTIOUS SUBSTANCE':.... 172,432 (c)The restrictions in paragraphs (a) and (b)of this (2) Class 7, shall be labeled in accordance with.- 7(see§172.403)....... RADIOACTIVE WHITE-1.......... 172.436 section, do not apply to packages labeled in §172.403 of this subpart. 7................................. RADIOACTIVE YELLOW-II..... 172.438 conformance with: (f)Division 2.2 materials. In addition to the label- 7................................. RADIOACTIVE YELLOW-III...,. 172.440 7(empty packages. EMPTY................................... 172.450 (1)The UN Recommendations (see §171.7 of this specified in Column 6-of the §172.101 Table, each see§173.427). subchapter); package of Division 2.2 material that also meets the 8................................. CORROSIVE.......................... 172.442 (2)The IMDG Code(see§171.7 of this subchapter); definition for an oxidizing gas (see §171.8 of this- 9................................. CLASS 9..........I...................... 172.446 (3)The ICAO Technical Instructions (see §171.7 of subchapter)must be labeled OXIDIZER. 1The ETIOLOGIC AGENT label specified in regulations of the this subchapter); (g)Division 2.3 materials. In addition to the label-•, Department of Health and Human Services at 42 CFR 72.3 may (4) The TDG Regulations (see §171.7 of this specified in Column 6 of the §172.101 Table, each apply to packages of Infectious substances. subchapter). package of Division 2.3 material that also meets §172.400a Exceptions from labeling. (d)The provisions of paragraph(a)of this section do definition for: not apply to a packaging bearing a label if that (1)Division 2.1,must be labeled Flammable Gas; (a)Notwithstanding the provisions of§172.400, a packaging is: (2)Division 5.1,must be labeled Oxidizer;and label is not required on- (3)Class 8,must be labeled Corrosive. (1) A cylinder, or a Dewar flask conforming to ( Unused or cleaned and purged all residue; §173.320 of this subchapter containing a Division 2.1 (22))Transported in a transport vehicle or freight §172.405 Authorized label modifications. container in such a manner that the packaging is not (a)For Classes 1,2,3,4,5,6,and 8,text indicating a or Division 2.2 gas that is- . visible duringtransportation;and (i)Not poisonous; P hazard (for example FLAMMABLE LIQUID)is not W Carried by a private or contract motor carrier; (3) Loaded by the shipper and unloaded by the required on a primary or subsidiary label. (iii)Not overpacked;and shipper or consignee. (b)For a package containing Oxygen;compressed,or-7 (iv) Durably and legibly marked in accordance with §172.402 Additional Labeling requirements. Oxygen, refrigerated liquid, the OXIDIZER label CGA Pamphlet C-7,appendix A. specified in §172.426 of this subpart, modified to p Pp (a) Subsidiary hazard labels. Each package display the word"OXYGEN"instead of"OXIDIZER", (2)A package or unit of military explosives(including containing a hazardous material- and the class number"2"instead of"5.1",may be used$ . ammunition) shipped by or on behalf,of the DOD (1) Shall be labeled with primary and subsidiary in place of the NON-FLAMMABLE GAS and when in hazard labels as specified in Column 6 of the OXIDIZER labels.Notwithstanding the provisions of W Freight containerload, carload or truckload §172.101 Table(unless excepted in paragraph(a)(2).of paragraph(a) of this section,the word"OXYGEN" shipments,if loaded and unloaded by the shipper or this section);and must appear on the label. DOD;or (2)For other than Class 1 or Class 2 materials (for (c)For a package containing a Division 6.1,Packing.. (ii)Unitized or palletized break-bulk shipments by subsidiary labeling requirements for Class 1 or Class Group III material,the POISON label specified in cargo vessel.under charter to DOD if at least one 2 materials see paragraph(e) or paragraphs (f)and §172.430 may be modified to display the text"PG III" required label is displayed on each unitized or (g),respectively,of this section),if not already labeled instead of"POISON"or"TOXIC"below the mid line ofri palletized load. under paragraph(a)(1)of this section,shall be labeled the label.Also see§172.313(d). ©Copyright 2002 J.J.KELLER&ASSOCIATES,INC.,Neenah,WI•USA•(800)327-6868•www.jjkeller.com•Printed in the United States 38-FB(Rev.9/02) i MATERIALS HANDLING IN THE WORK-PLACE-AN HANDLING MATERIALS -EMPLOYEE'S GUIDE TO * Goggles, aprons, rubber gloves, or other SAFETY required protective items should be worn when handling acids, bleaches, alkalis, solvents or boiler compounds. The proper handling of.materials insures that * If any chemicals should spill on your body, the right items are safely in the right place at the. rinse them off immediately with cold water. right time. It is essential,for this reason,that all of Change clothes if necessary. us exercise proper procedures in any situation * Use a carboy tilting device or pump when for personal protection and efficient movement transferring acid,alkalis,or solvents from a of materials. large container into a smaller container. The way to minimize any dangers in materials ' Use correct lifting methods and avoid back handling is for employers and employees to injuries: examine their own workplaces for any unsafe or a)Get a good footing. unhealthful conditions. These health or physical b) Bend at the knees to grasp the object. hazards can affect anyone exposed to those c)Keep the back straight and as upright as conditions at the workplace. These situations, possible. whether employee practices or equipment d)Get a firm hold on the object. conditions, should be corrected as quickly as e) Lift gradually by straightening the legs, possible. keep back straight. The MSDS sheets describe all of the specific f)Use similar procedures when putting a safety and handling procedures for the load down. chemicals listed on that form.These forms * Use hand trucks when moving heavy should be "reviewed by you, the employee, objects. before working with any new or unknown * Limit size of the load so you have a clear product. You should also seek any additional view when pushing the hand truck. supervisory assistance, if necessary, to insure * Keep the load trimmed so that it will pass safe and healthy practices. safely through aisles and doorways. *Clean up used crating and packing materials and avoid accidents. GENERAL SAFETY * Use a ladder or step stool when reaching for high objects. *Smoking is prohibited in the workplace *When using a straight ladder, make sure that except in designated areas only.This is the feet are about one-forth of the ladder especially important for everyone's benefit. length away from the object against which it The puffing on smoking materials(cigarettes, is leaning. cigars, pipes,-etc.)increases inhalation of * Stepladders must not be used as straight airborne materials that are present in the ladders. Always open them fully and lock the workplace. spreaders. *Keep all aisles and stairways clean of obstructions. *Wear clothing that is safe, sensible, and suitable for the job. Loose clothes should not be worn by anyone working around operating equipment. * Practical jokes and horseplay should not be - practiced in the workplace. *Do not eat or drink while at your work station. Use the cafeteria or lunchroom. * Never place electric appliances on boxes, v low tables, or places where they can be touched accidentally or be knocked over creating a safety hazard. * Make sure equipment guards are in place when using any machinery. * Keep floors as dry as possible around your work area. Get medical attention for all injuries immediately. i SHOP MAINTENANCE Check all extension cords, drop lights, and Oil, grease, adjust, or maintain machinery power tools for worn or frayed wires. only while it is stopped. * Use sand or floor absorbent for any spills * Pull circuit breaker or fuses to safe guard that cannot be wiped up immediately. against accidental startup. * Do not smoke around gasoline pumps or *Check to make sure that other employees are tanks. Smoke only in designated areas. not working on any equipment before you *Do not fill fuel tanks while engines are start it. running. * Wear goggles or face shield when using air to blow off or clean equipment. *Never attempt to repair electrical equipment STORAGE AND DISPOSAL unless you are qualified for that kind of work. * Replace all broken or worn machine drive * Store materials or bundles on shelves so that belts. they do not protrude into passageways. * Inspect regularly and keep all equipment * Store bottles of acid, alkalis, bleaches,or safety devices in place and operating cleaning material on bottom shelves. properly. *Store all objects so that they will be readily * Inspect regularly and repair or replace any available without moving other objects. broken, worn, or splintered hand trucks, * Place heavy objects on lower shelves. ladders, creepers, skids, or duct work. * Use proper step stools or hydraulic lifts * Use a safety solvent for washing parts. when getting items from upper shelves. Never use gasoline. *All items in storage shall be properly *Store waste materials and oily rags in labeled to identify their contents. covered metal containers. *All items shall be stored so that you can Wear goggles while using abrasive wheels read the labels without moving the container., or working beneath a machine. * Keep storage areas well lit so that people will * Fasten oxygen and acetylene tanks to a not be in danger from items they cannot see. rack, truck, or work bench before attaching *Dispose of all waste materials properly. See control valves. Handle gauges and valves specific MSDS form for each chemical. carefully. Check local disposal requirements for *Make sure that vehicles are securely nonchemical materials.. chocked. _ * Don't leave creepers lying around. Someone could trip on them. I MATERIAL SAFETY DATA SLEETS (MSDS) The Material Safety Data Sheets(MSDS)are LIST OF HAZARDOUS CHEMICALS kept and maintained by John Medeiros. Our List of Hazardous Chemicals is in John Medeiros, or his designee, is responsible the front of the MATERIAL SAFETY for obtaining new and updated MSDS. It is the DATA SHEET BOOK. It works also as al policy of this company that when toxic or an index listing for the MSDS' and hazardous substances are received without an enables you to find what.you are MSDS, or the appropriate MSDS is not on file looking for with the most efficiency here, that the chemical will not be accepted until possible. such information is available. _. Substances are listed by Manufacturer and John will review incoming data sheets for new Trade/Chemical Name, as the container in your and significant health/safety information. And work area is labeled. then see that any new information is passed on to the affected employees. If a MSDS is The following will help you to better understand incomplete, a new MSDS will be requested from and access necessary information from an the manufacturer or supplier.. MSDS. MSDS'are available to each employee during his/her workshift for their viewing. The Material Safety Data Sheet Book is kept in the Warranty Administration Room. In addition; posted with all the State and Federal Law Posters is a Safety Information Locator Form - listing locations as to where to find MSDS',the Hazardous Chemical List, copy of this Written Hazard Communication Program and who to direct your safety related questions to. l� MATERIAL SAFETY DATA SHEETS (MSDS) The Material Safety Data Sheet(MSDS)follows a This form will provide sufficient information to ,format that.has been prescribed by the allow safe use and handling of the product. The Occupational Safety and Health Administration Material Safety Data Sheet(MSDS), as designed (OSHA).The format clearly requires certain by OSHA, is divided into nine sections. Each information be included on all MSDS forms. section deals with specific information. If you Some companies change the style to suit their need further help in interpreting or finding needs but all OSHA required information is specific information on the MSDS form, get it contained on the MSDS form. Some of the now during the training session to avoid an MSDS forms will not number the sections but actual risk while at your workstation. The most use titles in bold letters. important sections to remember are. The MSDS format outlined in this section will •Health hazards information(V),especially first help you read and understand the form and aid know where to look for information, quickly, on Protective equipment(Vlll) hazards,toxicity,first aid, and safety precautions • Precautions and handling procedures (IX) associated with any chemical substance. remember, safety is your responsibility. EXPLANATION OF MSDS FORMS SECTION I—Material Identification SECTION VI—Reactivity Data Manufacturer's name, address,and Stability of product telephone number Reactions to other substances (water, Chemical name and synonyms chemicals,etc.) Trade name Incompatibility(materials to avoid) Chemical family Hazardous decomposition Formula and CAS number Conditions to avoid Date of preparation or change Name of person who prepared the form SECTION. VII—Handling Precautions SECTION 11-Hazardous Ingredients (spill or.leak) Identity Steps to be taken if substance spills or Threshold Levels(TLV)—Solvents, paints, leaks preservatives Waste disposal methods Threshold Levels(TLV)—Metals and alloy. Neutralization if necessary coatings Threshold Levels(TLV)—Hazardous SECTION Vill—Special Protection - mixtures of other liquids, solids, or gases Information Breathing protection (specifies type) SECTION III—Physical Data Ventilation or exhaust information Lists the chemical and physical properties Handling material specs(corrosive of the substance,the boiling point, vapor resistant,etc.) pressure, odor, volatility, appearance, and Protective gloves any other physical information. Eye protection Other protection (hard hat, shoes, aprons, . SECTION IV—Fire and Explosion I etc. Hazard Flash points and flammable limits SECTION .IX—Special Precautions Extinguishing procedures Storage and handling Special fire hazard instructions Venting if needed No smoking regulations SECTION V—Heallh Hazard Data Other precautions(temperature, pressure, Toxicology information etc.) Effects of overexposure (signs and Hygienic practices to be followed symptoms) How the chemicals enter the body First aid and emergency rocedures MATERIAL SAFETY DATA SHEET SAMPLE U.S. DEPARTMENT OF LABOR Form APPtoved Occupational Safety and Health Administration OM8 No.44.R1387 MATERIAL SAFETY DATA SHEET This Material Safety Data Sheet complies with 29 CFR 1910.1200(The Hazard Communication Standard) SECTION 1 MANUFACTURER'S NAME EMERGENCY TELEPHONE NO. ADDRESS(Number,Strcct•City.State.and Z/l'Cadcl CHEMICAL NAME AND SYNONYMS TRADE NAME AND SYNONYMS CHEMICAL FAMILY FORMULA SECTION II - HAZARDOUS INGREDIENTS TLv (Units) SECTION III - PHYSICAL DATA _._ BOILING POINT(•F.) SPECIFIC GRAVITY(Ht0=1) !" VAPOR PRESSURE(mm Hg.) PERCENT,VOLATILE BY VOLUME(!6) VAPOR DENSITY(AIR=), EVAPORATION RATE SOLUBILITY IN WATER APPEARANCE AND ODOR SECTION IV- FIRE AND EXPLOSION HAZARD DATA FLASH POINT(Method uw) FLAMMABLE LIMITS Lei I Uel EXTINGUISHING MEDIA SPECIAL FIRE FIGHTING PROCEOURES UNUSUAL FIRE AND EXPLOSION HAZAROS On ingredients - tY ng edients exhibiting a particular hazard will be listed on this form. Chemicals not classified as hazardous according to OSHA Guidelines as they are specified in 29 CFR, 1910 will not be listed on this form although one or more may be present. I ' t SECTION V - HEALTH HAZARD DATA THRESHOLD LIMIT VALUE EFFECTS OF OVEREXPOSURE I -r- m-rAGENCY AND FIRST Alp PR EOUR i SECTION VI - REACTIVITY DATA STABILITY UNSTABLE CONDITIONS TO AVOID STABLE INCOMPATABILITY(Materials to auuid) - - HAZARDOUS DECOMPOSITION PRODUCTS HAZARDOUS MAY OCCUR CONDITIONS TO AVOID POLYMERIZATION WILL NOT OCCUR SECTION VII - SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED WASTE DISPOSAL METHOD SECTION VI11 SPECIAL PROTECTION INFORMATION 1 . O RESPIRATORY PROTECTION(Specify.type) VENTILATION LOCAL EXHAUST SPECIAL MECHANICAL(Cenertal) OTHER PROTECTIVE GLOVES EYE PROTECTION OTHER PROTECTIVE EQUIPMENT SECTION IX - SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING i OTHER PRECAUTIONS Disclaimer of Liability The Information In this MSDS was obtained from sourges which we believe are reliable.HOWEVER,THE INFORMATION IS PROVIDED WITHOUT ANY REPRESENTATION OR WARRANTY,EXPRESS OR IMPLIED,REGARDING ITS ACCURACY OR CORRECTNESS. The conditions or methods of handling,storage,use and disposal of the product are beyond ourcontrol and maybe beyond our knowledge.FOR THIS AND OTHER REASONS,WE DO NOT ASSUME RESPONSIBILITY AND EXPRESSLY DISCLAIM LIABILITY FOR LOSS,DAMAGE OR EXPENSE ARISING OUT OF OR IN ANY WAY CONNECTED WITH THE HANDLING,STORAGE,USE OR DISPOSAL OF THE PRODUCT. S®S Glossary MSDS Glossary Alkali Any chemical substance that forms soluble soaps with fatty acids. Alkalis are also referred to Tne following glossary presents brief explanations as bases. They may cause severe burns to'the of acronyms and common terms frequently used skin. Alkalis turn.litmus paper blue and have pH by chemical manufacturers in their MSDS's. values from 8 to 14. ACGIH American Conference of Governmental In- Allergic Reaction An abnormal physiological dustrial Hygienists is an organization of profes- response to chemical or physical stimuli. sional personnel in governmental agencies or educational institutions engaged in occupational Amenorrhea Absence of menstruation. safety and health programs. ACGIH establishes recommended occupational exposure limits for Anesthetic A chemical that causes a total or par- chemical substances and physical agents. See tial loss of sensation. Overexposure to anesthet- TLV. ics can cause impaired judgment, dizziness, drowsiness, headache, unconsciousness, and Acid Any chemical that Undergoes dissociation in even death. Examples include alcohol, paint water with the formation of hydrogen ions. Acids remover, and degreasers. have a sour taste and may cause severe skin burns. Acids turn litmus paper red and have pH ANSI American National Standards Institute is a values of 0 to 6. privately funded, voluntary membership organiza- tion-that identifies industrial and public needs for -- - Acute Effect Aduerse effect on a human or national consensus standards and coordinates animal that has severe symptoms developing development of such standards. rapidly and coming quickly to a crisis. Antidote A remedy to relieve, prevent, or counter-' Acute Toxicity Acute.effects resulting from a sin- act the effects of a poison. gle dose of, or exposure to, a substance. Or- dinarily used to denote effects in experimental API American Petroleum Institute is a organization animals. of the petroleum industry. Adenocarcinoma A tumor with glandular (secret- Appearance -A description of a substance at nor- ing) elements. mal room temperature and normal atmospheric conditions. Appearance includes the color, size, Adenosis Any disease of a gland. and consistency of a material. Adhesion A union of two surfaces that are nor- Aquatic Toxicity The adverse effects to marine mally separate. life that result from being exposed to a toxic sub- stance. Aerosol A fine aerial suspension of particles suffi- ciently small in size to confer some degree of stability from sedimentation (e.g., smoke or fog). consciousness or death by suffocation (lack of oxygen). Most simple asphyxiants are harmful to Air-Line Respirator 'A respirator that is connected the body only when they become so concentrat- to a compressed breathable air source by a hose ed that they reduce oxygen in the air (normally of small inside diameter. The air is delivered con- about 21 percent) to dangerous levels (18 per- tinuously or intermittently in a sufficient volume to cent or lower). Asphyxiation is one of the prin- meet the wearer's breathing requirements. cipal potential hazards of working in confined and enclosed spaces. Air-Purifying Respirator A respirator that uses chemicals to remove specific gases and vapors ASTM American Society for Testing and Materials from the air or that uses a mechanical filter to re- is.the world's largest source of voluntary consen- susmove particulate matter. An air-purifying respira- standards for materials, products, systems, for must only be used when there is sufficient and services. ASTM is a resource for sampling oxygen to sustain life and the air contaminant and testing methods, health and safety aspects level is below the concentration limits of the of materials, safe performance guidelines, effects device. of physical and biological agents and chemicals. Asymptomatic Showing no symptoms. Allyl Chloride 1130F Ethylene Glycol 387OF Atm Atmosphere, a unit of pressure equal to 760 mmHg (mercury) at sea level. BOM, or BuMines Bureau of Mines, U.S. Depart- Atmosphere-Supplying Respirator A respirator ment of Interior. that provides breathable air from a source in- dependent of the surrounding atmosphere. There Bonding The interconnecting of two objects by are two types: air-line and self-contained breath- means of a clamp and bare wire. Its purpose is ing apparatus. to equalize the electrical potential between the objects to prevent a static discharge when trans- Auto-Ignition Temperature The temperature to ferring a flammable liquid from one container to which a closed, or nearly closed container must another. The conductive path is provided by be heated in order that the flammable liquid, clamps that make contact with the charged ob- when introduced into the container, will ignite ject and a low resistance flexible cable which al- spontaneously or burn. lows the charge to equalize. See Grounding. BAIL British Anti-Lewisite - A name for the drug Bulk Density Mass of powdered or granulated dimecaprol—a treatment for toxic inhalations. solid material per unit of volume. Base A substance.that (1) liberates hydroxide C Centigrade, a unit of temperature. (OH) ions when dissolved in water, (2) receives hydrogen ions from a strong acid to form a weak- Ceiling Limit.(PEL or TLV) The maximum allowa- er acid, and (3) neutralizes an acid. Bases react ble human exposure limit for an airborne sub- with acids to form salts and water. Bases have a stance which is not to be exceeded even pH greater than 7 and turn litmus paper blue. momentarily. Also see PEL and TLV.. See Alkali. BCIVI Blood-clotting mechanism effects. ca Approximately. Benign Not recurrent or not tending to progress. CAA Clean Air Act was enacted to regu- - cancerous. late/reduce air pollution. CAA is administered by Not U.S. Environmental Protection Agency. Biodegradable Capable of being broken down Carcinogen A substance or agent capable of... into innocuous products by the action of living causing or producing cancer in mammals, includ- things. ing humans. A chemical is considered to be a . Biopsy Removal and examination of tissue from carcinogen if the living body. (a) It has been evaluated by the International BLD Blood effects. Agency for Research on Cancer (IARC) and found to be a carcinogen or potential carcino- Boilin Points=BP The tem erature at which a gen; or 9 P liquid changes to a vapor state at a given pres (b) It is listed as a carcinogen or potential car- sure. The boiling point usually expressed in degrees Fahrenheit at sea level pressure (760 cinogen in the Annual Report on Carcino or one atmosphere). For mixtures, the in- gens published by the National Toxicology- mmHg, - itial boiling point or the boiling range may be Program (NTP) (latest edition); or . given. (c) It is regulated by OSHA as a carcinogen. Flammable materials with low boiling points gener- ally present special fire hazards. Some approxi- mate boiling points: Carcinoma A malignant.tumor. A form of cancer. Propane -440F CAS Chemical Abstracts Service is an organiza- Anhydrous Ammonia -28OF tion under the American Chemical Society. CAS Butane 31°F abstracts and indexes chemical literature from all over the world in "Chemical Abstracts." "CAS Gasoline 1000F Numbers" are used to identify specific chemicals or mixtures. 11-2 . Caustic See Alkali. lay pertinent emergency information concerning specific chemicals on requests from individuals. cc Cubic centimeter is a volume measurement in CHEMTREC has a 24-hour toll-free telephone the metric system that is equal in capacity to one number (800-424-9300) to help respond to chemi- milliliter (ml). One quart is about 946 cubic cen- cal transportation emergencies. timeters. Chronic Effect An adverse effect on a human or Central Nervous System The brain and spinal animal body, with symptoms that develop slowly cord. These organs supervise and coordinate the over a long period of time or that recur frequent- activity of the entire nervous system. Sensory im- ly. Also see Acute. pulses are transmitted into the central nervous system, and motor impulses are transmitted out. Chronic Exposure Long-term contact with a sub- stance. - CERCLA Comprehensive Environmental Response, Compensation, and Liability Act of Chronic.Toxicity Adverse (chronic) effects result- 1980. The Act requires that the Coast Guard Na- ing from repeated doses of or exposures to a tional Response Center be notified in the event substance over a relatively prolonged period of of a hazardous substance release. The Act also time. Ordinarily used to denote effects in ex- provides for a fund (the Superfund) to be used perimental animals. for the cleanup of abandoned hazardous waste disposal sites. Clean Air Act See CAA. CFR Code of Federal Regulations. A collection of Clean Water Act Federal law enacted to regu- the regulations that have been promulgated un- late/reduce water pollution. CWA is administered der United States Law. by EPA. Chemical An element (e.g., chlorine) or a CMA Chemical Manufactures Association. See compound (e.g.,sodium bicarbonate) produced by CHEMTREC. chemical reaction. CO Carbon monoxide is a colorless, odorless, Chemical Cartridge.Respirator A respirator that flammable, and very toxic gas produced by the uses various chemical substances to purify in- incomplete combustion of carbon..It is also a haled air of certain gases and vapors. This type byproduct of many chemical processes. A chemi. respirator is effective for concentrations no more cal asphyiant; it reduces the blood's ability to than ten times the TLV of the contaminant, if the carry oxygen. Hemoglobin absorbs CO two contaminant has warning properties (odor or irri-. hundred times more readily than it does oxygen. tation) below the TLV. CO2 Carbon dioxide is a heavy, colorless gas that Chemical Family A group of single elements or is produced by the combustion and decomposi compounds with a common general name. Exam- tion of organic substances and as a byproduct of ple: acetone, methyl ethyl-ketone (MEK), and many chemical processes. CO2 will not burn and methyl isobutyl ketone (MIRK) are of the "Ke- is relatively nontoxic (although high concentra- -' tone" family; acrolein, furfural, and acetaldehyde tions, especially in confined spaces, can create are of the "aldehyde" family. hazardous oxygen-deficient environments). COC Cleveland Open Cup is a flash point test -' Chemical Name The name given to a chemical in method. the nomenclature system developed by the Inter- national Union of Pure and Applied Chemistry Combustible A term used by NFPA, DOT, and (IUPAC) or the Chemical Abstracts Service others to classify certain liquids that will burn, on (CAS). The scientific designation of a chemical-or the basis of flash points. Both NFPA and DOT a name that will clearly identify the chemical for generally define "combustible liquids" as having hazard evaluation purposes. a flash point of 100OF ( 37.80C).or higher but be Chemical Pneumonitis. Inflammation of the lungs low 200OF (93.3°C). Also see "flammable." Non- caused by accumulation of fluids due to chemical liquid substances such as wood and paper are irritation. classified as "ordinary combustibles" by NFPA. CHEMTREC Chemical Transportation Emergency Combustible Liquid Any liquid having a flash- Center is a national center established by the point at or above 100 F (37.8 C), but below Chemical Manufacturers Association (CMA) to re- 200OF (93.30C), except any mixture having com- 11 II-3 i ponents with flashpoints of 200°F (93.3°C) or Appendix A to 49 CFR Part 173, it destroys or higher, the total volume of which makes up changes irreversibly the structure of the tissue at ninety-nine (99) percent or more of the total the site of contact following an exposure period volume of the mixture. of 4 hours. This term shall not refer to action on inanimate surfaces. Common Name Any means used to identify a chemical other than its chemical name (e.g., CPSC Consumer Products Safety Commission code name, code number, trade name, brand has responsibility for regulating hazardous name, or generic name). See Generic. materials when they appear in consumer goods. For CPSC purposes, hazards are defined in the Compressed Gas: Hazardous Substances Act and the Poison . Prevention Packaging Act of 1970. (a) A gas or mixture of gases having, in a con- tainer, an absolute pressure exceeding 40 Curettage Cleansing of a diseased surface. pounds per square inch (psi) at 70OF (21.1°C); or Cutaneous Toxicity See "Dermal Toxicity." (b) A gas,or mixture of gases having, in a con- CWA Clean Water Act was enacted to regu- tainer, an absolute pressure exceeding 104 late/reduce water pollution. It is administered by psi at 1300F.(54.4°C) regardless of the Ares- EPA. sure at 70OF (21.1°C); or Cyst A sac containing a liquid. Most cysts are (c) A liquid having a vapor pressure exceeding harmless. 40 psi at 100OF (37.8°C) as determined by ASTM D-323-72. Cytology The scientific study of cells. Conc.. See Concentration. Decomposition Breakdown of a material or sub- Concentration The relative amount of a sub- stance (by heat, chemical reaction, electrolysis, decay, or other processes) into parts or elements stance when combined or mixed with other sub or simpler compounds. stances. Examples: 2 ppm hydrogen sulfide in air, or a 50 percent caustic solution. Density The mass (weight) per unit volume of a substance. For example, lead is much more Conditions to Avoid Conditions encountered dur- dense than aluminum. ing handling or storage that could cause a sub- stance to become unstable. Depressant A substance that reduces a bodily Confined Space An area that has limited open- functional activity or an instinctive desire, such as p y p appetite. ings for entry and exit that would. make escape , difficult in an emergency, has a lack of ventila- Dermal Relating to the skin. tion, contains known and potential hazards, and is not intended nor designated for continuous hu- Dermal Toxicity Adverse effects resulting from man occupancy. skin exposure to a substance. Ordinarily used to denote effects in experimental animals. Conjunctivitis Inflammation of the conjunctiva, the delicate membrane that lines the eyelids and DHHS U.S. Department of Health and Human covers the eyeballs. Services (replaced U.S. Department of Health, Education and Welfare). NIOSH and the Public . Container Any bag, barrel, bottle, box,can, Health Service (PHS) are part of DHHS. cylinder, drum, reaction vessel, storage tank, or the like that contains a hazardous chemical. For Dike A barrier constructed to control or confine , purposes of MSDS or HCS, pipes or piping sys- hazardous substances and prevent them from en- tems are not considered to be containers. tering sewers, ditches, streams, or other flowing waters. Corrosive A chemical that causes visible destruc- tion of, or irreversible alterations in, living tissue Dilution Ventilation Air flow designed to dilute by chemical action at the site of contact. For contaminants to acceptable levels. Also see - example, a chemical is considered to be corro- general ventilation or exhaust. sive if, when tested on the intact skin of albino rabbits by the method described by the DOT in -4 f DOL U.S. Department of Labor. OSHA and MSHA FAST evaporating if greater than 3.0. Exam- are part of DOL. pies: Methyl Ethyl Ketone 3.8, Acetone = 5.6, Hexane = 8.3. DOT U.S. Department of Transportation regulates transportation of chemicals and other substances. — MEDIUM evaporating if 0.8 to 3.0. Exam- pies: 190 proof (95%) Ethyl Alcohol = 1.4, Dry Chemical A powdered fire-extinguishing VM&P Naphtha = 1.4, MIBK = 1.6. agent usually composed of sodium bicarbonate, potassium bicarbonate, etc. - SLOW evaporating if less than 0.8. Exam. pies: Xylene = 0.6, Isobutyl Alcohol = 0.6, Dysmenorrhea Painful menstruation. Normal Butyl Alcohol = 0.4, Water 0.3, Mineral Spirits = 0.1. Dsyplasia An abnormality of development. Explosive A chemical that causes a sudden, Dyspnea A sense of difficulty in breathing; short- almost instantaneous release of pressure, gas, ness of breath. and heat when subjected to sudden shock, pres- sure, or high temperature. Ectopic pregnancy The fertilized ovum becomes implanted outside of the uterus. Exposure or Exposed State of being open and vulnerable to a hazardous chemical by inhalation, Edema An abnormal accumulation of clear watery ingestion, skin contact, absorption, or any other fluid in the tissues. course; includes potential (accidental or possible) exposure. Endocrine glands Glands that regulate body ac- tivity by secreting hormones. Extinguishing Media The firefighting substance to be used to control a material in the event of a Endometrium The mucous membrane lining the fire. It is usually identified by its generic name, Uterus. such as fog, foam, water, etc. Environmental Toxicity Information obtained as a Eye Protection Recommended safety glasses, result of conducting environmental testing chemical splash goggles; face shields, etc. to be designed to study the effects on aquatic and utilized when handling a hazardous material. plant life. F Fahrenheit is a scale for measuring tempera- EPA U.S. Environmental Protection Agency. ture. On the Fahrenheit scale, water boils at 212OF and freezes at 32°F. Epidemiology Science concerned with the study of disease in a general population. Determination f/cc Fibers per cubic centimeter of air. of the incidence (rate of occurrence) and distribu- tion of a particular disease (as by age, sex, or FDA U.S. Food and Drug Administration. occupation) which may provide information about the cause of the disease. Fetal Pertaining to the fetus. Epithelium The covering of internal and external Fetus The developing young in the uterus from surfaces of the body. the seventh week of gestation until birth. Estrogen . Principal female sex hormone. Fibrosis An abnormal thickening of fibrous con- nective tissue, usually in the lungs. Evaporation Rate The rate at which a material will vaporize (evaporate) when compared to the FIFRA Federal Insecticide, Fungicide, and Roden- known rate of vaporization of a standard material. ticide Act requires that certain useful poisons, The evaporation rate can be useful in evaluating such as chemical pesticides, sold to the public the health and fire hazards of a material. The contain labels that carry health hazard warnings designated standard material is usually normal to protect users. It is administered by EPA. butyl acetate (NBUAC or n-BuAc), with a vapori- zation rate designated as 1.0. Vaporization rates First Aid Emergency measures to be taken when of other solvents or materials are then classified a person is suffering from overexposure to a as: hazardous material, before regular medical help can be.obtained. II-5 Flammable A chemical that includes one of the (c) Setaflash Closed Tester (see American Na- following categories: tional Standard Method of Test for Flash Point by Setaflash Closed Tester [ASTM D (a) "Aerosol, flammable." An aerosol that, when 3278-781). tested by the method described in 16 CFR 1500.45, yields a flame projection exceeding Foreseeable Emergency Any potential occur- 18 inches at full valve opening, or a flash- rence such as, but not limited to, equipment back (a flame extending back to the valve) at failure, rupture of containers, or failure of control any degree of valve opening; equipment which could result in an uncontrolled release of a hazardous chemical into the (b) "Gas, flammable." (1) A gas that, at ambient. workplace. temperature and pressure, forms a flammable mixture with air at a concentration of 13 per- Formula The scientific expression of the chemical. cent by volume or less; or (2) A gas that, at composition of a material (e.g., water is H2O, ambient temperature and pressure, forms a sulfuric acid is H2SO4, sulfur dioxide is S02). range of flammable mixtures with air wider than 12 percent by volume, regardless of the Fume A solid condensation particle of extremely lower limit; small diameter, commonly generated from molten metal as metal fume. (c) "Liquid, flammable." Any liquid having a flashpoint below 100OF (37.80C), except any g Gram is a metric unit of weight. One ounce mixture having components with flashpoints U.S. (avoirdupois) is about 28.4 grams. of 100OF (37.8°C) or higher, the total of which make up 99 percent or more of the General Exhaust A system for exhausting afr con- total volume of mixture. taining contaminants from a general work area. Also see Local Exhaust. (d) "Solid, flammable." A solid, other than a blasting agent or explosive as defined in Generic Name A designation or identification 1910.109(a), that is liable to cause fire used to identify a chemical by other than its through friction, absorption of moisture, spon- chemical name (e.g., code name, code number, taneous chemical change, or retained heat trade name, and brand name). from manufacturing or processing, or which can be ignited readily and when ignited burns Genetic Pertaining to or carried by genes. so vigorously and persistently as to create a Hereditary. serious hazard. A solid is a flammable solid if, when tested by the method described in 16 Gestation The development of the fetus in the CFR 1500.44, it ignites and burns with a self-- uterus from conception to birth; pregnancy. sustained flame at a rate greater than one- tenth of an inch per second.along its major g/kg Grams per kilogram is an expression of dose axis. used in oral and dermal toxicology testing to denote grams of a substance dosed per kilogram Flashback Occurs when flame from a torch burns of animal body weight. Also see "kg" (kilogram). back into the tip, the torch, or the hose. It is often accompanied by a hissing or squealing Grounding The procedure used to carry an elec- oz - sound with a smoky or sharp-pointed flame., trical charge to ground through a conductive path. A typical ground may be connected directly Flashpoint The minimum temperature at which a to a conductive water pipe or to a grounding bus liquid gives off a vapor in sufficient concentration and ground rod. See Bonding. to ignite when tested by the following methods: Gynecology The study of the reproductive organs (a) Tagliabue Closed Tester (see American Na- in women. tional Standard Method of Test for Flash Point by Tag Closed Tester, Z11.24 1979 Hand Protection Specific type of gloves or other [ASTM D56-79]). hand protection required to prevent harmful ex (b) Pensky-Martens Closed Tester (see American posure to hazardous materials. National Standard Method of Test for Flash Hazardous Chemical Any chemical whose Point by. Pensky-Martens Closed Tester, presence or use is a physical hazard or a health Z11.7-1979 [ASTM D93-791). hazard. 11-6 I Hazardous Warning Words, pictures, symbols, or Hormones Act as chemical messengers to body combination thereof presented on a label or other organs. appropriate form to inform of the presence of var- ious materials. Hyperplasia Increase in volume of a tissue or or- gan caused by the growth of new cells. HCS Hazard Communication Standard is an OSHA regulation issued under 29 CFR Part IARC International Agency for Research on 1910.1200. Cancer. Health Hazard A chemical for which there is sig- Ignitable Capable of being set afire. . nificant evidence, based on at least one study conducted in accordance with established scien- Impervious A material that does not allow another tific principles, that acute or chronic health ef- substance to pass through or penetrate it. fects may occur in exposed employees. The term "health hazard includes chemicals that are car- Incompatible Materials that could cause danger- cinogens, toxic or highly toxic agents, reproduc- ous reactions by direct contact with one another. tive toxins, irritants, corrosives, sensitizers, hepatotoxins, nephrotoxins, neurotoxins, agents Ingestion Taking in by the mouth. that act on the hematopoietic system, and agents that damage the lungs, skin, eyes, or mucous Inhal See inhalation. membranes. Inhalation Breathing in of a substance in the form Hemoglobin An iron-containing conjugated protein of a gas, vapor, fume, mist, or dust. or respiratory pigment occurring in the red blood cells of vertebrates. Inhibitor A chemical added to another substance to prevent an unwanted chemical change. Hematoma A blood clot under the surface of the skin. Insol See insoluble. Hematopoietic System The blood-forming . Insoluble . Incapable of being dissolved in a liquid. mechanism of the human body. - Intrauterine Within the uterus. Hematuria The presence of blood in the urine. Irritant A chemical, which is not corrosive, that - Hepatotoxin A substance that causes injury to causes a reversible inflammatory effect on living the liver. tissue by chemical action at the site of contact: A chemical is a skin irritant if, when tested on the Highly toxic A chemical in any of the following intact skin of albino rabbits by the methods of 16 categories: CFR 1500 41 for 4 hours exposure or by other appropriate techniques, it results in an empirical (a) A chemical with a median lethal dose (LD50) . score of 5 or more. A chemical is an eye irritant of 50 milligrams or less per kilogram of body if so determined under the procedure listed in 16 weight when administered orally to albino rats CFR 1500.42 or other appropriate techniques. weighing between 200 and 300 grams each. Irritating As defined by DOT, a property of a (b) A chemical with a median lethal dose (LD50) liquid or solid substance which, upon contact of 200 milligrams or less per kilogram of body. with fire or when exposed to air, gives off weight when administered by continuous con- dangerous or intensely irritating fumes (not in- tact for 24 hours (or less if death occurs cluding poisonous materials). See Poison, Class within 24 hours) with the bare skin of albino. A and Poison, Class.B. rabbits weighing between.2 and 3 kilograms each. kg Kilogram is a metric unit of weight, about 2.2 U.S. pounds. Also see "g/kg," "g," and "mg." (c) A chemical that has a median lethal concen- tration (LC50) in air of 200 parts per million by L Liter is a metric unit of capacity. A U.S. quart is volume or less of gas or vapor, or 2 milli-' about 9/10 of a liter. grams per liter or less of mist, fume, or dust, when administered by continuous inha- Lacrimation Secretion and discharge of tears. lation for 1 hour (or less if death occurs with- in 1 hour) to albino rats weighing between Label Notice attached to a container, bearing in- .200 and 300 grams each. formation concerning its contents. I I.7 I u Lactation The secretion of milk.by the breasts. Malignant Tending to become progressively worse and to result in death. LC Lethal concentration is the concentration of a substance being tested that will kill. Mammary Pertaining to the breast. - LCL Lethal concentration, low, lowest concentra- Mechanical Exhaust A powered device, such as tion of a gas or vapor capable of killing a speci- a motor-driven fan or air steam venturi tube, for fied species over a specified time. exhausting contaminants from a workplace, ves- set, or enclosure. LC50 The concentration of a material in air that will kill 50 percent of a group of test animals with Mechanical Filter Respirator A respirator used to a single exposure (usually 1 to 4 hours). The protect against airborne particulate matter like LC50 is expressed as parts of material per million dusts, mists, metal fume, and, smoke. Mechanical parts of air, by volume (ppm) for gases and filter respirators do not provide protection against vapors, or as micrograms of material per liter of gases, vapors, or oxygen deficient atmospheres. - air (g/1) or milligrams of material per cubic meter of air (mg/m3) for dusts and mists, as well as for. Melting Point The temperature at which a solid gases and vapors. substance changes to a liquid state. LID Lethal dose is the quantity of a substance be- Menorrhagia Excessive menstruation. ing tested that will kill Menstruation Periodic discharge of blood from LDL Lethal dose low, lowest administered dose of the vagina of a nonpregnant uterus. a material capable of killing a specified test species. Metabolism. Physical and chemical processes tak- ing place among the ions, atoms, and molecules - - LD50 A single dose of a material expected to kill of the body. 50 percent of a group of test animals. The LD50 dose is usually expressed as milligrams or grams Metastasis The transfer of disease from one or- of material per kilogram of animal body weight gan or part to another not directly connected with (mg/kg or g/kg). The material may be ad- it. ministered by mouth or applied to the skin. Meter A unit of length; equivalent to 39.37 inches. LEL, or LFL Lower explosive limit, or lower flam- mable limit, of a vapor or gas; the lowest concen- mg Milligram is a metric unit of weight that is-one- tration (lowest percentage of the substance in air) thousandth of a gram. that will produce a flash of fire when an ignition source (heat, arc,.or flame) is present. At concen- mg/kg Milligrams of substance per kilogram of trations lower than the LEL, the mixture is too body weight is an expression of toxicological "lean to burn. Also see "VEL." dose. Lesion Any damage to a tissue. mg/m3 Milligrams per cubic meter is a unit for ex- pressing concentrations of dusts, gases, or'mists Lfm Linear feet per minute, a unit of air velocity. in air. Local Exhaust A system for capturing and ex- Micron Micrometer A unit of length equal to one- Y P 9 (Micrometer) hausting contaminants from the air at the point millionth of a meter; approximately 0.000039 of where the contaminants are produced.(welding, an inch. grinding, sanding, other processes or operations). Also see General Exhaust. Mist Suspended liquid droplets generated by con- densation from the gaseous to the liquid state, or M Meter is a unit of length in the metric system. by breaking up a liquid into a dispersed state, One meter is about 39 inches. such as splashing, foaming or atomizing. Mist is formed when a finely divided liquid is suspended m3 Cubic meter is a metric measure of volume, in air. approximately 35.3 cubic feet or 1.3 cubic yards. Mixture Any combination of two or more chemi- Malaise A feeling of general discomfort, distress, cals if the combination is not, in whole or part, or uneasiness, an out-of-sorts feeling. the result of a chemical reaction. fl-8 Mid Mild NFPA technical committees. Among these is NFPA 704M, the code for showing hazards of ml Milliliter is a metric unit of capacity, equal in materials as they might be encountered under volume to 1 cubic centimeter (cc), or approxi. fire or related emergency conditions, using the mately one-sixteenth of a cubic inch. One- familiar diamond-shaped label or placard with ap- thousandth of a liter. propriate numbers or symbols. mmHg Millimeters (mm) of mercury (Hg) is a unit Neo See neoplasia. of measurement for low pressures or partial vacuums. Neonatal The first 4 weeks after birth. Molecular Weight Weight (mass) of a molecule Neoplasia A condition characterized by the based on the sum of the atomic weights of the presence of new growths (tumors). atoms that make up the molecule. Nephrotoxin A substance that,causes injury to mppcf .Million particles per cubic foot is a unit for the kidneys. expressing concentration of particles of a sub- stance suspended in air. Exposure limits for Neurotoxin A material that affects the nerve cells mineral dusts (silica, graphite, Portland cement; and may produce emotional or behavioral abnor- nuisance dusts, and others), formerly expressed malities. as.mppcf, are now more commonly expressed in mg/m3. Neutralize To eliminate potential hazards by inac- tivating strong acids, caustics, and oxidizers. For MSDS Material Safety Data Sheet. example, acids can be neutralized by adding an appropriate amount of caustic substance-to the MSHA Mine Safety and Health Administration, spill._ U.S. Department'of Labor. ng nanogram, one-billionth of a gram. Mutagen A substance or agent capable of altering the genetic material in a living cell. NIOSH National Institute for Occupational Safety and Health, U.S. Public Health Service, U.S. MW See molecular weight. Department of Health and Human Services (DHHS), among other activities, tests and certi- N2 Nitrogen is a colorless, odorless, and tasteless fies respiratory protective.devices and air sam gas that will not burn and will not support com- piing detector tubes, recommends occupational bustion:The earth's atmosphere (air) is about 78 ' exposure limits for various substances, and as- percent nitrogen. At higher concentrations, nitro- silts OSHA and MSHA in occupational safety gen can displace oxygen and become a lethal and health investigations and research. asphyxiant. See Asphyxiant. Nonflammable Not easily ignited, or-if ignited, not Narcosis A state of stupor, unconsciousness, or burning rapidly. - arrested activity produced by the influence of nar- cotics or other chemicals. Non-Sparking Tools Tools made from beryllium- copper or aluminum-bronze greatly reduce the Nausea Tendency to vomit,feeling of sickness at possibility of igniting dusts, gases,or flammable the stomach. vapors. Although these tools may emit some sparks when striking metal, the sparks have a NCI National Cancer Institute is that part of the low heat content and are not likely to ignite most National Institutes of Health that studies cancer flammable liquids. causes and prevention as well as diagnosis, treatment, and rehabilitation of.cancer,patients. NO, Oxides of nitrogen which are undesirable air pollutants. NO emissions are regulated by EPA NFPA National Fire Protection Association is an under the Clean Air Act. international.membership organization which pro- motesrmproves fire protection and prevention, NPIRS National Pesticide Information Retrieval and establishes safeguards against loss of life System is an automated data base operated by and property by fire. Best known on.the industrial Purdue University containing information on EPA scene for the National Fire Codes-16 volumes registered pesticides, including reference file of codes, standards, recommended practices and MSDS's. _ manuals developed (and periodically updated) by Y NRC National Response Center is a notification Pathologic Pertaining to or caused by disease. center that must be called when significant oil or chemical spills or other environment-related acci- Pathology Scientific study of alterations produced dents occur. The toll-free telephone number is by disease. .-800-424-8802. PEL Permissible Exposure Limit is an occupation- NTP National Toxicology Program. The NTP pub- al exposure limit established by OSHA's regulato- lishes an Annual Report on Carcinogens. ry authority. It may be a time-weighted average (TWA) limit or a maximum concentration ex- Odor A description of the. smell of the substance. posure limit. Odor Threshold The lowest concentration of a Percent Volatile Percent volatile by volume is the substance's vapor, in air, that can be smelled. percentage of a liquid or solid (by volume) that will evaporate at an ambient temperature of 70OF Olfactory Relating to the sense of smell. (unless some other temperature is specified). Ex- - amples: butane, gasoline, and paint thinner Oral Used in or taken into the body through the (mineral spirits) are 100 percent volatile; their.in- mouth. dividual evaporation rates vary, but in time, each. -Oral Toxicity Adverse effects resulting from tak- will evaporate completely. ing a substance into the body by mouth. Ordinari- pH The symbol relating the hydrogen ion (H+) ly used to denote effects in experimental animals. concentration to that of a given standard solution. A pH of 7 is neutral. Numbers increasing from 7 Organic Peroxide An organic compound that to 14 indicate greater alkalinity. Numbers contains'the bivalent -0-0 structure and may be decreasing from 7 to 0 indicate greater acidity. considered a structural derivative of hydrogen .peroxide where one or both of the hydrogen Physical Hazard Means a chemical for which atoms has been replaced by an organic radical there is scientifically valid evidence that it is-a combustible liquid, a compressed gas, explosive, Organogenesis The formation of organs during flammable, an organic peroxide, an oxidizer, development. pyrophoric, unstable (reactive) or water-reactive. OSHA Occupational Safety and Health Administra- Placenta A structure that grows on the wall of the lion, U.S. Department of Labor. uterus during pregnancy, through which the fetus is nourished. Ovary The female sex gland in which ova are formed. - PMCC Pensky-Martens Closed Cup. See Overexposure Exposure to a hazardous material Flashpoint. beyond the allowable exposure limits. pneumoconiosis A condition of the lung in which there is permanent deposition of particulate mat- Oxidation In a literal sense, oxidation is a reaction ter and the tissue reaction.to its presence. It may in which a substance combines with oxygen range from relatively harmless forms of iron oxide provided by an oxidizer or oxidizing agent. See deposition to destructive forms of silicosis. Oxidizing Agent. Poison, Class A A DOT term for extremely dan- Oxidizer A chemical other than a blasting agent gerous poisons—poisonous gases or liquids that, or explosive that initiates or promotes combustion in very small amounts, either as gas or as vapor in other materials, causing fire either by itself or of the liquid, mixed with air, are dangerous to through the release of oxygen or other gases. life. Examples: phosgene, cyanogen, hydrocyanic acid, nitrogen peroxide. Oxidizing Agent A chemical or substance that brings about an oxidation reaction. The agent Poison, Class R A DOT term for liquid, solid, may (1) provide the oxygen to the substance be- paste or semisolid substances—other than Class ing oxidized (in which case the agent has to be A poisons or irritating materials—that are known oxygen or contain oxygen), or (2) it may receive (or presumed on the basis of animal tests) to be electrons being transferred from the substance so toxic to humans that they are a hazard to undergoing oxidation (chlorine is a good oxidizing health during transportation. agent for electron-transfer purposes, even though it contains no oxygen). II-10 I r Polymerization A chemical reaction in which one Reducing agent In a reduction reaction (which at- or more small molecules combine to form larger ways occurs simultaneously with an oxidation molecules. A hazardous polymerization is such a reaction) the reducing agent is the chemical or reaction that takes place at a rate that releases substance which (1) combines with oxygen or 'large amounts of energy. If hazardous polymeri- (2) loses electrons to the reaction. See Oxidation. zation can occur with a given material, the MSDS usually will list conditions that could start the REL The NIOSH REL (Recommended Exposure reaction and—since the material usually contains Limit).is the highest allowable airborne concentra.- a polymerization inhibitor—the length of time dur- tion which is not expected to injure the workers. ing which the inhibitor will be effective. It may be expressed as a ceiling limit or as a time-weighted average (TWA). ppb Parts per billion is the concentration of a gas or vapor in air—parts (by volume) of the gas or Reproductive Toxin Substances that affect either vapor in a billion parts of air. Usually used to ex- male or female reproductive systems and may press extremely low.concentrations of unusually impair the ability to have children. toxic gases or vapors; also the concentration of a particular substance in a liquid or solid. Respiratory Protection Devices that will protect the wearer's respiratory system from overex-. ppm Parts per million is the concentration of a posure by inhalation to airborne contaminants. gas or vapor in air—parts (by volume) of the gas Respiratory protection is used when a worker or vapor in a million parts of air; also the concen- must work in an area where he/she might be.ex- tration of a particulate in a liquid or solid. . posed to concentration in excess of the allowable exposure limit. Prenatal . Preceding birth. Respiratory System The breathing system that psi Pounds per square inch (for MSDS purposes) includes the lungs and the air passages (trachea is the pressure a material exerts on the walls of or "windpipe," larynx, mouth, and nose) to-the a confining vessel or enclosure. For technical ac- air outside the body, plus the associated nervous curacy, pressure must be expressed as psig and circulatory supply. (pounds per square inch gauge) or psia (pounds per square inch. absolute; that is,.gauge.pressure Routes of Entry The means by which material plus sea level atmospheric pressure; or psig plus may gain access to the body, for example, inha- approximately 14.7 pounds per square inch). Also lation, ingestion, and skin contact. see mmHg. RCRA Resource Conservation and Recovery Act Pul See pulmonary. is environmental legislation aimed at controlling the generation, treating, storage, transportation Pulmonary Relating to, or associated with, the and disposal of hazardous wastes. It is ad- lungs. ministered by EPA. Pulmonary Edema Fluid irr the lungs. Sarcoma A tumor that is often malignant. Pyrophoric A chemical that will ignite spontane- Self-Contained Breathing Apparatus A respirato- ously in air at a temperature of 130F (54.4°C) or ry protection device that consists of a supply or la below. means of respirable air, oxygen, or oxygen- generating material, carried by the wearer. Reaction A chemical transformation or change. The interaction of two or more substances to Sensitizer A chemical that causes a substantial form new substances. proportion of exposed people or animals to de- velop an allergic reaction in normal tissue after Reactive See Unstable. repeated exposure to the chemical: Reactivity Chemical reaction with the.release of SETA Setaflash Closed Tester. See Flashpoint. energy. Undesirable effects—such as pressure buildup, temperature increase, formation of nox- Silicosis A disease of the lungs (fibrosis) caused ious, toxic or corrosive byproducts—may occur by the inhalation of silica dust. because of the reactivity of a substance to heat- ing, burning, direct contact with other materials, Skn Skin. or other conditions in use or in storage. -11 "Skin" A notation (sometimes used with PEL or ing, or that will oxidize to generate heat and TLV exposure data) that indicates that the stated ignite, or that absorbs moisture to generate heat I substance may be absorbed by the skin, mucous and ignite. membranes, and eyes—either airborne or by direct contact—and that this additional exposure Squamous Scaly or platelike. must be considered part of the total exposure to avoid exceeding the PEL or TLV for that sub- Stability The ability of a material to remain un stance. changed. For MSDS purposes, a material is sta- ble if it remains in the same form under expected Skin Absorption Ability of some hazardous chem- and reasonable conditions of storage or use. icals to pass directly through the skin and enter Conditions that may cause instability (dangerous the bloodstream. change) are stated; for example, temperatures above 1500F.; shock from dropping. Skin Sensitizer See Sensitizer. STEL Short-Term Exposure Limit (ACGIH termi- Skin Toxicity See Dermal Toxicity. nology). See TLV. i Solubility in Water A term expressing the per Stenosis Narrowing of a body passage or centage of a material (by weight) that will dis- opening. solve in water at ambient temperature. Solubility information can be useful in determining spill Steroid A complex molecule among which are the cleanup methods and reextinguishing agents and male and female sex hormones. methods fora material. Subcutaneous Beneath the layers of the skin. Solvent A substance, usually a liquid, in which other substances are dissolved. The most com Supplied-Air Respirators Air line respirators'of mon solvent is water. self-contained breathing apparatus. SOx, Oxides of sulfur. _ Sys System or systemic.. Species On the MSDS's, species refers to the Systemic Poison A poison that spreads through- test animals—usually rats, mice, or rabbits-used out the body, affecting all body systems and or- to obtain the toxicity test data reported. gans. Its adverse effect is not localized in one spot or area. Specific Chemical Identity The chemical name, Chemical Abstracts Service (CAS) Registry Num- Systemic Toxicity Adverse effects caused by a ber, or any precise chemical designation of a substance that affects the body in a general substance. rather than local manner. Specific Gravity The weight of a material com- Synonym Another name or names by which a pared to the weight of an equal volume of water material is known. Methyl alcohol, for example, is is an expression of the density'(or heaviness)of known as methanol or wood alcohol. a material. Insoluble materials with specific gravi- ty of less than 1.0 will float in (or on) water. In- Target Organ Effects The following is a target or- soluble materials with specific gravity greater gan categorization of effects that may occur, in- than 1.0 will sink in water. Most (but not all) flam- eluding examples of signs and symptoms and mable liquids have specific gravity less than 1.0 chemicals that have been found to cause such and, if not soluble, will float on water—an impor- effects. These examples are presented to illus- tant consideration for fire suppression. trate the range and diversity of effects and haz- ards found in the workplace, and the broad Spill or. Leak Procedures The methods, equip- scope employers must consider in this area, but ment, and precautions that should be used to they are not intended to be all inclusive. control or clean up a leak or spill. Splash-Proof Goggles Eye protection made of a noncorrosive material that fits snugly against the (a) Hepatotoxins Chemicals that produce face, and has indirect ventilation ports. liver damage. Signs and Jaundice; liver enlarge- Spontaneously Combustible A material that ig- Symptoms ment. nites as a result of retained heat from process- Chemicals Carbon tetrachloride; nitrosamines. II-12 P(b) Ne hrotoxins Chemicals that produce . Target Organ Toxin ' A toxic substance that at- kidney damage. tacks a specific organ of the body. For example, Signs and Edema; proteinuria. overexposure to carbon tetrachloride can cause liver damage. Symptoms Chemicals Halogenated hydrocar- TCC Tag (Tagliabue) Closed Cup. See Flashpoint. bons; uranium. TCL Toxic concentration low, the lowest concen- (c) Neurotoxins Chemicals that produce tration of a gas or vapor capable of producing a their primary toxic effects defined toxic effect in a specified test species on the nervous system. over a specified. time. Signs and Narcosis,; behavioral TDL Toxic dose low, lowest administered dose of Symptoms changes; decrease in mo- a material capable of producing a defined toxic for functions. effect in a specified test species. Chemicals Mercury, carbon disulfide. Temp Temperature. (d) Agents that act Decrease hemoglobin func- Ter See Teratogen. on blood hema- tion; deprive the body topoietic system tissues of oxygen. Teratogen A substance or agent, exposure to Signs and Cyanosis; loss of con- which by a pregnant female can result in malfor Symptoms sciousness. mations in the fetus. Chemicals Carbon monoxide; Tfx Toxic effect(s). cyanides (e) Agents that Chemicals that irritate or TLV Threshold Limit Value is a term used by damage the damage the pulmonary ACGIH to express the airborne concentration of lung tissue. material to which nearly all persons can be. ex- lung day after day without adverse effects. Signs and Cough, tightness in chest, ACGIH expresses TLVs in three ways: ; Symptoms shortness of breath.. Chemicals Silica; asbestos. TLV-TWA: The allowable Time-Weighted Aver- age concentration for a normal 8-hour workday (f) Reproductive Chemicals that adversely or 80-hour workweek. _ toxins affect the reproductive TLV-STEL: The Short-Term Exposure Lim , or Limit, capabilities including chro- maximum concentration for a continuous mosomal damage (muta- 15-minute exposure period (.maximum of four tions) and effects on such periods per day, with at least 60 minutes fetuses-(teratogenesis). between exposure periods, and provided the Signs and Birth defects; sterility. daily TLV-TWA is not exceeded): Symptoms - Chemicals Lead; DBCP TLV-C: The ceiling exposure limit—the concen- tration that should not be exceeded even in- (g) Cutaneous Chemicals that affect the stantaneously. hazards dermal layer of the body. TOC Tag Open Cup. See Flashpoint. Signs and Defatting of the skin; Symptoms rashes,irritation. Tom A unit of pressure, equal to 1/760 at Chemicals Ketones; chlorinated cons- mosphere. pounds. Toxic A chemical falling within any of the follow- (h) Eye hazards Chemicals that affect the ing categories: eye or visual capacity. (a) A chemical that has a median lethal dose than 50 milligrams per kilo- Symptoms of more t P I 9 cornea ( so) i and Conjunctivitis; . .S gns Symptoms damage. gram but not more than 500 milligrams per kilogram of body weight when administered Chemicals Organic solvents; acids. orally to albino rats weighing between 200 and 300 grams each. II-13 (b) A chemical that has a median lethal dose ug Microgram, one-millionth of a gram. (L D50) of more than 200 milligrams per kilo- gram but not more than 1,000 milligrams per Unstable Tending toward decomposition or other kilogram of body weight when administered unwanted chemical change during normal han- by continuous contact for 24 hours (or less if dling or storage. death occurs within 24 hours) with the bare skin of albino rabbits weighing between two Unstable Reactive A chemical that, in the pure and three kilograms each. state, or as produced or transported, will vigorously polymerize, decompose, condense, or (c) A chemical that has a median lethal concen- become self-reactive under conditions of shocks, tration (LC50)-in air of more than 200 parts pressure, or temperature. per million but not more than 2,000 parts per million by volume of gas or vapor, or more USDA U.S. Department of Agriculture. than two milligrams per liter but not more than 20 milligrams per liter of mist, fume, or Vapor The gaseous form of a solid or liquid sub- dust, when administered by continuous inha- stance as it evaporates. lation for one hour (or less if death occurs within 1 hour) to albino rats weighing between Vapor density The weight of a vapor or gas com 200 and 300 grams each. pared to.the weight of an equal volume of air is . an expression of the density of the vapor or gas. Toxic Substance Any substance that can cause Materials lighter than air have vapor densities acute or chronic injury to the human body, or less than 1.0 (examples: acetylene, methane, which is suspected of being able to cause dis- hydrogen). Materials heavier than air (examples: eases or injury under some conditions. propane, hydrogen sulfide, ethane, butane, chlo- rine, sulfur dioxide) have vapor densities greater Toxicity The sum of adverse effects resulting than 1.0. All vapors and gases will mix with air, ,from exposure to a material, generally, by the but the lighter materials will tend to rise and dis- mou'th, skin, or respiratory tract. sipate (unless confined). Heavier vapors and gases are likely to concentrate in low places— Trade Name The trademark name or commercial along or under floors, in sumps, sewers, and trade name for a material or product. manholes, in trenches and ditches-where they kill may. create fire or health hazards. - Transplacental An agent that causes physical defects in the developing embryo. Vapor pressure The pressure exerted by a satu- rated vapor above its own liquid in a�closed con- TSCA Toxic Substances Control Act (Federal En- tainer. When quality control tests are performed vironmental Legislation administered by EPA) on products, the test temperature is usually regulates the manufacture, handling, and use of 100°F, and the vapor pressure is expressed as materials classified as "toxic substances." pounds per square inch (psig or psia), but vapor pressures reported as MSDS's are in millimeters TWA Time-Weighted Average exposure is the air- of mercury (mmHg) at 68OF (200C), unless stated R borne concentration of a material to which a per- overwise. Three facts are important to remember: son is exposed, averaged over the total exposure time—generally the total workday (8 to 12 hours). 1. Vapor pressure of a substance at 100OF will Also see TLV. always be higher than the vapor pressure of i the substance at 680F (200C). UEL, or UFL Upper explosive limit or upper flam- mable , the highest con- 2. Vapor pressures reported on MSDS s in limit of a.vapor or gas; g � centration (highest percentage of the substance mmHg are usually very low pressures; 760mmHg is equivalent to 14.7 pounds per in air) that will produce a flash of fire when an ig- square inch. nition source (heat, arc; or flame) is present. At ' higher concentrations, the mixture is too "rich" 3. The lower the boiling point of a substance, the to burn. Also see LEL. higher its vapor pressure. 11-14 f I . Ventilation See General Exhaust, Local Exhaust, Water-Reactive A chemical that reacts with water and Mechanical Exhaust. to release a gas that is either flammable or presents a health hazard. Vermiculite An expanded mica (hydrated magnesium-aluminum-iron silicate) used as sor Work Area A room or defined space in a work- bent for spill control and cleanup. place where hazardous chemicals are produced or used, and where employees are present. Viscosity The tendency of a fluid to resist internal flow without regard to its density. Workplace An establishment at one geographic%' location containing one or more work areas. Volatility A measure of how quickly a substance forms a vapor at ordinary temperatures. Zinc Fume Fever A condition. brought on by inha.. lation of zinc oxide fume characterized by flulike Water Disposal Methods Proper disposal symptoms with a metallic taste in the mouth, methods for contaminated material, recovered liq- coughing, weakness, fatigue; muscular pain, and uids or solids, and their containers. nausea, followed by fever and chills. The onset of symptoms occurs four to twelve hours after eY- posure. Date: TOWN OF BARN TABL TOXIC AND HAZARDOUS MATERIALS ON-SIT INVENTORY NAME OF BUSINESS: BUSINESS LOCATION: INVENTORY MAILING ADDRESS: TOTAL AMOUNT: TELEPHONE NUMBER: -jo�,G�,�,✓'133 CONTACT PERSON: Mydz//wl EMERGENCY CONTACT TELEPHONE NUMBER: MSDS ON SITE? TYPE OF BUSINESS: �hb d.!'IMLL 54,14 l oeir Ue. INFORMATION/RECOMMENDATIONS: ����1 041 t -ll �'� dJ? � dl&ire ; trict: . ta,&6 , 6 LQS:� li 1/,64ply ` f--M 5 W& 1421 Vallfba) 21 dre 1 Waste Transportati n: Last, shipment of hazardous,waste: Name of Hauler• Destination: Waste Product: Licensed? Yes No NOTE: Under the provisions of Ch. 111, ection 31, of the General Laws of MA, hazardous materials use, storage and disposal of 111 gallons or more a month requires a license from the Public Health Division. LIST OF TOXIC AND HAZARDOUS MATERIALS The Board of Health and the Public Health Division have determined that the following products exhibit toxic or hazardous characteristics and must be registered regardless of volume. Observed/Maximum Observed/Maximum Antifreeze (for gasoline or coolant systems) _ Misc. Corrosive Od NEW MUSED Cesspool cleaners Automatic transmission fluid Disinfectants Engine and radiator flushes Road Salts (Halite) Hydraulic fluid (including brake fluid) Refrigerants U Motor Oils Pesticides NEW NO USED (insecticides, herbicides, rodenticides) Gasoline, Jet fuel, Aviation gas Photochemicals (Fixers) Diesel Fuel, kerosene, #2 heating oil NEW USED Misc. petroleum products: grease, Photochemicals (Developer) lubricants, gear oil NEW USED Degreasers for engines and metal Printing ink Degreasers for driveways &garages Wood preservatives (creosote) Caulk/Grout Swimming pool chlorine Battery acid (electrolyte)/Batteries Lye or caustic soda Rustproofers Misc. Combustible Car wash detergents Leather dyes Car waxes and polishes Fertilizers Asphalt & roofing tar PCB's Paints, varnishes, stains, dyes Other chlorinated hydrocarbons, Lacquer thinners (inc. carbon tetrachloride) NEW USED Any other products with "poison" labels Paint &varnish removers, deglossers (including chloroform, formaldehyde, Misc. Flammables hydrochloric acid, other acids) Floor&furniture strippers Other products not listed which you feel Metal polishes may be toxic or hazardous (please list): Laundry soil & stain removers C� -0 lb,6 (including bleach) Spot removers &cleaning fluids (dry cleaners) Other cleaning solvents Bug and tar removers Windshield wash WHITE COPY-HEALTH DEPARTMENT/CANARY COPY-BUSINESS ctS�eGC- Date: TOWN OF BARNSTABLE P. TOXIC AND HAZARDOUS MATERIALS ON-SITE INVENTORY NAME OF BUSINESS: -fv-kaf &,d� BUSINESS LOCATION: &Iff& 1/ " Pt Ua it I(�_ INVEN _ MAILING ADDRESS: �i T ALA OUNT: TELEPHONE NUMBER: 8� �—� Qt• � � U d� CONTACT PERSON: flP�PGA EMERGENCY CONTACT TELEPHONE NUMBER: MSDS ON SITE? TYPE OF BUSINESS: 2 INFORMATION/RECOMMENDATION �� �-�� �� C!�/,l .Q dK Fire District: ou bl'E y D_ . O s Waste T ansportation: Last shipment of hazardous waste: Name of Hauler- Destination: Waste Product: dd Licensed? Yes No NOTE: Under the provisions of Ch. 111, Sec Ion 31, of the General Laws of MA, hazardous materials use, storage and disposal of 111 gallons or more a month requires a license from the Public Health Division. LIST OF TOXIC AND HAZARDOUS MATERIALS The Board of.Health and the Public Health Division have determined that the following products exhibit toxic or hazardous characteristics and must be registered regardless of volume. Obs rued/Maximum Observed/Maximum Antifreeze (for gasoline or coolant systems) Misc. Corrosive jj NEW USED Cesspool cleaners Automatic transmission fluid Disinfectants Engine and radiator flushes Road Salts (Halite) Hydraulic fluid (including brake fluid) Refrigerants 3 Motor Oils Pesticides IVLNEW USED (insecticides, herbicides, rodenticides) Gasoline, Jet fuel, Aviation gas Photochemicals (Fixers) Diesel Fuel, kerosene, #2 heating oil NEW USED Misc. petroleum products: grease, Photochemicals (Developer) lubricants, gear oil NEW USED Degreasers for engines and metal Printing ink Degreasers for driveways &garages Wood preservatives (creosote) Caulk/Grout Swimming pool chlorine Battery acid (electrolyte)/Batteries Lye or caustic soda Rustproofers d Misc. Combustible Car wash detergents Leather dyes Car waxes and polishes Fertilizers Asphalt & roofing tar PCB's Paints, varnishes, stains, dyes Other chlorinated hydrocarbons, Lacquer thinners (inc. carbon tetrachloride) NEW USED Any other products with "poison" labels Paint &varnish removers, deglossers (including chloroform, formaldehyde, Misc. Flammables hydrochloric acid, other acids) Floor&furniture strippers Other products not listed which you feel Metal polishes may be toxic or hazardous (please list): Laundry soil & stain removers 6ky � (including bleach) Spot removers & cleaning fluids (dry cleaners) Other cleaning solvents Bug and tar removers Windshield wash :4 WHITE COPY-HEALTH DEPARTMENT/CANARY COPY-BUSINESS ! Town of Barnstable-Health Department Page 1 HAZARDOUS MATERIALS INVENTORY SITE VISITS DBA: Tracy Audi Volkswagon Fax: — Corp Name: Mailing Address a ....... ....._.. ....... _._......_ Location: 686 lyanough Road,Hyannis Street: P.O.Box 460 .......................... ................. mappar: City: Hyannis Contact: :John Medieros,Service Manager State: Ma Telephone: "508-775-3049 Zip: 02601 Emergency: 508-775-3468 Person Interviewed: Pete/Dan,Service and Parts Business Contact Letter Date: Category: VehicleMaintenance Inventory Site Visit Date: Type: :Automobile Dealers Follow.Up/Inspection Date: ❑� public water indoor floor drains ❑ outdoor surface drains ❑d license required ❑ private water ❑ indoor holding tank mdc ❑d outdoor holding tank mdc ❑d currently licensed ❑d town sewage ❑ indoor catch basin/drywell ❑ outdoor catch basin/drywell expir -- date: 6/30/2006 ❑ on-site sewage ❑ indoor on-site syste ❑ outdoor onsite system - / ............. Alternate emergency phone number:775-3468 ********See Donna- compliance: she has registration form as there is some question about use of Satisfactory property. Remarks 1/4196: Drains-MDC Trap(Inside)-Oil Separator (Baffles/Skimmer),Oil Separator installed 1 yr.ago by Canco. Inside tanks all have secondary containment parts washer unit-ZEP,Brake washing unit-Safety kleen,Freon Recovery Recycling Center,Oil Filters recycled. Remarks:3/24/97 MSDS sheets on site,absorbant mats, pillows,spill kit,rags&sped!-dry. Acme Apparel Master-laundry,7 hydraulic lifts. See 97 inspection report for current list of chemicals. 6/29/04 Onsite inventory&inspection. Staff has annual Right to Know and OSHA training. Shops are clean. MSDS and manifests onsite. First aid,eyewash,clean lunch area. Fire extinguishers currently serviced. Hazwaste storage is good. Oil filters taken by hauler every two weeks. ORDERS: Outdoor tire storage limit is 10 tires-and these must be covered. Obtain metal cans with metal lids for shop rags. Label all Hazardous Waste containers(used antifreeze containers),"Toxic"and"Hazardous Waste". Don't eat in shop area-workers should eat only in designated lunchroom. 10/11/05 alp-OBSERVATIONS:John Furrh every April to complete trainig,no contingency plan posted,MSDS present,oily rag cans present,new exhaust system to channel exhaust outside,fixed eyewash stations, absorbent pads,all caps on,cylinders are chained,tires are picked up every 2 days(12 outside at time of visit),waste oil is contained,floor washed every Friday(do have an oil/water seperator,all waste accumulation is properly labeled,drain all quarts of oil for 24 hours before throwing out.ORDERS: obtain new storage for old batteries- current is a rusted out tank that is sitting outdoors not on an impervious surface(photos on file),with a temporary lid.Place batteries indoors on an impervious surface until new container is obtained, remove all waste product immediately from catchpans,ensure wash water from the garage doesn't exit the facility onto the ground, recommend a burm for use to contain the water. Page 2 Town of Barnstable-Health Department HAZARDOUS MATERIALS INVENTORY Chemicals: ❑ Zero Toxic Waste Materials ❑ gty's>25 Ibs dry or 50 gals liquid but less than 111 gals gty's 111 gals or more ,unit,of,meas,rei car wash detergents ( 50 allons other cleaning solvents 55 gallons Misc.Flammable 12 gallons misc.petroleum products:grease,lubricants 89 gallons _.._...,.______..._..__._...._...____...__.._.._........._._..__._........_....__._.____._.__.._......._ ...._..__.__._-___...__............................_...........__......_............. .._......_._....._.__ automatic transmission fluid 12 gallons motor oil 378 gallons_ Windshield Wash _._..__ 74 gallons Batteries 128 gallons antifreeze(for gasoline or coolant systems) [ 79 gallons waste oil I 375 gallons __....._.._. _....___....._____- _..�.._____._. _ _ -..-..._......-.____ __.__._----- waste antifreeze 205 gallons gasoline 15 gallons _____....._....._..____.._...._.._ ___.._..._..._._ _ __.. ...__.___..__....____.._.....__....._.____.__.___...__..__..______ Misc.Combustible 10 gallons Misc.Corrosive 5 gallons _._."....._....._...................._.....__.__.__. .._._.._______._ _ _____.........__................-.___..__..... ......__._._. diesel fuel,kerosene,#2 heating oil 5 gallons _.._..._............____.__.........._._.._....... .__.._._.___....._..._...._.........______.._.._.__.._._ _.. ._...___ oil filters 220 gallons hydraulic fluids(including break fluid) 30 gallons Waste Transporter: Cyn Oil Fire District: ;Hyannis Last HW Shipment Date: 10/4/2005 Waste Hauler Licensed: Yes ti Town of Barnstable 'D • Gam' °Ft►+E rq,,, Regulatory Services Thomas F. Geiler,Director f0W4 13F BARNSTABLE `"MAW. `1639. Public Health DivisioU05 JUPd 15 PM 3: 35 (p ' iDTen Mai° Thomas McKean,Director 200 Main Street, Hyannis, MA�0260 ---,— Office: 508-862-4644 Fax: 508-790-6304 Application Fee: $100.00 ASSESSORS MAP AND PARCEL NO. DATE APPLICATION FOR PERMIT TO STORE AND/OR UTILIZE MORE THAN 111 GALLONS OF HAZARDOUS MATERIALS FULL NAME OF APPLICANT MAA u d LU —IQxW NAME OF ESTABLISHMENT ADDRESS OF ESTABLISHMENT u'c 13 a H& 0[S M L 0�U o 1 TELEPHONE NUMBER SOLE OWNER: YES NO IF APPLICANT IS A PARTNERSHIP,FULL NAME AND HOME ADDRESS OF ALL PARTNERS: IF APPLICANT IS A CORPORATION: FEDERAL IDENTIFICATION NO.042g 3 2-s�sq STATE OF INCORPORATIONSC,1�U- N-S FULL NAME AND HOME ADDRESS OF: . PRESIDENT 0-Jr u H.T(- r a a9L4 M i 5 h L DI r. H6V5-I-W) M,i I S HA 0-;�U q X TREASURER t)n �C4 i rac SQmk 05 000'x— CLERK Rtyy-t(d A. C'ti SS 8 white oaG , Tr0t't 0emeruuic, HA. DaLv 3`L r SIGNATURE OF APPLICANT RESTRICTIONS: HOME ADDRESS is b(&.r Ifi)! jQn f, -fttnS& M6 ®'�(P& HOME TELEPHONE# 508-L49D-;0 gp Haz.doc/wp/q f f.r�r OIL WASTE OIL / OIL FILTERS ANTIFREEZE/ WASTE f D II OS t/ I/ ANITFREEZE caT al- �° �� iPa 11 v GASOLINE WASTE GAS WASTE /W FLUID ATF SOLVENT / ® ' -14 a �� i HYDRAULIC MISC. MISC. MISC. MISC. FLUID COMMBUSTIBLE FLAMMABLE CORROSIV PETROLEUM (GEAR OIL/GREASE/ / LUBRICANTS) 5 Ip i a FREON ACETYLENE CAR WASH CAR WASH PAINTS/ WAX DETERGENTS THINNERS D SEALANT CLEANING BAT-TE-PjES/ POISION/TOXIC CAULK/GROUT SOLVENTS V/ BATTERY ACID FERTALIZERS DIESEL FUE. / OIL FI ERS HYD ULIC V �L a xs� B FLUI a-v ✓ `G p ol 6,eAl V-a� ,�- o l�- b � Sfis� �%►,. h�.�---�`� ol�Z'vr` -cry.° -f� `�� �6 /1 aCc u lh. ✓O -)off-� ✓ CW ' 7 6W e d ;r. >14— �. 1 � 0 I-vi-gc / VoIIe--,W Al _ 1/2 rx �a Hall t;UKIL - sf�.�-� �-v� U scab ��+I'�n� -ouf d oa►�s Kbt on a ki unnPu US sLArflLce- ..�; � �N,�°�-'*2`yr. A. � ".��y t `� r • .�- ,i o , a t. ,�• l "�� � .��. �, r� �� .� �;'�<•` .may~ _ Ack Tra #f"w x7� -0 u.�d o o r Stv used b-ttt-cn ,f l 1 Vu S f7.h.c1 O u-- O-A fj 6G�Oyy► o c py�'{�.� v - not on an �/z Z-75 la-lion t-&vtk-. I i I Ah :# 3-P wSt LOA 3 sYW /I 1 aY� ah a � r A � y � 1v J�•^c�`�� err,.4 .A � �. ,ry 1. 4 ray\E �� i*�3 p..]'S .�.�,' c�`�,�` �•�C � .v, _ �N. f i •�� � I Y�Gy VDIIGSw�ar► —Owl door 5{-tiraciL -fw Utcd �jattwte� bD -vm of - hot on an inn pervi bus S 1 'r K— e .jo °r'� A44-z . `7— 40 0 y ��h Date: r /29/ a cy O N OF BARNSTA j�, A OUS MATERIALS ON-SITE INV T R �� '�� ,TOXIC , �a NAME OF BUSINESS: y J i l4- BUSINESS LOCATION: INVENTOR�� MAILING ADDRESS: #It �'� OUNT: TELEPHONE NUMBER: SOS- '7-75- 3 ® 401 6 S, .SQQ,GIcy�s CONTACT PERSON: EMERGENCY CONTACT TEL PHONE NUMBER: MSDS ON SITE? TYPE OF BUSINESS: _ A%dia odeake, /,Se-.Gv.'e,e- q ea, INFORMATION/RECOMMENDATIONS: �a-�," s S-A= a iS Fire District: : 4a 777e�_rA/ ar,nd ejn/'e-.eea(, /`,/kar� 123 aAad Cans r 1615 12 L`0 vi 01e,s-r A. QAdLAOI oa s. �X/Gof "a�»d 44zd<i VVAs'r-E'.u t/1J"R.e-7 shot44,d n4,,*-eccs* i c7 .5h4e azeeL. Waste Transportation: Last shipment of hazardous.waste: Name of Hauler:C" Destination: aste Product: CyiA . A Licensed? a No NOTE: Under the provisions of Ch. 111, Section 31, of the General Laws of MA, hazardous materials use, e and disposal of 111 gallons or more a month requires a license from the Public Health Division, LIST OF TOXIC AND HAZARDOUS MATERIALS ° ' n 3 o - , /�-fs�st 'ea�k-r s ec�. The Board of Health and the Public Health Division have determined that the following products exhibit toxic or hazardous characteristics and must be registered regardless of volume. Observed/Maximum Observed/Maximum Antifreeze (for gasoline or coolant systems) Misc. Corrosive till I-IffW -USED Cesspool cleaners a, Automatic trans SrA-9sion fluid Disinfectants Engine and radiator flushes Road Salts (Halite) Hydraulic fluid (including brake fluid) Refrigerants Motor Oils 1200 Pesticides y�EW USED (insecticides, herbicides, rodenticides) Gasoline, Jet ufiuel, Aviation gas Photochemicals Fixers Diesel Fuel, kerosene, #2 heating oil NEW USED 6 Misc, petroleum products: grease, Photochemicals (Developer) Ll lubricants, gear oil NEW USED Degreasers for engines and metal Printing ink Degreasers for driveways &garages Wood preservatives (creosote) Caulk/Grout Swimming pool chlorine 46 Battery acid (electrolyte)/Batteries Lye or caustic soda Rustproofers Misc. Combustible J7A Car wash detergents Leather dyes Car waxes and polishes Fertilizers Asphalt & roofing tar PCB's Paints, varnishes, stains, dyes Other chlorinated hydrocarbons, Lacquer thinners (inc. carbon tetrachloride) NEW USED Any other products with "poison" labels 2 Paint &varnish removers, deglossers (including chloroform, formaldehyde, Misc. Flammables hydrochloric acid, other acids) Floor &furniture strippers Other products not listed which you feel Metal polishes may be toxic or hazardous (please list): Laundry soil &stain removers (including bleach) Spot removers &cleaning fluids (dry cleaners) Other cleaning solvents Bug and tar removers J�— Windshield wash WHITE COPY-HEALTH DEPARTMENT/CANARY COPY-BUSINESS p Town of Barnstable-Health Department Page 1 HAZARDOUS MATERIALS INVENTORY SITE VISITS Tracy Volkswagon Fax: I Corp Name: j Mailing Address ' Location: 686 lyanough Road,Hyannis Street. P.O.Box 460 mappar: �® City: Hyannis Contact: 'John Medieros State: Ma `/ I Telephone: 508-775-3049 Zip: 02601: / 3 Emergency: 508-775-3468 Person Interviewed: Business Contact Letter Date: 6/24/2004 Category: VehicleMaintenance Inventory Site Visit Date: 6/29/2004 Type: Automobile Dealers Follow Up/Inspection Date: ❑� public water indoor floor drains outdoor surface drains license requir d v ❑ private water ❑ indoor holding tank mdc ❑ outdoor holding tank mdc currently licens d d❑ town sewage ❑ indoor catch basin/drywell ❑ outdoor catch basin/drywell expir - - - - ❑ on-site sewage ❑ indoor on-site syste ❑ outdoor onsite system date: 6119120``0 Alternate emergency phone number:775-3468 ""'****"See Donna- compliance: she has registration form as there is some question about use of Satisfactory Scrz-t/� property. Remarks 1/4/96: Drains-MDC Trap(Inside)-Oil Separator (Baffles/Skimmer),Oil Separator installed 1 yr.ago by Canco. Inside tanks all have secondary containment parts washer unit-ZEP,Brake washing unit-Safety kleen,Freon Recovery Recycling Center,Oil Filters recycled. Remarks:3124/97 MSDS sheets on site,absorbant mats, pillows,spill kit,rags&sped!-dry. Acme Apparel Master-laundry,7 hydraulic lifts. See 97 inspection report for current list of chemicals. 6/29/04 Onsite inventory&inspection. Staff has annual Right to Know and OSHA training. Z) z - 1p ? 2� 2� C LA CIA- psi . Uri✓ 3 (� /J -� I w Page 2 i .t Town of Barnstable-Health Department HAZARDOUS MATERIALS INVENTORY Chemicals: ❑ Zero Toxic Waste Materials d❑ gty's>25 Ibs dry or 50 gals liquid but less than 111 gals ❑ gty's 111 gals or more description „ qt:T unitM me�`si re antifreeze(for gasoline or coolant systems) 25{gallons _..___............_........__..__...__.__.._.........._........................_.....___._....._._.,...._.._..._._....__._.._..............................._........_.......... _.__...._..... waste antifreeze 275 gallons ._....... motor oil _ 400gallons waste oil 400gallons .......__.....__..__.__................................_._............_....._.._............_ ....,... ............._....._..........................__................_....._..._.p..._....__......_.............._.........._.........__...._.......,............_.........................,,. automatic transmission fluid 1 1cases refrigerants ? 60pounds car wash detergentsi 25gallons Waste Transporter: Cyn Oil Fire District: Last HW Shipment Date: Waste Hauler Licensed: No VW"' 4et-------------------------- r 1V6: "V OLA �6-zo 1&vvle . i ;A Town of Barnstable � 'nwti Regulatory Services Thomas F. Geiler,Director Public Health Division Thomas McKean,Director 200 Main Street, Hyannis,MA 02601 Office: 508-862-4644 Fax: 508-790-6304 Application Fee:$100.00 ASSESSORS MAP AND PARCEL NO. DATE APPLICATION FOR PERMIT.TO STORE.AND/OR UTILIZE MORE THAN 111.GALLONS.OF.HAZARDOUS MATERIALS FULL NAME OF APPLICANT NAME OF ESTABLISHMENT C ADDRESS OF ESTABLISHMENT Rp 0-e IS2-� i 1 UZCDUl TELEPHONE NUMBER 503 SOLE OWNER: YES NO r r IF APPLICANT IS A PARTNERSHIP,FULL NAME AND HOME ADDRESS OFALI, p PARTNERS: c� c Co C11 r j IF APPLICANT IS A CORPORATION: FEDERAL IDENTIFICATION NO. STATE OF INCORPORATION FULL NAME AND HOME ADDRESS OF: PRESIDENT S l C D/• �'IG� �+'1 O (r111StjY9 02-Lu TREASURER 0-?L4 H11hISN D1, LLO 1115 2�oqs CLERK SIGNATMRE OF APPLICA RESTRICTIONS: HO JTLEPHONE SS HOM # Haz.doc/wp/q MAIL-IN REQUESTS - Please mail the completed application form to the address below. Also include a copy of your contingency plan (to handle hazardous waste spills, etc). In addition,please include the required fee of$100. Make check payable to: Town of Barnstable. Allow five to seven(7)working days for in- house processing. Our mailing address is: Town of Barnstable Public Health Division 200 Main Street Hyannis,MA 02601 FOR FAXED REQUESTS Our fax number is (508) 790-6304. Please fax a completed application form. Also, please fax us a copy of your contingency plan (to handle hazardous waste spills, etc). In addition, please.mail the required fee amount of$100.00. Please make the check payable to: Town of Barnstable. The check must be mailed to the address listed above. Allow up to four days for in-house processing. For further assistance on any item above, call(508) 862-4644 C5�'1 ca 4) I _ _ Date: /29/ a`Y TOWN OF BARNSTABLE TOXIC AND HAZARDOUS MATERIALS ON-SITE INVENTORY NAME OF BUSINESS: BUSINESS LOCATION: INVENTORY MAILING ADDRESS: !� TOTAL AMOUNT: TELEPHONE NUMBER: 5 oM- -7-76-- 3 o 4 c 0_?02� S. .SQc�G(chs CONTACT PERSON: 004LA, EMERGENCY CONTACT TEL PHONE NUMBER: MSDS ON SITE? TYPE OF BUSINESS: �"� �e��" f�•S /� �- _ INFORMATION/RECOMMENDATIONS: � �'� " B sru. %s Fire District: 4 z� A 4a Twit/ cr�-,d f✓a-i�u [� [',c1/e�.�e lire.terra-u ea:. e�$tt t C n7_ e ca 1. 5 e f,ce_ry►u o iao"AaA A:: r� Qld t r t 14e4 2AA CO vtJ�F s�C" t�iJaz if .s Yho toad r_�Psi- 6&&d �•r1 3ke c"ec`. Waste Transportation: Last shipment of hazardous_waste: Name of Haule CAyl Destination: tNOTE?: te Product:�t seA� - Licensed? a No Under the provisions of Ch. 111, Section 31, of the General Laws of MA, hazardous materials use, and disposal of 111 gallons or more a month requires a license from the Public Health Division. LIST OF TOXIC AND HAZARDOUS MATERIALS P re - a The Board of Health and the Public Health Division have determined that the following products exhibit toxic or hazardous characteristics and must be registered regardless of volume. Observed/Maximum Observed/Maximum Antifreeze (for gasoline or coolant systems) Misc. Corrosive /Z.f. SW _SUSED Cesspool cleaners �o aA Automatic transrrWsion fluid Disinfectants Engine and radiator flushes Road Salts (Halite) Hydraulic fluid (including brake fluid) Refrigerants Motor Oils Pesticides W- EW 1. 200 USED (insecticides, herbicides, rodenticides) Gasoline, Jet u5el, Aviation gas Photochemicals Fixers Diesel Fuel, kerosene, #2 heating oil NEW USED 2 Misc. petroleum products: grease, Photochemicals (Developer) lubricants, gear oil NEW USED Degreasers for engines and metal Printing ink Degreasers for driveways & garages Wood preservatives (creosote) Caulk/Grout Swimming pool chlorine �f2 Battery acid (electrolyte)/Batteries Lye or caustic soda Rustproofers Misc. Combustible J Car wash detergents Leather dyes Car waxes and polishes Fertilizers Asphalt & roofing tar PCB's Paints, varnishes, stains, dyes Other chlorinated hydrocarbons, Lacquer thinners (inc. carbon tetrachloride) NEW USED Any other products with "poison" labels 2-• Paint &varnish removers, deglossers (including chloroform, formaldehyde, Misc. Flammables hydrochloric acid, other acids) Floor&furniture strippers Other products not listed which you feel Metal polishes may be toxic or hazardous (please list): Laundry soil & stain removers (including bleach) Spot removers &cleaning fluids (dry cleaners) 1576 Pk Other cleaning solvents Bug and tar removers Windshield wash WHITE COPY-HEALTH DEPARTMENT/CANARY COPY-BUSINESS r TOWN OF BARNSTABLE COMPLIANCE: CLASS: 1.Marine,Gas Stations,Repair satisfactory 2.Printers BOARD OF HEALTH 3.Auto Body Shops jj O unsatisfactory- 4.Manufacturers COMPANY L'� d���fi?� (see"Orders") 5.Retail Stores 6.Fuel Suppliers ADDRESS 7.Miscellaneous �Y'- UANTITIES AND STORAGE (IN=indoors;OUT-outdoors) MAJOR MATES Case lots Drums Above Tanks Underground Tanks IN OUT IN OUT IN OUT #&gallons Age Test Fuels: Gasoline,Jat-FireLkA�_ .s Heavy Oils: waste motor oil (C) v new motor oil (C) �( v transmissiori/hydraulic 2� Synthetic Organics: degreasers Miscellaneous: Al _o DISPOS LUREMAIWATION REMARKS: r` 1. S nitary Sewage ''S 2.Water Supply ,WTown Sewer ^.� Public Q On-site a QPrivate 4 r 3. Indoor Floor Drains j YESVNO`_ r , O Holding tank:MDC Q Catch basin/Dry well - �„J Q On-site system 4. Outdoor Surface drains:YES NO V ORDER -. Q Holding tank:MDC �.` dw k t' ffe O Catch basin/Dry well O On-site system 5.Waste Transporter Name of Hauler Destination Waste Product OE Person(s) Vfte ed Inspector Date i ` Date: `�6 TOXICAND HAZARDOUS MATERIALS REGISTRATION FORM NAMEOFBUSINESS: BUSINESS LOCATION: C� �-- MAILING ADDRESS: Mail To: TELEPHONE NUMBER: Board of Health .�� ��� Town of Barnstable CONTACTPERSON: P.O. Box 534 EMERGENCY CONTACT TELEPHONE NUMBER: Hyannis, MA 02601 TYPEOFBUSINESS: Does your firm store any of the toxic or hazardous materials listed below, either for sale or for you own use? YES NO This form must be returned to the Board of Health regardless of a yes or no answer. Use the enclosed envelope for your convenience. If you answered YES above, please indicate if the materials are stored at a site other than your mailing address: ADDRESS: TELEPHONE: LIST OF TOXIC AND HAZARDOUS MATERIALS The Board of Health has determined that the following products exhibit toxic or hazardous character- istics and must be registered regardless of volume. Please estimate the quantity beside the product that you store. NOTE: LIST IN TOTAL LIQUID VOLUME OR POUNDS. Quantity Quantity Antifreeze(forgasol'n, or coolant systems) Drain cleaners NEWD Cesspool cleaners _(PPAutomatic transmission fluid Disinfectants Engine and radiator flushes f7 < Road Salt (Halite) 3164 ��H ,,draulic fluid (including brake fluid) _ Refrigerants " ���� 9lbtor oils �. Pesticides NEW d�RED (insecticides, herbicides, rodenticides) AJ Gasoline, Jet Fuel Photochemicals (Fixers) Diesel fuel, kerosene, #2 heating oil NEW USED l G Other petroleum products: grease, �_ Photochemicals (Developer) lubricants ear oil NEW E 9 USED AJA Degreasers for engines and metal Printing ink Degreasers for driveways & garages _ Wood preservatives (creosote) Battery acid (electrolyte) Swimming pool chlorine Rustproofers Lye or caustic soda Car wash detergents Jewelry cleaners Car waxes and polishes Leather dyes �V A ' Asphalt & roofing tar Fertilizers I'04�� Paints, varnishes, stains, dyes PCB-s _,&JJJ4� Lacquer thinners /"✓� Other chlorinated hydrocarbons, NEW USED (inc. carbon tetrachloride) Paint & varnish removers, deglossers Paint brush cleaners � Any other products with "poison" labels (including chloroform, formaldehyde, Floor& furniture strippers hydrochloric acid, other acids) A,17 Metal polishes Laundry soil & stain removers Other products not listed which you feel (including bleach) may be toxic or hazardous (please list): Spot removers & cleaning fluids (dry cleaners) Other cleaning solvents Bug and tar removers WHITE COPY-HEALTH DEPARTMENT/CANARY COPY-BUSINESS noni TRACY VOLKSWAGEN JEFFERY C. RUTHE"O" - I SERVICE MANAGER - - ROUTE 132 PHONE i HYANNIS, MA 02601 (508)775-3049 1-800-439-3049 Fax (508)778-5766 ! r .rr��� J2� vl TOWN OF BARNSTABLE COMPLIANCE: CLASS: 1.Marine,Gas Stations,Repair satisfactory 2.Printers BOARD OF HEALTH 3.Auto Body Shops unsatisfactory- 4.Manufacturers COMPANY 0� (see"Orders") 5.Retail Stores 6.Fuel Suppliers ADDRESS Class. ,. 7.Miscellaneous QUANTITIES AND STORAGE (IN=indoors; OUT=outdoors) MAJOR MATERIALS Case lots Drums Aboye Tanks Underground Tanks IN OUT IN OUT IN OUT #&gallons Age Test Fuels: Gasoline,Jet Fuel (A) - - Diesel, Kerosene, #2 (B) Heavy Oils: q00 waste motor oil (C) �47f r/ new motor oil (C) transmission/hydraulic Synthetic Organics: degreasers -Al iscellaneous: CIC 3° DISPOSAIJRECLAMATION REMARKS:1. S nitary Sewage 2.Water Supply kt--D/ 0 0 S _ Town Sewer Public ` n-site OPrivate S, . s 3. Indoor Floor Dra*n NO Molding tank: MDC 0 Catch basin/Dry well �/ 0 On-site system tq (/ 4. Outdoor Surface drains:YES,�e NO ORDER ,Jfolding tank:MDC U) atch basin/Dry well 0 On-site system 5.Waste Transporter Name of Hauler Destination Waste Product 1. �� tom " kAirleD/ �✓ r`c NO 2. U c fr Dl r (s-rhTttrrviewed I s ectQr Date n4 TOXIC AND HAZARDOUS MATERIALS REGISTRATION FORM NAME OF BUSINESS: Trany Vnl k.-,wAgen, !nr, Mail To: Board of Health BUSINESS LOCATION: 686 Imanoughi Road, Hy-ganis Town of Barnstable MAILING ADDRESS: P..n,, Rnx 46o, H3rannis ,Ma . 02601 P.O. Box 534 TELEPHONE NUMBER: 775-3049 Hyannis, MA 02601 CONTACT PERSON: Rradfnrd Tom', TrnCy EMERGENCY CONTACT TELEPHONE NUMBER: 420-2080 or 775-3468 Does your firm store any of the toxic or hazardous materials listed below, either for sale or for your own use, in quantities totalling, at any time, more than 50 gallons liquid volume or 25 pounds dry weight? YES x_ NO This form must be returned to the Board of Health regardless of ayes or no answer. Use the enclosed envelope for'your convenience. If you answered YES above, please indicate if the materials are stored at a site other than your mailing address: dba. Cape Cod Auto Collision and Restoration ADDRESS: 151 Iyanough Road, Hyannis TELEPHONE: 775-2722 LIST OF TOXIC AND HAZARDOUS MATERIALS The Board of Health has determined that the following products exhibit toxic or hazardous character- istics and must be registered regardless of volume. Please estimate the quantity beside the product that you store: \� Quantity/Case Quantity/Case 25 —� Antifreeze (for gasoline or coolant systems) Drain cleaners Automatic transmission fluid Toilet cleaners Engine and radiator flushes Cesspool cleaners Hydraulic fluid (including brake fluid) Disinfectants 3009 Motor oils/waste oils Road Salt (Halite) Gasoline, Jet fuel Refrigerants Diesel fuel, kerosene, #2 heating oil Pesticides (insecticides, herbicides, Other petroleum products: grease, lubricants rodenticides) Degreasers for engines and metal Photochemicals (fixers and developers) Degreasers for driveways & garages Printing ink Battery acid (electrolyte) Wood preservatives (creosote) Rustproofers Swimming pool chlorine �5g Car wash detergents Lye or caustic soda Car waxes and polishes Jewelry cleaners Asphalt & roofing tar Leather dyes 50g Paints, varnishes, stains, dyes �/ Fertilizers (if stored outdoors) 50g i Paint & lacquer thinners. ��/�S/y/ PCB's Paint & varnish removers, deglossers60r4rl/0 Other chlorinated hydrocarbons, Paint brush cleaners (inc. carbon tetrachloride) Floor & furniture strippers Any other products with "Poison" labels Metal polishes (including chloroform, formaldehyde, Laundry soil & stain removers hydrochloric acid, other acids) (including bleach) Other products not listed which you feel may Spot removers & cleaning fluids be toxic or hazardous (please list): 1 (dry cleaners) we are an automobile dealership. Other cleaning solvents and we have a separate body shop Bug and tar removers Household cleansers, oven cleaners White Copy- Health Department/ Canary Copy-Business A` -1 TOWN OF BARNSTABLE COMPLIANCE: CLASS: 1.Marine,Gas Stations,Repair BOARD OFnters fEALT -9c satisfactory 3.2.Auto Body Shops fO unsatisfactory- 4.Manufacturers COMPANY "" P (see"Orders") 5.Retail Stores 6.Fuel Suppliers ADDRESS Class: 7.Miscellaneous QUANTITIES AND STORAGE (IN= indoors;OUT=outdoors) MAJOR MATIMIAL Case lots Drums Above Tanks Underground Tanks 1" IN OUT IN OUT IN OUT #&gallons Age Test Fuels: Gasoline,Jet Fuel (A) l Diesel, Kerosene, #2 (B) H waste motor oil �'' w motor oil (C) transmissio ydraulic Syn e tc Organics: degreasers Miscellaneous: DISPOSALIRECLAMATION REMARKS: 1. S nitary Sewage 2.Water Supply S ,Town Sewer OPublic 0 On-site OPrivate 3. I door Floor Z' S NOHolding taMDC 0 atch basin/Dry well O On-site system 4. Outdo ce drains:YES NO n �' Eong t DC Catch basin/Dry well O On-site system 5. Waste Transporter Name of Hauler Destination Waste Product 1. /71 ' � YES NO 141V SO '' ervie ed Inspect r D e 4 L FIX: f Town of Barnstable °Ft rati Regulatory Services Thomas F. Geiler,Director BA `AM. Public Health Division '°TFn�+►A+A Thomas McKean,Director 200 Main Street, Hyannis, MA 02601 VED Office: 508-862-4644 �Faax�08-7 0 6304 Application Fee: $100.00 JAN 2 4 2001 TOWN OF BARNSTABLE 31 1 -01 1 HEALTH DEPT. ASSESSORS MAP AND PARCEL NO. DATE ja n u a ry 21 2002 APPLICATION FOR PERMIT TO STORE AND/OR UTILIZE MORE THAN 111 GALLONS OF HAZARDOUS MATERIALS FULL NAME OF APPLICANT Tracy Valkswageen, Inc NAME OF ESTABLISHMENT Trace V�olkswagn-, inG a!-Re dba TraGy AU i ADDRESS OFESTABLISHMENT 686 Tyanni>>h gnarl TELEPHONE NUMBER 5 0 8-7 7 5-3 0 4 9 SOLE OWNER: YES yNO Corporation IF APPLICANT IS A PARTNERSHIP,FULL NAME AND HOME ADDRESS OF ALL PARTNERS: IF APPLICANT IS A CORPORATION: FEDERAL IDENTIFICATION NO. 042-432887 STATE OF INCORPORATION Massachusetts FULL NAME AND HOME ADDRESS OF: PRESIDENT 1—�H. Tra GY, 93 Blantyre Av e�zenteroil=e,, -MA 02632 TREASURER Same CLERK G-!Q-nrotanee M. Traey, Same as above IGNATURE OF ' P CANT RESTRICTIONS: HOMEADDRESS 83 Blantyre Ave. HOME TELEPHONE#40 A7 7 53 4 68 Haz.doc/wp/q i �OFtNE roy� Town of Barnstable Regulatory Services BARNST"LE9 MASS. $ Thomas F. Geiler,Director 1639. ♦� AlEDMA Public Health Division Thomas McKean,Director 200 Main Street, Hyannis, MA 02601 Office: 508-862-46 4 Fax: 508-790-6304 0 December 19, 2001 NOTICE TO ALL BUSINESS OPERATORS IN BARNSTABLE f Recently,the Barnstable Town Council adopted a new requirement for each business operator to obtain an annual permit and to remit a fee of$100.06 if one-hundred and eleven(111) gallons or more of hazardous materials are stored and/or utilized at a particular site. Please complete the attached application form and submit it along with the required fee of $100 to this Office on or before January 31, 2002. °Checks should be made payable to the: Town of Barnstable. Upon receipt of the fee and a completed application form, and after an inspection is conducted revealing no violations or.minor violations, a permit will be issued. If this does not pertain to you,please disregard this letter. A health inspector will be conducting inspections in the near future to ensure compliance with these requirements. Please feel free to call or visit our office if you should have any questions or concerns. z ) VA TOWN OF BARNSTABLE COMPLIANCE: CLASS: 1. Marine,Gas Stations, Repair Q satisfactory 2. Printers BOARD OF HEALTH 3.Auto Body Shops O unsatisfactory- 4.Manufacturers COMPANY I_M� 0 SIAJ� (see"Orders") 5. Retail Stores 6.Fuel Suppliers ADDRESS ��--11 � 02WjC1ass: 7.Miscellaneous QUANTITIES AND STORAGE (IN= indoors; OUT=outdoors) MAJOR MATERIALS Case lots Drums Above Tanks Underground Tanks IN OUT IN OUT IN OUT #&gallons Age Test 4_ - low Diesel, Kerosene, #2 (B) ,.Heavy Oils: waste motor oil (C) ol " af ro" new motor oil(C) '' transmission/hydraulic Synthetic Organics: degreasers Miscellaneous: / 'D�s v5d t " C EpraA4 V4ix+ 8 ✓ b�1 ' '� V/ DISPOSAUR.ECLAMATION REMARKS: 1. Sanitary Sewage 2.Water Supply Town Sewer Public W O On-site OPrivate �} 7 I��✓3 C�el�' f.Jr7Y'[r/a fQ. u 6J�e�s 3. Indoor Floor Drains YES_LNO X Holding tank:MDC O/AJ O Catch basin/Dry well I a.va: a la' O On-site system �OS to 4. Outdoor Surface drains:YES N0--.u/ ORDER O Holding tank:MDC O Catch basin/Dry well O On-site system 5.Waste Transporter Name of Hauler Destination Waste Product Licensed? Y S MR1�(9q 3�R(cq?g YES NO ' &dp ;13U® c I 2. S �� ►"lA•-« v o p l�'11AD0Y3y041'oag Zr 0z erson(sYWe7rvtwed. Inspector I Date J \ /O 1 Board of Health Interview Form l Contact : �t\-�z�QS1Q Date: Title: ��;��� cw� Phone (ext) : Sri City/Town of : _ Site Occupant/Location: Is he/she aware of any releases of oils or hazardous mat erials on or near the Site? (including any accidents which may have impacted the Site) CRLn Have any complaints of dumping on or near the Site been reported? Any complaints of unusual odors in nearby basements? Any problems associated with septic system(s) on or near the Site where frequent pumping of the septic tank or rejuvinators was required? N r� Any knowledge of .discharges of any other chemicals either to the septic system or by other means on the Site and/or nearby properties? Where are the Town public drinking water supplies relative to the Site? (distance and hydrologic osition relative to th P e Site) AM Svc r A� J Any reports of contaminants or discharges to the Town drinking water supply, surface water Lodies or groundwater supplies near the Site? Are any gasoline stations, auto repair shops, industries, etc. in any proximity to the Site which may impact the Site in any way? (Including the tanks, floor drain destinations, septic systems, drywells, etc. ) GN Any reports of gasoline, petroleum products or other potbntial contaminants found during excavati of utility trenches in the area? TOWN OF BARNSTABLE OMPLIANCE: CLASS: 1.Marine,Gas Stations,Repair BOARD OF HEALTH satisfactory 3.A nters to Body Shops ./f unsatisfactory- 4.Manufacturers �/ (see"Orders") 5.Retail Stores COMPA,NY`� �04*_ t 6.Fuel Suppliers ADDRESS �' �� g• 7.Miscellaneous M,�'O"UANTITIES AND STORAGE (IN= indoors;OUT=outdoors) MAJOR MATERIALS IN OUT IN OUT IN OUT #&gallons Age Test �uels: � . Gasoline,Jet Fuel (A) , 9 Heavy Oils: waste motor oil (C) 41'r PA4-o ' a ` new motor oil(C) / transmission/hydraulic Synthetic Organics: ` degreasers 9 Miscellaneous: r Irk 4.�� Ago a T � rw.-zejc&. DISPOSALIREGLAMATION REMARKS: 40 1. Sanitary Sewage 2.Water Supply O Town Sewer OPublic 0407 . O On-site OPrivate Arl --� G� r 3. I door Floor Drains YES NO .r' Holding tank:MDC h O Catch basin/Dry well Lp ��b' O On-site system cq'vp ,74,1 C 4. Outdoor Surface drains:YES NO ORDERS: Q Holding tank:MDC O Catch basin/Dry well '�f O On-site system 5.Waste Transporter 2. �"�¢ &4=7 fEykg A;ict -f-*V 1."—A A It As' rpZ fie. Person(s) Interviewed Inspector Date