Loading...
The URL can be used to link to this page
Your browser does not support the video tag.
Home
My WebLink
About
0096 LOMBARD AVENUE - Health (3)
�(� lamb�w`k Me � �\ Number Fee (� 1072 THE COMMONWEALTH OF MASSACHUSETTS $100.00 Town of Barnstable Board of Health This is to Certify that Beacon Sales Acquisition Co. 96 Lombard Ave., West Barnstable,MA 02668 Is Hereby Granted a License FOR: STORING OR HANDLING 111 GALLONS OR MORE OF HAZARDOUS MATERIALS. ---------- ----- ------------------------------------------------ --------------------------------------------------------------- This license is granted in conformity with the Statutes and ordinances relating there to, and and expires June 30 2009 unless sooner suspended or revoked. --------------------- `1 WAYNE MILLER,M.D.,CHAIRMAN PAUL J.CANNIFF,D.M.D. 07/01/08 JUNICHI SAWAYANAGI THOMAS A.MCKEAN,R.S.,CHO Director of Public Health I M Y r Town of Barnstable Barnstable ��sTgyti Regulatory Services Department M�AmedCeCftv • -. Public Health Division Q + BA"STABLE, ' 9$ 639 � 200 Main Street, Hyannis MA 02601 m ABED MA'1 2007 Office: 508-862-4644 Thomas F.Geiler,Director FAX: 508-790-6304 Thomas A.McKean,CHO Application Fee: $100.00 ASSESSORS MAP AND PARCEL NO. DATE APPLICATION FOR PERMIT TO STORE AND/OR UTILIZE MORE THAN 111 GALLONS OF HAZARDOUS MATERIALS FULL NAME OF APPLICANT Beacon Sales .Acquisttion Co. Inc. NAME OF ESTABLISHMENT Beacon Sales Co. 96 Lombard Ave, West Barnstable, 5 ADDRESS OF ESTABLISHMENT I ( 508) 362-71 09 '; 'c` ' TELEPHONE NUMBER SOLE OWNER: YES XNO -� IF APPLICANT IS A PARTNERSHIP,FULL NAME AND HOME ADDRESS F ALLY? PARTNERS: N IF APPLICANT IS A CORPORATION: FEDERAL IDENTIFICATION NO. STATE OF INCORPORATION MD FULL NAME AND HOME ADDRESS OF: PRESIDENT On File TREASURER CLERK SIGNATURE OF APPLICANT RESTRICTIONS: HOME ADDRESS HOME TELEPHONE# Q:\Hazmat\Haz Mat Application2008.DOC s� Number Fee 1072 THE COMMONWEALTH OF MASSACHUSETTS $100.00 Town of Barnstable Board of Health This is to Certify that Beacon Sales Acquisition Co. 96 Lombard Ave., West Barnstable,MA 02668 Is Hereby Granted a License FOR: STORING OR HANDLING 111 GALLONS OR MORE OF HAZARDOUS MATERIALS. -------------------------------------------------------------------------------------------------------------- c� LA This license is granted in conformity with the Statutes and ordinances relating there to,and and expires 6/30/2013 unless sooner suspended or revoked. ---------------------------------------- WAYNE MILLER,M.D.,CHAIRMAN PAUL J.CANNIFF,D.M.D. 6/30/2012 JUNICHI SAWAYANAGI THOMAS A.MCKEAN,R.S.,CHO Director of Public Health Town of Barnstable op 114E R Regulatory Services Thomas F. Geiler,Director t 3 BAENSUBLE, i M Public Health Division 9� 36Ajq-' 1�$ Thomas McKean, Director 200 Main Street, Hyannis, MA 02601 Office: 508-862-4644 Fax: 508-790-6304 Application Fee: $100.00 I�c" ASSESSORS MAP AND PARCEL NO. DATE U APPLICATION FOR PERMUT TO STORE AND/OR UTILIZE MORE THAN Ill GALLONS OF HAZARDOUS MATERIALS FULL NAME OF APPLICANT NAME OF ESTABLISHMENT lu-M 5Q1t;5 1 ADDRESS OF ESTABLISHMENT �(D �/Yt�QJ7� !1 AJe t �rfi s /2 DXC�$ TELEPHONE NUMBER SD SOLE OWNER: YES NO 00 = `p IF APPLICANT IS A PARTNERSHIP,FULL NAME AND HOME ADDRESS OF ALL-- ' ' PARTNERS: r C) i r ? STATE OF INCORPORATION l l FULL NAME AND HOME ADDRESS OF: PRESIDENT TREASURER CLERK SIGNATURE�OFAPCANT RESTRICTIONS: HOME ADDRESS HOME TELEPHONE# Haz.dodwp/q Town of Barnstable OFT"E Tom, * Regulatory Services Thomas F. Geiler,Director 9 S. Public Health Division i639 ♦� Thomas McKean,Director 200 Main Street, Hyannis, MA 02601 Office: 508-862-4644 Wayne Miller,M.D. Fax: 508-790-6304 Paul J. Canniff,D.M.D. Junichi Sawayanagi NOTICE TO ALL BUSINESS OPERATORS WITH HAZARDOUS MATERIALS IN BARNSTA113LE The Town of Barnstable Town Council adopted, Chapter 108: Hazardous Materials, a requirement for each business operator to obtain an annual permit and to remit a fee of$100.00 if one-hundred and eleven (111) gallons or more of hazardous materials are stored, transported, utilized, and/or disposed of at a particular site. . STEPS 1 — 2 - 3: 1. Please complete the attached application form 2. Include a copy of your contingency plan (to handle hazardous waste spills, etc.) 3. Submit the fee of$100.00 payable to the: Town of Barnstable. MAIL all of the above to this office on or before June 30, 2012. A late charge of$10.00 will be assessed if payment is not received by .duly 6, 2012. Please feel free to view the above Code, Chapter 108: Hazardous Materials on the Town Website, www.town.barnstable.ma.us , which is located under the E-Code section if you should have any questions or concerns. i QAHazmat\Haz Mat Permit Letter.DOC F I f1 b Number Fee 1072 THE COMMONWEALTH OF MASSACHUSETTS 1oo.00 � Town of Barnstable Board of Health This is to Certify that Beacon Sales Acquisition Co. 96 Lombard Ave., West Barnstable, MA Is Hereby Granted a License FOR: STORING OR HANDLING 111 GALLONS OR MORE OF HAZARDOUS MATERIALS. ----------------------------------------------------------------------------------------------------------------------------------------------------------------- ------------------------------------------------------------------------------------------------------------------------------------------------------------------ This license is granted in conformity with the Statutes and ordinances relating there to, and and expires 6/30/2015 unless sooner suspended or revoked. ---------------------------------------- WAYNE MILLER,M.D.,CHAIRMAN PAUL J.CANNIFF,D.M.D. 6/30/2014 JUNICHI SAWAYANAGI THOMAS A.MCKEAN,R.S.,CHO Director of Public Health 06/09/2014 06:13 15083628107 BEACON PAGE 03/04 Town of Barnstable +� Regulatory Sexvices Richard V-Seed,-Director Public Health DM'Sion Thomas McKean,Director 200 Main,Street, Hyannis,MA 02601 Ofae: 508-9624644 Fax: 508-790-6304 Application Fee:$100.00 ASSESSORS KAP AND PARCEL NO. DATE 6-12-1 g APPLICATION FOR.PERMXT TO STORE AWOR UTILIZE MORE THAN III GALLONS OF HAZARDOUS MATERIALS - NAM OF APPLICANT NAME OIL ESTABLISTIlVdM 13ea con -sw -s o_ ADDWS OF ESI'ARLIS$MENT 96_Lombard Ave,_I es-l- BarnEitable, MA._— TELEPHONE NUMBER 5 0 8-36 2-710 9 SOLE O'4 NER: WS NO IF APPLICANT IS A,PARTNERSHIP,M-1 NAME AND HON Z ADDRESS OF ALL PARTNERS: 7. IF APPLICANT IS A CORPORATION: FEDERAL IDENTIFICATION NO.-3 6-417 3 3 66 - STATE OF INCORPORATION Maryland FULL NAME AND HOBU ADDRESS OF: PRESIDENT TREASURER - CT.�RKL SIGNATURE OF 1'YICA.NI' RESTRICTIONS: HOME ADDRF,SS_ _- , HOME TELEPHONE# - QAApp6c9icn Fo=UiAZAPFXg0C Ail Number Fee 1018 THE COMMONWEALTH OF MASSACHUSETTS $loo.00 Town of Barnstable Board of Health This is to Certify that EM Crosby Boatworks, Inc. 48 Lombard Ave#4, West Barnstable,MA 02668 Is Hereby Granted a License FOR: STORING OR HANDLING 111 GALLONS OR MORE OF HAZARDOUS MATERIALS. ---------------------------- -------------------------------------------------------------------------------------------------------------------------------- ---------------------------------------------------------------------------------------------------------------- -------------------------------------------------- This license is granted in conformity with the Statutes and ordinances relating there to, and and expires 6/30/2010 unless sooner suspended or revoked. ---------------------------------------- WAYNE MILLER,M.D.,CHAIRMAN PAUL J.CANNIFF,D.M.D. 12/15/2009 JUNICHI SAWAYANAGI THOMAS A.MCKEAN,R.S.,CHO Director of Public Health if Town of Barnstable i Regulatory Services Thomas.F. Geiler,Director Public Health Division "{ Thomas McKean,Director 200 Main Street, Hyannis,MA 02601 Office: 508-862-4644 Fax: 508-790-6304 AppI eation Fee:$100:00 ASSESSORS MAP AND PARCEL NO. ISe/`7-#7 ?(o DATE_ /Z APPLICATION.FOR PERMIT.TO.STORE.AND/OR UTILIZE.MORE.THAN. 111.GALLLONS.OF.HAZARDOUS MATERIALS FULL NAME OF APPLICANT 'Ie rX all NAME OF ESTABLISHMENT ADDRESS OF ESTABLISHMENT 5/8 �U�l�tJEZ•�� P TELEPHONE NUMBER (S-0e J62- 7 �. SOLE OWNER: AES NO IF APPLICANT IS A PARTNERSHIP,FULL NAME AND HOME ADDRESS OF ALL PARTNERS: IF APPLICANT IS A CORPORATION: FEDERAL IDENTIFICATION NO. STATE OF INCORPORATION FULL NAME AND//HOME ADDRE S OF: -O PRESID 'EN J' TREASURER CLERK SIGNAI OF APPLICANT RESTRICTIONS: HOME ADDRESS -�P'el4vo HOME TELEPHONE# 77V Ve 7- 7S"7S,- Hmdoc/wp/q 7- Emergency Coordinator, Name: Address: Daytime Phone: 5z q 3<2_ 7f db Evening Phone: 7 7,f cf g 7 _ 7 S-7 Fire Department: 4451- SOS Z_.3Z i Barnstable Public Health Division: 508-862-4644 DEP 24 Hour Spill Hot Line: 888-304-1133 Waste Hauler: Name: {� /7 /� zi--7 Phone: (ydl ) Building diagram indicating hazardous material/waste storage area, location of absorbent scavenger materials, fire extinguishers, fire alarms (if present), and evacuation route (if applicable). )tl,fli� Ott Actions to be taken to control a spill.or release and preventing it from re�ching a catch basin, sewer system or the ground. . f�✓ /S- g �6YI/Sc-a Ive-b dleb56 ivo7- ,-o use 54WbUl i P-L3c-xj'—/ ,tS /i IS Ca,tl3u5T7 C� �L�{ �Tei,4� lirl Number Fee 1072 THE COMMONWEALTH OF MASSACHUSETTS $100.0o Town o Barnstable f B table s Board of Health This is to Certify that Beacon Sales Acquisition Co. 96 Lombard Ave., MA 02668 Is Hereby Granted a License FOR: STORING OR HANDLING. 111 GALLONS OR MORE OF HAZARDOUS MATERIALS. -------------------------------------------------------------------------------------------------------------------------------------------------------------------- This license is granted in conformity with the Statutes and ordinances relating there to,and and expires June 30, 2008 unless sooner suspended or revoked. ---------------------------------------- WAYNE MILLER,M.D.,CHAIRMAN SUMNER KAUFMAN,M.S.P.H. 7/1/2007 PAUL J. CANNIFF,D.M.D. THOMAS A. MCKEAN,R.S.,CHO Director of Public Health Town of Barnstable �oFt rti Regulatory Services :r Thomas F. Geiler,Director SA MASS. Public Health Division Thomas McKean,Director 200 Main Street, Hyannis,MA 02601 Office: 508-862-4644 Fax: 508-790-6304 Application Fee: $100.00 ASSESSORS MAP AND PARCEL NO. DATE APPLICATION FOR PERMIT TO STORE AND/OR UTILIZE MORE THAN III GALLONS OF HAZARDOUS MATERIALS PAVL FULL NAME OF APPLICANT 'E;F>AG0M SALE ks . ITt -i:tx-- NAME OF ESTABLISHMENT Z eACOOO SA S II � - ADDRESS OF ESTABLISHMENT L-p)1�J ,C„(�j � W �AP�YLS'(� ' .TELEPHONE NUMBER SOS SO— ? l,D SOLE OWNER: YES�No e IF APPLICANT IS A PARTNERSHIP, FULL NAME AND HOME ADDRESS QW ALL PARTNERS: < 00 M wFL �, m M C) r-- M IF APPLICANT IS A CORPORATION: FEDERAL IDENTIFICATION NO.� STATE OF INCORPORATION FULL NAME AND HOME ADDRESS OF: PRESIDENT TREASURER CLERK - _F SIGNATURE OF APPLICANT RESTRICTIONS: HOME ADDRESS HOME TELEPHONE # Number Fee 1072 THE COMMONWEALTH OF MASSACHUSETTS $100.00 Town of Barnstable Board of Health This is to Certify that Beacon Sales Acquisition Co. 96 Lombard Ave., MA 02668 Is Hereby Granted a License FOR: STORING OR HANDLING 111 GALLONS OR MORE OF HAZARDOUS MATERIALS. ------------------------------------------------------------------------------------------------------------------------------------------------------------------ -------------------------------------------------------------------------------------------------------------------------------------------------------------------- This license is granted in conformity with the Statutes and ordinances relating there to, and and expires June 30, 2007 unless sooner suspended or revoked. ---------------------------------------- WAYNE MILLER,M.D.,CHAIRMAN SUMNER KAUFMAN,M.S.P.H. November 7, 2006 PAUL J. CANNIFF,D.M.D. THOMAS A. MCKEAN,R.S.,CHO Director of Public Health 1 Town of Barnstable Regulatory Services `a ' v N yes r �. Thomas F. Geiler,Director Public Health Division .a , "sF Thomas McKean,Director 200 Main Street, Hyannis,MA 02601 Office: 508-862-4644 Fax:.508-790-6304 . Application Fee: $100.00 ASSESSORS MAP AND PARCEL NO. 5"5 A1 DATE APPLICATION FOR PERMIT TO STORE AND/OR UTILIZE MORE THAN 111 GALLONS OF HAZARDOUS MATERIALS FULL NAME OF APPLICANT D> 0%v% & $ NAME OF ESTABLISHMENT F>e, ux1 SALS + q gmjj tan W. <»cam ADDRESS OF ESTABLISHMENT 01(0 Z—Or"IN64-PA 41re, W. '?V%r»SA-'tW YY1A TELEPHONE NUMBER 'SOLE OWNER: YES_YNO IF APPLICANT IS A PARTNERSHIP,FULL NAME AND HOME ADDRESS OF ALL PARTNERS: - 1 CA4 lw,,,( PA�,d--, D-,-4, , pe42644 , a. Ot Ct c�c� IF APPLICANT IS A CORPORATION: FEDERAL IDENTIFICATION NO. STATE OF INCORPORATION M-A FULL NAME AND HOME ADDRESS OF: PRESIDENT TREASURER CLERK SIGNATURE OF APPLICANT RESTRICTIONS: HOME ADDRESS HOME TELEPHONE.# Hs:..dac'vup;q f Y Material Safety Data Sheet SURE-SEAL EP-95 SPLICING CEMENT MSDS No. 302146 Date of Preparation: 11/15/05 Revision:011 Section 1 - Chemical Product and Company Identification Product/Chemical Name: SURE-SEAL EP-95 SPLICING CEMENT Chemical Formula:Mixture General Use: Splicing Adhesive Manufacturer: Carlisle SynTec Incorporated, 1285 Ritner Highway,Carlisle, PA 17013,Phone:800-479-6832 Emergency Phone Number: CHEMTREC(USA)800-424-9300 Section 2 - Composition /Information on Ingredients Ingredient Name CAS Number %wit or %vol Toluene 108-88-3 36-39 Xylene 1330-20-7 10-13 VM&P Naphtha 64742-89-8 5.5-6.5 Heptane 1.42-82-5 5.5-6.5 Isopropyl Alcohol 67-63-0 3.4-4.4 Halogenated Butyl Rubber 68441-14-5 Halogenated Olefin Polymer 134737-24-9 Hydrocarbon Resins 68132-00-3 and 68131-87-3 Hazardous Ingredients: OSHA PEL ACGIH TLV NIOSH REL NIOSH Ingredient TWA STEL TWA STEL TWA STEL IDLH Toluene 200 ppm 150 ppm 50 ppm 150 ppm 100 ppm 150 ppm 500 ppm (skin) (skin) X lene 100 ppin 150 ppin 100 ppm 150 ppin 100 ppill 150 ppm 900 ppm VM&P Naphtha 300 ppin 400 ppm 300 ppin None estab. 350 pprn None estab. None estab. He tane 400 pprn 500 ppin None estab. None estab. 85 ppm 440 ppin 750 ppm Isopropyl Alcohol 400 ppm 500 ppm 400 ppm 500 ppm 400 ppm 500 ppm 2000 ppm Section 3 - Hazards Identification Emergency Overview HMIS g Y H 1 F 4 R 0 Potential Health Effects PPEt Primary Entry Routes: Skin contact,skin absorption,eye contact, inhalation, ingestion TSec.8 Target Organs: Acute Effects Inhalation:throat irritation on short-term exposure to liquid or vapor. Aspiration into lungs can cause chemical pneumonitis, which can be fatal. Eye: irritation on short-term exposure to liquid or vapor. Skin: irritation on short-term exposure to liquid or vapor. Ingestion: ingestion can cause gastrointestinal irritation. Carcinogenicity: IARC,NTP,and OSHA do not list this product as a carcinogen. Medical Conditions Aggravated by Long-Term Exposure: Respiratory symptoms associated with pre-existing lung disorders and pre-existing heart disorders may be aggravated by exposure to this material. Chronic Effects:Overexposure may result in headache,dizziness,fatigue, nausea and possible unconsciousness,even asphyxiation. Moderate irritation of skin,eyes and mucous membranes of upper respiratory tract on prolonged/repeated contact. Dermatitis and defatting of the skin. Chronic exposure may cause reversible liver and kidney injury. Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Repeated exposure to Toluene has been associated with high frequency hearing loss based on animal tests. Section 4 - First Aid Measures Inhalation:Remove victim to fresh air and provide oxygen if breathing is difficult. Give artificial respiration if not breathing. Get medical attention immediately. I MSDS No.302146 Sure-Seal EP-95 Splicing Cement 11/15/05 Eye Contact:Immediately flush eyes with running water for at least 15 minutes. Get medical attention. Skin Contact:Immediately flush skin with running water and remove contaminated clothing. Wash exposed area with soap and water.Get medical attention. Ingestion:Do not induce vomiting.Get medical attention immediately. Note to Physicians:This product contains several organic solvents(Toluene,Heptane,Xylene and Isopropyl Alcohol). Special Precautions/Procedures:Whenever possible,remove the worker from the source of contamination. Section 5 - Fire-Fighting Measures Flash Point: 8°F(-13°C) NFPA Flash Point Method: Closed Cup Autoignition Temperature:223°C 4 LEL:0.9%v/v 1 0 UEL: 12.0%v/v Flammability Classification:Division 2 Extinguishing Media: In case of fire,use dry chemical,carbon dioxide,or foam. Water may not be effective as an extinguishing agent. Water fog or spray may be used to provide a smothering effect on fire and to cool fire-exposed containers and surrounding combustibles. Do not use a solid stream of water because it can scatter and spread the fire. Unusual Fire or Explosion Hazards: Extremely flammable. Store and use away fi•om all sources of heat,flame,or sparks. Do not smoke while applying. Vapors are heavier than air and may travel along ground or may be moved by ventilation and ignited by pilot lights,other flames,sparks,heaters,smoking,electrical motors,static discharge,or other ignition sources at location distant from material handling point and flash back. All containers should be grounded when material is transferred Hazardous Combustion Products:Toxic gases or vapors,such as carbon monoxide,carbon dioxide,or oxides of nitrogen may be released in a fire. Fire-Fighting Instructions:This product contains solvents that are dangerous fire and explosion hazards when exposed to heat or flame. Fire fighters should wear self-contained breathing apparatus and full protective clothing with a full face piece operated in the positive pressure demand mode. Fire-Fighting Equipment:Because fire may produce toxic thermal decomposition products,wear a self-contained breathing apparatus(SCBA)with a full face piece operated in pressure-demand or positive-pressure mode. Section 6 - Accidental Release Measures Spill/Leak Procedures: Remove all sources of ignition. Avoid breathing vapors. Use self-contained breathing apparatus in enclosed area. Ventilate area. Contain and remove with inert absorbent materials and non-sparking tools. Large Spills: Containment: For large spills,dike far ahead of liquid spill for later disposal.Do not release into sewers or waterways. Cleanup: Clean-up spill as soon as possible. Collect any excess material with absorbent pads,sand or other inert non- combustible absorbent materials. Place into appropriate waste containers for later disposal. Comply with all laws and regulations. Regulatory Requirements: Follow applicable OSHA regulations(29 CFR 1910.120). Section 7 - Handling and Storage Handling Precautions: Use away from all sources of heat,flame,or sparks. Do not smoke while using. Handling equipment must be grounded to prevent sparking. Handle with non-sparking tools. Wash with soap and water before eating or drinking. Launder contaminated clothing. KEEP OUT OF REACH OF CHILDREN. Storage Requirements: Keep containers cool,dry,and store way from all sources of heat,flame,and sparks. Keep containers tightly closed and store with adequate ventilation. Do not pressurize,cut,weld,or grind the containers or empty containers which may contain residual product and solvent vapors that may ignite explosively. Section 8 - Exposure Controls / Personal Protection Engineering Controls: Do not use in enclosed areas without proper explosion-proof ventilation. General and local exhaust ventilation must be sufficient to control vapor concentrations and keep the vapor concentration below 100 pprn. Ventilation: Provide general or local exhaust ventilation systems to maintain airborne concentrations below OSHA PELs (Sec.2). Local exhaust ventilation is preferred because it prevents contaminant dispersion into the work area by controlling it at its source. Administrative Controls: Respiratory Protection: A NIOSH approved respirator must be used if vapor concentration is 100 ppm or above. Protective Clothing/Equipment: Hycron or equivalent solvent permeation resistant gloves recommended. Glasses or goggles recommended. Industrial shoes to protect feet from adhesive contact. Long sleeves, long trousers to protect skin from adhesive contact. Protective skin creams or emollients useful. Safety Stations: Make emergency eyewash stations,safety/quick-drench showers,and washing facilities available in work area. Page 2 of 6 11/15/05 Sure-Seal EP-95 Splicing Cement MSDS No. 302146 Contaminated Equipment:Separate contaminated work clothes from street clothes.Launder before reuse.Remove this material from your shoes and clean personal protective equipment. Comments:Never eat,drink,or smoke in work areas.Practice good personal hygiene after using this material,especially before eating,drinking,smoking,using the toilet,or applying cosmetics. Section 9 - Physical and Chemical Properties Physical State:Liquid Water Solubility:Negligible Appearance and Odor:Black liquid with strong Boiling Point(°C): 82-139 hydrocarbon odor Freezing/Melting Point(°C): -48 Odor Threshold:Not available '%o Volatile:67-71 Vapor Pressure: 6.7-45 mm Hg Evaporation Rate(nBuAc=I):0.7-8.3 Vapor Density(Air=l):2.0-3.9 Specific Gravity(H20=10t 4°C):0.882 pH:N/A Section 10 - Stability and Reactivity Stability: Stable. Polymerization:Will not occur. Chemical Incompatibilities: Strong oxidizing agents,acids,bases. Conditions to Avoid: Heat,sparks,and flames;ignition sources. Hazardous Decomposition Products:Toxic gases or vapors,such as carbon monoxide,carbon dioxide,or oxides of nitrogen may be released in a fire. Section 11- Toxicological Information Toxicity Data: Eye Effects:Irritating Acute Inhalation Effects: Product toxicity has not been determined. Following are the component data: Skin Effects:Irritating TC50: Toluene: Rat>26,700 ppm I hi;Mouse 400 ppm 24 hr Heptane: Human TCLo: 1000 ppm/6 minutes Acute Oral Effects:Product toxicity has not been determined. Following are component data: LD50: Toluene: Rat 5000 mg/kg Heptane: Rat, ivn,222 mg/kg Chronic Effects: May cause skin sensitization in some people. Carcinogenicity:Not listed in IARC or NTP. Mutagenicity: Some evidence in animal exposure to Toluene. Teratogenicity: Some evidence in animal exposure to Toluene. Section 12 - Ecological Information Ecotoxicity:Not known Environmental Fate:Not known Environmental Degradation:Not known Soil Absorption/Mobility:Not known Section 13 - Disposal Considerations Disposal:Dispose of in accordance with all local,state,and federal regulations. Page 3 of 6 r - MSDS No.302146 Sure-Seal EP-95 Splicing Cement 11/15/05 Section 14 - Transport Information DOT Transportation Data (49 CFR 172.101): Shipping Name:Adhesives,3, Packaging Authorizations Quantity Limitations UN1133,11 a)Exceptions: 173.150 a) Passenger,Aircraft,or Railcar: 5L Shipping Symbols: Flammable b)Non-bulk Packaging: 173.173 b)Cargo Aircraft Only:60L Hazard Class:3 c)Bulk Packaging: 173.242 ID No.: UN1133 Vessel Stowage Requirements Packing Group: II a) Vessel Stowage: B Label: red caution label required b)Other:--- Special Provisions(172.102): 149,B52,IB2,T4,TP1,TP8 Section 15 - Regulatory Information EPA Regulations: RCRA Hazardous Waste Number(40 CFR 261.33): Not listed RCRA Hazardous Waste Classification(40 CFR 261):Not classified TSCA(Toxic Substances Control Act)Status: TSCA(United States)—The intentional ingredients of this product are listed. CERCLA Hazardous Substance RQ—40 CFR 302.4(a) Component RQ(lbs) Toluene 1000 Xylenes(O-,M-,P-Isomers) 100 CERCLA RQ—40 CFR 302.4(b) Materials with a"listed"RQ may be reportable as an"unlisted hazardous substance". See 40 CFR 302.5(b). SARA 311/312 Codes: Immediate(X) Delayed(X) Fire(X) Reactive( Sudden Release of Pressure( ) SARA 313 Components(40 CFR 372.65): Section 313 Components) CAS Number % Toluene 108-88-3 14— 18 Xylene 1330-20-7 6—10 Isopropyl Alcohol 67-63-0 3.4—4.4 SARA EHS(Extremely Hazardous Substance)(40 CFR 355): Not listed,Threshold Planning Quantity(TPQ) OSHA Regulations: Air Contaminant(29 CFR 1910.1000,Table Z-1,Z-1-A):Not listed OSHA Specifically Regulated Substance(29 CFR 1910): None listed EPA Accidental Release Prevention(40 CFR 68): None listed State Regulations: California Proposition 65: The following statement is made in order to comply with the California Safe Drinking Water and Toxic Enforcement Act of 1986: This product contains the following substance(s)known to the State of California to cause reproductive harm: Toluene Page 4 of 6 11/15/05 Sure-Seal EP-95 Splicing Cement MSDS No. 302146 Delaware Air Quality Management List: Chemical Name DRQ: State? Toluene 1000 Must be reported to the DRQ Xylene 100 N Florida Toxic Substance: The following components are listed as a toxic substance by the state of Florida: Toluene Xylene Heptane Isopropyl Alcohol Massachusetts Hazardous Substances List: Chemical Name CAS# Codes Toluene 108-88-3 2,4,5,6, F7, F8 Xylene 1330-20-7 2,4, F8,F9 Heptane 142-82-5 2,4,5,6 Isopropyl Alcohol 67-63-0 2,4, 5,6, F9 Michigan Critical Materials Registry: Chemical Name CAS# Report Class Toluene 108-88-3 -- - Xylene 1330-20-7 -- -- Minnesota Hazardous Substance: Chemical Name Codes Hazards Carcinogen? Toluene ANO skin No Xylene ANO -- No Heptane ANO - No Isopropyl Alcohol ANO --- No New Jersey RTK Label Information: Chemical Name CAS# Substance# DOT# TPQ EHS Toluene 108-88-3 1866 1294 - Xylenes 1330-20-7 2014 1307 New York List of Hazardous Substances: Chemical Name RQ—Air RQ—Land Note Toluene 1000 1 none Xylene 1000 1 none Pennsylvania RTK Label Information Chemical Name CAS# Code Benzene,Methyl 108-88-3 E Benzene,Dimethyl 1330-20-7 E Heptane 142-82-5 -. Isopropyl Alcohol 67-63-0 E Washington Air Contaminant: TWA(ppm): 100(Toluene) 400(Isopropyl Alcohol) TWA (mg): 375 (Toluene) 980(Isopropyl Alcohol) STEL(ppm): 150(Toluene) 500(Isopropyl Alcohol) STEL(rng): 560(Toluene) 1225(Isopropyl Alcohol) Ceiling(ppm): None listed Ceiling(mg): None listed Skin: None listed Page 5 of 6 MSDS No. 302146 Sure-Seal EP-95 Splicing Cement 11/15/05 Section 16 - Other Information Prepared By: Research&Development Revision Notes: Revised to new 16-part MSDS Format Disclaimer:The information contained in this document is based upon data that was supplied to Carlisle by other companies and organizations.No warranty of merchantability or fitness for a particular purpose is expressed or implied regarding the accuracy or completeness of the data and/or information in this material safety data sheet. Page 6 of 6 I Material Safety Data Sheet SURE-SEAL 90-8-30A BONDING ADHESIVE MSDS No. 302124 Date of Preparation:05/08/06 Revision:017 Section I - Chemical Product and Company Identification Product/Chemical Name: SURE-SEAL 90-8-30A BONDING ADHESIVE Chemical Formula:Mixture General Use:Contact Bonding Adhesive Manufacturer: Carlisle SynTec Incorporated, 1285 Ritner Highway,Carlisle,PA 17013,Phone: 800-479-6832 Emergency Phone Number: CHEMTREC(USA)800-424-9300 Section 2 - Composition / Information on Ingredients Ingredient Name CAS Number %wt or %vol Acetone 67-64-1 8.0-10.0 Heptane 142-82-5 27-31 Toluene 108-88-3 36-40 Xylene 1330-20-7 1.4-2.4 Magnesium Oxide 1309-48-4 0.6-1.0 Polychloroprene 9010-98-4 Phenolic Resin 26022-00-4 Hazardous Ingredients: OSHA PEL ACGIH TLV NIOSH REL NIOSH Ingredient TWA STEL TWA STEL TWA STEL IDLH Acetone 1000 m L000 m 500 ppm 750 pprn 250 ppm None estab. 2500 ppm He tare 400 ppni 500 ppin None estab. None estab. 85 ppm 440 pprn 750 ppm Toluene 200 ppm 150 ppm 50 ppm 150 ppm 100 ppm 150 ppm 500 ppm (skin) (skin) Xylene 100 ppin 150 pin 100 pprn. 150 ppm 100 ppin 150 ppm 900 ppm Magnesium Oxide 10 mg/m None estab. 10 mg/nr None estab. 10 mghn None estab. 750 mg/m (as dust) Section 3 - Hazards Identification Emergency Overview ******** r HMI I g Y H 1 F 4 R 0 Potential Health Effects PPEt Primary Entry Routes: Skin contact,skin absorption,eye contact, inhalation,ingestion. tsec.8 Target Organs: Acute Effects Inhalation:throat irritation on short-tern exposure to liquid or vapor. Aspiration into lungs can cause chemical pneumonitis, which can be fatal. Eye: irritation on short-term exposure to liquid or vapor. Skin: irritation on short-term exposure to liquid or vapor. Ingestion: ingestion can cause gastrointestinal irritation Carcinogenicity: IARC,NTP,and OSHA do not list this product as a carcinogen. Medical Conditions Aggravated by Long-Term Exposure: Respiratory symptoms associated with pre-existing lung disorders and pre-existing heart disorders may be aggravated by exposure to this material. Chronic Effects: Overexposure may result in headache,dizziness,fatigue,nausea,and possible unconsciousness,even asphyxiation. Moderate irritation of skin,eyes and mucous membranes of upper respiratory tract on prolonged/repeated contact. Dermatitis and defatting of the skin. Chronic exposure may cause reversible liver and kidney injury. Reports have associated rep:ated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Repeated exposure to Toluene has been associated with high frequency hearing loss based on animal tests. Section 4 - First Aid Measures Inhalation: Remove victim to fresh air and provide oxygen if breathing is difficult.Give artificial respiration if not breathing. Get medical attention immediately. Eye Contact:Immediately flush eyes with running water for at least 15 minutes. Get medical attention. I L MSDS No.302124 Sure-Seal 90-8-30A Bonding Adhesive 05/08/06 Skin Contact: Immediately flush skin with running water and remove contaminated clothing. Wash exposed area with soap and water. Get medical attention. Ingestion:Do not induce vomiting. Cet medical attention immediately. Note to Physicians:This product contains several organic solvents(Toluene,Heptane,Acetone and Xylene). Special Precautions/Procedures: Whenever possible,remove the worker from the source of contamination. Section 5 - Fire-Fighting Measures Flash Point: -4°F(-20°C) NFPA Flash Point Method:CC Autoignition Temperature:433.4°F(223°C) 4 LEL: 1.1%v/v 1 0 UEL: 12.8%v/v Flammability Classification: Division 2 Extinguishing Media: In case of fire,use dry chemical,carbon dioxide,or foam. Water may not be effective as an extinguishing agent. Water fog or spray may be used to provide a smothering effect on fire and to cool fire-exposed containers and surrounding combustibles. Do not use a solid stream of water because it can scatter and spread the fire. Unusual Fire or Explosion Hazards: Extremely flammable. Store and use away from all sources of heat,flame,or sparks. Do not smoke while applying. Vapors are heavier than air and may travel along ground or may be moved by ventilation and ignited by pilot lights,other flames,sparks,heaters,smoking,electrical motors,static discharge,or other ignition sources at location distant from material handling point and flashback. All containers should be grounded when material is transferred. Hazardous Combustion Products:Toxic gases or vapors,such as carbon monoxide,carbon dioxide,hydrogen cyanide,or oxides of nitrogen may be released in a fire. Fire-Fighting Instructions:This product contains solvents that are dangerous fire and explosion hazards when exposed to heat or flame.Fire fighters should wear self-contained breathing apparatus and full protective clothing with a full face piece operated in the positive pressure demand mode. Fire-Fighting Equipment: Because fare may produce toxic thermal decomposition products,wear a self-contained breathing apparatus(SCBA)with a full face piece operated in pressure-demand or positive-pressure mode. Section 6 - Accidental Release Measures Spill/Leak Procedures:Remove all sources of ignition. Avoid breathing vapors. Use self-contained breathing apparatus in enclosed area. Ventilate area.Contain and remove with inert absorbent materials and non-sparking tools. Large Spills: Containment:For large spills,dike far ahead of liquid spill for later disposal. Do not release into sewers or waterways. Cleanup:Clean-up spill as soon as possible. Collect any excess material with absorbent pads,sand or other inert non- combustible absorbent materials. Pace into appropriate waste containers for later disposal. Comply with all laws and regulations. Regulatory Requirements:Follow applicable OSHA regulations(29 CFR 1910.120). Section 7 - Handling and Storage Handling Precautions:Use away from all sources of heat,flame,or sparks. Do not smoke while using. Handling equipment must be grounded to prevent sparking. Handle with non-sparking tools. Wash with soap and water before eating or drinking. Launder contaminated clothing. KEEP OUT OF REACH OF CHILDREN. Storage Requirements:Keep containers cool,dry,and store way from all sources of heat,flame,and sparks. Keep containers tightly closed and store with adequate ventilation. Do not pressurize,cut,weld,or grind the containers or empty containers which may contain residual product and solvent vapors that may ignite explosively. Section 8 - Exposure Controls / Personal Protection Engineering Controls: Do not use in enclosed areas without proper explosion-proof ventilation. General and local exhaust ventilation must be sufficient to cont_ol vapor concentrations and keep the PEL below 100 ppm. Ventilation:Provide general or local exhaust ventilation systems to maintain airborne concentrations below OSHA PELs (Sec.2). Local exhaust ventilation is preferred because it prevents contaminant dispersion into the work area by controlling it at its source. Administrative Controls: Respiratory Protection: A NIOSH approved respirator must be used if vapor concentration is 100 ppm or above. Protective Cloth ing/Equipment:Hycron or permeation resistant gloves recommended. Glasses or goggles recommended. Industrial shoes to protect feet from adhesive contact. Long sleeves,long trousers to protect skin from adhesive contact. Protective skin creams or emollients useful. Safety Stations: Make emergency eyewash stations,safety/quick-drench showers,and washing facilities available in work area. Page 2 of 6 I 05/08/06 Sure-Seal 90-8-30A Bonding Adhesive MSDS No.302124 Contaminated Equipment: Separate contaminated work clothes from street clothes. Launder before reuse.Remove this material from your shoes and clean personal protective equipment. Comments:Never eat,drink,or smoke in work areas.Practice good personal hygiene after using this material,especially before eating,drinking,smoking,using the toilet,or applying cosmetics. Section 9 - Physical and Chemical Properties Physical State:Liquid Water Solubility:Negligible Appearance and Odor:Yellowish liquid with strong Boiling Point(°C): 56-139 hydrocarbon odor. Freezing/Melting Point(°C):-48 Odor Threshold:Not available %Volatile:79-83 Vapor Pressure:6.7 mm Hg at 400°F(204°C) Evaporation Rate(nBuAc=1):0.6-8.3 Vapor Density(Air=1):2.0-3.7 Specific Gravity(H2O=1,at 4°C):0.84 PH:N/A Section 10 - Stability and Reactivity Stability: Stable. Polymerization: Will not occur. Chemical Incompatibilities: Strong oxidizing agents,acids,bases. Conditions to Avoid:Heat,sparks,and flames;ignition sources. Hazardous Decomposition Products:Toxic gases or vapors such as carbon monoxide,carbon dioxide,or oxides of nitrogen may be released in a fire. Section 11- Toxicological Information Toxicity Data: Eye Effects: Irritating Acute Inhalation Effects:Product toxicity has not been determined. Following are the component data: Skin Effects: Irritating TC10: Toluene: Rat>26,700 ppm I hr;Mouse 400 ppm 24 hr Acetone: Rat>20,700 ppm 8 hr Heptane: Human TCLo: 1000 ppm/6 minutes Acute Oral Effects:Product toxicity has not been determined. Following are component data: LD50: Toluene: Rat 5000 mg/kg Acetone: Rate 5,800 mg/kg Mouse 3,000 mg/kg Rabbit 5,340 mg/kg Heptane: Rat, ivn,222 mg/kg Chronic Effects: May cause skin sensitization in some people. Carcinogenicity:Not listed in IARC or NTP. Mutagenicity: Some evidence in animal exposure to Toluene Teratogenicity: Some evidence in animal exposure to Toluene Section 12 - Ecological.Information Ecotoxicity:Not known Environmental Fate:Not known Environmental Degradation:Not known Soil Absorption/Mobility:Not known Section 13 - Disposal Considerations Disposal: Dispose of in accordance with all local,state,and federal regulations. Page 3 of 6 MSDS No.302124 Sure-Seal 90-8-30A Bonding Adhesive 05/08/06 Section 14 - Transport Information DOT Transportation Data (49 CFR 172.101): Shipping Name:Adhesives,3, Packaging Authorizations Quantity Limitations UN1133, 11 a)Exceptions: 173.150 a) Passenger,Aircraft,or Railcar: 5L Shipping Symbols: Flammable b)Non-bulk Packaging: 173.173 b)Cargo Aircraft Only: 60L Hazard Class:3 c)Bulk Packaging: 173.242 ID No.: UN1133 Vessel Stowage Requirements Packing Group:11 a) Vessel Stowage: B Label: red Flammable Liquid b)Other:--- label required Special Provisions(172.102): 149,B52, 1132,T4,TP1,TP8 Section 15 - Regulatory Information EPA Regulations: RCRA Hazardous Waste Number(40 CFR 261.33): Not listed RCRA Hazardous Waste Classification(40 CFR 261):Not classified TSCA(Toxic Substances Control Act)Status: TSCA(United States)—The intentional ingredients of this product are listed. CERCLA Hazardous Substance RQ—40 CFR 302.4(a) Component RQ(lbs) Toluene 1000 Xylenes(O-,M-,P-Isomers) 100 Acetone 5000 CERCLA RQ—40 CFR 302.4(b) Materials with a"listed"RQ may be reportable as an"unlisted hazardous substance". See 40 CFR 302.5(b). SARA 311/312 Codes: Immediate(X) Delayed(X) Fire(X) Reactive( Sudden Release of Pressure O SARA 313 Components(40 CFR 372.65): Section 313 Component(s) CAS Number % Toluene 108-88-3 36—40 Xylene 1330-20-7 1.4—2.4 SARA EHS(Extremely Hazardous Substance)(40 CFR 355): Not listed,Threshold Planning Quantity(TPQ) OSHA Regulations: Air Contaminant(29 CFR 1910.1000,Table Z-1,Z-1-A):Not listed OSHA Specifically Regulated Substance(29 CFR 1910): None listed EPA Accidental Release Prevention(40 CFR 68): None listed State Regulations: California Proposition 65: The following statement is made in order to comply with the California Sate Drinking Water and Toxic Enforcement Act of 1986: This product contains the following substance(s)known to the State of California to cause reproductive harm: Toluene Page 4 of 6 05/08/06 Sure-Seal90-8-30A Bonding Adhesive MSDS No.302124 Delaware Air Quality Management List: Chemical Name DRQ: State? Toluene 1000 Must be reported to the DRQ Xylene 100 N Acetone 5000 Must be reported to the DRQ Florida Toxic Substance: The following components are listed as a toxic substance by the state of Florida: Toluene Xylene Acetone Heptane Massachusetts Hazardous Substances List: Chemical Name CAS# Codes Toluene 108-88-3 2,4,5,6,F7,F8 Xylene 1330-2077 2,4,F8,F9 Acetone 67-64-1 2,4,5,6,F8, F9 Heptane 142-82-5 2,4,5,6 Michigan Critical Materials Registry: Chemical Name CAS# Report Class Toluene 108-88-3 - -- Xylene 1330-20-7 -- -- Minnesota Hazardous Substance: Chemical Name Codes Hazards Carcinogen? Toluene ANO skin No Xylene ANO -- No Acetone AON -- No Heptane ANO -- No New Jersey RTK Label Information: Chemical Name CAS# Substance# DOT# TPQ EHS Toluene 108-88-3 1866 1294 -- Xylenes 1330-20-7 2014 1307 -- New York List of Hazardous Substances: Chemical Name RQ—Air RQ—Land Note Toluene 1000 1 none Xylene 1000 .1 none Acetone 5000 1 none Pennsylvania RTK Label Information Chemical Name CAS# Code Benzene,Methyl 108-88-3 E Benzene,Dimethyl 1330-20-7 E 2-Propanone 67-34-1 E Heptane 142-82-5 -- Washington Air Contaminant: TWA (ppm): 100(Toluene) 750(Acetone) TWA (mg): 375(Toluene) 1800(Acetone) STEL(ppm): 150(Toluene) 1000(Acetone) STEL(mg): 560(Toluene) 2400(Acetone) Ceiling(ppm): None listed Ceiling(mg): None listed Skin: None listed Page 5 of 6 MSDS No. 302124 Sure-Seal 90-8-30A Bonding Adhesive 05/08/06 Section 16 - Other Information Prepared By:Research&Development Revision Notes: Corrected Packaging Group Information in Section 14. Disclaimer:The information contained in this document is based upon data that was supplied to Carlisle by other companies and organizations.No warranty of merchantability or fitness for a particular purpose is expressed or implied regarding the accuracy or completeness of the data and/or information in this material safety data sheet. Page 6 of 6 Material Safety Data Sheet WEATHERED MEMBRANE CLEANER MSDS No. 302074 Date of Preparation:01/09/06 Revision:006 Section 1 - Chemical Product and Company Identification Product/Chemical Name: WEATHERED MEMBRANE CLEANER Chemical Formula: Mixture General Use: Cleaning Solution for Weathered EPDM and TPO Membranes Manufacturer: Carlisle SynTec Incorporated, 1285 Ritner Highway,Carlisle,PA 17013,Phone: 800-479-6832 24-Hour Emergency Phone Number: CHEMTREC(USA)800-424-9300 Section 2 - Composition / Information on Ingredients Ingredient Name CAS Number %wt or %vol Aliphatic Petroleum Distillate 64742-89-8 100 Hazardous Ingredients: OSHA PEL ACGIH TLV NIOSH REL NIOSH Ingredient TWA STEL TWA STEL TWA STEL IDLH Aliphatic Petroleum 300 ppm 400 ppm 300 ppm none estab. 350 ppm none estab. none estab. Distillate Section 3 - Hazards Identification EmergencyOverview HMI I H 1 F 3 R 0 Potential Health Effects PPEt Primary Entry Routes: Skin contact,skin absorption,eye contact, inhalation, ingestion. tsec.8 Target Organs: May cause damage to the following organs: kidneys, lungs, liver,mucous membranes,upper respiratory tract, skin,eyes,central nervous system Acute Effects Inhalation: Breathing high concentrations may be harmful. Mist or vapor can irritate the throat and lungs. Breathing this material may cause central nervous system depression with symptoms including nausea,headache,dizziness,fatigue, drowsiness or unconsciousness. Breathing high concentrations of this material,for example, in an enclosed space or by intentional abuse,can cause irregular heartbeats which can cause death. Eye:This product can cause transient mild eye irritation with short-term contact with liquid sprays or mists. Symptoms include stinging,watering,redness and swelling. Skin:This material can cause skin irritation. The degree of irritation will depend on the amount of material that is applied to the skin and the speed and thoroughness that it is removed. Symptoms include redness,itching and burning of the skin. Repeated or prolonged skin contact can produce moderate irritation(dermatitis). Ingestion: If swallowed,this material may irritate the mucous membranes of the mouth,throat and esophagus. It can be readily absorbed by the stomach and intestinal tract. Symptoms include a burning sensation of the mouth and esophagus,nausea, vomiting,dizziness,staggering gait,drowsiness,loss of consciousness,and delirium,as well as additional central nervous system effects. Due to its light viscosity,there is a danger of aspiration into the lungs during vomiting. Aspiration can result in severe lung damage or death. Carcinogenicity:This product is not known to contain any components at concentrations above 0.1%which are considered carcinogenic by OSHA,IARC or NTP. Medical Conditions Aggravated by Long-Term Exposure:Disorders of the following organs or organ systems that may be aggravated by significant exposure to this material include: skin,respiratory system, liver,kidneys and central nervous system. Chronic Effects:Chronic effects of ingestion and subsequent aspiration into the lungs may cause pneumatocele(lung cavity) formation and chronic lung dysfunction. Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling this product may be harmful or fatal. ,r MSDS No.302074 Weathered Membrane Cleaner 01/09/06 Section 4 - First Aid Measures Inhalation:Immediately move victim to fresh air. If victim is not breathing, immediately begin rescue breathing. If heart has stopped,immediately begin card iopu'Imonary resuscitation(CPR). If breathing is difficult, 100 percent humidified oxygen should be administered by a qualified individual. Seek medical attention immediately. Eye Contact:Check for and remove contact lenses. If irritation or redness develops,flush eyes with cool,clean,low-pressure water for at least 15 minutes. Hold eyelids apart to ensure complete irrigation of the eye and eyelid tissue. Do not use eye ointment. Seek medical attention immediately. Skin Contact: Remove contaminated shoes and clothing. Flush affected area with large amounts of water. if skin surface is damaged,apply a clean dressing and seek medical attention. Do not use skin ointments. If skin surface is not damaged,clean affected area thoroughly with mild soap and water. Seek medical attention immediately. Ingestion:Do not induce vomiting. If spontaneous vomiting is about to occur,place victim's head below knees. If victim is drowsy or unconscious,place on the left side with head down. Never give anything by mouth to a person who is not fully conscious. Do not leave victim unattended. Seek medical attention immediately. Note to Physicians: INHALATION: Inhalation overexposure can produce toxic effects. Monitor for respiratory distress. If cough or difficulty breathing develops,evaluate for upper respiratory tract inflammation, bronchitis and pneumonitis. Administer supplemental oxygen with assisted ventilation,as required. This material sensitizes the heart to the effects of sympathomimetic amines. Epinephrine and other sympathomimetic drugs may initiate cardiac arrhythmias in individuals exposed to this material. Administration of sympathomimetic drugs should be avoided. INGESTION: If ingested,this material presents a significant aspiration and chemical pneumonitis hazard. Induction of emesis is not recommended. Consider activated charcoal and/or gastric lavage. If patient is obtunded,protect the airway by cuffed endotracheal intubation or by placement of the body in a Trendelenburg and left lateral decubitis position. Section 5 - Fire-Fighting Measures Flash Point:65 °F(18°C) NFPA Flash Point Method:TCC Autoignition Temperature:450°F(232°C) 1 3 O LEL: 0.9%v/v UEL:6.7%v/v Flammability Classification:NFPA Class—1 B flammable liquid. Extinguishing Media: SMALL FIRE: Use dry chemicals,carbon dioxide,foam,water fog or inert gas(nitrogen). LARGE FIRE: Use foam,water fog or water spray. Water fog and spray are effective in cooling containers and adjacent structures. However,water can cause frothing and/or may not extinguish the fire. Water can be used to cool the external walls of vessels to prevent excessive pressure,autoignition or explosion. DO NOT use a solid stream of water directly on the fire as the water may spread the fire to a larger area. Unusual Fire or Explosion Hazards: Flammable Liquid! This material releases vapors at or below ambient temperatures. When mixed with air in certain proportions and exposed to an ignition source, its vapor can cause a flash fire. Use only with adequate ventilation. Vapors are heavier than air and may travel long distances along the ground to an ignition source and flash back. A vapor and air mixture can create an explosion hazard in confined spaces such as sewers. If container is not properly cooled,it can rupture in the heat of a fire. Hazardous Combustion Products: Carbon dioxide,carbon monoxide,smoke,fumes and/or unburned hydrocarbons may be released in a fire. Fire-Fighting Instructions:Firefighters must use full bunker gear including NIOSH-approved positive pressure self-contained breathing apparatus(SCBA)to protect against potential hazardous combustion or decomposition products and oxygen deficiencies. Evacuate area and fight the fire from a maximum distance or use unmanned hose holders or monitor nozzles. Cover pooling liquid with foam. Containers can build pressure if exposed to radiant heat;cool adjacent containers with flooding quantities of water until well after the fire is out. Be aware that burning liquid will float on water. Notify appropriate authorities if liquid enters sewers or waterways. Section 6 - Accidental Release Measures Spill/Leak Procedures:Remove all sources of ignition. Avoid breathing vapors. Use self-contained breathing apparatus in enclosed area. Ventilate area. Contain and remove with inert absorbent materials and non-sparking tools. Page 2 of 6 01/09/06 Weathered Membrane Cleaner MSDS No. 302074 Flammable Liquid! Release causes an immediate fire or explosion hazard. A vapor-suppressing foam may be used to reduce vapors. Eliminate all ignition sources. All equipment used when handling this material must be grounded. Stop the leak if it can be done without risk. Do not touch or walk through spilled material. Remove spillage immediately from hard,smooth walking surfaces. Prevent spilled material from entering waterways,sewers, basements or confined area. Absorb or cover with dry earth,sand or other non-combustible material and transfer to appropriate waste containers. Use clean,non-sparking tools to collect absorbed material. For large spills,secure the area and control access. Prevent spilled material from entering sewers,storm drains,other drainage systems and natural waterways. Dike far ahead of a liquid spill to ensure complete collection. Water mist or spray may be used to reduce or disperse vapors;but it might not prevent ignition is closed spaces. This material will float on water and its run-off may create an explosion or fire hazard. In an urban area,cleanup spill as soon as possible; in natural environments,cleanup on advice from specialists. Pick up free liquid for recycle and/or disposal if it can be accomplished safely with explosion-proof equipment. Collect any excess material with absorbant pads,sand,or other inert non-combustible absorbent materials. Place into appropriate waste containers for later disposal. Comply with all laws and regulations. Section 7 - Handling and Storage Handling Precautions:A spill or leak can cause an immediate fire or explosion hazard. Keep containers closed and do not handle or store near heat,sparks or other potential ignition sources. Do not contact with oxidizable materials. Do not breath vapor. Use only with adequate ventilation and personal protection. Never siphon by mouth. Avoid contact with eyes,skin and clothing. Prevent contact with food and tobacco products. Do not take internally. KEEP OUT OF REACH OF CHILDREN. Storage Requirements: Store and transport in accordance with applicable laws. Keep containers tightly closed and store in a cool,dry,well-ventilated place,plainly labeled and out of closed vehicles. Keep away from ignition sources. Ground all equipment containing this material. Containers should be able to withstand pressures expected from warming and cooling in storage. This flammable liquid should be stored in a separate safety cabinet or room. Section 8 - Exposure Controls / Personal Protection Engineering Controls: Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapor and mists below the applicable workplace exposure limits of 300 ppm. All electrical equipment should comply with the National Electric Code. An emergency eye wash station and safety shower should be located near workstation. Ventilation: Provide general or local exhaust ventilation systems to maintain airborne concentrations below OSHA P.ELs (Sec.2).Local exhaust ventilation is preferred because it prevents contaminant dispersion into the work area by controlling it at its source. Administrative Controls: Respiratory Protection: Odor is not an adequate warning for potentially hazardous air concentrations. For unknown vapor concentrations,use a positive-pressure, pressure-demand,self-contained breathing apparatus(SCBA),especially when entering a confined space or where the oxygen concentrations may be reduced because of an accumulation of vapors. For known vapor concentrations above the occupational exposure guidelines(see Section 2), use a NIOSH-approved organic vapor respirator,if adequate protection is provided. Respirators should be used in accordance with OSHA requirements(29 CFR 1910.134). Eye Protection: Safety glasses equipped with side shields are recommended as minimum protection in industrial settings. Safety glasses/goggles should be worm during transfer operations or when there is a likelihood of misting,splashing or spraying of this material. Suitable eyewash water should be readily available. Hand Protection: Avoid skin contact. Use heavy duty gloves(such as Hycron©gloves)whenver handling material. Wash hands with plenty of mild soap and water before eating,drinking,smoking,use of toilet facilities or leaving work. Safety Stations: Make emergency eyewash stations,safety/quick-drench showers,and washing facilities available in work area. Contaminated Equipment: Separate contaminated work clothes from street clothes. Launder before reuse. Remove this material from your shoes and clean personal protective equipment. Comments:Never eat,drink,or smoke in work areas.Practice good personal hygiene after using this material,especially before eating,drinking,smoking,using the toilet,or applying cosmetics. Section 9 - Physical and Chemical Properties Physical State: Liquid Water Solubility: Very slight solubility in cold water Appearance and Odor: Clear liquid with characteristic (<O.11/,w/w) hydrocarbon solvent odor. Boiling Range(°C): 127 to 144(260 to 291°F) Odor Threshold(ppm):Not available. Freezing/Melting Point(°C):N/A Vapor Pressure: 5 mm Hg at 20°C Viscosity: <5(cSt @ 40°C) Vapor Density(Air=1):4.1 `%Volatile: 100 Density:average at 607=6.32 Ibs/gal(calculated) Evaporation Rate: 1.0(n-Butyl acetate= 1.0) Specific Gravity(H2O=1,at 4°C): 0.76 pH:N/A Page 3 of 6 MSDS No.302074 Weathered Membrane Cleaner 01/09/06 Section 10 - Stability and Reactivity Stability: Stable. Polymerization:Not expected to occur. Chemical Incompatibilities: Strong acids,alkalies and oxidizers such as liquid chlorine and oxygen. Conditions to Avoid:Keep away from heat,sparks,flame and strong oxidizing materials. Hazardous Decomposition Products:Toxic gases or vapors,such as carbon monoxide and carbon dioxide,may be released in a fire. Contact with strong oxidizing agents may cause fire and explosions. Section 11 Toxicological Information Eye Effects: Studies on laboratory animals have associated similar materials with eye and Acute Oral Effects:No data respiratory tract irritation. Chronic Effects:Rats developed kidney damage and elevated blood Skin Effects: Studies on laboratory animals urea nitrogen levels when exposed to a concentration of 1.9 rng/L for have shown similar materials to cause skin 65 days. The kidney damage occurred only in male rats and appeared irritation after repeated or prolonged contact. to involve both the tubules and glomeri. The significance of these Repeated direct application of Stoddard Solvent animal study results to human health is unclear. to the skin can produce defatting dermatitis and Carcinogenicity:No evidence kidney damage in laboratory animals. Mutagenicity:No evidence Teratogenicity:No evidence Section 12 - Ecological Information Ecotoxicity:This mixture contains components that are potentially toxic to freshwater and saltwater ecosystems. Environmental Fate:This mixture will normally float on water with its lighter components evaporating rapidly. In stagnant or slow-flowing waterways,a hydrocarbon layer can cover a large surface area. As a result,this covering layer might limit or eliminate natural atmospheric oxygen transport into the water. With time, if not removed,oxygen depletion in the waterway might be enough to cause a fish kill or create an anaerobic environment. This coating action can also be harmful or fatal to plankton,algae,aquatic life and water birds. Section 13 - Disposal Considerations Hazard characteristics and regulatory waste stream classification can change with product use. Accordingly,it is the responsibility of the user to determine the proper storage,transportation,treatment and/or disposal methodologies for spent materials and residues at the time of disposition. Disposal: Dispose of in accordance with all local,state,and federal regulations. Maximize material recovery for reuse or recycling. Recovered non-usable material may be regulated by US EPA as a hazardous waste due to its ignitability(D001) and/or its toxic(D018)characteristics. Conditions of use may cause this material to become a"hazardous waste",as defined by federal or state regulations. It is the-esponsibility of the user to determine if the material is a RCRA"hazardous waste"at the time of disposal. Disposal Regulatory Requirements:Transportation,treatment,storage and disposal of waste material must be conducted in accordance with RCRA regulations(see 40 CFR 260 through 40 CFR 271). State and/or local regulations may be more restrictive. Section 14 - Transport Information DOT Transportation Data (49 CFR 172.101): US DOT Status: This material is regulated by the U.S.Department of Transportation. Shipping Name:Paint related Packaging Authorizations Quantity Limitations material,3,UN1263 PG I1 a)Exceptions: 173.150 a) Passenger,Aircraft,or Railcar: 5L Shipping Symbols:Flammable b)Non-bulk Packaging: 173.173 b)Cargo Aircraft Only: 60L Hazard Class:3 c)Bulk Packaging: 173.242 1D No.:UN1263 Vessel Stowage Requirements Packing Group: 11 a)Vessel Stowage:B Label:red caution label required b)Other: n/a Special Provisions(172.102): 149,B52,1132,T4,TP1,TP8 Page 4 of 6 01/09/06 Weathered Membrane Cleaner MSDS No. 302074 Section 15 - Regulatory -information TSCA Inventory: This product and/or its components are listed on the Toxic Substances Control Act(TSCA)inventory. SARA 302/304 Emergency Planning and Notification: The Superfund Amendments and Reauthorization Act of 1986 (SARA)Title III requires facilities subject to Subparts 302 and 304 to submit emergency planning and notification information based on Threshold Planning Quantities(TPQs)and Reportable Quantities(RQs)for"Extremely Hazardous Substances" listyed in 40 CFR 302.4 and 40 CFR 355: No components were identified in this material. SARA 311/312 Hazard Identification: SARA Title III requires facilities subject to this subpart to submit aggregate information on chemicals by"Hazard Category"as defined in 40 CFR 370.2 This material would be classified under the following hazard categories: Fire,Acute(Immediate) Health Hazard;Chronic(Delayed) Health Hazard SARA 313 Toxic Chemical_Notification and Release Reporting: This product contains the following components in concentrations above de minimis levels that are listed as toxic chemicals is 40 CFR part 372 pursuant to the requirements of Section 313 of SARA: No components were identified. CERCLA: The Comprehensive Environmental Response,Compensation and Liability Act of 1980(CERCLA)requires notification of the National Response Center concerning release of quantities of"hazardous substances"equal to or greater than the reportable quantities(RQs)listed in 40 CFR 302.4. As defined by CERCLA,the term"hazardous substance"does not include petroleum, including crude oil or any fraction thereof which is not otherwise specifically designated in 40 CFR 302.4. Chemical substances present in this product that may be subject to this statute are: 2,2,4-Trimethylpenta-le[CAS No. 540-84-1]RQ= 1000 lbs. (453.6 kg) Concentration 1-5% Xylene,all isomers [CAS No. 1330-20-7] RQ= 100 lbs.(45.36 kg)Concentration<0.5% Ethylbenzene[CAS No. 100-41-4]RQ= 1000 lbs.(453.6 kg)Concentration<0.1% Benzene[CAS No.74-43-2]RQ= 10 lbs(4.536 kg)Concentration<0.005% Clean Water Act(CWA): This material is classified as an oil under Section 311 of the Clean Water Act(CWA)and the Oil Pollution Act of 1990(OPA). Discharges or spills which produce a visible sheen on waters of the United States,their adjoining shorelines,or into conduits leading to surface waters must be reported to the EPA's National Response Center at(800)424- 8802. California Proposition 65: This material may contain the following components which are known to the State of California to cause cancer,birth defects or other reproductive harm,and may be subject to the requirements of California Proposition 65(CA Health&Safety Code Section 25249.5): Ethylbenzene: <0.1% Toluene: <0.01% Benzene: <0.005% Delaware Air Quality Management List: none listed Florida Toxic Substances List: none listed Massachusetts Hazardous Substances List: none listed Michigan Critical Materials Register: none listed Minnesota Hazardous Substances List: none listed New Jersey Right-to-Know Label: none listed New York List of hazardous Substances: none listed Pennsylvania Hazardous Substances List: none listed Page 5 of 6 MSDS No. 302074 Weathered Membrane Cleaner 01/09/06 EPA Regulations: RCRA Hazardous Waste Number(40 CFR 261.33): Not listed RCRA Hazardous Waste Classification(40 CFR 261.30 through 261.38):Not listed SARA 311/312 Codes: SARA Toxic Chemical(40 CFR 372.65):Not listed SARA EHS(Extremely Hazardous Substance)(40 CFR 355):Not listed,Threshold Planning Quantity(TPQ) OSHA Regulations: Air Contaminant(29 CFR 1910.1000,Table Z-1,Z-1-A):Not listed Section 16 - Other Information Prepared By:Research&Development Revision Notes: Corrected Section 14—Transport Information Disclaimer:The information contained in this document is based upon data that was supplied to Carlisle by other companies and organizations.No warranty of merchantability or fitness for a particular purpose is expressed or implied regarding the accuracy or completeness of the data and/or information in this material safety data sheet. Page 6 of 6 Material Safety Data Sheet SURE-SEAL LAP SEALANT MSDS No. 302174 Date of Preparation: 10/31/05 Revision:013 Section I - Chemical Product and Company Identification Product/Chemical Name: SURE-SEAL LAP SEALANT Chemical Formula: Mixture General Use: Lap Sealant Manufacturer: Carlisle SynTec Incorporated, 1285 Ritner Highway,Carlisle,PA, 17013 , Phone: 800-479-6832 Emergency Phone Number:CHEMTREC(USA): 800-424-9300 Section 2 - Composition /Information on Ingredients Ingredient Name CAS Number %wt or %vol Light Aliphatic Solvent Naphtha 64742-89-8 37-38 Amorphous Silica 7631-86-9 3-6 Ethylene-Propylene Rubber 25038-36-2 Polybutene 9003-29-6 Calcium Carbonate 1.317-65-3 Ground Coal 125612-26-2 Paraffinic Oil 64742-01-4 Treated Clay 1332-58-7 Hazardous Ingredients: OSHA PEL ACGIH TLV NIOSH REL NIOSH Ingredient TWA STEL TWA STEL TWA STEL IDLH Light Aliphatic 300 ppm 400 ppm 300 ppm None estab. None estab. None None estab. Solvent Naphtha estab. Amorphous Silica 80mg/m/ None estab. 10 mg/m None estab. 6 mg/m None 3000 mg/m %SiO,_or 20 estab. b Section 3 - Hazards Identification Emergency Overview H MIS F 4 R 0 Potential Health Effects PPET Primary Entry Routes: Skin contact,eye contact, inhalation, ingestion. fSec.8 Target Organs: Acute Effects Inhalation:throat irritation on short term exposure to liquid or vapor. Aspiration into lungs can cause chemical pneumonitis which can be fatal. Eye: irritation on short-term exposure to liquid or vapor. Skin: irritation on short-term exposure to liquid or vapor. Ingestion: ingestion can cause gastrointestinal irritation Carcinogenicity: IARC,NTP,and OSHA do not list this product as a carcinogen. Medical Conditions Aggravated by Long-Term Exposure: Respiratory symptoms associated with pre-existing lung disorders and pre-existing heart disorders may be aggravated by exposure to this material. Chronic Effects: Overexposure may result in headache,dizziness,fatigue,nausea,and possible unconsciousness,even asphyxiation. Moderate irritation of skin,eyes and mucous membranes of upper respiratory tract on prolonged/repeated contact. Dermatitis and defatting of the skin. Chronic exposure may cause reversible liver and kidney injury. Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Section 4 - First Aid Measures Inhalation: Remove victim to fresh air and provide oxygen if breathing is difficult. Give artificial respiration if not breathing. Get medical attention immediately. Eye Contact:Immediately flush eyes with running water for at least 15 minutes. Get medical attention. I . MSDS No.302174 Sure-Seal Lap Sealant 10/31/05 Skin Contact:Immediately flush skin with running water and remove contaminated clothing. Wash exposed area with soap and water. Get medical attention. Ingestion:Do not induce vomiting. Get medical attention immediately. Special Precautions/Procedures:Whenever possible,remove the worker from the source of contamination. Section 5 - Fire-Fighting Measures Flash Point:4.4°C(40°F) NFPA Flash Point Method:TCC Autoignition Temperature:2490C(480°F) 4 LEL:0.9%v\v 1 0 UEL: 7.0%v/v Flammability Classification:Division 2. Ignition can occur when this product is exposed to heat,sparks,or flame. Extinguishing Media: In case of fire,use dry chemical,carbon dioxide,or foam. Water may not be effective as an extinguishing agent. Water fog or spray may be used to provide a smothering effect on fire and to cool fire-exposed containers and surrounding combustibles. Do not use a.solid stream of water because it can scatter and spread the fire. Unusual Fire or Explosion Hazards: Flammable. Store and use away from all sources of heat,flame,or sparks. Do not smoke while applying. Vapors are heavier than air and may travel along ground or may be moved by ventilation and ignited by pilot lights,other flames,sparks,heaters,smoking,electrical motors,static discharge,or other ignition sources at locations distant from material handling point and flash back. All containers should be grounded when material is transferred. Hazardous Combustion Products:Toxic gases or vapors,such as carbon monoxide or carbon dioxide,may be released in a fire. Fire-Fighting Instructions:This product contains solvents that are dangerous fire and explosion hazards when exposed to heat or flame. Fire fighters should wear self-contained breathing apparatus and full protective clothing with a full face piece operated in the positive pressure demand mode. Fire-Fighting Equipment: Because fire may produce toxic thermal decomposition products,wear a self-contained breathing apparatus with a full face piece operated in pressure-demand or positive-pressure mode. Section 6 - Accidental Release Measures Spill/Leak Procedures:Remove all sources of ignition. Avoid breathing vapors. Use self-contained breathing apparatus in enclosed area. Ventilate area.Contain and remove with inert absorbent materials and non-sparking tools. Large Spills: Containment:For large spills,dike far ahead of liquid spill for later disposal. Do not release into sewers or waterways. Cleanup: Clean-up spill as soon as possible. Collect any excess material with absorbent pads,sand or other inert non- combustible absorbent materials. Place into appropriate waste containers for later disposal. Comply with all laws and regulations. Regulatory Requirements:Follow applicable OSHA regulations(29 CFR 1910.120). Section 7 - Handling and Storage Handling Precautions: Use away from all sources of heat,flame,or sparks. Do not smoke while using. Handling equipment must be grounded to prevent sparking. Handle with non-sparking tools. Wash with soap and water before eating or drinking. Launder contaminated clothing. KEEP OUT OF REACH OF CHILDREN. Storage Requirements:Keep containers cool,dry,and store way from all sources of heat,flame,and sparks. Keep containers tightly closed and store with adequate ventilation. Do not pressurize,cut,weld,or grind the containers or empty containers which may contain residual product and solvent vapors that may ignite explosively. Section 8 - Exposure Controls / Personal Protection Engineering Controls:Do not use in enclosed areas without proper explosion-proof ventilation. General and local exhaust ventilation must be sufficient to control vapor concentrations and keep the vapor concentration below 300 ppm. Ventilation:Provide general or local exhaust ventilation systems to maintain airborne concentrations below OSHA PELs (Sec.2).Local exhaust ventilation is preferred because it prevents contaminant dispersion into the work area by controlling it at its source. Administrative Controls: Respiratory Protection:A NIOSH approved respirator must be used if vapor concentration is 300 ppm or above. Protective Clothing/Equipment:Hycron or equivalent solvent permeation resistant glove recommended. Glasses or goggles recommended. Industrial shoes to protect feet from sealant contact. Long sleeves, long trousers to protect skin from sealant contact. Protective skin creams or emollients useful. Page 2 of 5 10/31/05 Sure-Seal Lap Sealant MSDS No. 302174 Safety Stations: Make emergency eyewash stations,safety/quick-drench showers,and washing facilities available in work area. Contaminated Equipment: Separate contaminated work clothes from street clothes. Launder before reuse.Remove this material from your shoes and clean personal protective equipment. Comments:Never eat,drink,or smoke in work areas.Practice good personal hygiene after using this material,especially before eating,drinking,smoking,using the toilet,or applying cosmetics. Section 9 - Physical and Chemical Properties Physical State: Liquid Water Solubility:Negligible Appearance and Odor:Black,viscous paste with Boiling Point: 113-1420C hydrocarbon solvent odor Freezing/Melting Point: <-180C Odor Threshold:Not available %Volatile:36-38 Vapor Pressure:45mm Hg at 25°C Evaporation Rate: 1.6 Vapor Density(Air=1): 3.9 Specific Gravity(H2O=1,at 4°C): 1.03-1.04 pH:N/A Section 10 - Stability and Reactivity Stability: Stable. Polymerization: Will not occur. Chemical Incompatibilities: Strong oxidizing agents,acids,bases. Conditions to Avoid: Heat,sparks,and flames; ignition sources. Hazardous Decomposition Products:Toxic gases or vapors,such as carbon monoxide,carbon dioxide,or oxides of nitrogen may be released in a fire. Section 11- Toxicological Information Toxicity Data: Eye Effects: Irritating Acute Inhalation Effects:Product toxicity has not been determined. Following are component data: Skin Effects:Product toxicity has not been Light Aliphatic Solvent Naphtha: determined. Following are component data: Rat,inhalation, LC50:3400 ppm for four hours Light Aliphatic Solvent Naphtha: Rat,dermal,LD50: >4 mL/kg Acute Oral Effects:Product toxicity has not been determined. Following are component data: Light Aliphatic Solvent Naphtha: Rat,oral, LD50: >8 mL/kg Chronic Effects: May cause skin sensitization in some people Carcinogenicity:No evidence Mutagenicity:No evidence Teratogenicity:No evidence Section 12 - Ecoloaicai Information Ecotoxicity:Not known Environmental.Fate:Not known Environmental Degradation:Not known Soil Absorption/Mobility:Not known Section 13 - Disposal Considerations :Disposal:Dispose of in accordance with all local,state,and federal regulations. Page 3 of 5 MSDS No.302174 Sure-Seal Lap Sealant 10/31/05 Section 14 - Transport Information DOT Transportation Data (49 CFR 172.101): Shipping Name:Adhesives,3, Packaging Authorizations Quantity Limitations UN1133,II a)Exceptions: 173.150 a) Passenger,Aircraft,or Railcar: 5 L Shipping Symbols:Flammable b)Non-bulk Packaging: 173.173 b)Cargo Aircraft Only: 60 L Hazard Class: 3 c)Bulk Packaging: 173.242 ID No.: UN1133 Vessel Stowage Requirements Packing Group: 11 a)Vessel Stowage: B Label:red caution label required b)Other:--- Special Provisions(172.102): 149,B52,I132,T4,TP1,TP8 Section 15 - Regulatory Information EPA Regulations: RCRA Hazardous Waste Number(40 CFR 261.33): Not listed RCRA Hazardous Waste Classification(40 CFR 261):Not classified TSCA(Toxic Substances Control Act)Status: TSCA(United States)—The intentional ingredients of this product are listed. CERCLA Hazardous Substance RQ—40 CFR 302.4(a): Not listed CERCLA RQ—40 CFR 302.4(b) Materials with a"listed"RQ may be reportable as an"unlisted hazardous substance". See 40 CFR 302.5 (b). SARA 311/312 Codes: Immediate(X) Delayed(X) Fire(X) Reactive( Sudden Release of Pressure( ) SARA 313 Components(40 CFR 372.65): Not listed SARA EHS(Extremely Hazardous Substance)(40 CFR 355): Not listed,Threshold Planning Quantity(TPQ) OSHA Regulations: Air Contaminant(29 CFR 1910.1000,Table Z-1,Z-1-A):Not listed OSHA Specifically Regulated Substance(29 CFR 1910): None listed EPA Accidental Release Prevention(40 CFR 68): None listed State Regulations: California Proposition 65: The following statement is made in order to comply with the California Safe Drinking Water and Toxic Enforcement Act of 1986: This product contains the following substance(s)known to the State of California to cause reproductive harm: None Delaware Air Quality Management List: None Florida Toxic Substance: The following components are listed as a toxic substance by the state of Florida: Amorphous Silica Massachusetts Hazardous Substances List: Chemical Name CAS# Codes Amorphous Silica 7631-86-9 2,4, 5, F5 Page 4 of 5 I 10/31/05 Sure-Seal Lap Sealant MSDS No. 302174 Michigan Critical Materials Registry: None Minnesota Hazardous Substance: Chemical Name Codes Hazards Carcinogen? Silica ANOR -- T New Jersey RTK Label Information: None New York List of Hazardous Substances:None Pennsylvania RTK Label Information Chemical Name CAS# Code Silica 7631-86-9 --- Washington Air Contaminant: None Section 16 - Other Information Prepared By: Research&Development Revision Notes:Revised to new 16-part MSDS format. Disclaimer: The information contained in this document is based upon data that was supplied to Carlisle by other companies and organizations.No warranty of merchantability or fitness for a particular purpose is expressed or implied regarding the accuracy or completeness of the data and/or information in this material safety data sheet. Page 5 of 5 c Material Safety Data Sheet Product Name: Sure-Seal HP-250 Primer MSDS No. 302070 Date of Preparation: 05/31/05 Revision: 007 Section 1 - Chemical Product and Company Identification Product/Chemical Name: SURE-SEAL HP-250 PRIMER Chemical Formula: Mixture General Use:Primer for EPDM Membrane Manufacturer:Carlisle SynTec Incorporated, 1285 Rimer Highway,Carlisle,PA 17013,Phone—800-479-6832, 24-Hour Emergency Phone Number: CHEMTREC(USA): 800-424-9300 Section 2 - Composition / Information on Ingredients Ingredient Name CAS Number %wt or %vol Toluene 108-88-3 75-85 Heptane 142-82-5 4-8 Hydrocarbon Tackifying Resin 68131-87-3 >3 Hazardous Ingredients: OSHA PEL ACGIH TLV NIOSH REL NIOSH Ingredient TWA I STEL TWA I STEL TWA STEL IDLH Toluene 1200 ppin 1150 ppin 50 m None ekib. 100 m 150 m 500 m Heptane 500 m None estab. 400 p m 500 ppm 85 ppm None estab. 750 ppm Section 3 - Hazards Identification EmergencyOverview HMI H I t Appearance/Odor: Thin liquid with hydrocarbon odor. Color may range from pumpkin orange to olive F 4 green to light grey. R 0 PPEt WARNING: Flammable tSec.8 Potential Health Effects Primary Entry Routes: Eye contact, ingestion,inhalation,skin absorption,skin contact. Target Organs: Kidney and liver. Acute Effects Inhalation: May cause nose and/or throat irritation on short-term exposure to vapor. Aspiration into lungs can cause chemical pneumonitis,which can be fatal. Overexposure may result in headache,dizziness,fatigue,nausea and loss of consciousness. Eye: May cause eye irritation on short-term exposure to liquid or vapor. Skin: May cause skin irritation on short-term exposure to liquid or vapor. Solvents may be absorbed through the skin in toxic amounts. Ingestion: May cause irritation of gastrointestinal tract. Carcinogenicity: IARC,NTP,and OSHA do not list this product as a carcinogen. Medical Conditions Aggravated by Long-Term Exposure: May cause more significant skin irritation in people with pre- existing skin conditions. Respiratory symptoms associated with pre-existing lung disorders and pre-existing heart disorders may be aggravated by exposure to this material. Chronic Effects: Chronic exposure may cause reversible kidney and liver injury. Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Repeated exposure to Toluene has been associated with high frequency hearing loss based on animal tests. Section 4 - First Aid Measures Inhalation:Remove victim to fresh air and provide oxygen if breathing is difficult. Give artificial respiration if not breathing. Get medical attention immediately. Eye Contact:Immediately flush eyes with running water for at least 15 minutes. Get medical attention. Skin Contact: Immediately flush skin with running water and remove contaminated clothing. Wash exposed area with soap and water. Get medical attention. I s MSDS No. 302070 Sure-Seal HP-250 Primer 5/31/05 Ingestion:DO NOT induce vomiting.Get medical attention immediately. Note to Physicians:This material contains Toluene and Heptane. Special Precautions/Procedures: Whenever possible,remove the worker from the source of contamination. Section 5 - Fire-Fighting Measures Flash Point:4.40°C(407) NFPA Flash Point Method: C.0 4 Autoignition Temperature: 536°C(997°F) LEL: 1.3%v/v 0 UEL: 7.0%v/v Flammability Classification:Ignition can occur when this product is exposed to heat,Division 2 sparks,or flame. Extinguishing Media: In case of fire,use dry chemical,carbon dioxide,or foam. Water may not be effective as an extinguishing agent. Water fog or spray may be used to provide a smothering effect on fire and to cool fire-exposed containers and surrounding combustibles. Do not use a solid stream of water because it can scatter and spread the fire. Unusual Fire or Explosion Hazards: Extremely flammable. Store and use away from all sources of heat,flame,or sparks. Do not smoke while applying. Vapors are heavier than air and may travel along ground or may be moved by ventilation and ignited by pilot lights,other flames,sparks,heaters,smoking,electrical motors,static discharge,or other ignition sources at locations distant from material handling point and flash back. All containers should be grounded when material is transferred. Hazardous Combustion Products:Toxic gases or vapors,such as carbon monoxide or carbon dioxide,may be released in a fire. Fire-Fighting Instructions:This product contains solvents that are dangerous fire and explosion hazards when exposed to heat or flame. Fire-Fighting Equipment:Because fire may produce toxic thermal decomposition products,wear a self-contained breathing apparatus(SCBA)and full protective clothing along with a full face piece operated in pressure-demand or positive-pressure mode. Section 6 - Accidental Release Measures Personal Precautions: Use personal protection recommended in Section 8. Spill/Leak Procedures:Remove all sources of ignition. Avoid breathing vapors. Use self-contained breathing apparatus in enclosed area. Ventilate area. Contain and remove with inert absorbent materials and non-sparking tools. For large spills,dike far ahead of liquid spill for later disposal. Do not release into sewers or waterways. Regulatory Requirements: Follow applicable OSHA regulations(29 CFR 1910.120). Section 7 - Handling and Storage Handling Precautions: Use away from all sources of heat,flame,or sparks. Do not smoke while using. Handling equipment must be grounded to prevent sparking. Handle with non-sparking tools. Wash with soap and water before eating or drinking. Launder contaminated clothing. KEEP OUT OF REACH OF CHILDREN. Storage Requirements:Keep containers cool,dry,and store away from all sources of heat,flame,and sparks. Keep containers tightly closed and store with adequate ventilation. Do not pressurize,cut,weld,or grind the containers or empty containers, which may contain residual product and solvent vapors that may ignite explosively. Section 8 - Exposure Controls / Personal Protection Engineering Controls:Do not use in enclosed areas without proper explosion-proof ventilation. General and local exhaust ventilation must be sufficient to control vapor concentrations and keep the vapor concentration below 100 ppm. Ventilation: Provide general or local exhaust ventilation systems to maintain airborne concentrations below OSHA PELs(Sec. 2).Local exhaust ventilation is preferred because it prevents contaminant dispersion into the work area by controlling it at its source. Respiratory Protection:A NIOSH approved respirator must be used if vapor concentration is 100 ppm or above. Protective Clothing/Equipment:Hycron,Neoprene,Nitrile,or equivalent solvent permeation resistant gloves required. Protective glasses or goggles recommended. Industrial boots to protect feet from cleaner contact. Impervious clothing is recommended to protect skin from cleaner.contact. Protective skin creams or emollients useful. Safety Stations: Make emergency eyewash stations,safety/quick-drench showers,and washing facilities available in work area. Contaminated Equipment: Separate contaminated work clothes from street clothes.Launder before reuse.Remove this material from your shoes and clean personal protective equipment. Comments:Never eat,drink,or smoke in work areas.Practice good personal hygiene after using this material,especially before eating,drinking,smoking,using the toilet,or applying cosmetics. Page 2 of 4 M 5/31/05 Sure-Seal HP-250 Primer MSDS No.302070 Section 9 - Physical and Chemical Properties Physical State: Liquid Water Solubility: Negligible Appearance and Odor: Thin pumpkin orange to olive Boiling Point(°C): 110.4°C green to light grey liquid with hydrocarbon odor Freezing/Melting Point-95.0°C Odor Threshold(ppm): Not available °/o Volatile by Weight: 80-90 Vapor Pressure: 36.7 mm Hg at 30°C Evaporation Rate: (nBuAc=1):2.1 Vapor Density(Air=1): 3.14 Specific Gravity(H20=1,at 4°C): 0.89 pH: Not available Section 10 - Stability and Reactivity Stability: Stable under normal conditions. Polymerization: Will not occur. Chemical incompatibilities: Strong oxidizing agents,acids,bases,amines. Conditions to Avoid: Heat,sparks,and flames; ignition sources. Hazardous Decomposition Products:Toxic gases or vapors such as carbon monoxide or carbon dioxide,may be released in a fire. Section 11- Toxicological Information Toxicity Data: This product has not been tested. No data available. Section 12 - Ecological Information Ecotoxicity: No data available. Environmental Fate:No data available. Environmental Degradation: No data available. Soil Absorption/Mobility:No data available. Section 13 - Disposal Considerations Waste Disposal: Dispose of in accordance with all local,state,and federal regulations. Section 14 - Transport Information DOT Transportation Data (49 CFR 172.101): Shipping Name:Adhesives,3 Packaging Authorizations Quantity Limitations Shipping Symbols: Flammable a)Exceptions: 173.150 a)Passenger,Aircraft,or Railcar: 5 L Hazard Class: 3 b)Non-bulk Packaging: 173.173 b)Cargo Aircraft Only: 60 L ID No.: UN 1133 c)Bulk Packaging: 173.242 Packing Group: lI Vessel Stowage Requirements Label:Red caution label a)Vessel Stowage:B required. b)Other: -- Special Provisions(172.102): 149,1352, 1132,T4,TP1,TP8 Section 15 Regulatory Information EPA Regulations: RCRA Hazardous Waste Number(40 CFR 261.33): Toluene,CAS#108-88-3,RCRA Code U220 RCRA Hazardous Waste Classification(40 CFR 261.31):Not classified CERCLA Hazardous Substance(40 CFR 302.4): Toluene,CAS#108-88-3,RQ 1000 lb CERCLA Reportable Quantity(RQ): Materials with a"listed"RQ may be reportable as an"unlisted hazardous substance". See 40 CFR 302.5(b). SARA 313 Components(40 CFR 372.65): Toluene,CAS#108-88-3, 75-85% SARA Toxic Release Chemicals:Toluene,CAS#108-88-3,Concentration: 1.0%,Reporting Threshold: Standard Page 3 of 4 MSDS No. 302070 Sure-Seal HP-250 Primer 5/31/05 OSHA Regulations: Clean Water Act Hazardous Substances: Toluene,CAS#108-88-3, RQ 1000 lb Clean Air Act SOCMI Chemicals: Toluene,CAS#108-88-3 Clean Air Act Hazardous Air Pollutants: Toluene,CAS#108-88-3,HAP Code\OV OSHA,IARC,NTP Carcinogens: None listed. State Regulations: California Proposition 65 Chemicals: Toluene,CAS#108-88-3,Code D Delaware Air Quality Management List: Toluene,CAS#108-88-3,DRQ: 1000,State: Y Florida Toxic Substances List: Heptane,CAS#142-82-5 Toluene,CAS#108-88-3 Massachusetts Hazardous Substances List: Heptane,CAS#142-82-5,Codes: 2,4,5,6 Toluene,CAS#108-88-3,Codes: 2,4,5,6,F7,F8, F9 Michigan Critical Materials Register: Toluene,CAS#108-88-3, Report Code: --,Class:-- Minnesota Hazardous Substances List: Heptane,CAS#142-82-5,Codes:ANO, Hazards:--,Carcinogen:No Toluene,CAS#108-88-3,Codes:ANO,Hazards: Skin,Carcinogen:No New Jersey RTK Hazardous Substance List: Toluene,CAS#108-88-3,Substance#: 1866,DOT#: 1294 New York List of Hazardous Substances: Toluene,CAS#108-88-3,RQ-Air: 1000,RQ-Land: 1,Notes:None Pennsylvania Hazardous Substances List: Heptane,CAS#142-82-5,Code: --(Basic Hazard) Toluene,CAS#108-88-3,Code: E(Environmental Hazard) Washington Permissible Exposure Limits for Air Contaminants: Chemical Name CAS# TWA TWA STEL STEL Ceiling Ceiling Skin (pp"') (Ing) (pp"') (111g) (pp"') 011g) Heptane 142-82-5 400 1600 500 2000 - -- -- Toluene 108-88-3 100 375 150 560 - -- -- Section 16 - Other Information Prepared By:Research&Development Revision Notes: Converted to new 16-Part format. Additional Hazard Rating Systems: Disclaimer:The information contained in this document is based upon data that was supplied to Carlisle by other companies and organizations.No warranty of merchantability or fitness for a particular purpose is expressed or implied regarding the accuracy or completeness of the data and/or information in this material safety data sheet. Page 4 of 4