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0499 BEARSE'S WAY - HAZMAT
Is-0s - Poo I AI/17� Y ' I=PR 09 '91 16:53 HAVILArID C'Ot,19_IMER PD P.c/ a MATERIAL SAFETY DATA SHEET LITHIUM HYPOCFdLORITE. VAPOR DENSITY Qi r=l ) . . . . . . . . . Not Appl icabls SOLUB141TVIN H20. . . . . . . . . . . . . 4Z wt. C 25-C (77-F) APPEARANCE/ODOR. . . . . . . . . . . . . . . White Granules: Buro4ng- l i ka Chlorine ©do; SPECIFIC GRAVITY 020=0 . . . . . . 0- 1-19m/= F'H. . . . . . . . . . . . . . . . . . . . . . . . . . . 1l Slurry G 25-0 Ill SECT T�ION IV,..,_..,....��__-.._FIRE AND �..._..,.....-...r=EXPLOSION TMHAZARD WDATA ::.., FLASH�PQ I NT. . . . . . . . . . . . . . . . . . . . . . . . Not Flammable LOWER EXPLOSIVE LIMIT { by Volume) Not Applicab0 UPPER EXPLOSIVE LIMIT (I by Volume) Nct Applicable EXTINGUISH MEDIA— . . . . . . . . . . . . . . . . Any suitable +orR ?; re in surrounding area. SPECIAL FIRE FIGHTING PROCEDURES. — Wear 5el f-contained breatni ng apparatus and lull fire fighting protective clothing, UNUSUAL FIRE Ht'-1 ARD. . . . . . . . . . . . . . . . F=i'.roid cnf;ta : with C,_7muL'sa'.ible organicsubsti;9.mpe--. Firef...•nuld rus.Tilt, . oxy���j.an and toxic ahlocide gas may be released when heated , or when a ontac-ted with strong .acids. May catch spontaneously y o;i z of t{;.:'iC`,t with oxidizable materials. SECTION V - HEALTH HAZARD DATA CAPXCIhdOaEt+tICI Tel. . . . . . . . . . . . . . . None NTR. . . . . . . . . . . . . . . . . . . . . . . . . . No IpRC. . . . . . . . . . . . . . . . . . . . . . . . . . No OVER EXPOSURE EFFECTSi . . . . . . ; . Chemical burns of eyes and skin. PRIMARY ROUTE KS) OF ENTRY- - Eye and Skin Contact FIRST AID PROCEDURES. , .. . . . . . . . In case of contact; Immediately wash eyes and skin with plenty of water. if i ,haled: Remove to tr esh a&4 > - wallowed: Drink two glasses of water and see a physician. Do not induce vomiting. NOte to Physician: Product i s a,� eye irritant and corrosive to the skin. Treatment goal dilution and removal ; gastric lavage may be use+ul ?or ingestion exposure as emesis may produce esophageal damage. Treatment is otherwise symptomatic and supportive. EXPOSURE AGGRAVATED MEDICAL CONDITIONS None Curr snt l y Known SECTION VI - REACTIVITY DATA CHEMICAL ETABILITY. . . . . . . . . . . . Stahl: CONDITIONS TO AVCID , . . . . . . . . . Heat , moisture and organic matter. 1' �_ I ��� r r-� �. APR 09 '91 16:54 HAVILA1,T1 COrISUMER PD P.3/7 MATERIAW SAFETY DATA SHEET LITHIUM HYPOCHLORITE INCOMPAT&LE MATERIALS. . . . . . �, Acids, ammonia, organic matter and reducing agents DEC0MPQSjTION PRODUCTS. — . — Chlorinat trichlaroamine. HAZARDOUS POLYMEallOTIOM. . . . . . Will Not Occur POLYMERIZATION AVOID. . . . . . . . . . Not APPlicable SECTION VII - SPILL OR LEAK PROCEDURE FOR SPILL . . . . . . . . . . . . . . . . . . . - Sweep up and transfQr into clean dry drum and label or tag. WASTE DISPCSAL METHOD. . . . . . . . . Return to drum and dispose zcwQrding to iederall state and local regulations. SECTION V I I I - SPECIAL PROTECTION RESPIRATORY PROTECTION. . . . . . . . Wear x NIcSH/mSHA approved ruspirator whot-, ad2qUOtO vantilstion is not avzilabla. VENTILATION. . . . . . . . . . . . . . . . . . . Use only with zdaquate vantilatiQn. PROTECTIVE SLOPE,..:. . . . . . . . . . . . . Rubber or Other imParvicus myttrials- EYE PP07ECTION. . . . . . . . . . . . . . . . Chemical splash ProQi 90991ev. OTHER PROTECTIVE EKIPMENT. . . . A saiety showar and &ya bnih should bE available. For eperations where spills or splashing may occur , use an imperviovs body covering and boots. HANDLING AND Protect from m0sture and : haat. StorQ in cool , dry place. SECTION IX - SPECIAL PRECAUTIONS HAZARD CLASS. . . . . . . . . . . . . . . . . . Oxidi2er DOT SHIPPING NAME— - — . . . . — Lithium Hypowhicritai my UN NUMBER- - a . . . . . . . . I . . . . . . UN14711, REPORTABLE QUANTITY NOt Listed REFERENCES HM10 H-&;P-0;R-1 22ILTHYP SPACARE PH UP S1 MATERIAL SAFETY DATA SHEET This MSDS is being provided to your company for the purpose of pro- viding current health and safety information to your management and for your employees who work with this material . Please read the information on these sheets, and then provide this information to those people at your company whose responsibility it is to comply with FEDERAL and STATE RIGHT TO KNOW regulations . Also make this informa- tion available to any employee who requests it. Section I - PRODUCTION IDENTIFICATION ********************************************************************* * Producer 's Name : A&V, INCORPORATED * Address : N62 W22632 VILLAGE DRIVE * SUSSEX, WISCONSIN 53089 * * * Telephone Number for Information: 414-246-6922 * * * Trade Name and Synonyms : SPACARE PH UP, POOLCARE PH UP * * * Chemical Name & Synonyms : SODIUM CARBONATE * * * Hazard Classification: NONE ********************************************************************* Section II - HAZARDOUS COMPONENTS * * * Specific Chemical Identity: SODA ASH-ALKALI * * * O.S .H.A. PEL: N/A * * * A.C.G. I .H. TLV: N/A * * * Other Limits Recommended : N/A Section III - PHYSICAL DATA - TYPICAL * Boiling Point : DECOMPOSES * * * Vapor Density: NIL ************************continued on page SPACARE PH-UP MATERIAL SAFETY DATA SHEET Page 2 Section III - PHYSICAL DATA - TYPICAL ********************************************************************* * * * Solubility in Water : APPRECIABLE * Specific Gravity: 2 . 509 * * * Melting Point: N/A * * * Evaporation Rate : (BUTYLACETATE=1) NIL * * * Appearance and Odor : WHITE GRANULAR SOLID-ODORLESS * * Section IV - FIRE AND EXPLOSION DATA ********************************************************************* * * * Flash Point: NON-COMBUSTIBLE * * * Flammable Limits : NON-COMBUSTIBLE * * * Extinguishing Media: N/A * Special Fire Fighting Procedures : N/A * * * Unusual Fire and Explosion Hazards : NONE * * ********************************************************************* Section V - REACTIVITY DATA * Stability: STABLE * * * Incompatibility (Materials to Avoid ) : ACIDS * Hazardous Decomposition or Byproducts : CARBON DIOXIDE * Hazardous Polymerization: WILL NOT OCCUR - AVOID HIGH HUMIDITY * WHICH WILL CAUSE CAKING * * *************************continued on page 3************************* SPACARE PH-UP MATERIAL SAFETY DATA SHEET Page 3 Section VI - HEALTH HAZARD DATA ********************************************************************* * * * Health Hazards : SLIGHT IRRITATION TO EYES, SKIN AND * MUCOUS MEMBRANES . * Emergency and First Aid Procedures : EYES : FLUSH WITH CLEAN, * COOL WATER FOR 15 MIN. SEE A PHYSICIAN IF IRRITATION OCCURS . * SKIN: WASH WITH SOAP & WATER. SEE A PHYSICIAN IF IRRITATION * OCCURS . REMOVE & WASH CONTAMINATED CLOTHING. INHALATION: * REMOVE TO FRESH AIR. GET MEDICAL ATTENTION FOR IRRITATION, * INGESTION OR DISCOMFORT FROM INHALATION. INGESTION: IF CON- SCIOUS, IMMEDIATELY GIVE 2 TO 4 GLASSES OF WATER, & INDUCE * VOMITING BY TOUCHING FINGER TO BACK OF THROAT * * ********************************************************************* Section VII - SPILL AND DISPOSAL METHODS ********************************************************************* * * * Steps to be Taken in Case Material is Released or Spilled: * FOR MINOR SPILLS, SWEEP UP THE MATERIAL, TRANSFER TO A * CONTAINER & DISCARD IN GENERAL TRASH. RESIDUE MAY BE * WASHED AWAY WITH WATER. * Waste Disposal Method : RESIDUE QUANTITIES CAN BE WASHED AWAY * EMPTY CONTAINERS MAY BE INCINERATED OR DISCARDED AS GENERAL * TRASH. * * * Precautions to be Taken in Handling and Storing : STORE IN DRY * AREA - AVOID CONTACT WITH ACIDS . * * Section VIII - PROTECTIVE EQUIPMENT TO BE USED ********************************************************************* * Respiratory Protection: CARTRIDGE OR OTHER TYPE OF DUST FILTER * Ventilation: N/A * * * Protective Gloves : GENERAL PURPOSE GLOVES .,.. �» 'N.C"eCuea 3tCx.Lr£'f'a�a.%� .:.e�'wffi�.aS�W.Cds'1yKK.ti.l'�"°i+�:. Eye. Pr!otect�'i * Other Protective Clothing or Equipment : FULL COVER CLOTHING * * ********************************************************************* 12/J'S SPACARE PH DOWN S2 MATERIAL SAFETY DATA SHEET This MSDS is being provided to your company for the purpose of pro- viding current health and safety information to your management and for your employees who work with this material . Please read the information on these sheets, and then provide this information to those people at your company whose responsibility it is to comply with FEDERAL and STATE RIGHT TO KNOW regulations . Also make this informa- tion available to any employee who requests it . Section I - PRODUCTION IDENTIFICATION ********************************************************************* * Producer' s Name : A&V, INCORPORATED * * * Address : N62 W22632 VILLAGE DRIVE * SUSSEX, WISCONSIN 53089 * * * Telephone Number for Information: 414-246-6922 * Trade Name and Synonyms : SPACARE PH DOWN * * * C-hemical Name & Synonyms : Sodium Bisulfate Anhydrous Globular, * Technical * * * C .A.S. Number: 7681-38-1 * * * Hazard Classification (DOT) IRRITANT; NON HAZARDOUS ********************************************************************* Section II - HAZARDOUS COMPONENTS ********************************************************************* * * * Specific Chemical Identity Sodium Bisulfate Sodium Sulfate * of Hazardous Ingredients : 94. 5% 5 .D% * * * O.S.H.A. PEL: NONE ESTABLISHED * * * A.C.G. I .H. TLV: NONE ESTABLISHED * * * Other Limits Recommended: NONE ESTABLISHED * * ***********************Continued on Page 2*************************** SPACARE PH DOWN MATERIAL SAFETY DATA SHEET Page 2 Section III - PHYSICAL DATA - TYPICAL ********************************************************************* * * * Initial Boiling Poing: N/A * Vapor Pressure : N/A * * * Vapor Density: N/A * Solubility in Water: 100% Soluble * * * Specific Gravity: N/A Section III - PHYSICAL DATA - TYPICAL (continued) * Melting Point : 350 degrees F * * * Evaporation Rate : N/A * * II * Appearance and Odor: OFF-WHITE, BEAD LIKE, GRANULAR, * DRY MATERIAL Section IV - FIRE AND EXPLOSION DATA ********************************************************************* * * *Flash Point : Not Applicable, Will Not Burn * * * Explosive Limits : Upper: Not Applicable, Lower: Not Applicable * * * Flammable Limits : N/A * Extinguishing Media : Water or Dry Chemical as appropriate for * combustibles in area. Avoid water contact * to material if possible . * * * Special Fire Fighting Procedures : If water is used to extinguish * combustibles and product is dissolved in water forming sulfuric* * acid, wear acid protective equipment . If elevated temperatures * 0 570 degrees F) are reached self-contained breathing * apparatus should be worn. * Unusual Fire and Explosion Hazards: Product readily dissolves * in water to form a weak sulfuric acid solution. No gases or * toxic fumes are emitted from this reaction, but precautions * for exposure to sulfuric acid should be followed. * * * * ************************Continued on Page 3************************** SPACARE PH DOWN MATERIAL SAFETY DATA SHEET Page 3 Section V — REACTIVITY DATA * * * Stability: Stable * * * Conditions to avoid: Store in dry area to avoid moisture contact * above 160 C. * Incompatibilty With Other Materials : Avoid contact with strong * alkaline materials such as caustic . Reacts with water to form * weak sulfuric acid solution. * Hazardous Decomposition or Byproducts : * NONE Unless heated over 570 degrees F at which sulfur * dioxide and sulfur trioxide are formed. * * * w * Hazardous Polymerization: WILL NOT OCCUR Section VI — HEALTH HAZARD DATA. * Principal Health Hazards : * INHALATION: Irritant . May irritate or burn nose, throat and * lungs . No exposure limits established * * * * * EYE CONTACT: Mild to severe irritant . May cause burns if not * flushed with water. * SKIN CONTACT: Moderate irritant . May cause burns if not flushed * with water. * * * * * CARCINOGENICITY: NOT LISTED AS CARCINOGEN BY NTP, IARC, OR OSHA * * ******w******************Continued on Page 4************************* SPACARE PH DOWN MATERIAL SAFETY DATA SHEET Page 4 Section VI — HEALTH HAZARD DATA ********************************************************************* * * * * * INGESTION: Irritant . May irritate or -burn mouth, esophagus, or * stomach. * Animal Test Data : LD50 rat 2800 mg/kg * EMERGENCY AND FIRST AID PROCEDURES * EYE CONTACT: Immediately flush with water for 15 minutes * lifting eyelids to thoroughly flush. Get prompt medical * attention. * . SKIN CONTACT. Immediately flush with water for 15 minutes . If * burns occur obtain medical help . * INGESTION: Drink large quantities of water or milk. Follow with * milk of magnesia, beaten eggs or vegetable oil . Do not * induce vomiting. Contact physician immediately. * * * INHALATION. Move to fresh air location. If irritation or * discomfort persists, seek medical attention. *************************Continued on Page 5************************* SPACARE PH DOWN MATERIAL SAFETY DATA SHEET Page 5 wwwwwwwwwwwwwwwwwwwwwwwwwwwwww**w****wwwwwwwwwwwwwww*ww*****wwwwwwww * * NOTES TO PHYSICIAN: EYES: Natural watering of eyes will dissolve sodium * bisulfate forming a weak sulfuric acid solution which * may cause burns . Flush affected area thoroughly with * water. Do Not use chemical antidotes or neutralizing * solutions . w * * SKIN: Mild burns may occur if not thoroughly flushed * previously. w * * INHALATION: Mild burning sensations may occur to mucous * membranes, and upper respiratory tract . * w * INGESTION: Body water content will react with sodium * bisulfate to form a weak sulfuric acid solution, which * may burn tissues in mouth, esophagus, or stomach. * Solution should be diluted to reduce burning effect . * w w*************************Continued On Page 6ww***w.w**www*wwww*www** SPACARE PH DOWN MATERIAL SAFETY DATA SHEET Page 6 Section VII - SPILL AND DISPOSAL METHODS * * * STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: * SMALL SPILL: Material is a granular product and can be swept * up from surfaces . LARGE SPILL: Pick up as much as possible with shovel or other tool . Neutralize balance of spill with weak alkaline solution, * and wash down to sewer if federal , state, and local regulations * permit . * * * WASTE DISPOSAL METHOD: Comply with all local , state, and federal * regulations . * * * HANDLING AND STORAGE: Do Not store where exposed to moist * conditions . Do Not store near strong alkalies. * SPECIAL PRECAUTIONS: AVOID CONTACT WITH SKIN, EYES, OR CLOTHING * DO NOT STORE WHERE EXPOSED TO MOIST CONDITIONS OR NEAR STRONG * ALKALIES. kEEP CONTAINERS TIGHLY CLOSED. WEAR ALL RECOMMENDED * PROTECTIVE EQUIPMENT WHEN HANDLING. * * ********************************************************************* Section VIII - PROTECTIVE EQUIPMENT TO BE USED * * * Respiratory Protection: NIOSH Or MSA certified dust mask should * be worn while handling product; to control exposure * below nuisance dust limits of 10 mg/m3 * Eyes Protection: Safety Glasses or goggles . * * * Protective Gloves : Wear acid resistant gloves such as rubber or * neoprene . * Other Protective Equipment : Clothes should completely cover skin * to avoid skin contact . Coats, coveralls or aprons are * recommended. * * * Ventilation: Local Ventilation to a dust collector is recommended* * * 03/89 SPACARE FOAM GONE MATERIAL SAFETY DATA SHEET This MSDS is being provided to your company for the purpose of pro— viding current health and safety information to your management and for your employees who work with this material . Please read the information on these sheets, and then provide this information to those people at your company whose responsibility it is to comply with FEDERAL and STATE RIGHT TO KNOW regulations . Also make this informa— tion available to any employee who requests it . Section I — PRODUCTION IDENTIFICATION * * * Producer ' s Name : A&V, INCORPORATED * * * Address : N62 W22632 VILLAGE DRIVE * SUSSEX, WISCONSIN 5308.9 * * Telephone Number for Information: 414-246-6922 * * * Emergency Telephone Number: Chemtec 1-800-424-9300 * * * Trade Name and Synonyms : SPACARE FOAM GONE * * * Chemical Name & Synonyms : Polydimethylsiloxane emulsion * Organosilicone Emulsion * * * Hazard Classification: None * * ********************************************************************* Section II — HAZARDOUS COMPONENTS ********************************************************************* * * * Specific Chemical Identity * of Hazardous Ingredients : None * * * * * O. S .H.A. PEL: N/A * * * A. C.G. I .H. TLV: N/A * * I * Other Limits Recommended: N/A * * ***********************Continued on Page 2********w****************** SPACARE FOAM GONE MATERIAL SAFETY DATA SHEET Page 2 Section III - PHYSICAL DATA - TYPICAL w**www**************w**w*****wwwwww*ww*****wwwwww**wwwwww******wwwwww * Vapor Density (air = 1) : >1 * * * Solubility In Water by wt : Dispersible * w * Boiling Point : 760 mm Hg: >100 ' C (mixture) * w * Specific Gravity(H20 =1 ) : 1 , 006 @ 25/25 ' C w * * Freezing Point : ca . O' C * w * Vapor Pressure at 20 ' C: <20 mm Hg * * * Evaporation Rate (Butyl Acetate = 1) : < 1 * w * Appearance and Odor: Milky-White Liquid; mild .odor * w wwwwww*wwwwwwwwwwwwwwwwwwwwwww**wwwwwwwwwww*w***www***wwwwww**wwwwww* Section IV - FIRE AND EXPLOSION DATA wwwwwwwwwwwwwwwwwwww**wwwwwwww*wwww**wwwwww*wwwwwwwwwwwwwwwwwwwwwwwww w w * FLASH POINT (test methods) >: * None by Pensky-Martens closed cup ASTM D 93 (Aqueous * systems) w w * FLAMMABLE LIMITS IN AIR, by volume : * LOWER: Not determined * UPPER: Not determined * w * w * EXTINGUISHING MEDIA: * After water evaporates, residue can burn. Use water spray, * carbon dioxide, alcohol-type or universal-type foams applied * by manufacturer ' s recommended techniques . Use carbon dioxide * or dry chemical for small fires . w w * SPECIAL FIRE FIGHTING PROCEDURES: * None expected to be required w w * UNUSUAL FIRE AND EXPLOSION HAZARDS : NONE w w * w ***wwww* ****************Continued on Page 3wwwwwwwww*wwww****wwww*w** SPACARE FOAM GONE MATERIAL SAFETY DATA SHEET Page 3 Section V — REACTIVITY DATA wwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwww w * * Stability: STABLE w * * Conditions to avoid: NONE w * * Incompatibilty (materials to avoid) : NONE w w * Hazardous Combustion or Decomposition Products : * Burning can produce carbon monoxide, carbon dioxide, and oxides * of silicon. * w * Conditions to Avoid: NONE w * * Hazardous Polymerization: WILL NOT OCCUR w wwwwww*wwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwWwww Section VI — HEALTH HAZARD DATA wwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwww*wwwwwwwwwwww�rw*wwww,rwwww w * * TLV AND SOURCE: * None established by ACGIH or OSHA * * * EFFECTS OF SINGLE OVEREXPOSURE w * * SWALLOWING: * No evidence of adverse effects from available information w * * SKIN ABSORPTION: * No evidence of adverse effects from available information w w * INHALATION: * No evidence of adverse effects from available information * * * SKIN CONTACT: * No evidence of adverse effects from available information w * * EYE CONTACT: * No evidence of adverse effects from available information w w * EFFECTS OF REPEATED OVEREXPOSURE: * No evidence of adverse effects . from available information w w *'""""""""Continued on Page 4ww*wwwwwwwwwwww*wwwwwwww,aw** �� SPACARE FOAM GONE MATERIAL SAFETY SHEET Page 4 Section VI - HEALTH HAZARD DATE (Continued) wwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwww * w * MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: * A knowledge of the available toxicology information and * of the physical and chemical properties of the material * suggests that overexposure is unlikely to aggravate existing * medical conditions . * w * SIGNIFICANT LABORATORY DATA WITH POSSIBLE RELEVANCE TO HUMAN * HEALTH HAZARD EVALUATION: * None currently know. * OTHER EFFECTS OF OVEREXPOSURE: * None currently know. w * * EMERGENCY AND FIRST AID PROCEDURES: * w * EYE CONTACT: FLUSH WITH WATER * w * SKIN CONTACT: WASH WITH SOAP AND WATER. w w * INHALATION: NO EMERGENCY CARE ANTICIPATED w w * INGESTION: NO HARMFUL EFFECTS EXPECTED. w * * NOTES TO PHYSICIAN: * Toxicology studies have shown the material to be of very low * acute toxicity. There is no specific antidote . Treatment of * overexposure should be directed at the control of symptoms * and the clinical condition. w w ww**********************Continued on Page 5wwwwwwwwwwwwwwwwwwwwwwwwww POOLCARE FOAM GONE MATERIAL SAFETY DATA SHEET Page 5 Section VII — SPILL AND DISPOSAL METHODS wwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwww*wwwwwwwwww * * * Steps to be Taken in Case Material is Released or Spilled: * COLLECT FOR DISPOSAL. * * * Waste Disposal Method: BURY IN A LANDFILL WHERE PERMITTED UNDER * APPROPRIATE FEDERAL, STATE, AND LOCAL REGULATIONS. * w * w wwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwww*wwwwwwwwww � Section VIII — PROTECTIVE EQUIPMENT TO BE USED wwwwwwwwwww*wwwwwwwwwwww*wwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwww w * * Respiratory Protection: NONE REQUIRED IN NORMAL USE. w * * Ventilation: GENERAL (MECHANICAL) ROOM VENTILATION IS EXPECTED * TO BE SATISFACTORY. w w * Protective Gloves : PVC—COATED w * i * Eye Protection: SAFETY GLASSES w * * Other Protective Equipment : EYE BATH AND SAFETY SHOWER. wwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwww Section IX — HANDLING AND STORAGE wwwwwwwwwwwwwwwwwwwwwwwww****ww*wwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwww w * * Precautions to. be Taken in Handling and storage : * Normal precautions common to good manufacturing practice should be followed in handling and storage . w * wwwwwwwwwwwwwwwwwwwwwww*w**wwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwww 04/89 S7 SPACARE STAIN & SCALE MATERIAL SAFETY DATA SHEET This MSDS is being provided to your company for the purpose of providing current health and safety information to your management and for your employees who work with this material. Please read the information on these sheets, and then provide.this information to those people at your company whose responsibility it is to comply with FEDERAL and STATE RIGHT TO KNOW regulations. Also make this information available to any employee who requests it. Section I - PRODUCTION IDENTIFICATION Producer's Name: A & V INCORPORATED Address: N62 W22632 VILLAGE DRIVE SUSSEX, WISCONSIN 53089 Telephone Number for Information: 414-246-6922 Trade Names and Synonyms: SPACARE STAIN & SCALE Chemical Name: 1-Hydroxyethylidene-1, 1-diphosphonic Acid CAS Number: 2809-21-4 Hazard Classification: CORROSIVE Section II - HAZARDOUS COMPONENTS Hazardous Components: NONE r SPACARE STAIN & SCALE MATERIAL SAFETY DATA SHEET Page 2 Section III - PHYSICAL DATA TYPICAL Boiling Point: 108 degrees C (226 degrees F) Freezing Point: Approximately -25 degrees C (-13 degrees F) Solubility in Water: Complete Specific Gravity: 1.043 pH: 1.6 Viscosity @ 25 degrees C: Not Determined Appearance and Odor: Clear liquid; Mild odor. Section IV - FIRE AND EXPLOSION DATA Flash Point: Not applicable, aqueous solution Ignition Temperature: Not applicable aqueous solution Flammable Limits: Not applicable aqueous solution Extinguishing Media: Water. Fire and Explosion Hazard: Although this material is not flammable in aqueous state, it will burn in the presence of a strong ignition source after the water is removed. Special Fire Hazard & Fire Fighting Procedures: Eliminate ignition source. Wear self-contained breathing apparatus and complete personal protection equipment. Use water spray to cool fire, exposed structures and tanks, and to disperse vapor cloud if fire, is not present. Use CO2 or dry chemical for small fires; "alcohol foam" or water ` fog for large fires. i SPACARE STAIN & SCALE MATERIAL SAFETY DATA SHEET Page 3 Section V REACTIVITY DATA Hazardous Polymerization: Does not occur. Materials to Avoid: Avoid contact with strong alkalis; will result in violent reactions with the evolution of steam. Avoid contact with metal salts of sulfides and sulfites which could release toxic gases. Also avoid strong oxidizers and amines. Hazardous Decomposition Products: Highly toxic phosphines may form if the water is completely removed. CO, CO2 and oxides of nitrogen may also be formed. Section VI - TOXICITY DATA Oral Ingestion: Slightly toxic. Oral LD50 (rats) = 3000 mg/kg Skin Absorption: Practically non-toxic. Dermal LD50 (rabbits) = 10 g/kg Eye Irritation: May cause severe irritation and permanent eye irjury. A strong acid. FHSA (rabbits) = 38.8/110 Skin Irritation: May cause marked irritation or dermatitis. A strong acid. FHSA (rabbits) = 0.0 TLV/TWA: Not Established PEL: Not Established Possible Routes of Entry: Dermal and oral. However, none expected under normal procedures. SPACARE STAIN & SCALE MATERIAL SAFETY DATA SHEET Page 4 Section VII - HEALTH HAZARD DATA EMERGENCY AND FIRST AID PROCEDURES: EYE CONTACT: Immediately flush with plenty of water for at least 15 minutes. Hold eyelids open during washing. Washing within 1 minute is essential to achieve maximum effectiveness. If irritation persists, seek medical attention. SKIN CONTACT: Immediately flush skin with plenty of water while removing clothing and shoes. Thoroughly wash before reuse or discard. Wash skin with soap and water until clean. Get medical help if irritation persists. IF SWALLOWED: If conscious, immediately give several glasses of water or milk. DO NOT INDUCE VOMITING. Do not give anything to an unconscious person. Take immediately to hospital or physician. INHALATION: Immediately remove to fresh air. If breathing has stopped, give artificial respiration or oxygen. See a physician if irritation of eyes, skin, or respiratory tract occurs. EFFECTS OF OVEREXPOSURE: Inhalation of mist occurring during dilution and/or processing may be irritating to mucous membranes, throat, nose and eyes. Dermal contact is expected to be the primary route of occupational exposure to this product. It is considered to be corrosive to eyes and.skin. Occupational exposure to this product has not been reported to cause any adverse health effects when recommended safety precautions. are followed. Effects of Chronic.Exposure: None reported or expected. Others: None Known I SPACARE STAIN & SCALE MATERIAL SAFETY DATA SHEET Page 5 Section VI11 - SPILL AND DISPOSAL METHODS SPILL OR LEAK PROCEDURE: Wear splash-proof eye protection and impervious clothing. Dike and contain spills and leaks to prevent discharge to the environment. Dilute with water,.then neutralize cautiously with soda ash or sodium bicarbonate. Keep spills out of the sewers, watersheds and water systems. Contact authorities in the event of large spills. Obey all environmental regulations. WASTE DISPOSAL METHOD: The unneutralized product, when discharged, is a hazardous waste (EPA corrosive waste - D002). Its disposal, therefore, is regulated by federal RCRA regulations. Consult with appropriate regulatory agencies before discharging or disposing of waste material. The neutralized product, however, can be incinerated in a furnace where permitted under appropriate federal, state and local regulations or can be landfilled according to current local, state and federal regulations. CONTAINER DISPOSAL: Do not reuse empty container, triple rinse and discard. Emptied container retains vapor and product residue. Observe all labeled safeguards until container is cleaned, reconditioned or destroyed. SPACARE STAIN & SCALE MATERIAL SAFETY DATA SHEET Page 6 Section IX - PROTECTIVE EQUIPMENT TO BE USED Ventilation Requirements: Local exhaust. Protective Gloves: Impervious gloves Eye Protection: Splash proof safety goggles Skin Protection: Long-sleeved clothing, chemically-resistant safety shoes. Respiratory Protectiom None required for normal operations Other Protective Equipment: Eyewash facility and safety shower in immediate area. Moreover, when handling large amounts, use of impervious aprons and boots are suggested. Section X - HANDLING, STORAGE AND TRANSPORTATION Handling and Storage: Keep container closed when not in use. Freezes below -13 degrees F. Wear splash-proof safety goggles, impervious gloves and protective clothing. Wash contaminated clothing and shoes before reuse or discard. Precautionary Measures: Avoid breathing mist. Causes severe eye and skin burns, do not get in eyes, on skin or on clothing. Use with adequate ventilation. Handle with due care and wash thoroughly after handling. Harmful if swallowed, do not take internally. Keep away from heat and flame. Corrosive to metals. Transportation: Dot Proper Shipping Name: Corrosive Liquid, NOS DOT Hazard Class: Corrosive Material - UN 1760 DOT Hazard: Corrosive Label 12/91 SPACARE METAL PROTECTOR MATERIAL SAFETY DATA SHEET This MSDS is being provided to your company for the purpose of pro- viding current health and safety information to your management and for your employees who work with this material . Please read the information on these sheets, and then provide this information to those people at your company whose responsibility it is to comply with FEDERAL and STATE RIGHT TO KNOW regulations . Also make this informa- tion available to any employee who requests it . Section I - PRODUCTION IDENTIFICATION * * * Producer' s Name : A&V, INCORPORATED * * * Address : N62 W22632 VILLAGE DRIVE * SUSSEX, WISCONSIN 53089 * * * Telephone Number for Information: 414-246-6922 * Telephone Number for Emergencies : Chemtrec 1-800-424-9300 * Trade Name and Synonyms : SPACARE METAL PROTECTOR * * * Chemical Name & Synonyms: Phosphonic acid, (1-hydroxyethylidene) * bis . * HEDP; 1-Hydroxyethylidene-1 , 1-diphos- * phonic acid. * * * C .A. S. Number: 2809-21-4 * Hazard Classification: CORROSIVE ********************************************************************* Section II - HAZARDOUS COMPONENTS ********************************************************************* * * * Specific Chemical Identity * of Hazardous Ingredients: 1-Hydroxyethylidene-1 , 1-diphosphonic * acid, * Phosphorous acid * * * O.S.H.A. PEL: NONE ESTABLISHED * A. C.G. I .H. TLV: NONE ESTABLISHED ***********************Continued on Page 2*************************** I °t SPACARE METAL PROTECTOR MATERIAL SAFETY DATA SHEET Page 2 Section III - PHYSICAL DATA - TYPICAL *************w*w****www*w**w*****w*w****wwww**w*wwwwwwwwwwwwwwwwwwwww w * * Crystallizing Point : Less than 0 degrees C ( less than 32 * degress F) w * * Solubility in Water % by Wt . : Capable of being mixed (miscible) * in all proportions w * * PH (1% solids @ 25 degress C) : Less than 2 w w * Appearance and Odor: Clear Solution, yellow to amber color; * characteristic odor w w * Specific Gravity: 1 . 018 w w *wwwwwwww*wwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwww Section IV — FIRE AND EXPLOSION DATA wwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwww w w * OSHA CLASSIFICATION: CORROSIVE w w * Flash Point : N/A * w * Extinguishing Media : WATER SPRAY, DRY CHEMICAL, CO2 OR OTHER * CLASS B EXTINGUISHING AGENT. w w * Special Fire Fighting Procedures : w w * WHEN THIS PRODUCT IS INVOLVED IN A FIRE, FIREFIGHTERS OR OTHERS * SHOULD WEAR FULL PROTECTIVE CLOTHING AND SELF-CONTAINED * BREATHING APPARATUS IF EXPOSED TO VAPORS OR PRODUCTS OF * COMBUSTION. w w ************************Continued on Page 3wwwwwwwwwwwwwwwwwwwwwwwwww I SPACARE METAL PROTECTOR MATERIAL SAFETY DATA SHEET Page 3 Section V — HEALTH HAZARD DATA ww*******w********w*ww*w*www*w*wwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwww w w * Emergency and First Aid Procedures : w * * EYE CONTACT: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST * 15 MINUTES. CALL A PHYSICIAN. REMOVE MATERIAL FROM * SKIN AND CLOTHING. w w w * SKIN CONTACT: ALTHOUGH THIS PRODUCT DOES NOT PRESENT A * SIGNIFICANT. SKIN CONCERN, SKIN CONTAMINATION * SHOULD BE MINIMIZED AS GOOD INDUSTRIAL PRACTICE. * WEARING OF PROTECTIVE GLOVES IS RECOMMENDED. WASH * HANDS AND CONTAMINATED SKIN AFTER HANDLING. * w * RESPIRATORY: AVOID BREATHING VAPOR OR MIST. USE NIOSH/MSHA AP— PROVED EQUIPMENT WHEN AIRBORNE EXPOSURE IS EXCESSIVE * CONSULT RESPIRATOR MANUFACTURER TO DETERMINE * APPROPRIATE TYPE EQUIPMENT FOR GIVEN APPLICATION. * THE RESPIRATOR USE LIMITATIONS SPECIFIED BY * NIOSH/MSHA OR THE MANUFACTURER MUST BE OBSERVED. * HIGH AIRBORNE CONCENTRATIONS MAY REQUIRE USE OF * SELF—CONTAINED BREATHING APPARATUS OR SUPPLIED * AIR RESPIRATOR. RESPIRATORY PROTECTION PROGRAMS * MUST BE IN COMPLIANCE WITH 29 CFR 1910 . 134. * w w w w * * VENTILATION: PROVIDE VENTILATION TO MINIMIZE EXPOSURE. USE LOCAL * MECHANICAL EXHAUST VENTILATION AT SOURCES OF AIR * CONTAMINATION SUCH AS OPEN PROCESS EQUIPMENT. w w *************************Continued on Page 4wwwrrwwwwww*wwwwwwwwwwwwww SPACARE METAL PROTECTOR MATERIAL SAFETY DATA SHEET Page 5 Section VII - SPILL AND DISPOSAL METHODS wwwww**************************w*****w**wwwwwwwwwwwwwwwwwww*wwwwwwwww * Steps to be Taken in Case Material is Released or Spilled: w * * Contain spills and leaks to prevent discharge to the enviro- * ment . Absorb spillage with clay, sawdust, or other absorbent * material , contaminated sorbent materials, contaminated dirt, * and other contaminated material in drums . If possible, it is * also acceptable to contain spilled material and recover it as * a liquid prior to disposal . w * * Waste Disposal Method: * w * Dispose of in accordance with all applicable local , state * and federal regulations . * w * As currently defined in the federal Resource Conservation & * Recovery Act (RCRA) , this product when discarded, is a harardous * waste exhibiting the characteristic of corrosivity (D-002) . See * 40 CFR 261 . 22 . Its disposal , therefore, is regulated by federal * regulations . Consult your attorney or appropriate regulatory * officials for information regarding additional state and local * disposal requirements. w * * Disposal by incineration is recommended. Disposal of liquid in * a waste-water treatment at a waste-water facility is also * acceptable if approved by the facility. Landfill disposal may * also be acceptable if there are no free liquids and if approved * by the landfill facility. * w wwwwwwwwwwwwwwwwwwwwwwwwwww*****ww****ww*wwwwww*www�cwwwwwwwwwwwwwwwww 02/89 SPACARE METAL PROTECTOR MATERIAL SAFETY DATA SHEET Page 4 Section VI - TOXICOLGY * * * ACUTE ORAL LD 5,0 : (RAT) = 2,400 mg/kg, slightly toxic * In a 90 day feeding study rats were fed diets containing 3, 000, * 110, 000 or 30, 000 ppm of the concentrate from which this product * is made . At 30, 000 ppm, average body weight gains of both males * and females were reduced, and liver weights of males were de- * creased. Increased erthrocyte counts (males) , decreased * hemoglobin concentration (both sexes) , decreased hematocrit * values (both sexes) , and decreased leukocyte counts (females at * 84 days only) were observed at 30, 000 ppm. No other hematologic, * urinalysis or clinical chemistry parameter was affected. The no * effect level was 10, 000 ppm. * * * The concentrate from which this product is made was administered * to beagle dogs at dietary concentration of 1, 000, 3, 000 or 10, 000 * ppm for 90 days . No adverse hematologic, biochemical or * histopathologic, effects were observed. * * * Dermal LD 50 (Rabbit) : Greater than 7, 940 mg/kg, Practically * nontoxic . * * * Eye Irritation (Rabbit) : (FHSA) Corrosive * Skin Irritation (Rabbit) : (FHSA) 0. 0 out of 8 . 0, Nonirritating ***********************Continued on Page 5*************************** I FAST SHEEN MATERIAL SAFETY DATA SHEET This MSDS is being provided to your company for the purpose of providing current health and safety information to your management and for your employees who work with this material . Please read the information on these sheets, and then provide this information to those people at your company whose responsibility it is to comply with FEDERAL and STATE RIGHT TO KNOW regulations . Also make this information available to any employee who requests it . Section ' I - PRODUCTION IDENTIFICATION ********************************************************************** * Producer' s Name : A & V INCORPORATED * w * Address : N62 W22632 VILLAGE DRIVE * SUSSEX, WISCONSIN 53089 * * * Telephone Number for Information: 414-246-6922 * Trade Names and Synonyms: FAST SHEEN * * * Chemical Name : (1) Calcined Kaolin Clay * (an aluminum silicate material ) * (2) Mineral Spirits * (3) Silicone * * * Hazard Classification: DANGER - COMBUSTIBLE Section II - HAZARDOUS COMPONENTS * * * Hazardous Components : (1) Calcined Kaolin Clay * (an aluminum. silicate mineral ) * (2) Mineral Spirits * * * PEL: (1) None Established; (2) None Established * * * TLV: (1) TLV for nuisance dust : 10 mg/m3 of total dust < 1% * quartz, (or 5 mg/m3 respirable dust) * * Other Limits Recommended: N/A * * *************************Continued on Page 2************************** f N FAST SHEEN MATERIAL SAFETY DATA SHEET Page 2 Section III - PHYSICAL DATA TYPICAL wwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwww***********w***w******wwwwwwwwwwwwwww w * * Boiling Point : Not Determined * w * Solubility in Water: INSOLUBLE w * * Specific Gravity: 1 . 03 * w * PH: 6 . 6 w * * Appearance and Odor: White Milky Liquid; Petroleum Odor w w www**********************www*wwwwwwwwwwwwwwwwwwwwwwwwwww*wwwwwwwwwwwww Section IV - FIRE AND EXPLOSION DATA wwww*w*www*wwwww*w*wwwwwwww****w*wwwwwwwwww**wwwwwwwwww*www*ww*www*www * Flash Point : 105 degrees F w w * Flammable Limits : Upper 1 . 1 ; Lower 5 . 0 w w * Extinguishing Media: According to the National Fire Protection * Guide 49, combustible liquid fires may be * extinguished by water spray, dry chemical , * foam or carbon dioxide . Use water to keep * fire-exposed containers cool . If a leak or * spill has not ignited, use water spray to * disperse the vapors and provide protection * for persons attempting to stop leak. w w * Unusual Fire and Explosion Hazards : Vapors heavier than air, may * travel , be ignited at remote locations and flash back. * Explosive air-vapors mixtures may occur. w 8 w*wwwwwwwwww***********Continued on Page 3*wwww*ww*wwwww*wwwwwwwwwwwww s FAST SHEEN MATERIAL SAFETY DATA SHEET Page 3 Section V — REACTIVITY DATA ****w**********************w***wwwwwwwwwwwwwwwwwwwwwwwwwww*wwwwwwwwwww * * * Stability: Stable w * * Incompatibility: Oxidizing material can cause a reaction. * Heat or open flame can cause a fire or explosion. * w * Hazardous Decomposition or Byproducts : Silicon Dioxide, Carbon * Dioxide, and Traces of Incompletely Burned Carbon Products . w * � * Conditions to Avoid: Keep away from heat, sparks and open flame . w w **************************************w***ww*wwwwwwwwwwwwwwwwwwwwwwwww Section VI — HEALTH HAZARD DATA *******w****wwwwwwwwwwwwwwwwwwwwwwwwwwwwwww*w*wwwwwwwwwwwwwwwwwwwwwwww w * * Effects of Exposure: * w * EYE CONTACT: Mild to Severe Irritant . Possible Corneal * Injury. * SKIN CONTACT: Moderate Irritant . May cause redness, edema * or drying of skin if not flushed with water. * INGESTION: Irritant . Amounts transferred to the mouth by * fingers, ect . during normal use should not * cause injury. * INHALATION: Irritant . Respiratory irritation, dizziness, * and in poorly ventilated/confined areas, * unconsciousness, asphyxiation may result . w * w * *********************Continued on Page 4wwwwwwwwwwwwwwwwwwwwwwwwwwwwww FAST SHEEN MATERIAL SAFETY DATA SHEET Page 4 Section VI (cont . ) — HEALTH HAZARD DATA ********************************************************************** * * * Emergency and First Aid Procedures : * EYE CONTACT: Immediately flush with water for 15 minutes * Get prompt medical attention. * SKIN CONTACT: Wash exposed areas with soap and water. * IF SWALLOWED: DO NOT INDUCE VOMITING . Aspiration of the fluid * can cause serious lung injury, i . e . chemical * pneumonitis: CALL A WOMN I MIA'ELY: * INHALATION: Should symptoms noted of dizziness, or * drowsiness occurs, remove to fresh air. If not * breathing, apply artificial respiration. * * Section VIII — SPILL AND DISPOSAL METHODS ********************************************************************** * Steps to be Taken in Case Material is Released or Spilled: * Avoid contact with eyes . Ventilate area. Avoid breathing * vapor. Use self=contained breathing apparatus or supplied— air mask for large spills in confined area . Contain spill if * possible . Wipe up or absorb on suitable material and shovel * up * * * Waste Disposal Method: * All Federal , State and Local regulations concerning health and * pollution be reviewed to determine approved disposal procedures: * Contact the appropriate Federal , State or Local authorities on * proper disposal methods . **************************Continued on Page n FAST SHEEN MATERIAL SAFETY DATA SHEET Page 5 Section IX — PROTECTIVE EQUIPMENT TO BE USED wwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwww*wwwwwwwwwwwwwwwwww w * * Ventilation Requirements : Local Ventilation w * * Protective Clothing: Uniforms, coveralls or lab coats should be * worn. Launder or dry clean when soiled. * Gloves resistant to chemicals . and petroleum * distillants required. w * * Eye Protection: Chemical type goggles or safety glasses must be * worn. Do not wear contact lenses . w * * Other Protective Equipment : * Supplied air respiratory protection for cleaning large * spills or upon entry into tanks, vessels, or confined * spaces . wwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwww Section X — SPECIAL PRECAUTIONS wwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwww,rwwwwwwwwwwwwwwwwwwwwwwww w w * AVOID CONTACT WITH EYES, SKIN OR CLOTHING. * DO NOT STORE NEAR HEAT AND OPEN FLAME. * KEEP CONTAINERS TIGHTLY CLOSED. * WEAR ALL RECOMMENDED PROTECTIVE EQUIPMENT WHEN HANDLING. w * wwwwwwwwwwwwwww�cwwwwwwwwwwwwwwwwwwwww*wwwwwww*wwwwwwwwwwwwwwwwwwwwwwww 4/90 ALGAECIDE FOR SPAS MATERIAL SAFETY DATA SHEET This MSDS is being provided to your company for the purpose of pro- viding current health and safety information to your management and for your employees who work with this material . Please read the information on these sheets, and then provide this information to those people at your company whose responsibility it is to comply with FEDERAL and STATE RIGHT TO KNOW regulations . Also make this informa- tion available to any employee who requests it . Section I - PRODUCTION IDENTIFICATION * * * Producer 's Name : A&V, INCORPORATED * * Address : N62 W22632 VILLAGE DRIVE - SUSSEX, WISCONSIN 53089 * * Telephone Number for Information: 414-246-6922 * * * Trade Name and Synonyms : SPACARE ALGAECIDE, ALGAECIDE FOR SPAS. , * * * * * Hazard Classification: NONE * * Section II —HAZARDOUS COMPENENTS * Specific Chemical Identity: POLY(OXYETHYLENE( DIMETHYLIIiINIO) * ETHYLENE(DIMETHYLIMINIO)ETHYLEliE DICHLORIDE) * * * O . S . H.A. PEL: . N/A * * * A. C.G. I .H. TLV: N/A * * * Other Limits Recommended : N/A * * Section III - PHYSICAL DATA - TYPICAL ********************************************************************* * * * Initial Boiling Poing : ABOVE, 212 F * Vapor Pressure : N/A * * * Vapor Density: N/A * * Solubility in Water : COMPLETELY MISCIBLE IN WATER * Specific Gravity: 1 . 012 ************************Continued on Page 2************************** ALGAECIDE FOR SPAS MATERIAL SAFETY DATA SHEET Page 2 Section III - PHYSICAL DATA - TYPICAL (continued ) ********************************************************************* Melting Point : N/A Evaporation Rate : N/A * * * Appearance and Odor : CLEAR BROWN LIQUID WITH SLIGHT ODOR * * Section IV - FIRE AND EXPLOSION DATA * * * Flash Point : N/A * * Flammable Limits : N/A _ * * * Extinguishing Media : WATER FORG, CARBON DIOXIDE, FOAM, * DRY CHEMICAL * * * Special Fire Fighting Procedures : NONE * * Unusual Fire and Explosion Hazards : N/A * * ********************************************************************* Section V - REACTIVITY DATA * * Stability: STABLE * * * Incompatibility: NONE * * * Hazardous Decomposition or Byproducts : NONE * * * Hazardous Polymerization: WILL NOT OCCUR * * Section VI - HEALTH HAZARD DATA * * * Route (s ) of Entry: INHALATION LC 50 IS GREATER THAN 26 . 4MG/L SKIN : DERMAL LD 50 GREATER THAN 2G/KG * INGESTION : LOW SINGLE DOSE ORAL TOXICITY LD 50=3 . 7 G/KG * * * Health Hazards (Acute and Chronic) : IRRITATING TO EYES, PRODUCES * REVERSIBLE MINIMAL EFFECTS IN THE FORM OF ERYTHEMA, CHEMOSIS * AND DISCHARGE * * * Emergency and First Aid Procedures : EYES : FLUSH WITH CLEAN, * COOL WATER FOR 15 MIN. SEE A PHYSICIAN IF IRRITATION OCCURS . * SKIN: WASH WITH SOAP. & WATER. SEE A PHYSICIAN IF IRRITATION * OCCURS . REMOVE & WASH CONTAMINATED CLOTHING. INHALATION : * REMOVE TO FRESH AIR . * *********************Continued on Page 3***************************** ALGAECIDE FOR SPAS MATERIAL SAFETY DATA SHEET Page 3 Section VII - SPILL AND DISPOSAL METHODS * Steps to be Taken in Case Material is Released or Spilled : * LARGE SPILLS : DAM AREA TO PREVENT SPILL FROM ENTERING FISH * BEARING WATERS . PUMP INTO APPROPRIATE CONTAINERS DISPOSE OF * AS LISTED BELOW. SMALL SPILLS : FLUSH LIQUID TO SEWER WITH * COPIOUS AMOUNTS OF WATER. * * * Waste Disposal Method : PRODUCT DISPOSAL : PRODUCT IS NOT A * HAZARDOUS WASTE. IT CAN BE DISPOSED OF IN ANY APPROVED * LANDFILL . CONTAINER DISPOSAL: OFFER FOR RECYCLING OR * TRIPLE RINSE AND DISPOSE OF IN AN -APPROVED LANDFILL . * * ********************************************************************* Section VIII - PROTECTIVE EQUIPMENT TO BE USED * * i * .Precautions to Be Taken in Handling and Storing: * RUBBER GLOVES & SAFETY GLASSES OR GOGGLES RECOMMENDED * Respiratory Protection : NORMAL * * * Ventilation : NORMAL * Protective Gloves : RUBBER GLOVES RECOMMENDED * * * Eye Protection: SAFETY GLASSES OR GOGGLES RECOMMENDED * * * Other Protective Equipment : NONE * * 6/88 . SPACARE CHLORINATING GRANULES S20 MATERIAL SAFETY DATA SHEET This MSDS is being provided to your company for the purpose of pro- viding current health and safety information to your management and for your employees who work with this material . Please read the information on these sheets, and then provide this information to those people at your company whose responsibility it is to comply with FEDERAL and STATE RIGHT TO KNOW regulations . Also make this informa- tion available to any employee who requests it . Section I - PRODUCTION IDENTIFICATION ********************************************************************* * * * Producer' s Name : A&V, INCORPORATED * Address: N62 W22632 VILLAGE DRIVE * SUSSEX, WISCONSIN 53089 * * * Telephone Number for Information: 414-246-6922 * Emergency Telephone Number: CHEMTREC 800-424-9300 * * * Trade Name and Synonyms: SPACARE CHLORINATING GRANULES, * * * Chemical Name & Synonyms : Miscellaneous Blend * * * C.A.S. Number: 2893-78-9 * * * Hazard Classification: OXIDIZER * * ********************************************************************* Section II - HAZARDOUS COMPONENTS ********************************************************************* * * * Specific Chemical Identity * of Hazardous Ingredients : SODIUM DICHLOROISOCYANURATE * * * O.S.H.A. PEL: 15mg/m3 TWA * * * A. C.G. I .H. / TLV (UNITS) : 10mg/m3 TWA * * * Other Limits Recommended: N/A * * ***********************Continued on Page 2************* ************* SPACARE CHLORINATING GRANULES MATERIAL SAFETY DATA SHEET Page 2 Section III - PHYSICAL DATA - TYPICAL wwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwww**w*wwwwwwwwwwwwwwwwwwwwwwwwwwww w * * Initial Boiling Point : NO INFORMATION AVAILABLE w w * Freezing Point : 240-250 degrees C (Decomposes) w w * Vapor Pressure : NOT APPLICABLE w w * Vapor Density: (air=1) NOT APPLICABLE * w * Solubility in Water: 25g/100g @ 25 degrees C * Specific Gravity: NOT APPLICABLE w w * PH: 1% Solution: 1% Solution: 6. 0 * w * Appearance and Odor: White Crystalline Solid; Slight Chlorine * Odor. wwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwww ' Section IV - FIRE AND EXPLOSION DATA wwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwww*wwwww * Flash Point : Not Flammable w w * Explosive Limits (% by volume) : Upper: N/A, LOWER: N/A w w * Extinguishing Media: Thermal decomposition can be extinguished * by flooding with copious quantities of * water or by isolating the decomposing * material and allowing it to be consumed. w w * Special Fire Fighting 'Procedures : w w * Firefighters and others subjected to products of decomposition * should wear full protective clothing and self-contained * breathing apparatus . Chlorine-containing gases with traces of * of phosgene can be liberated at tempertures in excess of 400 * degrees F. w w * Unusual Fire and Explosion Hazards : w w * Nitrogen trichloride can be generated by reaction of water on * product under certain conditions . The reaction of water with * this chlorinating compostion generally does not present an ex- plosion hazard as rate of nitrogen trichloride formation is * very slow. wwwwwww*wwwww***********Continued on Page 3wwwwwwwwwwwwwwwwwwwwww*www I . SPACARE CHLORINATING GRANULES MATERIAL SAFETY DATA SHEET Page 3 Section V - REACTIVITY DATA * Stability: STABLE * . * * * Conditions to avoid: CONTACT WITH WATER * Incompatibilty With Other Materials: * Easily oxidizable organic material , ammonia, urea, or similiar * nitrogen-containing compounds, inorganic reducing compounds- calcium hypochlorite, alkalis . *Hazardous Decomposition or Byproducts : * * * CHLORINE- CONTAINING GASES CAN BE PRODUCED. TRACES OF PHOSGENE* * CAN BE LIBERATED AT HIGH TEMPERATURES >400 degrees F. * * * Hazardous Polymerization: WILL NOT OCCUR * * * Polymerization Avoid: NOT APPLICABLE Section VI - HEALTH HAZARD DATA * * * Carcinogenicity: NONE * * * NTP: No IARC: No * * * OVER EXPOSURE EFFECTS: Eye damage, burns to skin, irritation of * nose and throat . * Exposure Aggravated Medical Conditions : NONE CURRENTLY KNOWN * * * FIRST AID: * EYES: Flush immediately with plenty of water for at least * 15 minutes and get medical attention. * * * SKIN: Wash thoroughly with plenty of water. Wash contaminated* * clothing before reuse . * * * INHALATION: Remove to fresh air. * * * INGESTION: Drink milk, water or raw eggs whites * Get Medical Attention. * * *************************Continued on Page SPACARE CHLORINATING GRANULES MATERIAL SAFETY DATA SHEET Page 4 Section VII - SPILL AND DISPOSAL METHODS wwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwww w w *Steps to be Taken in Case Material is Released or Spilled: w w * CONTAIN SPILL. DO NOT ALLOW WATER OR OTHER IMCOMPATIBLE SUB- STANCES TO COME INTO CONTACT WITH SPILLED MATERIAL.KEEP OUT OF * SEWERS, WATERSHEDS, AND WATER SYSTEMS. SWEEP UP MATERIAL AND * PLACE IN CLEAN, DRY LABLED CONTAINER FOR DISPOSAL. w w * Waste Disposal Method: w w . * INCINERATE. COMPLY WITH ALL FEDERAL, STATE AND LOCAL * REGULATIONS. w w * Handling and Storage: w w * STORE IN COOL, DRY, WELL VENTILATED AREA. KEEP CONTAINERS * CLOSED WHEN NOT IN USE. w * i wwwwwww*wwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwww Section VIII - PROTECTIVE EQUIPMENT TO BE USED wwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwww*wwwwwww w w * Respiratory Protection: NIOSH APPROVED FULL FACEPIECE WITH * AIRBORNE EXPOSURE LIMITS ARE EXCEEDED. w w w w * Ventilation: TO MAINTAIN DUSTS BELOW LIMITS. w w * Protective Gloves : RUBBER OR OTHER IMPERVIOUS MATERIALS. w w * Eye Protection: CHEMICAL SPLASH PROOF GOGGLES. w w * Other Protective Equipment : A SAFETY SHOWER AND EYE BATH SHOULD * BE AVAILABLE. FOR OPERATIONS WHERE * SPILLS OR SPLASHING MAY OCCUR, USE * AN IMPERVIOUS BODY COVERING AND BOOTS. * wwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwww,rwwwwwwwwwwwwwwwwwwwwwwwwww 03/89 SLOW DISSOLVING BROM TABS MATERIAL SAFETY DATA SHEET This MSDS is being provided to your company for the purpose of pro- viding current health and safety information to your management and for your employees who work with this material . Please read the information on these sheets, and then provide this information to those people at your company whose responsibility i.t is to comply with FEDERAL and STATE RIGHT TO KNOW regulations . Also make this informa- tion available to any employee who requests it . Section I - PRODUCTION IDENTIFICATION * * * Producer' s Name : A&V, INCORPORATED * * * Address : N62 W22632 VILLAGE DRIVE * SUSSEX, WISCONSIN 53089 * * Telephone Number for Information: 414-246-6922 * Trade Name and Synonyms : SLOW DISSOLVING BROM TABS * * * Chemical Name & Synonyms : Halogenated hydantoin, * N-Bromo-N'-chloro-dimethyl hydantoin; * 1-Bromo-3-chloro-5,5-dimethyl hydantoin; * * 1-Bromo-3-chloro-5,5-dimethyl-2, * 4-imidazolidinedione . * * * C.A.S. Number: 126-06-7 Section II - HAZARDOUS COMPONENTS * * * Specific Chemical Identity * of Hazardous Ingredients : N-Bromo-N'-chloro-dimethyl hydantoin; * 1-bromo-3-chloro-5,5-dimethyl hydantoin; * * 1-bromo-3-chloro-5,5-dimethyl-2, * 4-imidazolidinedione. * * * O.S.H.A. PEL: Not Established * A. C.G. I .H. TLV: Not Established * * * Other Limits Recommended: Not Established * * ***********************Continued on Page 2*************************** i SLOW DISSOLVING BROM TABS MATERIAL SAFETY DATA SHEET Page 2 Section III - PHYSICAL DATA - TYPICAL ********************************************************************* * * * Initial Boiling Poing: N/A * Vapor Pressure : N/A * Vapor Density: N/A * Solubility in Water: . 2 G/100 G @ 25 C. * * * Specific Gravity: (H20=1) 1 . 8 - 2. 0 * * * Melting Point : 163-164 C. * * * Evap-oration ,Rate N/A * * * Appearance and Odor: WHITE SOLID OR FREE-FLOWING COLOR * FAINT HALOGENOUS ODOR ********************************************************************* Section IV - FIRE AND EXPLOSION DATA * * * Flash Point : NONE * * * * * Flammable Limits : N/A * Extinguishing Media: NONE * * * * * Special Fire Fighting Procedures: Cool containers with water * spray. In closed . stores, provide fire-fighters with self- contained breathing apparatus (in pressure demand or * other positive pressure mode) . * Unusual Fire and Explosion Hazards : From ca. 160 C. will decompose* * releasing irritant, toxic hydrogen bromide and bromine fumes. * Will smoulder in large fires fueled by other materials with * emission of dense black smoke for a long time . * * ************************Continued on Page 3************************** f SLOW DISSOLVING BROM TABS MATERIAL SAFETY DATA SHEET Page 3 Section V — REACTIVITY DATA wwww**wwwwwwwwwww*w****w***w*******w*www********w**ww*w******w*****ww w w * Stability: Stable when dry and uncontained w * * Conditions to avoid: Contamination with water, organic * materials or oxidizers. w * * Incompatibilty With Other Materials : Paints, petroleums and * other combustible organic * materials; organic and * inorganic oxidizers . w w * Hazardous Decomposition or Byproducts : * From ca. 160 C will decompose, releasing irritant, toxic * hydrogen bromide and bromine fumes. Will smoulder in large * fires fueled by other materials with emission of dense black * smoke for a long time. w * * Hazardous Polymerization: WILL NOT OCCUR w * Section VI — HEALTH HAZARD DATA ***w**w*********w*w***************wwwww*****ww*w***wwww************** * Toxicity: LD 50 (oral , rats) less than 200 mg/kg w * * Effects of overexposure : * INHALATION: Irritates mucous membranes . Dust will burn * respiratory tissues severely. w * * EYE CONTACT: Severe irritation. Corneal burns on prolonged * contact with dust or concentrated suspension. w * * SKIN CONTACT: Prolonged skin contact may cause reddening and * superficial necrosis . Burns may be severe if skin * is wet or damp . w * * SKIN ABSORPTION: None via intact skin. *************************Continued on Page 4**********w************** i SLOW DISSOLVING BROM TABS MATERIAL SAFETY DATA SHEET Page 4 Section VI - HEALTH HAZARD DATA (continued) * * * INGESTION: As for Inhalation; will burn digestive tract tissues * severely. * * * EMERGENCY AND FIRST AID PROCEDURES * EYE CONTACT: Holding eyelids apart and rolling the eyes, * flush eyes with copious flowing water for 15 minutes. Get * medical attention. * * * SKIN CONTACT: remove contaminated clothing. Wash skin thoroughly * with mild soap and plenty of water. Wash clothing before * reuse . Get medical attention if irritation persists. * INGESTION: If swallowed, give two glasses of water and induce * vomiting by touching a finger to the back of the throat. Get * medical aid immediately. DO NOT induce vomiting or give * liquids when patient is unconscious. * * * INHALATION: If exposed to Halobrome dust and or the fumes * released at higher temperatures, remove the patient to * fresh air, keep him quiet and warm, apply artificial * respiration if necessary, and get medical aid immediately. * * * * *************************Continued on Page 5************************* r r SLOW DISSOLVING BROM TABS MATERIAL SAFETY DATA SHEET Page 5 Section VII - SPILL AND DISPOSAL METHODS ***************w**ww*w***ww*w**wwww*wwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwww w * * STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: * Use protective goggles with side-shields, dust respirator and * rubber gloves . Prevent dusting; either shovel/sweep into clean, * intact packaging for possible re-use or hose down area. Hose * down concentrated suspension spills. w * * WASTE DISPOSAL METHOD: Follow state and/or local ordinances . * Dispose in approved landfill sites or an approved incinerator. * Crush and bury empty containers . w * * HANDLING AND STORAGE: Handle containers with care and keep them * well closed. Store in dark, cool , dry locations (ca. 20-32 C) , * away from energy sources and incompatible materials. * OTHER PRECAUTIONS: Use dry, clean clothing and equipment for * transfer; always re-cover and close original container well . * Do Not eat, drink or smoke during work, wash thoroughly with * soap and water after handling. *********wwwww****wwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwww � Section VIII - PROTECTIVE EQUIPMENT TO BE USED **************w**www*ww***wwwwwwwww*wwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwww * w * Respiratory Protection: Dust respirator essential if dusting * occurs. w * * Eyes .-Impact-resistant glass or plastic goggles with side-shields. * * * * Clothing: Body-covering clothes, impervious rubber gloves, and * boots w * * Other: Eye wash fountain and washing facilities must be provided. * Ventilation: Local Exhaust : Recommended if dusting occurs. * Mechanical Equipment : General ventilation. w w wwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwww*www*wwwwwwwwwwwwwwwwwwwwww 03/89 / 3 V SPACARE ULTRA CLEAR MATERIAL SAFETY DATA SHEET This MSDS is being provided to your company for the purpose of pro- viding current health and safety information to your management and for your employees who work with this material . Please read the information on these sheets, and then provide this information to these people at your company whose responsibility it is to comply with FEDERAL and STATE RIGHT TO KNOW regulations . Also make this information available to any employee who requests it . Section I - PRODUCTION IDENTIFICATION ****wwww*wwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwww w * *Producer ' s Name : A&V, INCORPORATED *Address : N62 W22632 VILLAGE DRIVE * SUSSEX, WISCONSIN 53089 w * * Telephone Number for Information: 414-246-6922 w * . * Trade Name and Synonyms : SPACARE ULTRA CLEAR w * * Chemical Names or Synonyms : SEAKLEAR * w * Hazard Classification: none w * ****************w*wwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwww Section II - HAZARDOUS COMPONENTS ***********w*wwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwww.wwwwwwwwwwww w * * Specific Chemical Identity: CHITOSAN, ACETIC ACID, WATER, * U.S. CERTIFIED COLORS * * * O. S.H.A. PEL: NOT ESTABLISHED w * * A. C.G . I .H. TLV: NOT ESTABLISHED w w * Other Limits Recommended: NOT ESTABLISHED w w wwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwwww i SPACARE ULTRA CLEAR MATERIAL SAFETY DATA SHEET Page 2 Section III - PHYSICAL DATA - TYPICAL * * * Initial Boiling Point : 211 DEGREES F * * * Vapor Pressure : N/A * * * Vapor Density: AIR = 1 * Solubility in Water: COMPLETE Specific Gravity: 1 . 004 * PH: 4.4 * Melting Point : N/A * * * Evaporation Rate : (BUTYLACETATE=1) N/A * * Appearance and Odor: CLEAR BLUE LIQIUD; SLIGHT FISH SMELL * * Section IV - FIRE AND EXPLOSION DATA * Flash Point : NON-COMBUSTIBLE * * * Extinguishing Media: DOES NOT BURN * * * Special Fire Fighting Procedures : NONE * * Section V - REACTIVITY DATA * Stability: STABLE * * * Conditions to avoid: N/A * * * Hazardous Decomposition or Byproducts : * * * Hazardous Polymerization: WILL NOT OCCUR * * SPACARE ULTRA CLEAR MATERIAL SAFETY DATA SHEET Page 3 Section VI - HEALTH HAZARD DATA ******************************************************************** * * * Health Hazards : 100% CHITOSAN LD50 > 16g/kg BODY WEIGHT (MICE) * Emergency and First Aid Procedures : FLUSH SKIN AND EYES WITH * WATER * * Section VII - SPILL AND DISPOSAL METHODS * * * Steps to be Taken in Case Material is Released or Spilled: * DILUTE WITH WATER AND HOSE DOWN DRAINS. MATERIAL IS BIOLOGI- CALLY DEGRADED. * * * Waste Disposal Method: MATERIAL IS 100% BIODEGRADABLE, IS NON- TOXIC AND CAN BE DISPOSED OF IN ANY APPROVED MANNER. * * Section VIII - PROTECTIVE EQUIPMENT TO BE USED * * * Respiratory Protection: NOT REQUIRED UNDER NORMAL USE * * * Ventilation: LOCAL: N/A SPECIAL: N/A * MECHANICAL: GENERALLY ADEQUATE * * * Protective Gloves: NOT REQUIRED UNDER NORMAL USE * * * Eye Protection: NOT REQUIRED UNDER NORMAL USE * * * Other Protective Equipment : N/A * * 4/90 "ORIN v V S4F4ArS*:S V44Y #y44wr.5* A14 . I I II I, 4 k • r I I i 1 w co l i r I l I 1 V • � 1 ,V 1 / ��`� 1.{,f1.7.7: J. r�naii.c,vo.6 �..�ay....,...r._ satisfactory BOARD OF HEALTH \ � 2. Printers 3. Auto Body Shops unsatisfactory- 4. Manufacturers COMPANY +� nUC� (see"Orders") S. Retail Stores (i ' f i,� " O 1 6. Fuel Suppliers ADDRESS rr -fit,. ii'� �`-� Class• 7. Miscellaneous C rti,,x..,•--� 1 I ,J QUANTITIES AND STORAGE (IN=indoors; OUT=outdoor. MAJOR MATERIALS Case lots Drums AbOveTanks Underground Tanks IN JOUT IN IOUT IN IOUT # & gygllon e Test Fuels: Gasoline, Jet Fuel (A) Diesel, Kerosene, #2 (B) Heavy Oils: waste motor oil (C) new motor oil (C) transmission/hydraulic Synthetic Organics: I degreasers i j -- t f 1 ' Miscellaneous: DISPOSAL RECLAN:ATION REW RKS: 1. Sanitary Sewage 2. Water Supply PO\Town Sewer O Public OOn-site O Private keA 3. Indoor Floor Drains: YES NO ?n O Holding tank: MDC _ 0 Catch basin/Dry well N//, On-site system 4. Outdoor Surface drains:YES NO O Holding tank: MDC O Catch basin/Dry well aOn-site system S. Waste Transporter Licensed? a-me of N �UC� Destination } aste.'Product ' 2- �► r 1z 23 el Person s) Interviewed Ulnspector Date TOWN OF BARNSTABLE BAR-W Ordinance or Regulation WARNING NOTICE Name of Offender/Manager Address of Offender MV/MB Reg.# Village/State/Zip Business Name am/pm, on 20_ Business Address W"1 ' j," viCSignature of of Enforcing Officer Village/State/Zip Location of Offense Enforcing Dept/Division Offense Facts This will serve only as a warning. At this time no legal action has been taken. It is the goal of Town agencies to achieve voluntary compliance of Town Ordinances, Rules and Regulations. Education efforts and warning notices are attempts to gain voluntary compliance. Subsequent violations will result in appropriate legal action by the Town. WHITE-OFFENDER CANARY-ORD./REG.-PROG. PINK-ENFORCING OFFICER GOLD-ENFORCING DEPT. ,rTOWN OF BARNSTABLE BAR-W 1-1197 Ordinance or Regulation WARNING' NOTICE Name of Offender/Manager A, 0 .r j Address of Offender MV/MB Re g- # Village/State/Zip Business Name , _ . F am/pm, on "• 20?'7 Business Address W-i Signature of_ Eriforci.ag Officer Village/State/Zip ' k t Location of Offense r _ E Enforcing Dept/Division Offense Facts 1 - ' 4- This will serve only as a warning. At this time no =legal action -has been taken. It is the goal of Town agencies to achieve voluntary, compliance of Town Ordinances, Rules and Regulations. Education efforts and` warning notices are attempts to gain voluntary compliance'. Subsequent violations will result in appropriate legal action .,by. the Town. WHITE-OFFENDER CANARY-ORD./REG.-PROG. PINK-ENFORCING OFFICER GOLD-ENFORCING DEPT. r TOWN OF BARNSTABLE COMPLIANCE: CLASS: 1. Marine,Gas Stations,Repair nters BOARD OF HEALTH satisfactory 3.2.Auto Body Shops O unsatisfactory- 4.Manufacturers COMPANY bn,Ad4' (see"Orders") 5,Retail Stores —T-- 6.'Fuel Suppliers ADDRESS !q! Class: 7.Miscellaneous QUAN ITIES AND STORAGE (IN=indoors; OUT=outdoors) MAJOR MATERIALS Case lots Drums Above Tanks Underground Tanks IN OUT IN OUT IN OUT #&gallons Age Test Fuels: Gasoline,Jet Fuel (A) Diesel, Kerosene, #2 (B) Heauy Oils: waste motor oil (C) new motor oil (C) transmission/hydraulic Synthetic Organics: degreasers Miscellaneous: t ® DISPOSAI,/RE(;LAMATION REMARKS: 1. Sanitary Sewage 2.Water Supply 'Town Sewer 'Public 0 On-site OPrivate 3. Indoor Floor Drains YES N0 O Holding tank:MDC 0 Catch basin/Dry well 0 On-site system 4. Outdoor Surface drains:YES NO ORDERS: 0 Holding tank: MDC O Catch basin/Dry well O On-site system 5. Waste Transporter Name of Hauler Destination Waste Product YES NO 1. 2. a 1 rson (s) Interviewed Inspecto Date TOXIC AND HAZARDOUS MATERIALS REGISTRATION FORM NAME OF BUSINESS: 'G�`'� i�z��`C�(�l�"�y� Mail To:Board of Health MAILING ADDRESS: �'��� ?��Y'r'''4-5 �� Town of Barnstable TELEPHONE NUMBER: P.O. Box 534 CONTACT PERSON: �✓+f� ��� �;c�_ Hyannis, MA 02601 Does your firm store any of the toxic or hazardous materials listed below, either for sale or for your own use, in qua (ties totalling, at any time, more than 50 gallons liquid volume or 25 pounds dry weight? YES NO This form must be returned to the Board of Health regardless of a yes or no answer. Use the enclosed envelope for your convenience. If you answered YES above, please indicate if the materials are stored at a site other than your mailing address: ADDRESS: TELEPHONE: LIST OF TOXIC AND HAZARDOUS MATERIALS The Board of Health has determined that the following products exhibit toxic or hazardous characteristics and must be registered when stored in quantities totalling more than 50 gallons liquid volume or 25 pounds dry weight. Please put a check beside each product that you store: Antifreeze (for gasoline or coolant systems) Drain cleaners Automatic transmission fluid Toilet cleaners Engine and radiator flushes Cesspool cleaners Hydraulic fluid (including brake fluid) Disinfectants Motor oils/waste oils Road Salt (Halite) Gasoline, Jet fuel Refrigerants Diesel fuel, kerosene, #2 heating oil Pesticides (insecticides, herbicides, Other petroleum products: grease, lubricants rodenticides) Degreasers for engines and metal Photochemicals (fixers and developers) Degreasers for driveways & garages Printing ink Battery acid (electrolyte) Wood preservatives (creosote) Rustproofers _ Swimming pool chlorine Car wash detergents Lye or caustic soda Car waxes and polishes Jewelry cleaners Asphalt & roofing tar Leather dyes Paints, varnishes, stains, dyes Fertilizers (if stored outdoors) Paint & lacquer thinners PCB's Paint & varnish removers, deglossers Other chlorinated hydrocarbons, Paint brush cleaners (inc. carbon tetrachloride) Floor & furniture strippers Any other products with "Poison" labels Metal polishes (including chloroform, formaldehyde, Laundry soil & stain removers hydrochloric acid, other acids) (including bleach) Other products not listed which you feel may Spot removers & cleaning fluids be toxic or hazardous (please list): (dry cleaners) Other cleaning solvents Bug and tar removers Household cleansers, oven cleaners White Copy-Health Department/ Canary Copy-Business A 1 TOXIC AND HAZARDOUS MATERIALS REGISTRATION FORM Mail To: NAME OF BUSINESS: `"� �� '�"'� � � ` � �� Board of Health MAILING ADDRESS: (272 � � °'^ `t` -�B —� } Town of Barnstable TELEPHONE NUMBER: ?� — C-� P.O. Box 534 CONTACT PERSON: Hyannis, MA 02601 Does your firm store any of the toxic or hazardous materials listed below, either for sale or for your own use, in quantities totalling, at any time, more than 50 gallons liquid volume or 25 pounds dry weight? YES . NO This form must be returned to the Board of Health regardless of a yes or no answer. Use the enclosed envelope for your convenience. If you answered YES above, please indicate if the materials are stored at a site other than your mailing address: ADDRESS: TELEPHONE: LIST OF TOXIC AND HAZARDOUS MATERIALS The Board of Health has determined that the following products exhibit toxic or hazardous characteristics and must be registered when stored in quantities totalling more than 50 gallons liquid volume or 25 pounds dry weight. Please put a check beside each product that you store: Antifreeze (for gasoline or coolant systems) Drain cleaners Automatic transmission fluid Toilet cleaners Engine and radiator flushes Cesspool cleaners Hydraulic fluid (including brake fluid) Disinfectants Motor oils/waste oils Road Salt (Halite) Gasoline, Jet fuel Refrigerants Diesel fuel, kerosene, #2 heating oil Pesticides (insecticides, herbicides, Other petroleum products: grease, lubricants rodenticides) Degreasers for engines and metal Photochemicals (fixers and developers) Degreasers for driveways & garages Printing ink Battery acid (electrolyte) Wood preservatives (creosote) Rustproofers Swimming pool chlorine Car wash detergents _ Lye or caustic soda " Car waxes and polishes Jewelry cleaners Asphalt & roofing tar Leather dyes Paints, varnishes, stains, dyes Fertilizers (if stored outdoors) Paint & lacquer thinners PCB's Paint & varnish removers, deglossers Other chlorinated hydrocarbons, Paint brush cleaners (inc. carbon tetrachloride) Floor & furniture strippers Any other products with "Poison" labels Metal polishes (including chloroform, formaldehyde, Laundry soil & stain removers hydrochloric acid, other acids) (including bleach) Other products not listed which you feel may Spot removers & cleaning fluids be toxic or hazardous (please list): (dry cleaners) Other cleaning solvents Bug and tar removers Household cleansers, oven cleaners White Copy-Health Department/ Canary Copy-Business POOL W V CMr6dz TOWN OF BARN TABLE COMPLIANCE: CLASS: 1.Marine,Gas Stations,Repair Q satisfactory 2.Printers BOARD OF HEALTH 3.Auto Body Shops COMPANY C G unsatisfactory- 4-Manufacturers V (see"Orders") It etail Stores uel Suppliers iscellaneous ADDRESS Mass: hS QUANTITIES AND STORAGE (IN=indoors; OUT=outdoors) MAJOR MA4RIALSUnderground Tanks IN OUT IN OUT IN OUT #&gallons Age Test Fuels: Gasoline,Jet Fuel (A) Diesel, Kerosene, #2 (B) Heavy Oils: waste motor oil (C) new motor oil (C) transmission/hydraulic Synthetic Organics: degreasers I Miscellaneous: i � A Cl�l LO�i�nl� ALGAC14DeS Ix DISPOSAUR.ECLAMATION RE P: 1. Sanitary Sewage 2. ater 5 Z, L"(�� Q2 Supply A , O Town Sewer ublic EXL DZILre 4 im 0 S. O On-site 9Private 3. Indoor Floor Drains YES NO 4 O Holding tank:MDC B0_LLD1W; O Catch basin/Dry well O On-site system 4. Outdoor Surface drains:YES NO O ERS: O Holding tank:MDC ma, O Catch basin/Dry well O On-site system 5. Waste Transporter Name of Hauler Destination Waste Product 1. 9ZA YES NO 2. 4A Person (s) Interviewed- Inspect D to TOWN OF BARNSTABLE COMPLIANCE:- CLASS: 1.Marine,Gas Stations,Repair 0 satisfactory 2.Printers BOARD OF HEALTH 3.Auto Body Shops fa L unsatisfactory- 4.,Manufacturers COMPANY �LJt�— k��tf`31�i W (see"Orders") �5?Retail Stores I 6.Fuel Suppliers ADDRESS � � ��� �1 �� �� (;lass: 'I '° �> (�-Miscellaneous QUANTITIES AND STORAGE (IN= indoors;OUT=outdoors) MAJOR MATERIALS Case lots 1Underground Tanks IN OUT IN OUT IN OUT #&gallons Age Test Fuels: Gasoline,Jet Fuel (A) Diesel, Kerosene, #2 (B) Heavy Oils: waste motor oil (C) new motor oil (C) transmission/hydraulic Synthetic Organics: degreasers Miscellaneous: Q n f d DISPOSAL/RECLAMATION REMARKS: 1. Sanitary Sewage 2.Water Supply O Town Sewer ®Public 0 � F' rip.( inr,_ ,� Q On-site QPrivate 3. Indoor Floor Drains YES NO X �^ r / r O Holding tank: MDC r Ar` l I J N(r C-y I r^) ' giver N V\L4 ,n O Catch basin/Dry well O On-site system 4. Outdoor Surface drains:YES NO ORDERS: O Holding tank:MDC IAJ 10, O Catch basin/Dry well O On-site system , . , _ .�. w - _ 5. Waste Transporter Name of Hauler Destination Waste Product NO 1. 2. �� "yI l Person (s) Interviewed- Inspector Date TOXIC AND HAZARDOUS MATERIALS REGISTRATION FORM � Mail To: NAME OF BUSINESS: � '`'G Board of Health MAILING ADDRESS: •, Town of Barnstable TELEPHONE NUMBER: P.O. Box 534 Hyannis, MA 02601 CONTACT PERSON: Does your firm store any of the toxic or hazardous materials listed below, either for sale or for your own use, in quantities totalling, at any time, more than 50 gallons liquid volume or 25 pounds dry weight? YES NO X This form must be returned to the Board of Health regardless of a yes or no answer. Use the enclosed envelope for your convenience. If you answered YES above, please indicate if the materials are stored at a site other than your mailing address: ADDRESS: c TELEPHONE: CE LIST OF TOXIC AND HAZARDOUS MATERIALS The Board of Health has determined that the following products exhibit toxic{or'hazardous characteristics and must be registered when stored i t. Please put a check beside each product that you'store.: Antifreeze (for gasoline or coolant systems) Drain cleaners Automatic transmission fluid Toilet cleaners F Engine and radiator flushes Cesspool cleaners Hydraulic fluid (including brake fluid) Disinfectants t, Motor oils/waste oils Road Salt (Halite) ' Gasoline, Jet fuel Refrigerants. Diesel fuel, kerosene, #2 heating oil Pesticides (insecticides, herbicides, , Other petroleum products: grease, lubricants rodenticides) Degreasers for engines and metal Photochemicals (fixers and developers) Degreasers for driveways & garages Printing ink Battery acid (electrolyte) Wood preservatives (creosote) Rustproofers Swimming pool chlorine Car wash detergents Lye or caustic soda Car waxes and polishes Jewelry cleaners Asphalt & roofing tar Leather dyes Paints, varnishes, stains, dyes Fertilizers (if stored outdoors) Paint & lacquer thinners PCB's- Paint & varnish removers, deglossers Other chlorinated hydrocarbons, Paint brush cleaners (inc. carbon tetrachloride) Floor & furniture strippers Any other products with "Poison" labels Metal polishes (including chloroform, formaldehyde, Laundry soil & stain removers hydrochloric acid, other acids) (including bleach) Other products not listed which you feel may Spot removers & cleaning fluids be toxic or hazardous (please list): (dry cleaners) Other cleaning solvents Bug and tar removers Household cleansers, oven cleaners White Copy-Health Department/ Canary Copy-Business � �.��,..�_a _.,...�'�-c. i'.+rrw.v:rrT.rti-++.—..=s..—,✓' --�`.a �. — tir N .. ..n e .,.--w T ..�.... .. e.- »..«,. ... .._ ,s.-.-sky.•....-. ;ti� ..-�,^+.�. . TOXIC AND- HAZARDOUS MATERIALS REGISTRATION FORM Mail To: -NAME OF BUSINESS: '� °�' Board of Health MAILING ADDRESS: 2 ° �'--�-- � ' Town of Barnstable P.O. Box 534 TELEPHONE NUMBER: r 'J 7.; 3 ' CONTACT PERSON: • Hyannis, MA 02601 Does your firm store any of the toxic or hazardous materials listed below, either for sale or for *your own use, in quantities totalling, at any time, more than 50 gallons liquid volume or 25 pounds dry weight? YES NO x This form-'must be returned to the Board of Health regardless of a yes or no answer. Use the, enclosed envelope for your convenience. ' If you answered YES above, please indicate if the materials are stored at a site other than your mailing address. ADDRESS: �'-a' .;r�a •� . ..� ; �' r TELEPHONE: LIST OF TOXIC AND HAZARDOUS MATERIALS n The Board of Health has determined that the following products exhibit toxic or hazardous characteristics and must be registered when stored in quantiti-es=totalling morerthan 0, aligns liquid- - volumeo r 25_pounds ,dry.weig-ht. Please put a check beside each product that you store: Antifreeze 9 for gasoline—or coolants stems Drain cleaners ( systems) Automatic transmission fluid Toilet cleaners Engine and radiator flushes Cesspool cleaners Hydraulic fluid (including brake fluid) Disinfectants Motor oils/waste oils Road Salt (Halite) Gasoline, Jet fuel Refrigerants ' Diesel fuel, kerosene, #2 heating oil Pesticides (insecticides, herbicides, Other petroleum products: grease, lubricants rodenticides) Degreasers for engines and metal Photochemicals (fixers and developers) Degreasers for driveways & garages Printing ink " Battery acid (electrolyte) Wood preservatives (creosote) Y Rustproofers Swimming pool chlorine Car wash detergents Lye or,caustic soda Car waxes and polishes Jewelry cleaners ' Asphalt & roofing tar Leather dyes Paints, varnishes,,stains, dyes-. Fertilizers (if stored outdoors) , Paint & lacquer thinners PCB's _.. Paint.& varnish removers, deglossers Other chlorinated hydrocarbons, Paint brush cleaners. (inc. carbon tetrachloride) Floor & furniture strippers Any other products with "Poison" labels Metal polishes �" ` (including chloroform, formaldehyde, Laundry soil & stain removers ' hydrochloric acid, other acids) (including bleach) M --Other products not listed which you feel may Spot removers & cleaning fluids be toxic or hazardous (please list): (dry cleaners) � � r Other cleaning solvents C_ 14A�5, Bug and tar removers. Household cleansers, oven cleaners White Copy- Health Department/ Canary Copy-Business 1