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HomeMy WebLinkAbout1780 MAIN ST./RTE 6A(W.BARN.) - Health 1780 Main St West Barnstable A = 217 - 004 d a r� N w g 2 a i ---------------------- Ja�SED Siq�s ENVIRONMENTAL PROTECTION AGENCY s. >W REGION 1—NEW ENGLAND �3'+7 PROZF•ESO Lynne A. Hamjian Deputy Director Office of Ecosystem Protection 5 Post Office Sq. Suite 100 Phone: (617)918-1601 Mail Code: OEP06-5 Fax: (617)918-0601 Boston,MA 02109-3912 hamjian.lynne@epa.gov I 3 ' UNITED STATES ENVIRONMENTAL PROTECTION AGENCY OFFICE OF INSPECTOR GENERAL 290 BROADWAY NEW YORK,NY 10001 i November 8, 2017 a Lynne Hamjian Acting Division Director «L fit ti=� Y?z Office of Ecosystem Protection U.S. EPA, Region 1 5 Post Office Square, MC.OEP06-5 Boston, MA 02109-3912 Dear Ms. Hamjian: The EPA Office of the Inspector General (OIG), Office of Investigations (01), New York Field--Office has received numerous complaints from Patrick Page, private citizen, 1780 Main Street, West Barnstable, MA 026% 508-280-7243 relative to environmental issues/concerns with his property in the Town of Barnstable, MA (the Town). Mr. Page has had a long standing dispute with the Town, the County, the Massachusetts Department of Environmental Protection (MADEP), the Massachusetts Department of Transportation (MADOT), and the United States Army Corps of Engineers (ACOE) Mr;#Page`:has�made�numerousallegatr'ons concerning a discharge pipe on his-property that he claims is havingian:adverse effectonlas water The EPA OIG 01 previously made a referral to your office on December 27, 20T6-, relative to numerous issues raised by Mr. Page.The EPA OIG 01 was recently provided with additional water test results related to Mr. Page's property. Enclosed with this referral are copies of two Memoranda of Activity related to the receipt and review of those results. The EPA OIG 01 has no direct nexus in the matters raised by Mr. Page. There will be no further action taken by the EPA Office of Inspector General concerning these allegations. As the alleged violations are outside the jurisdiction of this office, we are referring this matter to your office for any action you deem appropriate. This letter will serve as official notice of the referral to your office. An identical letter will be sent to the Office of Ground Water and Drinking Water, EPA, Washington, DC. Prior to contacting Mr. Page directly, please contact this office for important information regarding these allegations. If yoti.have any,gtiesti hs:or wish to discuss„ this matter in further detail,please contact me at,(2-12)637 3033_ f I Sincerely, _ Paul A. Brezins i Resident Agent in Charge New York Post of Duty Enclosures UNITED STATES ENVIRONMENTAL PROTECTION AGENCY OFFICE OF INSPECTOR GENERAL 290 BROADWAY NEW YORK,NY 10007 CASE #: COMP-2018-0003 CROSS REFERENCE #: COMP-2014-0153, COMP-2016-0088 TITLE: ENVIRONMENTAL ISSUES, BARNSTABLE, MA INTERVIEWEE (if applicable): PREPARED BY: RAC PAUL A. BREZINSKI MEMORANDUM OF ACTIVITY DOCUMENT REVIEW NARRATIVE: On October 31, 2017, Resident Agent in Charge Paul A. Brezinski, U.S. Environmental . Protection Agency, Office of Inspector General, Office of Investigations, 290 Broadway, Suite 1520,New York; NY completed a review of various test results provided by Ronald J. Saari, President, Envirotech Laboratories, Inc. (ELI), 8 Jan Sebastian Drive, Unit 12, Sandwich, MA 02563. The results were sent on behalf of his client, Patrick Page, private citizen, 1780 Main Street, West Barnstable, MA. Page previously made allegations about a discharge pipe on his property. The following was derived in substance: Saari sent page a letter dated September 27, 2016. Saari advised that on September 22, 2016, two water samples were collected by ELI at the trench located on Page's property. It was noted that the trench is an extension of the outfall pipe that is located on the property (Attachment 1, page 1). It was noted that the applicable EPA Method was 1603. A Chain of Custody Form accompanied the report. The test results follow: Results: E coli were detected at the bridge location: 1,900 cfull00ml. E coli were detected at the ditch location: 140,000 efull00ml. Comment: E coli counts are significant for sample sites. CASE: COMP-2018-0003 INTERVIEWEE(if applicable): DATE OF ACTIVITY: October 31, DRAFTED DATE: October 31,2017 AGENT(S): Brezinski 2017 and November 3,2017 RESTRICTED INFORMATION This report and any attachments are the property of the EPA Office of Inspector General,Office of Investigations and is Page I of 4 loaned to your agency. It and its contents may not be reproduced or disclosed without written permission. "Phis report contains information protected by the Privacy Act and is FOR OFFICIAL USE ONLY. Disclosure of this report to unauthorized persons is prohibited. See 5 U.S.C.552a. Saari sent page a second letter dated October 26, 2016. Saari advised that on September 28, 2016, two water samples were collected by ELI at the trench located on Page's property. It was noted that the trench is an extension of the outfall pipe that is located on the property (Attachment 1, page 4). It was noted that the applicable EPA Method was 1603. A Chain of Custody Form accompanied the report. The test results follow: Results: E coli were detected at the bridge location: 68,000 efull00ml. E coli were detected at the ditch location: 1,600 cfull00ml. Comment: E coli counts are significant for sample sites. Saari sent page a letter dated September 18, 2017. Saari advised that on August 29, 2017, a sample for algae was collected by ELI at the ditch located on Page's property. It was noted that the ditch is an extension of the outfall pipe that is located on the property. The sample was collected at the bridge location of the ditch. Saari stated "The material consists of large amounts of filamentous bacteria." (Attachment 2, page 1). The actual testing was conducted by Northeast Laboratories, Inc. (NLI), 129 Mill Street, Berlin, CT 06037. The documents include a summary of the test results and a Chain of Custody Form from ELI (Attachment 2, pages 3-4). Saari sent page a letter dated September 12, 2017. Saari advised that on August 7,'2017, water samples were collected by ELI at the ditch located on Page's property. It was noted that the ditch is an extension of the outfall pipe that is located on the property. The sample was taken at the bridge location of the ditch (Attachment 3, page 1). It was noted that the applicable EPA Method was 200.7 (for the water sample). The test results follow: There was found 1,800 ug/L of petroleum that most closely resembles 50w motor oil. Also, amounts of Lead, Copper, Chromium, Aluminum, Iron, and Manganese were detected. Sample.for Algae Identification was taken at the ditch located at the large boulder. Genus Aphanocapsa and Nostoc belong to the Cyanobacteria group. The analysis of the "Petroleum Fingerprint" was conducted by R.I. Analytical (RIA), 41 Illinois Avenue, Warwick, RI 02888. The documents included a summary of test results and chain of custody documents. (.Attachment 3, pages 3-6) The analysis of the"Algae Identification" was conducted by NLI. The documents included an analytical report and chain of custody documents (Attachment 3, pages 7-9). CASE: COMP-2018-0003 INTERVIEWEE(if applicable): DATE OF ACTIVITY: October 31, DRAFTED DATE: October 31,2017 AGENT(S): Brezinski 2017 and November 3,2017 RESTRICTED INFORMATION This report and any attachments are the property of the EPA Office of Inspector General,Office of Investigations and is Page 2 of 4 loaned to your agency. It and its contents may not be reproduced or disclosed without written permission. This report contains information protected by the Privacy Act and is FOR OFFICIAL USE ONLY. Disclosure of this report to unauthorized persons is prohibited. See 5 U.S.C.552a. An ELI report related to sample(s) taken on August 27, 2013 of discharge pipe A located on Page's property indicated E coli 5,000 cfu/100m1, Total Petroleum hydrocarbons 850 ug/L, C19- C36 Aliphatics 210 ug/L, Di-n-butyl phthalate 15 ug/L. Several of the analyses were conducted by RIA and the documents included a certificate of analysis and the test results (Attachment 4). An ELI report related to sample(s) taken on August 1, 2013 of outfall A located on Page's property yielded results for a"Petroleum Fingerprint". The analysis was conducted by RIA which noted: "Fingerprint: Chromatogram best matches weathered biodiesel fuel, possibly from vegetable oil sources."The sample type was identified as "Drinking". Agent's Note: The attachment titles and file names were provided by Saari and not changed by the Reporting Agent. Attachments: 1. Trench 9-22 & 9-28-17 2. 8-29-17 outfall bact 3. 8-7-17 ditch 4. 8-13-17 discharge pipe 5. 8-1-13 outfall CASE: COMP-2018-0003 INTERVIEWEE(if applicable): DATE OF ACTIVITY: October 31, DRAFTED DATE: October 31,2017 AGENT(S): Brezinski 2017 and November 3,2017 RESTRICTED INFORMATION This report and any attachments are the property of the EPA Office of Inspector General,Office of Investigations and is Page 3 of 4 loaned to your agency. It and its contents may not be reproduced or disclosed without written permission. This report contains information protected by the Privacy Act and is FOR OFFICIAL USE ONLY. Disclosure of this report to unauthorized persons is prohibited. See 5 U.S.C.552a. Attachments: 1. Trench 9-22 & 9-28-17 Trench 9-22& 9-28-17.pdf 2. 8-29-17 outfall bact 8-29-17 outfall bact.pdf 3. 8-7-17 ditch Uj 8-7-17 ditch.pdf 4. 8-13-17 discharge pipe 8-13-17 discharge pipe.pdf 5. 8-1-13 outfall 8-1-13 outfall.pdf CASE: COMP-2018-0003 INTERVIEWEE(if applicable): DATE OF ACTIVITY: October 31, DRAFTED DATE: October 31,2017 AGENT(S): Brezinski 2017 and November 3,2017 RE'STRIC'FED INFORMATION This report and any attachments are the property of the EPA Office of Inspector General,Office of Investigations and is Page 4 of 4 loaned to your agency. It and its contents may not be reproduced or disclosed without written permission. This report contains information protected by the Privacy Act and is FOR OFFICIAL USE ONLY. Disclosure of this report to unauthorized persons is prohibited. See 5 U.S.C.552a. Envir®tech Laboratodes, 8 Jan Sebastian Dr Unit 12 Sandwich, MA 02563 Inc Sandwich, 888-6460 Fax(508)888-6446 September 27,2016 Patrick Page 1780 Main Street W. Barnstable, MA Dear Patrick, On September 22,2016, two water samples were collected by Envirotech Laboratories at the trench located at 1780 Main Street West Barnstable, MA. The trench is an extension of the outfall pipe that is located on the property. Results: E coli were detected at the bridge location: 1,900 cfu/100ml. E coli were detected at the ditch location: 140,000 cfu/100ml. Comment: E coli counts are significant for sample sites. i Sincerely you , 4 .�2on J. Saari � Pre ' ent PH:508 888 6460 rsenviro@comcast.net k' I i r' ENVIR0TECH LABORA TORIES INC. MA CERT. NO: M MA 063 8 Jan Sebastian Drive . Sandwich, MA 02563 (508)888-6460 1-800-339-6460 FAX(308)888-6446 Tuesday,Seplernber 27, `2016 ; Page, Patrick 1780,Ifain D 1V Bejrnstahle, A,1 ProjectName: 1780 Main St Comments: Project Number: Collection Date: 09122/16 Collection Time: 14:50 Sampled By: R Saari Lab Order Numbers TYGY-161984 Date Received: 091221.16 — .rz:;.k �.._ sx_„ ..,..._...,:.. ,x....yH Ty �^, '82'1xx'�-...,�,.',l�,:o-a�"+a,:�Jf� .t .,3 .Fn dik.,,eT•.,�+'x'�--�.r.r., -'. Parantders Units Test Results Reportable Limits DareAnalyted Analyst ,11ed,od E.11 coli CFU/100ML 1,900 NA 09/22/16 RS EPA 1603 4SamplrTYpe p T ,.� SamplrDate a -,_ar a1n rS Parameters Units Test Results Reportable Limits Dare t»niyzed tnalysl tledmrl E soli CFU/100mL 140,000 NA 09/22/16 RS EPA 1603 i t BRl_=below reportable lbnus `s•ee attaches! V s 1?0n0l(l.T. Sauri l i Lahorator),v ector Page 1 of 1 — k I`. CHAIN OF CUSTODY FORM ENVIROTECH LABS, IN Client: Patric Page 8 Jan Sebastian Dr., Unit Proj. No, Project Name: Ecoli Sandwich, MA 02563 Address: 1780 Main St I it � S (508)888-6460./1-800-339-6460 Sampler: Ron Saari/Env W. barnstable,MA 02668 FAX(508)888-6446 Phone#: 508 280 7243 Lab ID# Date Time Comp Grab Fax#: P Sample location container Pres. 11g2& 9/22/16 (4,(1 )�,k I Analysis Requested t E coil Relinquished: / Oat ime Rec eve r ERelinquished: Date/Time Received: Relinquished: Da e/Time i R ei Date/Time Received: Envi otech Laboratories, 8 Jan Sebastian Dr Unit 12 Sandwich, MA 02563 Inc (508) 888-6460 Fax (508) 888-6446 October 26,2016 Patrick Page 1780 Main Street W.Barnstable, MA Dear Patrick, On September 28,2016,two water samples were collected by Envirotech Laboratories at the trench located at 1780 Main Street West Barnstable, MA.The trench is an extension of the outfall pipe that is located on the property. Results: E coli were detected at the bridge location:68,000 cfu/1 poml. E coli were detected at the ditch location: 1,600 cfu/100011. Comment: E coli counts are significant for sample sites. Sincerely yours, Ronal Saari Presi nt PH:s508 888 6460 rsenviro@comcast.net i i i l 7 r. is I: f: ENVIROTECHLABORATORIES, INC. MA CERT. NO.: M-MA 063 8.Ian Sebastian Drive Sandwich,MA 02563 (508)888-6460 1-800-339-6460 " FAX(50b)888-6446 Alonday,October 03,2016 Page, Patrick 1780 Alain St 1Y Barnstable, M ProjeclNume: Trench Comments;Project Number: Collection Data: 09128116 Collection Time; Sampled By: R Scrari Lab Order Number: WIY-162032 Dale Received: 09128116 Safi p!e T�pe} Sum"!e Inte • ,� r 09/28/16 III ... ... ... •_ ' { ;l� Y ' -- ...,.., w.,...., ._�,:..� • .,-r.. .. ... a � .. Dredge;.Badge � Parameters Writs Tesl Resrr/ts Repvrtnb/e Lnnits Dare A1rn/nzed Ann/psl t ilelhor/p E coli CFUr100mL 68 000 NA 09128/16 RS EPA 1603 Sau1�lc Type,� r t ��; �Sr»�rpl4g,�Tinret Srunple Datc '' r, �� Trench B63 14 50 09/28/16 k` , Dre ge=Di- c Parameters Units Test Results ReparluGle Linrils DrrleAnrrlpzed Analyst ,11e1/rod E coli CFU/ OOmL 1,600 NA Os/28/16 RS EPA 1603 i • `r 5 3 �i r BRL=below reportable l/nrits ibsee aaached --- r Rona d aart F. Lnbor�lo Director g Page 1 of 1 CHAIN OF CUSTODY FORM ENVIROTECH LABS, INC. Client: Patrick Page 8 Jan Sebastian Dr., Unit 12 Proj. No. Project Name: 1780 Main St W Barnstable Sandwich, MA 02563 Address: 1780 Main St � NL(+ (508)888-6460/1-800-339-6460 W. barnstable,MA 02668 Sampler: FAX(508)888-6446 Phone#: 508 280 7243 Fax#: Lab ID# Date Time Comp Grab Sample location container Pres. Analysis Requested l NEC, ITT 0 i 1 f I Relinquis ed Date ime (,l( Recei4e I / Reliquished: Daterrime Received: JU -VI A 14 Z' Refi"nquisEied: Da e�me Rec .iv d: Relinquished: Date/Time Received: I , Envirotech Laboratories, 8 Jan Sebastian Dr Unit 12 Sandwich, MA 02563 Inc (508) 888-6460 Fax (508) 888-6446 September 18,2017 Patrick Page 1780 Main Street W.Barnstable, MA Dear Patrick, On August 29,2017,a sample for algae was collected by Envirotech Laboratories at the ditch located at 1780 Main Street West Barnstable,MA. The ditch is an extension of the outfall pipe that is located on the property.The sample was collected at the bridge location of the ditch. The results are attached. The material consists of large amounts of filamentous bacteria, Sincerely yours, onald J. ari President PH: 508 8 6460 rsenvirc comcast.net I I, { T ENVIROTECH LABORATORIES, INC. MA CERT. NO.: 1-MA 063 8 Jan Sebastian Drive Sandwich, BIA 02S63 (S08)88.8-6460 1-800-339-6460 FAX(.508)888-6446 Ahmilay,September 18,2017 F'nge, Patrick 17,90,d Inin S/ FP Ban isloble, A ProjectNatne: Continents: Project Number: Collection Date: 08129117 Collection Time: 12.20 Sampler!BY: R Saari Lab Order Number: TVTV-171903 Date Received: 08129117 Sample Type Smriple Trrne Sample Mfg Co»mienls Ditch at t3ndge A 1220 08/29/17 Filamentous bacteria Parameters Units Test Results Reportable Limits Date Anal-ed Analpst Method Algae Identification #/ml see comment NA 09/08/17 INortheast Lab BRI.=belom reportable lit ti s 'see attached r f` Roilald J aari . Laborat y Director Page 1 of 1 . i 4- Northeas't Laboratories Inc. ANALYTICAL REPORT Pa e 1 of 1. Report To: ENVIROTECH LABORATORIES, INC. Attn: Ronald Saari, President EMAIL ADDRESSEE: rsenviro@comcast.net. 8 Jan Sebastian Dr= Unit#12 Sandwich MA 02563 Report Date: 9/13/2017 Date Sampled: 8/29/2017 Laboratory 1D#: N1771449 Date Received: 9/06/2017 Envirotech's iD#: DW— 171903 Date Tested: 9/08/2017 MICROSCOPIC EXAMINATION: Raw Water—SITE: Ditch Bridge ORGANISM #/ml ORGANISM #/ml ORGANISM ##/ml ORGANISM #/ml Diatomaceae Chloro h ceae C ano h ceae Protozoa Amphora Actinastrum Anabaena* Actinophrys Asterionella* Arthrodesmus Anabaeno sis Amoeba Am hiprora Ankistrodesmus A hanoca sa Arcella Cocinodiscus Chorelta A hanizomenon* Bursaria* C clotella* Closterium A hanothece Ceratium C mbella Coelastrum Aulosira lCercornonas Diatoma* Cosmarium Arthros ira IChilomonas Frustulia Dictyos haerium* Chroococcus IChlarnydornonas Fra ilaria Eudorina* Clathroc stis* I Codonella Gyrosigma Elakatothrix Coelosphaerium* C tomonas* Gom honema Gleoc stis C lindros ermum Difflugia Melosira Micrasterias Cus idothrix Dinob on* Meridion* Mougeotia Dact lococco sis Euglena Navicula Pandorina* Euca sis Glenodinium* Nitzschia Pediastrum Gleoca sa Gonium Pleurosigma Protococcus Galucocystis Halteria LSt nulada Quadri ula Gloeothece Mallomonas* hanodiscus Scenedesmus Gom hos haeria Monas phanodiscus S haeroc stis Hydrocoleum Peridiniuin* rella Sphaerozosma Microcystis S nura*edra Spirogyra Merismo edia Trachelomonas Tabellaria* Staurastrum Nostoc Uro leno sis* Tetras ora Nodularia Vorticella Rotifera Westella Oscillatoria Anuraea Ulothrix Pseudanabaena As lanchna Volvox* S irulina Brachionus Xanthidium Rivularia* Conochilus Zygnema Xenococcus SchizoTi Euchlanis Euastrum Crenot Keratella Notholca Xenococcus Miscellaneous Pol arthra Acarina Rotifer Anguillula S nchaeta Miscellaneous - Bosmina Canthocam tus *Odor Palmella Anac stis Cyclops Phacus Golenkinia Daphnia Diaptomus x li R s Conclusions: Total Natural Unit Count: 0 per mL F Comments: Results are based on sample, as submitted to Northeast Laboratories, Inc. on: 8/08/2017. Large number of filamentous bacteria noted in sample. Approved by: Laboratory Director Northeast Laboratories,Inc. .129 Mill Street Berlin, CT 06037 wwwaielabset.corn Telephone: 860-828-9787 Toll Free(hi State)800-826-0105 (Out of State)800-654-1230 Fat: 860-829-1050 f CT Ca•f.#PFI-OJOa SPA Cerl.#CT=024 USDA Cer1.g097G P'DA Rcg.g086650a88 CT CSL#0000624 E; P CHAIN OF CUSTODY FORM ENVIROTECH LABS, INC. Client: Patrick Page 8 Jan Sebastian Dr., Unit 12 Proj. No. Project Name: 1780 Main St W Barnstable Sandwich, MA 02563 Address: 1780 Main St (508)888-6460/1-800-339-6460 W. barnstable,MA 02668 Sampler: FAX (508)888-6446 Phone#: 508 280 7243 -- lFax#: Lab ID# Date Time Comp Grab Sample location container Pres. Analysis Requested I Relinquish Date/Time Rece ed: Reliquished: Date/Time Received: �1 Relinqui ed: Date/Time Received: Relinquished: Date/Time Received: 3 � s Enviratech Laboratodes, 8 Jan Sebastian Dr Unit 12 Sandwich, MA 02563 Inc (508)888-6460 Fax (508)888-6446 September 12,2017 Patrick Page 1780 Main Street W. Barnstable, MA Dear Patrick, On August 7,2017,water samples were collected by Envirotech Laboratories at the ditch located at 1780 Main Street West Barnstable,MA. The ditch is an extension of the outfall pipe that is located on the property.The sample was collected at the bridge location of the ditch. The results are attached. There was found 1,800 ug/L of petroleum that most closely resembles 50w motor oil.Also,amounts of Lead,Copper,Chromium,Aluminum,Iron,and Manganese were detected. Sample for Algae Identification was taken at the ditch located at the large boulder.Genus Aphanocapsa and Nostoc belong to the Cyanobacteria group. Sincerely yours, onald J.S�ri President PH:508 88 6460 rsenviro@com cast,net i f i f ENVIR 0 TECH LA B ORA TORIES, INC MACERT NO.eMMA063 8 Jan Sebastian Drive Sandivich,MA 02563 (508)888-6460 1-800-3.39-6460 F,4V(508)888-6446 Wednesday,September 06,2017 Page, Patrick 178011ain St IF Barnstable,All ProjectName: Comments: Project Number: Collection Date: 08107117 Collection Time: 12:45 Sampled By: Saari/Envirotech Lab Order Number: WW-171705 Date Received: 08107117 �.'Sart p, Trine � .Sm»•'te Dates. .,� .«£ M.Z x =c J.,+t 4:F �y�{ '.�.4e.�t".¢ti�..,:�.�r2, �f+c.,'*'�'�'�p��K"'+'e rs,'z"'T: Y � � F4•• �.,�+.;a--,��i�,�� s�3 c.,g�-�..�,7�. "�a.,,�.r�COlfllftelltS�5 �7 r ' t t i.ti�.. S �: x,,.. " a .� yam;_ �"s6t2�y " ."a-n .; Parameters Units Test Results Reportable Lindis Date Analyzed Analyst Method Total Iron mg/L 33 0,01 08/10/17 MC EPA 200.7 Manganese mg/L 0.237 0.005 08/10/17 MC EPA 200.7 Aluminum mg/L 3.75 0.010 08/10/17 MC EPA 200.7 Barium mg/L 0.197 0.002 08/10/17 MC EPA 200.7 Chromium mg/L. 0.019 0.002 08/10/17 MC EPA 200.7 Nickel mg/L 0.009 0.005 08/10/17 MC EPA 200.7 Lead mg/L 0.037 0.006 08/10/17 MC EPA 200.7 Copper mg/L 0.024 0.003 08/10/17 MC EPA 200.7 Zinc mg/L 0.209 0.004 08/10/17 MC EPA 200.7 Petroleum Fingerprint' 1,800 08/18/17 RIA* • x BRL=below reporlabte limits i 'see anacle'd By: LX Ronal J. Saai Lab ratory Dtre for Page 1 of 1 ;; Page 2 of 3 R.I.Analytical Laboratories,Inc. Laboratory Report Envirotech Laboratories, Inc. Work Order#:1708-17187 Project Name: 1780 MAIN STREET, W.BARNSTABLE MA Sample Number: 001 Sample Description: WW-171705 DITCH a OUTFALL BRIDGE Sample Type: GRAB Sample Date/Time: 8/07/2017 @ 12:45 SAMPLE DET. DATE/TIME PARAMETER RESULTS LIMIT UNITS METHOD ANALYZED ANALYST TPH �7 TPH GC/F1D 1800 ]40 ug/I SW-846 8100M 8/18/2017 12:53 CCS Surrogate RANGE SW-84681OOM 8/18/2017 12:53 CCS 2-Fluorobiphenyl 53 40-140% SW-846 BLOOM 8/18/2017 12:53 CCS Extraction Date SW-846351OC 8/11/2017 9:55 JBW TPH Fingerprint=Chromatogram most closely resembles 50w motor oil. s e f S. r: r C CHAIN OF CUSTODY FORM ENVIROTECH LABS,INC. RI Analytica; 8 Jan Sebastian Dr Unit 12 M RI 015 PWS: Project Name: 1780 Main St, W Barnstable Sandwich,MA 02563 Address 41 Illinois Avenue (508)888-6460 Warwick,RI 02888 Sampler. R SaarUEnvirotech 1-800-339-6460 ahone# 401-737-8500 FAX(508)888-6446 Fax# 401-738-1970 Lab ID# Date Time, Comp Grab Station location DEP ID Container Pres. Sample pe Analysis requested WW-171705 08/07/17 1246 X Ditch Ig Outfall Bridge Glass HCl Petroleum Scan --------------- Relinauished: \�1 I DateMme, ! Race] Reiiauished: Datemme R 2 eve Nye Relinaulshed• j'I DatoMme Received: Relinquished; Ft M-e eco ved• S,s Pagel of 3 R.I. ANALYTICAL Specialists in Environmentel Services LABORATORY REPORT Envirotech Laboratories, Inc. Date Received: 8/9/2017 Attn: Mr. Ron Saari Date Reported: 8/18/2017 8 Jan Sebastian Drive P.O.Number Sandwich,MA 02563 Work Order#: 1708-17187 Project Name: 1780 MAIN STREET, W.BARNSTABLE MA Enclosed are the analytical results-and Chain of Custody for your project referenced above. The sample(s) were analyzed by our Warwick,RI laboratory unless noted otherwise. When applicable,indication of sample analysis at our Hudson,MA laboratory and/or subcontracted results are noted and subcontracted reports are enclosed in their entirety. All samples were analyzed within the established guidelines of US EPA approved methods with all requirements met, unless otherwise noted at the end of a given sample's analytical results or in a case narrative. The Detection Limit is defined as the lowest level that can be reliably achieved during routine laboratory conditions. i These results only pertain to the samples submitted for this Work Order#and this report shall not be reproduced except in its entirety. We certify that the following results are true and accurate to the best of our knowledge, If you have questions or-need further assistance,please-contact our Customer Service.Department. Approved by: Melissa A.Manamon QA/QC Officer b Laboratory Certification Numbers(as applicable to sample's origin state): Warwick RI*RI LA100033,MA M-RI015,CT PH-'0508,ME R100015,N142070,NY 11726 Hudson MA*M-MA1117,RI LA000319 K 41 Illinois Avenue,Warwick,RI 02888 www,rianalytical.com 131 Coolidge Street,Suite 105,Hudson MA01749 r Phone:401-737-8500 Fax:401-7,38-1970. Phone:978-568,0041 Fax:978-568-0078 s i, t; CHAIN OF CUSTODY FORM ENVIROTECH LABS,INC. Client: Patrick Page r 8 Jan Sebastian Dr.,Unit 12 Proj.No. Project Name: 1780 Main St W.Bamstable Sandwich,MA 02563 Address: 1780_MaimSt (508)888-646011-800-339-6460 W.barnstable,MA 02668 Sampler: qVV FAX(508)888-6446 Phone#: 508 280 7243 Fax#: Lab ID:; Date 7ime/Comp Grab I Sample location container Pres. Analysis Requested �' 1 g C; tN-c_e Petroleum Scan ' i metals I _ Relinquis *atem -1UJRe i ed: Reliquished: Dater lore Received: 1TRelinquishe e Received: Relinquished: DatelTime Received: II ENVIROTECHLABORATORIES, INC. MA CERT. NO.: M MA 063 8 Jan Sebastian Drive Sandwich,MA 02563 (,508)888-6460 1-800-339-6460 FAX(508)888-6446 Tuesday,September 12,2017 Page, Patrick 1780 t1,1ain St IY Barnstable,All , ProjeciName: 1780 Main St., W..-Barn, Comments: Project Number: NA Collection Date: 817117 Collection Time: 12:20 Sampled By: RS/Envirotech Lab Order Number: WW-171706 Date Received: 08107117 a�` �`' �San ple�ype'"''�'� 'k1"Sam'�leTinei�' �.S'�°` leDate,� � ���;�.,,,,���.� �� -•�- x w�: ��.�Y ��, �� - Parameters Units Test Results Reportable Limits Datertnat)Ized Analprr 4lerhod Algae Identification #/ml see attached NA 08/08/17 INortheast Lab i I f j 0 a { f ' I i' BRL=below reportabl `see attached j Rol ld J. Sa 1 Ldborato y irector Page 1 of 1 i f 0 Northeast Laboratories, Inc. .ANALYTICAL REPORT Page 1 of 1. Report To: ENVIROTECH LABORATORIES, INC. Attn: Ronald Saari, President EMAIL ADDRESSEE: rsenviro@comcast.net 8 Jan Sebastian Dr= Unit#12 Sandwich MA 02563 Report Date: 8/14/2017 Date Sampled: 8/07/2017 Laborato ID#: N1771079 Date Received: 8/08/2017 Envirotech's ED#: DW— 171706 Date Tested: 8/08/2017 Raw Water—SITE: 1780 Main St. West Barnstable MA, Ditch @ MICROSCOPIC EXAMINATION: Boulder ORGANISM #/ml ORGANISM #/ml ORGANISM #/ml ORGANISM #/ml Diatomaceae lChlorophyceae C ano h ceae Protozoa Am hora Actinastrum Anabaena* Actino h s Asterionella* Arthrodesmus Anabaeno sis Amoeba Am hi rora Ankistrodesmus A hanoca sa 1,900.. Arcella Cocinodiscus Chorella jAphanizomenon* Bursaria* C clotella* Closterium A hanothece Ceratium C mbella Coelastrum Aulosira ' Cercomonas Diatoma* Cosmarium Arthros ira Chilomonas Frustulia Dict os haerium* Chroococcus Chlam dorrionas Fra ilaria Eudorina* Clathroc stis* Codonella G rosi ma Elakatothrix Coelos haerium* C tomonas* Gom honema Gleoc stis C lindros ermurh Difflu is Melosira Micrasterias Gus idothrix Dinob on* Meridion* Mou eotia Dact lococco sis Eu Jena Navicula 15,000 Pandorina* Euca sis Glenodinium* Nitzschia Pediastrum Gleoca sa Gonium Pleurosi ma Protococcus Galucoc stis Haiteria Pinnularia Quadri ula Gloeothece Mallomonas* Ste hanodiscus Scenedesmus Gom hos haeria Monas Ste hanodiscus S haeroc stis H drocoleum Peridinium* Surirella S haerozosma Microc stis S nura* lBrachionus Spirogyra 3,900 Merismo edia Trachelomonas ia* Staurastrum Nostoc 960 Uro leno sis* Tetras ora Nodularia Vorticella Westella Oscillatoria Ulothrix 5,800 IPseudanabaena hna Volvox* S irulina Xanthidium Rivularia* us Z nema Xenococcus Schizom cetes s Euastrum Crenothrix Keratella Notholca Xenococcus Miscellaneous _ Pol arthra Acarina Rotifer An uillula S nchaeta Miscellaneous Bosmina Canthocam tus *Odor Producin Palmella Anac stis Cyclops Phacus Golenkinia Daphnia Dia tomus Conclusions: Total Natural Unit Count: 28,000 per mL k, Comments: Results are based on sample, as submitted to Northeast Laboratories, Inc. on: 8/08/2017 (rounded). . c Approved by: Laboratory Director Northeast Laboratories,Inc. 129 Mill Street Berlin,CT 06037 N«vw.nelabsct.com a Telephone: 860-828-9787 Toll Free(In State)800-826-0105 (Out of State) 800-654-1230 Fax: 860-829-1050 CT Cert.#PH-0404 EPA Cert.#CT-024 USDA Cert.#0976 FDA Reg.#086650488 CT CSL 90000624 F. CHAIN OF CUSTODY FORM ENVIROTECH LABS, INC. Client: Patrick Page 8 Jan Sebastian Dr.,Unit 12 Proj.No. Project Name: 1780 Main St W Barnstable Sandwich,MA 02563 Address: 1780 Main St (508)888-6460l1-800-339-6460 W.bamstable,MA 02668 Sampler. FAX(508)888-6446 Phone#: 508 280 7243 Fax#: Lab ID# Date Time Comp crab Sample location container Pres. Analysis Requested 77— G 6 i q ice° Algae ID (specifically cyanobacteria) Relinquish D im Jtl Rece' e : Reliquished: DatelTime Received: Relinquished: i DateTime Received: Relinquished: DateTime Received: I i ,J ENVIROTECH LABORATORIES, INC. MA CERT. NO.: M.-MA 063 8 Jan Sebastian Drive Swidwicb,NIA 02563 (508)888-6460 1-800-33 9-6460 FAX(508)888-6446 r FridaY,September 27, 2013 Page, Pnh•ick l780 114ah?S1 17"/3arnstable, Al Projec/Nante: 1780 Hwin St lY Bcnwslable Conunellis: Rain event in AM Project Number: Collection Date: 08127113 Collection Time: 12:05 Salnpled Bp: R Saari Lab Order Ntrnrber: WTV-132030 Date Received: 08127113 Sn»tple T}pe''_ Sample Trme Siurple Datc: � 2G Comments � DrScharge Prpe A h 2:05 08127/13 T,. 4m r 5, s,, �w - .W �-»-�u aranrelers Unite Tect Results`~ Reportable Limits Date Analyzed Analyst Alet/rod FEcoli ium mg/L 11.4 1.0 08/29/13 /PAH MC 200.7 ug/L 210 os/o4I13 RIA* MADEP ug/L None Detected oa/2s/13 RIA* MADEP /100 5,000i-volatile Compounds ug/L 15 RS EPA 1603 *' * 09/05/131 RIA* EPA 625 Dioxin pg/L None Detected 09/16/13 Summit EPA 16136 r • E L 4 }r E I ' C r D 1 4 A ItRL=Gelow reportable lr�ul see ollor/red 1 s Ro talrl J.7 t tri Laborat ii Director Page 2 of 2 R.I . ANALYTICAL Page I of 7 Specielists in Environmental Services , CERTIFICATE OF ANALYSIS Envirotech Laboratories, Inc. Date Received: 8/28/2013 Attn: . Mr. Ron Saari Date Reported: 9/6/2013 8 Jan Sebastian Drive P.O. #: Sandwich, MA 02563 Work Order#: 1308-18481 DESCRIPTION: PAGE, PATRICK Subject sample(s) has/have been analyzed by our Warwick,R.I. laboratory with the attached results. Reference: All parameters were analyzed by U.S. EPA approved methodologies. The specific methodologies are listed in the methods column of the Certificate of Analysis. Data qualifiers (if present) are explained in full at the end of a given sample's analytical results. The Certificate of Analysis shall not be reproduced except in full, without written approval of R.I. Analytical. Results relate only to samples submitted to the laboratory for analysis. Test results are not blank corrected. Certification#: RI-033, MA-RI015, CT-PH-0508, ME-RIO15 NH-253700 A& B, USDA 5-41844 F If you have any questions regarding this work, or if we may be of further assistance,please contact 1 our customer service deimilment. Approved b ; r Sharon Baker i MIS/Data Reporting enc: Chain of Custody z V 1 i t 41 Illinois Avenue,Warwick,RI 02888 131 Coolidge Street,Suite 105,Hudson,MA 01749 Phone:401.737.8500 Fax:401.738.1970 wwwAanalytical.com Phone:978.568.0041 Fax:978.568.0078 I a Page 2 of 7 R.I. Analytical Laboratories, Inc. CERTIFICATE OF ANALYSIS Envirotech Laboratories;Inc. Date Received: 8/28/2013 Work Order#: 1308-18481 Sample# 001 SAMPLE DESCRIPTION: WW-132030 1780 MAIN ST. W.BARNSTABLE SAMPLE TYPE: GRAB SAMPLE DATE/TIME: 8/27/2013 @ 12:05 SAMPLE DET. DATE/TIIYIE PARAMETER RESULTS LIMIT UNITS METHOD ANALYZED ANALYST TOC 15 5 mg/l SM-5310B 8/29/2013 12:45 EC IPH TPH GC/FID 850 100 ug/l SW846 8100M 9/4/2013 19:37 THP Surrogate RANGE SW-846 8100 9/4/2013 19:37 Tf- 2-Fluorobiphenyl 86 40-140% SW-846 8100 9/4/2013 19:37 THP Extraction date Extracted SW8463510 9/1/2013 10:15 RJL PCB Aroclor-1016 <0.5 0.5 ug/l EPA 608 9/4/2013 10:10 JEB Aroclor-1221 <0,5 0.5 ug/l EPA 608 9/4/2013 10:10 JEB Aroclor-1232 <0.5 0.5 ug/I EPA 608 9/4/2013 10:10 JEB Aroclor-1242 <0.5 0.5 ug/l EPA 608 9/4/2013 10:10 JEB Aroclor-1248 <0.5 0.5 ug/l EPA 608 9/4/2013 10:10 JEB Aroclor-1254 <0.5 0.5 ug/l EPA 608 9/4/2013 10:10 JEB Aroclor-1260 <0.5 0.5 ug/l EPA 608 9/4/2013 10:10 JEB Surrogate RANGE 9/4/2013 10:10 JEB Tetrachloro-m-aylene(TCMX) 70 30-150% EPA 608 9/4/2013 10:10 JEB Decachlorobiphenyl 30 30-150% EPA 608 9/4/2013 10:10 JEB Extraction date Extracted EPA 608 9/1/2013 10:15 RD., VPH Unadjusted C5-C8 Aliphatics(FID) <150 150 ug/l MADEP 8/29/2013 11:38 *ET Unadjusted C9-C12 Aliphaties(FID) <150 150 ug/1 MADEP 8/29/2013 11:38 *ET Methyl-tert-butylethcr <1.5 1.5 ug/l MADEP 8/29/2013 11:38 *ET Benzene <1,5 1.5 ug/I MADEP 8/29/2013 11:38 Toluene <5.0 5.0 ug/l MADEP 8/29/2013 11:38 *ET p Ethylbenzene <5.0 5.0 ug/l MADEP 8/29/2013 11:38 *ET m,p-Xylenc <10.0 10.0 ug/l MADEP 8/2.9/2013 11:38 *ET o-Xylene <5.0 5.0 ug/l MADEP 8/29/2013 11:38 *ET Naphthalene <5.0 5.0 ug/1 MADEP 8/29/2013 11:38 *ET Adjusted C5-C8 Aliphatics(FID) <150 150 ug/l MADEP 8/29/2013 11:38 *ET 3 Adjusted C9-C12 Aliphatics(FID) <150 150 ug/1 MADEP 8/29/2013 11:38 *ET-. .. C Momatics(PID) <100 100 ug/1 MADEP. 8/29/2013 11:38 *ET Surrogate te RANGE 8/29/2013 1138 *ET 2,5-Dibromotoluene(PID) 100 70-130% MADEP 8/29/2013 11:38 *ET 2,5-Dibrontotoluene(F1D) 92 70-130% MADEP 8/29/2013 11:38 *ET EPH/PAH . C9-C18 Aliphatics <100 100 ug/1 MADEP 9/4/2013 16:32 THP C19-C36 Aliphatics 210 100 ug/1 MADEP 9/4/2013 16:32 THP Cl l-C22 Aromatics <100 100 ug/l MADEP 9/4/2013 16:32 THP TARGET PAH ANALYTES 9/4/2013 16:32 THP Page 3 of 7 R.I. Analytical Laboratories, Inc. CERTIFICATE OFANALYSIS Envirotech Laboratories Llc. Date Received: 8/28/2613 Work Order#: 1308-18481 Sample# 001 SAMPLE DESCRIPTION: WW-132030 1780 MAIN ST. W. BARNSTABLE SANIPLE TYPE: GRAB SAMPLE DATE/TIME: 8/27/2013 @ 12:05 SAMPLE DET. DATE/TIME PARAMETER RESULTS LIMIT UNITS METHOD ANALYZED ANALYST Naphthalene <5 5 ug/l MADEP 9/4/2013 16:32 1'14I' 2-Methylnaphthalene <5 5 ug/I MADEP 9/4/2013 16:32 THY Acenaphthylene <5 5 ug/l MADEP 9/4/2013 16:32 THP Acenaphtheue <5 5 ug/l MADEP 9/4/201.3 16:32 THP Fluorene <5 5 ug/l MADEP 9/4/2013 16:32 THP Phenanthrene <5 5 ug/l MADEP 9/4/2U13 1632 THP Anihracene <5 4-Ar�r41' gE4.11914 14.32 TIIP Fluoranthene <5 5 ug/1 MADEP 9/4/2013 16:32 THP Pyrene <5 5 ug/l MADEP 9/4/2013 16:32 THP Bcnzo(a)amlhracenc <5 5 ug/l MADEP 9/4/2013 16:32 THP Chrysene <5 5 ug/1 MADEP 9/4/2013 16:32 THP Benzo(b)fluorantliene <5 5 ug/l MADEP 9/4/2013 16:32 THP Benzo(k)fluoranthene <5 5' ug/l MADEP 9/4/2013 16:32 THP Benzo(a)pyrene <5 5 ug/l MADEP 9/4/2013 16:32 THP Jndcno(1,2;3-cd)pyrenc <5 5 ug/i MADEP 9/4/2013 16:32 THP Di ben•zo(a,h)amthracene <5 5 , ug/l MADEP 9/4/2013 16:32 THP Benzo(g,h,i)perylene <5 5 uM A4ADEP 9/4/2013 16:32 THP Extraction Surrogates RANGE 9/4/2013 16:32 THP f 5-alpha-Androstane 87 40-140% MADEP 9/4/2013 16:32 THP Ortho-terphenyl 79 40-140% MADEP 9/4/2013 16:32 THP Fractionation Surrogates RANGE 9/4/2013 16:32 THP 2-Fluorobiphenyl 78 40-140% MADEP 9/4/2013 16:32 THP } 2-Bromonaphthalene 63 40-140% MADEP 9/4/2013 16:32 THP Extraction date Extracted MADEP 9/3/2013 16:37 MMM s Semi-Volatile Organic Compounds Acenaphthene <5. 5 ug/l EPA 625 9/5/2013 15:11 KF Acenaphthylene <5 5 ug/l EPA625 9/5/2013 I5:11 KF Anthracene <5 5 ug/l EPA 625 9/5/2013 15:11 KF Benzidine <$ 5 ug/I EPA 625 9/5/2013 15:11 KF Benzo(a)anthracene <5 5 ug/l EPA 625 9/5/2013 15:11 KF Benzo(b)fluoranthene <5 5 ug/l EPA 625. 9/5/2013 15:11 KF Benzo(k)fluoranthene <5 5 ug/l EPA625 9/5/2013 15:11 KF Benzo(g,h,i)perylene <5 5 ug/l EPA 625 9/5/2013 15:11 KF Benzo(a)pyrene <5 5 ug/l EPA625 9/5/2013 15:11 KF 1 bis(2-Chloroethyl)Ether <5 5 ug/1 EPA 625 9/5/2013 15:11 KF ! � Bis(2-Chloroethoxy)mcthane <5 5 ug/l EPA625 9/5/2013 15:11 KF Bis(2-chloroisoprop),l)ether <5 5 ug/l EPA625 9/5/2013 15:11 KP Bis(2-ethylhexyl)phthalate <5 5 ug/l EPA625 9/5/2013 15:11 KF l 4-13romophcnyl phenyl ether <5 5 ug/l EPA625 9/5/2013 15:11 KF it Butylbenzyl phthalate <5 5 ug/) EPA625 9/5/2013 15:11 KF 2-Chioronaptlialene <5 5 ug/l EPA 625 9/5/2013 15:11 KF 5 I Page 4 of 7 R.I. Analytical Laboratories, Inc. CERTIFICATE OF ANALYSIS' Envirotech Laboratories, hie. Date Received: 8/28/2013 Work Order#: 1308-18481 Sample# 001 SAMPLE DESCRIPTION: WW-132030 1780 MAIN ST. W.BARNSTABLE SAMPLE TYPE: GRAB SAMPLE DATE/TIME: 8/27/2013 a, 12:05 SAMPLE DET. DATE/TIll4E PARAMETER RESULTS LIMIT UNITS METHOD ANALYZED ANALYST 4-Chlorophenyl phenyl ether <5 5 ug/l EPA 625 9/5/2013 15:11 KF Chrysene <5 5 ug/l EPA 625 9/5/2013 15:11 KF Dibenzo(a,h)anthracene <5 5 ug/1 EPA 625 9/5/2013 15:11 KF Di-n-butyl phthalate 15 5 ug/1 EPA 625 9/5/2013 15:11 KF 1,2-Dichlorobenzene <5 5 ug/l EPA 625 9/5/2013 15:11 KF 1,3-Dichlorobenzene <5 5 ug/l EPA 625 9/5/2013 15:11 KF 3,Y-Dichlorobenzidine <5 5 ug/l g/ EPA 625 9/5/2013 15:11 KF Diethyl phthalate <5 5 ug/l EPA 625 9/5/2013 15:1 I KF Dunethyl phtlialate <5 5 ug/l EPA 625 9/5/2013 15:11 KF 2,4-Dinitrotoluene <5 5 ug/l EPA 625 9/5/2013 15:11 KF 2,6-Dinitrotoluene <5 5. ug/l EPA 625 9/5/2013 15:11 KF Di-n-octyl phthalate <5 5 ug/l EPA 625 9/5/2013 15:11 KF 1,2-Diphenylhydra7ine <5 5 ug/l EPA 625 9/5/2013 15:11 KF Fluoranthene <5 5 ug/l EPA 625 9/5/2013 15:11 KF Fluorene <5 5 ug/1 EPA 625 9/5/2013 15:11 KF Hexachlorobenzene <5 5 ug/l EPA 625 9/5/2013 15:11 KF Hexachlorobutadiene <5 5 118/1 EPA 625 9/5/2013 15:11 KF Hexachlorocycl open todiene <5 5 no EPA 625 9/5/2013 15:11 KF . Hexachloroethane <5 5 ug/l EPA 625 9/5/2013 15:11 KF Indeno(1,2,3-ed)pyrene <5 S ug/1 EPA 625 9/5/2013 15:11 KF Isophorone <5. 5 ugA EPA 625 9/5/2013 15:11 KF Naphthalene <5 5 ug/1 EPA 625 9/5/2013 15:11 KF Nitrobenzene <5 S ug/l EPA 625 9/5/2013 I5:11 KF N-nitrosodimet hylamino <5 5 ug/1 EPA 625 9/5l2013 I5;11 KP N-nitrosodiphenylamine <5 5 ug/l EPA 625 . 9/5/2013 15:11 Kh N-nilrosodi-n-propylamine <5 5 ug/l EPA 625 9/5/2013 I5:11 KF Phenanthrene € <5 5 ug/l EPA 625 .9/5/2013 15:11 KF i Pyrene <5 5 ug/l EPA 625 9/5/2013 15:11 KF 1,2,4-Trichlorobenzene <5 5 ug/1 EPA 625 9/5/2013 15:11 KF 4-Cliloro-3-methylphenol <5 5 ug/1 EPA 625 9/5/2013 15:11 KF 2-Chlorophenol <5 5 ug/l EPA 625 9/5/2013 '15:11 KF I 2,4-Dichlorophenol <5 5 ug/1 EPA 625 9/5/2013 15:11 KF (: 2,4-Dimethylphehol <5 5 ug/1 EPA 625 9/5/2013 15:11 KF 2-Methyl-4,6-dinitrophenol <5 5 ug/l EPA 625 9/5/2013 15:11 KF. 2,4-Dinitrophenol <5 5 ug/l EPA 625 9/5/2013 15:11 2-Nitrophenol <5 5 ug/1 EPA 625 9/5/2013 15:11 KF 4.Nitrophenol <5 5 ug/1 EPA 625 .9/5/2013 15:11 ICI'. f Pentachlorophenol <5 5 ug/1 EPA 625 9/5/2013 15:11 KF - 4 Phenol <5 r' 5 ugn EPA 625 9/5/2013 15:11 KF . 2,4,6-1'richlorophenol <5 5 ug/1 EPA 625 9/5/2013 15:11 KF Surrogates RANGE EPA 625 9/5/2013 15:11 KF - r> Page 5 of 7 R.I. Analytical Laboratories, Inc. CERTIFICATE OF ANALYSIS Envirotecll Laboratories, Ine. Date Received: 8/28/2613 Work Order#: 1308-18481 Satliple# 001 SAMPLE DESCRIPTION: WW-132030 1780 MAIN ST'. W.BARNSTABLE SAATPLE TYPE: GRAB SAMPLE DATE/TIME: 8/27/2013 @ 12:05 SAMPLE DET. DATE/TIME PARAMETER RESULTS LIATIT UNITS METHOD ANALYZED ANALYST Phenol-d5 29 15-110% EPA 625 9/5/2013 15:1 J KF 2-Fluorophenol 36 15-110% EPA 625 9/5/2013 15:11 KF 2,4,6-Tribromoplienol 91 15-110% EPA 625 9/5/2013 15:11 KF Nitrobenzene-d5 89 30-130%. EPA 625 9/5/2013 15:11 KF 2-Fluorobiphenyl 69 30-130% EPA 625 9/5/2013 ISAI KF P-Terphenyl-dI4 85 30-130% EPA 625 9/5/2013 15:11 KF Volatile Organic Compounds Benzene <l 1 ug/l SW-846 8260B 8/31/2013 15:29 KAC Bromobenzene <1 1 ug/l SW-846 8260B 8/31/2013 15:29 KAC Bromochloromethane <1 1 ug/J SW-846 8260B 8/31/2013 15:29 KAC Bromodichloromethane <1 I ug/l SW-846 8260B 8/31/2013 15:29 KAC Bromofonn <1 ] ug/1 SW-8468260B 8/31/2013 15:29 KAC Bromomethane <5 5 ug/l SW-846 8260B 9/31/2013 15:29 KAC n-Butylbenzene <1 I ug/l SW-846 8260B 8/31/2013 15:29 KAC Sec-butylbenzene <1 I ug/l SW-846 8260B 813 t/2013 15:29 KAC tert-Butyl benzene <1 I ug/l SNV-846 8260B 8/31/2.013 15:29 KAC Carbon Tetrachloride <1 I ug/1 -SW-846 8260B 8/31/2013 15:29 KAC Chlorobenzene <1 1 ug/l SW-846 8260B 3/31/2013 15:29 KAC Chloroethane <5 5 ugh SW-846 8260B 8/31/2013 15:29 KAC Chlorofonn <1 I ug/1 SW-846 8260B 8/31/2013 15:29 KAC r Chloromefhane <5 5 ug/l SW-846 8260B 8/31/2013 15:29 KAC 2-Chlorotoluene <1 I ug/I SW-846 8260B 8/31/2013 15:29 KAC 4-Chlorotoluene <1 I ug/l SW-846 8260B 8/31/2013 15:29 KAC Dibromochloromethane <1 1 ug/1 SW-846 8260B 8/31/2013 15:29 KAC 1,2-Dibromo-3-Chloropropa»c <2 2 ug/1 SW-8.46 8260B 8/31/2013 15:29 KAC r l,2-Dibromoethmlc(EDB) <1. I ug/l SW-846 8260E 8/31/2013 15:29 KAC w Dibromomethanc <2 2 ug/1 SW-8468260B 8/31/2013 15:29 KAC 1,2-Dichlorobenzene <1 I ug/1 SW-8468260B 8/31/2013 15:29 KAC j 1,3-Dichlorobenzene <1 1 ug/l SW-8468260B 8/31/2013 15:29 KAC 1,4-Dichlorobenzene <l. 1 ug/l SW-846 8260B 8/31/2013 15:29 KAC R DichlorodiJluoromethane <5 5 ug/1 SW-846 8260B 8/31/2013 15:29 KAC 4 1,1-Dichloroethane <1 1 ug/l SW-846 8260B 8/31/2013 15:29 KAC 1,2-Dichloroethane <1 1 ug/l SW-846 8260B 8/31/2013 15:29 KAC ],I-Dichloroethene <I I ug/1 SW-846 8260B 8/31/2013 15:29 KAC cis-1,2-Dichloroethene <1 I ug/l SW-846 8260B 8/31/2013 15:29 KAC trans-l,2-Dichloroeth,lene <2 2 u��1 SW-846 3260E 8/31/2013 15:29 KAC 1,2-Dichloropropane <1 1 ug4 SW-846 8260B 8/31/2013 15:29 KAC 1,3-Dichloropropane <I 1 ug l SW-846 8260B 8/31/2013 15:29 KAC 2,2-Dichloropropane <1 I ug/1 SW-846 8260B 8/31/2013 15:29 KAC 1,1-Dichloropropene <1 1 ug/1 SW-8468260B 8/31/2013 15:29 KAC Ethylbenzene <l 1 ug/l SW-846 8260B 8/31/2013 15:29 KAC k I Page 6 of 7 R.I. Analytical Laboratories, Inc. CERTIFICATE OF ANALYSIS Envirotech Laboratories, hie. Date Received: 8/28/2613 Work Order#: 1308-18481 Sample# 001 SAMPLE DESCRIPTION: WW-132030 1780 MAIN ST. W.BARNSTABLE SAMPLE TYPE: GRAB SAMPLE DATE/TIME: 8/27/2013 @ 12:05 SAMPLE DET. DATE/TIME PARAMETER RESULTS LIMIT UNITS METHOD ANALYZED ANALYST 1-lesachlorobuladieue <I 1 ug/l SW-8468260B 8/31/2013 15:29 KAC Lsopropylbenzcne <1 I u8/1 SW-8468260B 8/31/2013 15:29 1CAC p-lsopropyltoluene <1 I ug/I SW-846 8260B 8/31/2013 15:29 KAC Methylene Chloride <5 5 ug/l SW-846 8260B 8/31/2013 15:29 KAC Naphthalene <1 1 ug/1 SW-846 8260B 8/31/2013 15:29 KAC n-Propylbenzene <1 I ug/ l SW-846 8260B 8/31l2013 15.29 KAC � Slvrei e <I I 1,1,1,2-Tetrachloroethane <1 1 ug/l SW-8468260B 8/31/2013 15:29 KAC 1,1,2,2-Tetrachloroethane <1 1 ug/1 SW-846 8260B 8/31/2013 15:29 KAC Tetrachloroethene <1 I ug/1 SW-846 8260B 8/31/2013 15:29 KAC Toluene <1 ] ug/l SW-846 8260B 8/31/2013 15:29 KAC 1,2,3-Trichlorobenzene <1 1 ug/l SW-846 8260B 8/31/2013 15:29 KAC 1,2,4-Trichlorobenzene <1 1 ug/l SW-846 8260E 8/31/2013 15:29 KAC 1,1,1-Trichloroethane <1 1 ug/1 SW-8468260B 8/31/2013 , 15:29 KAC 1,1,2-Trichlorocthane <1 1 ug/l SW-8468260B 8/31/2013 15:29 KAC Trichloroethene <1 1 ug/l SW-846 8260B 8/31/2013 15:29 KAC rrichloro[luoromethane <I I ug/1 SW-846 8260B 8/31/2013 15:29 KAC i 1,2,3-1'ricliloropropane <2 2 ug/l SW-846 8260E 9/31/2013 15:29 KAC j 1,2,4-Trimediy1benzene <] 1 ug/1 SW-846 8260B 8/31/2013 15:29 KAC 1,3,5-Trimelhylbenzene <1 1 ug/l SW-846 8260B 8/31/2013 15:29 KAC e Vinyl Chloride <1 1 ug/1 SW-846 8260B 8/31/2013 15:29 KAC o-Xylene <1 1 ug/l SW-846 8260B 3/31/2013 15:29 KAC m,p-Xylene <1 1 ug/l SW-846 8260B 8/31/2013 15:29 KAC MTBE <2 2 ug/l SW-846 8260E 8/31/2013 15:29 KAC Acetone <10 10 ug/l SW-846 8260B 8/31/2013 15:29 KAC Surrogates RANGE SW-846 8260B 8/31/2013 15:29 KAC Dibromofluoromethane 107 86-118% SW-846 8260B 8/31/2013 15:29 KAC Toluene-d8 97 88-110% SW-846 8260B 8/31/2013 15:29 KAC 4-Bromofluorobenzene 94 86-115% SW-846 8260B 8/31/2013 15:29 KAC a 1,2 Dichloroethanc-d4 97 80-120% SW-846 8260B 8/31/2013 15:29 KAC i Total Metals Mercury <0.0005 0.0005 mg/1 EPA 245.1 8/30/2013 9:31 YJC w Mercury Digestion EPA 245.1 8/30/2013 9:12 JL r� r€ u k Page 7 of 7 R.I. Analytical Laboratories,Inc. CERTIF'ICArE OF'ANALYSIS Envirotech Laboratories,Inc. Date Received: 8/28/2013 Work Ordet•#: 1308-18481 VPH method was analyzed by a subcontracted laboratory,ESS Laboratory. A.II QA/QC procedures required by the EPH Method were followed. All Performance/Acceptance Standards for the required QA/QC procedures were achieved or othei"vise stated. No significant modifications were made to the EPH Method. i E a 1 k t u s c: ENVIR O TECH LABORA TORIES, INC. MA CERT. NO.: lid-MA 063 8 Jan Sebastian Drive Sandwich,MA 02563. (508)888-6460 1-800-339-6460 FAX(508)888-6446 Wednesday,September 18,1013 Page, Patrick 1780 Alain St 1•J�13arnslahle, A,1 ProjectName: 1780 Main Streel Continents: Project Number. Collection Date: 08101113 Collection Time: NA Sampled By: P. Page Lab Order Number: WTv-131905 Dale Received: 08115113 Sample Type: Spniple Tirue Sntirp/ Dnl ee Coiinterr/s Outfall. A 08/09/13 Parameters Units Test Results Reportable Limits Dare Analyzed Analyst A4erhod Petroleum Fingerprint" See Attached 08/23/13 RIA' i i t r BRL=below reportable limits *see attached J P,611ald J. Iri Laborato Director Page 1 of 1 f Page 2 of 2 R.I.Analytical Laboratories; Inc. CERTIFICATE OFANALYSIS III Enviroteeb Laboratories,Inc. Date Received: 8/20/2013 Work Order 4: 1308-1.7844 Sample# 001 SAMPLE DESCRIPTION: WW-131905 OUTFALL SAMPLE TYPE: GRAD SAMPLE DATE/TIME: 8/01/2013 SAMPLE DET. DATE/TIME PARAMETER RESULTS LIMIT UNITS METHOD ANALYZED ANALYST TPH TPH GUM 450 - 110 ug/1 SW846 8100M 8/2YNN 16:45 TRIP Surrogate RANG13 SW-846 8100 8/23/20.13 16:45 THP 2-Fluorobiphenyl 66 40-140% SW-846 8100 8/23/2013 16:45 THP Extraction date Extracted SW846 3510 8/22/2013 21:00 IviN1M The sample was received at the laboratory outside of the recommended hold time for the TPH analysis. Fingerprint:Chromatogram best matches weathered biodiesel fuel,possibly from vegetable oil sources. i e 6 M, k CHAIN OF CUSTODY FORM ENVIIaOTECIi LABS, INC. RI Analytical 8 Jan Sebastian Dr Unit 12 M Ri 015 PWS: Project Name: Sandwich,MA 02563 Address 41 Illinois Avenue (508)888-6460 Warwick, RI 02888 Sampler: P. Page 1-800-339-6460 Phone# 401-737-8500 FAX(508)808-6446 Fax# 401-738-1970 Lab ID# Date Time Comp Grab Station location DEP ID Container Pres. Sample p type Analysis requested WW-131905 0801113. NA X Outfall Glass H2SO4 Drinking Petroleum Fingerprint ------------------ Reifn uiahed: DateMrne Received: Reliauished: DateMme Received: In u hed Gm` Rceived• Relinquished: bate/time ' Received: �J Lam' �i... �/Ww• CHAIN OF CUSTODY FORM ENVIROTECH LABS, INC. Client: C ices 8 Jan Sebastian Dr., Unit 12 Proj. No. Project Name: + U , Sandwich, MA 02563 Address: o d sPark (508)888-6460/1-800-3 6460 Sampler: el N e A 02031 FAX(50B)888-6446 Phone#: ; Fax#: Lab ID# Date_„ - Time Comp Grab _ Sample location container Pres, Qv_13iR6� g�� l3 Analysis Requested I Relinquished: DatelT'me Receive Reliquished: DateTme /5 )3 - Received: Relinquished: DafeTime � — Received: Relinquished: DateTme Received: Town of Barnstable �oF114e t � Town Council 367 Main Street,Village of Hyannis,MA 02601 508-862-4738 • 508-862-4770 g® 4`uv\ BARNSTABLE, * E-mail: council@town.barnstable.ma.us W bitim� MASS. www.town.barnstable.ma.us i639• 1� ArEpMp�a� Councillors: October 12, 2016 Jessica Rapp Grassetti President Dr. Paul Canniff, DMD Precinct 7 Eric R.Steinhilber Chair, Barnstable Board of Health Vice President 200 Main Street Precinct 2 Hyannis, MA 02601 John G.Flores Dear Dr. Canniff. Precinct 1 Paul Hebert Precinct 3 q The Barns requested p Barnstable Town Council has re ted that the enclosed report from Envirotech Frederick Chirigotis Laboratories , Inc. dated September 22, 2016 be sent to the Board of Health. It was presented by Precinct 4 Mr. Patrick Page to the Town Council at its October 6, 2016 meeting. James H.Crocker Jr. Precinct 5 Thank you for your consideration. William Crocker Jr. Precinct 6 Sl eerel , Dr.Debra S.Dagwan Precinct 8 nthia Love 1 James M.Tinsley Administrator, Precinct 9 Barnstable Town Council Sara Cushing Precinct 10 Enc. Philip Wallace Precinct 11 John T.Norman Precinct 12 Jennifer L.Cullum Precinct 13 Admnustrator: Cynthia A.Lovell Administrative Ad 9T&tiT 130 Assistant: Kelly Crahan 232' 2 f� yi. Hamblin dated pebruary 21, 1927 recorded with Barnstable Deeds Book 440 page 33'.-Said promisee are conveyed subject to a mortgage for $1000000 held by the�{�ellflsat Savings Bank and takes for current year. Witness my hand and gaal�thia s_ ixth day ,o September 1997 iota H. King (TA) pommon:jo,m alt .o Maeeaohusattah Suffolk ea. Boston, Sp 1987 Thou personally appeared the above-named John He King and sokaowledged the foregoing instrument to be his free act and deed, before me j J Ralph WellMan Justice of the Paaoe yj commission expires 1%y 8 1930 Barnstable, no. Received September 13, 19E7 and is recorded. IO'oW all-Men by these preaente, That I Victor-beeman,-being mevried,- and of Barnstable, in the County of Barnstable and Commonwealth of Maesaohusette, for myself, my heirs, exeoutora, administrators and V� aeaigns, in consideration of the gum of one Dollar paid by the Common- wealth of Massachusetts, through its Department of public Works, astob- jIlahed under the provisions of Chapter 16 of the General Laws and acts in amendment thereof and in addition thereto, the receipt whereof Is n hereby acknowledged, do hereby grant unto the acid Commonwealth of Massachusetts and its assigns forever the right .to discharge into an • Jexisting ditch upon my land, situated on the north-westerly side of the proposed State highway in the town of Barnstable, water from a �j drainage system to be oonatruated within the limits of eaid highway between about stations 179.60 and 1934,00, to carry water away from said highway and over and through my land above described, for public convenience and for the proper construction and ogre of said highway, and to enter upon my land at-any time for the purpose of constructing, repairing and maintaining said drainage system and an outlet bhereof, under the provisions of Section 4, Chapter 83 of the General jaws and note in amendment thereof and in addition thereto; the proposed looation �.!J of eaid drainage system and outlet being as shown on plan drawn by J Ar W. Dean, Chief gnginear, dated Aug. 31, 19U, and entitled: 01The Commonwealth of Massachusetts, Department of public Works. Town of Barnstable Plan of proposed Drainage System and outlet About Sta. 179t80 on the proposed State Highway, Scale: 40 feat to the inch e certified copy of which is,to be recorded herewith. And for the oon- sidoration aforesaid, I do ocoept said gum in full payment of said easement and for myself and my hairs, executors, administratore and • assigns do hereby release the eaid Commonwealth Of Massachusetts and herearte all other persona from all damages. that,have arisen or may^ar ao ty reason of the construction of eaid.draivage system and the carrying Of o , T , •_ . . •. .. 233 water away from the said highway and over or through any of the land here- • inbefore desoribed. And I do hereby, for myself and my heirs, executors, ; administrators and assigns covenant with the grantee and its assigns that I am lawfully seined in fee simple of the granted premises, and that I have good right to grant the within described easement. And, I, acpemia Leeman, wife of said grantor, release to said grantee all rights of curtsey, dower and homestead and other interests therein. In Witne88 Whereof, we bareunto set our hands and goals this let day of September in the year nineteen hundred and twenty-seven- victor Leeman (13) Eapemia Leeman The Commonwealth of gaseachoo tte Barnstable as. Sept 1- 1927, Then personally appeared the above-named Victor Leeman and aoknowl.edged the foregoing instrument to be his free act and deed. Before me, W. Nowell Wade Justioe of the Peace. W Commiseion Expires may 4- 1928 Barnstable, Be. Received September 13', 1927 and is reoorded. 2pnox all Lien by these Presents, that Y John Loki. Doing married, and of--- -- Barnstable, in the County of Barnstable and Commonwealth of M84achuaette, for myself my heirs, executors, administrators and assigns, in ooneid- • oration of the snm of One MUM paid by the Commomwealth of Liaasachu- setts, through its Department of Public Worka; eatabliehed undei the ��provieiong of chapter 16 of the General Laws and note 132 amendment 1 ry thereof and in addition thereto, the reoeipt whereof in hereby so)mowl- edged, do hereby grant unto the said Commonwealth of Masachueette and its assigns forever.the right to discharge into an existing ditch upon jmy land, situated on,the north-weeterly aide of the proposed State highway in the town of Barnstable, water from a drainage system to be ' oonstruote4 within the limits of said highway between about stations 179e80 and 193f00. to oarry water away from said highway and over and \f `� through my land above described, for public convenience and for the proper construction and care of said highway, and to enter upon my land at say time for the purpose of constructing,.repairing and maintaining eaid drainage system and an outlet thereof, under the provisions of Section 4, Chapter 83 of the General jAwe and note in amendment thereof =4 is addition thereto; the proposed location Of 6414 drainage system ' and outlet being an shown on plan drawn by A. W. Dean, 0410f Engineer, dated Aug. 31, 1927, and entitled: "The commonwealth of NAaaachusette. . Department of Public Wor):a. Sown of Barnstable plan of proposed Drainage System and Outlet about Sta. 179t80 on the propose4 State Highway. Scaler 40 feet to the ingh " a certified copy of which is to be recorded here- with. And for tha oonaiderstion aforesaid, I do accept amid sum in fu11 L • I 10 t34 payment of said easement and for myself and my heirs, executors, admin- ietratore and assigns do hereby release the said Commonwealth of Haaaa- • ohusette and all other persona from all damages that have arisen or may hereafter arise by reason of the construction of said drainage system and the carrying of water away from said highway and over or through any of the land hereinbefore described. And I do hereby, for myself and my heirs, executors, administrators and assigns covenant with the grantee and its assigns that I am lawfully seised in tee simple of the granted premises, and that I have good right to grant the within described easement. And, I, Johnna $ski wife of said grantor, release to said grantee all rights of curtsey, dower and homestead and other intereata therein. In Witness Whereof, we hereunto set our hands and seals this let day of Sept in the year nineteen hundre4 and twenty-seven. John Maki. (KS) Johnny Haki c�•�a) The Commonwealth of ]4assa0husetts Barnstable us. Sept 1- 19g7, Then personally appeared the above-named John Uaki and acknowledged the foregoing instrument to be his free act and deed. Before me, W. Newell Wads Juetioe of the Peace. My Commission Expires May 4- 1928 Barnstable, ea. Reoeived September 13, 1927 and is reoorded. y - X, Jessie-G+-B000aokof Boaton, Suffolk County, being unmarried, for ooneideration paid, grant to Killian P. Butterfield of 177 St. Botolph St Boston Uaae. with %uitolaim covenants the land in Eastham in Barnstable County itaeeaohueetto at North Eastham bounded V and described as follows:- On the north by my other land 318 feet; on 4,th* east by my other land.293 feet; on the south by land of the heirs 'i of Isaiah H Horton 321 feet and on the west by the State Highway B50 feet and containing an area of 0ne'andl99/100 acres be the•eame more p or leas, all as shown on a "Plan of 1,ana in Eastham scalee.100 :root to an inch from the office of A. L. Sparrow So+ r_ sans Aug. 1927" to be ' filed herewith, to whloh reference may be made,�granted premises are a part of the land conveyed to me by deed of Oraog•w. Doyle, Trustee, dated October 1, 1918 and recorded with Barnet#b(le County Deeds in Book 365 page 115. Witness my hand and seal.-hie twelfth day of September 1987. Jessie G• Booaoak (YiS) , Commonwealth of Massachusetta Barnstable as. September 12, 1927• Then personally appeared the above- named Jessie G. B00000k and acknowledged the foregoing inetxuwent to be her free act and deed, before me John H. Paine Justice of the peace My oommieaion expires Oct. 23 1930. THE COMMONWEALTH OF MABekACHU9ETT8 vzpAraTMFNr OF'PUBLIC W04116 TOWN. OF'-BARNSTABLE " R=Z Of Phoposed DrnirZotge sum.arLd Outlet ABOUT STA.179+eO ON THE: P20POSED STATE H01WAY • J�tE:4D FLCt"t0 TTi t►r!i AUI9.31,WZ7. /c'�//1 VICT02 LEEMAN i t IDI{ > * poi ►1p� `, �+RPe ;yi��•'�,,.,re-..,��+T-3rp ��e�,�r�----- I` � �.. ape - �� '.. �HN MAKI t -e;- G.�1 lHT;L7 Fr t� i t ELL + ce+c: .� tw 'X1 ;'i2 e k 2 P{• ca+5r. /Y'Hp7 cbtct. � / i2 Plpr /2 PZ-.� L �e -- ,'Is- .p�2-o-_---^- �2--- `� iei tt�2 as 'teA tas r♦ 166 tar tet3vY :,►�9 ��i90 t91 t i Fr' i py f t - I r-pe eldispe \o'r/o'Rpe �i0'Ftpo�,�p�i rb�_- = b Skeith showing corr+plfOe drainage sgdterr?, •Z' t�'^L, . . ,y^V;•• a., _ - .r ..�.y, -. _- .. ,.;:L�Li_. - , _ - :v • �' .n �r' 'ja- YY,c�.• .r ' r - - - - +%:'i�..- i Nr Ohl..-.•e*•':; ;�� +•�.. :l�]?. J'el"•_ - ''1 I vile':.: �� +'-!:+`y':!ir`• - '�it7:•t L4 ..F..:.T= .1~!� = y�� •, '3. �f '+ ."��4• _ _.r ':%r? .'a_ _:fwr,3•r -' ��• .. '.+ttTn. a�.7s-w �rt ..., r:- - - =i.. �i`+( a.-:' i - 7i F-�6'1 T' \ ElM L ibomhNieS, 8 Jan Sebastian Dr Unit 12 ! Sandwich, MA 02563 Inc (508)888-6460 Fax(508)888-6446 September 27,2016 Patrick Page 1780 Main Street W. Barnstable, MA Dear Patrick, On September 22,2016,two water samples were collected by Envirotech Laboratories at the trench located at 1780 Main Street West Barnstable,MA.The trench is an extension of the outfall pipe that is located on the property. Results:E coli were detected at the bridge location: 1,900 cfu/100m1. E coli were detected at the ditch location: 140,000 cfu/100m1. Comment E coli counts are significant for sample sites. Sincerely yo on J.Saari Pre ' ent PH:508 888 6460 rsenvim@comcast.net i ENVIROTECH LABORATORIES, INC. MA CERT. NO.: M-MA 063 8 Jan Sebastian Drive Sandwich,MA 02563 (508)888-6460 1-800-339-6460 " FAX(508)888-6446 Tuesday,September 27,2016 Page,Patrick 1780 Main St W Barnstable,M ProjedName: 1780 Main St Comments: Project Number: Collection Date: 09122116 Collection 27me: 14:50 Sampled By: R Saari Lab Order Number: War-161984 Dale Received: 09122116 F Saar �'L?e Sarnpit-Time Sar+ ile 1�de Causmeasis 77 t ' 4 ` T- i a 45 09122I16 Trench_et 6ndge,±A ,:, ,; .:.: _ _•;' .. , Parameters Units Teo RGu1Ls Reportable Litadi s OaueAnaly<ed Anal4w ,1lahod E coli (CFU/100/^mL 1,900]-]\ NA 09/2211116 RS EPA 1603 Parameters t�nicr TestResulis Reportable Limit nafi.lral�.ed anal}n nrz d y E coii CFU/100mL 140,000 NA o9n2+16 RS EPA 1503 BRL=below reportable limits 4tee aKached Ronald J. Saari LaboratorJ !)' ector Page 1 of 1 CHAIN OF CUSTODY FORM ENVIRCTECH LABS, IN Client: Patrick Rage 8 Jan Sebastian Dr., Unit Proj. No. Project Name: Ecoli Sandwich, MA 02563 Address: 1780 Main St It S (508).888-6460/1-800-339-6460 W. barnstable,MA.02668 Sampler: Ron Saari/Env FAX (6:08)888-6446 Phone#: 508 280 7243 Fax#: Lab ID# Date Time Comp Grab Sample location container Pres. Analysis Requested ' c4� 9/22/16 t�tgl yrze�iL Vf E coli Relinquished: Date/Time, Received: Reliquished: DaterTime Received: Relinquished: Date rime Received: Relinquished: Dater rime Received: Official Website of The Town of Barnstable - Property Lookup Page 1 of 4 Select Language(v Assessing Division Property Lookup Results - 2016 367 Main Street,Hyannis,MA.02601 BACK TO SEARCH<< Print Friendly Owner Information-Map/Block/Lot:217/004/-Use Code:1010 Owner Owner Name as of SAUNDERS,JANE D Map/Block/Lot GIS MAPS 1/1/15 1780 ROUTE 6A 217/004/ Property Address WEST BARNSTABLE,MA. 1780 MAIN ST./RTE 6A(W.BARN.) 02668 Co-Owner Name Village:West Barnstable Town Sewer At Address:No GIS Zoning Value:RF Assessed Values 2016-Map/Block/Lot:217/0041-Use Code: 1010 2016 Appraised Value2016 Assessed Value Past Comparisons Building $66,900 $66,900 Year Total Assessed Value: Value Extra $23,200 $23,200 2015-$276,100 Features: 2014-$276,200 2013-$280,500 Outbuildings:$2,400 $2,400 2012-$299,200 2011-$300,600 Land Value: $177,700 $177,700 2010-$392,400 2009-$394,000 2008-$430,200 2016 Totals $270,200 $270,200 2007-$448,000 Residential Exemption Received=$90,000 Tax Information 2016-Map/Block/Lot:217/004/-Use Code:1010 Taxes W.Barnstable FD Tax $724.14 (Residential) Fiscal Year 2016 TAX RATES HERE Community Preservation $50.33 Act Tax Town Tax(Residential) $ 1,677.66 $ 2,462.13 http://www.townofbamstable.us/Assessing/propertydisplaysc.reenl 6.asp?ap=O&searchpar... 10/14/2016 Official Website of The Town of Barnstable - Property Lookup Page 2 of 4 Sales History-Map/Block/Lot:217/004/-Use Code: 1010 History: Owner: Sale Date Book/Page: Sale Price: I SAUNDERS,JANE D 1989-07-05 6797/163 $145000 1 WEBER,ROBERT A&BARBARA D 1987-05-04 5700/346 $0 1 I WEBER,ROBERT A&MARTHA J&BARBARA D1960-01-01. 1086/348 $0 I (I Photos 217/004/-Use Code:1010 ---------� Sketches-Map/Block/lot:217/0041-Use Code:1010 2 ! WDK" FTQ p ,,FER" 1� z.410 20rr 10' 1FH91 �. BMi �0* AS Built Cards:Click card#to view:Card#1 Constructions Details-Map/Block/Lot:217 1 004/-Use Code: 1010 Building Details Land Building value $66,900 Bedrooms 2 Bedrooms USE CODE 1010 Replacement Cost $111,553 Bathrooms 1 Full-0 Half Lot Size(Acres) 3.16 Model Residential Total Rooms 5 Rooms Appraised $177,700 Value Style Cape Cod Heat Fuel Oil Assessed $ Value 177,700 Grade Average Heat Type Hot Water Year Built 1935 AC Type None Effective 40 Interior Floors Hardwood depreciation Stories 1 1/2 Interior Walls Plastered Stories Living Area sq/ft 990 Exterior Walls Wood Shingle Gross Area sq/ft 2,480 Roof Gable/Hip Structure Roof Cover http://www.townofbamstable.us/Assessing/propertydisplayscreenl 6.asp?ap=0&searchpar... 10/14/2016 Official Website of The Town of Barnstable - Property Lookup Page 3 of 4 Asph/F GIs/Cmp Outbuildings&Extra Features-Map/Block/Lot:217/004/-Use Code:1010 Code Description Units/SO ft Appraised Value Assessed Value FEP Enclosed porch- 200 $7,000 $7,000 roof,ceiling BMT Basement- 660 $12,900 $12,900 Unfinished PAT1 Patio-Average 100 $600 $600 FPL2 Fireplace 1.5 1 $3,300 $3,300 I stories WDCK Wood Decking 200 $1,800 $1,800 w/railings Sketch Legend Property Sketch Legend 62N Bam-any 2nd story area FPC Open Porch Concrete Floor REF Reference Only BAS First Floor,Living Area FTS Third Story Living Area(Finished) SOL Solarium BMT Basement Area(Unfinished)FUS Second Story Living Area SPE Pool Enclosure (Finished) BRN Barn GAR Garage TQS Three Quarters Story(Finished) CAN Canopy GAZ Gazebo UAT Attic Area(Unfinished) CLP Loading Platform GRN Greenhouse UHS Half Story(Unfinished) FAT Attic Area(Finished) GXT Garage Extension Front UST Utility Area(Unfinished) FCP Carport KEN Kennel UTQ Three Quarters Story (Unfinished) FEP Enclosed Porch MZ1 Mezzanine,Unfinished UUA Unfinished Utility Attic FHS Half Story(Finished) PRG Pergola UUS Full Upper 2nd Story (Unfinished) FOP Open or Screened in Porch PRT Portico WDK Wood Deck PTO Patio ` Print Friendly I Contact I i f Director of Assessing !Jeffrey Rudziak 1 `P 508-862-4022 I F 508-862-4722 i http://www.townofbarnstable.us/Assessing/propertydisplayscreen l 6.asp?ap=0&searchpar... 10/14/2016 Official Website of The Town of Barnstable - Property Lookup Page 4 of 4 8:30a.m.to 4:30p.m. Helpful Links to mm R Downloads Abatements s I SALES LISTINGS I Barnstable FD i Residential I C.O.M.M FD Residential j Commercial-Industrial- Mixed Use Cotuit FD Residential Hyannis FD Residential Townwide Condominium , i # W.Barnstable FD i Residential I Department of Revenue Exemptions j Parcel Consolidation i Questions about values i Town Tax Rates Town Land Use Codes I � ,Helpful Maps All Town Maps j Flood Insurance Maps Property Maps t a Owned and Operated by The Town of Barnstable-Information Technology Home Departments&Services I Boards&Committees I Residents&Visitors I Doinq Business Town Calendar I Phone Directory I Employment I Email Town Hall http://www.townofbarnstable.us/Assessing/propertydisplayscreen 16.asp?ap=0&searchpar... 10/14/2016 Official Website of The Town of Barnstable - Property Lookup Page 1 of 3 Select Language Assessing Division Property Lookup Results - 2016 367 Main Street,Hyannis,MA.02601 <<BACK TO SEARCH<< Print Friendly Owner Information-Map/Block/Lot:217/031/-Use Code: 1300 Owner Owner Name as of PAGE,PATRICK F TR Map/Block/Lot GIS MAPS 1/1115 1780 MAIN ST/ROUTE 6A 217/031/ Property Address WEST BARNSTABLE,MA. 21 BUTTON WOOD LANE 02668 Co-Owner Name JDS REALTY TRUST Village:West Barnstable Town Sewer At Address:No GIS Zoning Value:RF Assessed Values 2016-Map/Block/Lot:217/031/-Use Code:1300 2016 Appraised Value2016 Assessed Value Past Comparisons Building $0 $0 Year Total Assessed Value: Value Extra $0 $0 2015-$154,500 Features: 2014-$154,500 2013-$160,700 Outbuildings:$0 $0 2012-$154,500 2011 -$154,500 Land Value: $155,300 $155,300 2010-$290,500 2009-$163,900 2008-$170,900 2016 Totals $155,300 $155,300 2007-$170,900 I Tax Information 2016-Map/Block/Lot:217 1 031/-Use Code:1300' Taxes f W.Barnstable FD Tax $416.20 (Residential) Fiscal Year 2016 TAX RATES HERE Community Preservation $43.38 Act Tax I I j Town Tax(Residential) $ 1,445.84 $ 1,905.42 Sales History-Map/Block/Lot:217/031/-Use Code:1300 http://www.townofbarnstable.us/Assessing/propertydisplayscreenl6.asp?ap=0&searchpar... 10/14/2016 Official Website of The Town of Barnstable - Property Lookup Page 2 of 3 History: Owner: Sale Date Book/Page: Sale Price: PAGE,PATRICK F TR 2002-04-04 15016/164 $15000 FOLLETT,HELENA C 1981-07-13 3322151 $0 Photos 217/0311-Use Code: 1300 There are not any photos for this parcel _ _ I Sketches-Map/Block/Lot:217/031/-Use Code:1300 i A sketch is not available for this parcel. AsBuilt Card N/A Constructions Details-Map/Block/Lot:217/031/-Use Code:1300 Land USE CODE 1300 Lot Size(Acres) 0.97 1 Appraised Value $155,300 Assessed Value $155,300 Construction details are not available for this parcel. I Outbuildings&Extra Features-Map/Block/Lot:217/031/-Use Code:1300 There are not any extra building features on record at this time. i Sketch Legend Property Sketch Legend B2N Barn-any 2nd story area FPC Open Porch Concrete Floor REF Reference Only BAS First Floor,Living Area FTS Third Story Living Area(Finished) SOL Solarium BMT Basement Area(Unfinished)FUS Second Story Living Area SPE Pool Enclosure (Finished) BRN Barn GAR Garage TQS Three Quarters Story(Finished) CAN Canopy GAZ Gazebo UAT Attic Area(Unfinished) CLP Loading Platform GRN Greenhouse UHS Half Story(Unfinished) FAT Attic Area(Finished) GXT Garage Extension Front UST Utility Area(Unfinished) FCP Carport KEN Kennel UTQ Three Quarters Story (Unfinished) FEP Enclosed Porch MZ1 Mezzanine,Unfinished UUA Unfinished Utility Attic FHS Half Story(Finished) PRG Pergola UUS Full Upper 2nd Story (Unfinished) IFOP Open or Screened in Porch PRT Portico WDK Wood Deck PTO Patio Print Friendly http://www.townofbamstable.us/Assessing/propertydisplayscreen 16.asp?ap=0&searchpar... 10/14/2016 i Official Website of The Town of Barnstable - Property Lookup Page 3 of 3 � u iContact !Director of Assessing iJeffrey Rudiiak 1P 508-862-4022 F 508-862-4722 8:30a.m.to 4:30p.m. Helpful Links to 'Downloads I Abatements SALES LISTINGS I Barnstable FD Residential C.O.M.M FD Residential Commercial-Industrial- Mixed Use 1 Cotuit FD Residential Hyannis FD Residential ; Townwide Condominium i W.Barnstable FD # Residential r Department of Revenue Exemptions Parcel Consolidation x Questions about values i Town Tax Rates i Town Land Use Codes ;Helpful Maps r All Town Maps s Flood Insurance Maps i Property Maps r b The Town of Barnstable-Information Technolo Owned and Operated y ov Home Departments&Services I Boards&Committees I Residents&Visitors I Doing Business I Town Calendar I Phone Directory I Employment I Email Town Hall http://www.townofbamstable.us/Assessing/propertydisplayscreenl 6.asp?ap=0&searchpar... 10/14/2016 _ . - . ,�... . • 4- it . . !O !iYMZ1. 03/26/2013® o ®0 7.2 5! } ZIP 02109 ® 041PV11127900E ii 0AIM:!C[-A-0V UNITED STATES C)"04 I� ENVIRONMENTAL PROTECTION AGENCY ' REGION 1 5 POST OFFICE SQUARE SUITE 100 BOSTON,MASSACHUSETTS 02109-3912 OFFICIAL BUSINESS PENALTY FOR PRIVATE USE,$300 AN EQUAL.OPPORTUNITY EMPLOYER r " Thomas A. McKean Barnstable Board of Health Director Barnstable Town Hall w,* 367 Main Street Hyannis, MA 02601 P 4 ,z ' r UNITED STATES ENVIRONMENTAL PROTECTION AGENCY OFFICE OF INSPECTOR GENERAL Y 290 BROADWAY y NEW YORK,NY 10007 CASE #: COMP-2018-0003 CROSS REFERENCE #: COMP-2014-0153, COMP-2016-0088 TITLE: ENVIRONMENTAL ISSUES, BARNSTABLE, MA INTERVIEWEE (if applicable): PREPARED BY: RAC PAUL A. BREZINSKI MEMORANDUM OF ACTIVITY DOCUMENT REVIEW f i NARRATIVE: On October 19, 2017, Resident Agent in Charge (RAC) Paul A. Brezinski, EPA Office of Inspector General (OIG), Office of Investigations (01), New York,NY sent copies of lab test results (Attachments 1 to 9) to Dr. Bruce Woods, Chemist, EPA OIG, 01, Electronic Crimes Division, Seattle, WA for a review. The lab reports were based on samples taken frpm a ditch and outfall pipe located on the private property of Patrick Page and Jane Saunders, 1780 Main Street, West Barnstable, MA 02668, 508-280-7243. The purpose of the request for review was to get Dr. Woods' insight into what had been reported. The following was provided: Dr. Woods sent the Reporting Agent an email (Attachment 10) this same date indicating that two primary things jumped out at him from a review of the reports— (1) the concentration of E. coli found and (2) the Total Petroleum Hydrocarbon (TPH) test. Dr. Woods wrote: 1 think the most striking information is for E. coli bacteria in the Trench report. E. coli is a specific indicator of human or animal waste being present somewhere to get into the water, i.e.,.farm, septic tank, ????, etc. It is stated in the report that the E. coli concentrations are significant, i.e., 1,900 CFU and 140,000 CFUper.100 milliliters (or about 3 ounces). CFU's is short-hand for Colony Forming Units, which can replicate and increase the bacteria.concentration. The reason I say that this appears to be a discharge of human/animal waste is the samples tested positive for E. coli. For CASE: COMP-2018-0003 INTERVIEWEE(if applicable): . DATE OF ACTIVITY: October 11, DRAFTED DATE: October 13 & 16, AGENT(S): Brezinski 2017 2017 RESTRICTED INFORMATION This report and any attachments are the property of the EPA Office of Inspector General,Office of Investigations and is Page I of 4 loaned to your agency. It and its contents may not be reproduced or disclosed without written permission. This report contains information protected by the Privacy Act and is FOR OFFICIAL USE ONLY. Disclosure of this report to unauthorized persons is prohibited. See 5 U.S.C.552a. comparison, Total Coliform limits in drinking water is < I CFUper 100 ml sample. The test for Total Coliforms would be higher than a test for fecal coliforms, which would be higher than a specific test for E. Coli. With respect to the TPH test, Dr. Woods wrote: I did not check for a regulatory limit for the Total Petroleum Hydrocarbon test, to compare with their result o 1,800 u /l. But the two different re orts or these tests p f gp f tentatively identified the pattern as 50 weight motor oil and weathered biodiesel. Because I don't know anything about this area, I don't,know if this might be run-off from a road or parking lot. On this same date, the RA and Dr. Woods spoke in further detail. The RA explained the history with the complainants, the issues with the property, the attempts to get remedies/responsibilities and the fact that the property was residential. Dr. Woods utilized Google Maps to get a better understanding of the property and the approximate location of the tests. The RA advised he was not sure of the exact source(s) of the materials that are reportedly emanating from the outfall pipe nor the location as to where the pipe begins. In addition, the RA added that some of the materials found in the ditch.could be runoff from the local roads. Dr. Woods agreed that this is a matter that would fall under the jurisdiction of either the Agency or the Commonwealth of Massachusetts. Attachments: 1. Trench 9-22 & 9-28-17 2. 8-29-17 outfall bact 3. 8-7-17 ditch 4. 8-13-17 discharge pipe 5. 8-1-13 outfall 6. cover letter 8-8-16 7. 12-25-15 stone well 8. 8-27-13 discharge pipe 9. 8-27-13 cranberry bog 10. Email from Dr. Woods, dated October 19, 2017. CASE: COMP-2018-0003 INTERVIEWEE (if applicable): DATE OF ACTIVITY: October 11, DRAFTED DATE: October 13 & 16, AGENT(S): Brezinski 2017 2017 RESTRICTED INFORMATION This report and any attachments are the property of the EPA Office of Inspector General,Office of Investigations and is Page 2 of 4 loaned to your agency. It and its contents may not be reproduced or disclosed without written permission. This report contains information protected by the Privacy Act and is FOR OFFICIAL USE ONLY. Disclosure of this report to unauthorized persons is prohibited. See 5 U.S.C.552a. Attachments: 1. Trench 9-22 & 9-28-17 Trench 9-22& 9-28-17.pdf 2. 8-29-17 outfall bact 8-29-17 outfall bact.pdf 3. 8-7-17 ditch 8-7-17 ditch.pdf 4. 8-13-17 discharge pipe 8-13-17 discharge pipe.pdf 5. 8-1-13 outfall' 8-1-13 outfall.pdf 6. cover letter 8-8-16 MMM cover letter 8-8-16.pdf CASE: COMP-201.8-0003 INTERVIEWEE(if applicable): DATE OF ACTIVITY: October 11, DRAFTED DATE: October 13 & 16, AGENT(S): Brezinski 2017 2017 RES'T'121011)INFORMA110N This report and any attachments are the property of the EPA Office of Inspector General,Office of Investigations and is Page 3 of 4 loaned to your agency. It and its contents may not be reproduced or disclosed without written permission. This report contains information protected by the Privacy Act and is FOR OFFICIAL USE ONLY. Disclosure of this report to unauthorized persons is prohibited. See 5 U.S.C.552a. � K t 7. 12-25-15 stone well 12-25-15 stone well.pdf 8. 8-27-13 discharge pipe 8-27-13 discharge pipe.pdf 9. 8-27-13 cranberry bog 8-27-13 cranberry bog.pdf 10. Email from Dr. Woods, dated October 19, 2017. Email.Woods.190ct 17.pdf CASE: COMP-2018-0003 tNT ERV I EW EE(if applicable): DATE OF ACTIVITY: October 11, DRAFTED DATE: October 13 & 16, AGENT(S): Brezinski 2017 2017 RESTRICTED INFORMATION This report and any attachments are the property of the EPA Office of Inspector General,Office of Investigations and is Page 4 of 4 loaned to your agency. It and its contents may not be reproduced or disclosed without written permission. This report contains information protected by the Privacy Act and is FOR OFFICIAL USE ONLY. Disclosure of this report to unauthorized persons is prohibited. See 5-U.S.C.552a. Enviif Otech Laboratones, 8 Jan Sebastian Dr Unit 12 Sandwich MA 02563 Inc Sandwich, 888-6460 Fax(508)888-6446 September 27,2016 Patrick Page 1780 Main Street W. Barnstable, MA Dear Patrick, On September 22,2016,two water samples were collected by Envirotech Laboratories at the trench located at 1780 Main Street West Barnstable,MA.The trench is an extension of the outfall pipe that is located on the property. Results: E coli were detected at the bridge location: 1,900 cfu/100ml. E coli were detected at the ditch location: 140,000 cfu/100ml. Comment: E coli counts are significant for sample sites, P f Sincerely you 4 i E �fent ri P PH:508 888 6460 rsenviro@comcast.net FP i F. a5 lY p. f { 4' r y ENVIR 0 TECH LA B ORA TOMES, INC. MA CERT NO.: M-MA 063 8 Jan Sebastian Drive Sandwich, AM 02563 (508)888-6460 1-800-339-6460 F (568)888-6446 Tuesday,September 27, 2016 page,Patrick 1750 Alvin.9 IV Bornstable, Al ProjectNnme: 1780 rbicrin St C.vnnnents: Project Number: Collection Date: 09122i16 Collection Time: 14:50 Sampled By: R Saari Lab Order Number: PVTV-161984 Date Received: 09122116 rar T�Yrenc h 1 a.k,.,.5.,,..� F" �.6K at ��'M^,�;°��+:ra^A3�`�� H{�wx^-:5� rs..a?;�'k�Pt'�.,..3`,::���'^.: ;'����,�ls �' '�"�'a�c� -�s3'�'!..3��e�a� .$.r����'" k,� ^�' �tT'rY'��cam"A�" "'.•. ¢v... '�a..rK..,�i,....r.. 2s,'2C",� �.��n, �'!k:i.5 '.aaYa,�r, y� msa..s i�•ti� ,-}Parameters Units Test Results Reporfnble Limits Dare,4»nlj,zed A,mlpsr tleilmd E coif CFU/100mL 1,900 NA O9122116 Sam¢le T e � T ram* S : '€ S EPA 1603 i.Tlme,. a ..r�x''[R, is e 4 4 uH' Comnienlr a�ay"4r w. w uti' h Onoav ` �£�:> x �c,-� ".z.,.a&,.+w aa� s�z..•as.; �x TrenchsDilch3s B � t4:5009123I16a r � 3 !+ =w"`"?fi x'*..; - 4Yio_.a�a..+�.:,"�..P. .,. " ,�,,�; �i�. v: - 'a� '�' t„ rZ •"ram• `#"'D. t�.' *rsU.4."� NI Parameters Units Test Results ReLortable Limits Dale Analyzed Analyst Method E coli CFU/100mL 140,000 NA 09/22/16 IRS EPA 1603 f S' F � l I3IU_=belory repnrlaGle lurrits 'see attached .Ronald,l. Saari Labor Pori,/D' ector Page 1 of 1 v k"s ry ,..,� .__-..._: CHAIN OF CUSTODY FORM ENVIROTECH LABS, IN Client: Patrick Page 8 Jan Sebastian Dr., Unit Proj. No. Project Name: Ecoli Sandwich, MA 02563 S Address: 1780 Main St I (508)888-6460/1-800-339-6460 W. barnstable,MA 02668 Sampler: Ron Saari/Env FAX(508)888-6446 Phone#: 508 280 7243 Fax#: Lab ID# Date Time Comp Grab Sample location container Pres. Analysis Requested l�& 9i22/16 /��(i t3,-�� t E cold Relinquished: Dat ime n�7 Rec ve Reliquished: Date/Time 'C,l%i1J, ,-, (JJ Received: Relinquished: f Da e/Time R tei Relinquished: Date/Time Received: { t a. En � 8 Ja virotech Labo n Sebastian Dr Unit 12 ® �� Sandwich, MA 02563 Inc (508) 888-6460 Fax (508)888-6446 October 26, 2016 Patrick Page t 1780 Main Street W.Barnstable,MA Dear Patrick, On September 28,2016,two water samples were collected by Envirotech Laboratories at the trench located at 1780 Main Street West Barnstable, MA.The trench is an extension of the outfall.pipe that is located on the property. Results: E coli were detected at the bridge location:68,000 cfu/100ml. E coli were detected atthe ditch location: 1,600 cfu/100ml. Comment:E coli counts are significant for sample sites. Sincerely yours, Ronal /.Saari Presi nt PH: 508 888 6460 rsenviro@comcast.net } i k 7 G 4 ti s iF 4. k t w It' S'! s r 7 EN VIR 0 TECH LA B ORA TORIES, INC. MA CERT. NO.: 1V1-MA 063 8 An Sebastian Drive Sandwich, AIA 02563 (.508)888-6460 1-800-339-6460 FAX(508)888-6446 Alonday,October 03,2016 Page, Palrick 1786 Moin Sl H/Barnslable, M ProjeclNreme: Trench Comments: Projecl Number: Collection D(ile: 09/28/16 Collection Time: Sampled.By: R Saari Lab Order Number: W111-I62032 Date Received: 09128116 �,�- � Srunple�j pe '` 3r'�ln Ie�`+Tuire Simi le Date ; - i'sr� 14 45< Q9/28/16 �,•� ,.T�e�=�h _.�:A w , v �� � .�� Parameters Units Test Results Reportable Limits Date Analyzed Anal)w Alelhorl k E coli CFUJ100mL 68,000 NA 09/28/16 RS EPA 1603 Sa»rp1J Tjpe SnnrpleRTrine SairleDa1� Conimen(s �� � c: Trench B �Y'50 09J28/ 6 �; ;Dredge DitchwL <,a+a + �....;.. ...� � .•., Parameters Units Test Results Reportable Limits Dote Analyzer) Armful ,lletlrod E coli CFU/t 00mL 1,600 NA 09/28/16 RS EPA 1603 i i E- r c BRL=below reportable limits i *see attached Rona il. aari Laborrlo 1 Director Page 1 of 1 ik CHAIN OF CUSTODY FORM EN 4 VIROTECH LABS, INC. Client. Patrick Page 8 Jan Sebastian Dr., Unit 12 Proj. No. Project Name: 1780 Main St W Barnstable Sandwich, MA 02563 Address: 1780 Main St tlL�� (508)888-6460 Sampler: /1-800-339-6460 W. barnstable,MA 02668 FAX(508)888-6446' Phone#: 508 280 7243 Lab ID# Date Time Comp Grab Fax#: Sample location container Pres. � � ��� Analysis Requested -71 1 Relinqtsed.�! J ' e / Date ime (((,t tl Receiv I' '] Reliquished: Date/Time Received: Refin-quistkd: Da eTme Recliv Relinquished: Daterrime I' Received: Ci) Envirotech Laboratories, 8 Jan Sebastian Dr Unit 12 Sandwich, MA 02563 Inc (508) 888-6460 Fax (508) 888-6446 September 18,2017 Patrick Page 1780 Main Street W.Barnstable, MA Dear Patrick, On August 29,2017,a sample for algae was collected by Envirotech Laboratories at the ditch located at 1780 Main Street West Barnstable,MA. The ditch is an extension of the outfall pipe that is located on the property.The sample was collected at the bridge location of the ditch. The results are attached. The material consists of lame amounts of filamentous bacteria. Sincerely yours, onald J. a President PFi: 508 8 6460 rsenviro comcast.net i j I t +h� C x ENVIROTECH LABORATORIES, INC. MA CERT. NO.: M MA 063 8 Jan Sebastian Drive SandWeh,111A 02S63 (508)888-6460 1-860-339-6460 FAX(508)888-6446 Monday,September 18,2017 Page. Palricic 1780Aloilt Sl IF Barreslable, Al ProjectNante: Comments: Project Number: Collection Date: 08129117 Collection Time: 12:20 'Sampled BY: R Saari Lah Order Number: WTTr-171903 Date Received: 08129117 Ditch atlBndge A 1220 ` 08/29/17 M Filamentous bacte`na < Parameters Units Test Results Reportable Limits nareefrmly.ed fnnlyst .Ilcthod Algae Identification NMI see comment NA 09/08/17 Northeast Lab i 13R1=belong reportable lirl}i s ,see attached s R iald J aart r Laboral y Director Page 1 of 1 I? �r 0 JI. Northeast Laboratories, Inc. ANAL=Y'TICAL RI PORT Page 1 of 1 Report To: ENVIROTECH LABORATORIES, INC. Attn: Ronald Saari, President EMAIL ADDRESSEE: rsenviro@comeast.net 8 Jan Sebastian Dr= Unit#12 Sandwich MA 02563 Report Date: 9/13/2017 Date Sampled: 8/29/2017 . Laboratory ID#: N1771449 Date Received: -9/06/2017 Envirotech's 10#: OW— 171903 Date Tested: 9/06/2017 MICROSCOPIC EXAMINATION: ' Raw Water=SITE: Ditch @ Bridge ORGANISM #/ml ORGANISM #/ml ORGANISM #/ml ORGANISM #/ml Diatomaceae Chloro h ceae C ano h ceae Protozoa Amphora Actinastrum Anabaena* Actino hrys A sterionella* Arthrodesmus Anabaenopsis Amoeba iAm hi rota Ankistrodesmus A hanoca sa Arcella Cocinodiscus Chorella A hanizomenon* Bursaria* C clotella* Closterium A hanothece Ceratium Cymbella Coelastrum Aulosira Cercomonas Diatoma* Cosmarium Arthros ira Cfiilomonas Frustulia Dictyos haerium* Chroococcus Chlam domonas Fra ilaria Eudodna* Clathroc stis* Codonella G rosigma Elakatothk Coelosphaerium* C ptomonas* Gom honema Gleoc stis Cylindros ermum Difflugia Melosira Micrasterias . Cus idothrix Dinob on* Meridion* Mougeotia Dact lococcopsis Euglena77 Navicula Pandorina* Euca sis Glenodinium* Nitzschia Pediastrum Gleoca sa Gonium Pleurosigma Protococcus Galucocystis Halteria Pinnularia Quadri ula Gloeothece Mallomonas*` Ste hanodiscus Scenedesmus Gom hos haena Monas Ste hanodiscus S haeroc stis Hydrocoleum Peridinium* Surirella S haerozosma Microc stis S nura* S nedra Spirogyra Merismo edia Trachelomonas Tabellaria* Staurastrum Nostoc Urogleno sis* Tetras ora Nodularia Vorticella Rotifera Westella Oscillatoria Anuraea Ulothrix Pseudanabaena Asplanchna Volvox* S irulina Brachionus Xanthidium Rivularia* Conochilus Z gnema Xenococcus Schizom cetes j Euchfanis Euastrum Crenothrix Keratella Notholca Xenococcus Miscellaneous Polyarthra Acarina ` Rotifer Anguillula S nchaeta Miscellaneous Bosmina Canthocam tus *Odor Producin Palmella Anac stis C cl0 s Phacus Golenkinia Da hnia J(Diaptomus d Conclusions: Total Natural Unit Count: 0 per mL Comments: Results are based on sample,as submitted to Northeast Laboratories, Inc. on:8/08/2017, Large number of filamentous bacteria noted in sample. Approved by; Laboratory Director P. Northeast Laboratories,Inc. 1.29 Mill Street Berlin, CT 06037 a «�i w.ne}a6sct.con, Telephone: 960-828-9787 Toll Free(hi State)800-826-0105 (Out of State)800-654-1230 Fax:860-829-1050 CT Cerl.#PH-0404 EPA Cerf.ftCT-024 USDA Cerf.90976 FDA Rcg.N086650488 CT CSLt/0000624 CHAIN OF CUSTODY FORM ENVIROTECH LABS, INC. Client: Patrick Page 8 Jan Sebastian Dr., Unit 12 Proj. No.. Project Name: 1780 Main St W Barnstable Sandwich, MA 02563 Address: 1780 Main St (508)888-6460/1-800-339-6460 W. bamstable,MA 02668 Sampler: f� FAX(508)888-6446 Phone#: 508 280 7243 Fax#: Lab ID# Date Time Comp Grab Sample location container Pres. Analysis Requested Relinquish Daterrime Rece ed: Reliquished: DateTme Received: 01 Relinqui ed: Date/Time Received: Relinquished: Date/Time Received: ~ . r S Enviro$ech Laboratories, 8 Jan Sebastian Dr Unit 12 Sandwich, MA 02563 Inc (508)888-6460 Fax (508)888-6446 September 12,2017 Patrick Page 1780 Main Street W. Barnstable,MA Dear Patrick, On August 7,201-7,water samples were collected by Envirotech Laboratories at the ditch located at 1780 Main Street West Barnstable, MA. The ditch is an extension of the outfall pipe that is located on the property.The sample was collected at the bridge location of the ditch. The results are attached. There was found 1,800 ug/L of petroleum that most closely resembles 50w motor oil.Also,amounts of Lead, Copper,Chromium,Aluminum, Iron,and Manganese were detected. Sample for Algae identification was taken at the ditch located at the large boulder.Genus P 9 9 Aphanocapsa and Nostoc belong to the Cyanobacteria group. Sincerely yours, AonalldJ.S�ri President PH:508 88 6460 rsenviro@comcast.net t ENYMOTECHLABORATORIES, INC. MA CERT. NO.: M MA 063 8 Jan Sebastian Drive Sandwich,MA 02563 (508)888-6460 1-RQ0-3:39-6460 FAX(508)888-6446 IYednesday,Septetnher 06,2017 Page, Pafrick 1780 A,tairt Sf IF Barrrslable, Ad ProjeciName: Comments: Project Number: Collection Date: 08107117 Collection Time: 12:45 Sampled By: Saari/Envirofech Lab Order Number: WW-171705 Date Received: 08107117 -,.a ��i��t�'� � �s-fy�'�. �,�` �i'�. .,�� s,�Y�s3.�� x � �,�z. � �—�bti� zS" ri:".'� � �� �s��-•a� '3 ,��-�'�'e +" t; r� '3�3�bs� D�tCtl����1 A��, �',, i 12•,95�-x �"�.� 08/07/17�" :5 h... :.,4 � � 3'�� i� Dltch�outfall bndge�,��'�4�""t�' s„ sGi ` .•-,' Parameters Units Test Results Reportable Limits Date Analyzed Atta4ut w Method Total Iron mg/L 33 0.01 08/10/17 MC EPA 200.7 Manganese mg/L 0.237 0.005 08/10/17 MC EPA 200.7 Aluminum mg/L 3.75 0.010 08/10/17 MC EPA 200.7 Barium mg/L 0.197 0.002 08/10/17 MC f EPA 200.7 Chromium mg/L 0.019 0.002 08/10/17 MC EPA 200.7 Nickel mg/L 0.009 0.005 08/10/17 MC EPA 200.7 Lead mg/L 0.037 0.006 08/10/17 MC EPA 200.7 Copper mg/L 0.024 0.003 08/10/17 MC EPA 200.7 Zinc mg/L 0.209 0.004 08/10/17 MC EPA 200.7 Petroleum Fingerprint' 1,800 ' 08/18/17 RIA' ' N F if i i R v ;i k f, BRL=below reportable limits 'see attached B Ronal J. Saari Lab ratory Dire for Page 1 of 1 r Page 2 of 3 R.I.Analytical Laboratories,Inc. Laboratory Report Envirotech Laboratories, Inc, Work Order 4:1708-17187 Project Name: 1780 MAIN STREET, W. BARNSTABLE MA Sample Number: 001 Sample Description: WW-171705 DITCH @ OUTFALL BRIDGE Sample Type: GRAB Sample Date/Time: 8/07/2017 @ 12:45 SAMPLE DET. DATE/TIME PARAMETER RESULTS LIMIT UNITS METHOD ANALYZED ANALYST TPH TPH GUM 1800 140 ug/l SW-846 8100M 8/18/2017 12:53 CCS Surrogate RANGE SW-8468100M 8/18/2017 12:53 CCS 2-Fluorobiphenyl 53 40-140% SW-846 8100M 8/18/2017 12:53 CCS Extraction Date SW-846 3510C 8/11/2017 9:55 JBW TPH Fingerprint=Chromatogram most closely resembles 50w motor oil. I i i e t i i z' CHAIN OF CUSTODY FORM ENV6ROTECH LABS, INC. RI Analytical! 8 Jan Sebastian Dr Unit 12 PWS: M RI 015 Project Name: 1780 Main St, W Barnstable Sandwich,MA 02563 Address 41 Illinois Avenge® (508)888-6460 Warrick, RI 02888 Sampler. R Saari/E.nvirotech 1-800-339-6460 Phone# 401-737-8600 FAX(508)88"446 Lab ID aex 401-735-19►70 Date Time re Comp Grab Station location DEP ID Container Pres. Sample WW-171705 08/07/17 1245 X Ditch Outfall Bride type Analysis requested 9 Glass HClNCI Petroleum Scare a ' Rellnauished Da me Received: Reiiauished• D Al lTime Q cf' 5 Re eve R Iin I hod: Da Received: kRofln'�uls7hhod: 15',ze; �� 1 Datem— Received; r Page I of 3 R.I. ,ANALYTICAL Specialists in Environmental Services 3 ' LABORATORY REPORT Envirotech Laboratories,Inc. Date Received: 8/9/2017 ' Attn: Mr. Ron Saari N Date Reported: 8/18/2017 8 Jan Sebastian Drive P.O.Number Sandwich,MA 02563 Work Order#: 1708-17187 Project Name: 1780 MAIN STREET, W. BARNSTABLE MA Enclosed are the analytical results and Chain of Custody for your project referenced above. The sample(s) were analyzed by our Warwick,RI laboratory unless noted otherwise. When applicable, indication of sample analysis at our Hudson,MA laboratory and/or subcontracted results are noted and subcontracted. reports are enclosed in their entirety. All samples were analyzed within the established guidelines of US EPA approved methods with all requirements met, unless otherwise noted at the end of a given sample's analytical results or in a case narrative. The Detection Limit is defined as the lowest level that can be'reliably achieved during,routine laboratory. conditions. These results only pertain to the samples submitted for this Work Order#and this report shall not be reproduced except in its entirety. s 1 We certify that the following results are.true and accurate to the best of our knowledge. If you have questions or need further assistance,please contact our Customer Service Department. Approved by: i r` Melissa A.Manamon QA/QC Officer is x Laboratory Certification Numbers(as applicable to sample's origin state): . Warwick RI*RI LAI00033,MA M-R1015,CT PH-0508,ME RI00015,NH 2O70,NY 11726 Hudson MA*M-MAI 117,RI LA000319 41 Illinois Avenue,Warwick,RI 02888 www.rianalytical.com 131 Coolidge Street,Suite 105,Hudson MA 0174.9 .19 Phone,401-737-8500 Fax:401-7,U-1970, Phone:978-56870041 Fax:978-56870078 K r CHAIN OF CUSTODY FORM ENVIROTECH LABS, INC. Client: Patrick Page Proj. No. Project Name: 0 Jan Sebastian Dr., Unit 12 1780 Main St W Barnstable sandwich, MA 02563 i Address: 1780,Mairu St Sampler: (508)888-6460/1-800-339-6460 W. barnstable,MA 02668 FAX (508)888-6446 Phone#: 5082807243 Lab ID.._# Date Time/ Comp Grab (� Sample location Fax#: container Pres. Analysis Requested i n Petroleum Scan i metals • a I y�1 Relinquis Date m' ,I L�UU Re ate/TiAme i Reliquished: D j��' ( Received: Relinquished: Dat /Time !t Received: Relinquished: Date/Time Received: t , ENVIROTECII LABORATORIES, INC. MA CERT. NO.: M-MA 063 8"Jan Sebastian Drive Sandrvich,MA 02563. (,508)888-6A60 1-800-339-6460 FAX(508)888-6446 Tuesday,September 12,2017 Page, Patrick 1780 A,1oin,S1 IYBarnstable,Al ProjectName: 1780 Main St., W. Barn. Comments: Project Number: NA Collection Date: 817117 Collection Time: 12:20 Sampled By: RS/Envirotech Lab Order Number: WW-171706 Date Received: 08107117 Boultler��.kA Parameters. Units Test Results Reportable Llerits Dare Analyzed Analyst Method Algae Identification #/ml see attached NA 68108/17 Northeast Lab i {t Y. • r' i P BRL=belowreportabl ' 'see attached 13y: Rol Id J. Sa i r` Ldhorato y irector 4' K: Page 1 of 1 1 C Y � I - L .00 Northeast Laboratories, Inc. ANALV T I(;Al, REPORT Page 1 of 1 Report To: ENVIROTECH LABORATORIES, INC.- .Attn: Ronald Saari, President ( EMAIL ADDRESSEE: rsenviro@comcast.net 8 Jan Sebastian Dr= Unit#12 Sandwich MA 02563 Report Date: 8/14/2017 Date Sampled: t 8/07/2017 Laborato ID#: N1771079 Date Received: 8/08/2017 Envirotech's 6D#. DW— 171706 Date Tested: 8/08/2017 Raw Water-SITE: 1780 Main St. West Barnstable MA, Ditch @ MICROSCOPIC EXAMINATION: Boulder ORGANISM #/ml I ORGANISM #/ml ORGANISM #/ml ORGANISM #/ml Diatomaceae Chloro h ceae C ano h ceae I jProtozoa _ Amphora Actinastrum Anabaena* Actinophrys Asterionella* lArthrodesmus jAnabaenopsis jArnoeba Am hi rora lAnkistrodesmus jAphanocapsa 1,900 Zrsaria* cella Cocinodiscus Chorella A hanizomenon* C clotella* Closterium A hanothece Ceratium C mbella lCoelastrurn Aulosira Cercomonas Diatoma* Cosmarium Arthros Ira IChilomonas Frustulia Dici os haerium* Chroococcus Chlam domonas Fra ilaria Eudorina* Clathroc stis* Codonella G rosi ma Elakatothrix Coelos haerium* C tomonas* Gornp honema Gleoc stis C lindros ermum jDifflugla Melosira Micrasterias Cus idothrix Dinob on* Meridion* Mou eotia Dact lococco sis Eu lena Navicula 15,000 Pandorina* Euca sis Glenodinium* Nitzschia Pediastrum Gleoca sa Gonium Pleurosi ma lProtococcus Galucoc stis Halteria Pinnularia IQuadrigula Gloeothece Mallomonas* Ste hanodiscus IScenedesmus 11 Gom hos haeria I IMonas Ste hanodiscus ISphaerocystis I H drocoleum Peridinium* Surirella ISphaerozosma Microc stis S nura* S nedra ISpirogyra 3.900 IMerismopedia I iTrachelomonas Tabellaria* IStaurastrurn Oodularia ostoc 960 Uro leno sis` Tetras ora Vorticella Rotifera Westella Oscillatoria Anuraea �Ulothrix 5,800 Pseudanabaena As lanchna Volvox* S irulina Brachionus Xanthidium Rivularia* Conochilus Zygnema Xenococcus Schizom cetes Euchlanis Euastrum Crenothrix Keratella Notholca Xenococcus Miscellaneous Pol arthra A Acarina l r F Rotifer n uillula S nch,aeta Miscellaneous Bosmina Canthocam tus *Odor Producing Palmella Anac stir Cyclops Phacus Golenkinia Daphnia z Dia tomus F i Conclusions: ITotal_Natural Unit Count: 28,000 per mL Comments: Results are based on sample, as submitted to Northeast Laboratories, Inc, on: 8/08/2017 (rounded) Approved by: Laboratory Director Northeast Laboratories,Inc. 129 Mill Street Berlin, CT 06037 Nvivw.nelabsct.com Telephone: 860-828-9787 Toll Free(In State)800-826-0105 (Out of State)800-654-1230 Fax: 860-829-1050 CT Cert.#PH-0404 EPA Cert.#CT-024 USDA Cert.#0976 FDA Reg.#086650488 CT CSL#0000624 E e { CHAIN OF CUSTODY FORM ENVIROTECH LABS, INC. Client: Patrick Page 8 Jan Sebastian Dr., Unit 12 Proj. No. Project Name: 1780 Main St W Barnstable Sandwich, MA 02563 Address: 1780 Main St (508)888-6460/1-800-339-6460 W. barnstable,MA 02668 Sampler: r FAX 508 888-6446 ( ) Phone#: 508 280 7243 Fax#: Lab ID# Date Time Comp Grab Sample location p container Pres.00- 17 /706, Analysis Requested Algae ID (specifically cyanobacteria) Relinquish D irno Ido Rece" e Retiquished: Date/Time Received: Relinquished: DateM6 Received: Relinquished: Daterrime Received: - 'J ENVIROTECH LABORATORIES, INC. ` 3M CERT. NO.: M MA 063 8 Jan Sebastiaii Drive Sandwich,AL1 02563 (508)888-6460 1-800-33 9-6460 FAX ffb8)888-6446 rrie iy,September 27,2013 Page, Palrick /780 Xfahi St Pi,'13arnslable, Al Projec/Name: 1780 AlAd17 St lY Brn astable Comments: Rain event in AM Project Number. Collection Date: 08127113 Collection Time: 12:05 Sampled BN: R Saari Lab Order Number: W7,Y 132030 Dale Received: 08/27/13 Samp/e T}pe Soliple 77me Sainple,Dai� 777, Comments ,r 4 Dischatge Pipe ;A 12 05 08/27/13 s s *y.D ` i n butylphthalate, Parameters nits Test Results Reportable Limits Date Analyzed Analyst Alethod Sodium mg/L 11.4 1.0 08/29/13 MC 200.7 EPH/PAH ug/L 210 09ro4/13 RlT7__T MADEP VPH ug/L None Detected 08/29/13 RIA* MADEP E coli 1100 5,000 NA 08/27/13 RS E_ PA 1603 , Semi-volatile Compounds ug/L 15— 09/05/13 RIA* EPA 625 Dioxin pg/L None Detected * 09/16/13 Summit EPA 16136 i { t s s n { 't t i N Ik ySy I3RL=Gelow reportable lin t *see attacked 4 a Ro,rnld J. 1 ri Laborat *Director Page 2 of 2 •} 1 R.I . ANALYTICAL Page i of Specialists in Environmental Servic®s CERTIFICATE OF•ANALYSIS Envirotech Laboratories, Inc. Date Received: 8/28/2013 Attn: Mr. Ron Saari Date Reported: 9/6/2013 8 Jan Sebastian Drive P.O.#: Sandwich, MA 02563 Work Order#: 1308-18481 DESCRIPTION: PAGE, PATRICK Subject saniple(s) has/have been,analyzed by our Warwick,R.I. laboratory with the attached results. Reference: All parameters were analyzed by U.S. EPA approved methodologies. The specific methodologies are listed in the methods column of the Certificate of Analysis. Data qualifiers (if present) are explained in full at the end of a-given sample's analytical results. The Certificate of Analysis shall not be reproduced except in full, without written approval of R.I. Analytical. Results relate only to samples submitted to the laboratory for analysis. Test results are not blank corrected. fY Certification#: RI-033, MA-RI015, CT-PH-0508, ME-R.I015 NH-253700 A&B, USDA 5-41844 If you have any questions regarding this work, or if we may be of further assistance,please contact 1 ot.ir Customer service department. r e • B Approved b i Sharon Baker MIS/Data Reporting enc: Chain of Custody { I�. 41 Illinois Avenue,Warwick,RI 02888 4, 131 Cooifd e Sheet Suite ui e t 105 www.rianalytical.com 9 Hudson,MAo1799 . Phone:401:737.8500 Fax:401.738.1970 Y Phone:978.568.00 41 Fax:978.568.0078 s Page 2 of 7 R.I. Analytical Laboratories, Inc. CERTIFICATE OF ANALYSIS Envirotech Laboratories Inc. Date Received: 8/28/2613 Work Order#: 1308-18481 Sample# 001 SAMPLE DESCRIPTION: WW-132030 1780 MAIN ST. W.BARNSTABL.E SAMPLE TYPE: GRAB 'SAMPLE DATE/TIME: 8/27/2013 @ 12:05 SAMPLE DET. DATE/TIME PARAMETER RESULTS LIMIT UNITS METHOD ANALYZED ANALYST TOC 15 5 mg/I SM-5310B 8/29/2013 12:45 EC TPH TPH GC/FID 850 100 ug/I SW846 8100M 9/4/2013 19:37 THP Surrogate RANGE SW-846 8100 9/4/2013 19:37 THP 2-Fluorobiphenyl 86 40-140% SW-846 8100 9/4/2013 19:37 THP Extraction date Extracted SW8463510 9/l/2013 10•I5 RJI PCB Aroclor-1016 <0.5 0.5 ug/i EPA 608 9/4/2013 10:10 JEB Aroclor-1221 <0.5. 0.5 ug/I EPA 608 9/4/2013 10:10 JEB Aroclor-1232 <0.5 0.5 ug/l EPA 608 9/4/2013 10:10 JEB Aroclor-1242 <0.5 0.5 ug/I EPA 608 9/4/2013 10:10 JEB Aroclor-1248 <0.5 0.5 ug/I EPA 608 9/4/2013 10:10 JEB Aroclor-1254 <0.5 0.5 ug/I EPA 608 9/4/2013 10:10 JEB Aroclor-1260 <0.5 0.5 ug/I EPA 608 9/4/2013 10:10 JEB Surrogate RANGE 9/4/2013 10:10 JEB Tetrachloro-m-xylene(TCMX) 70 30-150% EPA 608 9/4/2013 10:10 JEB Decachlorobiphenyl 30 30-150% EPA 608 9/4/2013 10:10 JEB j Extraction date Extracted EPA 608 9/l/2013 10:15 RJL VPH I Unadjusted CS-C8 Aliphatics(FID) <150 150 ug/I MADEP 8/29/2013 11:38 *ET 1 Unadjusted C9-C12 Aliphatics(FID) <150 150 ug/I MADEP 8/29/2013 11:38 *ET } Methyl-tert-butylelher <1.5 1.5 ug/I MADEP 8/29/2013 11:38 *ET Benzene <1.5 1.5 ug/l MADEP 8/29/2013 11:38 *ET Toluene <5.0 5.0 ug/I MADEP 8/29/2013 11:38 Elhylbenzene <5.0 5.0 ug/I MADEP 8/29/2013 11:38 *ET G m,p-Xylene <I0.0 10.0 ug/I MADEP 8/29/2013 11:38 *ET o-Xylene <5.0 5.0 ug/I MADEP 8/29/2013 11:38 *ET Naphthalene <5.0 5.0 ug/I MADEP 8/29/2013 11:38 *ET Adjusted CS-C8 Aliphatics(FID) <150 150 ug/I MADEP. 8/29/2013 11:38 *ET Adjusted C9-C12 Aliphatics(FID) <150 150 ug/I MADEP 8/29/2013 11:38 ET.- C9-C10 Aronlatics(PID) <100 100 ug/I MADEP 8/29/2013 11:38 *ET Surrogate RANGE 8/29/2013 11:38 *ET k 2,5-Dibromotoluene(PID) 100 70-130% MADEP 8/29/2013 11:38 *ET 2,5-Dibronlololuene(FID) 92 70-130% MADEP 8/29/2013 11:38 *ET EPH/PAH C9-C18 Aliphatics <100 100 ug/l MADEP 9/4/2013 16:32 THP 4 C19-C36 Aliphatics 210 100 ug/I MADEP 9/4/2013 1.6:32 THP C11-C22 Aromatics <100 100 ug/I MADEP 9/4/2013 16:32 THP s TARGET PAH ANALYTES 9/4/2013 16:32 THP . I. C Page 3 of 7 R.I. Analytical Laboratories, Inc. CERTIFICATE OF ANALYSIS > nvirotech Laboratories Iuc,. Date Received: 8/28/2613 Work Order#: 1308-18481 Sample# 001 SAMPLE DESCRIPTION: WW-132030 1780 MAIN ST. W, BARNSTABLE SAMPLE TYPE: GRAB SAMPLE DATE/TIME: 8/2-7/2013 cr 12:05 SAMPLE DET. DATE/TIME PARAMETER RESULTS LIMIT UNITS METHOD ANALYZED ANALYST Naphthalene <5 5 ug/1 MADEP 9/4/2013 16:32 THP 2-Methyinaphthalene <5 5 ugft MADEP 9/4/2013 16:32 TIP Acenaphthylene <5 5 ug/1 MADEP 9/4/2013 16:32 THP Acenaphthene <5 5 ug/l MADEP 9/4/2013 16:32 THP Fluorene <5 5 ug/1 MADEP 9/4/2013 16:32 THP Phenanthrcnc <5 5 ug/l MADEP 9/4/2013 16:32 THP Anihracene <L s g/t ADD R14/2913 1.63-2 Tlfp Fluoranthene <5 5 ug/l MADEP 9/4/2013 16:32 THP Pyrene <5 5 ugh MADEP 9/4/2013 16:32 THP Benzo(a)anthracene <5 5 ug/l MADEP 9/4/2013 16:32 THP Chrysene <5 5 ug/1 MADEP 9/4/2013 16:32 THP Benzo(b)fluoranthene <5 5 u8/1 MADEP 9/4/2013 16:32 THP Benzo(b)fluoranthene <5, 5 ug/l MADEP 1 9/4/2013 16:32 THP Benzo(a)pyrene <5 5 ug/l MADEP 9/4/2013 16:32 THP Indeno(1,2;3-ed)pyrene <5 5 ug/l MADEP 9/4/2013 16:32 THP Dibenzo(a,h)anthracene <5 5 ug/l MADEP 9/4/2013 MR THP Be.nzo(g,h,i)perylenc <5 5 UM MADEP 9/4/2013 16:32 THP Extraction Surrogates RANGE 9/4/2013 16:32 THP 5 alpha-Androstane 87 40-140% MADEP 9/4/2013 16:32 THP Ortho-terphenyl 79 40-140% MADEP 9/4/2013 16:32 THP Fractionation Surrogates RANGE 9/4/2013 16:32 THP a 2-Fluorobiphenyl 78 46-140% MADEP 9A/2013 16:32 THP ` t 2-Bromonaphtltalenc 63 40-140% MADEP 9/4/2013 16:32 TI-W Extraction date Extracted MADEP 9/3/2013 16:37 MMM t Semi-Volatile Organic Compounds . Acenaphthene <5 5 ug/1 EPA 625 9/5/2013 15:11 KF Acenaphthylene <5 5 ug/1 EPA 625 9/5/2013 15:11 KF Anihracene <5 5 ug/1 EPA625 9/5/2013 15:11 KF Benzidine <5 5 ug/1 EPA625 9/5/20H 15:11 KF Benzo(a)anthracene <5 5 ug/l EPA 625 9/5/2013 15:11 KF Benzo b Buoranthene <5 r' O 5 ug/l EPA 625 9/5/2013 15:11 KF Benzo(b)Duoranthene <5 5. ug/l EPA 625 9/5/2013 15:11 KF 5 Benzo(g,h,i)perylene <5 5 ug/1 EPA625 9/5/2013 15:11 KF $ Benzo(a)pyrene <5 5 ug/l EPA 625 9/5/2013 15:11 KF bis(2-Chloroethyl)Ether <5 5 ug/l EPA625 9/5/2013 15:11 KF Bis 2-Chloroethox methane <5 ( Y) 5 ug/l } EPA 625 9./5/2013 15:11 KF Bis(2-ell loroisopropyl)ether <5 5 ug/1 1 EPA625 9/5/2013 15:11 KF Bis(2-et.hy1hcxyl)phthalate <5 5 ugh EPA625 9/5/2013 15:11 KF 4-Bromophenyl plienyl ether <5 5 ug/l EPA625 9/5/2013 15:11 KF Butylbenzylphthalate <5 5 ug/1 EPA625 9/5/2013 15:11 KF. 2-Chloronapthalene <5 5 ug/l EPA 625 9/5/2013 15:11 KF. h.; �r r Page 4 of 7 R.L Analytical Laboratories, Inc. CERTIFICATE OF ANALYSIS Envirotech Laboratories hic. Date Received: 8/28/2613 Work Order 4: 1308-18481 Sample# 001 SAMPLE DESCRIPTION: WW-132030 1780 MAIN ST. W.BARNSTABLE SAMPLE TYPE: GRAB SAMPLE DATE/TIME: 8/27/2013'@ 12:05 SAMPLE DET. DATE/TIME PARAMETER RESULTS LIMIT UNITS, METHOD ANALYZED ANALYST 4-Clilorophenyl phenyl ether <5 5 ug/l EPA625 9/5/2013 15:11 KF Chrysene <5 5 ug/l EPA 625 9/5/2013 15:11 KF Dibenzo(a,h)anthracene <5 5 ug/l EPA 625 9/5/2013 15:11 KF Di-n-butyl phthalate 15 5 ug/1 EPA625 9/5/2013 15:11 KF 1,2-Dichlorobenzene <5 5 ug/1 EPA 625 9/5/2013 15:11 KF 1,3-Dichlorobenzene <5 5 ugll EPA 625 9/5/2013 15:11 KF l.4-tlirhlnrnhrn7rnr $ S 6511 E- A626 9f5,99H Hii fe 3,3'-Dichlorobenzidine <5 5 ug/l EPA 625 9/5/2013 15:11 KF Dietlryl phthalate <5 5 ug/1 EPA 625 9/5/2013 15:1 I KF Dimethyl phthalate <5 5 ug/l EPA 625 9/5/2013 15:11 KF 2,4-Dinitrotoluene <5 5 ug/1 EPA625 9/5/2013 15:11 KF 2,6-Dinitrotoluene <5 5 ug/l EPA 625 9/5/2013 15:l 1 KF Di-n-octylphthalate <5 5 ug/1 EPA625 9/5/2013 15:1I KF 1,2-Dipheny1hydra7ine <5 5 ug/l EPA 625 9/5/2013 15:11 KF Fluoranthene <5 5 ug/l EPA625 9/5/2013 15:11 KF Fluorene <5 5 ug/l EPA 625 9/5/2013 15:11 KF Hexachlorobenzene <5 5 ug/l EPA 625 9/5/2013 15:11 KF Hexachlorobutadiene <5 5 ug/1 EPA625 9/5/2013 15:11 KF Hexachlorocyclopentadiene <5 5 ug/l EPA625 9/5/2013 15:11 KF Hexachloroethane <5 5 ug/1 EPA 625 9/5/2013 15:11 KF lndeno(1,2,3-cd)pyrcnc <5 5 ug/I EPA625 9/5/2013 15:11 KF j Isophorone <5 5 ug/1 EPA 625 9/5/2013 15:11 KF i Naphthalene <5 5 ug/l EPA 625 9/5/2013 15:11 KF i Nitrobenzene <5 5 ug/l EPA625 9/5/2013 15:11 KF I N-nitrosodimethylamine <5 5 ug/l EPA625 9/5/2013 15:11 KF N-nitrosodiphenylamine <5 5 ug/1 EPA 625 9/5/2013 15:11 KF N-nitrosodi-n-propylamine <5 5 ug/1 EPA625 9/5/2013 15:11 KF s Phenanthrene <5 5 ug/1 EPA 625 9/5/2013 15:11 KF Pyrene <5 5 ug/1 EPA 625 9/5/2013 15:11 KF ' 1,2,4-Triclilorobenzene <5 5 ug/l EPA 625 9/5/2013 15:11 KF 4-Chioro-3-methylphenol <5 5 ug/1. EPA 625 9/5/2013 15:11 KF 2-Chlorophenol <5 5 ug/1 EPA 625 9/5/2013 15:11 KF a' 2,4-Dichlorophenol <5 5 ug/1 EPA 625 9/5/2013 15:11 KF 2,4-Dimethylphenol <5 5 ug/l EPA 625 9/5/2013 15:11 KF 2-Mcthyl-4,6-dinitrophenol <5 5 ug/l EPA 625 9/5/2013 15:11 KF 2,4-Dinitrophenol <5 5 ug/l EPA625 9/5/2013 15:11 KF 2-Nitrophenol <5 5 ug/1 EPA 625 9/5/2013 15:11 KF 4-Nilrophenol <5 5 ug/l EPA625 9/5/2013 15:11 KF . Pentachlorophenol <5 5 ug/l EPA 625 9/5/2013 15:11 KF Phenol <5 5 ug/1 EPA625 9/5/2013 15:11 KF 2,4,6-Trichlorophenol <5 5 ug/1 EPA 625 9/5/2013 15:11 KF Surrogates RANGE EPA 625 9/5/2013 15:11 KF h Page 5 of 7 R.I. Analytical-Laboratories, Inc. CERTIFICATE OF ANALYSIS Envirotech Laboratories,Lic. Date Received: 8/28/2013 Work Order#: 1308-18481 Sample# 001 SAMPLE DESCRIPTION: WW-132030 1780 MAIN ST. W.BA- NSTABLE SAMPLE TYPE: GRAB SAMPLE DATE/TIME: 8/27/2013 @ 12:05 SAMPLE DET, DATE/TIME PARAMETER RESULTS LIMIT UNITS ATE,THOD ANALYZED ANALYST Phevol-d5 29 15-110% EPA 625 9/5/2013 15:11 KF 2-Fluorophcnol 36 15-110% EPA 625 9/5/2013 15:11 KF 2,4,6-Tribromophenol 91 15-110% EPA 625 9/5/2013 15:11 K.F Nitrobenzene-0 89 30-130%, EPA 625 9/5/2013 15:11 KF 2-I-luorobiphcnyl 69 30-130% EPA 625 9/5/2013 15:11 KF P-Terphenyl-d14 85 30-130% EPA 625 9/5/2013 15:11 KF Volatile Organic Compounds Benzene <1 1 ug/l SW-846 8260E 8/31/2013 15:29 KAC Bromobenzene <1 1 ug/l SW-846 8260B 8/31/2013 15:29 KAC Bromochloromethane <1 1 ug/l SW-846 8260B 8/31/2013 15:29 KAC Bromodichloromethane <1 I ug/l SW-8468260B 8/31/2013 15:29 KAC Bromoform <1 1 ug/l SW-8468260B 8/31/2013 15:29 KAC Bromomethane <5 5 ug/l SW-846 8260B 8/31/2013 15:29 KAC n-Butylbenzene .<1 1 ug/l SW-8468260B 8/31/2013 15:29 KAC Sec-butylbenzene <1 I ug/1 SW-846 8260B 8/31/2013 15:29 KAC tert-Butylbenzene <1 1 ug/l SW-846 8260B 8/31/2013 15:29 KAC Carbon Tetrachloride <1 1 ug/1 SW-846 8260B 8/31/2013 15:29 KAC Chlorobenzene <1 1 ug/1 SW-846 8260B 8/31/2013 15:29 KAC Chloroethane <5 5 ug/l SW-846 8260B 8/31/2013 15:29 KAC C:hloraform <1 1 ug/1 SW-846 8260B 8/31/2013 15:29 KAC t Chloromethane <5 5 ug/1 SW-8468260B 8/31/2013 15:29 KAC 2-Chlorotoluene <I 1 ugll SW-8468260B 8/31/2013 15:29 KAC 4-Chlorotoluene <1 1 ug/1 SW-846 8260E 8/31/2013 15:29 KAC 3 Dibromochloromethane <1 l ug/1 SW-846 8260B 8/31/2013 15:29 KAC 1,2-Dibionio-3-Chloropropane <2 2 ug/l SW-846 8260B 8/31/2013 15:29 KAC . l,2-Dibrom0ethane(EDB) <1 I ug/l SW-846 8260B 8/31/2013 15:29 KAC Dibromomethane <2 2 ug/l SW-846 8260B 8/31/2013 15:29 KAC k 1,2-Dichlorobenzene <I I ug/1 SW-846 8260E 8/31/2013 15:29 KAC 1,3 Dichlorobenzene <] 1 ug/l SW-846 8260B 8/31/2013 15:29 KAC 1,4-Dichlorobenzene <1 1 ug/l SW-846 8260B 8/31/2013 15:29 KAC ` Dichlorodilluoromethane <5 5 ug/1 SW-846 8260E 8/31/2013 15:29 KAC s I,1-Dichloroethane <1 I ug/1 SW-846 8260B 8l31/2013 15:29 KAC . 1,2-Dichloroethane <1 1 ug/1 SW-846 8260B 8/31/2013 15:29 KAC ],I-Dichloroethene <1 I ug/1 SW-8468260B 8/31/2013 .15:29 KAC ` 1: cis-1,?_-Dichloroethene <1 1 ug/l SW-846 8260B 8/31/2013 15:29 KAC trans-1,2-Dichloroethylene <2 2 ug/1 SW-846 8260E 8/31/2013 15:29 KAC 1,2-Dichloropropane <1 1 ug/I SW-846 8260B 8/31/2013 15:29 KAC 1,3-Dichloropropane <1 1 110 SW-846 8260B 8/31/2013 15:29 KAC I 2,2-Dichloropropane <I I ug/l SW-846 8260B 8/31/2013 15:29 KAC k 1,1-Dichloropropene <1 I ugh SW-846 8260B 8/.31/2013 15:29 KAC Ethylbenzene <I 1 ug/1 SW-846 8260B 8/31/2013 15:29 KAC t,. .r: . J Page 6 of 7 R.I. Analytical Laboratori'es;,Inc: CERTIFICATE OF ANALYSIS Envirotech Laboratories, Ina Date Received: 8/28/2013 Work Order 0: 1308-18481 Sample# 001 SAMPLE DESCRIPTION: WW-132030 1780 MAIN ST. W.BARNSTABLE SAMPLE TYPE: GRAB SAMPLE DATE/TIME: 8/27/2013 a 12:05 SAMPLE DET. DATE/TIME PARAMETER IZESULTS LIMIT UNITS METHOD ANALYZED ANALYST llexachlorobutadiene <1 1 ug/l SW-8468260B 8/31/2013 15:29 -KAC Isopropylbenzene <1 1 ug/I SW-8468260B 8/31/2013 15:29 KAC p-Isopropyltoluene <1 I ug/l SW-846 8260B 8/31/2013 15:29 KAC Methylene Chloride <5 5 ug/I SW-846 8260B 8/31/2013 15:29 KAC Naphdialene <1 1 ug/l SW-846 8260B 8/31/2013 15:29 KAC n-Propylbenzene <1 I ug/l SW-846 8260B 8/31/2013 15:29 KAC Styrene <1 1 o/I etzr-84AR-)611i3-8/31/Z913 15-20- Yet: 1,1,1,2-Tetrachloroethane <1 1 ug/1 SW-8468260B 8/31/2013 15:29 KAC 1,1,2,2=retrachloroethane <1 1 ug/l SW-846 8260B 8/31/2013 15:29 KAC Tetrachloroethene <1 I ug/1 SW-846 8260B 8/31/2013 15:29 KAC Toluene <1 1 ug/1 SAT-846 8260B 8/31/2013 15:29 'KAC 1,2,3-Trichlorobenzene <1 1 ug/1 SW-846 8260B 8/31/2013 15:29 KAC 1,2,4-Trichlorobenzene <1 1 ug/1 SW-846 8260B 8/31/2013 15:29 KAC 1,1,1-Trichloroetlrane <1 1 ug/1 SW-8468260B 8/31/2013 15:29 KAC 1,1,2-Trichloroethane <1 1 ug/1 SW-846 8260B 8/31/2013 15:29 KAC Trichloroethene <1 1 ug/1 SW-846 8260B 8/31/2013 15:29 KAC Trichlorofluoromethane <1 1 ug/1 SW-846 8260B 8/31/2013 15:29 KAC 1,2,3-Tricliloropropane <2 2 ug/1 SW-846 8260B 8/31/2013 15:29 KAC 1,2,4=rrimethylbenzeue <1 1 ug/1 SW-8468260B 8/31/2013 15:29 KAC 1,3,5-Trimethylbenzene <1 I ug/1 SW-846 8260B 8/31/2013 15:29 KAC s Vinyl Chloride <1 1 ug/l SW-846 8260B 8/31/2013 15:29 KAC o-Xylene <1 1 ug/l SW-846 8260B 8/31/2013 15:29 KAC m,p-Xylene <7 1 ug/l SW-846 8260B 8/31/2013 15:29 KAC MTBE <2 2 ug/1 SW-846 8260B 8/31/2013 15:29 KAC Acetone <10 10 ug/l SW-846 8260B 8/31/2013 15:29 KAC Surrogates RANGE SW-846 8260B 8/31/2013 15;29 KAC Dibromofluoromethane 107 86-118% SW-846 8260B 8/31/2013 15:29 KAC Toluene-d8 97 88-110% SW-846 8260B 8/31/2013 15:29 KAC 4-Bromofluorobenzene 94 86-115% SW-846 8260B 8/31/2013 15:29 KAC 1,2 Dichloroethane-d4 97 80-120% SW-846 8260B 8/31/2013 15:29 KAC i Total Metals Mercury <0.0005 0.0005 mg/1 EPA245.1 8/30/2013 9:31 PJC Mercury Digestion EPA245.1 8/30/2013 9:12 JL 1 4 f t: t ^ ,1 c Page 2 of 2 R.I.Analytical.Laboratories, Inc, CERTIFICATE OFANALYSIS Envirotech Laboratories, Inc. Date Received: 8/20/2613 Work Order#: 1308-17844 Sample# 001 SAMPLE DESCRIPTION: WW-131905 OUTFALL SAMPLE TYPE: GRAB SAMPLE DATE/TIME: 8/01/2013 SAMPLE DET. DATE/TIME PARAMETER RESULTS LIMIT UNITS METHOD ANALYZED ANALYST TPH TPH GUM 450 110 ug/l SW846 8100M 8/23/2013 16:45 THY Surrogate RANGE SW-846 8100 8/23/2013 16:45 11113 2-Fluorobiphenyl 66 40-140% SW-846 8100 8/23/2013 16:45 THP Extraction date Extracted SW8463510 8/22/2013 21:00 MMM The sample was received at the laboratory outside of the recommended hold time for the TPH analysis. Fingerprint:Chromatogram best matches weuthered biodiesel fuel,possibly from vegetable oil sources. I 4 l 1 5 M N 3 i M1 l gg� I[; CHAIN OF CUSTODY FORM ENVIROTECH LABS, INC. RI Analytical 8 Jan Sebastian Dr Unit 12 M Rl 015 PWS: Project Name: Sandwich,MA 02563 Addn3ss 41 Illinois Avenue Sampler: P. Page (508)888-6460 Warwick, RI 02888 9 1-60039-6460 Phone# 401-737-8500 FAX(508)888-64" Fax 401-738-1976 Lab ID# Date :: Time Comp Grab Istation location DEP ID Container ' Pres: ._ Sample type Analysis requested WW-131905 0901113 NA X of ttail Glass H2SO4 Drinking Petroleum Fingerprint y -- Relin uiahed: pl;acm Received: Datelfime Received:in u hed• Received: Relinquished: Datel7ime Received: ,w -:CHAIN.-OF"CUSTODY FORM z h:x ENVIROTECH LABS,IN:C. Client: C . . ices 8 Jan Sebastian Dr., Unif 12 Proj. No. Project Name: Sandwich, MA 02563 Address: o d- Park (508)888-6460%1-800- 3n-6460 Sam ler: ­� - N e :, A 02031 ' p 'e @1 �'L _ FAX{50B1888-6446 Phone#: Fax#: Lab ID# Date: Time Comp GrabA. Sample Location container Pres. ` 13Igb� Analysis Requested LULU------------ S � F . r V e 1 Relinquished: Date/T'me ReceiveEE���L Reli uished: Y /5 )3 , '� DateTme Received:' Relinquished: Dat1 /5 Received: Relinquished: DateTme Rec6 ived: I Envirotech Laboratories, 8 Jan Sebastian Dr Unit 12 Sandwich, MA 02563 Inc (508) 888-6460 Fax(508) 888-6446 August 8, 2016 Patrick Page 1780 Main Street W.Barnstable, MA Dear Patrick, Samples taken by Envirotech Laboratories at different locations from sites located at 1780 Main Street West Barnstable, MA. Results: 8/27/13:Sample at discharge pipe located at 1780 Main Street showed E.coli 5,000 cfu/100ml,Total Petroleum hydrocarbons 850 ug/L,C19-C36 Aliphatics 210 ug/L, Di-n-butyl phthalate 15 ug/L. 8/27/13:Solid sample from old cranberry bog showed detection of Cadmium 0.14 mg/Kg dry wt., Chromium 7.90 mg/Kg dry wt.and Barium 13.7 mg/Kg dry wt. 12/24/15: Sample at Stone Well located off of route 6A at 1780 Main Street showed nitrate 3.49 mg/L, Total Nitrogen 6.1 mg/L,Aluminum 19.8mg/L. Results indicate that further investigation is recommended by a qualified environmental organization (i.e. DEP or EPA)or qualified environmental engineering company. Sincerely your , f1ddn460cast.net f Si F h; Uq ENVIROTECHLABORATORIES, INC. MA CERT. .NO.: M-MA 063 8 Jtttt Sebastian Drive Saadlvich, 41A 02563 (508)888-6460 1-800-339-6460 FAX(508)888-6446 Friday,January 08,2016 Page, Patrick 1780 Alain St by Bat•nslable, bf ProjectNarne: 1780 Main.A W Barnslable Comments: Project Number: Collection Date: 12124115 Collection Time: 09:55 Sampler/By: R Saari Lab Order Number: WTV-153151 Date Received: 12124115 r W�$-:,.'^.� !xL'.?,�`' �`+,�rfi-{t�,y��:rSf .� 7 ?s -Yiai`� k } ' w r� k`,b:,tij'" 'F't+.�"'S�"�.A''•Z?��'*' ww"'. Gx sr r �� t Rs� 3� �� �"� �"�t �,•fix � � �-� '�} 'rr :. a-y. � � � s �s` � 9 �y`z"� z" _ �, �rk�,.�a�;� �.�'�.,�..trc�3+1�:a��"ei�;a���� �..��a :�,��� .n^'r.;v,:��,�,,.u.�„^r" �.�,�.��� �i"��_�'_ ;�^`����� •+s a x '"," .:C Parameters Units Test Results Reportable Limits Date Analyzed Attalj+.rt A4et/iod Kjeldhal Nitrogen mg/L 2.6 0.6 01/06/16 KB SM4500 NH3 C Ammonia-N mg/L BRL 0.5 ol/05/16 KB SM4500 NH3 C Nitrate-N mg/L 5.49 0.01 12/24/15 RL 300.0 Nitrite-N mg/L BRL 0.006 12/24/15 RL 300.0 Total Nitrogen mg/L 6:1 NA 01/07/16 KB Calculation Total Phosphorous(P) mg/L 0.025 0.005 01/08/16 MC 4500-P Sodium-grab I mg/L 12.3 1.0 12/30/15 MC 200.7 Total Iron mg/L 24.1 0.01 12/30/15 MC 200.7 Manganese mg/L 0.55 0.005 12/30/15 MC 200.7 Aluminum mg/L 19.8 0.010 12/30/15 MC 200.7 Barium mg/L 0.15. 0.002 12/30/15 MC 200.7 Zinc mg/L 0.19 0.004 12/30/15 MC 200.7 Potassium mg/L 8.8 0.1 12/30/15 MC 200.7 . Magnesium mg/L 10.5 0.1 12/30/15 MC 200.7 EPFI/PAH ug/L ND* 01/05/16 RIA" MADEP VPH ug/L ND* 12/30/15 RIA` MADEP: BRL=below reportable/halts s c `'see attached t Ronald J. Sa7iri 7 Laboratory Director Page 1 of 1 R.I. ANALYTICAL Pagel of3 Specialists in Environmental Services CERTIFICATE OF ANALYSIS Envirotech Laboratories, Inc. Date Received: 12/28/2015 Attn: Mr. Ron Saari Date Reported: 1/7/2016 8 Jan Sebastian Drive P.O.#: Sandwich, MA 02563 Work Order#: 1512-28061 DESCRIPTION: PAGE, PATRICK 1780 MAIN STREET, W BARNSTABLE MA Subject sample(s)has/have been analyzed by our Warwick, RI laboratory with the attached results. Reference: All parameters were analyzed by U.S. EPA approved methodologies. The specific methodologies are listed in the methods column of the Certificate of Analysis, Data qualifiers (if present) are explained in full at the end of a given sample's analytical results. The Detection Limit is defined as the lowest level that can be reliably achieved during routine laboratory conditions. The Certificate of Analysis shall not be reproduced except in full,without written approval of R.I. Analytical. Results relate only to samples submitted to the laboratory for analysis. Test results are not blank corrected. Certification#(as applicable to the,sample's origin state): RI LAI0033,MA'M-RI015, CT PH-0508, ME RI00015, NH 2537,NY 11726 If you have any questions regarding this work, or if we may be of further assistance,please contact our customer service department. Approved by: t .enc: Chain of Custody r F• 41 Illinois Avenue,Warwick,RI 02888 131 Coolidge Street,Suite 105,Hudson,MA 0174.9 Phone:401.737.8500. Fax:401.738.19 www. .70 rianal Ytical.com Phone:978.568.0041 Fax:978.568.0078 r: Page 2 of 3 R.I. Analytical Laboratories,Inc. CERTIFICATE OF ANALYSIS Envirotech Laboratories,Inc. Date Received: 12/28/2015 Work Order#: 1512-28061 Sample# 001 ' SAMPLE DESCRIPTION: WW-153151 STONE WELL SAMPLE TYPE:GRAB SAMPLE DATE/TIME: 12/24/2015 a 09:55 SAMPLE DET. DATE/TIME PARAMETER RESULTS LIMIT UNITS METHOD ANALYZED ANALYST TPH TPH GC/F1D <100 t00 ug/l SW-846 8100M 1/6/2016 8:51 KS Surrogate RANGE SW-846 8100M 1/6/2016 8:51 KS 2-Fluorobiphenyl 63 40-140% SW-846 8100M 1/6/2016 8:51 KS Extraction Date SW-8463510C 12/30/2015 13:15 JPB VPH Unadjusted C5-C8 Aliphaties(FID) <100 100 ug/1 MADEP VPH-04-1.1 12/30/2015 16:02 KF Unadjusted C9-C12 Aliphatics(FID) <100 100 ug/1 MADEP VPH-04-1.I 12/30/2015 16:02 KF Adjusted C5-C8 Aliphatics(F1D) <100 100 ug/l MADEP VPH-04-1.1 12/30/2015 16:02 KF Adjusted C9-C12 Aliphaties(FID) <100 100 ug/1 MADEP VPH-04-1.1 12/30/2015 16:02 KF C9-CI0 Aromatics(PID) <100 100 ug/l MADEP VPH-04-1.1 12/30/2015 16:02 KF Target Aromatic Analytes 12/30/2015 16:02 KF Methyl-tert-butylether <5 5 ug/l MADEP VPH-04-1.1 12/30/2015 16:02 KF Benzene <5 5 ug/l MADEP VPH-04-1.1 12/30/2015 16:02 KF Toluene <5 5 ug/l MADEP VPH-04-1.1 12/30/2015 16:02 KF Ethylbenzene <5 5 ug/l MADEP VPH-04-1.1 12/30/2015 16:02 KF m,p-Xylene <5 5 ugA MADEP VPH-04-1.1 12/30/2015 16:02 KF o-Xylene <5 5 ug/1 MADEP VPH-04-1.1 12/30/2015 16:02 KF Naphthalene <5 5 ug/l MADEP VPH-04-1.1 12/30/2015 16:02 KF Sun-ogate RANGE 12/30/2015 16:02 KF 2,5-Dibroinotoluene(PID) 95 70-130% MADEP VPH-04-1.1 12/30/2015 16:02 KF 2,5-Dibroinotoluene(FID) 100 70-130% MADEP VPH-04-1.1 12/30/2015 16:02 KF EPH/PAH C9-C18Aliphalics <120 120 ug/1 MADEPEPH-04-1.1 1/5/2016 17:58 KS C19-C36 Aliphatics <120 120 ug/I MADEP EPH-04-1.1 1/5/2016 17:58 KS Unadj.CI1-C22 Aromatics <100 100 ug/l MADEP EPH-04-1.1 1/5/2016 17:58 KS 1 Adj.CI I-C22 Aromatics <100 100 ug/l MADEP EPH-04-1.1 1/5/2016 17:58 KS s t TARGET PAH ANALYTES r Naphthalene <5 5 ug/1 MADEP EPH-04-1.1 1/5/2016 17:58 KS 2-Methylnaphthalene <5 5 ug/l MADEP EPH-04-1.1 1/5/2016 17:58 KS Acenaphthylene <5 5 ug/l MADEP EPH-04-1.1 1/5/2016 17:58 KS Acenaphthene <5 5 ug/l MADEP EPH-04-1.1 1/5/2016 17:58 KS Fiuorene <5 5 ug/l MADEP EPH-04-1.1 1/5/2016 17:58 KS Phenanthrene <5 5 ug/l MADEPEPH-04-1.1 I/5/2016 17:58 KS Antluacenc <5 5 ug/1 MADEP EPH-04-1.1 1/5/2016 17:58 KS Fluoranthcne <5 5 ug/l MADEP EPH-04-1.1 1/5/2016 17:58 KS ' Pyrene <5 5 ug/1 MADEP EPH-04-1.1 1/5/2016 17:58 KS Benzo(a)anlhraccne <5 5 ug/l MADEP EPH-04-1.1 1/5/2016 17:58 KS Cluysene <5 5 ug/l MADEP EPH-04-1.1 1/5/2016 17:58 KS C I Page 3 of 3 R.I. Analytical Laboratories, Inc. CERTIFICATE OF ANALYSIS l;nvirotech Laboratories, Inc. Date Received: 12/28/2015 Work Order#: 1512-28061 Sample#. 001 SAMPLE DESCRIPTION: WW-153151 STONE WELL . SAMPLE TYPE:GRAB SAMPLE DATE/TIME: 12/24/2015 L 09:55 SAMPLE DET. DATE/TIME PARAMETER—' RESULTS LIMIT UNITS METHOD ANALYZED ANALYST Benzo(b)f]uoranthene <5 5 ug/1 MADEP EPH-04-1.1 1/5/2016 17:58 KS Benzo(k)fluoranthene <5 5 ug/1 MADEP EPH-04-I.1 1/5/2016 17:58 KS Benzo(a)pyrene <5 5 ug/1 MADEP EPH-04-1.1 1/5/2016 17:58 1(S Indeno(1,2,3-cd)pyrene <5 5 ug/1 MADEP EPH-04-1.1 1/5/2016 17:58 KS Dibenzo(a,h)antlu-acetic <5 5 ug/l� MADEP EPH-04-1.1 1/5/2016 17:58 KS Benzo(g,h,i)perylene <5 5 ug/1 MADEP EPH-04-1.1 1/5/2016 17:58 KS Extraction Sunogates RANGE 5-alpha-Androstane 73 40.140% MADEP EPH-04-1.1 1/5/2016 17:58 KS Ortho-terphenyl 85 40-140% MADEP EPH-04-I.I 1/5/2016 17:58 KS Fractionation Swrogates RANGE 2-Fluorobiphenyl 86 40-140% MADEP EPH-N-1.1 1/5/2016 17:58 KS 2-Bromonaphthalene 89 40-140% MADEP EPH-04-1.1 1/5/2016 17:58 KS TPH:Samplc does not exhibit a hydrocarbon pattern. i i t i k i S r CHAIN OF CUSTODY FORM ENVIROTECH LABS, INC. RI Analytical 8 Jan Sebastian Dr Unit 12 M Rl 015 - Project Name: Page, Patrick Sandwich, MA 02563 Address 41 Illinois Avenue 1780 Main Street,W. Barnstable, MA (508)888-6460 Warwick, RI 02888 Sampler: R. Saari 1-800-339-6460 Phone# 401-737-8500 FAX(508)888-6446 Fax# 401-738-1970 Lab ID# Date ITime Coml Grab Station location Container Pres. Sample p typ Analysis requested WW-153151 12/24/15 0955 X Stone Well I Glass H2SO4 Groudwater TPH fingerprint 2 VOA WC Groudwater VPH 2 Glass HCL Groudwater EPH/PAH Relinquished: Date/Time Received: 12-)&/s ilia � Contact lab with any exceeded MCL Relinquished: Datemme Received: CHAIN OF CUSTODY FORM EN1ilROTECH LABS, INC. RI Analytical 8 Jan Sebastian Dr Unit 12 M RI 016 Project Name: Page, Pabick Sandwich,MA 02563 Address 41 Illinois Avenue I 1780 main Street,W.Barnstable,MA (508)888-6460 Warwick, RI 02888 Sampler. R. Saari 1-800�39-6460 Phone# 401-737-8500 fAX(508)888-6446 Fax# 401-738-1970 Lab ID Date Time Come Grab Station location Container Pros... Sample typ Anal sis requested WW 1±53151 12/24H`5 0955 X Stone Well 1L Glass, H2SO4 Groudwater 4 TPH fingerprint I 2 VOA HCL Groudwater VPH 2 Glass HCL Groudwater EPH/PAH i f I14f:, Contact lab with any exceocled MCL / 1 r CHAIN OF CUSTODY FORM ENWIROTECH LABS, INC. Client: Patrick Page 8 Jan Sebastian Dr., Unit 12 Proj. No. Project Name: 1780 Main St W Barnstable Sandwich, MA 02563 Address: 1780 Main St (508)888-6460/1-800-339-6460 W. barnstable,MA 02668 Sampler: FAX(508)888-6446 Phone#: 608 280 7243 Fax M Lab ID# . , Dat Time Comp Grab Sample location container Pres. Analysis Requested Ve l� L L( U P v Relinquis Vd Date/Tim Receive Reliquished: Date/Time / Received: Relinquish d: Daterrime Received' Relinquished: Daterrime Received: ENVIROTECH LABORATORIES, INC. 1V1A CERT. NO.: M-MA 063 8 Jan Sebastian Drive Slnidwich,AZ4 02563 (508)888-6460 1-800-339-6460 FAX(508)888-6446 l,rirlay,September 27, 2013 Page, Palrick l 780 Adaln Sl W Barnstable, A4 Project'Natite: 1780 Mahe St YYBmislable Colttrnents: Rain event in AM Project Nnntber: Collection Dale: 08127113 Collection Tinte: 12:05 Saliipled By: •R Saori Lab Order Nianber: WTV-132030 Date Received.• 08/27/13 Sam le Type Sanpli Timex _ Sam 1c Dnte '�� ` t V s Con�unent� Y r T r t ' Discharge Pipe A 12 05` 08/27113 { a ` p`u ate' ' y lkn�butylPhthalate s Parameters Ullits, Test Results y Reportable Limits Date Analyzed Analyst A1ethod BOD 5-Day mg/L 4.1 3.0 08/28/13 MC 5210 B Kleldhal Nitrogen mg/L 0.8 0.6 09/09/13 KB SM4500 NH3 C Ammonia-N mg/L BRL 0.5 08/29/13 KB SM4500 NH3 C Nitrate-N mg1L 0.70 0.05 08/27/13 LL 300.0 Nitrite-N mg/L BRL 0.020 08/27/13 LL 300.0 Total Nitrogen mg/L 1.5 NA 09/23/13 RIA* Calculation Total Phosphorous(P) mg/L 0.20 0.013 09/25/13 MC 4500-P Chemical Oxygen Demand mg/L 63.8 5.0 09/04/13 MC Hach 8000 Total Organic Carbon` mg/L 15 D.5 08/29/13 RIA* SM 5310 C Volatile Organic Compounds" ug/L None Detected 0e/31/13 RIA* Total Iron mg/L 0.59 0.01 08/29/13 MC 200.7 Manganese mg/L 0.11 0.008 09/13/13 MC 200.7 Aluminum mg/L 0.99 0.010 09/13/13 MC .200.7 Silver mg/L BRL 0.002 09/13/13 MC 200.7 i Barium mg/L 0.018 0.002 09/13/13 MC 200.7 1 Cadmium mg/L BRL 0.001 Os/1.3I13 MC 200 7 [ Chromium mg/L BRL. 0.002 09/13/13. MC 200 7 Mercury' mglL <0.0005.. 0,0005: 08/30,/13 RIA* . .`: 2451 Selenium mg/L BRL 0.006 09/13/.1,3 MC 200.7 t Lead. mg/L BRL 0.006 'OW13/13 MC. 200.7 Copper mg/L 0.025 0.003- ;P5/29/13: .. ...... MC. 200.7 Zinc mg/L 0.098 0.004 09/13/13 d MC 20.0.7.:. f. Arsenic mg/L BRL 0.010 09/13/13 ;MC. 200.7 Petroleum Fingerprint` 850 o9/04/13 RIA* *. PCB 8080` "None Detected 09/04/13 "RIA SW-846 8082 BRL=heloiv reportable lindts *.Tee attaehed . By. Ron ilt/J`Sr ri Laborat r ireclor t Page 1 of 2 _ /i i ESS Laboratory BAL Laboratory Division of Thielscli Engineeting,Inc. ' -The ATicrobiologj,Division 1� \ ofThielsch Engineering,Inc. A CERTIFICATE OF ANALYSIS Data Reporting RI Analytical Laboratories, Inc. 41 Illinois Avenue Warwick,RI 02888 RE: RIAL Sampling-MCP(1308-18481) ESS Laboratory Work Order Number: 1308604 This signed Certificate of Analysis is our approved release of your analytical results. These results are only representative of sample aliquots received at the laboratory. ESS Laboratory expects its clients to follow all regulatory sampling guidelines. Beginning with this page, the entire report has been paginated. This report should not be copied except in full without the approval of the laboratory. Samples will be disposed of thirty days after the final report has been delivered. If you have any questions or concerns, please feel free to call our Customer Service Department. '� 'By ESS Laborat ry�at�20 amzS p�0�4,���'`0,1,,3R, Laurel Stoddard yt ... Laboratory Director Analytical Summary The project. as described above has been analyzed in accordance with the ESS Quality Assurance Plan. This plan utilizes the following methodologies: US EPA S W-846, US EPA Methods for Chemical Analysis of Water and Wastes per 40 CFR Part 136, APHA Standard Methods `for, the Examination of Water and Wastewater, American Society for Testing and Materials (ASTM), .and other recognized methodologies. The analyses with these noted observations are in conformance to the Quality Assurance Plan. In chromatographic analysis, manual integration is fi•equently used instead of automated integration because it produces more accurate results. The test results present in this report are in compliance with NELAC Standards, A2LA and/or client Quality Assurance Project Plans (QAPP). The laboratory has reviewed the following: Sample t Preservations, Hold Times, Initial Calibrations, Continuing Calibratins, Method Blanks, Blank Spikes, s Blank Spike Duplicates, Duplicates, Matrix Spikes, Matrix Spike Duplicates, Surrogates and internal Standards. Any results which were found to be outside of the recommended ranges. stated in our SOPs h will be noted in the Project Narrative. - F n 185 Frances Aeenue,Cranston,RI 02910-2211 Tel:401461 7181 Fax:401-461-4486 litto.//%�nvw.ESSLaboratory.coni Dependability 0 Quality 4 service Pam I of 12 fir. I ESS Laboratory BAL Laboratory Division ofTbielseb Engineeting,Inc. The11ficrobiologyDivision - 1 ofTbidsch En-Lucering,Inc. CERTIFICATE OF ANALYSIS Client Name: RI Analytical Laboratories,Inc. Client Project lD: RiAL Sampling-MCP ESS Laboratory Work Order: 1308604 SAMPLE RECEIPT The following samples were received on August 29,2013 for the analyses specified on the enclosed Chain of Custody Record. To achieve CAM compliance for MCP data, ESS Laboratory has performed and reviewed all QA/QC Requirements and Performance Standards listed in each method. Holding times and preservation have also been reviewed. All CAM requirements have been achieved unless noted in the project narrative. Each method has been set-up in the laboratory to reach required MCP standards. The methods for aqueous VOA and Soil Methanol VOA have known limitations for certain analytes. The regulatory standards may not be achieved due to these limitations. In addition, for all methods, matrix interferences, dilutions, and %Solids may elevate method reporting . limits above regulatory standards. ESS Laboratory can provide, upon request, a Data Checker (regulatory standard comparison spreadsneet)e ec ronic deliverable w plc i will highlight ttiese excee antes. For EPH soil samples, the aromatic range results have been corrected for identified cartridge contaminant in accordance with the CAM protocol. Lab Number SamnleName Matrix Analysis 1308604-01 1308-18481-001 Waste Water MADEPNPH { k 185 Frances Avenue,Cranston,FJ 02910-2211 Tel:401-461-7181 Fax:401-461-4486 htts:/h«inv.ESSLaboraton com Dependability 4 Quality 4 Service ih Pase 2 of 12 E S S Laboratory BAL Laboratory The_Microbiol d Division Division ofThielsch Engineering, Inc. °2' of T6ie/sch Lo giueerirg,Inc. AA - CERTIFICATE OF ANALYSTS Client Name: RI Analytical Laboratories,Inc. Client Project ID: RIAL Sampling-MCP ESS Laboratory Work Order: 1308604 PROJECT NARRATIVE No unusual observations noted. End of Project Narrative. DATA USABILITY LINKS Definitions ofOuality Control Parameters Semivolatile Organics Internal Standard Information Semivolatile Organics Surrogate Tnformation Volatile Organics Internal Standard Information Volatile Organics Surrogate Information EPH and VPH Alkane Lists 4 s f is E i 185 Frances Avenue,Cranston,RI 02910-2211 Tel:401461-7181 Fax:401-461-4496 httn:/hw%,Nv.ESSI,aboratory.com t Dependability Quality 4 Service l Paee 3 of 12 F= ESS Laboratory BAL Laboratory - . Division ofThielsch Engineering,Inc, The blicrobiolosj,Division - of Thiels-ch Ena incerin5,Inc. CERTIFICATE OF ANALYSIS Client Name: RI Analytical Laboratories,Inc, Client Project ID: RIAL Sampling-MCP ESS Laboratory Work Order: 1308604 CURRENT SW-846 METHODOLOGY VERSIONS Analytical Methods Prep Methods I O1 OA-Flashpoint 3005A-Aqueous ICP Digestion 6010C-ICP 3020A-Aqueous Graphite Furnace/ICP MS Digestion 6020A-1CP MS 3050B-Solid ICP/Graphite Furnace/ICP MS Digestion 7010 -Graphite Furnace 3060A-Solid Hexavalent Chromium Digestion 7196A-Hexavalent Chromium 3510C-Separatory Funnel Extraction 7470A-Aqueous Mercury 3520C-Liquid/Liquid Extraction 7471 B-Solid Mercury 3540C-Manual Soxhlet Extraction 3011 -EDB/DBCP/TCP 3541 -Automated Soxhlet Extraction 3015C-GRO/DRO 3580A-Waste Dilution 3 08 1 B-Pesticides 5030B-Aqueous Purge and Trap 9082A-PCB 5035 -Solid Purge and Trap 3100M-TPH ' —3I 5 tr' 3260B- VOA 3270D-SVOA 3270D SIM-SVOA Low Level 9014-Cyanide 9038-Sulfate 9040C-Aqueous pH 9045D-Solid pH(Corrosivity) 9050A-Specific Conductance 9056A-Anions(IC) 9060A-TOC , 9095E-Paint Filter MADEP 04-1.1 -EPH/VPH ( P; F w z d 185 Frances Avenue,Cranston,RI 02910-2211 Tel:401461-7181 Fax:4014614486 htto://«1"w.ESSLaboratory com Dependability 4 Quality 4 Service Page 4 of 12 r k - F ESS Laboratory. BAL Laboratory Division ofThiclsch Eiigiijeeting,lac. The Microbiology Division ( 7 S ofThie/sch Engineering,Inc. A CERTIFICATE OFANALPSIS Client Name: RI Analytical Laboratories,In(;. Client Project ID: RIAL Sampling-MCP. ESS Laboratory Work Order: 1308604 MassDEP Analytical Protocol Certification Forty MADEP RTN: Phis form provides certification for the following data set:1308604-01 Matrices: (X)Ground Water/Surface Water O Soil/Sediment ( )Drinking Water O Air O Other: CAM Protocol (check all that apply below): ( ) 8260 VOC ( ) 7470/7471 I-Ig (X) MassDEP VPH ( )8081 Pesticides ( ) 7196 Hex Cr ( ) MassDEP APH CAM 11 A CAM IIi B CAM IV A CAM V B CAM VI B CAM IX A ( ) 8270 SVOC ( ) 7010 Metals ( ) MassDEP EPH ( ) 8151 Herbicides ( ) 8330 Explosives ( ) TO-15 VOC CAM Il B CAM Ill C CAM IV B CAM V C CAM VII1 A CAM 1X B ( ) 6010 Metals ( ) 6020 Metals ( ) 8082 PCT3 (. ) 6860 Perchlorate ( ) 9014 Total C',yanide./PAC CAM ITT A CAM III D CAM V A CAM VIII B CAM VI A Affirmative responses to questions A through Fare required for Presumptive Certainty Vatus A Were all samples received in a condition consistent with those described on the Chain-of-Custody,properly Yes(X) No( ) preserved(including temperature)in the field or laboratory,and prepared/analynd within method holding times? B Were the analytical method(s)and all associated QC requirements specified in the selected CAM protocol(s) Yes(X) No( ) followed? C Were all required corrective actions and analytical response actions specified in the selected CAM protocol(s) Yes(X) No( ) implemented for all identified performance standard non-conformances? D Does the laboratory report comply with all the reporting requirements specified in the CAM VII A,"Quality Yes(X) No( ) Assurance and Quality Control Guidelines for the Acquisition and Reporting of Analytical Data"? C a.VPH,EPH,APH and TO-15 only:Was each method conducted without significant modification(s)?(Refer Yes(X) No( ) to the individual method(s)for a list of significant modifications). b.APH and TO-15 Methods only:Was the complete analyte list reported for each method? Yes( ) No( ) F Were all applicable CAM protocol QC and performance standard non-conformances identified and evaluated Yes(X) No( ) in a laboratory narrative(including all"No"responses to Questions A through E)? Responses to Questions C,H and I below are required for Presrutrptive Certair:ty'Ratus G Were the reporting limits at or below all CAM reporting limits specified in the selected CAM protocols(s)? Yes(X) No( )* Data User Note:Data that achieve Presumptive Certainty'Statuspiay not necessarily meet the data usability and representativeness requirements described in 310 CMR 40. 1056(2)(k)and TYSG07--350. H Were all QC performance standards specified in the CAM protocol(s)achieved? Yes(X) No( )* I Were results reported for the complete analyte list specified in the selected CAM protocol(s)? Yes(X) No( )* *A11 negative responses mist be addressed in an attached laboratory narrative. I,the undersigned,attest raider thepains and penalties ofperjnry that,based upon my personal inquiry of those responsible for obtaining the information,the material contained in this analytical report is,to.lhe.bestsof my knowledge and belief, accurate and complete Signature: Date: September 04,2013 Printed Name:Laurel Stoddard Position:Laboratory Director i 185 Frances Avenue,Cranston,RI 02910-2211 Tel:401461.7181 Fax:401-4614486 htto://h�rnNv.ESSLaboratorv.coni Dependability 4 Quality Service f Pape 5 of 12 s 4 ESS Laboratory BAL Laboratory Division of Engineering,Inc. The Microbio/000yDivision o' o z - � ofThielsch En mccr' Inc. 1 3r �, o CERTIFICATE OF ANALYSIS Client Name: RI Analytical Laboratories,Inc. Client Project ID: RIAL Sampling-MCP ESS Laboratory Work Order: 1308604 Client Sample ID: 1308-18481-001 ESS Laboratory Sample ID: 1308604-01 Date Sampled: 08/27/13 12:05 Sample Matrix: Waste Water Percent Solids: N/A Units:ug/L Initial Volume: 5 Analyst: NS Final Volume: 5 Extraction Method: 5030B MADE,P-VPH.Volatile Petroleum Hydrocarbon Anal to Results(MRL) MDL Method Limit DF Analyzed Sequence Batch C9-C10Aromatics ND(100) MADEP-VPFI 1 08/29/13 I1:38 CWH0374 CH32847 C5-C8 Aliphaticsl,2 ND(150) MADEP-VPH 1 08/29/13 11:38 [CALCJ CS-C8 Unadjusted Aliphatics ND(150) MADEP-VPH 1 08/29/13 11:38 CWH0374 CH32847 C9-C]2 Aliphatics2,3 ND(150) MADEP-VPH 1 08/29/13 11:38 [CALCJ C9-C12 Unadjusted Aliphatics ND(ISO) MADEP-VPH 1 08/29/13 11:38 CWH0374 CH32847 Benzene ND(1.5) MADEP-VPH 1 08/29/13 I1:38 CWH0374 CH32847 Glhylbenzene ND(5.0) MADEP-VPH 1 08/29/13 11:38 CWH0374 CF132847 Metliyl tert-Butyl Ether ND(1,5) MADEP-VPH 1 08/29/13 11:38 CWH0374 CH32847 Naphthalene ND(5.0) MADEP-VPH 1 08/29/13 11:38 CWH0374 CH32847 Toluene ND(5.0) MADEP-VPH 1 08/29/13 11:38 CWH0374 CH32847 Xylene 0 ND(5.0) MADEP-VPH 1 08/29/13 11:38 CWH0374 CH32847 Xylene PM ND(10.0) MADEP-VPH 1 08/29/13 11:38 CWH0374 CH32847 Preservative: pH<=2 MADEP-VPH CH32847 %Recovery QualiRer umlts Surrogate:2,5-Dibromotoluene-FID 92% 70-130 Surrogate:2,5-Dlbromotoluene-PID 100% 70-130 i 4 r I` I, i v 185 Frances Avenue,Cranston,IU 02910-2211 Tel:401461-7181 Fax:401-461-4486 htlp://il'15RY.ESSLaboratorV.eoni Dependability 4 Quality 4 Service Paee 6 of 12 - i �N ESS Laboratory BAL Laboratory Division of 7hielsch 1 Engineering, lix. The AficrobiologyDAdsion e ofThielsch E �ineerin - Inc. 4, K CERTIFICATE OF ANALYSIS Client Name: RI Analytical Laboratories,Tne. Client Project ID: RIAL Sampling-MCP ESS Laboratory Work Order: 1308604 Quality Control Data Spike Source %REC RPD Arialyte Result MRL Units Level Result %REC Limits RPD Limit Qualifier MADEP-VPH Volatile Petroleum Hydrocarbon Batch CH32847-503013 Blank 1,2,4-Trlmethylbenzene ND 5.0 y ug/L 2,2,4-Trimethylpentane NO 5.0 ug/L - 2-Methylpentane NO 5.0 ug/L Benzene NO 1.5 - ug/L :5-C8 Unadjusted Allphatics NO 150 ug/L -9-C10 Aromatic NO 100 ug/L -9-C12 Unadjusted Allphabc NO ISO ug/L Ethylbenzene NO 5.0 ug/L Methyl tert-Butyl Ether NO 1.5 ug/L " MD 5.0 UYJL rBuycyclohexane 5.8 5.0 ug/L i-Decane 6.3 510 ug/L Nonane(0) 8.6 5.0 ug/L Pentane NO 5.0 ug/L roluene NO 5.0 ug/L , Kylene 0 NO 5.0 ug/L Kylene P,M NO 10.0 ug/L Surrogate:2,5-Dlbromotoluene-FID 47.9 - ug/L 50.00 96 70.130 Surrogate 2,5-Dlbromotoluene-PID 51.7 ug/L 50.00 103 70-130 LCS 1,2,4-Trimethylben2ene 110 ug/L 100.0 110 70-130 2,2,4-Trimethylpentane 143 ug/L 150.0 95 70-130 2-Methylpentane 156 ug/L 15010 104 70-130 Benzene 53.8 ug/L 50.00 108 70-130 { -5-C8 Unadjusted Allphatics 399 ug/L 400.0 100 70-130 -9-CIO Aromatics 109 ug/L 100.0 109 70-130 j .t �9-C12 Unadjusted Allphatic 257 ug/L 300.0 86 70-130 ;2 Ethylbenrene 54.8 ugJL 50.00 110 70.130 Methyl tert-Butyl Ether 166 ug/L 150.0 111 70-130 Naphthalene 108 ug/L 100.0 108 70.130, } rButylcydohexane 77.7 ug/L 100.0 78 70-130 I' r Dea'me 88.1 ug/L 100.0 88 70.130 e Nonane(C9) 81.3 ug/L 100.0 81 30-130 Pentane 102 ug/L 100.0 102 70-130 roluene - 167 ug/L 150,0 111 70.130 i Kylene 0 112 ug/L 100.0 112 - 70-130 Kylene P,M 219 ug/L 200.0 110 70-130 Sumzgate:2,5 Dibromohzluene-FID 48.6 ug/L 50.00 97 70-130 57raogale:2,5-Dlbromotoluene-PID 53.7 ug/L 50.00 107 70-130 k' LCS Dup F 7 1,2,4-Trimethylbenzene 109 ug/L 10010 109 70-130 1 25 2,2,4-Trimethylpentane 139 ug/L 150.0 92 70-130 3 25 185 Frances Avenue,Cranston,RI 02910-2211 Tel:401461-7181 Fax:401-461-4486 httD://RM,Nv.ESSLaboratory cons Dependability # Quality 4 Service Paee 7 of 12 r ESS Laboratory BAL Laboratory Division ofThic1sch Engineering,Inc. The Microbiology,Division l nl of Thielsch Engineering,Inc. *AB CERTIFICATE OFANALESIS Client Name: RI Analytical Laboratories,Inc. Client Project ID: RIAL Sampluig-MCP ESS Laboratory Work Order: 1308604 Quality Control Data Spike Source %REC RPD Analyte Result MRL Units Level Result %REC Limits RPD Limit Qualifier MADEP-VPH Volatile Petroleum Hydrocarbon Batch CH32847-5030B 2-Methylpentane ISO ug/L 150.0 100 70.130 3 25 Benzene 52.8 ug/L 50.00 106 70-130 2 25 -5-C8 Unadjusted Allphatics 384 ug/L 100.0 96 70-130 4 25 -9-C10 Aromatics 104 ug/L 100.0 104 70-130 4 25 -9-C12 Unadjusted Allphattcs 238 ug/L 300.0 79 70.130 8 25 Ethylbenzene 54.7 lug/L 50.00 109 70-130 0.2 25 Methyl tert-Butyl Ether 161 ug/L 150.0 107 70-130 3 25. Naphthalene 101 ug/L 100.0 104 70.130 4 25 i-Butylcyclohexane 70.9 ug/L 100.0. 71 70-130 9 25 t-Decane 76A ug/L 100.0 76 70.130 15 25 nnan J[9,1 77 F q/1 inn n 7e 30 r30 rn 29 - Pentane 101 Ug/L 100.0 101 70-130 1 25 roluene 161 ug/L 150.0 109. 70.130 2 25 Xylene 0 112 ug/L 100.0 112 70-130 0.2 25 <ylene P,M 220 ug/L 200.0 110 70-130 0.1 25 Surrogate:1,5-Dtbromota/uene-FID Sl.l ug/L 50.00 101 70-130 5urra3a1e:7,5-0tbramotoluene-PID 59,5 ug/L S0.00 109 70-130 t I I. k i t k s Cf e 1 a 185 Frances Avenue,Cranston,RI 02910.2211 Tel:401461-7181 Fax:401-461-4486 hLV://RmNV.ESSLaboratory.com if Dependability Quality 4 Service k Paae 8 of 12 ESS Laboratory BAL Laboratory Division ofThielscb Engineeting, Inc. TheAlicrobiolo��Division ofThieisch Eggincermg,Inc. A CERTIFICATE OF ANAL 3'SIS Client Name: RI Analytical Laboratories, Inc. Client Project rD: RIA.L Sampling-MCP ESS Laboratory Work Order: 1308604 Notes and Definitions G-06 pH<=2 (i Analyte included in the analysis, but not detected ND Analyte NOT DETECTED at or above the MRL(LOQ),LOD for DoD Reports,MDL for J-Flagged Analytes dry Sample results reported on a dry weight basis RI)D Relative Percent Difference MDL Method Detection Limit MRL Method Reporting Limit LOD Limit of Detection LOQ Limit of Quantitation DL Detection Limit UV Initial Volume F/V Final Volume § Subcontracted analysis;see attached report 1 Mange result excludes concentrations of surrogates and/or internal standards eluting in that range. 2 Range result excludes concentrations of target analytes eluting in that range. 3 Range result excludes the concentration of the C9-C'10 aromatic ranvP Avg Results reported as a mathematical average. Mt. No Recovery [CALL] Calculated Analyte SUB Subcontracted analysis;see attached report i i 185 Frances Avenue,Cranston,RI 02910-2211 Tel:401-461-7181 Fax:401461-4486 htta_/_/ii,�%,Nv.ESSLaboratory,com Dependability 4 Quality 4 service Page 9 of 12 Lf , ESS Laboratory BAL Laboratory Division ofThic1sch Engineering, Inc. The Microbiolob-3,Division 1 A130I of Thielsch&Wr b Bering,Inc. A CERTIFICATE, OFANALYSIS Client Name: RI Analytical Laboratories;Inc. Client Project 1D: R1AL Sampling-MCP ESS Laboratory Work Order: 1308604 ESS LABORATORY CERTIFICATIONS AND ACCREDITATIONS ENVIRONMENTAL Department of Defense(DoD)Environmental Laboratory Accreditation Program(FLAP) A2LAAccredited:Testing Cert#2864.01 http•//www a2la ore/scopee6df/2864-01 pdf Rhode Island Potable and Non Potable Water:LAI00179 bttp://iv%viv.heaIth.r-i.gov/1abs/ivaterlabs-instate.plip Connecticut Potable.and Non Potable Water,Solid and Hazardous Waste:PH-0750 http://wwNv.ct.gov/dplVlib/dph/environmental health/environmental laboratories/pdf/OutofStateCommercialLaboratories pdf Maine Potable and Non Potable Water,and Solid and Hazardous Waste: RI0002 http://wivNv.maine.gov/dep/blwg/topie/vesseU[ab list pdf Massachusetts Potable and Non Potable Water:M-RIO02 http://Public.dep.st,,ate.ma.us/labcert/labeert.aspx New Hampshire(NELAP accredited)Potable and Non PotableWater,Solid and Hazardous Waste:2424 http://www4.e og v.rJi gov/des/nhelap/narnesea.rch asp New York(NELAP accredited)Non Potable Water,Solid and Hazardous Waste: 11313 http://www.wads%voiih org/labcert/elap/comm html New Jersey(NELAP accredited)Non Potable Water,Solid and Hazardous Waste:R1.006 http://datainine2.state.ni.us/dep/DEP OPRA/ ` United States Department of Agriculture Soil Permit:S-54210 Maryland Potable Water:301 http://vvwiv.mde.state.md.us/assets/documentfWSP labs-2009apr20_pdf CHEMISTRY H I A2LAAccredited:Testing Cert#2864,01 { Lead in Paint,Phthalates,Lead in Children's Metals Products(Including Jewelry) http://iv%v%Y.A2LA.org/dirsearchneFv/neivsearch.cfm CPSC ID# 1141 Lead Paint,Lead in Children's Metals Jewelry hM.'/hvNvw.cpsc.pov/cgi-bin/labapolist ash v 185 Frances Avenue,Cranston,RI 02910-2211 Tel:401461-7181 Fax:401-461-4486. http://iA,%tiv.ESSLaboratory.com ri Dependability Quality 4 Service �. Pape 10 of 12 Attachment B >arnple and Cooler Receipt Checklist SOP 10_0001 Client: RIAL ESS Project ID: 13080604 Client Project ID: Date Project Due: 9/3/13 t 3 Shipped/Delivered Via: Client Days For Projec D:47 [teens to be checked upon receipt: j 1. Air Bill Manifest Present? *No 10. Are the samples properly preserved: Yes Air No.: 11. Proper sample containers used? Yes 2. Were Custody Seals Present? No 12. Any air bubbles in the VOA vials? No 3. Were Custody Seals Intact? F-Ni-A-1 13. Holding times exceeded? No 4. Is Radiation count < 100 CPM? Yes 14. Sufficient sample volumes? Yes 5. Is a cooler present? Yes 15, Any Subcontracting needed? No Cooler Temp: 3.4 16. Are ESS labels on correct container aflNo Iced With: Ycepacks 17. Were samples received intact? a No 6, Was COC included with samples? Yes ESS Sample iDs: 7. Was COC signed and dated by client? Yes Sub Lab: 8. Does the COC match the sample Yes Analysis: 9. Is COC complete and correct? Yes TAT: 18, Was there need to call project manager to discuss status? If yes, please explain. Who was called?: By whom? Sample Number Properly Preserved Container Type #of Containers Preservative 1 Ye 40 ml-VOA 2 HCL } Completed By, DateMme: OZ' Reviewed By: Date/Time: a' Pan 11 of 12 4 ----------------------- . - A-ni viieal:Laborat6fi-,s= 41 Illinois Avenue 131 Coolidge St, Suite 105 Warwick, RI 02888-3007 Hudson,MA 01749-1331 Ei Te1:401-737-8500 Te1: 978-568-0041 0 Fax: 401-738-1970 Fax: 978-568-0078 0 0 v :':': •_: - . :. . ...:. .. • Collected: 'Coilected Our Sample IderitifIcatioiis'. Chi a l 8/27/13 12:05 1308-18481-001 vUW-132030 1780 Main St W Barnstable G 2V H WW X ;Send Re ort and Invoice To. _ _ Company: R,I. Anal ical Laboratories Inc. Subcontractor In;foxmation Address: 41 111inois Avenue Sub° °tractor: ESS Laboratory Cityl State I Zip: Warwick, RI 02888 Addre sLine 1: 185 Frances Ave Telephone: 8OO-937-2580 Addre s Line 2: Fax: 401-738-1970 Report To: Data Reporting city: Cranston state: R1 Zip: 02910-2211 Email: datareporting@rianalyticai.com T lephone: 401-461-7181 FAX: Coaraet for quetmioas Kristin Phelan ext: 116 401-461-4486 Emil: kphelan@rianalytical.corn R iagiiished By ...:-.. te: Received By_ : . . g Date Time.:._ r 3 _. Turn:Arotm d Time ro a� ad Norman: Z �730 X RUSH: 3-4 Business Days -,rTOject.Commenfs`' :.. NDtiSh Notes to e ;_... Subcontract (:p# 'Zg9.$Z r> Results due 9/4/13. Thank you. �, �-j Courier �S Laboratory: �� p�. DHL stainers:P=Poly,G=Gass,AG=Amber Glass,l/=Val,St=Sterile Presemat;vecq=g4=NH<CI,H=HCI, =MeOH N=Matri x Codes•GW=Groundwater,SW=Surface Water,WW=Wastewater, DW=Drinking Water,S=Soil,SL=Sludge,A=AIr ell,6=B'N=H O N=Swab,p= l=Narkordo: 0 ; ; , ; HNO�,NP-None,S=H2S0,,SB=NaHSOa,SH=NaOH,T=NazSiOa,Z=ZnOAc ---.------ Page 1 of 1 . 330-253-4489 02:32:06 p.m. 09-18-2013 6/7 m mmmly ENVIRONMENTAL TECHNOLOGIES, INC. September 17,2013 ' Analytical,Laboratories Client: Envirotech Laboratories,Inc. Address: 8 Jan Sebastian Dr unit 12 Sandwich,MA 02563 Received:8/30/2013 Project#:WW 132030 Client TDO Lab(Dt# Collected Anal a Result Units Matrix Method DF LOB( Run Analyst WW132030 1780 1314637-01 16-Jun-13 2,3,7,8-TCDD ND pg/1 L 1613B 2 1 16-Sep-13 CM Main St Page 4. t "Analytical Integrity-" EPA Certified NELAP Certified 3310 Win Street Cuyahoga Falls, Ohio 44223 • Phone:330-253-8211 • Fax: 330-253-4489 S Web Site:weww.settek.com y 9 i 330-253-4489 02:32:17 p.m. 09-18-2013 7/7 Summit Environmental Technologies, Inc. Method 1613 QC Report Batch ID: 1109 . ICAL Date : 5/2/2013 Extraction Date: 9/4/2013 Blank Results: 2,3,7,8-TCDD<1.0 pg/L Labeled Unlabeled Compound Compound % Recovery %Recovery 13C-2,3,7,8- 2,3,7,8- Analysis Parameter TCDD TCDD Date LCS 57.3 74.3 9/8/2013 Acceptance Limits 25-141 73-146 CCV1 99.5 95.8 9/16/2013 CCV2 102.6 107.9 9/16/2013 Acceptance Limits 85-117 82-123 Blank 48.4 9/8/2013 Acceptance Limits 25-164 Sample 1314637-01 39.1 9/16/2013 Acceptance Limits 25- 164 - I r. x h 4 330-253-4489 02:30:54 p.m, 09-18-2013 2/7 Rev. 12 I I�IIIII IIIIu III�I llll�lll�fill!u llll I��IIII III��IIIII IIIII IIIII IIIIIIIIIII(ll llll Date: 07/27/13 Summit Environmental Techr Order ID: 1314637 COOLER- Cooler Receipt For,,, r Initials of person Inspecting cooler and samples.--L Client:!'11 (11 1^e3� y�7 Order Number: Date Received:T Time Received: lc.L' cz c7 Date cooler(s)opened and samplesiinspected: L o� Number of Coolers/Boxes:_ N/A Shipper: FED EX UP$ DHL Airborne US Postal Walk-in Pickup Other: Packaging: Peanuts ubble Wrap Paper Foam None Other: Tape on cooler/box: ` ✓ N N/A Custody Seals Intact Y N/A C-O-C in plastic ( N N/A Ice lue Ice present / absent / etnl ted • N/A Sample Temperature IR Gun#16020459 CF C 16 .5 `°C N/A N/A (see page 2 for scan results) "*Use 1 sheet per sample for Radiological Testing, if sample is HOT,the Radiological Safety Officer must be notified Immediately. C-O-C filled out properly N N/A Samples In separate bags 6y�> N N/A Sample containers intact* ( Y� N N/A *If no,list broken sample(s): Sample label(s)complete(ID,date,etc.) OY N N/A Label(s)agree with C-O-C \ " N N/A Correct containers used N N/A Sufficient sample received N N/A Bubbles absent from 40 mL vials** Y N N/A :) **Samples with bubbles<6mm are acceptable. Indicate bubble size if>6mm. Was client contacted about samples Y N Will client send new samples Y N ' Client contact: i k Date/Time: I{: Logged In by: Comments: r K k f� t en M 11 4e e_. n___ • -rn 330-253-4489 02:31:14 p.m. 09-18-2013 3/7 I E I ENVIRONMENTAL TECHNOLOGIES,INC. Analytical Laboratories LABORATORY REPORT Client Envirotech Laboratories, inc. 8 Jan Sebastian Dr unit 12 Sandwich, MA 02563 Order Number 1314637 B rej e n tumbe r WW132030 issued Tuesday, September 17, 2013 Total Number of Pages 4 (excluding C.O.C. and cooler receipt form) a G Approved By : a QA Manager 4 Certifications; A2LA/DOD 0724.01,Alabama 41600,Arkansas 88-0735,California 07256CA,Colorado,Connecticut PH-0105, . Delaware,Florida NELAC E87688,Georgla E87688 and 943,Idaho OH00923,Illinois 200061 and Reg.5,Indiana C-OH-13,Kansas E-10347,Kentucky(underground Storage Tank)3,Kentucky 90146, Louisiana 04001 and LA12004,Maine 2012015,Maryland 339,Massachusetts M-OPH923,Michigan(Reg.S),Minnesota 409711, Montana CERT0099,New Hampshire 2996,New Jersey 01-1006,New York 11777,North Carolina 39705 and 631,Ohio 4170,Ohio VAP CL0052,Oklahoma 9940,Oregon OH2O0001,Pennsylvania 68-01335,Rhode Island tA000317,South Carolina 92016001,Tennessee TN04018,Texas T104704466-11-5,Region 5 WG-15J,Region E 8 8TMS-L,USDA/APHIS P330-11-00244,Utah OH009232011-1,Vermont VT-87688,Virginia 00440 and 1581, ' Washington C891,West Virginia 248 and 9957C and E87688,Wisconsin 399013010 "Analytical Integrity" EPA Certified - NELAP Certified 3310 Win Street CuyahogaTalis, Ohio 44223 • 'Phone: 330-253.8211 Fax:330.253-4489 Web Site:www.settek.com p ,a 330-253-4489 02:31:33p.m. 09-18-2013 4/7 wmMMIT LijENVIRONMENTAL TECHNOLOGIES, INC. Analytical Laboratories 2 Sample Summary Client: Envirotech Laboratories Inc. Order Number: 1314637 Laboratory ID Client ID Matrix Sampling Date 1314637-01 WWI 32030 1780 Main Liquid 6/16/2013 _ f t • 7 r . F 4 f a F6 . "Analytical integrity" EPA-Certified_'• NELAP Certified 3310 Win Street Cuyahoga-Falls, Ohio 44223 • Phone:330-253-8211 • Fax: 330-253-4489 Web Site:www.settek.com F 4 fa 330-253-4489 02:31:42 p.m. 09-18-2013 5/7 U A11h Agh r .001 IT 8 1 1 ENVIRONMENTAL TECHNOLOGIES, INC. Analytical Laboratories 3 Report Narrative Client: Envirotech Laboratories, Inc. Order Number: 1314637 No problems were encountered during analysis of this order number, except as noted. Method numbers, unless specified as SM or ASTM, are EPA methods. Method of analysis for TCLP Volatiles is 1311/8260B Method of analysis for TCLP Metals is 1311/6010B and 1311/7471A Method of analysis for TCLP BNA is 1311/8270C Data Quallfiers: B=Analyte found in the method blank J=Estimated concentration of analyte between MDL(LOD)and Reporting Limit(LOQ) C=Analyte has been confirmed by another instrument or method E=Analyte exceeds the upper limit of the calibration curve. Matrices: D=Sample or extract was analyzed at a higher dilution A=Air X=User defined data qualifier. C=Cream S=Surrogate out of control limits DW=Drinking Water U=Undetected L=Liquid a=Not Accredited by NELAC o=Oil St.=Sludge ND= Non Detected at LOQ SO=Soil DF=Dilution Factor S=Solid T=Tablet TC=TCLP Extract Limit Of Quantitation(LOQ)=Laboratory Reporting Limit(not adjusted for dilution factor) WW=Waste Water Limit Of Detection(LOD)=Method Detection Limit W=Wipe Practical Quantitation Limit(PQL)=(same as LOQ) ! Method Detection Limit(MDL)=(same as LOD). Reporting Detection Limit(RDL)=(same as LOD) Estimated uncertainty values are available upon request. The test results meet the requirements of the NELAC standard,except where noted. The information contained in this analytical report is the sole property of Summit Environmental Technologies,Inc.and that of the client. It cannot be reproduced in any form without the consent of Summit Environmental .echn.ologies, Inc.or..the.client.for.which this report was issued. The results contained in this report are only representative of the samples received. Conditions can vary at different times and at different sampling conditions. Summit Environmental Technologies,Inc.Is not responsible for use or Interpretation of the data included herein, "Analytical Integrity" EPA Certified • NELAP Certified 3310 Win Street - Cuyahoga Falls, Ohio 44223 • Phone: 3307253-8211 • Fax: 330-253-4489 Web Site;www.settek.com 1. 1 ATSDR-ToxFAQsTM:Di-n-butyI Phthalate Page I of 4 Agency for Toxic Substances & Disease Registry ToxFAQsTM for Di-n-butyl Phthalate (Di-n-butil ftalato) September 2001 CAS# 84-74-2 i PDF Version, 2s KB This fact sheet answers the most frequently asked health questions about di-n- butyl phthalate. For more information, you may call the ATSDR Information Center at 1-888-422-8737. This fact sheet is one in a series of summaries about hazardous substances and their health effects. This information is important because this substance may harm you. The effects.of exposure to any hazardous substance depend on the dose, the duration,how you are exposed,personal traits and habits, and whether other chemicals are present. Highlights Di-n-butyl phthalate is a iffdhufactured chemical that is added to plastics, paint, glue, hair spray,another household products..It is commonly found in the environment, and most people are exposed to low levels in the air, water, and food. No harmful effects have been found in humans. In laboratory animals, oral exposure to very high levels can cause impaired reproduction and developmental effects. This substance has been found in at least 471 of the 1,585 National Priorities List sites identified by.the Environmental Protection Agency(EPA). What is di-n-but phthalate? y. p Di-n-butyl phthalate is a manufactured chemical that ioes..not occur naturally. It is an odorless` and oily liquid that is colorless to faint yellow in color. It is slightly soluble in water-and does not evaporate easily. Di-n-butyl phthalate is used to make plastics more flexible-acid is also�in carpet backings, pantulue�insect ieellenta.,rhair_spray--nail polsh,and_rocket fuel'. What happens to di-n-butyl phthalate when it enters the environment? . Di-n-butyl phthalate is released to air as a vapor.It can react.with other chemicals in . . the air and is usually broken down within a few days. Di-n-butyl phthalate can also attach to particles in the air and eventually settle to the land and water. . Most of the di-n-butyl phthalate in water attaches to sediment and settles out of the water or is broken down by bacteria. Small amounts may evaporate to the air. When released to the soil, it attaches to soil particles and is broken down by bacteria. . There is no evidence that it builds up in the food chain. . s http://www.atsdr.cdc.Rov/toxfags/tf.asp?id=858&tid=167 9/23/2013 ATSDR-ToxFAQsTM: Di-n-butyl Phthalate Page 2 of 4 How might I be exposed to di-n-butyl phthalate? e Most people are probably exposed to low levels of di-n-butyl phthalate in the air because it is used in so many household products. People who use products which contain di-n-butyl phthalate, such as nail polish, may be exposed by breathing it in the air or getting it on their skin. . The general population.may also be exposed by eating food containing di-n-butyl phthalate, such as fish and shellfish, or food which is packaged or stored in materials containing di-n-butyl phthalate. . If you work or live near a factory where di-n-butyl phthalate is made or used,you could be exposed to higher than usual levels. o People living near uncontrolled hazardous waste sites may also be exposed to higher than usual levels of di-n-butyl phthalate. How can di-n-butyl phthalate affect my health? Di-n-butyl phthalate appears to have relatively low toxicity.Adverse effects have not been reported in humans as a result of exposure to di-n-butyl phthalate.. In laboratory animals, studies show that eating large amounts of di-n-butyl phthalate can affect their abilityto reproduce Sperm produc:Uap-can decrease,but r-au-irps to p.aar normal le-vels when exposure stops. Large amounts of di-n-butyl phthalate repeatedly applied to the skin for a long time can cause mild irritation.We do not know if similar effects would occur in humans. How likely is di-n-butyl phthalate to cause cancer? There have been no cancer studies in humans and the one study in laboratory animals is inadequate. The EPA has determined that di-n-butyl phthalate is not classifiable as to human carcinogenicity based on inadequate evidence in both humans and animals. How can di-n-butyl phthalate affect children? It is likely that health effects seen in children exposed to high levels of di-n-butyl phthalate will be similar to the effects seen in adults. We do not know_ whether-children differ from adults in their susceptibility to di-n-butyl phthalate. We do not know if exposure to di-n-butyl phthalate will result in birth defects or other developmental effects in people. Birth defects have been observed in laboratory animals exposed to high levels of di-n-butyl phthalate during development. Death,low body weights, skeletal effects, cleft palate, and damage to the testes have been observed in animals exposed during development. How can families reduce the risk of exposure to di-n-butyl phthalate? Di-n-butyl phthalate is used in many household products.The level of di=n-butyl phthalate in a product is higher when the product is new than when the product is old. Because di-n-butyl phthalate may be in some toys, children chewing on such toys could be exposed; however, no measurements have yet been made to show whether children are exposed in this way. E httt)://www.atsdr.cdc.Qov/toxfaas/tfasr)?id=858&tid=l67 9/23/2013 w ATSDR- ToxFAQsTM: Di-n-butyl Phthalate Page 3 of 4 Children should avoid playing in soils near uncontrolled hazardous waste sites where di-n- butyl phthalate may have been discarded. Is there a medical test to show whether I've been exposed to di-n- butyl phthalate? Tests are available to measure di-n-butyl phthalate in blood and body tissues, and its major breakdown products in urine. However, these tests cannot determine whether you will experience health effects or be used to predict the nature or severity of any effects. Because special equipment is needed, these tests are not usually done in the doctor's office. Has the federal government made recommendations to protect human health? The EPA recommends that levels of di-n-butyl phthalate in lakes and streams should be limited to 34 parts of di-n-butyl phthalate per million parts of wate (34�­,ppm),,to prevent possible human health effects from drinking water or eating fish contaminated with this chemical. The Occupational Safety and Health Administration (OSHA)has set a limit of 5 milligrams of di-n-butyl phthalate per cubic meter of g/ ace air(5 workplace m ma)for 8 hour shifts and 4o hour work weeks. References Agency for Toxic Substances and Disease Registry(ATSDR). 2001.Toxicological Profile for Di- n-butyl phthalate. Update.Atlanta; GA: U.S. Department of Health and Human Services, Public Health Service. Where can i get more information? If you have questions or concerns, please contact your community or state health or environmental quality department or: For more information, contact: , Agency for Toxic Substances and Disease Registry Division of Toxicology and Human Health Sciences 1600 Clifton Road NE, Mailstop F-57 Atlanta, GA 30333 Phone: 1-800-CDC-INFO . 888-232-6348 (M) Fax: 1-770-488-4178 Email: cdcinfo@cdc.gov r ATSDR can also tell you the location of occupational and environmental health clinics. These clinics specialize in recognizing, evaluating, and treating illnesses resulting from exposure to 4 hazardous substances. b Information line and technical assistance: Phone: 888-422-8737 z FAX: (770)-488-4178. . To order toxicological profiles, contact: Fs. i3 ki httn://www.atsdr.edc.gov/toxfaos/tf.asn?id=R5R&tid=167 ATSDR-ToxFAQSTM: Di-n-butyl Phthalate Page 4 of 4 National Technical Information Service. 5285 Port Royal Road Springfield,VA 22161 Phone: 800-553-6847 or 703-605-6000 Disclaimer All ATSDR Toxicological Profile, Public Health Statement and ToxFAQs PDF files are electronic conversions from paper copy or other electronic ASCII text files. This conversion may have resulted in character translation Or format errors. Users are referred to the original paper copy of the toxicological profile for the official text, figures, and tables. Original paper copies can be obtained via the directions on the toxicological profile home-page, which also contains other important information about the profiles. • Page last revievved:March 3,2011 • Page last updated:October 21,2oii • Content source:Agency for Toxic Substances and Disease Regis ........................................................................................................................................................................................................................................................................................................:.............................. Agency for Toxic Substances and Disease Registry,477o Buford Hwy NE, Atlanta,GA 30341 SA 90V � Contact CDC:800-232-4636/TTY: 888-232-6348 U}}Government Made Easy i http://www.atsdr.cd.e.gov/toxfaqs/tfasp?id=858&tid=l 67 9/23/2013 �O��NVIRON�y�y! 7 0 Cr m .c n yd �� 1l4rE of MA`�'c UNDERSTANDING EXTRACTABLE PETROLEUM HYDROCARBONS and VOLATILE PETROLEUM HYDROCARBONS WATER TEST RESULTS The purpose of this informational handout is to help you understand petroleum test results for your drinking water. The Maine Department ,of Environmental Protection [DEP] relies on laboratory tests called EPH [Extractable Petroleum Hydrocarbons] and VPH [Volatile Petroleum Hydrocarbons] to test for the presence of gasoline or fuel oil in drinking water. These tests provide information needed to determine if drinking water supplies near petroleum spills are contaminated with petroleum above health-based guidelines. Petroleum does not contain just one single compound [for example benzene], but many hundreds of compounds, all based on the chemistry of carbon and hydrogen. That is why petroleum compounds are commonly referred to as "hydrocarbons.". Some of the compounds contained in petroleum [again, for example benzene] are more harmful than others. The EPH and VPH tests identify concentrations of the more harmful compounds and those that are more abundant in fuels [called target compounds) and also identify all of the remaining petroleum hydrocarbons by grouping compounds with similar chemical properties and toxicity into "fractions" as shown on the table below. Each fraction has its own health guideline. EPH/VPH Defined Hydrocarbon Fractions Hydrocarbon Fraction - Analytical Method C9-C18 aliphatics EPH C19-C36 aliphatics EPH C11-C22 aromatics EPH C5-C8 aliphatics VPH C9-C12 ali hatics VPH C9-C10 aromatics VPH To determine the health risk from petroleum contamination i r n your water, DEP may have to use one or both tests. Our recommendations for testing depend on the type of petroleum product spilled as outlined in the t table below. Recommendations for EPH and VPH Testing Petroleum Product VPH EPH Gasoline X i Fresh diesel/#2 fuel oil X X Weathered diesel/#2 fuel oil X r #3-#6 fuel oils X Waste oil X X Jet fuels/kerosene X X r Mineral oil/dielectric oils X Unknown oils or sources X X i I To determine if a water supply is safe to use, the DEP compares sample results from these tests to a list of I health-based guidelines developed by the Maine Center for Disease Control and Prevention's [CDC's] I Environmental Toxicology Program. These guidelines are conservative and assume you will drink u approximately two quarts of water from this particular water supply every day for 70 years. Although EPH/VP,H test results are detailed and require explanation, these test methods do a better job of addressing the health implications of petroleum releases than previous [simpler] testing and allow the DEP to better determine appropriate actions.for protecting drinking water based on human health concerns. Below are explanations of the various sections of most laboratory reports. Result: Numbers contained in this column represent the concentration of target compounds and fractions detected in our water.v Compare these numbers to the drinking water guidelines in'the table below. Results above the guidelines indicate that the water may not be safe for regular use without treatment. Results less than the guidelines are generally considered to be safe for use. When test results are close to the drinking water guideline, the DEP may still wish to take measures to address the petroleum found. GUIDELINES FOR TARGET COMPOUNDS AND FRACTIONS Test Target Compound Guideline[ug/L or PPB] Benzene 4 Eth (benzene 30 Meth I-tert-but I ether MTBE 35 VPH Naphthalene 10 Toluene 600 Total x lenes 1,000 TEST Fractions: C5-C8 Aliphatic Hydrocarbons 300 C9-C12 Aliphatic Hydrocarbons 700 C9-C10 Aromatic Hydrocarbons 200 2-Meth ilLaphthalene 30 Acena hthene 1 400 Acena hth lene 400 Anthracene 2,000 PBeEnzo(g,hEj)peryIene oa ne 0.0 5 obanthene 0.5 200 EPH Benzo k fluoranthene 15 Chrysene 1 50 Dibenz a,h anthracene 0.05 �Fluoranthene 300TEST Fluorene 300 Indeno 1,2,3-cd rene 0.5 Na hthalene 10 Phenanthrene 200 P rene 200 ` Fractions: C9-C18 Aliphatic Hydrocarbons 700 F- C19-C36 Aliphatic Hydrocarbons 14,000 i k C11-C22 Aromatic Hydrocarbons 200 I G The analytical results section also contains the following information: • Range/Target Analyte: This is a list of the parameters that are included on the test. Note that unadjusted results should be iqnored. They are included only for DEP information purposes. • Surrogate %Recovery. Surrogate chemicals are added to the sample in the laboratory to determine the accuracy of the test. These chemicals were not found in your water. • RL [Reporting Limit]: The minimum concentration of a compound or a hydrocarbon fraction that the. laboratory will report. Concentrations less than this RL are reported out in the result column as "U" (undetected) or < [less than] the reporting limit, In some cases the laboratory will report an estimated concentration lower than the RL and flag the result with a "J"to indicate the number is estimated. • Units: How the sample was measured, usually in micrograms per liter [ug/1] or parts per billion [ppb] for r water samples. Micrograms per liter are comparable to parts per billion. For Further Assistance: If you have questions or need assistance understanding your petroleum test results and what they mean, please'call the DEP chemist at 207-287-7878. MITAn-Allysis Request / Chaiift -®f Cyst®d '° 'EtdVIROAIMENTALTECIiNOLpGtES, INC. � � N Er33 10 Win street For Summit EnvirontnentaI Technologies,Inc,use only `n Cuyahoga Falls,Ohio 44223 i II�IIIIIVIIIIIIIIIVIIII CIIIIIIalllf[IIIIIII�I�IIVIIIV�IiIIII 8100-270-0 140 co Client Name, Project Identification Envirotech Laboratories,Inc WW132030 IIIIII�IIIIIIIIIIII '` .h Client Address ` . Project Address t Order ID:_ 1314637 COC 8 Jan Sebastian D F r unit 12 Sandwich, MA 02563 1780 Main St W.Barnstable,MA. t Client Phone Report To 5088886460 Ron Saari Clicnt Par No. to Receive Results by Fnx PO Number 506 8886446 082713 ❑ Contact Person Quote Number Ron Saari :; "'~::. , : 2 . 'a: Sampled By R Saari if Ohio VAP Samples #- �� ."r,'.� :�._ ..�•• s�'.. - �,:=°-D,ati:'�;%F rak°'u. t.�.. rk.:iri:: :• =x'.,' f. A al" , 1-r:':'..• ,'7: O'.'G"Ilecfwt8i� • ;C3 f�:`:ur,�j' -'ra,rti;,.:; ,.Z.: Q WW132030 1780 Main St 06/16/26. .12:05 h L ice 2 XX 0 N W Q - W a r�'1':;ty: eT' i.• `"��i1t`i��'''•�A Er a�`- ,��-�=Ti :,:��a: -:; - ,:... _ - t3ie.. :. :ReceiveiF'6 - ^: ,> ,- :DAfcr= >•';• �,.',-i irii> `:'- Notes/Comments °O LS 12-3o o W �;;:;:ReceiVed'•io�LR6:b :'" f: "'•bdteF�` '•��r:�i?.Tiirt¢<=-_ . Rush Requested: Day(s) Must be approved by[.<�b Manager _ V CHAIN OF CUSTODY FORM ENVIROTECH LABS, INC. RI Analytical 8 Jan Sebastian Dr.Unit 12 M RI 015 _ PWS: Project Name: Page, Patrick Sandwich, MA 02563 Address 41 Illinois Avenue (508)888-6460 Warwick, RI 02888 Sampler: R. Saari 1-800-339-6460 Phone# 401-737-8500 FAX(508)888-6446 Fax# 401-738-1970 Lab ID# Date Time Comp Grab IStation location DEP ID. Container Pres. Sample type Analysis requested WW-132030 08/27/13 1205 X 1780 Main St. W Barnstable Wastewater EPA 625 2� ;-'';.�` Wastewater EPFi with PAH C !i Wastewater PCB 608 P6,,+i<- YzSc Wastewater -TOC C LaA-� 45-4 Wastewater Petroleum Scan Z Ups}- Wastewater EPA 8260 PIa� G /j�D .Wastewater Hg ZU04 tkZ. _ Wastewater VPH Call._Lab with any 'Exceeded;MCL - Relinquished: Date/T' a Recei d: Religuished: Date/Time Received: 13 �3" Relin uishe / Date/Time Received: Relinquished: Date/Time Received: CHAIN OF CUSTODY FORM ENVIROTECH LABS, INC. Client: Patrick Page 8 Jan Sebastian Dr., Unit 12 Proj. No. Project Name: 1780 Maid St W Barnstable Sandwich, MA 02563 I Address: 1780 Main St (508)888-6460/1-800-339-646 W. bamstable,MA 02668 Sampler: ` FAX 508 8884446 P�71 Phonet€: 508 280 7243 a Fax#: dab°ID. , Dake Time comp Grad ati Sample locon` container Pros. Analysis Requested f -12Q EPA 625 L EPH with PAH PC B � Total N� BOD CO D T C U C�ZS I� Petroleum Scan VDL �Ct EPA 8260 I) RECRA 8 metals I CA (( r Relingiished' Datofrlm Received- Reliquished: Datefrime ' f _ Received: IqID RelinGujShed: % DatelFime Received: Relinquished: Datefrime Received: Attachment B ;ample and Cooler Receipt Checklist SOP 10_0001 Client: RIAL ESS Project ID: 13080604 Client Project ID: Date Project Due: 9/3/13 Shipped/Delivered Via; Client Days For Projec€� items to be checked upon receipt: 1. Air Bill Manifest Present? FT No 10. Are the samples properly preserved, Yes Air No.: 11. Proper sample containers used? FYes 2. Were Custody Seals Present? No 12. Any air bubbles in the VOA vials? No 3. Were Custody Seals Intact? NIA 13. Holding times exceeded? No 4. Is Radiation count < 100 CPM? Yes 14. Sufficient sample volumes? Yes 5. Is a cooler present? Yes 15. Any Subcontracting needed? No Cooler Temp: 3.4 16. Are ESS labels on correct container e lNo Iced With: Ice packs 17. Were samples received intact? a No 6. Was COC Included with samples? Yes ESS Sample IDs: 7. Was COC signed and dated by client? Yes Sub Lab: 8. Does the COC match the sample Yes Analysis: 9. Is COC complete and correct? Yes TAT: 18. Was there need to call project manager to discuss status? If yes, please explain. Who was called?: By whom? Sample Number Properly Preserved Container Type #of Containers Preservative 1 Ye 40 ml-VOA 2 HCL Completed By: Date/Time: 0� Reviewed By: Date/Time: 'p- L15P O F IE VM' ti Page I of 12 4 330-253-4489 02:31:14 p.m. 09-18-2013 3/7 SUMMIN ENVIRONMENTAL TECHNOLOGIES, INC. Analytical Laboratories LABORATORY REPORT Client Envirotech Laboratories, Inc. 8 Jan Sebastian Dr unit 12 Sandwich, MA 02563 Order Number 1314637 Project Number WW132030 Issued Tuesday, September 17, 2013 Total Number of Pages, 4 (excluding C.O.C. and cooler receipt form) Approved By : i QA Manager k Cerfifications; A2LA/DOD 0724.01,Alabama 41600,Arkansas 88-0735,California 07256CA,Colorado,Connecticut PH-0105, Delaware,Florida NELAC E87688,Georgia E87688 and 943,Idaho OH00923,Illinois 200061 and Reg.5,Indiana C-OH-13,Kansas E-10347,Kentucky(underground Storage Tank)3,Kentucky 90146, Louisiana 04061 and =. LA12004,Maine 2012015,Maryland 339,Massachusetts M-OPH923,Michigan(Reg.5),Minnesota 409711, Montana CERT0099,New Hampshire 2996,New Jersey OH006,New York 11777,North Carolina 39705 and 631,Ohio 4170,Ohio VAP CL0052,Oklahoma 9940,Oregon OH2O0001,Pennsylvania 68-01335,Rhode Island LA000317,South Carolina 92016001,Tennessee TN04018,Texas T104704466-11-5,Region 5 WG-15J,Region 8 8TMS-L,USDA/APHIS P330-11-00244,Utah OH009232011-1,Vermont Vr-87688,Virginia 00440 and 1581, Washington C891,West Virginia 248 and 9957C and E87688,Wisconsin 399013010 k "Analytical Integrity" - EPA Certified - NELAP'Certified 3310 Win Street Cuyahoga Falls, Ohio 44223 - Phone: 330-253-8211 Fax: 330-253-4489 Web Site:www.settek.com r 330-253-4489 02:31:33 p.m. 09-18-2013 4/7 K;M00PI am Am am Am IT ENVIRONMENTAL TECHNOLOGIES, INC. LLJ Analytical Laboratories 2 Sample Summary Client: Envirotech Laboratories, Inc. Order Number: 1314637 Laboratory ID Client ID Matrix Sampling Date 1314637-01 WW132030 1780 Main Liquid 6/16/2013 i f fff 1 "Analytical Integrity" EPA Certified NELAP Certified 3310 Win Street - Cuyahoga Falls, Ohio 44223 . Phone:330-253-8211 Fax: 330-253-4489 Web Site;www.settek.com c 330-253-4489 02:31:42p.m. 09-18-2013 5/7 sp—qu, ISUMMIMT III I ENVIRONMENTAL TECHNOLOGIES, INC. Analytical Laboratories 3 Report Narrative Client: Envirotech Laboratories. Inc. Order Number: 1314637 No problems were encountered during analysis of this order number, except as noted. Method numbers, unless specified as SM or ASTM, are EPA methods. Method of analysis for TCLP Volatiles is 1311/8260B Method of analysis for TCLP Metals is 1311/6010B and 1311/7471A Method of analysis for TCLP BNA is 1311/8270C Data Qualifiers: B=Analyte found in the method blank J=Estimated concentration of analyte between MDL(LOD)and Reporting Limit(LOQ) C=Analyte has been confirmed by another instrument or method E=Analyte exceeds the upper limit of the calibration curve. Matrices: D=Sample or extract was analyzed at a higher dilution A=Air X=User defined data qualifier. C=Cre am S=Surrogate out of control limits DW=Drinking Water U=Undetected L=Liquid a=Not Accredited by NELAC O=oil SL=Sludge ND= Non Detected at LOQ SO=Soil DF=Dilution Factor S=Solid T=Tablet TC=TCLP Extract Limit Of Quantitation(LOQ)=Laboratory Reporting Limit(not adjusted for dilution factor) W/y=Waste Water Limit Of Detection(LOD)=Method Detection Limit W=Wipe Practical Quantitation Limit(PQL)=(same as LOQ) Method Detection Limit(MDL)=(same as LOD) Reporting Detection Limit(RDL)=(same as LOD) Estimated uncertainty values are available upon request. The test results meet the requirements of the NELAC standard,except where noted. The information contained in this analytical report is the sole property of Summit Environmental Technologies,Inc.and that of the client. It cannot be reproduced in any form without the consent of Summit Environmental Technologies, Inc.or the client for which this report was Issued. The results contained in this report are only representative.of the samples received. Conditions can vary at different times and at different sampling conditions. Summit Environmental Technologies,Inc,is not responsible for use or Interpretation of the data included herein. ' r I` I; "Analytical Integrity" EPA Certified NELAP Certified 3310 Win Street Cuyahoga Falls, Ohio 44223 • Phone:330-253-8211 • Fax: 330-253-4489 Web Site:www.settek.com i? . t a 330-253-4489 02:32:06 p.m. 09-18-2013 6/7 Adwk� gook an r=0012 SummIT ENVIRONMENTAL TECHNOLOGIES, INC. September 17,2013 Analytical Laboratories Client:Envirotech Laboratories,Inc. Address: 8 Jan Sebastian Dr unit 12 Sandwich,MA 02563 Received:8/30/2013 Project#:WW 132030 Client D Lab IMi/ cQiiecte Anal Result Units Matrix Method DF LOg Run Analyst, WW132030 1780 1314637-01 16-)un-13 2,3,7,8-TCDD ND pg/I L 1613B 2 1 16-Sep-13 CM Main St Page 4 E s" "Analytical Integrity" EPA Certified NELAP Certified 3310 Win Street • Cuyahoga Falls, Ohio 44223 • Phone: 330-253-8211 • Fax: 330-253-4489 Web Site:wwwsettek.com Y 330-2531-4489 02:32:17 p.m, 09-18-2013 7/7 Summit Environmental Technologies, Inc. Method 1613 QC Report Batch ID: 1109 ]CAL date : 5/2/2013 Extraction Date: 9/4/2013 Blank Results: 2,3,7,8-TCDD < 1.0 pg/L Labeled Unlabeled Compound Compound % Recovery % Recovery 13C-2,3,7,8- 2,3,7,8- Analysis Parameter TCD'D TCDD Date LCS 57.3 74.3 9/8/2013 LCSD 58.8 75.2 Acceptance Limits 25-141 73-146 CCV1 99.5 95.8 9/16/2013 CCV2 102.6 107.9 9/16/2013 Acceptance Limits 85-117 82-123 Blank 48.4 9/8/2013 Acceptance Limits 25- 164 Sample 1314637-01 39.1 9/16/2013 Acceptance Limits 25- 164 x r t i r+ j r f. Rev. 12 II�IIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIII�I� IIIIIIIIIIIIIII�IIIIIIIIfIIIIIIIIIIIIIIIIIII Date: 07/27/13 Order I®: 1314637 COOLER Summit Environmental Techr CooW Receipt Force, ( Initials of person inspecting cooler and samples:_ Client:�(,Jj r0l�ed% 'V� �s_e Order Number: Date Received:$/ 4 Time Received: (rJ ' 0 Date cooler(s)opened and samples inspected:-�_ Number of Coolers/Boxes: N/A Shipper: FED EX UPS DHL Airborne US Postal Walk-in Pickup Other: Packaging: Peanuts ubble Wrap Paper Foam None Other: Tape on cooler/box: Y N N/A Custody Seals intact Y N/A C-O-C in plastic N N/A Ice lue ice present / absent / elted N/A Sample Temperature IR Gun#16020459 CF c-t- lzo 'C 1 6 1 °C N/A Radiological Testing Instrument serial#35127 Y N N/A (see page 2 for scan results) Use 1 sheet per sample for Radiological Testing, If sample is HOT,the Radiological Safety Officer must be notified Immediately. C-O-C filled out properly l N N/A Samples in separate bags t Y> N N/A Sample containers Intact* t N NIA *If no,list broken sample(s): Sample label(s)complete(ID,date,etc.) t Y N N/A Label(s)agree with C-O-C \ ' N N/A Correct containers used N N/A Y Sufficient sample received ` V N N/A Bubbles absent from 40 mL vials** Y N N/A **Samples with bubbles<6mm are acceptable. Indicate bubble size if>6mm. Was client contacted about samples Y N Will client send new samples Y N Client contact: Date/Time: Logged in by: I Comments: i i f. G:\QC SHARED\Document Control Templates-Tracking\Cooler receipt form Rev. 12 07-27-13.doc Page 1 of 2. (S 330-253-4489 02:30:54 p.m. 09-18-2013 2/7 Rev. 12 IIIIIIIIIIIIIIIIIIIIIIIIIiiII�IIINIIII Illllllllllllllllllilllllillllll�illllllll Date:07/27/13 Summit Environmental Techr Order ID: 1314637 COOLER Cooler Receipt Fors„ 0 Initials of person Inspecting cooler and samples: L O Client:Cn ,��r�csa��/P,,L���� Order Number: Date Received Time Received: !2 ' 0y Date cooler(s)opened and samples Inspected: _ Number of Coolers/Boxes:. I I WA Shipper: FED FCC UPS DHL Airborne US Postal Walk-In Pickup, Other: Packaging: Peanuts ubble Wrap Paper .Foam None Other: Tape on cooler/box: ` ✓ N NIA Custody Seals Intact YY N/A C-O-C in plastic (lr N�� N/A Ice lue Ice > present / absent / rid ' N/A Sample Temperature IR Gun#16020459 CF m- °C °C N/A Radiological Testing Instrument serial#f35127 Y N N/A (see page 2 for scan results) "Use 1 sheet per sample for Radiological Testing, If sample is HOT,the Radiological Safety Officer must be notified Immediately. C-O-C filled out properly 1 ✓ N N/A Samples in separate bags t✓ N NIA Sample containers Intact' ' / > N NIA 'If no,list broken sample(s): Sample label(s)complete(ID,date,etc.) `✓ N N/A Label(s)agree with C-O-C l ' N N/A Correct containers used Y N N/A I, Sufficient sample received N N/A I Bubbles absent from 40 mL vlals" Y N N/A Samples with bubbles<6mm are acceptable. Indicate bubble size if>6mm. a Was client contacted about samples .Y N Will client send new samples Y N Client contact: Date/Time: Logged In by: Comments: f 1. r' /'_`•1(1!`CLJADGh1t1....n...nn1 h....�...1 T..m..ln/..,. T.....W....1/^....t....n....;..i t...-..C..., d1 f1�•f7 Ae ems_ n___� _in -C: N O]F': CIT _ ECZS :.... _ (5 •13 U ical:Laboratores Iris 41 Illinois Avenue w 131 Coolidge St, Suite 105 o Warwick, RI 02888-3007 Hudson,Iv1A 01749-1331 E u x Tel:401-737-8500 Tel: 978-568-0041 UI o j Fax: 401-738-1970 Fax: 978-568-0078 v X Date :::::.:•:::;Time:'. •`r..' i ``:,';. ...` . •'.:. .• o _ I Collected "Collected Oiir Sample Identifications .: �! a IL 8127113 12:05 1308-18481-001 ww-132030 1780 Main St 2V H vvvv Barnstable X t -Send Re drt and Invoice To. Subcontractor Information'::'company: R.I. Analytical Laboratories Inc. subcontractor: ESS Laboratory Address: 41 Illinois Avenue- _ Address Line 1: 185 Frances Ave City/State/Zip: Warwick, RI 02888 Address Line 2: Telephone: 800-937-2580 Fax 401-738-1970 city: Cranston state: Report To: Data Reporting RI zip: 02910_2211 p g Email: data repo Telephone: 401-461-7181 FAx: 401-461-4486 Contact for questions: Krisfin Phelan ext: 116 Emaik, kphelan@rianalytical.com R inquished By ... ._.. D. ate: Time, Received By. .' : Date'- Time.:' Turn:AroundTiine , odd Normal: Business Days ro a4 ,3a z 5130 X RUSH: 3-4 Business Days X oject.Comments' :.. :.. Date Shipped::--- Notes to X Courier UPS Subcontract p Q#'; g:9'$2`'<>` Results due 9/4/13. Thank you. 2, q '`� P``� Laboratory: c� :..................... 1' FedEx DHL 8t2�f r? I X On Ice 1 ; ; Containers P=Poly,G=Glass,AG=Amber Glass,V=Vial,St--Sterile Preservatives: Workorder No: A=Ascorbic Acid,NH4=NH4CI,H=HCI,M=MeOH,N=HNO3,NP=None,S=H2SO4,SB=NaHSO4.SH=NaOH,T=Na2SZ03,Z=ZnOAc Matrix Codes:GW=Groundwater,SW=Surface Water,WW=Wastewater,DW=Drinking Water,S=Soil,Sl-=Sludge,A=Alr Cell,B=Bulk/Solid,SB=Swab,O= Page 1 of 1 . mMMIT � analysis Request / Chain of Custod ENVIRONMENTAL TECHNOLOGIES. INC. y 331 O WIn Sireet For Summit Environmental Technologies,Inc.use only Cuyahoga falls,Ohio 44223 e00_2713_0140 Illlllllllllllilllllllll IIIIIIIIIIIIIIIIIIlIIIIIIIIIIIIIIIIIIIIIII Client Name Project Identification Envirotech Laboratories, Inc WWI32030 IIIIIIIIIIIIIIIIIIII Client Address Projecl Address 8 Jan Sebastian Dr unit 12 Sandwich, MA ', Order ID: 1314637 co 02563 1780 Main St W.Barnstable, MA. Client Phone Report To 508 888 6460 Ron Saari ;® Client Fax No. V to Receive Results by Pax PO Number 508 888 6446 ❑ 082713 Contact Person �. Quote Number Ron Saari .� c •o Sampled By R Saari ❑ if Ohio VAP Samples o ,. Date # �, Samplel}denttcatlon Tlmc x C'nllected WW132030 1780 Main St 06/16/26. 12:06 XL _ ice 2 XX by . Da a :Time "Rccei�cel,9w Date. I itnc ._, Notes/Cor,nncnts: 1-S IZ7 v Q � Rec'elved,tn:LaU by"_ '.Date Tune r,Rush Requested: DaY(s). Must be approved by Lab Manager l i ENVIROTECHLABORATORIES, INC. MA CER T. NO.: M-MA 063 8 Jan Sebastian Drive Sandivicltr MA 02563 (508)888-6460 1-800-339-6460 FAX(508)888-6446 Trresda,,September 24, 2013 Page, Patrick 1780 11,fain Si W Barnstable, M ProjectNrnne: 1780 Merin St TV Bcn'nstable Corrrnrerrls: Projecl Number Collection Date: 08127113 Collection Pine: 12:15 Sanipled By: R Saor•i Lab Order Nlnnber: TYW-132032 Date Received: 08127113 Sample Type Santple.Tilire. Snriile Dale Conriuerrts Old Cranberry bog exiA 12 1.5 08/27/13.,.. Mud Sample Parameters Uilits Test Results Reportable Limits Dare Analyzed Analyst Method PCB 8080` ND` 08/31/13 RIA` SW-846 8082 Lead mg/Kg dry BRL 0.6 09/20/13 MC 200.7 Cadmium mg/Kg dry 0.14 0.2 O9I20/13 MC 200.7 Chromium mg/Kg dry 7.90 0.2 09/20/13 MC 200.7 Mercury` mg/Kg dry <0.070" 08/29/13 RIA` Sliver mg/Kg dry BRL 0.2 09/20/13 MC 200.7 Selenium mg/Kg dry BRL 1.0 09/20/13 MC 200.7 Arsenic mg/Kg dry BRL 1.0 09/20/13 MC 200.7 Barium mg/Kg dry 13.7 0.2 09/20/13 MC 200.7 Total Petroleum Hydrocarbons" mg/Kg dry 100' 08/30/13 RIA' SW 8468100M BRL=below reportable limits *see adached � By: i Rona d J. Saadl Laboratory D rector I Page 1 of 1 i } t J � ®I . NALYT' AL Page 1 of Specialists in Environmental Services CERTIFICATE OF ANALYSIS Envirotech Laboratories, Inc. Date Received: 8/28/2013 Attn: Mr. Ron Saari Date Reported: 9/3/2013 8 Jan Sebastian Drive P.O. #: Sandwich, NIA 02563 Work Order#: 1308-18482 DESCRIPTION: PAGE, PATRICK Subject sample(s) has/have been analyzed by our Warwick, R.I. laboratory with the attached results.- / Reference:-All parameters were analyzed by U.S.`EPA approved methodologies. The specific methodologies are listed in the,methods column of the Certificate of Analysis, Data qualifiers (if present) are explained in fill at the end of a given sample's analytical results. Me Certificate of Analysis shall not be reproduced except in full,without written approval of R.I. Analytical. Results relate only to samples submitted to the laboratory for analysis. Test results are not blank corrected: Certification#: RI-033, MA-RIO15, CT-PH-0508,ME-RI015 NH-253700 A& B, USDA 5-41844 If you have any questions regarding this work, or if we may be of further assistance, please contact our customer e deU ent. Approv d by: Sh ron B ker i MI' /Da eporti r en.c: Chain of Custody r: r" 3, 4 41 Illinois Avenue,Warwick,RI 02888 131 Coolidge Street,Suite 105,Hudson,MA 01749 www.rianaly�ical.com Phone:401:737.8500.Fax:401.738.1970 y Phone:978.568.0041 Fax;978.568.0078 Page 2 of 2 R.I. Analytical Laboratories, Inc. CERTIFICATE OF ANALYSIS Envirotech Laboratories,Inc. Date Received: 8/28/2013 Work Order#: 1308-18482 Sample# 001 SAMPLE DESCRIPTION: WW-132032 1780 MAIN ST. W.BARNS'IABLF SAMPLE TYPE: GRAB SAMPLE DATE/TIME: 8/27/2013 @ 12:15 SAMPLE DET. DATE/TIME PARAMETER RESULTS LIMIT UNITS METHOD ANALYZED ANALYST TPH TPH GC/FID l00 14 mg/kg dry SW846 8,100M 8/30/2013 13:39 THP Surrogate RANGE SW-846 8100 8/30/2013 13:39 THP 2-Fluorobiphenyl 65 40-140% SW-846 8100 8/30/2013 13:39 THP Moisture 30 % SM2540 G. 8/29/2013 13:58 JRW Aroclor-1016 <0.1 0.1 mg/kg dry SW-846 8082 8/31/2013 16:59 JEB Aroclor-1221 <0.1 .0.1 mg/kg dry SW-846 8082 8/31/2013 16:59 JEB Aroclor-1232 <0.1 0.1 mg/kg dry SW-846 8082 8/31/2013 16:59 JEB Aroclor-1242 <0.1 0.1 mg/kg dry SW-846 8082 8/31/2013 16:59 JEB Aroclor-1248 <0.1 0.1 mg/kg dry SW-846 8082 8/31/2013 16:59 JEB Aroclor-1254 <0.1 0.1 mg/kg dry SW-846 8082 8/31/2013 16:59 JEB Aroclor-1260 <0.1 0.1 mg/kg dry SW-846 8082 8/31/2013 16:59 JEB I Surrogate RANGE SW-846 8082 8/31/2013 16:59 JEB Telrachloro-nrxylene(TCMX) 76 30-150% SW-846 8082 8/31/2013 16:59 JEB Decachlorobiphenyl 79 30-150% SW-846 8082 8/31/2013 16:59 JEB Extraction date SW8463540 8/29/2013 9:25 JRG t TOTAL METALS Mercury <0.070 0.070 mg/kg dry SW-846 7471A 8/29/2013 12:44 JRW Mercury Digestion SW-846 7471A 8/29/2013 12:02 PJC s i is e t i ppp� b i 4 M it F. CHAIN OF CUSTODY FORM ENVIROTECH LABS, INC. RI Analytical 8 Jan Sebastian Dr Unit 12 M RI 015 PWS: Project Name: Page, Patrick Sandwich, MA 02563 Address 41 Illinois Avenue (508)888-6460 Warwick, RI 02888 Sampler: R. Saari 1-800-339-6460 Phone# 401-737-8500 FAX(508)888-6446 Fax# 401-738-1970 Lab ID# Date Time Comp Grab IStation location DEP ID Container Pres. Sample type Analysis requested WW-132032 08/27/13 1215 X 11780 Main St.W Barnstable Plastic soil PCB 608 Plastic soil Petroleum Scan Plastic ' soil Hg Call Lab wsth any, Exceeded:MCL_ _� •� Relinquished: j ffDatd/Tim Receive Reliauished: DateMme Received: Relin uis `2d: Received: Relinquished: DateTme Received: _ r- CHAIN OF CUSTODY FORM ENVIROTECH LABS, INC. Client: Patrick Page 8 Jan Sebastian Dr., Unit 12 Proj. No. Project Name: 1780 Main St W Barnstable Sandwich, MA 02563 Address: 1780 Main St (508)888-6460/1-800-339-646 �� W. barnstable,MA 02668 Sampler: FAX(508)888-6446 Phone#: 508 280 7243 Fax#: Lab ID# Date Time Compyg4b Sample location container Pres. Analysis Requested 0u1<3 h3Z-- 08/27/13 Lc f_ Old Cranberry bog exit soil PCB Petroleum Scan RECRA 8 metals i Relinquishe Date/T' e IK(/"/ Receive Reliquished: Daterrime Received: Relin ished Da(./rime/ Received: Relinquished: Daterrime Received: -----Original Message- From: Brezinski,Brezinski, Paul Sent:Thursday, October 19, 2017 6:31 AM To:Woods, Bruce<Woods.Bruce@epa.gov> Subject: FW: Emailing:Trench 9-22 &9-28-17,8-29-17 outfall bact,8-7-17 ditch,8-13-17 discharge pipe,8-1-13 outfall Bruce, The attached are related to a complaint we have in MA. There is an outflow pipe that discharges onto a residential property. The property owner had tests done and the tests are attached. The matter will be referred to the Agency. I am not well versed in what exactly these results are showing. Not sure if you would be able to add anything to the results attached to this email but any input would be appreciated. Thanks. Paul Paul A. Brezinski Resident Agent in Charge New York Post of Duty United States Environmental Protection Agency Office of Inspector General Office of Investigations 290 Broadway,Suite 1S20 New York, NY 10007 212-637-3033 (Office) 917-359-2535.(Mobile) To report fraud,waste or abuse impacting EPA, please contact the EPA OIG Hotline via telephone numbers 202-566- 2476 or 888-546-8740,fax 202-566-2599,or email at oig_hotline@epa.gov To report threats directed against EPA employees,contractors,facilities and assets,please emailreport.EPA.threats@epa.gov -----Original Message----- From: Ron Saari [mailto:rsenviro@comcast.net] Sent: Wednesday, October 18, 2017 11:43 AM To: Brezinski, Paul<Brezinski.Paul@epa.gov> Cc: pagecarpentry66@gmail.com Subject: Emailing:Trench 9-22&9-28-17,8-29-17 outfall bact, 8-7-17 ditch,8-13-17 discharge pipe,8-1-13 outfall Your message is ready to be sent with the following file or link attachments: Trench 9-22&9-28-17 8-29-17 outfall bact 8-7-17 ditch 8-13-17 discharge pipe 8-1-13 outfall 2 Note:To protect against computer viruses, e-mail programs may prevent sending or receiving certain types of file attachments. Check your e-mail security settings to determine how attachments are handled.- 3 a uptp�&�6 Barnstable TOWN OF BARNSTABf U-MMca NY BARMSTABU. • OFFICE OF TOWN ATTORNEY I MASS. a 9° 2639• , 367 MAIN STREET °ArEDM�a HYANNIS, MASSACHUSETTS 02601-3907 2007 RUTH J.WEIL,Town Attorney ruth.weil@town.barnstable.ma.us T. DAVID HOUGHTON, 1st Assistant Town Attorney david.houghton @town.barnstable.ma.us CHARLES S. McLAUGHLIN,JR.,Assistant Town Attorney Charles.mclaughIin@town.barnstable.ma.us CLAIRE R. GRIFFEN, Paralegal/Legal Assistant April 13, 2009 claire.griffen@town.barnstable.ma.us PAMELA D.GORDON, Legal Clerk TEL.508-862-4620 •FAX.508-862-4724 Ms.Jane Saunders Mr. Patrick F. Page 1780 Main Street, Route 6A West Barnstable, MA 02668-1137 Re: 1780 Route 6A and 21 Buttonwood Lane Our File Ref: #2006-0223 - Dear Jane and Patrick: Following several telephone conferences March 30 and April 8'and 9, I left it with Patrick that his suggestion that Jane would apply for an additional lot at 1780 before going ahead with 21 Buttonwood was a good idea. I was speaking with Tom Geller about another matter and he didn't think that was a bad idea either. I did tell Patrick that we would keep the offer open on 21 Buttonwood while 1780 went forward. Since Jane is not under.any prohibitions, she can contact the folks at 200 Main if she has questions about the process for 1780. To recap, when I spoke with you both on March 30 we talked about setting up a meeting with staff about 21 Buttonwood. Since I didn't hear back right away after I called on April 3, 1 did discuss 21 Buttonwood with Tom McKean and Rob Gatewood on April 7. The consensus was that 21 Buttonwood had a good chance of getting standard wetlands conditions with growback mitigation, a perc test in the C2 layer in test pit number 7 and engineered plans. I even expressed a willingness to contact BSC. The idea was that this would end the war between you and the Town. When I spoke to Patrick on April 8 he said in addition he wanted either compensation or an additional buildable lot at 1780. I said I wouldn't recommend compensation nor linking dividing 1780 to permitting 21. He called back on the 9th and that when he mentioned dividing 1780 first. 20060223 pageletter15 This changes the previous standing offer(see letter dated Feburary 5, 2009) to meet with Rob, but I agree that it makes sense. There aren't any legal issues with 1780 so you can proceed without my involvement. In fact, I can't and won't be involved, so calls to our office should cease and Jane can deal directly with the folks at 200 Main. Best wishes for success. Sincerely, /tdh T. DAVID HOUGHTON cc: Tom Geiler Rob Gatewood Tom McKean 20060223 pageletter15 d o COPY10/ TOWN OF BAR14STABLE LOCATICN SEWAGE # 3a -.�PILLAGE � •A S SSOMAPR'S MP F� LOT �. KENNEDY TRUCKING INSTALLER'S NAME & PHONE NO. 575 WILLOW STREET WEST LARNSTAKl N,ASS, 02668.:._, SEPTIC TANK CAPACITY +` TEL. 362.30m LEACHING FACILITTY:(twe) — (size) ' $, NO. OF BEDROOMS PRIVATE WELL OR nUBLIC WATER BUILDER OR OWNER ' DATE PERMIT ISSUED: —14 DATE COtiPLIANCE ISSUED- VARIANCE GRANTED: Yes r No �` QQ � t• tF � �t M+�•�r i.. 3� 41 q2. .13. O F He4lfA Cop Y IODQ Jb al �AjXj� s J�a Fimx THE COMMONWEALTH OF MASSACHUSETTS BOARD OF HEALTH Application is hereby made for a Permit to Construct or Repair an Individual Sewage Disposal ............. ft. 4z,".............................................................................................. � System at: Location Address or Lot No. � � Own ............. . ... ..... ,, A 'X/ dof Building Size Lot............................Sq. feet 04 Other—Type of Building ._-_---.............. No. of persons............................ Showers ( ) -- Cafeteria ( ) � Other fixtures Deu6ro Flum------.------_'----_.gallons per person per day. Total daily flow---x�~049�'A���----.gallons. Septic Tank—Liquid ..gallons Length................ Width................ Diameter................ Depth................ Disposal Trench--No .................... Width.................... Total .................... Total area....................ug fc Seepage Pit No..................... Diameter.................... Depth below inlet.................... Total leaching area..................sq. ft. Z Other Distribution box ( ) Dosing tank ( ) ' ~~ Percolation Test Reao8u Ierf000edhy----.-.-------- - --------- Dutc------------------' �Tes Pit No. l-----_minutes per inch Depth of Test Pit.................... Depth to ur000dwatcr-------_ 44 Test Pb No. 2................minutes per inch Depth of Test Pit--------- Depth ro ground water------------------------ ---------- __' 0 Description of | '---------------'-------------'--------'--'-----'--'---'---'-'-----'-'----'----'- � U Nutoreof Repairs or Alterations—Answer when, licable -_-_''-'''' ' ''g'___-'. _ ~ The undersigned agrees to install the aforedescribed Individual Sewage Disposal System in accordance with the provisions of'ITlE 5 ofdeStateSanitaryCode— I} e undersigned further agrees not m place the system in operation until u Certificate of Compliance ha be issued by the bo�rd of health. � Signed ~_ � - -------'-- -'----.�atApplication Approved �--'.__' By.................. ................................ ----'.�-�-K��- = � ~ Date Application Disapproved for the following reasons:.............................................................................................................. - ......................................................................................................................................................................................................... Permit c,. No.. c' - _3g. FE$....... ,. . ..... THE COMMONWEALTH OF MASSACHUSETTS BOARD OF HEALTH ...................... ...................OF...................... .........._.... Appliration for Uiapu.ial Works Tnmuurtinn Famit Application is hereby made for a Permit to Construct ( ) or Repair ( ) an Individual Sewage Disposal System at: .............LZ&... ....6_ ..... :-., o. .---------.................--------...-- Location-Address or Lot No. • ..... a ...... �y Ow ------------------- -__!Fiddrrvc :. �I�!LC/°� ._. Installer Address gype of Building Size Lot...............:------------Sq. feet aDwelling—No. of Bedrooms.._._`.....................................Expansion Attic ( ) Garbage Grinder ( ) WOther—Type of Building ............................ No. of persons............................ Showers ( ) — Cafeteria ( ) P4Other fixtures -----------------------------------------------------------•-•-•••......--------------- -------------------•--•••---�..._. W Design Flow................v..........................gallons per person per day. Total daily flow......... ._____..gallons. WSeptic Tank—Liquid capacity�'':(*----gallons Length---------------- Width................ Diameter................ Depth................ x Disposal Trench—No..................... Width.................... Total Length.........._......... Total leaching area....................sq. ft. Seepage Pit No--------------------- Diameter................_--- Depth below inlet.................... Total leaching area..................sq. ft. Z Other Distribution box ( ) Dosing tank ( ) 1.4 Percolation Test Results Performed by.......................................................................... Date........................................ Test Pit No. 1................minutes per inch Depth of Test Pit.................... Depth to ground water........................ (� Test Pit No. 2................minutes per inch Depth of Test Pit-_-_____-__.__------ Depth to ground water-------:................ 119---------- Description of Soil........... . . .................... .. . f x -------------------------•-----------------------------------------------------•.---- U .........................................................--------------------------------------------------•------------------------------------------------------------------....--------•............ W UNature of Repairs or Alterations,—Answer when a• icable... ........................................................................................... •-------- ----------------------•-----•••••••------•---•--•••-••-••......•••--•......._....._.... Agreement: The undersigned agrees to install the aforedescribed Individual Sewage Disposal System in accordance with the provisions of l yT .,. p }of the State Sanitary Code—The undersigned further agrees not to place the system in operation until a Certificate of Compliance has be issued by the board of health. 14 Signed _..........., --------------------------.-.--.•.-.-................•----- .. .. ... % Application Approved BY Dat . V.- ��Z�- Date Application Disapproved for the following reasons---------------------------------------------------------------------------------------------------------------_ ........----•---••-••---•••--•-•....•---•...............••••-•----------------••-------••••-•------••••-------•--••-••--•-••-••-•••-------------------•-•-•---•----------•--•••-•------•••-....._---•-- Date PermitNo.----- ------------------------ Issued....................................................... THE COMMONWEALTH OF MASSACHUSETTS BOARD OF HEALTH .............O F............... ? � ry...... ................................ TrrtifirFatr of TiantpliFanrr THIS IS T,CERTIFY That the Individual Sewage Disposal System constructed ( ) or Repaired ( } by -- •--------------------- ............. ._�................................................................................................................................... Installer at-•-•---•--••-•••••47--ir.0.........At......... .-n............ram /'.1." ................................................ has been installed in accordance with the provisions of TITIZ 5 of The State Sanitary Code as described in the application for Disposal Works Construction Permit No........Fl_.:....L_11,1:2...... dated-------------------------------------------•---. THE ISSUANCE OF THIS CERTIFICATE SHALL NOT BE CONSTRUED AS A GUARANTEE THAT THE SYSTEM WILL FUNCTION SAT SFACTPPY DATE...................... ..:..T•..................... Inspector_...__.... ........................................... THE COMMONWEALTH OF MASSACHUSETTS 'BOARD OF HEALTH ,\ ...... all�t-�............OF.......... ���?��Y1+......................................... No.....V,r /..�£�-- FEE.....��?..... Disposal Iforks 0,41ntrnrtion rrntit Permission is hereby granted........... ...........ice^'""`"1 --------------------------------------------------------••--...................--•-- to Construct ( ) or Repair >1 an Individual Sewage Disposal System atNo........... --? -..r'------ .. ------ ,!�-------kn.,f --------------------•------------------------------------------.----------.-- Street as shown on the application for Disposal Works Construction Permit No.4,1:_l3Q.._ Dated.......................................... ................................ ...................................................... Board of Health DATE--- !�-------------�-------�- .-17 .................................... .FORM 1255 HOBBS & WARREN. INC.. PUBLISHERS