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0033 BROOKS ROAD - HAZMAT
, ��gd r z6 � zr+r- Number Fee - 1056 THE COMMONWEALTH OF MASSACHUSETTS $150.00 Town of Barnstable Board of Health This is to Certify that Hubbard Oil Co. 33 Brooks Road, Hyannis, MA Is Hereby Granted a License For: Storing or Handling 500 gallons or more of Hazardous Materials. ---------------------------------------------------------------------------------------------------------------------------------------------------------------- --------------------------------------------------------------------------------------------------------------------------------------------------------------- This license is granted in conformity with the Statutes and ordinances relating there to, and and expires 06/30/2017 unless sooner suspended or revoked. ---------------------------------------- WAYNE MILLER,M.D.,CHAIRMAN PAUL J.CANNIFF, D.M.D. 07/01/2016 JUNICHI SAWAYANAGI THOMAS A. MCKEAN,R.S.,CHO Director of Public Health Town of Barnstable Regulatory Services 0 Richard V. Scali, Director MASS.. Public Health Division 1� BAMSTABLE eaawsanc•mianmue•mnm•„rarc a 1639. p�0 wanaiaMnts•oAEtvtuF•wsrwnnsyst � QED MPS ��1(j �0 4 Thomas McKean, Director 771�� 1e 200 Main Street, Hyannis,MA 02601 Office: 508-862-4644 Fax: 508-790-630 APPLICATION FOR PERMIT TO STORE AND/OR UTILIZE HAZARDOUS MATERIALS IN ACCORDANCE.WITH THE TOWN OF BARNSTABLE GENERAL ORDINANCE, CHAPTER 108, HAZARDOUS MATERIALS,ALL BUSINESSES THAT HANDLE OR STORE HAZARDOUS MATERIALS GREATER THAN HOUSEHOLD QUANTITIES ARE REQUIRED TO OBTAIN AN ANNUAL PERMIT(RUNS DULY 1 st—JUNE 30th). APPLICATION FEES CATEGORY 1 PERMIT 26— 110 Gallons: $ 50.00 ❑ CATEGORY 2 PERMIT 111 —499 Gallons: $125.00 ❑ CATEGORY 3 PERMIT 500 or more Gallons: $150.00 �•S' • A late charge of$10.00 will be assessed if payment is not received by July 1st. ASSESSORS MAP AND PARCEL NO. DATE FULL NAME OF APPLICANT: NAME OF ESTABLISHMENT: A) f "V'/ ADDRESS OF ESTABLISHMENT: iS MAILING ADDRESS(IF DIFFERENT); TELEPHONE NUMBER OF ESTABLISHMENT: __�� EMAIL ADDRESS: e✓ec/ � �si9d�, /)�Z� z SOLE OWNER:RYES NO IF NO,NAME OF PARTNER: FULL NAME,HOME ADDRESS,AN) ELEPHONE#OF: CORPORATION NAME , PRESIDENT - TREASURER .F CLERK • IF PREPARED BY OUTSIDE PARTY: SIGN TU OF APPiLICANT Name: Company Address Telephone#: Email: Q:\Application Forms\HAZZAPP Rev I6.docx Page 1 of 2 'W �1 Number Fee 1056 THE COMMONWEALTH OF MASSACHUSETTS 1oo.00 Town of Barnstable Board of Health This is to Certify that Hubbard Oil Co. 33 Brooks Road, Hyannis, MA Is Hereby Granted a License FOR: STORING OR HANDLING 111 GALLONS OR MORE OF HAZARDOUS MATERIALS. ------------------------------------------------------------------------------------------------------------------------------------------------------------------ This license is granted in conformity with the Statutes and ordinances relating there to, and and expires 06/30/2016 unless sooner suspended or revoked. ------------------------------------- WAYNE MILLER,M.D.,CHAIRMAN PAUL J.CANNIFF,D.M.D. 07/01/2015 JUNICHI SAWAYANAGI THOMAS A.MCKEAN, R.S.,CHO Director of Public Health -t?' 6w Town of Barnstable Regulatory Services Richard V. Scali,Director ublic Health Division P r n '� Th�ergg„� �a omas�1Vlc�ea 9' rw •7.k fn tr #S.�i!°� `•,t s i, :w U. 200'Ma1n'Str'ee� 'Hyaluus, Office: 508-862-4644 Fax: 508-790-6304 Application Fee: $100.0.0 �/\ ASSESSORS MAP AND PARCEL NO. DATE APPLICATION FOR PERMIT TO STORE AND/OR UTILIZE MORE THAN III GALLONS OF HAZARDOUS MATERIALS FULL NAME OF APPLICANT aeezz,44,Vd .q �O z[�.nc�a s— NAME OF ESTABLISHMENT 4.9 S2 (c:�e',C_ ADDRESS OF ESTABLISHMENT TELEPHONE NUMBER CSC 7'J�-,.-z,7 SOLE OWNER: YES NO IF APPLICANT IS A PARTNERSHIP,FULL NAMEAND HOME ADDRESS OF ALL PARTNERS: IF APPLICANT IS A CORPORATION: FEDERAL IDENTIFICATION NO.e!� STATE OF INCORPORATION FULL NAME AND HOME ADDRESS OF: ,,�q PRESIDENT `'[" Qa,�7,6 TREASURER kgE4W CLE04 _ SI NATURE OF APPLICANT RESTRICTIONS: HOME ADDRESS171 Jy�p �, �e. �u�Q7dleoa��s HOME TELEPHONE# � C:\cache\Temporary Intemet Fi1es\0LKD3ULVAPP Rev2015.DOC if "t 1 x Town of Barnstable Office: 508-862-4644. Fax: 508-790-6304 Regulatory Services Department Public Health Division �. Mom. Thomas A. McKean,CHO 200 Main Street, Hyannis, MA 02601 �o Mai Payment Receipt jHazardous Materials Payment received: $100.00 (Check) on 7/6/2015 Permit number: 1056 i ;Check number: 1100 Check amount: $100.00 Name on check: H&B Petroleum, Inc. 113usiness: Hubbard Oil Co. ;Address: 33 BROOKS ROAD, Hyannis j 1 I 1 i• Number Fee 1056 THE COMMONWEALTH OF MASSACHUSETTS 1oo.00 Town of Barnstable Board of Health This is to Certify that Hubbard Oil Co. 33 Brooks Road, Hyannis, MA Is Hereby Granted a License FOR: STORING OR HANDLING 111 GALLONS OR MORE OF HAZARDOUS MATERIALS. ------------------------------------------------------------------------------------------------------------------------------------------------------------------- -------------------------------------------------------------------------------------------------------------------------------------------------------------------- This license is granted in conformity with the Statutes and ordinances relating there to, and and expires 6/15/2015 unless sooner suspended or revoked. ---------------------------------------- WAYNE MILLER,M.D.,CHAIRMAN PAUL J.CANNIFF, D.M.D. 6/30/2014 JUNICHI SAWAYANAGI THOMAS A.MCKEAN,R.S.,CHO Director of Public Health J r Town of Barnstable �TraE rq,,, Regulatory Services ti °s Richard V. Scali,Director '"R'''A&& ' Public Health Division i639• ♦0 '°rEn nno+° Thomas McKean, Director 200 Main Street, Hyannis, MA 02601 Office: 508-862-4644 Fax: 508-790-6304 ' Application Fee: $100.00 ASSESSORS MAP AND PARCEL NO. &,.2CP/oZ6 DATE Z o2J=/�Z APPLICATION FOR PERMIT TO STORE AND/OR UTILIZE MORE THAN- 111 GALLONS OF HAZARDOUS MATERIALS FULL NAME OF APPLICANT 3E4Z�e /I ef'L- NAME OF ESTABLISHMENT iJ fi�R d (D1 Z G• aC ADDRESS OF ESTABLISHMENT /"• D. �' / TELEPHONE NUMBER `;�)dr--72 -- SOLE OWNER:-YES NO IF APPLICANT IS A PARTNERSHIP,FULL NAME AND HOME ADDRESS OF ALL PARTNERS: IF APPLICANT IS A CORPORATION: FEDERAL IDENTIFICATION NO. 0 STATE. OF INCORPORATION FULL NAME AND HOME ADDRESS OF: _ PRESIDENT 2h�i�g� s9 11atrRnie2 �� Y�APS/aps A�� �A� oa ,fie/ `?l/���6 TREASURER CLERK d Zr /6,3]5 ��GNATUItEc RESTRICTIONS: HOME ADDRESS ^/ HOME TELEPHONE# 02 8 8 Q:Wpplication Forms\HAZAPP.DOC �i Nu056Number Fee mb THE COMMONWEALTH OF MASSACHUSETTS $loo.00 Town of Barnstable Board of Health This is to Certify that Hubbard Oil Co. 33 Brooks Road, Hyannis,MA 02601 Is Hereby Granted a License FOR: STORING OR HANDLING 111 GALLONS OR MORE OF HAZARDOUS MATERIALS. - ----------------------------------------------- --------------------------------------------------------------------------------------------------------- ---------------------------------------------------------------------------------- ------------------ ----------------------------------------------------------- This license is granted in conformity with the Statutes and ordinances relating there to,and and expires 6/30/2014 unless sooner suspended or revoked. -------------------------------------- WAYNE MILLER,M.D.,CHAIRMAN PAUL J.CANNIFF,D.M.D. 6/30/2013 JUNICHI SAWAYANAGI THOMAS A.MCKEAN, R.S.,CHO Director of Public Health r— Town off'Barnstable o�,HE Regulatory Services Thomas F. Gefler,Diredar ' ion e�Nc,•aars � ]Public Health D1�1� 9 MASS. A 39. Tho-as McKean,DiredDr 2X Main Ste-, Hya=�s, MA 02601 Fes: 508-790-63 04 ofEca: 5088E2-4644 Appjjc;a jan Fee: $100.00 ASSESSORS ASAP A�D P ARCS+L No, oZ DATA+ 6�2 7�1-3 I3PLI�A'IrIO�T FOR PERMU TO STOIC A�/OR UT�,T�' MORE THAT 111 GALLONS OF ILL SOUS MATERLkLS o APPLICANT T`III,I,NA�SE . �� n A� OF EST IL .0• k / w ADDRESS OF ESTABLUaLN ENT c A 0 TELEPHONE NUNOER �5 f- v . SOLE OAR: YES NO IF APPLICANT IS A FAR' ' ,FULL NA1�11�AND HOlyiE ADDRESS OF ALL w PART1'TERS: - I - I IF APPLICANT ISACORPflRATION: FEDERAL IDEN=CATIONNO. STATE OF INCORPORATION 1 I7I�L NAiE AND EONIE ADDRESS OF: PRESIDENT E s1cNATURF,of APTLJC .NT F STRICTIONS: H(DNI ADDRESS 7 HOYE TEII ?HON &,da2 i s i N��aclwp/q I � I I Number Fee 1056 THE COMMONWEALTH OF MASSACHUSETTS $100.00 Town of Barnstable Board of Health This is to Certify that Hubbard Oil Co. 33 Brooks Road, MA 02601 Is Hereby Granted a License FOR: STORING OR HANDLING 111 GALLONS OR MORE OF HAZARDOUS MATERIALS. ----------------------------------------------------------------------------------------------------------------------------------------------------------------- ------------------------------------------------------------------------------ ------------------------------------------------------------------------ This license is granted in conformity with the Statutes and ordinances relating there to, and and expires June 30, 2008 unless sooner suspended or revoked. ---------------------------------------- WAYNE MILLER,M.D.,CHAIRMAN SUMNER KAUFMAN,M.S.P.H. 7/1/2007 PAULJ. CANNIFF,D.M.D. THOMAS A.MCKEAN,R.S.,CHO Director of Public Health Town of Barnstable oFlow%r � Regulatory Services Thomas F. Geiler,Director BARNStABiE, i public Health Division Yd 16 39. 19� Thomas McKean,Director = 200 Main Street, Hyannis,MA 02601 Office: 508-862-4644 _F j Far: 508r30-630- rn Co Application Fee: $100.00 CV 7Q C) co w r ASSESSORS MAP AND PARCEL NO. 3 a DATE �- az� -ezo "� M APPLICATION FOR PERMIT TO STORE AND/OR UTILIZE MORE THAN 111 GALLONS OF HAZARDOUS MATERIALS FULL NAME OF APPLICANT �;� /e�z! ee An d NAiVIE OF ES TADLISHMENT ADDRESS'OFESTABLISHMENT TELEPHONE NUMBER 77�J-&f ZZ SOLE OWNER: YES NO IF APPLICANT IS A PARTNERSHIP, FULL NAME AND HOME ADDRESS OF ALL PARTNERS: 17 h IF APPLICANT IS A CORPORATION:-FEDERAL IDENTIFICATION NO. D a2 �96 STATE OF INCORPORATION FULL NAME AND HOME ADDRESSOF: PRESIDENT ZFRdzehad W. 7-7` a ea/6E �3 91 I 2A Tins a,,21i 1elma- flov1 T/i9 TREASURERQ CLERK �v SIGNATURE OF APPLICANT i RESTRICTIONS: HOME ADDRESS HOME TELEPHONE i BENNETT ENVIRONMENTAL ASSOCIATES, INC. LICENSED SITE PROFESSIONALS,ENVIRONMENTAL SCIENTISTS,GEOLOGISTS,SANITARIANS 1573 Main Street,P.O.Box 1743 (508)896-1706 Brewster,MA 02631 fax(508)896-5109 LETTER OF TRANSMITTAL TO: DATE: JOB NUMBER: Mr.Gerard Martin,Section Chief 10/16/2009 BEA02-3490 B W SC/SMP MA DEP SERO 20 Riverside Drive REGARDING: Lakeville,MA 02347 PHASE V STATUS REPORT TO MAINTAIN REMEDY OPERATION STATUS WITH REMEDIAL MONITORING REPORT SHIPPING METHOD: �' "` Inc?RTN 4-0824(Linked to RTN#4-15370) 7 -33 and-51-Brooks_Road'[Asse ap 328;Parcel-125'and 126] Regular Mail El Pick Up ❑ rHyanra MA 0260P Priority Mail ❑ Hand Deliver ❑ Express Mail ❑ Other uploaded X❑ Certified Mail ❑ Green Card/RR ❑ COPIES DATE DESCRIPTION 1 09/28/09 PHASE V STATUS REPORT TO MAINTAIN REMEDY OPERATION STATUS WITH REMEDIAL MONITORING REPORT Hubbard Oil Company,Inc.-RTN 4-0824(Linked to RTN#4-15370) 33 and 51 Brooks Road[Assessors Map 328,Parcel 125 and 126] Hyannis,MA 02601 For review and comment: ❑ For approval: ❑ As requested: ❑ For your use: ❑X REMARKS: cc: Hubbard Oil,Inc.-Attn:Evelyn Read,General Manager (Full report on CD) Robert A.Fasanella,Esq.-RUBIN&RUDMAN,LLP(Full report on CD) Lieutenant Hubler-Hyannis Fire Department(Narrative,title page,Site plan,transmittal forms only) Thomas McKean-Barnstable Board of Health(Narrative,title page,Site plan,transmittal forms only) John Klimm-Barnstable Town Manager(Narrative,title page,Site plan,transmittal forms only) John Robichaud,Abutter-Robie's Refrigeration(Narrative,title page,Site plan,transmittal forms only) FROM: John Tadema-Wielandt/gjb If enclosures are not as noted,kindly notify us at once v BENNE.TTENVIRONMENTALAssOCIATES, INC.' LICENSED SITE PROFESSIONALS 6 ENVIRONMENTAL SCIENTISTS 6 GEOLOGISTS & SANITARIANS 1573 Main Street-P.O. Box 1743, Brewster, MA 02631 Q 508-896-1706 6 Fax 508-896-5109 www.benneft-ea.com BEA02-3490 September 28, 2009 Mr. Gerard Martin, Section Chief Bureau of Waste Site Cleanup (BWSC)/Sites Management Program(SMP) _ MASSACHliSETTS DEPARTMENT OF ENVIRONMENTAL PROTECTION(MA DEPy o Southeast Regional Office(SERO) > 20 Riverside Drive ` -� Lakeville, MA 02347 a' CM RE: PHASE V STATUS REPORT TO MAINTAIN REMEDY OPERATI N STA .IJS WITH REMEDIAL MONITORING REPORT N Hubbard Oil Company,Inc. -RTN 4-0824 (Linked to RTN#4-15370) rn 33 and 51 Brooks Road [Assessors Map 328,Parcel 125 and 126] Hyannis, MA 02601 Dear Mr. Martin: On behalf of our client, Hubbard Oil Company, Inc. ("Hubbard"), BENNETT ENVIRONMENTAL ASSOCIATES, INC. (herein referred to as BEA) has prepared this Phase V Status Report to maintain Remedy Operation Status for the above referenced Site in accordance with the provisions of 310 CMR 40.0892. This filing documents the remedial response actions and environmental monitoring activities conducted at the Site over the past six (6) months associated with the shutdown of the active bioventing remedial system and suspension of the use of remedial additives towards the recognition that it is infeasible to meet a Class A Response Action Outcome objective as a Permanent Solution wherein GW-1 standards must be achieved. As such, this Phase V Status Report provides the final Remedial Monitoring Report for the use of remedial additives and outlines the continuation of environmental monitoring to evaluate natural attenuation without the benefit of the active remedial system or use of remedial additives. This report also evaluates additional targeted soil and groundwater sampling conducted to further evaluate Substantial Hazards towards a Class C-1, Response Action Outcome. During the past six-month reporting period, laboratory analysis of the downgradient monitoring wells reported fractional Extractable Petroleum Hydrocarbon (EPH) and target analyte concentrations as significantly below the applicable and most restrictive GW-1, Method 1 - Risk Characterization standards or as below reporting limits (BRL) of the analysis. During the June 2009 sampling event, a single downgradient monitoring well (GZA-2) reported concentrations of fractional C9-C10 aromatic Volatile Petroleum Hydrocarbons (VPH) as marginally above the applicable GW-1 Standards. The well was immediately resampled for EPH EMERGENCY SPILL RESPONSE & WASTE SITE CLEANUP 6, SITE ASSESSMENT Q ENVIRONMENTAL PERMITTING Q LAND USE PLANNING WATER SUPPLY DEVELOPMENT,OPERATION&MAINTENANCE 6 WASTEWATER TREATMENT,OPERATION&MAINTENANCE SEPTEMBER 28,2009 HUBBARD-BROOKS ROADBEA08-3490 PAGE 2 OF 14 PHASE V STATUS REPORT and VPH as well as target analytes and reported concentrations of all fractional EPH, target PAHs and fractional VPH and target BTEX compounds as BRL, absolving any condition of Substantial Release Migration (SRM) or practical ingestion exposures associated with the consumption of impacted drinking water. Under Comprehensive Response Actions over the past five years a reduction of contaminant source, through SVE, air sparging and remedial additive applications, has resulted in decreasing concentrations of petroleum hydrocarbons in soils and groundwater. Environmental monitoring over the past several years has characterized "lines of evidence" for stable environmental conditions and attenuation of the dissolved-phase petroleum hydrocarbon plume as documentation of No Substantial Hazard. In September 2008, BEA terminated the air sparging system and the active bioventing system, as based on documented performance, in favor of a passive venting system to evaluate any potential Substantial Hazard in the absence of an active remedial system. Over the reporting period, a spike of fractional VPH was reported in downgradient monitoring well GZA-2 above the applicable GW-1 Standards. The well was retested immediately and reported results of EPH, VPH and all target analytes as BRL. Results of groundwater analyses from the remaining downgradient wells reported groundwater impacts as BRL. Based on the expected lifetime of the reactive barrier (12-months) at the downgradient property line, BEA will continue groundwater monitoring of downgradient and interior monitoring wells to evaluate any potential Substantial Release Migration and Substantial Hazard in the absence of remedial additives in consideration of a Class C RAO as a Temporary Solution. Over the reporting period BEA also performed soil sampling of accessible soils. Results of the soil sampling, in general, reported low concentrations of EPH and VPH with target analytes, with one sample reporting concentrations above the Method 2 Direct Contact Exposure Criteria and the S-1/GW-1 Method 1 Risk Characterization standards. As such, based on the analytical results of these shallow soil samples, it is apparent that the reliance on the locked gate surrounding the property is still required to prevent any potential exposure to human receptors. However, the results of the soil sampling document a reduced area of soil excavation in order to absolve Direct Contact and leaching issues. This Phase V Status Report is an addendum to, and an essential part of, the public record for Site characterization, risk assessment of exposure pathways and corrective remedial efforts under Comprehensive Response Actions as a Tier 1C Site. For the purposes of this Report, the previous information offered is omitted as redundant and summarized only to orient the reader. For specific information on historic environmental assessment activities and remedial response actions, the reader should reference the "Phase I Limited Site Investigation" [LCR (2/20/90)], "Phase I - Initial Site Investigation with Tier Classification" [RAM (8/9/96)], "Immediate Response Action Completion Report" [SEA (8/11/00)], and the Phase lI Scope of Work (9/20/02), Phase H Comprehensive Site Assessment Completion Statement (11/18/02), and Phase III Identification, Evaluation and Selection of Comprehensive Response Actions (2/18/03), Phase IV Implementation of Selected Remedial Action Alternatives (6/23/03), Remedy Operation Status Report I (12/30/03), through Remedy Operation Status Report 111 (3/8/05), Phase IV SEPTENIBER 28,2009 HUBBARD-BROOKS ROADBEA08-3490 PAGE 3 OF 14 PHASE V STATUS REPORT Completion Statement, Remedy Operation Status Report IV (9/27/05), Remedy Operation Status V (3/16/06) Remedy Operation Status VI (9/7/06), Remedy Operation Status Report VII(3/7/07), Remedy Operation Status Report VIII (9/17/07), Remedy Operation Status Report IX (3/21/08), Remedy Operation Status Report X (9/17/08) and the most recent Phase V Status Report (3/26/09) prepared by BENNETT & O'REILLY, INC. as filed with the MA DEP (SERO). As of January 28, 2008, BEA became the successor to BENNETT& O'REILLY, INC. The work represented within this document has proceeded under my supervision in a manner consistent with 309 CMR 4.02 (2), the MCP Response Action Performance Standards (RAPS), pursuant to 310 CMR 40.0191 and Quality Assurance/Quality Control policies of BEA. . The facts and statements herein are, to the best of our knowledge, a true and accurate representation of the current Site activities, remedial response actions and environmental conditions associated with the project. As such, this document serves as the technical justification and rationale for the LSP Opinions represented by the certifications on the Comprehensive Response Action transmittal forms attached relative to current regulations and standard of care practices at the time of filing. PHASE V OPERATION,MAINTENANCE AND ENVIRONMENTAL MONITORING Consistent with the Operation, Maintenance and Environmental Monitoring Plan set forth, BEA performed periodic Site inspections during the reporting period to assess environmental conditions and conduct prescribed soil and groundwater sampling in consideration of remedial system performance and exposure risks. Three Site inspections were conducted on June 10, June 12, and July 6, 2009. These inspections, and specific daily activities, are documented on field reports in Appendix B. The following is a summary of significant events during the past six months. SITE INSPECTIONS Reactive Barrier On May 7, 2008, BEA personnel were at the Site with ADH Drilling to replenish the reactive barrier at the downgradient property line. The reactive barrier consisted of 500 lbs. of Regenesis' Oxygen Releasing Compound Advanced (ORC-A) injected to the groundwater. interface between 23 to 25 feet below grade surface (bgs) at the downgradient property line and within each of the source areas in Zone A and Zone B, as recommended by Regenesis. During.the sampling 'event on June 10, 2009, downgradient monitoring wells MW-5S, MW-6S(R) and GZA-2 on the Robies Refrigeration property were sampled for remedial additive use pursuant to 310 CMR 40.0046 and as specified in the Phase IV Remedy Implementation Plan. No adverse impacts associated with remedial additive use have been observed as measured by magnesium, which is the primary compound of ORC. Given the longevity of ORC-Advanced is estimated at up to 12 months, BEA has evaluated the effectiveness of the additive by monitoring dissolved oxygen (DO) concentrations in these downgradient monitoring wells [Refer 4 , SEPTEMBER 28,2009 HUBBARD-BROOKS ROADBEA08-3490 PAGE 4 OF 14 PHASE V STATUS REPORT to the Environmental Monitoring section of this report]. Based on the elevated concentrations of DO reported, it appears that the ORC may still be active and there is currently no plan to replenish the remedial additives at this time in order to evaluate natural attenuation. Additional field-testing, groundwater sampling and analysis of interior well water quality in May 2009, will be used in the consideration Substantial Hazards with the depletion of the remedial additive and in the absence of active bioventing. Bioventing Sstem Over the past three years of operation, concentrations of petroleum hydrocarbons in soil have been reduced to below the applicable S2 and S3/GW-1 and GW-3 Method 1 Risk Characterization Standards, with the exception of surficial soils (0-6') and soils at the groundwater interface (18-25'). Although some reductions through treatment or attenuation are apparent, the benefits of active treatment relative to O&M costs were not justified, as No Substantial Hazards were apparent. As such, on September 12, 2008 the active Bioventing system was shut down in favor of a passive venting system using a wind driven turbine vent erected above the roofline of the garage building. BEA personnel conducted regular monthly Site inspections at the Hubbard Site since September 2005 prior to the discontinuation of the active system. Each time, the vacuum, pressure and magnahelic flow gauges on the regenerative blower were checked and recorded on Bioventing System 0&M Inspection Reports previously documented. The final system inspection was conducted on September 12, 2008, prior to the shutdown of the active bioventing system. A graphic representation of TOV concentrations over time is shown below. Hubbard Oil Co., Brooks Road -TOV Tracking at All SVE Points 600 500 - - s +. - A 1S Q. 400 _ _ _ A1D T-AAN lD C w _ _. _. ` �-83S C -�B3D t417 200 �l - —+—B4S C O B4D 100 p 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 o a o 0 0 0 0 0 0 0 0 0 0 0 0 o a o 0 o 0 0 0 o a o 0N 0N 0y 0 0 0 0 0 0 0 0 ti y N ti t N ti ti L N y N N N N y N y N_ N N y N y y � N N N N 9 ti N N Q ti ti `y v� :p n" 47 G ' C7 y i" �D a PS Date 1 ' SEPTEMBER 28,2009 HUBBARD-BROOKS ROADBEA08-3490 PAGE 5 OF 14 PHASE V STATUS REPORT Air-Sparging Syste The air sparging pilot study was also terminated on September 12, 2008. The pilot study began on February 16, 2007, as specified in the ROS Status Report VI (9/7/06). The sparging point (AS-1) was installed approximately ten feet northwest (upgradient) of monitoring well SEA-1 and approximately ten feet southeast of bioventing points SVE B-3S and D. BEA elected to abandon the air sparging system at the Site in favor of a passive venting system and engineering controls after monthly sampling and then quarterly sampling showed no significant further decreases in fractional petroleum hydrocarbons. ENVIRONMENTAL MONITORING/RISK CHARACTERIZATION [APPENDIX B & D] On June 10, 2009 BEA personnel were on Site to complete semi-annual groundwater sampling of select downgradient monitoring wells in review of potential exposure pathways, as specified in the Environmental Monitoring section of the previous Remedy Operation Status report. Downgradient monitoring wells GZA-1, GZA-2, MW-5 S/D and MW-6S(R)/D on the Robies Refrigeration property were gauged, purged, and sampled for EPH with target-4 poly aromatic hydrocarbons (PAHs) and VPH with target BTEX analytes. Remedial additive testing was also performed in downgradient monitoring wells as previously noted. Perimeter Monitoring_Wells Results of the June 10, 2009 semi-annual sampling event indicated that all concentrations of fractional EPH and target-4 PAH analytes in all perimeter monitoring wells were below the reporting limits of the analysis or as significantly below the applicable GW-1 and GW-3 Method 1 Risk Characterization Standards. In each case, the reported value or reporting limit was significantly less than the applicable GW-1 and GW-3 standards, with one exception. Concentrations of fractional VPH C9-C10 aromatics were detected in monitoring well GZA-2 at 211 mg/L, above the applicable GW-1 Standard of 200 mg/L. Monitoring well GZA-2 was resampled on July 6, 2009 along with proximal monitoring well GZA-3 to the northeast. Concentrations of EPH and target PAHs and fractional VPH and all target BTEX analytes were reported as BRL in the retest results. A summary of groundwater laboratory analysis is presented in Appendix D of this report. Interior Monitoring Wells On June 12, 2009 BEA personnel were at the Site to complete sampling of selected interior groundwater monitoring wells, to assess concentrations of petroleum hydrocarbons close to the identified source areas. Monitoring wells MW-1, MW-2, SEA-1, SEA-2, MW-4 were sampled for EPH(carbon range only) and VPH(carbon range only). ' 1 SEPTEMBER 28,2009 HUBBARD-BROOKS ROADBEA08-3490 PAGE 6 OF 14 PHASE V STATUS REPORT Results of the June 12, 2009 sampling event reported concentrations of fractional EPH in interior monitoring wells MW-1, SEA-1 and SEA-2 as above the applicable GW-1 Method 1 Risk Characterization Standards. Concentrations of fractional EPH were reported as BRL in interior monitoring wells MW-2 and MW-4 wherein the reported value or reporting limit was significantly less than the applicable GW-1 and GW-3 standards. Concentrations of fractional VPH were reported above the applicable GW-1 Method 1 Risk Characterization Standards in monitoring wells SEA-1 and SEA-2. Concentrations of fractional VPH and all target BTEX compounds were reported as BRL in interior monitoring wells MW-I, MW-2 and MW-4 wherein the reported value or reporting limit was significantly less than the applicable GW-1 and GW-3 standards. A graphic representation of C 11 to C22 fractional EPH in monitoring well SEA-1 is shown below. EPH CI To C22 Fractional Aromatics in SEA-1 Over Time .25,000 _ 23,400 20,000 J . 15,000 - C O C 10,000 - 9,600 ORC InJe�lona V 7,300 ;7,200 .��f A19 5/7IQ6 - 5,000 QI 'i lh.]@5 11 9 2100 "�43�3,840 3,400 330 r PC 1,500 1,6 000 p - Od-02 Feb-04 Nov-04 May-05 Nov-05 May-06 Nov-06 Mar-07 Apr-07 May-07 Sep-07 Nov-07 Feb-08 Jun-08 Jun-09 Date Soil R On June 12, 2009 BEA personnel were at the Site to perform shallow soil sampling in areas of identified historic soil impact. It is reported that releases occurred at the fueling rack during transfers of product to trucks owned by Hubbard. Three hand borings were performed in the identified areas of impact,Zone A and Zone B, from grade to between four and six feet below grade. Hand boring HB-1 was performed in the northeastern portion of Zone B east of the existing fuel transfer pump. HB-2 was performed in the western central portion of Zone B and HB-3 was performed in the eastern central portion of'Zone B. Field screening results from Zone B reported concentrations of TOVs from background conditions (1.4 ppm) in HB-1 to 53.7 ppm SEPTEMBER 28,2009 HUBBARD-BROOKS ROADBEA08-3490 PAGE 7 OF 14 PHASE V STATUS REPORT in HB-3:0-2' bgs. Hand boring HB-4 was performed in the central portion of Zone A in the vicinity of the former diesel ASTs. Hand borings HB-5 and HB-6 were performed in the southeastern and Southwestern portion of Zone A in the vicinity of a former loading rack. Field screening results reported concentrations of TOVs from background concentrations (1.1 ppm) to 41.3 ppm in HB-5: 24' bgs. Samples were placed in the appropriate preserved containers and forwarded to Groundwater Analytical Laboratories in Buzzards Bay, MA for EPH and VPH analysis. Results of the shallow soil sampling reported concentrations of fractional EPH, VPH and all target BTEX and PAH analytes as below the applicable Method 1 S-1/GW-1 Risk Characterization Standards with one exception. Concentrations of EPH C9-C18 fractional aliphatics were reported in the Zone A- HB-6: 04' sample at 1,200 mg/kg. These concentrations are marginally above the applicable S-1/GW-1 standards of 1,000 mg/kg as well as the Method 2 Direct Contact standards for S-1 soils. Microbial Respiration Analysis No respiration analysis was performed over the reporting period. The bioventing system was shut down on September 12, 2008, as such no further respiration analysis is proposed. Previous analysis of soils collected from SVE A-1 and SVE B-3 indicated sufficient indigenous bacteria with a lack of sufficient nutrients. As such, supplemental nutrient additions were made, by introducing a low-strength fertilizer through the soil vapor points, during monthly Site inspections. The final injection of nutrients was performed on September 12, 2008. REMEDIAL SYSTEM PERFORMANCE SoilBio-venting The bioventing remedial system treating soil impact at the Site was suspended in September 2008. The system had been operating since September 2005. Over the past three years decreasing concentrations of EPH and VPH were documented during the yearly soil sampling events. The last soil sampling was performed on July 7, 2008 to qualify the reduction of petroleum concentrations in vadose zone soils in the areas of identified impact. As previously noted, soil sampling was conducted via three test borings; two in Zone B (TB-6C and TB-8C) and one in Zone A (TB-11C). Samples were collected in two-foot intervals, every five feet and then composited into three distinct intervals (3-5', 8-15' and 18-25') for analysis. Soil samples were analyzed for EPH and VPH and the results were compared with samples collected from similar locations during Phase II activities conducted in October 2002 and performance sampling conducted in May 2006 and May 2007. The July 2008 soil-sampling event reported that significant levels of petroleum impact remain in shallow soils (3-5' bgs) in Zone A because the bioventing remedial system was not designed or constructed to adequately treat shallow soil impact as readily accessible. SEPTEMBER 28,2009 HUBBARD-BROOKS ROADBEA08-3490 PAGE 8 OF 14 PHASE V STATUS REPORT Concentrations of residual soil impact in the intermediate and deeper depths in Zones A and B responded well to the bioventing system with concentrations of fractional EPH and VPH concentrations below the applicable S-2 and S-3 Method 1 Risk Characterization Standards, with the exception of TB-8C: 18-25' (350 ug/L), which remains marginally above the S-3/GW-1 standard of 300 ug/L,most likely due to groundwater impact at the Site. BEA previously recommended the mechanical removal of surficial soils and the construction of an infiltration system and engineered barrier at the Site to eliminate the direct contact exposures and absolve the potential leaching of contaminants within the soils to groundwater as a chronic and persistent source of groundwater impact. Most recently,the cost to benefit of such work has been revisited under the context of Feasibility wherein static or attenuating groundwater impact is apparent and limited to a discreet area. The facility is surrounded by a six-foot high chain link fence topped with barbed wire fence as effectively limiting dermal contact exposures to Site workers. Over the reporting period, BEA performed shallow soil sampling in the areas of surficial soil impacts for comparison to the Method 2 Direct Contact Exposure Criteria. Results of EPH and VPH analysis from the shallow soil samples reported concentrations of EPH C 11 to C22 fractional aromatics marginally above the applicable Method 2 Direct Contact Exposure Criteria for S-1 soils. In all other samples concentrations of fractional EPH/VPH and all target analytes were reported below the Method 2 Direct Contact Standards. As such, based on the most recent results, BEA is considering reducing the area of soil removal and construction of an engineered barrier as previously proposed in moving the project towards a Class C-1, RAO. Such work and recommendations for isolation of residually impacted soils is being made in consideration of future use and redevelopment of the property. A tablemaker report is included for reference in Appendix D. Groundwater/Reactive Barrier BEA conducted an air sparging pilot study, in consideration of feasibility to treat groundwater, which was suspended in September 2008. The air sparging system operated for 18- months upgradient of monitoring well SEA-1 to evaluate if groundwater impact may be treated more effectively. The influence of the supplemental sparge treatments was further evaluated by regular groundwater sampling for treatment performance. Results of the air sparging system pilot study did not indicate any significant reductions in fractional EPH and VPH. As such, the air sparging system was suspended in September 2008 and a Class C RAO alternative is currently ` being considered, as equally effective in absolving potential exposure risks and maintaining No Substantial Hazard. The remedial additive ORC-Advanced was replenished as a reactive barrier at the downgradient property line as well as within the source area in May 2008 based on laboratory analytical results of downgradient perimeter monitoring wells indicating the diminishing capacity of the ORC-Advanced to act as an oxygen barrier. Results of groundwater sampling of f SEPTEMBER 28,2009 HUBBARD-BROOKS ROADBEA08-3490 PAGE 9 OF 14 PHASE V STATUS REPORT downgradient monitoring wells reported concentrations of fractional C9-C 10 aromatics above the applicable Method 1 GW-1 Risk Characterization Standards in GZA-2. Subsequent sampling of the GZA-2 well reported no concentrations of EPH or VPH fractions or target analytes above the method detection limits. Based on the retesting results, reporting all VPH/EPH/target analytes as BRL, no condition of Substantial Release Migration (SRM) is apparent. BEA will continue to monitor the downgradient monitoring wells on a semi-annual basis for SRM. If additional results report concentrations of petroleum hydrocarbons above the applicable standards, BEA will consider replenishing the ORC wall to avoid migration of significant levels of petroleum hydrocarbons towards the Maher Wellfield. Remedial Additive Monitoring During the June 2009 sampling event, the perimeter monitoring wells were sampled for wet chemistry in accordance with the provisions for remedial additive use, 310 CMR 40.0046. Wet chemistry analysis included dissolved magnesium. Concentrations of- wet chemistry parameters observed over the reporting period have been consistent with baseline/background concentrations indicating no significant degradation of water quality associated with remedial treatments downgradient of the treatment area. Wet chemistry tracking charts are included for reference in Appendix D. RISK CHARACTERIZATION AND REVIEW OF SUBSTANTIAL HAZARD Groundwater Contaminant concentrations in groundwater sampling of central wells SEA-1 and SEA-2, located immediately downgradient of the source areas on the Hubbard property, have been significantly fluctuating since they were first sampled in 2002. Regardless, Mann-Kendall statistical evaluations of laboratory results from 2002 through current data indicate a negative nineteen (49) value at SEA-1 and a negative nineteen (49) value at SEA-2, representing statistically decreasing concentrations of petroleum hydrocarbons at these locations [Refer to Tables 5 and 6]. Table 5: Mann-Kendall Worksheet for SEA-1 (TPH) Date 10/02 2/04 11/04 5105 11/05 5/06 11/06 3/07 4/07 5/07 9/07 11/07 2/07 6/08 6/09 Totals Conc. 6.4 26.0 23.0 12.0 39.0 11.9 5.19 4.66 9.41 34.70 3.65 7.36 15.1 14.6 5.21 (mom) 6A +1 +1 +1 +1 +1 -1 -1 +1 +1 -1 +1 +1 +1 -1 +6 26.0 1 -1 -1 +1 -1 -1 -1 -1 +1 -1 -1 -1 -1 -1 -9 23.0 -1 +1 -1 -1 -1 -1 +1 12.0 +1 -1 1 1 -1 +1 SEPTEMBER 28,2009 HUBBARD-BROOKS ROADBEA08-3490 PAGE 10 OF 14 PHASE V STATUS REPORT Table 5: Mann-Kendall Worksheet for SEA-1 TP Date 10/02 2/04 11/04 5105 11105 5/06 11/06 3/07 4/07 5/07 9/07 11/07 2/07 6/08 6/09 Totals Conc. 6.4 26.0 23.0 12.0 39.0 11.9 5.19 4.66 9.41 34.70 3.65 7.36 15.1 14.6 5.21 (mg/L) 39.0 -1 -1 -1 -1 -1 -1 -1 -1 -1 -1 -10 11.9 -1 -1 -1 +1 -1 -1 +1 +1 -1 -3 5.19 -1 +1 +1 -1 +1 +1 +1 +1 +4 4.66 -1 +1 -1 +1 +1 +1 +1 +3 9.41 +1 -1 -1 +1 +1 -1 +1 34.70 -1 -1 -1 -1 -1 -5 3.65 +1 +1 +1 -1 +2 7.36 +1 +1 -1 +1 15.1 x -1 -1 -2 14.6 -1 -1 5.21 Total -19 Table 6: Mann-Kendall Worksheet for SEA-2 (TPI) Date 10/02 2/5/04 11/04 5105 11105 5/06 11/06 5/07 11/07 6/08 6/09 Totals Conc. 40.0 6.45 81.0 2.1 2.6 33.4 1.27 3.22 11.2 1.59 1.66 (mg/L) 40.0 1 +1 -1 +1 -1 -1 -1 -1 -1 -1 -6 6.45 +1 -1 -1 +1 -1 -1 +1 -1 -1 -3 81.0 -1 -1 -1 -1 -1 -1 -1 -1 -8 2.1 +1 +1 -1 +1 +1 -1 -1 +1' 2.6 +1 -1 +1 +1 -1 -1 0 33.4 -1 -1 -1 -1 -1 -5 1,27 +1 +1 +1 +1 +4 3.22 +1 -1 -1 -1 11.2 -1 -1 -2 1.59 +1 +1 1.66 Total -19 SEPTEMBER 28,2009 HUBBARD-BROOKS ROADBEA08-3490 PAGE 11 OF 14 PHASE V STATUS REPORT. During the reporting period, and throughout testing conducted over the past seven years, all concentrations of EPH and VPH and associated target analytes in downgradient monitoring wells have been consistently reported as at or below the applicable GW-1 and GW-3, Method 1 - Risk Characterization standards. Concentrations of fractional VPH were reported marginally above the Method 1 GW-1 Standard in a single monitoring well in June of this year. However, a retest of the well reported concentrations of EPH or VPH as BRL. In addition, based on the statistical evaluation of petroleum hydrocarbon reduction in the source areas and the absence of impacts in downgradient monitoring wells, an attenuating plume of reduced size and decreasing groundwater concentrations is indicated. As such, there is presently no Condition of Substantial Release Migration nor any Critical Exposure Pathway is apparent. As such, presently there is no Substantial Hazards associated with residual static or attenuation groundwater impacts under current Site conditions and uses relative to potential ingestion, inhalation or dermal contact exposures to identified human receptors or significant environmental impacts to ecological receptors. Soils Although there may be potential human exposures associated with surficial soil impacts, these areas are publicly restricted, with no children present, by a gated six foot chain-link fence topped with barbed wire, with No Trespassing signs along the perimeter of the property which is patrolled and monitored during business operations and locked at all other times. Employees of Hubbard have been advised of environmental hazards. BEA has also recommended the removal . of shallow accessible soils (0-3' bgs) to negate issues related to petroleum impact in these surficial soils. Therefore, there is neither a condition of Imminent Hazard nor any Substantial Hazards associated with the Site under current Site conditions, conditioned upon restricted access by locked fencing, signage, patrolling and monitoring of the area of release area on the subject property. FUTURE OPERATION, MAINTENANCE AND ENVIRONMENTAL MONITORING Bio-venting_System Operation&Maintenance: As previously noted, the active bioventing system has been suspended and replaced with a passive wind-driven turbine vent erected above the roofline of the garage building at the Site. Results of the May 2008 soil analysis indicate concentrations of fractional EPH and VPH as below the applicable Method 1 S-2 and S-3 Risk Characterization Standards with the exception of the shallow surficial soils, which the bioventing system cannot effectively treat, as well as at the TB-8C location at the groundwater interface. BEA was also injecting a nutrient solution into the subsurface in the form of a low-strength fertilizer poured into the shallow bioventing points. The final addition of the nutrient solution was performed in September 2008 and the nutrients are no longer being applied. As such, no additional remedial additive monitoring will be conducted in downgradient wells for nitrate or phosphate. SEPTEMBER 28,2009 HUBBARD-BROOKS ROADBEA08-3490 PAGE 12 OF 14 PHASE V STATUS REPORT Environmental Monitoring: Soil Results of the May 2008 soil sampling event report concentrations of fractional EPH and VPH at the TB-11 (Zone A) locations as greater than the Method 1 Risk Characterization Standards and the Method 2, Direct Contact standards (S-2). Results of the most recent soil sampling conducted in June 2009 continue to report concentrations of EPH fractional aromatics above the Method S-1/GW-1 and Method 2 Direct contact standards in Zone A near TB-11. Although there may be potential human exposures associated with surficial soil impacts, access to these areas are publicly restricted by locked fencing, signage, patrolling and monitoring of the area of release area on the subject property. Further soil (and groundwater) sampling may be used in consideration of modifying or eliminating the planned removal of the surficial soils and engineered barrier in favor of an Activity and Use Limitation with Site Health and Safety and Soil Management Plans as an alternative to assure No Substantial Hazard under a Class C-1, RAO condition. This alternative is currently being investigated under potential redevelopment of the property. Environmental Monitoring: Groundwater As reported in the previous Remedy Operation Status Report, Semi-annual (May,/November) groundwater monitoring of the downgradient perimeter monitoring wells GZA- 1, GZA-2, MW-5 S/D and MW-6S(R)/D will be conducted for EPH with target 4 PAHs and VPH analysis with target BTEX analytes. In addition, central monitoring wells SEA-1, SEA-2, MW-1, MW-2 and MW-4 will be sampled for VPH/EPH analysis with all targets on an annual basis in May. All sampling will be accompanied by field measurements of dissolved oxygen, pH, conductivity and temperature. Based on the projected life span of the ORC-Advanced estimated to be up to 12-months, no more remedial additive monitoring will be conducted. Subsequent to the anticipated lifetime of the reactive barrier, BEA will monitor for any rebound or evidence of any migration in downgradient monitoring wells through the projected time of travel to evaluate natural attenuation without any active remedial systems. Soil Removal with Engineered Barrier and Infiltration SyLtern Remedial efforts under Comprehensive Response Actions over the past five years have resulted in the significant reduction of petroleum hydrocarbons in soils and groundwater. However, reducing groundwater concentrations below the Method 1 GW-1 groundwater standards to meet a Class A, RAO is apparently infeasible at the present time as based on cost to benefit analysis of continuing an active remedial strategy. SEPTEMBER 28,2009 HUBBARD-BROOKS ROADBEA08-3490 PAGE 13 OF 14 PHASE V STATUS REPORT Environmental monitoring over the past three years has indicated "lines of evidence" for stable environmental conditions and attenuation of the petroleum hydrocarbon plume. Based on the premise of technical infeasibility, BEA has recommended the removal of surficial contaminated soils for the construction of an engineered barrier to effectively cap the area of soil contamination to protect against potential dermal exposures and leaching to groundwater in support of a Class C, Response Action Outcome. Based on the most recent sampling results of shallow soils, it appears that the area of soil removal can be reduced to smaller areas in Zones A and B. Competitive bids have been solicited for the recommended response actions and the results of the analysis with the bids and specifications including cross-sections and groundwater flow plans were previously sent to Hubbard. BEA is prepared to implement the removal of the more heavily impacted, easily accessible (0-3') soils at the Site as well as the construction of the engineered barrier and infiltration system originally proposed in the Remedy Implementation Plan (6/23/03). The implementation of such recommendations remains under review by Hubbard. The mechanical removal of a nominal amount of impacted soils may also be used in conjunction with an Activity and Use Limitation to effectively manage Significant Risk and maintain No Substantial Hazard. Assuming the facility will remain a fuel storage and transfer facility or remain in commercial use, the AUL is a more cost effective alternative in eliminating potential exposure risks used under the Class C-1, RAO. SUMMARY AND CONCLUSION Remedial efforts under various response actions conducted over the past five years have resulted in the reduction of petroleum hydrocarbons in soils and groundwater. Environmental monitoring, however, has indicated "lines of evidence" for stable environmental conditions and attenuation of the dissolved-phase petroleum hydrocarbon plume. Based on limitations caused by technical infeasibility to meet a Permanent Solution given current and foreseeable GW-1 standards, BEA has recommended moving the project into a Class C, Response Action Outcome as a Temporary Solution. In September 2008, BEA terminated the air sparging system and the active bioventing system, in favor of a passive venting due to the limited effect of the air sparging point to treat groundwater and the inability of the active bioventing system to treat surficial soils. Over the next reporting period BEA will continue to monitor groundwater on a semi-annual basis to monitor any potential Substantial Release Migration and Substantial Hazards in moving towards a Class C-1, RAO. Periodic groundwater sampling will be documented over the next six months and reported in a Phase V Status Report in March 2010. The LSP opinions represented by this report are established by the certifications made on the Comprehensive Response Action [BWSC-108] Transmittal Form. The LSP opinions are based upon available data and regulations in effect at the time of this reporting. Should you have SEPTEMBER 28,2009 HUBBARD-BROOKS ROADBEA08-3490 PAGE 14 OF 14 PHASE V STATUS REPORT any questions or require any further information, please contact me directly. Sincerely, BE i TT E IRONMENTAL ASSOCIATES,INC. 1 vid ennett, LSP Jo D. Tade a-Wie dt Principal Project Manager Encl. Supporting Appendices [A through E] r cc: Hubbard Oil, Inc. -Attn: Evelyn Read, General Manager 1 Robert A. Fasanella,Esq. -RUBIN&RUDMAN, LLP 1 Lieutenant Hubler-Hyannis Fire Department 2 Thomas McKean- Barnstable Board of Health 2 John Klimm- Barnstable Town Manager 2 John Robichaud, Abutter- Robie's Refrigeration 2 . r 1 Full report 2 Report Narrative,Transmittal Forms and Site Plan PHASE V STATUS REPORT TO MAINTAIN REMEDY OPERATION STATUS WITH REMEDIAL MONITORING REPORT SUPPORTING DOCUMENTATION RTN 4-0824/4-15370 Hubbard Oil Co.,Inc. 33 & 51 Brooks Road[Assessors Map 328,Parcel 125& 126] Hyannis,MA.02601 Project#BEA02-3490 SEPTEMBER 28,2009 Prepared BY: BENNETT ENVIRONMENTAL ASSOCIATES,INC. 1573 Main Street P.O.Box,1743 Brewster,MA 02631 David C.Bennett,LSP. Prepared For: Mr. Gerard Martin,Chief Sites Management&Permitting Section,BWSC Massachusetts Department of Environmental Protection(MA DEP) Southeast Regional Office(SERO) Bureau of Waste Site Cleanup(BWSC)/Sites Management Program(SMP) 20 Riverside Drive Lakeville,MA 02347 On Behalf Of: Hubbard Oil Co.,Inc. P.O.Box 10-Hyannis,MA 02601 Evelyn Read,General Manager APPENDIX A:Reference Plans -Figure 1: Site Locus Plan from USGS Topographic Quad.,Hyannis-Excerpt(TOPO 1998) -Figure 2:MA DEP BWSC GIS Map,Hyannis-Excerpt(MA DEP 9/29/00) Figure 3:Water Table Contour Map Excerpt,Town of Barnstable, 1992 - Site Plan ROS-1 `Comprehensive Response Actions...", Prepared by BENNETT ENVIRONMENTAL ASSOCIATES,INC.,Dated March 16,2006(rev.09/10/09) APPENDIX B: Field Reports -Field Inspection Reports:#74(6/10/09), #75(6/12/09),and#76(7/6/09) -Monitor Well Sampling Log:6/10/09,7/6/09 APPENDIX C: Environmental Records -BWSC-108:Comprehensive Response Actions Transmittal Form -BWSC-108A:Remedial Monitoring Report Transmittal Forms(1) APPENDIX D:Laboratory Analysis -Table 1:EPH analysis summary-Perimeter Groundwater Monitoring Wells -Table 2:VPH analysis summary-Perimeter Groundwater Monitoring Wells -Table 3:EPH analysis summary-Central Groundwater Monitoring Wells -Table 4:VPH analysis summary-Central Groundwater Monitoring Wells -Table 5:EPH analysis summary-Soil -Table 6:VPH analysis summary-Soil -Tablemaker report for shallow soil sampling on 6/12/2009 -Wet chemistry Tracking Charts-Perimeter wells[GZA-2,MW-5S,MW-6S(R)] -Groundwater Analytical Laboratory Reports: [Groundwater—6/26/09,6/29/09,7/21/09] [Soil—7/l/09] APPENDIX E:Quality Assurance/Quality Control LiMassachusetts Department of Environmental Protection Bureau of Waste Site Cleanup BWSC108 COMPREHENSIVE RESPONSE ACTION TRANSMITTAL Release Tracking Number FORM & PHASE I COMPLETION STATEMENT F j Pursuant to 310 CMR 40.0484(Subpart D)and 40.0800(Subpart H) A. SITE LOCATION: 1. Site Name:JATWOOD OIL (HUBBARD OIL CO INC) _ 2. Street Address: 133 BROOKS RD 3. City/Town: HYANNIS 4. ZIP Code: 1026010000 5. Check here if a Tier Classification Submittal has been provided to DEP for this disposal site. 1-1 a. Tier IA ❑ b. Tier IB ❑ c. Tier IC d. Tier II 6. If applicable,provide the Permit Number: B.THIS FORM IS BEING USED (check all that apply) 1. Submit a Phase 1 Completion Statement,pursuant to 310 CMR 40.0484. 2. Submit a Revised Phase I Completion Statement,pursuant to 310 CMR 40.0484. 3. Submit a Phase II Scope of Work, pursuant to 310 CMR 40.0834. ❑ 4. Submit an interim Phase II Report. This report does not satisfy the response action deadline requirements in 310 CMR 40.0500. 5.Submit a final Phase II Report and Completion Statement,pursuant to 310 CMR 40.0836. 6.Submit a Revised Phase II Report and Completion Statement, pursuant to 310 CMR 40.0836. 7. Submit a Phase III Remedial Action Plan and Completion Statement,pursuant to 310 CMR 40.0862. 8. Submit a Revised Phase III Remedial Action Plan and Completion Statement, pursuant to 310 CMR 40.0862. 9. Submit a Phase IV Remedy Implementation Plan, pursuant to 310 CMR 40.0874. 10. Submit a Modified Phase IV Remedy Implementation Plan,pursuant to 310 CMR 40.0874. 11. Submit an As-Built Construction Report,pursuant to 310 CMR 40.0875. 12. Submit a Phase IV Status Report,pursuant to 310 CMR 40.0877. 13. Submit a Phase IV Completion Statement,pursuant to 310 CMR 40.0878 and 40.0879. Specify the outcome of Phase IV activities:(check one) a. Phase V Operation, Maintenance or Monitoring of the Comprehensive Remedial Action is necessary to achieve a Response Action Outcome. b. The requirements of a Class A Response Action Outcome have been met. No additional Operation, Maintenance or Monitoring is necessary to ensure the integrity of the Response Action Outcome. A completed Response Action Outcome Statement and Report(BWSC104)will be submitted to DEP. c. The requirements of a Class C Response Action Outcome have been met. No additional Operation, Maintenance or Monitoring is necessary to ensure the integrity of the Response Action Outcome. A completed Response Action Outcome Statement and Report(BWSC104)has been or will be submitted to DEP. d. The requirements of a Class C Response Action Outcome have been met. Further Operation, Maintenance or Monitoring of the remedial action is necessary to ensure that conditions are maintained and that further progress is made toward a Permanent Solution. A completed Response Action Outcome Statement and Report (BWSC104)has been or will be submitted to DEP. Revised:4/1/2009 Page 1 of 5 Massachusetts Department of Environmental Protection Bureau of Waste Site Cleanup BWSC108 COMPREHENSIVE RESPONSE ACTION TRANSMITTAL Release Tracking Number FORM & PHASE I COMPLETION STATEMENT Pursuant to 310 CMR 40.0484(Subpart D)and 40.0800(Subpart H) B.THIS FORM IS BEING USED TO(cont.):(check all that apply) 14. Submit a Revised Phase IV Completion Statement,pursuant to 310 CMR 40.0878 and 40.0879. R✓ 15. Submit a Phase V Status Report,pursuant to 310 CMR 40.0892. ❑✓ 16. Submit a Remedial Monitoring Report. (This report can only be submitted through eDEP.) a.Type of Report: (check one) Ej i. Initial Report [] ii. Interim Report ✓0 iii. Final Report b. Frequency of Submittal: (check all that apply) i. A Remedial Monitoring Report(s)submitted monthly to address an Imminent Hazard. ii. A Remedial Monitoring Report(s)submitted monthly to address a Condition of Substantial Release Migration. ✓Z iii. A Remedial Monitoring Report(s)submitted concurrent with a Status Report c.Status of Site: (check one) i. Phase IV Z ii. Phase V iii. Remedy Operation Status iv. Class C RAO d. Number of Remedial Systems and/or Monitoring Programs: 1 I A separate BWSC108A,CRA Remedial Monitoring Report,must be filled out for each Remedial System and/or Monitoring Prcgram addressed by this transmittal form. ❑ 17. Submit a Remedy Operation Status,pursuant to 310 CMR 40.0893. n 18. Submit a Status Report to maintain a Remedy Operation Status,pursuant to M 0 CMR 40.0893(2). 19. Submit a Transfer and/or a Modification of Persons Maintaining a Remedy Operation Status(ROS), pursuant to 310 CMR 40.0893(5)(check one,or both, if applicable). a. Submit a Transfer of Persons Maintaining an ROS(the transferee should be the person listed in Section D, "Person Undertaking Response Actions"). b. Submit a Modification of Persons Maintaining an ROS(the primary representative should be the person listed in Section D,"Person Undertaking Response Actions"). c. Number of Persons Maintaining an ROS not including the primary representative: ® 20. Submit a Termination of a Remedy Operation Status, pursuant to 310 CMR 40.0893(6).(check one) a. Submit a notice indicating ROS performance standards have not been met. A plan and timetable pursuant to 310 CMR 40.0893(6)(b)for resuming the ROS are attached. b. Submit a notice of Termination of ROS. (� 21. Submit a Phase V Completion Statement,pursuant to 310 CMR 40.0894. Specify the outcome of Phase V activities: (check one) a. The requirements of a Class A Response Action Outcome have been met. No additional Operation, Maintenance or Monitoring is necessary to ensure the integrity of the Response Action Outcome. A completed Response Action Outcome Statement(BWSC104)will be submitted to DEP. b. The requirements of a Class C Response Action Outcome have been met. No additional Operation,Maintenance or Monitoring is necessary to ensure the integrity of the Response Action Outcome. A completed Response Action Outcome Statement and Report(BWSC104)will be submitted to DEP. c. The requirements of a Class C Response Action Outcome have been met. Further Operation, Maintenance or Monitoring of the remedial action is necessary to ensure that conditions are maintained and/or that further progress is made toward a Permanent Solution. A completed Response Action Outcome Statement and Report(BWSC104)will be submitted to DEP. 22. Submit a Revised Phase V Completion Statement, pursuant to 310 CMR 40.0894. 23. Submit a Post-Class C Response Action Outcome Status Report,pursuant to 310 CMR 40.0898. Revised: 4/1/2009 Page 2 of 5 Massachusetts Department of Environmental Protection Bureau of Waste Site Cleanup BWSC108 COMPREHENSIVE RESPONSE ACTION TRANSMITTAL Release Tracking Number FORM & PHASE I COMPLETION STATEMENT - Pursuant to 310 CMR 40.0484(Subpart D)and 40.0800(Subpart H) C. ILSP SIGNATURE AND STAMP: I attest under the pains and penalties of perjury that I have personally examined and am familiar with this transmittal form, including any and all documents accompanying this submittal. In my professional opinion and judgment based upon application of(i)the standard of care in 309 CMR 4.02(1), (ii)the applicable provisions of 309 CMR 4.02(2)and(3),and 309 CMR 4.03(2),and(iii)the provisions of 309 CMR 4.03(3),to the best of my knowledge,information and belief, > if Section B indicates that a Phase 1,Phase 11,Phase III,Phase IV or Phase V Completion Statement and/or a Termination of a Remedy Operation Status is being submitted,the response action(s)that is(are)the subject of this submittal (i)has(have)been developed and implemented in acccrdance with the applicable provisions of M.G.L.c.21 E and 310 CMR 40.0000,(ii)is(are) appropriate and reasonable to accomplish the purposes of such response action(s)as set forth in the applicable provisions of M.G.L. c.21 E and 310 CMR 40.0000,and (iii)comply(ies)with the identified provisions of all orders, permits,and approvals identified in this submittal; > if Section B indicates that a Phase H Scope of Work or a Phase IV Remedy Implementation Plan is being submitted,the response action(s)that is(are)the subject of this submittal(i)has(have)been developed in accordance with the applicable provisions of M.G.L.c.21 E and 310 CMR 40.0000, (ii)is(are)appropriate and reasonable to accomplish the purposes of such response action(s)as set forth in the applicable provisions of M.G.L.c.21 E and 310 CMR 40.0000,and(iii)comply(ies)with the identified provisions of all orders,permits,and approvals identified in this submittal; > if Section B indicates that an As-Built Construction Report, a Remedy Operation Status,a Phase IV,Phase V or Post-Class C RAO Status Report,a Status Report to Maintain a Remedy Operation Status,a Transfer or Modification of Persons Maintaining a Remedy Operation Status and/or a Remedial Monitoring Report is being submitted,the response action(s)that is (are)the subject of this submittal(i)is(are)being implemented in accordance with the applicable provisions of M.G.L.c.21 E and 310 CMR 40:0000, (ii)is(are)appropriate and reasonable to accomplish the purposes of such response action(s)as set forth in the applicable provisions of M.G.L.c.21E and 310 CMR 40.0000,and(iii)comply(ies)with the identified provisions of all orders,permits, and approvals identified in this submittal. I am aware that significant penalties may result,including, but not limited to, possible fines and imprisonment,if I submit information which I know to be false,inaccurate or materially incomplete. 4303 1. LSP#. �+ ' DAVID C h 'i _ _f BENNET,T r 2. First Name: ��- --, � � � 3. Last Name: _ _ , ., 5088961706 h �' 4. Telephone: 5. Ext. ., 6. FAX: 7. Signature. - ;s r r _ 8. Date: 9. LSP Stamp: (mm/dd/yyyy) Revised:4/1/2009 Page 3 of 5 Massachusetts Department of Environmental Protection Bureau of Waste Site Cleanup BWSC108 COMPREHENSIVE RESPONSE ACTION TRANSMITTAL Release Tracking Number FORM $ PHASE I COMPLETION STATEMENT —-- - - - - Pursuant to 310 CMR 40.0484(Subpart D)and 40.0800(Subpart H) D. PERSON UNDERTAKING RESPONSE ACTIONS: 1. Check all that apply: ® a.change in contact name b.change of address ❑ c. change in the person undertaking response actions 2. Name of Organization: HUBBARD OIL COMPANY INC 3. Contact First Name: EVELYN 4.Last Name: READ 5. Street: PO BOX 10 6.Title: 7. City/Town: HYANNIS 8. State: MA 9. ZIP Code: 026010000 10. Telephone: 8002877103 11. Ext.: 12. FAX: E. RELATIONSHIP TO SITE OF PERSON UNDERTAKING RESPONSE ACTIONS: Check here to change relationship Q1. RP or PRP a. Owner 0 b. Operator c. Generator d. Transporter e. Other RP or PRP Specify: 2. Fiduciary,Secured Lender or Municipality with Exempt Status(as defined by M.G.L. c.21 E,s. 2) 3. Agency or Public Utility on a Right of Way(as defined by M.G.L.c.21 E,s.50)) 4. Any Other Person Undertaking Response Actions Specify Relationship: F. REQUIRED ATTACHMENT AND SUBMITTALS: 1. Check here if the Response Action(s)on which this opinion is based,if any,are(were)subject to any order(s), permit(s) and/or approval(s)issued by DEP or EPA. If the box is checked,you MUST attach a statement identifying the applicable provisions thereof. ❑✓ 2. Check here to certify that the Chief Municipal Officer and the Local Board of Health have been notified of the submittal of any Phase Reports to DEP. 3. Check here to certify that the Chief Municipal Officer and the Local Board of Health have been notified of the availability of a Phase III Remedial Action Plan. 4. Check here to certify that the Chief Municipal Officer and the Local Board of Health have been notified of the availability of a Phase IV Remedy Implementation Plan. 5. Check here to certify that the Chief Municipal Officer and the Local Board of Health have been notified of any field work involving the implementation of a Phase IV Remedial Action. ❑ 6. If submitting a Transfer of a Remedy Operation Status (as per 310 CMR 40:0893(5)), check here to certify that a statement detailing the compliance history for the person making this submittal(transferee)is attached. ❑ 7. If submitting a Modification of a Remedy Operation Status(as per 310 CMR 40.0893(5)),check here to certify that a statement detailing the compliance history for each new person making this submittal is attached. ❑ 8. Check here if any non-updatable information provided on this form is incorrect,e.g.Site Name. Send corrections to: BWSC.eDEP@state.ma.us. ❑✓ 9. Check here to certify that the LSP Opinion containing the material facts,data, and other information is attached. Revised:4/1/2009 Page 4 of 5 r' f Massachusetts Department of Environmental Protection Bureau of Waste Site Cleanup BWSC108 Release Tracking Number COMPREHENSIVE RESPONSE ACTION TRANSMITTAL FORM & PHASE I COMPLETION STATEMENT IL Pursuant to 310 CMR 40.0484(Subpart D)and 40.0800(Subpart H) G. CERTIFICATION OF PERSON UNDERTAKING RESPONSE ACTIONS: 1. 1 1 ,attest under the pains and penalties of perjury(i)that I have personally examined and am familiar with the information contained in this submittal, including any and all documents accompanying this transmittal form, (ii)that, based on my inquiry of those individuals immediately responsible for obtaining the information,the material information contained in this submittal is,to the best of my knowledge and belief,true,accurate and complete,and(iii)that I am fully authorized to make this attestation on behalf of the entity legally responsible for this submittal. I/the person cr entity on whose behalf this submittal is made am/is aware that there are significant penalties, including,but not limited to, possible fines and imprisonment,for willfully submitting false,inaccurate,or incomplete information. >if Section B indicates that this is a Modification of a Remedy Operation Status(ROS), I attest under the pains and penalties of perjury that I am fully authorized to act on behalf of all persons performing response actions under the ROS as stated in 310 CMR 40.0893(5)(d)to receive oral and written correspondence from MassDEP with respect to performance of response actions under the ROS,and to receive a statement of fee amount as per 4.03(3). 1 understand that any material received by the Primary Representative from MassDEP shall be deemed received by all the persons perform ing response actions under the ROS,and I am aware that there are significant penalties,including,but not limited to, possible fines and imprisonment,for willfully submitting false, inaccurate or incomplete information. GENERAL MANAGER 2• By — 3. Title: Signature 4. For: HUBBARD OIL COMPANY INC 5. Date: (Name of person or entity recorded in Section D) (mm/dd/yyyy) 6. Check here if the address of the person providing certification is different from address recorded in Section D. 7. Street: 8. City/Town: 9. State: 10. ZIP Code: 11. Telephone: 12.Ext.: 13. FAX: YOU ARE SUBJECT TO AN ANNUAL COMPLIANCE ASSURANCE FEE OF UP TO$10,000 PER BILLABLE YEAR FOR THIS DISPOSAL SITE. YOU MUST LEGIBLY COMPLETE ALL RELEVANT SECTIONS OF THIS FORM OR DEP MAY RETURN THE DOCUMENT AS INCOMPLETE. IF YOU SUBMIT AN INCOMPLETE FORM,YOU MAY BE PENALIZED FOR MISSING A REQUIRED DEADLINE Date Stamp(DEP USE ONLY:) Revised: 4/1/2009 Page 5 of 5 I Massachusetts Department of Environmental Protection Bureau of Waste Site Cleanup BWSC108A CRA REMEDIAL MONITORING REPORT Release Tracking Number Pursuant to 310 CMR 40.0800(SUBPART H) Remedial System or Monitoring Program: Q of: A. DESCRIPTION OF ACTIVE REMEDIAL SYSTEM OR ACTIVE REMEDIAL MONITORING PROGRAM: 1. Type of Active Remedial System or Active Remedial Monitoring Program:(check all that apply) ❑ a. Active Remedial System:(check all that apply) ® I.NAPL Recovery ❑ ii. Soil Vapor Extra ction/Bioventing ® iii. Vapor-phase Carbon Adsorption ® iv.Groundwater Recovery ❑ v. Dual/Multi-phase Extraction ❑ vi. Aqueous-phase Carbon Adsorption ❑ vii.Air Stripping ® viii. Sparging/Biosparging ® ix. Cat/Thermal Oxidation ❑ x. Other Describe: F ® b. Application of Remedial Additives:(check all that apply) ❑ i.To the Subsurface ❑ ii. To Groundwater(Injection) ❑ iii. To the Surface ® c. Active Remedial Monitoring Program Without the Application of Remedial Additives:(check all that apply;Sections C,D and E are not required;attach supporting information,data,maps and/or sketches needed by checking Section 175) ❑✓ i.Reactive Wall ❑ ii. Natural Attenuation ❑ iii. Other Describe: 2. Mode of Operation:(check one) ❑ a. Continuous ❑ b. Intermittent ❑ c. Pulsed ® d. One-time Event Only ❑ e. Other: 3. System Effluent/Discharge:(check all that apply) ❑ a.Sanitary Sewer/POTW ❑ b.Groundwater Re-infiltratioi/Re-injection:(check one) ® I. Downgradient ® ii. Upgradient ❑ c. Vapor-phase Discharge to Ambient Air:(check one) ® i. Off-gas Controls ® ii. No Off-gas Controls ❑ d. Drinking Water Supply ® e. Surface Water(including Storm Drains) ❑ f. Other Describe: B. MONITORING FREQUENCY: 1. Reporting period that is the subject of this submittal: From: 3/18/2009 —� To: �9/18/2009 (mm/dd/yyyy) (mm/dd/yyyy) 2. Number of monitoring events during the reporting period:(check one) ® a.System Startup:(if applicable) ❑ i. Days 1,3,6,and then weekly thereafter,for the first month. ❑ ii. Other Describe: Qb.Post-system Startup(after first month)or Monitoring Program: ❑ i.Monthly ❑ ii.Quarterly ✓0 iii. Other Describe: BIANNUALY BASED ON PREPONDERANCE OF EVIDENCE ®✓ 3. Check here to certify that the number of required monitoring events were conducted during the reporting period. C. EFFLUENT/DISCHARGE REGULATION:(check one to indicate how the effluent/discharge limits were established) ® 1.NPDES: (check one) ® a. Remediation General Permit ❑ b. Individual Permit — ® c. Emergency Exclusion Effective Date of Permit: mm/dd ❑ 2. MCP Performance Standard MCP Citations(s): ❑ 3. DEP Approval Letter Date cf Letter: mm/dd/ ❑✓ 4. Other Describe: MA DRINKING WATER STANDARDS MAGNESIUM Revised: 2/9/2005 Page 1 of 3 - - Massachusetts Department of Environmental Protection Bureau of Waste Site Cleanup BWSC108A CRA REMEDIAL MONITORING REPORT Release Tracking Number Pursuant to 310 CMR 40.0800(SUBPART H) Remedial System or Monitoring Program: 1 1 of:l I D. WASTEWATER TREATMENT PLANT OPERATOR:(check one) ® 1. Required due to Remedial Wastewater Treatment Plant in place for more than 30 days. a. Name: _ b. Grade: c. License No.: �� d.License Exp.Date: 2. Not Required (mm/dd/yyyy) 3. Not Applicable E. STATUS OF ACTIVE REMEDIAL SYSTEM OR ACTIVE REMEDIAL MONITORING PROGRAM DURING REPORTING PERIOD: (check all that apply) ❑ 1.The Active Remedial System was functional one or more days during the Reporting Period. a. Days System was Fully Functional: b.GW Recovered(gals): c. NAPL Recovered(gals): r d.GW Discharged(gals): e.Avg.Soil Gas Recovery Rate(scfm): f. Avg.Sparging Rate(scfm) ® 2.Remedial Additives: (check all that apply) a. No Remedial Additives applied during the Reporting Period. b.Enhanced Bioremediation Additives applied:(total quantity applied at the site for the current reporting period) L Nitrogen/Phosphorus: ii.Peroxides: Name of Additive . Date Quantity Units Name of Additive Date Quantity Units r iii. Microorganisms: ® iv.Other: Name of Additive Date Quantity Units Name of Additive Date Quantity Units c.Chemical oxidation/reduction additives applied:(total quantity applied at the site for the current reporting period) ❑ i. Permanganates: ❑ ii. Peroxides: Name of Additive Date Quantity Units Name of Additive Date Quantity Units ® iii. Persulfates: ® iv.Other: Name of Additive Date Quantity Units Name of Additive Date Quantity Units Revised: 2/9/2005 Page 2 of 3 �C*wT�4^'y^'Yr.�TVt.4r.Y�ryKYr1��r ry F -r.�-..,-.-._�1.r���...-'.1•'-'�1,i"" -K .TOWN OF BARNSTABLE - UNDERGROUND FUEL AND CHEMICAL STORAGE REGISTRATION MAP NO. PARCEL NO. ADDRESS OF TANK: P poo S 'G V I LLAGE: 0 A v) f) i_` NumbdPr Ytr��t MAILING ADDRESS ( IF DIFFERENT FROM ABOVE) : l J 4 , 1 GL3 OWNER NAME: �7oop re i Pa L-om rn . nr PHONE: I NSTALLAT I ON._.DATE: BY: INSTALLER ADDRESS: -CERT.NO. *TANK LOCATION: A�QV�Q Roo �4 C) (oaacm z n& 7^NK LOOAT Z ON W S TH ACOP¢CT TO mU Z_LD S NCO CAPAC ICY� TYPE OF TANK -5T'eeF L AGE n+ YRS. FUEL/CHEM I CAL )1 F L? .� TESTING CE'RTI�F-ACATION [ ] PASS. [ ] FAIL DATE LEAK DETECTI`0N31,j[VCHECK IF N/A TYPE/BRAND ZONE OF CON'TRJZBUT ION [ ] YES_j� t 1--N;0'---- DA1 E -TO. BE REMOVED FIRE DEPT. PERMXT ISSUED C ] 'YjES¢, r [ �.I NO DATE CONSERVATION [ ] CHECK_.IF.l N/A �/7 � DATE ; !' s BOARD OF HEALTH TAG NO. C t' ] DATE '"' y' % ""� C2 PLEASE PROVIDE A SKETCH SHOWING. THE TANK LOCATION ON THE BACK OF THIS CARD i /off, A3ov�— �/tov�D Le6 F16 S i TOWN. OF BARNSTABLE —UNDERGROUND FUEL AND CHEMICAL STORAGE REGISTRATION NO. R3. PARCEL NO. ADDRESS OF TANK: ��)0-00�, i t. .'� .a Qx VILLAGE: lit A� yt MAILING: ADDRESS CIF D I FFERE{NT FROM ABOVE},<: -13 .� OWNER NAME: o U R.N t --Y� �T4�^2 t.� ?t f ► _ � PHONE: , 1 6'-- f7r l 5"0) C) a__�i 1 INSTALLATION DATE: BY: INSTALLER ADDRESS: -CERT.140. *TANK LOCATION: h 6 y e QRQ OI('` Q �---- c acscw 2 UK TANK LOOAT 2 ON W 2 TH RCGPCCT TO i (. . CAPACITY u� TYPE OF TANK S?'EFC, AGE '° YRS. FUEL/CHEM I CAfL TESTINGICERTIFICATION C ] PASS C ] FAIL DATE LEAK DETECTION C ] CHECK IF N/A TYPE/BRAND r ZONE OF CONTRIBUTION C ] YES C ] NO DATE TO BE REMOVED FIRE DEPT. PERMIT ISSUED C ] YES C ] NO DATE CONSERVATION C ] CHECK IF N/A DATE BOARD OF HEALTH TAG NO. C � ] DATE PLEASE PROVIDE A SKETCH SHOWING THE TANK LOCATION ON THE BACK OF THIS CARD W a 0 - o TOWN OF BARNSTABLE - UNDERGROUND FUEL AND CHEMICAL STORAGE REGISTRATION MAP NO. tR37-? PARCEL ADDRESS OF TANK: 1(1,00 k ll� I V I LLAGEr: i~I�f r� 1 Number ;�tr��t f t s f{ MAILING ADDRESS ( IF DIFFaEREN,Tfi FROM ABOVE)_: )c. 1 OWNER NAME: 11Zb }64 C PHONE: ! d"U? -Zl 42 1 91— � INSTALLATION DATE: BY: fJ. INSTALLER ADDRESS: 'CERT.140. *TANK LOCATION: t ('�uG.C1)Zou f) '` (D69Ql�=1raC TANK LOQAT2ON WSTH PfCOPQCT TO mUZ'C D'Z`1V0")�"------ �r+++ . CAPACITY TYPE OF TANK STE+E L AGE YRS. FUEL/CHEMICALL ((' i. 1 TESTING CERTIFICATION C 7 PASS C ] FAIL DATE --7- - LEAK DETECTION C 7 CHECK IF N/A TYPE/BRAND ZONE OF CONTRIBUTION [ ] YES [ ] NO DATE TO BE REMOVED FIRE DEPT. PERMIT ISSUED [ ] YES C 7 NO DATE CONSERVATION [ ] CHECK IF N/A DATE BOARD OF HEALTH TAG NO. C la 7C J ] DATE �' PLEASE PROVIDE A SKETCH .SHOWING THE TANK LOCATION ON THE BACK OF THIS CARD f VV a 7 IQ _7/10$F v A do va (�qo unl 0 r TOWN OF BARNSTABLE - UNDERGROUND FUEL AND CHEMICAL STORAGE REGISTRATION MAP NO. PARCEL NO. laA ADDRESS OF TANK: 69.00 1� t.S 0A) VILLAGE: i"t Y, 1N /,4 .S Number / Y!r^mm! r MAILING ADDRESS '( I F DIFFERENT FROM ABOVE)': OWNER NAME cj T f/�� / t2 % l � t> A4 , PHONE: _5-0,P ;7 -5 0/R . R INSTALLATION DATE: BY: INSTALLER ADDRESS: -CERT.1-40. *TANK LOCATION: Ri-,nyt-. 6 koUhl-z (owsom Z um TANK LOQAT=ON W S TH mammacT TO nu S LD 2 NO) CAPACITY TYPE ZF TANK -5T6�F t. AGE YRS. FUEL/CHEMICAL TEST G CER'T.,IFICATION [ ] PASS [ ] FAIL DATE LEAK DETEGT�ION- C ] CHECK IF N/A TYPE/BRAND -'IZONE �OF CONVtI HUT I ON [ ] YES [ ],, NO,,,< DATE TO BE REMOVED J �F I RE DEPT. PERMIT ISSUED C ]} YES,;, ]. NO DATE ONSERVATION [ ] CHECK IF N/A DATE BOARD OF 1HEALTH TAG NO. [ ,� /� ] DATE PLEASE PROVIDE A SKETCH SHOWING THE TANK LOCATION ON THE BACK OF THIS CARD 9 63 T,at. £3oUE Rb,,►�� _ .. . .-. tom.-,. �_..f.--1NY+r....-j.•r.i, -..*.r:.-:ry.y.r..+,-►'P,.•�-yiTiti+:..I'r6hn1'arn•.,d��te• rir1, .•''""^'—_�,.,_,.,.r..�...,,,_....»�i�"`_'_..-"_r"_.�" _.,,r. 1.•-1M?\..`• TOWN OF BARNSTABLE - UNDERGROUND FUEL AND CHEMICAL STORAGE REGISTRATION MAP NO. ; PARCEL NO. I Q tea ADDRESS OF TANK: V I LLAGE: T'`4t,Aki n S MAILING ADDRESS ( I F DIFFERENT FROM ABOVE) : ell (?)C1?L. IA 3 R OWNER NAME: lkoL&-U m 0,v • -t- PHONE: 5V -71 S'"0 1 - INSTALLATION DATE: BY: INSTALLER ADDRESS,: 'CERT.NO. *TANK LOCATION: I j/r1lQ . rrrII 40 _ (DCmOPt 2 ma TANK LOQAT Z ON W Z TH mmuRaCT TO mu 2 L�D,�`NCR) CAPACITY `� TYPE OF TANK .STcEC AGE C� YRS. FUEL/CHEMICAL "•-f111._. TESTING CERTIFICATION [ ] PASS C ] FAIL DATE LEAK DETECTION [-,] HECK IF N/A TYPE/BRAND ZONE OF CONTRIBUTION [ ] YES C ] NO DATE TO BE REMOVED 1` FIRE DEPT. PERMIT ISSUED C ] YES C ] NO DATE CONSERVATION C ] CHECK IF N/A DATE BOARD OF HEALTH TAG NO. C �� ] DATE PLEASE PROVIDE A SKETCH SHOWING THE TANK LOCATION ON THE BACK OF THIS CARD 'J IV) 0_ I I � TOWN OF BARNSTABLE UNDERGROUND FUEL AND CHEMICAL STORAGE REGISTRATION MAP NO. i\ PARCEL NO. ADDRESS OF TANK: Bp'no�-'s --I�o,Z" VILLAGE: Nuntbmr strmqnt MAILING ADDRESS ( IF DIFFERENT FROM ABOVE) OWNER NAME: 1 a IQ N ! u r - fMC_. PHONE: 9-'R` �5—019 c r hq INSTALLATION DATE: BY: t =' INSTALLER ADDRESS: -,CERT NO. STANK LOCATION: t��+n,��-?�,�,.� �� A1.+ 4 ) jlr `t d�acmoPi z nQ TANK LOOAT I ON W I TN PfQOP°QCT.. T.O.'mL�7 LD I NO) CAPACITY '-NO TYPE OF TANK AGE Q YRS. FUEL/CHEMICAL f TESTING CERTIFICATION Cw PASS C ] FAIL DATE t IZhJ 1190 LEAK DETECTION Ud CHECK IF N/A TYPE/BRAND ZONE OF CONTRIBUTION C ] YES C ] NO DATE TO` BE REMOVED F , FIRE DEPT. PERMIT ISSUED C ] YES C ] NO DATE E CONSERVATION C ] CHECK IF N/A DATE HOARD OF HEALTH TAG N0. C ] DATE r �e PLEASE PROVIDE A SKETCH SHOWING THE TANK LOCATION ON THE BACK OF THIS CARD 61 I 0 4v� v 1 ` 1 ' PHASE II SCOPE OF WORK - COMPREHENSIVE SITE ASSESSMENT TIER I MINOR PERMIT MODIFICATION SUPPORTING DOCUMENTATION RTN 4-0824 1 Hubbard Oil, Inc. 33 & 51 Brooks Road Hyannis, MA ' Project#: B002-3490 SEPTEMBER 20,2002 1 1 t 1iaENNETT A OJREILI:�Y Inc. 1 Engineering, Environmental & Surveying Services 1573 Main Street Sanitary 21E/Site Remediafion Property Line PO Box 1667Brewster,MA 02631 � Site Development Hydrogeologic Survey Subdivision $; ' Waste Water Treatment Water Quality Monitoring Land Court 508-896-6630 Water Supply Consulting Trial Court Witness 508-896-4687 Fax . 1 f� L— & OTREILLY, INC. Engineering &-.Environmental-Services- LETTER OF 1573 Main Street,P.O. Box 1667 Brewster,MA 02631 TRANS IITTAL (508) 896-6630 FAX 508) 896-4687 TO: DATE: JOB NUMBER: Ms.Laura Stanley 9/20/02 fl002 3490 . Massachusetts Department of Etwironnienta Protection Southeast Regional.Office(SERO) Bureau of Waste Site Cleanup(BWSC) REGARDING:... 20 Riverside Drive Phase 11-Scope.of Work/Tier 1 Minor Permit Modification - 33&-5-1 Brooks Road-RTN 4-0824 We are sending you. Hyannis,MA Phase II Scope of Work/Tier i Minor Permit Modification COPIES DATE DESCRIPTION 1 9/20/02 Phase 11 Scope cf Work/Tier 1 Minor Permit Modification For review and comment: ❑ For approval.-M. As requested:❑. For your use:❑ REMARKS: cc.Hubbard Oil,Inc. -Attn:Evelyn_Read + Lieutenant Huber-Barnstable Fire Department- Thomas McKean--Barnstable.Board of Health. John Klimm.-Barnstable Town Manager - John Robichaud-Robie's Petroleum From:- John-D.Tadema-Wielandt ENNET T n0 'RE I L LY, Inc, Engineering, Environmental & Surveying Services G 1573 Main Street Q I ' Sanitary 21E/Site Remediation Property Line PO Box 1667Brewster, MA 02631 Site Development Hydrogeologic Survey Subdivision Q Waste Water Treatment Water Quality Monitoring Land Court 508-896-6630 Water Supply Licensed Site Professional Trial Court Witness 508-896-4687 Fax B002-3490 ' September 20, 2002 ' Ms. Laura Stanley Massachusetts Department of Environmental Protection Southeast Regional Office (SERO) ' Bureau of Waste Site Cleanup (BWSC) 20 Riverside Drive Lakeville, MA'02347 RE: PHASE II SCOPE OF WORK COMPREHENSIVE SITE ASSESSMENT/ TIER I MINOR PERMIT MODIFICATION Hubbard Oil Co., Inc. -- RTN 4-0824/4-15370 33 & 51 Brooks Road [Assessors Map 328, Parcel 125 & 126] Hyannis, MA. 02601 Dear Ms. Stanley, ' On behalf of our client, Hubbard Oil Co., Inc., BENNETT&O'REILLY,INC. has prepared the following Phase II Scope of Work/Tier I Minor Permit Modification in accordance with the ' provisions of 310 CMR 40.0830 and 40.0725, respectively. The Phase II - Scope of Work summarizes the environmental assessment to be conducted in association with the above referenced site with a specific timetable for the implementation of testing activities and the reporting of ' findings. Assessment activities are designed to qualify the source(s) of contamination, determine the extent and present magnitude of soil and groundwater impact associated with the historic use of the subject property as a bulk fuel storage facility and establish current subsurface and hydrogeologic conditions at the site and review of exposures to identified environmental and human receptors. The Tier I Minor Permit Modification is for the purpose of changing the LSP of Record. The Phase 11 Comprehensive Site Assessment will assess the present risk to public health, ' safety, welfare and the environment and to re-evaluate any critical exposure pathways associated with current conditions. As may be appropriate from risk characterization,this information will be used to conceptualize, pilot and make preliminary review of various remedial strategies towards ' Phase III of Comprehensive Response Actions to mitigate significant'environmental hazards,if any. The technical rational and justification for such work is to determine the quality of subsurface conditions at the property to determine the risk of harm posed to health,safety,public welfare or the 1 i 1 ' SEPTEMBER 20,2002 HUBBARD OIL,INC.B002-3490 PAGE 2 OF 7 PHASE II-SCOPE OF WORK ' environment and to bring the site into regulatory compliance. Records presented by various consultants were reviewed in the generation of this Phase II Scope of Work(SOW). These reports represent the period from December 1989 [Phase I Limited Site Investigation (LCR, Inc.)], [Phase 1 I Initial Site Investigation Report and Tier Permit Application(RAM Environmental)August 19961, through August 2000 [IRA Completion Report (SEA Consultants, Inc.) RTN 4-0824/4-15370]. It is assumed that the information reported and on record with the MA DEP,as represented by the work ' of other professionals and persons familiar with the properties,may be relied upon as a thorough and accurate representation of significant facts. ' SITE DESCRIPTION The subject properties are located at 33 and 51 Brooks Road in Hyannis,MA. The properties are located approximately 250 feet east of the intersection of Mary Dunn Road and Brooks Road in the Town of Hyannis,MA [Refer to Site Locus Plan-Appendix A]. The two parcels of land contain approximately 0.71 and 0.67 acres of.land, respectively, with frontage along Brooks Road. The ' parcels are identified on the Town of Hyannis Assessors' Map 328 as Parcels 126 and 125, respectively. 1 The parcel identified as 33 Brooks Road(Map 328,Parcel 126)consists of a 0.71 acre parcel of land. According to RAM Environmental,this parcel was developed in 1929 and operated by Shell ' Oil Co. as a fuel oil depot supplying gasoline and fuel oil to gas stations and other retail operations. In 1941 the property was purchased by B. W. Atwood and continued to be operated as a fuel oil depot. In 1959 a railroad spur was added to the railway abutting the property, to allow fuel oil 1 delivery by freight car to the former storage tanks at the property. At the time of the"Phase I Initial Site Investigation Report" conducted by RAM Environmental (8/96), the parcel was being used as a fuel oil storage depot. At that time,the parcel contained a two-story wood and brick framed office ' building, a single-story wood and concrete framed storage garage and a wood framed pumping station/loading rack. At the time of RAM's Phase I investigation, the site also contained a 106,635 gallon aboveground storage tank (AST) used for the storage of No. 2 fuel oil. According to the 1 RAM report several tanks have historically existed at the site including: Six ASTs used for the storage and distribution of fuel oil; one 275 gallon No. 2 fuel oil underground storage tank(UST) servicing the oil burner at the site(The SEA report indicates that this is a septic tank and that a 275 ' AST existed in the basement of the site building); One 550 gallon kerosene UST; and one 1,000- gallon waste oil UST. According to the RAM report all of the USTs were removed in August 1992 by EnviroSafe Corp. of Sagamore Beach, MA and all of the ASTs were removed in May1995, by ' EnviroSafe. No tank disposal receipts were available for the tanks. The RAM report also references LCR's 1990 Phase I report which identifies several areas of soil staining at the property. The parcel identified as 51 Brooks Road(Map 328,Parcel 125)consists of a 0.67 acre parcel of land. At the time of the "Phase I Initial Site Investigation Report" conducted by RAM ' Environmental (8/96), the parcel was being used for the storage of petroleum marketing supplies. Site plans associated with both previous reports[RAM-PH-1 (8/96)and SEA-IRAC(8/00)]indicate 5 former ASTs at the property, however no narrative is provided on the historic use or removal of I SEPTEMBER 20,2002 HUBBARD OIL,INC./13002-3490 PAGE 3 OF 7 PHASE 11-SCOPE OF WORK ' such vessels in either report. According to Evelyn Read,the General Manager of Hubbard 011,Inc., these tanks contained diesel fuel and were removed prior to 1986. As part of the proposed Phase II, a formal review of Fire Department records will be made. ' Currently, 33 Brooks Road contains a two-story office building, a single story garage, a pumping station/loading rack,and the 100,000-gallon AST. Access to the site is restricted by a fence ' along the property line. The 51 Brooks Road property is undeveloped with all petroleum marketing and fuel storage appurtenances removed. Land uses in the vicinity include commercial,residential ' and industrial. Abutting properties to the east include two residential properties, to the south is a commercial office building, to the west is an active railroad line, owned and operated by the Old Colony Railroad Company and to the north is an undeveloped property. ' ENVIRONMENTAL SETTING Review of the Geologic Map of Cave Cod & the Islands. Massachusetts, 1986, by Oldale ' and Barlow, indicates the area is underlain by Barnstable Plain Deposits,typified by mostly gravelly sand and pebble to cobble gravel and locally includes boulders. The site is characterized by the Soil ' Survey of Barnstable County, Massachusetts, 1993,as CcA-Carver loamy coarse sand,typified by very deep, nearly level, excessively drained soil generally in broad areas on outwash plains but is also in areas of sandy glacial lake deposits. These glacial outwash sands typically display hydraulic conductivities between 50-200 ft/day with associated groundwater flow velocity between 100-200 ft/year. Slug testing conducted by SEA in June of 2000 indicates an average hydraulic conductivity of 28.2 ft/day and a groundwater velocity of approximately 120 feet/year at the site. Supplemental aquifer characterization will be included as part of this Phase II investigation. Review of regional groundwater contours indicate a southerly groundwater flow direction, ' toward Lewis Bay, some 3/4 mile south (see Figure 3). Site specific groundwater flow has been determined to be in a generally southeasterly direction at approximately 20 feet below grade surface (bgs). According to the MA DEP BWSC 2 1 e GIS overlay map, both parcels appear to be fully ' within a designated Non-Potential Drinking Water Source Area(NPDWSA). Both parcels are also depicted as being within the DEP Approved Wellhead Protection Area (Zone II) of the Maher Wellfield,containing 3 Public Water Supply Wells,located approximately 250 feet southeast of the ' site. A significant area of land east of the site including the Barnstable Municipal Airport is also designated as NPDWSA. ' A review of potential ingestion,dermal contact,inhalation hazard and frequency and intensity of use was conducted to evaluate applicable Method 1 - Risk Characterization standards. The presence of children was established, as a conservative measure, with low frequency and low ' intensity of use for determination of soil standards. As such, the S-3 soil category is applicable to potentially accessible soils from 3-15'below grade in unpaved areas and from 0-15'in paved areas, ' as well as to isolated soils greater than 15' below grade or soils underlying buildings or permanent structures. In review of groundwater exposure, MA DEP 21 E GIS mapping indicates the area as a NPDWSA, however since the site is within the boundaries of a Zone 2 of a Public Water Supply t 1 SEPTEMBER 20,2002 HUBBARD OIL,INC.BO02-3490 PAGE 4 OF 7 PHASE fI-SCOPE OF WORK Well, the GW-1 ingestion standards are applicable. Based on a depth to groundwater at a depth greater than 15' below grade, the GW-2 inhalation standards are excluded. The GW-3 Method 1 - g Risk Characterization Standard for dermal contact is also applicable to groundwater beneath the site. BACKGROUND [Refer to Appendix B] ' In November 1989 B& A Realty, Inc. was issued a Notice of Responsibility (NOR) by the MA DEP in response to volatile organic compound(VOC) impact within the three municipal water supply wells of the Maher Wellfield. In response to the NOR,LCR,Inc.(LCR)was hired to conduct ' a "Phase I Limited Site Investigation" at the 33 Brooks Road property. During the site reconnaissance by LCR several petroleum storage tanks were observed on the site as well as several areas of soil staining. In December 1989 and January 1990 LCR conducted testborings/monitoring ' well installations(MW-1 and MW-2)with soil and groundwater sampling. Volatile organic vapors were reported in.soil samples collected during monitor well installation from levels of Not Detected (ND) to 46 ppmv. Results of groundwater sampling indicated trace levels of benzene in MW-2, no VOCs were detected in the sample from MW-1. In August 1996, RAM Environmental, LLC. (RAM) Submitted a Phase I Initial Site ' Investigation Report and Tier Permit Application for the Hubbard Oil Co.,Inc.fuel oil storage depot facility located at the 33 Brooks Road property. RAM advanced a soil boring, completed as a groundwater monitoring well,in a hydrologically upgradient position on the site. A soil sample was collected at the groundwater interface and submitted to a Mass. Certified laboratory for VOC analysis (8260) and TPH (GC/FID) analysis. One round of groundwater sampling was conducted ' at the three on site monitoring wells. Groundwater samples were submitted for VOC and total petroleum hydrocarbon (TPH) analysis. Results of the analysis indicated no VOCs in any of the samples submitted. TPH was detected in wells MW-1 and MW-2 at concentrations of 0.84 mg/L ' and 7.94 mg/L, respectively, above the applicable RCGW-1 Reportable Concentration, indicating that an Immediate Response Action was necessary to address soil and groundwater impact at the ' property. On December 30, 1999 the Department issued a Notice of Noncompliance (NON) to Hubbard, since the previous Tier I Permit Application was determined to be administratively incomplete. On February 22, 2002 SEA Consultants, Inc. (SEA) submitted a Tier IC Permit ' Application to the DEP on.behalf of Hubbard. During DEP's Permit Review process, a site inspection was conducted at the 33 Brooks Road property and the 51 Brooks Road property on March 20, 2000. Seven 55-gallon drums in poor condition and containing various amounts of ' unknown liquids and solids were observed at the 51 Brooks Road property as well as several empty, rusted storage tanks, formerly used as USTs. I ' On March 30,2000,the Department issued aNON to Hubbard for the facility at 33 Brooks Road(RTN 4-0824). DEP requested that an IRA Plan be submitted to evaluate current site soil and groundwater quality. DEP also assigned.RTN 4-15370 to the Threat of Release at the 51 Brooks ' Road property. Hubbard subsequently requested approval to link the two RTNs and a Minor Permit Modification to the existing Tier IC permit, which was submitted to the DEP along with the IRA ' Plan on April 13, 2000. 1 t SEPTEMBER 20,2002 HUBBARD OIL,INC./BO02-3490 PAGE 5 OF 7 PHASE II-SCOPE OF WORK IRA activities included the removal of the potential sources of release at the 51 Brooks Road property, research of the property and the downgradient wellfield, the evaluation of soil and t groundwater conditions at specific locations at the site and the removal of up to ten yards of impacted surface soils. A response contractor was hired by Hubbard to remove all existing debris at the 51 Brooks Road property and on April 27, 2000 Cyn Environmental Services removed ten ' drums of oil and oily solids from the property under a Hazardous Waste Manifest. Soil and groundwater assessment activities included eight test borings (SB-1 through SB-5) with three completed as groundwater monitoring wells(SEA-1 through SEA-3).'Soil samples were analyzed ' for VOCs, volatile petroleum hydrocarbons (VPH), extractable petroleum hydrocarbons (EPH), ethylene dibromide (EDB), RCRA 8 Metals and Methyl tert- Butyl Ether (MtBE). Levels of EPH and VPH were detected above applicable standards in SEA-1 and SEA-3.Naphthalene was detected ' above applicable standards in SEA-1 (located downgradient of the former ASTs and loading racks) and SB-3(located adj acent to the two former pump pads). 2-Methyl naphthalene was detected above applicable standards in SEA-1 and SB-3. TPH identified as No.2 fuel oil was reported above ' standards in SEA-1 and SB-3. On June 14, 2000, SEA sampled eight monitoring wells at the site and in the immediately upgradient property. Groundwater samples were analyzed for VOCs, VPH, EPH, EDB, RCRA 8 Metals and MtBE. Fractional VPH compounds were detected above standards in SEA-1 and SEA-2. ' EPH compounds were detected above standards in SEA-I (located downgradient of the former ASTs and loading racks), SEA-2 (located south of the former diesel ASTs on lot 125)and MW-1 (located downgradient of the large existing fuel oil AST). Naphthalene was detected above standards in SEA-1. 2-Methyl Naphthalene was detected above applicable standards in SEA-1 and SEA-2. COMPREHENSIVE SITE ASSESSMENT - PHASE II SCOPE OF WORK ' Phase II Activities shall consist of a series of eight to twelve (8-12) test borings to be conducted at the subject properties. These are shown on the Site Plan dated 9/9/02 in Appendix A. ' The locations of the proposed testborings correspond with former and current bulk fuel storage,fuel transfer,areas of the property which have not yet been thoroughly investigated and areas of staining on the ground surface as evidence of a"recognized environmental condition", to define the extent ' and magnitude of impact in these areas. Specifically, these areas include the northern and eastern portions of 51 Brooks Road (Lot 125), as well as the area of the former ASTs in the southeastern portion of that property. At 33 Brooks Road(Lot 126),the areas of testing will include the areas of ' current and former fuel storage tanks in the southeastern portion of the property as well as downgradient of a drywell in the central portion of the property. Subsequent to the discovery of any newly discovered areas of vadose zone impact, as many as three (3) of the boring locations will be ' used to establish shallow monitor wells within the shallow aquifer. These test borings will be used to create a geologic cross section and map subsurface conditions through the area of significant soil impact previously identified. Three to five (3-5) additional test borings will also be conducted on the downgradient ' abutting property (Robie's Refrigeration) as within the projected solute transport pathway of any f SEPTEMBER 20,2002 HUBBARD OIL,INC.BO02-3490 PAGE 6 OF 7 PHASE II-SCOPE OF WORK ' dissolved phase contamination,to define the longitudinal and lateral extent of identified groundwater impact. Three(3)monitor well couplets(deep/shallow)will be constructed within these test borings for laboratory analysis of groundwater samples for qualification of risk. Provide laboratory analysis ' of representative samples for qualification of source and risk and in consideration of remedial treatment alternatives. An access agreement is being sought for the use and testing of existing monitoring wells and the placement of these additional monitoring wells. The hollow stem auger method, with split spoon soil sampling, will be employed at each ' testboring location to permit a detailed evaluation of subsurface conditions relative to soil types and the presence of organic vapors. A photoionization detector(PID)will be employed to measure"jar headspace" of organic vapors as consistent with the MA DEP policy WSC-94-400. Ground elevations,soil types,PID screening and specifications for the construction of monitoring wells will be provided on Borehole Logs prepared by BENNETT & O'REILLY, INC. Representative soil samples will be�'collected and field preserved for TPH/VPH analysis with target analytes where tsignificant impact is indicated. After the wells are installed, each will be located by instrument as established by field traverse. Existing elevations will be carried to all wells to establish groundwater elevations to common vertical datum for groundwater contouring between the existing and newly installed monitor wells. All wells will be gauged and field screened for total volatile organic compounds, ' dissolved oxygen,conductance, pH, and temperature. Representative groundwater samples will be preserved and analyzed for VPH/EPH/TPH and EDB analyses and will focus particular attention on the partitioning and ".fingerprinting" of petroleum contaminants in groundwater to establish the . ' relative age and delineate the specific source(s) of any petroleum hydrocarbons and the full extent of associated groundwater contamination. All soil and groundwater testing will be conducted by a MA certified laboratory. Slug testing will be conducted for aquifer characterization and ' determination of groundwater flow velocity for solute transport modeling. ' At the conclusion of site investigation activities,BENNETT&O'REILLY,INC.will prepare a Phase II Completion Statement as a Comprehensive Site Assessment to provide detailed site description, site history, site hydrogeology, delineation of contaminant source, the full extent and ' magnitude of environmental impact, risk characterization and exposure pathway assessment in of the Phase III Review of Remedial Alternative and Remedy Implementation Plan. ' All proposed activities will be conducted in accordance with the Response Action Performance Standards, pursuant to 310 CMR 40.0191 and the QA/AC policies of BENNETT& O'REILLY, INC. The contractors scheduled to perform work at the site under the direction of ' BENNETT & O'REILLY, INC. include Jenkins Well Drilling of Orleans, MA for testboring and monitoring well installation and EnviroSafe Corp.of Sandwich,MA for any soil removal activities and removal of hazardous waste. This work is scheduled to begin on October 1, 2002 with ' testborings and installation of monitoring wells. A site specific Health and Safety Plan has been developed to evaluate and identify potential hazards associated with site activities for the protection of worker safety as attached. The findings of the Phase II Comprehensive Site Assessment will be ' presented in the Phase II status report or Completion Statement to be filed with the Department by I ' SEPTEMBER 20,2002 HUBBARD OIL,INC.BO02-3490 PAGE 7 OF 7 PHASE II-SCOPE OF WORK ' Administrative Consent Order by November 21, 2002. This document will include updated plans representing new testing locations, additional research of historic uses in the area, updated environmental data and risk characterization relative to any exposure pathways in accordance with ' the performance standards for conducting an Phase II CSA (310 CMR 40.0833). If you have any questions or need additional information, please contact our office at your ' earliest convenience. S* cerel B NN , INC. ; ' vidQ- e;ett, LSP Jfoject em -Wiel dt,E Directvironmental Services P Manager cc. Hubbard Oil, Inc. - Attn: Evelyn Read ' Lieutenant Hubler - Barnstable Fire Department Thomas McKean - Barnstable Board of Health John Klimm - Barnstable Town Manager ' John Robichaud - Roble's Petroleum II PHASE II SCOPE OF WORK - COMPREHENSIVE SITE ASSESSMENT ' TIER I MINOR PERMIT MODIFICATION SUPPORTING DOCUMENTATION ' RTN 4-0824 Hubbard Oil, Inc. ' 33 & 51 Brooks Road Hyannis, MA Project#: B002-3490 ' SEPTEMBER 20,2002 ' Prepared By BENNETT & O"REILLY, INC. 1573 Main Street ' P.O. Box 1667 Brewster, MA 02631 David C. Bennett, LSP. On Behalf Of: ' Hubbard Oil, Inc. P.O. Box 10 Hyannis, MA 02601 ' Prepared For: Laura Stanley, Case Officer ' MA Department of Environmental Protection(MA DEP) Southeast Regional Office (SERO) Bureau of Waste Site Cleanup (BWSC) ' 20 Riverside Drive - Lakeville, MA 02347 APPENDIX A: Reference Plans - Site Plan entitled"Comprehensive Response Action...", Prepared by BENNETT&O'REILLY, INC.,Dated 9/9/02 -Figure 1: Site Locus Plan(USGS Topographic Quad) [1999 Excerpt] ' -Figure 2: MA DEP GIS Map,BWSC Overlay [1999 Excerpt] -Figure 3: Water Table Contour Map Excerpt [Town of Barnstable, 1992] APPENDIX B: Research and Reference ' -MA DEP Web Page"Searchable Site List"(8/28/02) -Database Research: EDR(9/10/02) -MA DEP File Review Request(9/12/02) APPENDIX C: Environmental Records I ' -Comprehensive Response Action Transmittal Form,BWSC-108 -Tier I Minor Permit Modification Transmittal Form,BWSC-109 APPENDIX D: Health & Safety Plan ' APPENDIX E: Quality Assurance/Quality Control Plan 1 1 1 APPENDIX A 1 1 1 1 1 1 1 1 1 1 v HyAmAnS j M4, N w 44 t ' L6Cus i fyf L )WNp'°sf�C �F-y ND 5Mao M WELL T 1rE5 E W PO AS g E t21F►1C,1s • 'al TT PlArd By 5 M ecus,)c.TAA Z )N( ,, 44ma iD9f, W. 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Box 1667 c 508.896-6630 Officc Brewster, MA 02631 508-896-4687 Fax 7 DATE: SCALE BY CHECK: JOB NUMBER: `z 1 ' Hubbard Oil Co.,Inc. -33 and 51 Brooks Road, Hyannis,MA yanrus 41040-15",70017-18" 41040'15",70015'44" 1 - �...• ILI rr r"ViTe 544 f � � fe � c ;'� � ��� a r of '4 r 5.:.. ir" t � ,:• ' � f �, 15 :�t �df E 1 •Y _ , 1 41039'06 70017'18"NAD83 f 41039'06°70015'44" Ml� TN 0 1/2 1 MILE 16 a 1000 0 1000 2000 �000 4000 FEET -- Printed from TOPO! @1998 Wildflower Productions www.topo.com) ' Figure 1: The subject properties are located at 33 and 51 Brooks Road in Hyannis, MA. The properties are located approximately 250 feet east of the intersection of Mary Dunn Road and Brooks ' Road in the Town of Hyannis, MA. The two parcels of land contain approximately 0.71 and 0.67 acres of land,respectively,with frontage along Brooks Road. The Barnstable Registry of Deeds lists the owner of record for both parcels as B&A Fournier Realty,Inc. 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Ail iL r wr� file bPus � e� r'��'' ` .., ;p1,,4� �� ' � !� �!►`5E'"' ���'�t �` `ti,rt►cr '+ � al�r'f� 1I gill A My: t r 1 � 1 .lilt W �� IT MAr r fill t ' Ix L r 1 1 1 APPENDIX B 1 ' 1 1 1 1 1 1 1 1 1 1 1 d, Site/Reportable Release Look Up RTN: Site Name/Location Aid: Street: City: BARNSTABLE-BARNSTABLE Status: Chemical Type: Search Results Release Release Tracking Reporting Notification Compliance RAO Chemical Tracking Number City/Town Release Address Site Name/Location Aid Category Date Status Date Phase Class Type Number (RTN) (RTN) BARNSTABLE-I BOARDMAN-POLANDO BAP AIRPORT Hazardous 4-0012048 BARNSTABLEFIELD IFHANGER I 120 DY 4/29/1996 RTN CLOSED 4/6/1999 Material 4-0012048 4-0000706 BARNSTABLE BARNSTABLERD l[iiARNSTABLESTA ON ETTY NONE 4/15/1989 LSPNFA 7/18/1996 4-0000706 4-0000025 RNSTABLE- SW FLINT O STABLE BARNSTABLE I E RD BLAND LARNSTABLE ADEQUATE NONE 1/15/1987 RATE EU B CI 8/2/1995 4-0000025 4-0012965 TAB BARNSTABLE 153 FREEZER RD BARNSTABLE MARINE 72 HR 4/14/1997 RAO 7/7/2000 PHASE AlBARNSTAB BARNSTABLE Oil 4-0012965 4-0015600 BARNSTABLE480 BARNSTABLE RD MUN CIPAL AIRPORT- TWO HR 7/15/2000 RAO 9/1 I/2000 AI Oil 4-0015600 4-0013875 BARNSTABLE F3180 MAIN ST IF B RNSTABLETA ERN TWO HR 5/13/1998 RAO 6/30/1998 A2 Oil 4-0013875 4-0015715 BARNSTABLE-� ] BARNSTABLE 110 MARY DUNN RD11 F CAPE FLIGHT TWO HR 8/30/2000 RAO 5/10/2002 Al Oil 4-0015715 4-0000323 BARNSTABLE 120 S MAIN ST NURS NG HOME NONE 4/15/1987 DEPNDS 7/23/1993 4-0000323 LLE BARNSTAB ERVI 11"4-0000756 BARNSTABLE 1456 FARL EO8TH RD CENTSTATIONGULF NONE 10/IS/1989 RAO 7/27/1998 PHASE A2 4-0000756 4-0000825 BARNSTABLE 3000 F LM MOCOT UTH RD COTUIT LANDING NONE S/21/1990 WCSPRM 10/1/1993 4-0000825 4-0014697 BARNSTABLE MARSTONS LN CUMCLUB INC MAQUID GOLF 72 HR 5/3/1999 RAO 6/29/1999 Al Oil 4-0014697 4-0000233 BARNSTABLE MARSTON LA CUM AQU D GOLF NONE i l/3/1986 DEPNFACOUR 7/23/1993 4-0000233 BARNSTABLE- Oil and 4-0012670 BARNSTABLE RTE 132&RTE 6 FACILITY NO 133 120 DY 1 1/18/1996 RAO 11/14/1997 A2 Hazardous 4-0012670 Material 4-0011707 BARNSTABLE- MARY DUNK RD FLINT LOCK RD 72 HR 10/6/1995 RAO 12/18/1995 Oil 4-0011707 I BARNSTABLE E 4-0014264 BARNSTABLE 82 RIDGEWOOD AVE GARAGE RETRAC 10/19/1998 DEF TIER IB 10/26/1999 4-0014264 BARNSTABLE- GRANDPAS USED Oil and 4-0013201 BARNSTABLE 210 YARMOUTH RD BIKES 120 DY 7/18/1997 DPS 1/30/1998 Hazardous 4-0013201 Material Oil and BARNSTABLE- PHASE 4-0012911 BARNSTABLE AIRPORT GRIFFIN AVIONICS 120 DY 3/20/1997 TIER 1C 3/24/1998 Hazardous 4-0012911 BARNSTABLE III Material 4-0000740 BARNSTABLE 792 MAIN ST BBARD OIL CO NONE 7/15/1989 TIER 2 8/9/1996 PHASE Oil 4-0000740 4-0010991 BARNSTABLE RTE 132 HYANNIS MOBIL TWO HR 12/13/1994 RAO 2/13/1995 Al Oil 4-0010991 BARNSTABLE- BREEDS 4-0013454 BARNSTABLE HILL/INDEPENDENCE INDUSTRIAL PARK TWO HR 10/28/1997 RAO 12/26/1997 Al Oil 4-0013454 PARK 4-0013792 BARNSTABLE RTE 6A IN T OLD JAIL LANE TWO HR 4/]0/1998 RAO 8/6/1998 Al 4-0013792 4-0000624 BARNSTABLE-]F BARNSTABLE 53 SOUTH ST LEWIS BAY MOTEL NONE 1/15/1989 DEPNFA 7/23/1993 Oil 4-0000624 4-0016957 BARNSTBLE ARNSTAB BARNSTABLE HARBOR MN LONLEY HUNTER TWO HR 3/24/2002 AD REG TE 3/24/2002 Oil 4-0016957 4-0011220 BARNSTABLE ]06 ROSA LN MARSTON MILLS TWO HR 3/23/1995 RAO 10/16/1996 A2 Oil 4-00 1 1 220 4-0014016 BARNSTABLE [::2LLBURYBARNSTAB I RD MILLWAY MARINA 120 DY 6/26/1998 RAO 5/19/1999 A3 Oil 4-0014016 4-0011972 BAR ISTABLE 156 IYANOUGH RD f Q MOBIL SEERiSTN#01- 120 DY 3/16/1996 RAO 7/1/1996 A2 Oil 4-0011972 BARNSTABLE- Hazardous 4-0010893 BARNSTABLE MARY DUNN RD NO LOCATION AID 120 DY 10/28/1994 DEF TIER 1B 11/6/1995 Material 4-0010893 4-0014345 BARNSTA LE 253 MILLWAY RD NO LOCATION AID 72 HR 11/18/1998 RAO 5/19/1999 A3 Oil 4-0014345 4-0015637 BARNSTABLE HYANNIS HARBORIF NO LOCATION AID TWO HR 7/29/2000 AD REG TE 7/29/2000 Oil 4-0015637 R 4-0016838 BARNSTABLE BARNSTAB 73 HARRISS MEADOW NO LOCATION AID TWO HR 1/21/2002 RAO 3/7/2002 E Oil 4-0016838 e 11 LA BARNSTABLE- Oil and 4-0016856 BARNSTABLE 3240 MAIN ST NO LOCATION AID 120 DY 1/24/2002 UNCLASSIFIED 1/24/2002 Hazardous 4-0016856 Material 4-0017000 BARNSTABLE 1617 FARL EOBUTH RD NO LOCATION AID 72 HR 4/9/2002 RTN CLOSED 6/11/2002 Oil 4-0017000 NO LOCATION Oil and BARNSTABLE- PHASE 4-0015670 BARNSTABLE 43-55 IYANOUGH RD AID/D'OLIMIPIO REAL 120 DY 8/3/2000 TIER 1C 8/16/2001 II Hazardous 4-0015670 ESTATE T Material BARNSTABLE- PACKAGING Hazardous 4-0011988 BARNSTABLE 70 AIRPORT RD INDUSTRIES PLANT#1 120 DY 3/16/1996 RAO 7/31/1998 Material 4-0011988 4-0000331 BARNSTABLE BARNSTABLE- 749 MAIN ST PROPERTY NONE 4/15/1987 DEPNDS 7/23/1993 4-0000331 4-0000585 BARNSTABLE 57 LAKE ST PROPERTY NONE 10/l6/1987 DEPNFA 8/2/1995 4-0000585 4-0000310 BARNSTABLE619 MAIN STIF PROPERTY NONE 1/IS/1988 DEPNDS 7/23/1993 4-0000310 4-0000545 BARNSTABLE RTE 6A PLUM ST PROPERTY NONE 10/15/1988 DEPNFA 7/23/1993 Oil 4-0000545 4-0000609 BARNSTABLE 355 EEL RIVER RD PROPERTY NONE 1 I/29/1988 RAO 6/15/1995 A2 Oil 4-0000609 4-0000732 BARNSTABLE 64 HARBOR RD PROPERTY NONE 2/23/1989 RAO 1/3/2001 132 Oil 4-0000732 4-0006049 BARNSTABLE 39 LUMBERT MILL RD RESIDENCE NONE 2/25/1994 DEF TIER 1 B 3/6/1995 4-0006049 BARNSTABLE- ROBERTS AUTO Oil and 4-0013202 BARNSTABLE 202 YARMOUTH RD WHOLESALE 120 DY 7/18/1997 DPS 8/7/1998 Hazardous 4-0013202 Material 4-0014788 BARNSTABLE STONEWALL LN RTE 6A&RTE 132 TWO HR 6/11/1999 RAO 10/11/2000 FA2] Oil 4-0014788 4-0010961 BARNSTABLEFREEZER RD SEWAGE STATION ONPING 72 HR 11/30/1994 RAO 12/1/1995 A2 Oil 4-0010961 4-0013355 BARN SBLE SCHOOL ST STEAMSHIP TWO HR 9/IS/1997 RAO 11/17/1997 Al 4-0013355 4-0010479 ITY BARNSTABLE65 INDEPENDENCE DR STOP&SHOP PLAZA TWO HR 5/14/1994 RAO 7/14/1994 Al 4-0010479 BARNSTABLE- Oil and 4-0013286 BARNSTABLE OLD MILL RD SUBSTATION TWO HR 8/18/1997 RAO 10/17/1997 A2 Hazardous 4-0013286 Material 4-0013380 BARNSTABLE 1617 FALMOUTH RD SUNOCO SEER ICE 120 DY 9/11/1997 TIER I 6/11/2002 PHA IVSE azardols 4-0013380 STA4-0000279 BARNSTABLE STRAIGHT WAY THE STRAIGHT WAY NONE 1/IS/1987 DEF TIER 1BF/9/1995] 4-0000279 4-0013433 BARNSTABLE25 FALMOUTH RD FTRMOTORS TIC TWO HR 10/16/1997 RAO 12/12/1997 Al Oil 4-0013433 4-0000801 BARNSTABLE- 135 RTE 149 MM VILLAGE GARAGE NONE 1/15/1990 RAO 7/19/1996 E Oil 4-0000801 BARNSTABLE 4-0014244 BARNSTABLE 333 PARKER RD WBARNS BLE- AGNER RESIDENCE TWO HR ]0/13/1998 RAO 8/17/2000 PHASE Al Oil 4-0014244 4-0016448 BARNSTABLE WEST BAY WEST BAY TWO HR 7/31/2001 ADERQEUCATE 7/31/2001 4-0016448 4-0016184 BARNSTABLE 4738 FALMOUTH RD XTRA MART 1260 TWO HR 4/11/2001 RAO 6/11/2001 Al Oil 4-0016184 Total of 54 Records Matched. * Search Again * * Definitions (Contact: dbakely_j state.ma.us] ISitesl IBWSC Publications) IBWSC HomeI IDEP.Ilome][Privacy Policy-] AAc ltc A—AAA nPI) MAICZ0 Quo I,ct 4ZA-1, D.— 1 nff Ala up i i � • r Site/Reportable Release Look Up RTN:Site Name/Location Aid: Street: City: BARNSTABLE-HYANNIS Status: Chemical Type: Search Results E Release Reporting Notification Compliance RAO Chemical Tracking City/Town Release Address Site Name/Location Aid Category Date Status Date Phase Class Type Number (RTN) 4-0014472 1 B RNSTA S E 480 BARNS TABLE RD AIRPORT TWO HR 1/23/1999 RAO 6/28/1999 A211 Oil 4-0014472 4-0015997 B RNSTA S E 156 IYANOUGH RD AIRPORT MOBIL TWO HR 1/23/2001 RTN CLOSEDHYANN 6/1/2001 Oil 4-0015997 4-0000873 B RNSTABS E 556 YARMOUTH RD AIRPORTBMOTORS INC NONE 4/15/1990 TIER IA 10/1/1993 PHASE HYANN4-0000873 4-0012134 B HYAIT�IANBS E 345 ARROWHEAD DR ATE OYAN RD RNER F TWO HR 5/5/1996 DEF TIER I B 5/12/1997 Oil 4 0012134 4-0000824 BAHYANNIS STABLE 33 BROOKS ROAD F(HUBBARD OIDLOIO INC) NONE 11/1/1989 TIER 1C 8/9/1996 PHI SE Oil 4-0000824 4-0010888 B RNSTA BL S E- 75 PER 11 WAVYRENCE AUBURN WIRE CO TWO HR 11/10/1994 RAOHYANN 1/9/1995 Al Oil 4-0010888 BARNSTABLE- Hazardous 4-0016577 HYANNIS 43-55 IYANOUGH RD BAGEL PORT 72 HR 8/15/2001 UNCLASSIFIED 8/15/2001 Material 4-0016577 4-0000976 B HRYANNIS E 47 OLD YRADRMOUTH BAP PROPERTY NONE 9/19/1990 DEPNFA 5/24/1996 Oil 4-0000976 BARNSTABLE- BOARDMAN- PHASE [Ed 4-0000823 HYANNIS POLANDO FIELD BARNSTABLE AIRPORT NONE 1 I/10/1989 TIER 1B 10/11/1994 V 4-000 BARNSTABLE- BARNSTABLE FIRE PHASE Oil and 4-0000190 HYANNIS MARY DUNN ROAD TRAINING NONE 8/25/1986 RAO 6/1/2001 V Al Hazardous 4-0000190 Material JJBARNSTABLE- BARNSTABLE MOBIL PHASE 4-0013422 HYANNIS 156 IYANOUGH RD STATION 72 HR 10/9/1997 TIER 1C 10/16/1998 IV Oil 4-0013422 BARNSTABLE- BARNSTABLE Hazardous 4-0012687 HYANNIS EAST RAMP MUNICIPAL AIRPORT 120 DY 12/2/1996 RTN CLOSED 4/6/1999 Material 4-0012687 BARNSTABLE- Oil and 4-0016853 HYANNIS CENTER ST BARNSTABLE RD TWO HR 1/24/2002 ,RAO 2/22/2002 [A]lHazardous 4-0016853 Material BARNSTABLE- RTE 132 CAPE COD 4-0014747 HYANNIS MALL BEHIND SEARS TWO FiR 5/25/1999 RAO 7/29/1999 A2II[ ARNSTABL Oil 4-0014747 4-0000383 B HYANNIS E 5 CHARLES ST BENS AUTO REPAIR NONE 7/15/1987 DEPNFA 8/2/1995 4-0000383 4-0000461 BARNSTABL HYANNIS E 599 IYANOUGH RD BOUY S REALTY BDP NONE 1/15/1988 DEPNDS 7/23/1993 4-0000461 4-0000392 BARNSTABL HYANNIS 9 230 IYANOUGH ROAD BP SERVICE STATION NONE 7/15/1987 TIER IA 10/21/1994 Oil 4-0000392 ARNSTA4-0000477 B HYANNIS E 242 MAI=ST [ C EDLEYS DR ANER DP NONE 1/15/1988 RAO 7/18/2000 BI 4-0000477 4-0000435 B HYANNIS STABLE 24 PLANT RD CANDLEMR BAPPANY NONE 1/15/1988 LSPNFA 7/29/1996 F-0000435 4-0016505 BARNSTABL S E RTE 132 CAPECOPARKING LIOLL TWO HR 8/16/2001 RAO 11/20/2001 A2 Oil 4-0016505 HYANNSTABL 4-0010059 B HYANNIS E 44 BODICK RD CAPE DAIRY TWO HR 10/28/1993 RAO 1/31/1995 E ,IL Oil 4-0010059 4-0014860 BARNSTA HYANNIS E MUNICIPAL AIRPORT CAPE FLIGHT AREA TWO HR 7/14/1999 RAO 7/14/1999 A2ARNSTABI, Oil 4-0014860 4-0000026 B HYANNIS E 258 IYANOUGH ROAD CHART6843 FMRER STATION NO. NONE 1/15/1987 TIER I 10/28/1994 PHASE Oil 4-0000026 4-0000222 BARNSTABL HYANNIS E 725 MAIN ST CHE FA IL VR N GULF NONE 7/3/1986 WCSPRM 7/6/1993 Oil 4-0000222 MR 4-0015250 BARNSTAB HYANNIS E 232 MAIN ST COLONIAL CANDLE TWO HR 2/1/2000 RAO 4/5/2000 Al Oil 4-0015250 4-0000878 B HYANNIS E 232 MAIN ST COLONIBALLPCANDLE NONE 7/15/1993 RAO 6/5/1998 E 4-0000878 IL14-0000890 11 BARNSTAHYANNIS E- 109 CORPPOROAD TI�Fc ORPORATION PLAZA NONE 4/15/1990 RAO 9/1/2000 PHASEE Oil 4-0000890 4-0000852 B HRYANNIS E 201 YARMOUTH RD COTTON PICKIN TS NONE 1/15/1990 DPS 4/17/1997 Oil 4-0000852 4-0010952 BARNSTAB HYANNIS E 1171 RTE 132 Fc UMBERLAND FARMS 72 HR 11/25/1994 RAO 1/24/1995 B1 Oil 4-0010952 4-0014257 B HYANNIS E 395 WEST MAIN�s- -cuM BERLAND FARMS 72 HR ]0/16/1998 TIER 1C ]0/25/1999 PHASE Oil 4-0014257 - ARNSTABL 4-0000368 B HYANNIS qF 15 AAIRPORT RD CYTRUST SAPPRUS LTY NONE 7/15/1987 DEPNDS 8/22/1996 4-0000368 4-0017095 B HYANNIS E CALMUS BEACH DUNBAR POINT TWO HR 5/31/2002 AD REUC'ATE 5/31/2002 Oil 4-0017095 -J 4-0010348 B RNSTABHYANNIS E RAO 71 PLEASANT ST INTERVENTION CTR TWO HR 3/17/1994 4/1/1994 Al Oil 4-0010348 4-0016491 B HRYANNIS STABLE RTE 6 W EXIT 6 TWO HR 8/12/2001 RAO 10/]0/2001 Al Oil 4-0016491 4-0001301 B HYANNBS E 484 SOUTH ST EXXON STATION 3 575] NONE 7/15/1993 RAO 12/15/1997 PHASE A2 4-0001301 4-0016148 B HYANNIS E OFF OCEAN ST FERRY TERMINAL IH HR 3/29/2001 ADERQEUCJATE 3/29/2001 4-0016148 BARNSTABLE- Hazardous 4-0016283 HYANNIS 1070 RTE 132 FESTIVAL AT HYANNIS 120 DY 6/4/2001 DPS 6/4/2001 Material 4-0016283 4-0014685 B HYANNISTABS E 112 BARNSTABLE RD GETTY SERVICE STA 120 DY 4/22/1999 RAO 7/9/1999 A2 MaYea,°als 4-0014685 4-0014059 B HRYANNIS STABI,E 112 BARNSTABLE RD GE F STATION ICE JEEI 7/9/1998 RAO 7/9/1999 A2 Oil 4-0014059 BARNSTABLE- CAPE COD MALL RTE GIBBS SERVICE Oil and 4-0000898 HYANNIS 132 STATION FMR NONE 4/15/1990 RAO 5/30/1997 A2 Hazardous 4-0000898 Material 4-0016708 B RNSTABS E INNER HARBOR INNER HARBOR TWO HR 12/10/2001 AD QUCATE 12/]0/2001 4-0016708 HYANNI4-0013502 B RNSTABL S E FERNDOCK RD LAIDLAW BUS CO. TWO HR 11/21/1997 RAOHYANN 12/18/1997 Oil 4-0013502 4-0010175 BARNSTAB HYANNIS E 63 ENTERPRISE ST LARRYS ALIGNMENT TWO HR 1/2/1994 RAO 7/1/1994 A2 Oil 4-0010175 4-0000862 BAHYANNIS E 156 IYANOUGH RD MOSTATIONBIL ICE NONE 1/15/1990 RAO ]2/29/1994 A2 Oil 4-0000862 4-0000214 B RNSTABE 49 MOBIL STATION#01 NONE 7/1/1986 TIER 1B 10/7/1994 PHASE HYANNIS IYANOUGH Oil 4-0000214 BARNSTABLE- -][ MOTOR VEHICLE � FA2] HYANNIS 16 HINKLEY RD GARAGE TWO HRRAO Oil 4-0010187 --][4-0013581 B HYANNIS LE-1 149 NORTH ST MUTUAL STATION#73 TWO HR 1/10/]998 RAO 4/9/1998 Al Oil 4-0013581 4-0011270 B HYANNIS E- 6 AIRPORT WAY NEAR) 1[ DEND rORFDMARY TWO HR 4/6/1995 RAO 4/8/1996 FA2]FH��ardosa 4-0011270 4-0000716 B HRYANNBS E 180 IYANOUGH ROAD NELSON COAL&OIL NONE 5/23/1989 RAO 10/4/2001 PHASE ❑C 1 Oil 4-0000716 4-0000782 BARNSTA S E 30 CORPORATION RD NEVADA BOB S BDP NONE 9/11/1989 DEPNFA 7/23/1993 Oil 4-0000782 4-0010142 B RNSTA S E- 123 GENE DAL PATTON NO LOCATION AlD TWO HR 12/10/1993 RAOHYANN 3/25/1994 A2 Oil 4-0010142 4-0010287 BARNSTA s E 74 CAMP ST NO LOCATION AID 72 HR 2/18/1994 RAO 5/I 1/1995 A3 Oil 4-0010287 BARNSTABLE- =Hazardous 4-0010603 HYANNIS 1471 RT 132 NO LOCATION AID 72 HR 7/1 1/1994 RTN CLOSED 5/24/1995 4-0010850 B RNSTABL S E 1171 IYANOUGH RD NO LOCATION AID 72 HR 10/14/1994 TIER 1C 10/27/1995 PHASE Oil 4-0010850 HYANN4-0010971 11 B RNSTABS EI F 18 CENTER ST NO LOCATION AID 120 DY 11/9/1994 RAO 10/17/2000 PHIISE Bl Hazardous 4-0010971 4-0011140 IF—BA HYANNIS E 1171 RTE 132 NO LOCATION AID TWO HR 2/16/1995. RTN CLOSED 12/3/1996 Oil 4-0011140 4-00 1 13270 B RNSTABS E 281 GOSNOLD ST NO LOCATION AID 120 DY 4/21/1995 RAOHYANNI 2/6/1996 A2 Oil 4-0011320 BARNSTABLE- Oil and 4-0011841 HYANNIS 480 BARNSTABLE RD NO LOCATION AID 120 DY 12/1/1995 RTN CLOSED 12/18/1996 Hazardous 4-00 1 1 84 1 Material 4-00 1 26 33 BARNSTABLE- 31 GENEDR PATTON NO LOCATION AID TWO HR 12/1/1996 RAO 3/31/1997 FAI] Oil 4-0012683 4-00129 11 BAHRNSST`AABLE- 13 GENEDRL PATTON NO LOCATION AID TWO HR 4/4/1997 RAO. 3/13/1998 FA21 Oil 4-0012941 4-0014148 B RNSTABS E 7 CORPORATIO:N:R:D] NO LOCATION AID 120 DY 5/4/1998 RAO 12/22/1998 PHASE B1 Oil 4-0014148 4-0013857 11 B RNSTABL S E 725 MAIN ST NO LOCATION AID 120 DY 5/6/1998 RAO HYANN5/6/1998 A2 Oil 4-0013857 4-00 1 42 33 B RNSTA S E 381 CAMP ST NO LOCATION AID 120 DY 9/25/1998 RTN CLOSED 10/1/1999 Hazardou Materials 4-0014213 4-0014565 B RNSTABS E- 44 COMM,UU EICATION NO LOCATION AID TWO HR 2/25/1999 RAOHY 4/6/1999 Al Oil 4-0014565 4-0016090 B RNSTABS E 252 HINCKLEY RD NO LOCATION AID 120 DY 2/23/2001 RAO 12/20/2001 A2 Oil 4-0016090 HYANN4-0016772 B RNSTABI,HYANNBS E 577 WEST MAIN ST NO LOCATION AID 72 HR 12/l0/2001 UNCLASSIFIED 12/10/2001 Oil 4-0016772 4-00169 44 B ARNSTABL HYANNIS E INNER HARBOR NO LOCATION AID TWO HR 2/27/2002 AD Q GATE 2/27/2002 Oil 4-0016914 4-00170 00 B HYANNIS ARNSTABI,E BARNSTABLE RD NO LOCATION AID TWO HR 5/17/2002 UNCLASSIFIED 5/17/2002 Oil 4-0017060 4-0017126 B ENSTAHYANNIS E 27 PARK ST NO LOCATION AID 120 DY 6/i l/2002 UNCLASSIFIED 6/11/2002 Oil 4-0017126 4-0010273 B RNSTABS E 46 NORTH ST NYNEX 72 HR 2/10/1994 RAO 1/13/1997 PHIISE AlSTABI, Oil 4-0010273 4-0010375 B HRYANNIS E 69 STUDLEY RD OFF OCEAN AVE 72 HR 4/4/1994 RAO 6/6/1994 Ai Oil 4-0010375 4-0010112 BARNSTABLE- HYANNIS E 42 WAREHOUSE RD OFF RTE 28 TWO HR 11/30/1993 RAO 3/14/1997 FA2] Oil 4-OOIOI 12 4-0014306 V HYANNBS STALE 181 SPRING ST OFF RTE 28 120 DY 11/2/1998 RAO 4/8/1999 A2 Oil 4-0014306 4-0001289 BARNSTA S E 1180 IYANOUGH RD IF LD HARBORCO F CANDLE NONE 7/15/1993 RAO 7/25/1997 B1 Oil 4-0001289 4-0013121 BARNSTABLE- 17 ELM AVE P&B STREET RAILWAY 120 DY 6/23/1997 RAO 6/22/1998 E Oil 4-0013121 HYANNIS PACKAGING Oil and BARNSTABLE- 70-84 AIRPORT RD PHASE 4-0001080 INDUSTRIAL GROUP NONE 7/15/1991 RAO 8/13/2001 E]2 Hazardous 4-0001080 HYANNIS PLANTS 12 3 FMR III Material BARNSTABLE- PERSEVERENCE WAY PACKAGING 4-0000938 HYANNIS PT 5 INDUSTRIES GROUP NONE 6/12/1990 DEPNDS 4/19/1994 4-0000938 BAP 4-0015370 B HRYANNIS E 33 BROOKS RD PARCEL 125 TWO HR 3/20/2000 RTN CLOSED 3/20/2000 4-0015370 4-0016335 iir B11_ RNSTABHYANNIS E- 143 OLD R RMOUTH FP ENTTIS AUTOMOTIVE TWO HR 5/21/2001 DES'TIER 1B 1 5/28/2002 4-0016335 4-0016083 B HYANNIS E OCEAN ST PIER 1 TWO HR 3/4/2001 ADERQ GATE 3/4/2001 Oil 4-0016083 �� 4-0014312 IF—B RNSTABL S E RTE 132 POLE 150/86 TWO HR I l/6/1998 RAO 1/5/1999 Al 4-0014312 4-0000251 VHYANNISA E A60 YARMOUTH RD PURITAN PONTIAC BDP NONE 1/15/1987 DEPNFA 7/23/1993 Oil 4-0000251 4LACKBURN-0001081 BARNSTABL HYANNIS E AIRPORT RD. AUTO 11YSALVAGE BAP NONE 7/15/1991 TIER IC 8/22/2000 pHIISE Oil 4-0001081 4-0016741 B RNSTABHYANNI STS E 33 CHASE RESIDENCE TWO HR 11/]3/2001 UNCLASSIFIED 11/13/2001 Oil 4-0016741 4-0012714 BHYANNIS E 26 YARMOUTH RD RESIDENTIAL 72 HR 12/16/1996 RAO 3/5/1997 E Oil 4-0012714 4-0000582 BARNSTABLE-HYANNIS 488-504 SOUTH ST ROADHOUSE CAFE NONE 10/15/1988 WCSPRM 3/14/1995 4-0000582 4-0001126 BAHYANNBS E 645 MAIN ST ROBERTS CLEANERS NONE 11/1/1991 TIER 2 8/4/1998 PHASE 4-0001126 BARNSTABLE- ROBIES Oil and 4-0000934 HYANNIS 279 YARMOUTH RD REFRIGERATION NONE 6/14/1990 RAO 6/2/1997 B1 Hazardous 4-0000934 Material 4-00 1 04 1 5 BARNSTA S E 317 FALMOUT7P-D RTE 28 WTAYEARES 120 DY 4/4/1994 RAO 4/28/1998 PH III A2 MateriaHazal 4-0010415 ANNBARNSTABLE- CAPE COD MALL RTE SEARS AUTOMOTIVE joiandHYANNIS 132 CENTER NONE 7/15/1990 RAO 7/31/1997 A2 rdous 4-00erial 4-0015762 B HYANNI' E 825 FALMOUTH RD SENIOR CENTER TWO HR 9/18/2000 RAO 12/27/2000 A2]1 Ma[enals 4-0015762 4-0000793 B RNSTA S E 590 IYANOUGH RD SHELL SERVICE NONE 10/15/1989 RAO 11/13/1996 E Oil F4-0000793 TION L SHELL SERVICE 4-000 1 1 79 BARNSTABLE-HYANNIS 381 CAMP ST STATION/WILLOW ST NONE 7/15/1992 RAO 5/1/2001 PHASEE Oil 4-0001179 SHELL V 4-0010573 BAHYANNIS STAB7—]E AIRPORT ROTARY SHELL STATION 72 HR 6/23/1994 RAO 10/17/1994 Al Oil 4-0010573 4-0011085 BAHYANNIS E 11 HIGH SCHOOL RD SOUTH END OF MAIN 72 HR 1/2/1995 RAO 3/17/1995 E Oil 4-0011085 o0 o FAI 4-0012393 BARNSTABLE- 21 SCHOOL ST SOUTH ST DOCK TWO HR 7/31/1996 RAO 11/29/1996 Oil 4-0012393 HYANNIS 4-0012608 B HYANNIS E- STEAMSHIP MARY DUNN RD AUTHORITY TWO HR 10/29/1996 RAO 1/3/1997 Al]E�i,:][ 4-0012608 BARNSTABLE- STEAMSHIP 4-0014802 HYANNIS 141 SCHOOLST AUTHORITY TWO HR 6/22/1999 RAO11 8/30/1999 Al Oil 4-0014802 BARNSTABLE- 65INDEPENDENCE 4-0010054 1 HYANNIS DR STOP&SHOP TWO HR 11/3/1993 RAO1[- I/27/1994 Al Oil 4-0010054 4-0010094 B HYANNIS E- 65 INDEDIR DENCE STOP&SHOP TWO HR 1 1/24/1993 RAO 1/24/1994 Al Oil 4-0010094 BARNSTABLE- Hazardous 4-0016597 HYANNIS 10 HADAWAY RD SUN FREIGHT CO 72 HR 9/26/2001 UNCLASSIFIED 9/26/2001 Material 4-0016597 4-0001338 BARNSTABL HYANNIS q 14 W MAIN ST SUNOCO FACILITY NONE 10/1/1993 RAO 5/1/1998 PHASE B1 Oil 4-0001338 BARNSTABLE- TEXA SERVICE 4-0016161 HYANNIS 1140 IYANOUGH RD STATION__ 72 HR 4/5/2001 RTN CLOSED 6/12/2001 Oil 4-0016161 BARNSTABLE- PHASE Hazardous 4-0011301 HYANNIS - 1 140 RTE 132 TEXACO STATION 120 DY 4/6/1995 TIER 1 C 4/9/1996 IV Material 4-0011301 4-00009 7 SB HYANNIS E 100 BREEDS HILL RD THE CAPE COD CO NONE 6/19/1990 TIER IA 12/1/1994 PFIVSE M ter aldous 4-0000937 4-00007 77 B HYANNIS ARNSTABLE 528 BEARSE'S WAY][ TI�SHOP BAP TOR NONE 10/15/1989 DEF TIER I 11/28/1994 4-0000717 --]I4-0015365 BARNSTABL HYANNIS E RTE 28 TJ MAXX PARKING LOT TWO HR 3/17/2000 RAO 7/14/2000 A2 Oil 4-0015365 4-0013685 BARNSTABL HYANNIS E ATTUCKS WAY [TRANSFORMER VAULT TWO HR 2/18/1998 RAO 4/15/1998 A2 Oil 4-0013685 4-0000991 BARNSTABL9 143 OLD YHYANNISRADRMOUTH1[ WARRUST DICK REALTY NONE I/15/1991 DEPNDS 7/23/1993 F4-0000991 4-0000027 BAHYANNIS RNSTABL9 100 BARNSTABLE RD WARREN BUICK BDP NONE 1/31/1985 RAO 3/31/1997 A2 4-0000027 Total of 110 Records Matched. ** Search A ain ** Definitions ]Contact: dbakely_@a state_ma.us] ]Sites] ]BWSC Publications] ]BWSC Home] ]DEP Home](Privacy Policy_) ' Environmental L=LrData Resources, Inc. The EDR Radius Map ' with GeoCheck° 1 1 1 33 & 51 33 & 51 Hyannis, MA 02601 Inquiry Number: 843894.1s 9 Y The Source For Environmental Risk Management Data ' September 10, 2002 3530 Post Road I ' Southport, Connecticut 06890 ' Nationwide Customer Service Telephone: 1-800-352-0050 Fax: 1-800-231-6802 Internet: www.edrnet.com TABLE OF CONTENTS ' SECTION PAGE Executive Summary------------------------------------------------------- ES1 Overview Map----------------------------------------------------------- 2 ' Detail Map-------------------------------------------------------------- 3 Map Findings Summary---------------------------------------------------- 4 MapFindings------------------------------------------------------------ 5 OrphanSummary--------------------------------------------------------. 86 Government Records Searched/Data Currency Tracking-------------------------- GR-1 GEOCHECK ADDENDUM Physical Setting Source Addendum------------------------------------------. A-1 ' Physical Setting Source Summary-__________________________________________. A-2 Physical Setting Source Map------------------------------------------------ A-7 ' Physical Setting Source Map Findings---------------------------------------- A-8 Physical Setting Source Records Searched------------------------------------- A-20 ' Thank you for your business. Please contact EDR at 1-800-352-0050 with any questions or comments. Disclaimer Copyright and Trademark Notice This report contains information obtained from a variety of public and other sources. NO WARRANTY EXPRESSED OR IMPLIED, IS MADE WHATSOEVER IN CONNECTION WITH THIS REPORT. ENVIRONMENTAL DATA RESOURCES INC.SPECIFICALLY ' D;SCLAIMS THE MAKING OFANY SUCH WARRANTIES, INCLUDING WITHOUT LIMITATION,MERCHANTABILITY OR FITNESS FOR A PARTICULAR USE OR PURPOSE. ALL RISK IS ASSUMED BY THE USER. IN NO EVENT SHALL EDR BE LIABLE TO ANYONE, WHETHER ARISING OUT OF ERRORS OR OMISSIONS,NEGLIGENCE,ACCIDENT OR ANY OTHER CAUSE,FOR ANY LOSS OR DAMAGE,INCLUDING, WITHOUT LIMITATION,SPECIAL, INCIDENTAL, CONSEQUENTIAL, OR EXEMPLARY DAMAGES. ' Entire contents copyright 2001 by Environmental Data Resources,Inc. All rights reserved. Reproduction in any media or format,in whole or in part,of any report or map of Environmental Data Resources,Inc.,or its affiliates,is prohibited without prior written permission. ' EDR and the edr logos are trademarks of Environmental Data Resources,Inc.or its affiliates. All other trademarks used herein are the property of their respective owners. TC843894.1 s Page 1 ' EXECUTIVE SUMMARY a A search of available environmental records was conducted by Environmental Data Resources, Inc. (EDR). The report meets the government records search requirements of ASTM Standard Practice for ' Environmental Site Assessments, E 1527-00. Search distances are per ASTM standard or custom distances requested by the user. TARGET PROPERTY INFORMATION ' ADDRESS 33&51 ' HYANNIS, MA 02601 COORDINATES ' Latitude(North): 41.662400-41° 39'44.6" Longitude(West): 70.276100-70° 16'34.0" Universal Tranverse Mercator: Zone 19 -UTM X(Meters): 393755.7 ' UTM Y(Meters): 4612867.5 USGS TOPOGRAPHIC MAP ASSOCIATED WITH TARGET PROPERTY ' Target Property: 2441070-173 HYANNIS(DIGITAL), MA Source: USGS 7.5 min quad index TARGET PROPERTY SEARCH RESULTS ' The target property was identified in the following government records. For more information on this property see page 5 of the attached EDR Radius Map report: Site Database(s) EPA ID PARCEL 125 SHWS N/A 33 BROOKS RD Release ' BARNSTABLE,MA 02601 ATWOOD OIL (HUBBARD OIL CO IN Release N/A 33 BROOKS ROAD HYANNIS,MA 02601 ' FOURNIER PETROLEUM INC RCRIS-SQG MAD051799252 33-51 BROOKS RD FINDS HYANNIS,MA 02601 ' DATABASES WITH NO MAPPED SITES No mapped sites were found in EDR's search of available ( "reasonably ascertainable ") government records either on the target property or within the ASTM E 1527-00 search radius around the target property for the following databases: FEDERAL ASTM STANDARD ' NPL------------------------- National Priority List Proposed NPL-------------- Proposed National Priority List Sites CERCLIS--------------------.Comprehensive Environmental Response, Compensation,and Liability Information System ' TC843894.1s EXECUTIVE SUMMARY 1 ' EXECUTIVE SUMMARY ' CORRACTS------------------Corrective Action Report RCRIS-TSD------------------ Resource Conservation and Recovery Information System RCRIS-LOG------------------Resource Conservation and Recovery Information System I ERNS------------------------ Emergency Response Notification System ' STATE ASTM STANDARD ' SWFILF---------------------- Solid Waste Facility Data Stations FEDERAL ASTM SUPPLEMENTAL Delisted NPL----------------. National Priority List Deletions NPL Liens------------------- Federal Superfund Liens SSTS------------------------.Section 7 Tracking Systems SURROUNDING SITES:SEARCH RESULTS Surrounding sites were identified. l Elevations have been determined from the USGS 1 degree Digital Elevation Model and should be evaluated g g on a relative (not an absolute) basis. Relative elevation information between sites of close proximity should be field verified. EDR's definition of a site with an elevation equal to the target property includes a tolerance of +/- 10 feet. Sites with an elevation equal to or higher than the target property have been differentiated below from sites with an elevation lower than the target property (by more than 10 feet). Page numbers and map identification numbers refer to the EDR Radius Map report where detailed data on individual sites can be reviewed. Sites listed in bold italics are in multiple databases. Unmappable(orphan)sites are not considered in the foregoing analysis. FEDERAL ASTM STANDARD ' CERCLIS-NFRAP:As of February 1995. CERCLIS sites designated"No Further Remedial Action Planned" (NFRAP) have been removed from CERCLIS. NFRAP sites may be sites where, following an initial investigation, no contamination was found, contamination was removed quickly without the need for the ' site to be placed on the NPL, or the contamination was not serious enough to require Federal Superfund Action or NPL consideration. EPA has removed approximately 25,000 NFRAP sites to lift the unintended barriers to the redevelopment of these properties and has archived them as historical records so EPA does not needlessly repeat the investigations in the future. This policy change is part of the EPA's ' Brownfields Redevelopment Program to help cities, states, private investors and affected citizens to promote economic redevelopment of unproductive urban sites. A review of the CERC-NFRAP list,as provided by EDR,and dated 05/15/2002 has revealed that there is ' 1 CERC-NFRAP site within approximately 0.25 miles of the target property. Equal/Higher Elevation Address Dist/Dir Map ID Page PURITAN PONTIAC 460 YARMOUTH ROAD 0- 118 SSE C13 18 TC843894.1s EXECUTIVE SUMMARY 2 1 ' EXECUTIVE SUMMARY ' RCRIS: The Resource Conservation and Recovery Act database includes selected information on sites that generate, store, treat, or dispose of hazardous waste as defined by the Act. The source of this database is the U.S. EPA. ' A review of the RCRIS-SQG list,as provided by EDR,and dated 06/10/2002 has revealed that there are 6 RCRIS-SQG sites within approximately 0.125 miles of the target property. Equal/Higher Elevation Address Dist/Dir Map ID Page 1 CENTRAL CAPE DODGE INC 600 YARMOUTH RD 0-1/8 SE B9 14 CAPE COD LINCOLN MERCURY MAZDA 556 YARMOUTH RD 0-.1/8 SE B10 15 PURITAN PONTIAC 460 YARMOUTH ROAD 0- 118 SSE C13 18 ' CAPE COD TREATMENT&PEST CONT 450 YARMOUTH RD 0- 118 SSE C15 19 AAMCO TRANSMISSIONS 380 YARMOUTH RD 0- 118 S D18 21 ZEPHYR INSTANT PRINTING CENTER 367 YARMOUTH RD 0- 118 S ' D19 21 STATE ASTM STANDARD SHWS: Non Leaking Underground Storage Tank sites within the Releases Database. A review of the SHWS list, as provided by EDR, has revealed that there are 37 SHWS sites within approximately 1 mile of the target property. Equal/Higher Elevation Address Dist/Dir Map ID Page ATWOOD I YARD BROOKS RD 0- 118 NE A4 8 PURITAN PONTIAC BDP 460 YARMOUTH RD 0- 118 SSE C12 17 BP SERVICE STATION 230/YANOUGH ROAD 118- 114SW E22 23 ROBIES REFRIGERATION 279 YARMOUTH RD 118- 114S G23 24 NELSON COAL& OIL INC 180/YANOUGH ROAD 118- 114S F24 26 ' MOBIL SERV STA 156/YANOUGH RD 118- 114S G27 29 CHARTER STATION NO. 6843 FMR 2581YANOUGH ROAD 118- 114 WSW H28 34 GRANDPAS USED BIKES 210 YARMOUTH RD 118- 114S G29 36 ROBERTS AUTO WHOLESALE 202 YARMOUTH RD. 118- 114S 131 38 ' AIRPORT MOBIL 156/YANOUGH RD 118- 114S J35 42 NO LOCATION AID 381 CAMP ST 118- 114 S 36 43 OFF RTE 28 181 SPRING ST 114- 112W 37 44 CAPE DAIRY 44 BODICK RD 114- 112 ENE 38 45 ' WARDICK REALTY TRUST BLIP 143 OLD YARMOUTH RD 114- 112 ENE 39 47 PENTTIS AUTOMOTIVE 143 OLD YARMOUTH RD 114- 112NE 40 48 GARAGE 82 RIDGEWOOD AVE 114- 112SW 41 49 GETTY STATION#30488 112 BARNSTABLE RD 112- 1 SW K43 52 GETTY SERVICE STATION 112 BARNSTABLE RD 112- 1 SW K44 54 ' MARSTON MILLS 106 ROSA LN 112- 1 NE 47 59 BARNSTABLE AIRPORT BOARDMAN-POLANDO FIELD 112- 1 NW L48 60 GRIFFIN AVIONICS BARNSTABLE AIRPORT 112- 1 NW L49 62 ' BOUY S REALTY BDP 5991YANOUGH RD 112- 1 WNW 54 70 BARNSTABLE MUNICIPAL AIRPORT 480 BARNSTABLE RD 112- 1 WNW N55 71 NO LOCATION AID 480 BARNSTABLE RD 112- 1 WNW N56 73 AIRPORT 480 BARNSTABLE RD 112- 1 WNW N57 74 ' NO LOCATION AID 252 HINCKLEY RD 112- 1 W 59 78 BANKS RESIDENCE 312 CAMP ST 112- 1 NE 60 79 SHELL SERVICE STATIOWWILLOW S 381 CAMP ST 112 1 NE 61 80 Lower Elevation Address Dist/Dir Map ID Page COLONIAL CANDLE 232 MAIN ST 112- 1 S 42 50 ' TC843894.1s EXECUTIVE SUMMARY 3 EXECUTIVE.SUMMARY ' Lower Elevation Address Dist/Dir Map ID Page SOUTH ST DOCK 21 SCHOOL ST 112- 1 S 45 55 NO LOCATION AID 18 CENTER ST 112- 1 SSW 46 57 LEWIS BAY MOTEL 53 SOUTH ST 112- 1 S M50 64 STEAMSHIP AUTHORITY 141 SCHOOL ST 112- 1 S M51 65 NYNEX 46 NORTH ST 112- 1 SW 52 67 ' EDUCATION INTERVENTION CTR 71 PLEASANT ST 112- 1 S 53 69 MUTUAL STATION#73 149 NORTH ST 112- 1 SW 58 76 SOUTH END OF MAIN ST 11 HIGH SCHOOL RD 112- 1 SW 62 83 ' LUST:Sites within the Releases Database that have a UST listed as its source. A review of the LUST list, as provided by EDR, and dated 06/26/2002 has revealed that there are 3 ' LUST sites within approximately 0.25 miles of the target property. Equal/Higher Elevation Address Dist/Dir Map ID Page MOBIL SERV STA 156 IYANOUGH RD 118- 114 S G27 29 CHARTER STATION NO. 6843 FMR 258 IYANOUGH ROAD 118- 114WSW H28 34 COTTON PICK/N TS 201 YARMOUTH RD 118 114S 132 39 UST: The Underground Storage Tank database contains registered LISTS. USTs are regulated under Subtitle I of the Resource Conservation and Recovery Act(RCRA). The data come from the Department of Environmental Protection's Summary Listing of all the Tanks Registered in the State of Massachusetts. A review of the UST list, as provided by EDR,and dated 07/17/2002 has revealed that there are 8 UST sites within approximately 0.125 miles of the target property. ' Equal/Higher Elevation Address Dist/Dir_ Map ID Page ATWOOD I YARD BROOKS RD 0- 118 NE A4 8 ' ATWOOD II YARD BROOKS RD 0- 1/8 NE 5 9 CAPEFLIGHT LTD 110 MARY DUNN WAY 0- 1/8 NW 6 12 RUSTY'S INC 55 MARY DUNN RD 0-1/8 SW 7 13 CENTRAL CAPE DODGE. 600 YARMOUTH RD 0-1/8 SE 68 13 PURITAN PONTIAC-ISUZU 460 YARMOUTH RD 0-1/8 SSE C14 18 ' FRANK NUOVO 444 YARMOUTH RD 0- 1/8 SSE C16 19 MANUAL BRITO 657 YARMOUTH RD 0- 1/8 ENE 17 20 Release: MA Release Tracking.Database. ' A review of the Release list as Y provided b EDR and dated 06/26/2002 has revealed that there are 11 P Release sites within approximately 0.25 miles of the target property. rEqual/Higher Elevation Address Dist/Dir Map ID Page PURITAN PONTIAC BDP 460 YARMOUTH RD 0- 118 SSE C12 17 ' SP SERVICE STATION 2301YANOUGH ROAD 118- 114SW E22 23 ROBES REFRIGERATION 279 YARMOUTH RD 118- 114S G23 24 NELSON COAL& OIL INC 180 IYANOUGH ROAD 118- 114S F24 26 MOBIL SERV STA 156 IYANOUGH RD 118- 114 S G27 29 ' CHARTER STATION NO. 6843 FMR 258 IYANOUGH ROAD 118- 114 WSW H28 34 GRANDPAS USED BIKES 2.10 YARMOUTH RD 118- 114S G29 36 TC843894.1s EXECUTIVE SUMMARY 4 EXECUTIVE SUMMARY Equal/Higher Elevation Address Dist/Dir Map ID Page ROBERTS AUTO WHOLESALE 202 YARMOUTH RD 118- 114 S 131 38 COTTON PICKIN TS 201 YARMOUTH RD 118- 114S 132 39 AIRPORT MOBIL 156 IYANOUGH RD 118- 114S J35 42 NO LOCATION AID 381 CAMP ST 118- 114 S 36 43 STATE OR LOCAL ASTM SUPPLEMENTAL ' AST: The Aboveground Storage Tank database contains registered ASTs. The data come from the Department of Environmental Protection's Summary Listing of all the Tanks Registered in the State of Massachusetts. ' A review of the AST list, as provided by EDR, and dated 07/17/2002 has revealed that there is 1 AST site within approximately 0.125 miles of the target property. ' Equal/Higher Elevation Address Dist/Dir_ Map ID Page AIRPORT MOTORS INC 556 YARMOUTH RD 0- 1/8 SE B11 15 MA Spills:This historical spills list includes sudden releases reported to DEP from the mid-1980's through September 30, 1993. The list has been archived and will not undergo further updates. The source is the Department of Environmental Protection's Spills Database. ' A review of the MA Spills list, as provided by EDR, and dated 09/30/1993 has revealed that there are 8 MA Spills sites within approximately 0.25 miles of the target property. t Equal/Higher Elevation Address Dist/Dir_ Map ID Page SANDY'S ROAST BEEF 225 IYANOUGH RD 1/8- 1/4SW E20 22 PROPERTY 180 IYANOUGH RD 1/8- 1/4SSW F21 22 PROPERTY 258 IYANOUGH RD 1/8- 1/4WSW H25 28 ' RTE 132 MOBIL STATION 156 IYANOUGH RD 1/8- 1/4S G26 28 MOBIL SERV STA 156 IYANOUGH RD 118- 114S G27 29 WASTE OIL DUMPING 202 YARMOUTH RD 1/8- 1/4S 130 37 COOTN PICKIN T'S 201 YARMOUTH ROAD 1/8- 1/4S 133 40 ' TEXACO SERV STATION 140 IYANOUGH RD 1/8-1/4SSE J34 41 ' TC843894.1s EXECUTIVE SUMMARY 5 ' EXECUTIVE.SUMMARY' ' Due to poor or inadequate address information,the following sites were not mapped: Site Name Database(s) ' POLE 150/86 SHWS, Release BEHIND SEARS SHWS, Release CUMBERLAND FARMS SHWS, LUST, Release FESTIVAL AT HYANNIS SHWS, Release TJ MAXX PARKING LOT SHWS, Release EXIT 6 SHWS, Release RAY BLACKBURN AUTO SALVAGE BAP SHWS, Release ' NEAR END OF MARY DUNN RD SHWS, Release PACKAGING INDUSTRIAL GROUP FMR SHWS, Release TRANSFORMER VAULT SHWS, Release CAPE FLIGHT AREA SHWS, Release TIRRELL RADIATOR SHOP BAP SHWS, Release ' DUNBAR POINT SHWS SEARS AUTOMOTIVE CENTER SHWS, LUST, Release LAIDLAW BUS,CO. SHWS, Release ROBERTS CLEANERS FMR SHWS, Release ' SUNOCO"FACILITY SHWS, Release STEAMSHIP AUTHORITY SHWS, Release BARNSTABLE FIRE TRAINING SHWS, Release PIER 1 SHWS, Release FERRY TERMINAL SHWS, Release BAP PROPERTY SHWS, Release AUBURN WIRE CO SHWS, Release PACKAGING INDUSTRIES GROUP BAP SHWS, Release ' CANDLE COMPANY FMR BAP SHWS, Release BARNSTABLE MUNICIPAL AIRPORT SHWS, Release NO LOCATION AID SHWS, Release BED AND BREAKFAST SHWS, Release JOSEPHS GAS STA FMR SHWS, Release A&B CANCO SHWS, Release RTE 28 SHWS, Release PURITAN PATH SHWS, Release ' SAQUETUCKET HARBOR SHWS, Release NO LOCATION AID LUST, Release SHELL STATION LUST, Release GIBBS SERVICE STATION FMR LUST, Release ' SUN ISLAND DELIVERY UST MOBIL SS#11730 UST AVIS RENT-A-CAR SYSTEM INC UST PROVINCETOWN BOSTON AIRLINE UST TRANS ATLANTIC MOTORS INC RCRIS-SQG AUTO ZONE 5160 A D A P INC RCRIS-SQG ' TC843894.1s EXECUTIVE SUMMARY 6 ' DETAIL MAP - 843894.1s - Bennett & O'Reilly °o s� Qo �e J �pP ES pJ1 z ' pip o 38 h� ' Z � D A O 5 Q O Q \aP UN N k4 of~� �pJ FD 3T Ree" 1 NDUC BROOK �9D �01 ' 37 /ygNNO �pJ� GNN9p pP 2 3P ENO% o� oQ � FNc/NFyO y9° 1�2 a �c�oJ / 3 / L a SF99 MA RD UHHAMf0 �4~ of~� 23 �1AME0 �Q Fn2 4 � srRFFr �� G o� 29� J34 / A ' 36 °UCH RD UNNAMED STREET �Q',�1 /yAHN0 4Q eo v UCH R UNNAMED P� qN STREET Jam' o CEDAR Si NDUCHRD ' 0^ i/16 N1l8 114 Nlles �t Target Property A Sites at elevations higher than ' or equal to the target property ♦ Sites at elevations lower than Power transmission lines Areas of Critical the target property A' Oil&Gas pipelines Environmental Concern V A Coal Gasification Sites ® 100-year flood zone i Sensitive Receptors ® 500-year flood zone National Priority List Sites Landfill Sites ' TARGET PROPERTY: 33&51 CUSTOMER: Bennett&O'Reilly ADDRESS: 33&51 CONTACT: John Tadema-Wielandt CITY/STATE/ZIP: Hyannis MA 02601 INQUIRY#: 843894.1s 1 ATII nhiel•• Ai 004A /7A n7C4 MA TC- C...+!•n..+L....1A Annll 4i•no...v. Tw , FIRM agoot gas ez 1 MAP FIN NDINGS SUMMARY ' Search Target Distance Total Database Property (Miles) < 1/8 1/8- 1/4 1/4- 1/2 1/2- 1 > 1 Plotted ' FEDERAL ASTM STANDARD ' NPL 0.250 0 0 NR NR NR 0 Proposed NPL 0.250 0 0 NR NR NR 0 CERCLIS 0.500 0 0 0 NR NR 0 CERC-NFRAP 0.250 1 0 NR NR NR 1 CORRACTS 0.250 0 0 NR NR NR 0 RCRIS-TSD 0.250 0 0 NR NR NR 0 RCRIS Lg. Quan.Gen. 0.125 0 NR NR NR NR 0 RCRIS Sm. Quan. Gen. X 0.125 6 NR NR NR NR 6 ERNS TP NR NR NR NR NR 0 STATE ASTM STANDARD ' State Haz.Waste X 1.000 2 9 5 21 NR 37 State Landfill 0.250 0 0 NR NR NR 0 LUST 0.250 0 3 NR NR NR 3 ' UST 0.125 8 NR NR NR NR 8 Release X 0.250 1 10 NR NR NR 11 FEDERAL ASTM SUPPLEMENTAL 1 Delisted NPL 0.250 0 0 NR NR NR 0 FINDS X TP NR NR NR NR NR 0 NPL Liens 0.250 0 0 NR NR NR 0 ' SSTS TP NR NR NR NR NR 0 STATE OR LOCAL ASTM SUPPLEMENTAL AST 0.125 1 NR NR NR NR 1 MA Spills 0.250 0 8 NR NR NR 8 EDR PROPRIETARY HISTORICAL DATABASES ' AQUIFLOW-see EDR Physical Setting Source Addendum ' TP=Target Property NR=Not Requested at this Search Distance Sites may be listed in more than one database ' TC843894.1s Page 4 ' Map ID MAP FINDINGS Direction Distance Distance(ft.) EDR ID Number ' Elevation Site Database(s) EPA ID Number Al PARCEL 125 SHWS S104562723 ' Target 33 BROOKS RD Release N/A Property BARNSTABLE,MA 02601 Site 1 of 4 in cluster A p SHWS: Facility ID: 4-0015370 Site Status: Response Action Outcome Not Required Source Type: DRUMS ' Release Town: HYANNIS Notification Date:03/20/2000 Category: TWO HR Associated 1D: 4-00000824 Status Date: 03/20/2000 Phase: Not reported MA RELEASE: Facility ID: 4-0015370 Facility Status: Response Action Outcome Not Required Status Date: 03/20/2000 Phase: Not reported Notification: 03/20/2000 Category: TWO HR Official City: BARNSTABLE Action: Date: 03/20/2000 ' Type: Response Action Outcome Not Required Status: Related to a Tier Classified Site Response action Outcome: Activity Use Limitaion: ' LSP Number: 4966 Action: Date: 03/20/2000 Type: Release ' Status: REPORT Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported ' Action: Date: 08/11/2000 Type: Immediate Response Status: Completion Statement Received ' Response Action Outcome: Activity Use Limitaion: LSP Number: 4966 Action: Date: 03/20/2000 ' Type: Response Action Outcome Not Required Status: Related to a Tier Classified Site Response Action Outcome: ' Activity Use Limitaion: LSP Number: 4966 Action: Date: 03/20/2000 ' Type: Release Status: REPORT Response Action Outcome: Activity Use Limitaion: ' LSP Number: Not reported ' TC843894.1s Page 5 ' Map ID MAP FINDINGS Direction Distance Distance(ft.) EDR ID Number ' Elevation Site Database(s) EPA ID Number PARCEL 125 (Continued) S104562723 Action: Date: 08/11/2000 Type: Immediate Response Status: Completion Statement Received Response Action Outcome: Activity Use Limitaion: LSP Number: 4966 ' Chemical Released: Chemical: UNKNOWN CHEMICAL OF UNKNOWN TYPE Amount: 385,gallons Location Type: COMMERCIAL Source Type: DRUMS ' ASC Relewe Tracking Number: 4-00000824 A2 ATWOOD OIL (HUBBARD OIL CO IN Release S105309489 ' Target 33 BROOKS ROAD N/A Property HYANNIS,MA 02601 Site 2 of 4 In cluster A MA RELEASE: Facility ID: 4-0000824 Facility Status: TIERIC ' Status Date:; 08/09/1996 Phase: PHASE II Notification: 11/01/1989 Category: NONE Official City: BARNSTABLE Action: Date: 11/01/1989 Type: Release Status: TCTRNS Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported ' Action: Date: 04/03/2000 Type: Tier Classification Status: PEREFF ' Response Action Outcome: Activity Use,Limitaion: LSP Number: Not reported Action: Date: 08/09/1996 Type: Phase I Status: Completion Statement Received Response Action Outcome: Activity Use Limitaion; ' LSP Number: Not reported Action: Date: 08/11/2000 Type: Immediate Response Status: Imminent Hazard Evaluation Received Response Action Outcome: Activity Use Limitaion: LSP Numbe,-: Not reported ' Action: Date: 11/01/1989 Type: Release ' TC843894.1 s Page 6 Map ID MAP FINDINGS Direction Distance Distance(ft.) EDR ID Number ' Elevation Site Database(s) EPA ID Number ATWOOD OIL (HUBBARD OIL CO IN (Continued) S105309489 Status: TCTRNS Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported ' Action: Date: 04/03/2000 Type: Tier Classification Status: PEREFF ' Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported Action: ' Date: 08/09/1996 Type: Phase I Status: Completion Statement Received Response Action Outcome: ' Activity Use Limitaion: LSP Number: Not reported Action: Date: 08/11/2000 Type: Immediate Response Status: Imminent Hazard Evaluation Received Response Action Outcome: Activity Use Limitaion: ' LSP Number: Not reported Chemical Released: Chemical: PETROLEUM BASED OIL Amount: Not reported ' Location Type: COMMERCIAL Source Type: AST ASC Release Tracking Number: Not reported ' A3 FOURNIER PETROLEUM INC RCRIS-SQG 1000365393 Target 33-51 BROOKS RD FINDS MAD051799252 Property HYANNIS,MA 02601 ' Site 3 of 4 In cluster A RCRIS: Owner: B&A FOURNIER REALTY INC ' (617)555-1212 EPA ID: MAD051799252 Contact: ALFRED FOURNIER ' (508)775-0192 Classification: Small Quantity Generator Used Oil Recyc: No TSDF Activities: Not reported ' Violation Status:Violations exist Regulation Violated: 310 CMR 30.35(8) Area of Violation: GENERATOR-ALL REQUIREMENTS(OVERSIGHT) Date Violation Determined: 06/24/1991 Actual Date Achieved Compliance: 06/24/1996 Regulation Violated: 682 Area of Violation: GENERATOR-ALL REQUIREMENTS(OVERSIGHT) ' Date Violation Determined: 06/24/1991 Actual Date Achieved Compliance: 06/24/1996 TC843894.1s Page 7 1 ' Map ID MAP FINDINGS Direction Distance Distance(ft.) EDR ID Number ' Elevation Site Database(s) EPA ID Number FOURNIER PETROLEUM INC (Continued) 1000365393 ' Regulation Violated: 685 Area of Violation: GENERATOR-ALL REQUIREMENTS(OVERSIGHT) Date Violation Determined: 06/24/1991 Actual Date Achieved Compliance: 06/24/1996 ' Regulation Violated: 340(1)(b) Area of Violation: GENERATOR-ALL REQUIREMENTS(OVERSIGHT) Date Violation Determined: 06/24/1991 Actual Date Achieved Compliance: 06/24/1996 Regulation Violated: 253(1)(h) Area of Violation: GENERATOR-ALL REQUIREMENTS(OVERSIGHT) Date Violation Determined: 06/24/1991 ' Actual Date Achieved Compliance: 06/24/1996 There are 5 violation record(s)reported at this site: Date of Evaluation Area of Violation ___ Comoliance Compliance Evaluation Inspection GENERATOR-ALL REQUIREMENTS(OVERSIGHT) 19960624 GENERATOR-ALL REQUIREMENTS(OVERSIGHT) 19960624 GENERATOR-ALL REQUIREMENTS(OVERSIGHT) 19960624 ' GENERATOR-ALL REQUIREMENTS(OVERSIGHT) 19960624 GENERATOR-ALL REQUIREMENTS(OVERSIGHT) 19960624 ' FINDS: Other Pertinent Environmental Activity Identified at Site: AIRS Facility System(AIRS/AFS) Facility Registry System(FRS) Resource Conservation and Recovery Act Information system(RCRAINFO) 1 A4 ATWOOD I YARD SHWS 0002007995 NE BROOKS RD UST N/A <118 HYANNIS,MA 02601 86 ft. Higher Site 4 of 4 in cluster A ' SHWS: Facility ID: 4-0000824 Site Status: TIERIC Source Type: AST ' Release Town: HYANNIS Notification Date:11/01/1989 Category: NONE Associated ID: - ' Status Date: 08/09/1996 Phase: PHASE II ' TC843894.1s Page 8 t Map ID MAP FINDINGS Direction Distance Distance(ft.) EDR ID Number ' Elevation Site Database(s) EPA ID Number ATWOOD 1 YARD (Continued) 0002007995 UST: Facility ID: 1076.0000 Tank ID: 1.00000 ' Tank Status: Removed Tank Useage: Not reported Capacity: 275.00000 Owner: HUBBARD OIL COMPANY INC ' Owner Address: PO BOX 10 HYANNIS,MA 02601 Serial Number: Not reported Aboveground: No ' Contents: Fuel Oil Tank Material: Steel Tank Contents: Not reported Tank,Leak Detection:) Pipe Leak Detection:Not reported Facility ID: 1076.0000 Tank ID: 2.00000 Tank Status: Removed Tank Useage: Not reported Capacity: 550.00000 Owner: HUBBARD OIL COMPANY INC Owner Address: PO BOX 10 HYANNIS,MA 02601 Serial Number: Not reported Aboveground: No Contents: Kerosene Tank Material: Steel Tank Contents: Not reported Tank Leak Detection:] Pipe Leak Detection:Not reported ' Facility ID: 1076.0000 TanklD: 3.00000 Tank Status: Removed ' Tank Useage: Not reported Capacity: 1000.0000 Owner: HUBBARD OIL COMPANY INC Owner Address: PO BOX 10 ' HYANNIS,MA 02601 Serial Number: Not reported Aboveground: No Contents: Fuel Oil ' Tank Material: Steel Tank Contents: Not reported Tank Leak Detection:I Pipe Leak Detection:Not reported ' 5 ATWOOD 11 YARD UST 0002007924 NE BROOKS RD N/A ' <1/8 HYANNIS,MA 02601 225 ft. Higher TC843894.1 s Page 9 ' Map ID MAP FINDINGS Direction Distance Distance(ft.) EDR ID Number ' Elevation Site Database(s) EPA ID Number ATWOOD II YARD (Continued) 0002007924 ' UST: Facility ID: 1043.0000 Tank ID: 1.00000 Tank Status: Removed Tank Useage: Not reported Capacity: 4000.0000 Owner: B&A FOURNIER REALTY INC ' Owner Address: P.O.BOX 1238 HYANNIS,MA 02601 Serial Number: Not reported Aboveground: No Contents: Gasoline Tank Material: Steel Tank Contents: Not reported Tank Leak Detection:Not reported Pipe Leak Detection:Not reported ' Facility ID: 1043.0000 Tank ID: 2.00000 Tank Status: Removed ' Tank Useage: Marina Capacity: 4000.0000 Owner: B&A FOURNIER REALTY INC Owner Address: P.O.BOX 1238 I ' HYANNIS,MA 02601 Serial Number: Not reported Aboveground: No Contents: Gasoline Tank Material: Steel Tank Contents: Not reported Tank Leak Detection:Not reported Pipe Leak Detection: Not reported ' Facility ID: 1043.0000 TanklD: 3.00000 Tank Status: Removed ' Tank Useage: Marina Capacity: 4000.0000 Owner: B&A FOURNIER REALTY INC Owner Address: P.O:BOX 1238 t HYANNIS,MA 02601 Serial Number: Not reported Aboveground: No Contents: Diesel t Tank Material: Steel Tank Contents: Not reported Tank Leak Detection:Not reported Pipe Leak Detection:Not reported TC843894.1 s Page 10 Map ID _.MAP.FINDINGS , Direction Distance Distance(ft.) EDR ID Number ' Elevation Site Database(s) EPA ID Number ATWOOD II YARD (Continued) 0002007924 ' Facility ID: 1043.0000 TanklD: 4.00000 Tank Status: Removed ' Tank Useage: Marina Capacity: 4000.0000 Owner: B&A FOURNIER REALTY INC Owner Address: P.O.BOX 1238 ' HYANNIS,MA 02601 Serial Number: Not reported Aboveground: No Contents: Gasoline I ' Tank Material: Steel Tank Contents: Not reported Tank Leak Detection:Not reported Pipe-Leak Detection:Not reported Facility ID: 1043.0000 Tank ID: 5.00000 Tank Status: Removed I ' Tank Useage:. Marina Capacity: 500.00000 Owner: B&A FOURNIER REALTY INC Owner Address: P.O.BOX 1238 ' HYANNIS,MA 02601 ; Serial Number: Not reported Aboveground: No Contents: Kerosene ' Tank Material: Steel Tank Contents: Not reported Tank Leak Detection:Not reported Pipe Leak Detection:Not reported ' Facility ID: 1043.0000 Tank ID: 6.00000 Tank Status: Removed ' Tank Useage: Marina Capacity: 500.00000 Owner: B&A FOURNIER REALTY INC Owner Address: P.O.BOX 1238 ' HYANNIS,MA 02601 Serial Number: Not reported Aboveground: No Contents: Waste Oil ' Tank Material: Steel Tank Contents: Not reported Tank Leak Detection:Not reported Pipe Leak Detection:Not reported ' TC843894.1 s Page 11 I ' Map ID - . - -.- MAP FINDINGS Direction Distance Distance(ft.) EDR ID Number ' Elevation Site Database(s) EPA ID Number ATWOOD II YARD (Continued) 0002007924 ' Facility ID: 1043.0000 Tank ID: 7.00000 Tank Status: Removed ' Tank Useage: Marina Capacity: 8000.0000 Owner: B&A FOURNIER REALTY INC Owner Address: P.O.BOX 1238 ' HYANNIS,MA 02601 Serial Number: Not reported Aboveground: No Contents: Diesel Tank Material: Cathodic Tank Contents: Not reported Tank Leak Detection:I Pipe teak Detection: Not reported ' 6 CAPEFLIGHT LTD UST 0003185812 NW 110 MARY DUNN WAY N/A <1/8 HYANNIS,MA 02601 348 ft. Higher UST: Facility ID: 1056.0000 Tank:ID: 1.00000 Tank Status: Removed Tank Useage: Not reported ' Capacity: 10000.000 Owner: CAPEFLIGHT LTD Owner Address: 110 MARY DUNN WAY ' HYANNIS,MA 02601 Serial Number: Not reported Aboveground: No Contents: Gasoline Tank Material: Steel ' Tank Contents: 1 Wall Tank Leak Detection:Not reported Pipe Leak Detection:Not reported Facility ID: 1056.0000 TanklD: 2.00000 Tank Status: Removed Tank Useage: Not reported ' Capacity: 10000.000 Owner: CAPEFLIGHT LTD Owner Address: 110 MARY DUNN WAY HYANNIS,MA 02601 ' Serial Number: Not reported Aboveground: No Contents: Gasoline Tank Material: Steel ' Tank Contents: 1 Wall Tank Leak Detection:Not reported Pipe Leak Detection:Not reported I ' TC843894.1 s Page 12 ' Map ID MAP FINDINGS. . Direction Distance Distance(ft.) EDR ID Number ' Elevation Site Database(s) EPA ID Number 7 RUSTY'S INC UST 0002007329 ' SW 55 MARY DUNN RD N/A <1/8 HYANNIS,MA 02601 412 ft. Higher ' UST: Facility ID: 40814.000 Tank ID: 1.00000 Tank Status: Removed ' Tank Useage: MV Capacity: 1000.0000 Owner: ESTATE OF WILLIAM J COTTER Owner Address: 111 POND VIEW DR CENTERVILLE,MA 02632 Serial Number: Not reported Aboveground: No Contents: Gasoline I ' Tank Material: Steel Tank Contents: 1 Wall Tank Leak Detection:Not reported Pipe Leak Detection:Not reported: ' Facility ID: 40814.000 Tank ID: 2.00000 Tank Status: Removed Tank Useage: Not reported Capacity: 1000.0000 Owner: ESTATE OF WILLIAM J COTTER Owner Address: 111 POND VIEW DR ' CENTERVILLE,MA 02632 Serial Number: Not reported Aboveground: No Contents: Fuel Oil ' Tank Material: Not reported Tank Contents:. Not reported Tank Leak Detection:Not reported Pipe Leak Detection:Not reported B8 CENTRAL CAPE DODGE UST 1000418460 SE 600 YARMOUTH RD N/A <118 HYANNIS,MA 02601 ' 423 ft. Higher Site 1 of 4 in cluster B ' TC843894.1s Page 13 ' Map ID MAP FINDINGS- Direction Distance Distance(ft.) EDR ID Number ' Elevation Site Database(s) EPA ID Number CENTRAL CAPE DODGE (Continued) 1000418460 ' UST: Facility ID: 1078.0000 TanklD: 1.00000 Tank Status: Removed ' Tank Useage: MV Capacity: 4000.0000 Owner: AIRPORT MOTORS INC ' Owner Address: 600 YARMOUTH RD HYANNIS,MA 02601 Serial Number: Not reported Aboveground: No Contents: Gasoline Tank Material: Steel Tank Contents: 1 Wall Tank.Leak Detection:Not reported Pipe Leak Detection:Not reported I ' Facility ID: 1078.0000 Tank ID: 2.00000 Tank Status: Removed ' Tank Useage: MV Capacity: 4000.0000 Owner: AIRPORT MOTORS INC Owner Address: 600 YARMOUTH RD ' HYANNIS,MA 02601 Serial Number: Not reported Aboveground: No Contents: Gasoline Tank Material: Steel Tank Contents: 1 Wall Tank Leak Detection:Not reported Pipe Leak Detection:Not reported ' Facility ID: 1078,0000 TanklD: 3.00000 Tank Status: Removed ' Tank Useage: MV Capacity: 500.00000 Owner: AIRPORT MOTORS INC Owner Address: 600 YARMOUTH RD ' HYANNIS,MA 02601 Serial Number: Not reported Aboveground: No Contents: Waste Oil Tank Material: Steel Tank Contents: 1 Wall Tank Leak Detection:Not reported Pipe Leak Detection:Not reported ' 89 CENTRAL CAPE DODGE INC RCRIS-SQG 1004717327 SE 600 YARMOUTH RD MAD982198210 <1/8 HYANNIS,MA 02601 423 ft. Higher ' Site 2 of 4 in cluster B ' TC843894.1s Page 14 ' Map ID MAP FINDINGS Direction Distance Distance(ft.) EDR ID Number ' Elevation Site Database(s) EPA ID Number CENTRAL CAPE DODGE INC (Continued) 1004717327 ' ... RCRIS: Owner: NANCY WILBUR (617)555-1212 ' EPA ID: MAD982198210 Contact: ALAN LANE (508)775-1444 Classification: Conditionally Exempt Small Quantity Generator ' Used Oil'Recyc: No TSDF Activities: Not reported Violation Status:No violations found ' CT MANIFEST Additional detail is available in CT MANIFEST. Please contact your EDR Account Executive for more information. ' B10 CAPE COD LINCOLN MERCURY MAZDA RCRIS-SQG 1004715466 SE 556 YARMOUTH RD MAD019411016 <1/8 HYANNIS,MA 02601 ' 449 ft. Higher Site 3 of 4 In cluster B RCRIS: ' Owner: NANCY WINTHROP (617)555-1212 EPA ID: MAD019411016 Contact: ALAN LANE (508)775-1444 Classification: Conditionally Exempt Small Quantity Generator Used Oil Recyc: No TSDF Activities: Not reported ' Violation Status:No violations found CT MANIFEST ' Additional detail is available in CT MANIFEST. Please contact your EDR Account Executive for more information. 1311 AIRPORT MOTORS INC AST 0002007311 SE 556 YARMOUTH RD N/A <1/8 HYANNIS,MA 02601 ' 449 ft. Higher Site 4 of 4 in cluster B ' AST: Facility ID: 1077.0000 TanklD: 1.00000 Tank Status: In Use ' Tank Use: MV Owner: AIRPORT MOTORS INC Owner Address: 600 YARMOUTH RD HYANNIS,MA 02601 ' Serial Number: Not reported Aboveground: Yes Contents: Other Tank: ' Material: Steel Construction: 1 Wall Leak Detection: Not reported ' TC843894.1s Page 15 ' Map ID MAP FINDINGS Direction Distance Distance(ft.) EDR ID Number Elevation Site Database(s) EPA ID Number AIRPORT MOTORS INC (Continued) 0002007311 ` Pipe: Material: Steel Construction: 1 Wall Leak Detection: Not reported ' Facility ID: 1077.0000 TanklD: 2.00000 Tank Status: In Use ' Tank Use: MV Owner: AIRPORT MOTORS INC Owner Address:' 600 YARMOUTH RD HYANNIS,MA 02601 ' Serial Number: Not reported Aboveground: Yes Contents: Other Tank: ' Material: Steel Construction: 1 Wall Leak Detection: Not reported Pipe: ' Material: Steel Construction: 1 Wall Leak Detection: Not reported ' Facility ID: 1077.0000 TanklD: 3.00000 Tank.Status: In Use Tank Use: MV Owner: AIRPORT MOTORS INC Owner Address: 600 YARMOUTH RD HYANNIS,MA 02601 Serial Number: Not reported ' Aboveground: Yes Contents: Waste Oil Tank: Material: Steel ' Construction: 1 Wall Leak Detection: Not reported Pipe: Material: Steel Construction: 1 Wall Leak Detection: Not reported Facility ID: 1077.0000 TanklD: 4.00000 ' Tank Status: In Use Tank Use: MV Owner: AIRPORT MOTORS INC Owner Address: 600 YARMOUTH RD ' HYANNIS,MA 02601 Serial Number: Not reported Aboveground: Yes Contents: Other ' Tank: Material: Steel Construction: 1 Wall Leak Detection: Not reported 1 ' TC843894.1 s Page 16 ' Map ID MAP FINDINGS Direction Distance Distance(ft.) EDR ID Number ' Elevation Site Database(s) EPA ID Number AIRPORT MOTORS INC (Continued) 0002007311 Pipe: Material: Steel Construction: 1 Wall Leak Detection: Not reported 1 I C12 PURITAN PONTIAC BDP SHWS 1000264319 SSE 460 YARMOUTH RD Release N/A <1/8 BARNSTABLE,MA 02110 538 ft. Higher Site 1 of 5 in cluster C SHWS: ' Facility ID: 4-0000251 Site Status: DEPNFA Source Type: DRUMS Release Town: HYANNIS ' Notification Date:01/15/1987 Category: NONE Associated ID: - Status Date: 07/23/1993 ' Phase: Not reported Facility ID: 4-0000251 ' Site Status: DEPNFA Source Type: SEWER TRAP Release Town: HYANNIS Notification Date:01/15/1987 Category: NONE Associated ID: - Status Date: 07/23/1993 Phase: Not reported ' MA RELEASE: Facility ID: 4-0000251 Facility Status: DEPNFA Status Date: 07/23/1993 ' Phase: Not reported Notification: 01/15/1987 Category: NONE Official City: BARNSTABLE ' Action: Date: 01/15/1987 Type: Release Status: TCTRNS ' Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported Action: Date: 01/15/1987 Type: Release Status: TCTRNS Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported Chemical Released: Chemical: WASTE OIL Amount: Not reported ' Location Type: Not reported Source Type: DRUMS ' TC843894.1 s Page 17 ' Map ID MAP FINDINGS Direction Distance Distance(ft.) EDR ID Number ' Elevation Site Database(s) EPA ID Number PURITAN PONTIAC BDP (Continued) 1000264319 ' SEWER TRAP ASC Release Tracking Number: Not reported ' C13 PURITAN PONTIAC RCRIS-SQG 1003862874 SSE 460 YARMOUTH ROAD CERC-NFRAP MAD019412386 <1/8 BARNSTABLE(HYANNIS),MA 02601 539 ft. Higher Site 2 of 5 in cluster C CERCLIS-NFRAP Classification Data: Site Incident Category: Not reported Federal Facility: Not a Federal Facility Non NPL Code: NFRAP Ownership Status: Private NPL Status: Not on the NPL CERCLIS-NFRAP Assessment History: Assessment: DISCOVERY Completed: 05/27/1988 Assessment: PRELIMINARY ASSESSMENT Completed: 06/27/1988 Assessment: ARCHIVE SITE Completed: 06/27/1988 RCRIS: Owner: Not reported EPA ID: MAD019412386 I ' Contact: JOHN BOYD (508)775-7111 Classification: Conditionally Exempt Small Quantity Generator ' Used Oil Recyc: No TSDF Activities: Not reported Violation Status:No violations found ' CT MANIFEST Additional detail is available in CT MANIFEST. Please contact your EDR Account Executive for more information. C14 PURITAN PONTIAC-ISUZU UST 0002007972 SSE 460 YARMOUTH RD N/A <1/8 HYANNIS,MA 02601 539 ft. Higher Site 3 of 5 in cluster C UST: Facility ID: 1064.0000 Tank ID: 1.00000 Tank Status: Removed Tank Useage: Not reported Capacity: 3000.0000 ' Owner: ROBERT MISKINIS Owner Address: 100 MAIN ST BRIDGEWATER,MA 02324 Serial Number: Not reported Aboveground: No Contents: Gasoline Tank Material: Steel Tank Contents: Not reported ' Tank Leak Detection:Not reported Pipe Leak Detection:Not reported TC843894.1s Page 18 ' Map ID MAP FINDINGS Direction Distance Distance(ft.) EDR ID Number ' Elevation Site Database(s) EPA ID Number PURITAN PONTIAC-ISUZU (Continued) 0002007972 Facility ID: 1064.0000 Tank ID: 2.00000 Tank Status: Removed ' Tank Useage: Not reported Capacity: 750.00000 Owner: ROBERT MISKINIS Owner Address: 100 MAIN ST ' BRIDGEWATER,MA 02324 Serial Number: Not reported Aboveground: No Contents: Not reported ' Tank Material: Steel Tank Contents: Not reported Tank Leak Detection:Not reported Pipe-Leak Detection:Not reported ' Facility ID: 1064.0000 Tank ID: 3.00000 Tank Status: Removed Tank Useage: Not reported` ' Capacity: 1000.0000 Owner: ROBERT MISKINIS Owner Address: 100 MAIN ST ' BRIDGEWATER,MA 02324 Serial Number: Not reported Aboveground: No Contents: Waste Oil ' Tank Material: Steel Tank Contents: Not reported Tank Leak Detection:Not reported Pipe Leak Detection:Not reported ' C15 CAPE COD TREATMENT&PEST CONTROL RCRIS-SQG 1000196018 SSE 450 YARMOUTH RD FINDS MAD044814002 4111 HYANNIS,MA 02601 ' 551 ft. Higher Site 4 of 5 in cluster C RCRIS: ' Owner: Not reported EPA ID: MAD044814002 Classification: Small Quantity Generator Used Oil Recyc: No TSDF Activities: Not reported Violation Status:No violations found FINDS: Other Pertinent Environmental Activity Identified at Site: Facility Registry System(FRS) Resource Conservation and Recovery Act Information system(RCRAINFO) C16 FRANK NUOVO UST 0002007974 SSE 444 YARMOUTH RD NIA ' <118 HYANNIS,MA 02601 558 ft. Higher Site 5 of 5 in cluster C TC843894.1 s Page 19 ' Map ID MAP FINDINGS Direction Distance Distance(ft.) EDR ID Number Elevation Site Database(s) EPA ID Number FRANK NUOVO (Continued) 0002007974 UST: Facility ID: 1065.0000 Tank ID: 1.00000 ' Tank Status: Removed Tank Useage: Not reported Capacity: 1000.0000 Owner: FRANK NUOVO ' Owner Address: 444 YARMOUTH RD HYANNIS,MA 02601 Serial Number: Not reported Aboveground: No ' Contents: Gasoline Tank Material: Steel Tank Contents: Not reported Tank,Leak Detection:Not reported Pipe Leak Detection: Not reported Facility ID: 1065.0000 TanklD: 2.00000 Tank Status: Removed t Tank Useage: Not reported Capacity: 1000,0000 Owner: FRANK NUOVO Owner Address: 444 YARMOUTH RD ' HYANNIS,MA 02601 Serial Number: Not reported Aboveground: No Contents: Not reported ' Tank Material: Steel Tank Conterts: Not reported Tank Leak Detection:Not reported Pipe Leak Detection:Not reported 17 MANUAL BRITO UST 0001004332 ENE 657 YARMOUTH RD N/A <1/8 HYANNIS,MA 02601 618 ft. Higher UST: ' Facility ID: 1060.0000 TanklD: 1.00000 Tank Status: Removed ' Tank Useage: Not reported Capacity: 1000.0000 Owner: MANUAL BRITO Owner Address: 657 YARMOUTH RD HYANNIS,MA 02601 ' Serial Number: Not reported Aboveground: No Contents: Gasoline Tank Material: Steel ' Tank Contents: Not reported Tank Leak Detection:Not reported Pipe Leak Detection:Not reported TC843894.1s Page 20 1 Map ID MAP-FINDINGS- Direction Distance Distance(ft.) EDR ID Number ' Elevation Site Database(s) EPA ID Number MANUAL BRITO (Continued) 0001004332 ' Facility ID: 1060.0000 Tank ID: 2.00000 Tank Status: Removed ' Tank Useage: Not reported Capacity: 1000.0000 Owner: MANUAL BRITO Owner Address: 657 YARMOUTH RD ' HYANNIS,MA 02601 Serial Number: Not reported Aboveground: No Contents: Gasoline ' Tank Material: Steel Tank Contents: Not reported Tank Leak Detection:Not reported Pipe-Leak Detection:Not reported D18 AAMCO TRANSMISSIONS RCRIS-SQG 1000177869 South 380 YARMOUTH RD FINDS MAD981061781 ' <1/8 HYANNIS,MA 02601 638 ft. Higher Site 1 of 2 in cluster D ' RCRIS: Owner: LEROY FRAZIER (617)555-1212 EPA ID: MAD981061781 ' Contact: LEROY FRAZIER (508)771-9133 Classification: Small Quantity Generator Used Oil Recyc: No ' TSDF Activities: Not reported Violation Status:No violations found ' FINDS: Other Pertinent Environmental Activity Identified at Site: Facility Registry System(FRS) Resource Conservation and Recovery Act Information system(RCRAINFO) ' D19 ZEPHYR INSTANT PRINTING CENTER RCRIS-SQG 1000244689 South 367 YARMOUTH RD FINDS MAD084651181 <1/8 HYANNIS,MA 02601 657 ft. Higher Site 2 of 2 in cluster D I ' TC843894.1s Page 21 ' Map ID MAP FINDINGS. Direction Distance Distance(ft.) EDR 10 Number ' Elevation Site Database(s) EPA ID Number ZEPHYR INSTANT PRINTING CENTER (Continued) 1000244689 ' RCRIS: Owner: ROBERT C TAVEY SR (617)555-1212 ' EPA ID: MAD084651181 Contact: DAVID PALMERI (508)771-2185 1 Classification: Small Quantity Generator Used Oil Recyc: No TSDF Activities: Not reported Violation Status:No violations found FINDS: Other Pertinent Environmental Activity Identified at Site: 'Facility Registry System(FRS) ' Resource Conservation and Recovery Act Information system(RCRAINFO) E20 SANDY'S ROAST BEEF MA Spills S101043613 ' SW 225 IYANOUGH RD N/A 1/8-1/4 BARNSTABLE,MA 02630 708 ft. Higher Site 1 of 2 in cluster E ' MA Spills: Facility ID: 0000 Spill ID: S92-0565 Staff Lead: BRENNAN,S Date Entered: 09/22/1993 Last Entered: 09/22/1993 First Response: 08/11/1992 Spill Date: 08/09/1992 Report Date: 08/11/1992 Spill Time: Not reported Report Time: 04:15PM Case Closed: YES Mat Type: PETROLEUM Virgin Waste: VIRGIN Contam Soil: Not reported Env Impact: _ Other Impact: Not reported Material: #2 FUEL OIL Other Material: Not reported CAS No: Not reported PCB Lev(ppm): NONE Qty Reported: 51-100 GALLONS Qty Actual: ` Source: A.S.T. Other Source: Not reported Incident: LEAK Other Incdnt: Not reported ' Cleanup Type: — Contractor: NOT USED Referral: NO LUST Elig: NO Notifier: DPT CHF HAROLD BRUNELLE/FD Notif Tel: Not reported Notify Date: Not reported ' Report Prep: Not reported Category: Not reported Days/Close: 0 Capacity: Not reported Chemical: Not reported Quantity: Not reported F21 PROPERTY MA Spills S101036913 SSW 180 IYANOUGH RD N/A 118-1/4 BARNSTABLE,MA 02630 ' 728 ft. Higher Site 1 of 2 in cluster F 1 ' TC843894.1s Page 22 Map ID MAP FINDINGS Direction Distance Distance(ft.) EDR ID Number tElevation Site Database(s) EPA ID Number PROPERTY (Continued) S101036913 ' MA Spills: Facility ID: 4-0716 Spill ID: S90-0405 Staff Lead: PINAUD,L Date Entered: 08/08/1994 Last Entered: 08/08/1994 First Response: 05/31/1990 Spill Date: 05/31/1990 Report Date: 05/31/1990 Spill Time: 12:15PM Report Time: 02:15PM Case Closed: YES Mat Type: PETROLEUM ' Virgin Waste: VIRGIN Contam Soil: Not reported Env Impact: SOIL Other Impact: Not reported Material: DIESEL FUEL Other Material: Not reported CAS No: Not reported PCB Lev(ppm): NONE _ A- Qty Reported: 101-250 GALLONS Qty Actual: Source: ABOVE-GRND TANK Other Source: Not reported Incident: SPILL Other Incdnt: Not reported Cleanup Type: — Contractor: NOT USED Referral: SA LUST Elig: --- Notifier: BRETT MOSCATELLO Notif Tel: Not reported Notify Date: Not reported Report Prep: Not reported Category: Not reported 1 Days/Close: 1 Capacity:. Not reported Chemical: Not reported Quantity: Not reported E22 BP SERVICE STATION SHWS S105309485 SW 230 IYANOUGH ROAD Release N/A 118-1/4 BARNSTABLE,MA 02601 ' 757 ft. Higher Site 2 of 2 in cluster E SHWS: ' Facility ID: 4-0000392 Site Status: TIER1A Source Type: UNKNOWN Release Town: HYANNIS ' Notification Date:07/15/1987 Category: NONE Associated ID Status Date: 10/21/1994 ' Phase: Not reported MA RELEASE: Facility ID: 4-0000392 Facility Status: TIERIA Status Date: 10/21/1994 Phase: Not reported Notification: 07/15/1987 Category: NONE Official City: BARNSTABLE Action: Date: 07/15/1987 Type: Release ' Status: TCTRNS Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported ' Action: Date: 10/21/1994 Type: Tier Classification TC843894.1 s Page 23 Map ID MAP FINDINGS Direction Distance Distance(ft.) EDR ID Number Elevation Site Database(s) EPA ID Number BP SERVICE STATION (Continued) S105309485 ' Status: PEREFF Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported ' Action: Date: 08/13/1999 Type: Phase II Status: Scope of Work Received Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported Action: Date: 07/15/1987 Type: Release Status: TCTRNS Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported Action: Date: 10/21/1994 Type: Tier Classification Status: PEREFF Response Action Outcome: Activity Use Limitaion: ' LSP Number: Not reported Action: Date: 08/13/1999 Type: Phase II Status: Scope of Work Received Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported ' Chemical Released: Chemical: PETROLEUM BASED OIL Amount: Not reported Location Type: GASSTATION Source Type: UNKNOWN tASC Release Tracking Number: Not reported G23 ROBIES REFRIGERATION SHWS S101696571 South 279 YARMOUTH RD Release N/A 1/8-1/4 BARNSTABLE,MA 02601 786 ft. Higher Site 1 of 4 in cluster G ' TC843894.1 s Page 24 ' Map ID MAP FINDINGS Direction Distance Distance(ft.) EDR ID Number Elevation Site Database(s) EPA ID Number ROBIES REFRIGERATION (Continued) S101696571 SHWS: Facility ID: 4-0000934 Site Status: Response Action Outcome Source Type: UNKNOWN Release Town: HYANNIS Notification Date:06/14/1990 Category: NONE ' Associated ID: - Status Date: 06/02/1997 Phase: Not reported MA RELEASE: ' Facility ID: 4-0000934 Facility Status: Response Action Outcome Status Date: 06/02/1997 Phase: Not reported ' Notification: 06/14/1990 Category: NONE Official City: BARNSTABLE Action: ' Date: 06/14/1990 Type: Release Status: TCTRNS Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported Acton: Date: 12/28/1998 ' Type: Response Action Outcome Status: APPTIA Response Action Outcome: Remedial actions have not been conducted because a level of No Significant Risk exists. Activity Use Limitaion: NONE LSP Number: Not reported Action: Date: 06/14/1990 ' Type: Release Status: TCTRNS Response Action Outcome: Activity Use Limitaion: ' LSP Number: Not reported Action: Date: 12/28/1998 Type: Response Action Outcome ' Status: APPTIA Response Action Outcome: Remedial actions have not been conducted because a level of No Significant Risk exists. Activity Use Limitaion: NONE LSP Number: Not reported Chemical Released: Chemical: UNKNOWN CHEMICAL OF TYPE-HAZARDOUS MATERIAL Amount: Not reported ' Chemical Released: Chemical: UNKNOWN CHEMICAL OF TYPE-OIL Amount: Not reported Location Type: COMMERCIAL Source Type: UNKNOWN ' ' TC843894.1s Page 25 ' Map ID MAP FINDINGS Direction Distance Distance(ft.) EDR ID Number ' Elevation Site Database(s) EPA ID Number ROBIES REFRIGERATION (Continued) S101696571 ' ASC Release Tracking Number: Not reported F24 NELSON COAL&OIL INC SHWS S105309488 ' South 180 IYANOUGH ROAD Release N/A 1/8-1/4 BARNSTABLE,MA 02601 836 ft. Higher Site 2 of 2 in cluster F SHWS: Facility ID: 4-0000716 Site Status: Response Action Outcome Source Type: AST ' Release Town: HYANNIS Notification Date:05/23/1989 Category.: NONE Associated ID Status Date: 10/04/2001 Phase: PHASE IV MA RELEASE: Facility ID: 4-0000716 f Facility Status: Response Action Outcome Status Date: 10/04/2001 Phase: PHASE IV I ' Notification: 05/23/1989 Category: NONE Official City: BARNSTABLE Action: ' Date: 05/23/1989 Type: Release Status: TCTRNS Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported Action: Date: 07/10/2000 Type: Tier Classification ' Status: PEREXT Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported ' Action: Date: 10/04/2001 Type: Phase ll Status: Completion Statement Received ' Response Action Outcome: Activity Use Limitaion: LSP Number: 4414 Action: ' Date: 04/22/1999 Type: Release Abatement Measure Status: Completion Statement Received Response Action Outcome: ' Activity Use Limitaion: LSP Number: Not reported Action: Date: 10/04/2001 Type: Phase III Status: Completion Statement Received TC843894.1s Page 26 ' Map ID MAP FINDINGS Direction Distance Distance(ft.) EDR ID Number ' Elevation Site Database(s) EPA ID Number NELSON COAL&OIL INC (Continued) S105309488 ' Response Action Outcome: Activity Use Limitaion: LSP Number: 4414 Action: ' Date: 10/04/2001 Type: Response Action Outcome Status: RAO Statement Received Response Action Outcome: A temporary solution,which ensures the elimination of any substantialhazard, ' has been achieved at the disposal site. Activity Use Limitaion: NONE LSP Number:. 4414 Action: ' Date: 0 1/2411 9 9 7 Type: Release Abatement Measure Status: Written Plan Received Response Action Outcome: ' Activity Use Limitaion: LSP Number: Not reported Action: Date: 05/23/1989 Type: Release Status: TCTRNS Response Action Outcome: Activity Use Limitaion: ' LSP Number: Not reported Action: Date: 07/10/2000 Type: Tier Classification ' Status: PEREXT Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported ' Action: Date: 10I04/2001 Type: Phase II Status: Completion Statement Received ' Response Action Outcome: Activity Use Limitaion: LSP Number: 4414 Action: ' Date: 04/22/1999 Type: Release Abatement Measure Status: Completion Statement Received Response Action Outcome: ' Activity Use Limitaion: LSP Number: Not reported Action: Date: 10/04/2001 Type: Phase III ' Status: Completion Statement Received Response Action Outcome: Activity Use Limitaion: LSP Number: 4414 Action: Date: 10/04/2001 Type: Response Action Outcome Status: RAO Statement Received TC843894.1s Page 27 ' Map ID MAP FINDINGS Direction Distance Distance(ft.) EDR ID Number ' Elevation Site Database(s) EPA ID Number NELSON COAL&OIL INC (Continued) S105309488 ' Response Action Outcome: A temporary solution,which ensures the elimination of any substantialhazard, has been achieved at the disposal site. Activity Use Limitaion: NONE LSP Number: 4414 ' Action: Date: 01/24/1997 Type: Release Abatement Measure Status: Written Plan Received Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported ' Chemical Released: Chemical: PETROLEUM BASED OIL Amount: Not reported Location Type: COMMERCIAL Source Type: AST ' ASC Release Tracking Number: Not reported H25 PROPERTY MA Spills S101042852 ' WSW 258 IYANOUGH RD N/A 1/8-1/4 BARNSTABLE,MA 02630 861 ft. Higher Site 1 of 2 In cluster H ' MA Spills: Facility ID: 0000 Spill ID: S92-0324 Staff Lead: PACKARD,R Date Entered: Not reported ' Last Entered: 06/12/1992 First Response: 05/12/1992 Spill Date: 05/12/0768 Report Date: 05/12/1992 Spill Time: Not reported Report Time: Not reported Case Closed: NO Mat Type: PETROLEUM ' Virgin Waste: VIRGIN Contam Soil: Not reported Env Impact: SOIL Other Impact: Not reported Material: GASOLINE Other Material: Not reported CAS No: Not reported PCB Lev(ppm): NONE ' Qty Reported: UNKNOWN GALLONS Qty Actual: UNKNOWN GALLONS Source: U.S.T. Other Source: Not reported Incident: --------- Other Incdnt: Not reported Cleanup Type: — Contractor: NOT USED ' Referral: NO LUST Elig: NO Notifier: Not reported Notif Tel: Not reported Notify Date: Not reported Report Prep: Not reported Category: Not reported ' Days/Close: 0 Capacity: Not reported Chemical: Not reported Quantity: Not reported ' G26 RTE 132 MOBIL STATION MA Spills S101037634 South 156 IYANOUGH RD N/A 1/8-1/4 BARNSTABLE,MA 02630 865 ft. Higher Site 2 of 4 in cluster G ' TC843894.1 s Page 28 Map ID MAP FINDINGS Direction Distance Distance(ft.) EDR ID Number ' Elevation Site Database(s) EPA ID Number RTE 132 MOBIL STATION (Continued) S101037634 ' MA Spills: Facility ID: 4-0862 Spill ID: S91-0200 Staff Lead: KEARNS,R Date Entered: 02/27/1992 ' Last Entered: 02/27/1992 First Response: 04/16/1991 Spill Date: 04/16/1991 Report Date: 04/16/1991 Spill Time: 01:OOAM Report Time: 01:45AM Case Closed: YES Mat Type: NEITHER Virgin Waste: --- Contam Soil: Not reported ' Env Impact: Not reported Other Impact: Not reported Material: OTHER MATERIAL > Other Material: EFFLUENT WATER ' CAS No: Not reported PCB Lev(ppm): ---------- Qty Reported: UNKNOWN----- Qty Actual: UNKNOWN------- Source: OTHER SOURCE > Other Source: GW REC SYS Incident: OTHER RELEASE> Other Incdnt: LEACHING Cleanup Type: — Contractor: NOT USED ' Referral: SA LUST Elig: NO Notifier. CAPT GRANT/FD Notif Tel: Not reported Notify Date: Not reported Report Prep: Not reported Category: Not reported ' Days/Close: 1 Capacity: Not reported Chemical: Not reported Quantity: Not reported I ' G27 MOBIL SERV STA SHWS S101026778 South 156 IYANOUGH RD LUST N/A 1/8-1/4 BARNSTABLE,MA 02630 Release ' 865 ft. MA Spills Higher Site 3 of 4 in cluster G SHWS: ' Facility ID: 4-0011972 Site Status: Response Action Outcome Source Type: DRYWELL Release Town: BARNSTABLE Notification Date:03/16/1996 Category: 120 DY Associated ID: 4-00000862 Status Date: 07/01/1996 ' Phase: Not reported Facility ID: 4-0013422 Site Status.: TIERIC Source Type: PIPE ' Release Town: HYANNIS Notification Date:10/09/1997 Category: 72 HR Associated ID: 4-00000862 Status Date: 10/16/1998 Phase: PHASE IV i TC843894.1 s Page 29 ' Map ID _ MAP FINDINGS. Direction Distance Distance(ft.) EDR ID Number ' Elevation Site Database(s) EPA ID Number MOBIL SERV STA (Continued) S101026778 ' LUST: Facility ID: 4-0000862 Site Status: Response Action Outcome ' Source Type: UST Release Town: HYANNIS Notification Date:01/15/1990 Category: NONE ' Associated ID: - Status Date: 12/29/1994 Phase: Not reported MA RELEASE: ' Facility ID: 4-0000862 Facility Status: Response Action Outcome Status Date: 12/29/1994 Pharse: Not reported ' Notification: 01/15/1990 Category: NONE Official City: BARNSTABLE Action: Date: 01/15/1990 Type: Release Status: TCTRNS Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported Action: Date: 12/29/1994 Type: Response Action Outcome Status: RAO Statement Received Response Action Outcome: A permanent solution has been achieved. Contamination has not been reduced to background. ' Activity Use Limitaion: NONE LSP Number: Not reported Action: Date: 10/07/1994 ' Type: Tier Classification Status: PEREFF Response Action Outcome: Activity Use Limitaion: ' LSP Number: Not reported Action: Date: 01/15/1990 Type: Release Status: TCTRNS Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported ' Action: Date: 12/29/1994 Type: Response Action Outcome Status: RAO Statement Received Response Action Outcome: A permanent solution has been achieved. Contamination has not been reduced to background. Activity Use Limitaion: NONE LSP Number: Not reported ' Action: ' TC843894.1s Page 30 Map ID - MAP FINDINGS Direction Distance Distance(ft.) EDR ID Number Elevation Site Database(s) EPA ID Number MOBIL SERV STA (Continued) S101026778 ' Date: 10/07/1994 Type: Tier Classification Status: PEREFF Response Action Outcome: ' Activity Use Limitaion: LSP Number: Not reported Chemical Released: Chemical: PETROLEUM BASED OIL ' Amount: Not reported Location Type: COMMERCIAL GASSTATION Source Type: UST ASC Release Tracking Number: Not reported Facility ID: 4-0011972 Facility Status: Response Action Outcome Status Date: 07/01/1996 Phase: Not reported Notification: 03/16/1996 Category: 120 DY Official City: BARNSTABLE ' Action: Date: 03/16/1996 Type: Release ' Status: REPORT Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported Action: Date: 05/02/1996 Type: RNF Status: REPORT ' Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported Action: Date: 07/01/1996 ' Type: RNF Status: REPORT Response Action Outcome: ' Activity Use Limitaion: LSP Number: Not reported Action: Date: 07/01/1996 Type: Response Action Outcome Status: RAO Statement Received Response Action Outcome: A permanent solution has been achieved. Contamination has not been reduced to background. Activity Use Limitaion: NONE ' LSP Number: Not reported Action: Date: 03/16/1996 Type: Release Status: REPORT Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported I TC843894.1 s Page 31 ' Map ID MAP FINDINGS_ _. Direction Distance Distance(ft.) EDR ID Number Elevation Site Database(s) EPA ID Number MOBIL SERV STA (Continued) S101026778 Action: Date: 05/02/1996 Type: RNF Status: REPORT ' Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported Action: ' Date: 07/01/1996 Type: RNF Status: REPORT Response Action Outcome: ' Activity Use Limitaion: LSP Number: Not reported Action: Date: 07/01/1996 ' Type: Response Action Outcome Status: RAO Statement'Received Response Action Outcome: A permanent solution has been achieved. Contamination has not been reduced to background. Activity Use Limitaion: NONE LSP Number: Not reported Chemical Released: Chemical: TOTAL PETROLEUM HYDROCARBONS(TPH) ' Amount: 8160,parts per million Location Type: COMMERCIAL Source Type: DRYWELL ASC Release Tracking Number: 4-00000862 ' Facility ID: 4-0013422 Facility Status: TIERIC Status Date: 10/16/1998 Phase: PHASE IV Notification: 10/09/1997 Category: 72 HR Official City: BARNSTABLE ' Action: Date: 10/09/1997 Type: Release Status: REPORT ' Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported Action: ' Date: 11/21/1997 Type: RNF Status: REPORT Response Action Outcome: Activity Use Limitaion' LSP Number: Not reported Action: Date: 04/03/2002 ' Type: Immediate Response Status: Completion Statement Received Response Action Outcome: Activity Use Limitaion: LSP Number: 5895 1 ' TC843894.1s Page 32 ' Map ID MAP FINDINGS Direction Distance Distance(ft.) EDR ID Number ' Elevation Site Database(s) EPA ID Number MOBIL SERV STA (Continued) S101026778 Action: Date: 03/06/2000 Type: Tier Classification ' Status: PEREFF Response Action Outcome: Activity Use Limitaion: LSP Number: 7710 ' Action: Date: 10/16/1998 Type: Phase I Status: Completion Statement Received Response Action Outcome: ' Activity Use Limitaion: LSP Number: 7710 Action: Date: 03/07/2002 ' Type: Phase II Status: Completion Statement Received Response Action Outcome: Activity Use Limitaion: ' LSP Number: 5895 Action: Date: 03/07/2002 ' Type: Phase III Status: Completion Statement Received Response Action Outcome: Activity Use Limitaion: LSP Number: 5895 Action: Date: 10/09/1997 Type: Release Status: REPORT ' Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported Action: ' Date: 11/21/1997 Type: RNF Status: REPORT Response Action Outcome: ' Activity Use Limitaion: LSP Number: Not reported Action: Date: 04/03/2002 ' Type: Immediate Response Status: Completion Statement Received Response Action Outcome: Activity Use Limitaion: ' LSP Number: 5895 Action: Date: 03/06/2000 Type: Tier Classification ' Status: PEREFF Response Action Outcome: Activity Use Limitaion: LSP Number: 7710 � t Action: ' TC843894.1s Page 33 Map ID MAP FINDINGS Direction Distance Distance(ft.) EDR ID Number I ' Elevation Site Database(s) EPA ID Number MOBIL SERV STA (Continued) S101026778 Date: 10/16/1998 t LL' Type: Phase I Status: Completion Statement Received ' Response Action Outcome: Activity Use Limitaion: LSP Number: 7710 Action: ' Date: 03/07/2002 Type: Phase II Status: Completion Statement Received Response Action Outcome: Activity Use Limitaion: LSP Number: 5895 Action: Date: 03/07/2002 Type: Phase III ' Status: Completion Statement Received Response Action Outcome: Activity Use Limitaion: LSP Number: 5895 Chemical Released: Chemical: GASOLINE Amount: Not reported Location Type: COMMERCIAL ' Source Type: PIPE ASC Release Tracking Number: 4-00000862 MA Spills: ' Facility ID: 4-0862 Spill ID: S89-0812 Staff Lead: OTHER Date Entered: 12/09/1993 Last Entered: 12/09/1993 First Response: 11/20/1989 Spill Date: 11/20/0768 Report Date: 11/16/1989 ' Spill Time: Not reported Report Time: 04:15PM Case Closed: YES Mat Type: PETROLEUM Virgin Waste: Contam Soil: Not reported Env Impact: Not reported Other Impact: Not reported ' Material: GASOLINE "-- Other Material: Not reported CAS No: Not reported PCB Lev(ppm): Qty Reported: UNKNOWN GALLONS Qty Actual: UNKNOWN GALLONS Source: U.S.T. Other Source: Not reported Incident: LEAK Other Incdnt: Not reported Cleanup Type: Contractor: NOT USED Referral: SA LUST Elig: -- Notifier. JOAN LUCIA/ENGR CLERK Notif Tel: Not reported Notify Date: Not reported Report Prep: Not reported Category: Not reported Days/Close: 0 Capacity: Not reported Chemical: Not reported ' Quantity: Not reported H28 CHARTER STATION NO.6843 FMR SHWS S105309482 ' WSW 258 IYANOUGH ROAD LUST N/A 1M-1/4 BARNSTABLE,MA 02601 Release 882 ft. Higher Site 2 of 2 in cluster H 1 ' TC843894.1s Page 34 Map ID MAP FINDINGS.:__ Direction Distance Distance(ft.) EDR ID Number Elevation Site Database(s) EPA ID Number CHARTER STATION NO.6843 FMR (Continued) S105309482 SHWS: Facility ID: 4-0000026 Site Status: TIER1A Source Type: UNKNOWN Release Town: HYANNIS Notification Date:01/15/1987 Category: NONE Associated ID: - Status Date: 10/28/1994 Phase: PHASE III LUST: Facility ID: 4-0000026 Site Status: TIERIA Source Type: UST Release Town: HYANNIS ' Notification Date:01/15/1987 Category: NONE Associated ID: - Status Date: 10/28/1994 Phase: PHASE III MA RELEASE: Facility ID: 4-0000026 ' Facility Status: TIERIA Status Date: 10/28/1994 Phase: PHASE III Notification: 01/15/1987 Category: NONE Official City: BARNSTABLE Action: Date: 01/15/1987 ' Type: Release Status: TCTRNS Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported Action: Date: 11/14/2001 Type: Tier Classification ' Status: PEREXT Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported ' Action: Date: 02/27/1998 Type: Phase II Status: Completion Statement Received ' Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported Action: ' Date: 11/21/1994 Type: Release Abatement Measure Status: Completion Statement Received Response Action Outcome: ' Activity Use Limitaion: LSP Number: Not reported ' TC843894.1s Page 35 ' Map ID MAP FINDINGS Direction Distance Distance(ft.) EDR ID Number Elevation Site Database(s) EPA ID Number CHARTER STATION NO.6843 FMR (Continued) S105309482 Action: Date: 01/15/1987 Type: Release Status: TCTRNS ' Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported Action: Date: 11/14/2001 Type: Tier Classification Status: PEREXT Response Action Outcome: ' Activity Use Limitaion: LSP Number: Not reported Action: pate: 02/27/1998 Type: Phase II Status: Completion Statement Received Response Action Outcome: Activity Use Limitaion: I ' LSP Number: Not reported Action: Date: 11/21/1994 Type: Release Abatement Measure ' Status: Completion Statement Received Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported ' Chemical Released: Chemical: GASOLINE Amount: Not reported Location Type: GASSTATION Source Type: UNKNOWN UST ASC Release Tracking Number: Not reported 1 G29 GRANDPAS USED BIKES SHWS S102687528 South 210 YARMOUTH RD Release N/A 1/8-1/4 BARNSTABLE,MA 02630 ' 896 ft. Higher Site 4 of 41n cluster G SHWS: Facility ID: 4-0013201 Site Status: Downgradient Property Status Source Type: UNKNOWN Release Town: BARNSTABLE Notification Date:07/18/1997 Category: 120 DY Associated ID Status Date: 01/30/1998 Phase: Not reported ' TC843894.1 s Page 36 ' Map ID MAP FINDINGS Direction Distance Distance(ft.) EDR ID Number ' Elevation Site Database(s) EPA ID Number GRANDPAS USED BIKES (Continued) S102687528 ' MA RELEASE: Facility ID: 4-0013201 Facility Status: Downgradient Property Status ' Status Date: 01/30/1998 Phase: Not reported Notification: 07/18/1997 Category: 120 DY ' Official City: BARNSTABLE Action: Date: 01/30/1998 Type: Downgradient Property Status ' Status: Fee Received Response Action Outcome: Activity Use Limitaion: LSP Number: 7893 ' Action: Date: 07/18/1997 Type: Release Status: REPORT Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported Action: ' Date: 01/30/1998 Type: Downgradient Property Status Status: Fee Received Response Action Outcome: ' Activity Use Limitaion: LSP Number: 7893 Action: Date: 07/18/1997 ' Type: Release Status: REPORT Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported Chemical Released: Chemical: TOTAL PETROLEUM HYDROCARBONS(TPH) Amount: 3.51 parts per million ' Chemical Released: Chemical: NAPHTHALENE,2-CHLORO- Amount: 230,parts per billion Location Type: COMMERCIAL Source Type: UNKNOWN ' ASC Release Tracking Number: Not reported 130 WASTE OIL DUMPING MA Spills S101038741 South 202 YARMOUTH RD N/A 1/8-1/4 BARNSTABLE,MA 02630 908 ft. Higher Site 1 of 4 In cluster I ' TC843894.1 s Page 37 Map ID MAP FINDINGS— --- - -- ' Direction Distance Distance(ft.) EDR ID Number ' Elevation Site Database(s) EPA ID Number WASTE OIL DUMPING (Continued) S101038741 ' MA Spills: Facility ID: 0000 Spill ID: S91-0470 Staff Lead: MORAN,M Date Entered: 03/02/1992 ' Last Entered: 03/02/1992 First Response: 08/13/1991 Spill Date: 08/13/0768 Report Date: 08/13/1991 Spill Time: Not reported Report Time: 10:30AM Case Closed: NO Mat Type: PETROLEUM Virgin Waste: WASTE Contam Soil: Not reported Env Impact: Not reported Other Impact: Not reported Material: OTHER MATERIAL > Other Material: WASTE OIL&PAINT WASTE CAS No: Not reported PCB Lev(ppm): --------- Qty Reported: UNKNOWN------- Qty Actual: UNKNOWN------- Source: OTHER SOURCE > Other Source: CONTAINERS Incident: DUMPING Other Incdnt: Not reported ' Cleanup Type: -- Contractor: NOT USED Referral: NO LUST Elig: Notifier. RICK BARTLETT Notif Tel: Not reported Notify Date: Not reported ' Report Prep: Not reported ' Category: Not reported Days/Close: . 0 Capacity: Not reported Chemical: Not reported Quantity: Not reported ' 131 ROBERTS AUTO WHOLESALE SHWS S103812511 South 202 YARMOUTH RD Release N/A ' 1/8-1/4 BARNSTABLE,MA 02630 908 ft. Higher Site 2 of 4 in cluster 1 SHWS: ' Facility ID: 4-0013202 Site Status: Downgradient Property Status Source Type: UNKNOWN Release Town: BARNSTABLE ' Notification Date:07/18/1997 Category: 120 DY Associated ID: - Status Date: 08/07/1998 ' Phase: Not reported MA RELEASE: Facility ID: 4-0013202 ' Facility Status: Downgradient Property Status Status Date: 08/07/1998 Phase: Not reported Notification: 07/18/1997 ' Category: 120 DY Official City: BARNSTABLE Action: Date: 07/18/1997 Type: Release ' Status: REPORT Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported Action: Date: 08/07/1998 Type: Downgradient Property Status ' TC843894.1s Page 38 r ' Map ID MAP FINDINGS' Direction Distance Distance(ft.) EDR ID Number ' Elevation Site Database(s) EPA ID Number ROBERTS AUTO WHOLESALE (Continued) S103812511 ' Status: Transmittal Received Response Action Outcome: Activity Use Limitaion: LSP Number: 7893 ' Action: Date: 07/18/1997 Type: Release Status: REPORT ' Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported Action: ' Date: 08/07/1998 Type: Downgradient Property Status Status: Transmittal Received Response Action Outcome: ' Activity Use Limitaion: LSP_Number: 7893 Chemical Released: Chemical: NAPHTHALENE,2-CHLORO- ' Amount: 67,parts per billion Chemical Released: Chemical: TOTAL PETROLEUM HYDROCARBONS(TPH) Amount: 205,parts per million ' Location Type: COMMERCIAL Source Type: UNKNOWN ASC Release Tracking Number: Not reported 132 COTTON PICKIN TS LUST S100830843 South 201 YARMOUTH RD Release N/A 1/8-1/4 HYANNIS,MA 02601 ft. Hig Higher Site 3 of 4 in cluster I LUST: Facility ID: 4-0000852 ' Site Status: Downgradient Property Status Source Type: UST Release Town: HYANNIS Notification Date:01/15/1990 ' Category: NONE Associated ID Status Date: 04/17/1997 Phase: Not reported ' MA RELEASE: Facility ID: 4-0000852 Facility Status: Downgradient Property Status ' Status Date: 04/17/1997 Phase: Not reported Notification: 01/15/1990 Category: NONE ' Official City: BARNSTABLE Action: Date: 01/15/1990 Type: Release ' Status: TCTRNS Response Action Outcome: Activity Use Limitaion: ' TC843894.1s Page 39 ' Map ID MAP FINDINGS Direction Distance .Distance(ft.) EDR ID Number ' Elevation Site Database(s) EPA ID Number COTTON PICKIN TS (Continued) S100830843 ' LSP Number: Not reported Action: Date: 04/17/1997 Type: Downgradient Property Status ' Status: Transmittal Received Response Action Outcome: Activity Use Limitaion: ' LSP Number: Not reported Action: Date: 10/17/1994 Type: Tier Classification Status: PEREFF Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported Action: ' Date: 01/15/1990 Type: Release Status: TCTRNS Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported Action: Date: 04/17/1997 ' Type: Downgradient Property Status Status: Transmittal Received Response Action Outcome: Activity Use Limitaion: ' LSP Number: Not reported Action: Date: 10/17/1994 Type: Tier Classification ' Status: PEREFF Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported ' Chemical Released: Chemical: PETROLEUM BASED OIL Amount: Not reported Location.Type: COMMERCIAL ' MANUFACT Source Type: UST ASC Release Tracking Number: Not reported ' 133 COOTN PICKIN T'S MA Spills S101020777 South 201 YARMOUTH ROAD N/A 1/8-1/4 BARNSTABLE,MA ' 908 ft. Higher Site 4 of 4 in cluster I ' TC843894.1 s Page 40 ' Map ID MAP FINDINGS Direction Distance Distance(ft.) EDR ID Number ' Elevation Site Database(s) EPA ID Number COOTN PICKIN T'S (Continued) S101020777 ' MA Spills: Facility ID: 0000 Spill ID: S88-0206 Staff Lead: BOLSTER,H Date Entered: 05/31/1988 ' Last Entered: 05/31/1988 First Response: 03/01/1988 Spill Date: 03/01/0768 Report Date: 03/01/1988 Spill Time: Not reported Report Time: 10:50AM Case Closed: YES Mat Type: PETROLEUM ' Virgin Waste: VIRGIN Contam Soil: Not reported Env Impact: Not reported Other Impact: Not reported Material: MISCELLANEOUS OIL Other Material: Not reported ' CAS No: Not reported PCB Lev(ppm): Not reported Qty Reported: NONE Qty Actual: NONE Source: OTHER SOURCE > Other Source: UNKNOWN Incident: OTHER RELEASE> Other Incdnt: UNKNOWN ' Cleanup Type: Not reported Contractor: NOT USED Referral: NO LUST Elig: Not reported Notifier: Not reported Notif Tel: Not reported Notify Date: Not reported Report Prep: Not reported Category: Not reported Days/Close: 1 Capacity: Not reported Chemical: Not reported Quantity: Not reported ' J34 TEXACO SERV STATION MA Spills S101037633 SSE 140 IYANOUGH RD N/A ' 1/8-1/4 BARNSTABLE,MA 02630 940 ft. Higher Site 1 of 2 In cluster J MA Spills: ' Facility ID: 0000 Spill ID: S91-0199 Staff Lead: KEARNS,R Date Entered: 02/27/1992 Last Entered: 02/27/1992 First Response: 04/13/1991 Spill Date: 04/13/1991 Report Date: 04/13/1991 ' Spill Time: 02:OOAM Report Time: 02:19PM Case Closed: YES Mat Type: PETROLEUM Virgin Waste: VIRGIN Contam Soil: Not reported Env Impact: Not reported Other Impact: Not reported ' Material: GASOLINE Other Material: Not reported CAS No: Not reported PCB Lev(ppm): ------ Qty Reported: 51-100 GALLONS Qty Actual: -------- Source: PIPE/HOSE/LINE Other Source: Not reported Incident: SPILL Other Incdnt: Not reported Cleanup Type: SSC Contractor: NOT USED Referral: NO LUST Elig: NO ' Notifier: DISP NOLAN/FD Notif Tel: Not reported Notify Date: Not reported Report Prep: Not reported Category: Not reported Days/Close: 1 Capacity: Not reported Chemical: Not reported Quantity: Not reported I TC843894.1s Page 41 t Map ID MAP FINDINGS Direction Distance Distance(ft.) EDR ID Number ' Elevation Site Database(s) EPA ID Number J35 AIRPORT MOBIL SHWS S104942038 ' South 156 IYANOUGH RD Release N/A 1/8-1/4 BARNSTABLE,MA 02601 986 ft. Higher Site 2 of 2 in cluster J ' SHWS: Facility ID: 4-0015997 Site Status: Response Action Outcome Not Required ' Source Type: VEHICLE Release Town: HYANNIS Notification Date:01/23/2001 Category: TWO HR I ' Associated ID: 4-00013422 Status Date: 06/01/2001 Phase: Not reported MA RELEASE: Facility ID: 4-0015997 Facility Status: Response Action Outcome Not Required Status Date: 06/01/2001 Phase: Not reported Notification: 01/23/2001 Category: TWO HR Official City: BARNSTABLE Action: Date: 01/23/2001 Type: Release Status: REPORT Response Action Outcome: ' Activity Use Limitaion: LSP Number: Not reported Action: Date: 06/01/2001 ' Type: Immediate Response Status: Completion Statement Received Response Action Outcome: Activity Use Limitaion: ' LSP Number: 7710 Action: Date: 03/26/2001 Type: RNF ' Status: REPORT Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported Action: ' Date: 06/01/2001 Type: Response Action Outcome Not Required Status: Related to a Tier Classified Site Response Action Outcome: ' Activity Use Limitaion: LSP Number: 7710 Action: Date: 01/23/2001 ' Type: Release Status: REPORT Response Action Outcome: Activity Use Limitaion: ' LSP Number: Not reported ' TC843894.1s Page 42 f ' Map ID MAP FINDINGS Direction Distance Distance(ft.) EDR ID Number ' Elevation Site Database(s) EPA ID Number AIRPORT MOBIL (Continued) S104942038 ' Action: Date: 06/01/2001 Type: Immediate Response Status: Completion Statement Received Response Action Outcome: Activity Use Limitaion: LSP Number: 7710 ' Action: Date: 03/26/2001 Type: RNF Status: REPORT ' Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported Action: Date: 06/01/2001 Type: Response Action Outcome Not Required Status: Related to a Tier Classified Site Response Action Outcome: Activity Use Limitaion: ' LSP Number: 7710 Chemical Released: Chemical: GASOLINE Amount: 20,gallons ' Location Type: COMMERCIAL Source Type: VEHICLE ASC Release Tracking Number: 4-00013422 ' 36 NO LOCATION AID SHWS S103384109 South 381 CAMP ST Release N/A 1/8-1/4 BARNSTABLE,MA 02601 ' 1063 ft. Higher SHWS: ' Facility ID: 4-0014213 Site Status: Response Action Outcome Not Required Source Type: Not reported Release Town: HYANNIS Notification Date:09/25/1998 ' Category: 120 DY Associated ID: 4-00001179 Status Date: 10/01/1999 Phase: Not reported ' MA RELEASE: Facility ID: 4-0014213 Facility Status: Response Action Outcome Not Required ' Status Date: 10/01/1999 Phase: Not reported Notification: 09/25/1998 Category: 120 DY ' Official City: BARNSTABLE Action: Date: 09/25/1998 Type: RNF ' Status: REPORT Response Action Outcome: Activity Use Limitaion: ' TC843894.1 s Page 43 ' Map ID MAP FINDINGS Direction Distance Distance(ft.) EDR ID Number ' Elevation Site Database(s) EPA ID Number NO LOCATION AID (Continued) S103384109 ' LSP Number: Not reported Action: Date: 10/01/1999 ' Type: Response Action Outcome Not Required Status: Related to a Tier Classified Site Response Action Outcome: Activity Use Limitaion: LSP Number: 7212 Action: ' Date: 09/25/1998 Type: RNF ' Status: REPORT Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported Action: ' Date: 10/01/1999 Type: Response Action Outcome Not Required Status: Related to a Tier Classified Site Response Action Outcome: ' Activity Use Limitaion: LSP Number: 7212 Chemical Released: Chemical: BENZ[EJACEPHENANTHRYLENE ' Amount: 2.18,parts per million Location Type: Not reported Source Type: Not reported ASC Release Tracking Number: 4-00001179 ' 37 OFF RTE 28 SHWS S103546683 West 181 SPRING ST Release N/A ' 1/4-1/2 BARNSTABLE,MA 02601 1448 ft. Higher i ' SHWS: Facility ID: 4-0014306 Site Status: Response Action Outcome Source Type: Not reported ' Release Town: HYANNIS Notification Date:11/02/1998 Category: 120 DY Associated ID: - Status Date: 04/08/1999 Phase: Not reported MA RELEASE: Facility ID: 4-0014306 ' Facility Status: Response Action Outcome Status Date: 04/08/1999 Phase: Not reported Notification: 11/02/1998 ' Category: 120 DY Official City: BARNSTABLE Action: Date: 11/02/1998 ' Type: RNF Status: REPORT Response Action Outcome: I ' TC843894.1s Page 44 Map ID MAP FINDINGS Direction Distance Distance(ft.) EDR ID Number Elevation Site Database(s) EPA ID Number OFF RTE 28 (Continued) S103546683 Activity Use Limitaion: LSP Number: Not reported Action: Date: 04/08/1999 Type: Release Abatement Measure Status: Completion Statement Received Response Action Outcome: ' Activity Use Limitaion: LSP Number: 1127 Action: Date: 04/12/1999 Type: Response Action Outcome Status: Fee Received Response Action Outcome: A permanent solution has been achieved. Contamination has not been reduced to background. Activity Use Limitaion: NONE LSP Number: 1127 Action: Date: 11/02/1998 Type: RNF Status: REPORT Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported Action: Date: 04/08/1999 Type: Release Abatement Measure Status: Completion Statement Received Response Action Outcome: Activity Use Limitaion: LSP Number: 1127 Action: Date: 04/12/1999 Type: Response Action Outcome Status: Fee Received Response Action Outcome: A permanent solution has been achieved. Contamination has not been reduced to background. Activity Use Limitaion: NONE LSP Number: 1127 Chemical Released: ' Chemical: TOTAL PETROLEUM HYDROCARBONS(TPH) Amount: 17000,parts per million Location Type: Not reported Source Type: Not reported ' ASC Release Tracking Number: Not reported 38 CAPE DAIRY SHWS S102087752 ' ENE 44 BODICK RD Release N/A 1/4-1/2 BARNSTABLE,MA 02601 1469 ft. Higher ' TC843894.1 s Page 45 ' Map ID MAP-'FINDINGS- Direction Distance Distance(ft.) EDR ID Number ' Elevation Site Database(s) EPA ID Number CAPE DAIRY (Continued) S102087752 SHWS: Facility ID: 4-0010059 Site Status: Response Action Outcome Source Type: FUELTANK Release Town: HYANNIS Notification Date:10/28/1993 Category: TWO HR ' Associated ID: - Status Date: 01/31/1995 Phase: Not reported ' MA RELEASE: Facility ID: 4-0010059 Facility Status: Response Action Outcome Status Date: 01/31/1995 Phase: Not reported Notification: 10/28/1993 Category: TWO HR Official City: BARNSTABLE ' Action: Date: 02/07/1995 Type: Response Action Outcome Status: Fee Received Response Action Outcome: A permanent solution has been achieved. Contamination has not been reduced to ' background. Activity Use Limitaion: NONE LSP Number: 1127 Action: Date: 12/17/1993 Type: RNF Status: REPORT Response Action Outcome: ' Activity Use Limitaion: LSP Number: Not reported Action: Date: 10/28/1993 ' Type: Release Status: REPORT Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported Action: Date: 01/31/1995 Type: Immediate Response Status: Completion Statement Received Response Action Outcome: Activity Use Limitaion: LSP Number: 1127 ' Action: Date: 02/07/1995 Type: Response Action Outcome Status: Fee Received Response Action Outcome: A permanent solution has been achieved. Contamination has not been reduced to background. Activity Use Limitaion: NONE LSP Number: 1127 Action: ' TC843894.1s Page 46 ' Map ID MAP FINDINGS Direction Distance Distance(ft.) EDR ID Number ' Elevation Site Database(s) EPA ID Number CAPE DAIRY (Continued) S102087752 ' Date: 12/17/1993 Type: RNF Status: REPORT Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported Action: ' Date: 10/28/1993 Type: Release Status: REPORT Response Action Outcome: ' Activity Use Limitaion: LSP Number: Not reported Action: Date: 01/31/1995 ,.Type: Immediate Response Status: Completion Statement Received Response Action Outcome: Activity Use Limitaion: LSP Number: 1127 ' Chemical Released: Chemical: DIESEL FUEL Amount: 30,gallons Chemical Released: ' Chemical: DIESEL FUEL Amount: 30,gallons Location Type: COMMERCIAL Source Type: FUELTANK ASC Release Tracking Number: Not reported 39 WARDICK REALTY TRUST BDP SHWS S100828155 ' ENE 143 OLD YARMOUTH RD Release N/A 1/4-1/2 BARNSTABLE,MA 02601 1625 ft. Higher SHWS: Facility ID: 4-0000991 Site Status: DEPNDS ' Source Type: Not reported Release Town: HYANNIS Notification Date:01/15/1991 Category: NONE Associated ID: - ' Status Date: 07/23/1993 Phase: Not reported MA RELEASE: ' Facility ID: 4-0000991 Facility Status: DEPNDS Status Date: 07/23/1993 Phase: Not reported ' Notification: 01/15/1991 Category: NONE Official City: BARNSTABLE Action: Date: 01/15/1991 ' Type: Release Status: TCTRNS '` TC843894.1 s Page 47 Map ID MAP FINDINGS ' Direction Distance Distance(ft.) EDR ID Number tElevation Site Database(s) EPA ID Number WARDICK REALTY TRUST BDP (Continued) S100828155 ' Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported ' Action: Date: 01/15/1991 Type: Release Status: TCTRNS ' Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported Chemical Released: ' Chemical: UNKNOWN CHEMICAL OF UNKNOWN TYPE Amount: Not reported Location Type: Not reported Source Type: Not reported ASC Release Tracking Number: Not reported 40 PENTTIS AUTOMOTIVE SHWS S105125216 NE 143 OLD YARMOUTH RD Release N/A ' 1/4-1/2 BARNSTABLE,MA 02601 1821 ft. G-Iigher ' SHWS: Facility ID: 4-0016335 Site Status: DEFT1 B Source Type: DRUMS ' Release Town: HYANNIS Notification Date:05/21/2001 Category: TWO HR Associated ID: - ' Status Date: 05/28/2002 Phase: Not reported MA RELEASE: Facility ID: 4-0016335 ' Facility Status: DEFTIB Status Date: 05/28/2002 Phase: Not reported Notification: 05/21/2001 Category: TWO HR Official City: BARNSTABLE Action: Date: 05/21/2001 ' Type: Release Status: REPORT Response Action Outcome: Activity Use Limitaion: ' LSP Number: Not reported Action: Date: 05/21/2001 Type: Immediate Response ' Status: Oral Approval of Plan Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported Action: Date: 05/21/2001 Type: Release ' TC843894.1 s Page 48 I Map ID MAP FINDINGS -- -=--= Direction Distance Distance(ft.) EDR ID Number Elevation Site Database(s) EPA ID Number PENTTIS AUTOMOTIVE (Continued) S105125216 ' Status: REPORT Response Action Outcome: Activity Use Limitaion: ' LSP Number: Not reported Action: Date: 05/21/2001 Type: Immediate Response ' Status: Oral Approval of Plan Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported ' Chemical Released: Chemical: UNKNOWN CHEMICAL OF UNKNOWN TYPE Amount: 55,gallons Location Type: COMMERCIAL Source Type: DRUMS ASC Release Tracking Number: Not reported 41 GARAGE SHWS S103812560 SW 82 RIDGEWOOD AVE Release N/A 1/4-1/2 BARNSTABLE,MA 02630 2298 ft. ' Higher SHWS: Facility ID: 4-0014264 Site Status: DEFTIB Source Type: PIPE Release Town: BARNSTABLE Notification Date:10/19/1998 Category: RETRAC ' Associated ID: - Status Date: 10/26/1999 Phase: Not reported MA RELEASE: ' Facility ID: 4-0014264 Facility Status: DEFTIB Status Date: 10/26/1999 Phase: Not reported ' Notification: 10/19/1998 Category: RETRAC Official City: BARNSTABLE Action: ' Date: 10/19/1998 Type: Release Status: REPORT Response Action Outcome: ' Activity Use Limitaion: LSP Number: Not reported Action: Date: 10/20/1998 ' Type: Immediate Response Status: Oral Approval of Plan Response Action Outcome: Activity Use Limitaion: ' LSP Number: Not reported Action: Date: 10/12/1999 ' TC843894.1s Page 49 f i ' Map ID MAP FINDINGS Direction Distance Distance(ft.) EDR ID Number ' Elevation Site Database(s) EPA ID Number GARAGE. (Continued) S103812560 ' Type: Release Status: RETRAC Response Action Outcome: Activity Use Limitaion: ' LSP Number: Not reported Action: Date: 10/12/1999 ' Type: Release Status: REPORT Response Action Outcome: Activity Use Limitaion: ' LSP Number: Not reported Action: Date: 10/19/1998 Type: Release Status: REPORT Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported Action: II ' Date: 10/20/1998 Type: Immediate Response Status: Oral Approval of Plan ' Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported Action: Date: 10/12/1999 Type: Release Status: RETRAC Response Action Outcome: Activity Use Limitaion: ' LSP Number: Not reported Action: Date: 10/12/1999 Type: Release ' Status: REPORT Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported Chemical Released: Chemical: UNKNOWN CHEMICAL OF UNKNOWN TYPE Amount: 45,gallons Location Type: COMMERCIAL ' Source Type: PIPE ASC Release Tracking Number: Not reported ' 42 COLONIAL CANDLE SHWS 0002008037 South 232 MAIN ST Release N/A 1/2-1 BARNSTABLE,MA 02601 2646 ft. Lower I TC843894.1s Page 50 ' Map ID MAP FINDINGS Direction Distance Distance(ft.) EDR ID Number ' Elevation Site Database(s) EPA ID Number COLONIAL CANDLE (Continued) 0002008037 ' SHWS: Facility ID: 4-0015250 Site Status: Response Action Outcome ' Source Type: UNKNOWN Release Town: HYANNIS Notification Date:02/01/2000 Category: TWO HR ' Associated ID: - Status Date: 04/05/2000 Phase: Not reported MA RELEASE: ' Facility ID: 4-0015250 Facility Status: Response Action Outcome Status Date: 04/05/2000 Phase: Not reported Notification: 02/01/2000 Category: TWO HR Official City: BARNSTABLE Action: ' Date: 02/01/2000 Type: Release Status: REPORT ' Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported Action: Date: 02/29/2000 Type: RNF Status: REPORT Response Action Outcome: Activity Use Limitaion: ' LSP Number: Not reported Action: Date: 04/05/2000 Type: Response Action Outcome ' Status: RAO Statement Received Response Action Outcome: A permanent solution has been achieved.Contamination has been reduced to background or a threat of release has been eliminated. Activity Use Limitaion: NONE ' LSP Number: 8493 Action: Date: 02/01/2000 Type: Release ' Status: REPORT Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported ' Action: Date: 02/29/2000 Type: RNF Status: REPORT ' Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported Action: ' Date: 04/05/2000 I ' TC843894.1s Page 51 ' Map ID MAP FINDINGS Direction Distance Distance(ft.) EDR ID Number ' Elevation Site Database(s) EPA ID Number COLONIAL CANDLE (Continued) 0002008037 Type: Response Action Outcome Status: RAO Statement Received Response Action Outcome: A permanent solution has been achieved.Contamination has been reduced to ' background or a threat of release has been eliminated. Activity Use Limitaion: NONE LSP Number: 8493 Chemical Released: Chemical: DIESEL FUEL ' Amount: 40,gallons Location Type: COMMERCIAL Source Type: UNKNOWN ASC Release Tracking Number: Not reported I K43 GETTY STATION#30488 SHWS 0002008042 SW 112 BARNSTABLE RD UST N/A 1/2-1 HYANNIS,MA 02601 2796 ft. Higher Site 1 of 2 In cluster K i SHWS: Facility ID: 4-0014685 Site Status: Response Action Outcome Source Type: Not reported ' Release Town: HYANNIS Notification Date:04/22/1999 Category: 120 DY Associated ID: - ' Status Date: 07/09/1999 Phase: Not reported UST: Facility ID: 1105.0000 ' Tank ID: 1.00000 Tank Status: Removed Tank Useage: MV Capacity: 6000.0000 ' Owner: GETTY PETROLEUM MARKETING INC Owner Address: MASSASOIT AVE&DEXTER RD EAST PROVIDENCE,RI 02914 Serial Number: Not reported ' Aboveground: No Contents: Gasoline Tank Material: Steel Tank Contents: 1 Wall ' Tank Leak Detection:I Pipe Leak Detection:P ' TC843894.1s Page 52 ' Map ID MAP FINDINGS Direction Distance Distance(ft.) EDR ID Number ' Elevation Site Database(s) EPA ID Number GETTY STATION#30488 (Continued) 0002008042 ' Facility ID: 1105.0000 TanklD: 2.00000 ' Tank Status: Removed Tank Useage: MV Capacity: 5000.0000 Owner: GETTY PETROLEUM MARKETING INC Owner Address: MASSASOIT AVE&DEXTER RD t EAST PROVIDENCE,RI 02914 Serial Number: Not reported Aboveground: No ' Contents: Gasoline Tank Material: Steel Tank Contents: 1 Wall Tank Leak Detection:l Pipe Leak Detection:P ' Facility ID: 1105.0000 TanklD: 3.00000 Tank Status: Removed ' Tank Useage: MV Capacity: 5000.0000 Owner: GETTY PETROLEUM MARKETING INC Owner Address: MASSASOIT AVE&DEXTER RD EAST PROVIDENCE,RI 02914 Serial Number: Not reported Aboveground: No Contents: Gasoline Tank Material: Steel Tank Contents: 1 Wall Tank Leak Detection:I Pipe Leak Detection:P ' Facility ID: 1105.0000 TanklD: 4.00000 Tank Status: In Use Tank Useage: MV Capacity: 10000.000 Owner: GETTY PETROLEUM MARKETING INC Owner Address: MASSASOIT AVE&DEXTER RD ' EAST PROVIDENCE,RI 02914 Serial Number: Not reported Aboveground: No Contents: Gasoline ' Tank Material: Reinforced Tank Contents: 2 Walls Tank Leak Detection:I Pipe Leak Detection: I 1 t ' TC843894.1 s Page 53 Map ID MAP FINDINGS Direction Distance Distance(ft.) EDR ID Number Elevation Site Database(s) EPA ID Number GETTY STATION#30488 (Continued) 0002008042 Facility ID: 1105.0000 Tank ID: 5.00000 Tank Status: In Use Tank Useage: MV Capacity: 10000.000 Owner: GETTY PETROLEUM MARKETING INC Owner Address: MASSASOIT AVE&DEXTER RD EAST PROVIDENCE,RI 02914 Serial Number: Not reported Aboveground: No ' Contents: Gasoline Tank Material: Reinforced Tank Contents: 2 Walls Tank Leak Detection:I Pipe'teak Detection: I II' K44 GETTY SERVICE STATION SHWS S103384067 SW 112 BARNSTABLE RD Release N/A 1/2-1 BARNSTABLE,MA 02601 2796 ft. Higher Site 2 of 2 in cluster K ' SHWS: Facility ID: 4-0014059 Site Status: Response Action Outcome Source Type: Not reported Release Town: HYANNIS Notification Date:07/09/1998 I Category: 120 DY Associated ID: - Status Date: 07/09/1999 Phase: Not reported MA RELEASE: Facility ID: 4-0014059 Facility Status: Response Action Outcome Status Date: 07109/1999 Phase: Not reported Notification: 07/09/1998 Category: 120 DY Official City: BARNSTABLE Action: Date: 05/18/1999 Type: Release Abatement Measure Status: Completion Statement Received Response Action Outcome: Activity Use Limitaion: ' LSP Number: 6105 Action: Date: 07/09/1998 Type: RNF Status: REPORT Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported Action: Date: 07/13/1999 Type: Response Action Outcome TC843894.1s Page 54 �. 1 Map ID MAP FINDINGS Direction Distance Distance(ft.) EDR ID Number ' Elevation Site Database(s) EPA ID Number GETTY SERVICE STATION (Continued) S103384067 Status: Fee Received Response Action Outcome: A permanent solution has been achieved. Contamination has not been reduced to background. Activity Use Limitaion: NONE LSP Number: 6105 Action: Date: 05/18/1999 Type Release Abatement Measure Status: Completion Statement Received Response Action Outcome: Activity Use Limitaion: LSP Number: 6105 ' Action: Date: 07/09/1998 Type: RNF Status: REPORT ' Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported Action: ' Date: 07/13/1999 Type: Response Action Outcome Status: Fee Received Response Action Outcome: A permanent solution has been achieved. Contamination has not been reduced to background. Activity Use Limitaion: NONE LSP Number: 6105 Chemical Released: Chemical: TOTAL PETROLEUM HYDROCARBONS(TPH) Amount: 827,parts per million Location Type: Not reported Source Type: Not reported ' ASC Release Tracking Number: Not reported 45 SOUTH ST DOCK SHWS S102404073 ' South 21 SCHOOL ST Release N/A 1/2-1 BARNSTABLE,MA 02601 2797 ft. Lower SHWS: Facility ID: 4-0012393 Site Status: Response Action Outcome Source Type: SADDLETNK Release Town: HYANNIS Notification Date:07/31/1996 Category: TWO HR Associated ID: - Status Date: 11/29/1996 Phase: Not reported ' TC843894.1s Page 55 Map ID MAP'FINDINGS'- Direction Distance Distance(ft.) EDR ID Number Elevation Site Database(s) EPA ID Number SOUTH ST DOCK (Continued) S102404073 Facility ID: 4-0012393 Site Status: Response Action Outcome ' Source Type: VEHICLE Release Town: HYANNIS Notification Date:07/31/1996 Category: TWO HR ' Associated ID: - Status Date: 11/29/1996 Phase: Not reported MA RELEASE: Facility ID: 4-0012393 Facility Status: Response Action Outcome Status Date: 11/29/1996 Phase: Not reported Notification: 07/31/1996 ' Category: TWO HR Official City: BARNSTABLE Action: t Date: 11/29/1996 Type: RNF Status: REPORT Response Action Outcome: ' Activity Use Limitaion: LSP Number: Not reported Action: Date: 11/29/1996 ' Type: Immediate Response Status: Written Plan Received Response Action Outcome: Activity Use Limitaion: ' LSP Number: 6815 Action: Date: 11/29/1996 Type: Response Action Outcome ' Status: RAO Statement Received Response Action Outcome: A permanent solution has been achieved.Contamination has been reduced to background or a threat of release has been eliminated. Activity Use Limitaion: NONE ' LSP Number: 6815 Action: Date: 07/31/1996 Type: Release ' Status: REPORT Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported ' Action: Date: 11/29/1996 Type: RNF Status: REPORT Response Action Outcome: ' Activity Use Limitaion: LSP Number: Not reported Action: Date: 11/29/1996 Type: Immediate Response ' TC843894.1s Page 56 ' Map ID MAP FINDINGS. Direction Distance Distance(ft.) EDR ID Number Elevation Site Database(s) EPA ID Number SOUTH ST DOCK (Continued) S102404073 Status: Written Plan Received Response Action Outcome: Activity Use Limitaion: ' LSP Number: 6815 Action: Date: 11/29/1996 Type: Response Action Outcome ' Status: RAO Statement Received Response Action Outcome: A permanent solution has been achieved.Contamination has been reduced to background or a threat of release has been eliminated. Activity Use Limitaion: NONE ' LSP Number: 6815 Action: Date: 07/31/1996 Type: Release Status: REPORT ' Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported ' Chemical Released: Chemical: DIESEL FUEL Amount: 75,gallons Location Type: COMMERCIAL STATE Source Type: SADDLETNK ' VEHICLE ASC Release Tracking Number: Not reported ' 46 NO LOCATION AID SHWS S103043880 SSW 18 CENTER ST Release N/A 1/2-1 BARNSTABLE,MA 02601 3011 ft. Lower SHWS: ' Facility ID: 4-0010971 Site Status: Response Action Outcome Source Type: Not reported Release Town: HYANNIS Notification Date:11/09/1994 ' Category: 120 DY Associated ID Status Date: 10/17/2000 ' Phase: PHASE III MA RELEASE: Facility ID: 4-0010971 Facility Status: Response Action Outcome ' Status Date: 10/17/2000 Phase: PHASE III Notification: 11/09/1994 Category: 120 DY ' Official City: BARNSTABLE Action: Date: 12/01/1995 Type: Phase II ' Status: Completion Statement Received Response Action Outcome: Activity Use Limitaion: ' TC843894.1s Page 57 Map ID MAP FINDINGS ' Direction Distance Distance(ft.) EDR ID Number ' Elevation Site Database(s) EPA ID Number NO LOCATION AID (Continued) S103043880 LSP Number: Not reported Action: Date: 10/31/1995 ' Type: Tier Classification Status: Tier 2 Classification Response Action Outcome: Activity Use Limitaion: ' LSP Number: Not reported Action: Date: 11/09/1994 Type: RNF Status: REPORT Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported Action: Date: 10/19/2000 Type: Response Action Outcome Status: Fee Received Response Action Outcome: Remedial actions have not been conducted because a level of No Significant Risk i ' exists. Activity Use Limitaion: NONE LSP Number: 6846 Action: I, Date: 12/01/1995 Type: Phase II Status: Completion Statement Received Response Action Outcome: Activity Use Limitaion: LSP.Number: Not reported Action: Date: 10/31/1995 ' Type: Tier Classification Status: Tier 2 Classification Response Action Outcome: Activity Use Limitaion: ' LSP Number: Not reported Action: Date: 11/09/1994 Type: RNF t Status: REPORT Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported ' Action: Date: 10/19/2000 Type: Response Action Outcome Status: Fee Received ' Response Action Outcome: Remedial actions have not been conducted because a level of No Significant Risk exists. Activity Use Limitaion: NONE LSP Number: 6846 ' Chemical Released: Chemical: ETHENE,TETRACHLORO- Amount: 190,micrograms per liter Location Type: Not reported Source Type: Not reported ' TC843894.1s Page 58 Map ID MAP FINDINGS - Direction Distance Distance(ft.) EDR ID Number ' Elevation Site Database(s) EPA ID Number NO LOCATION AID (Continued) S103043880 ' ASC Release Tracking Number: Not reported 47 MARSTON MILLS SHWS S102088347 ' NE 106 ROSA LN Release N/A 1/2-1 BARNSTABLE,MA 02630 3196 ft. ' Higher SHWS: Facility ID: 4-0011220 Site Status: Response Action Outcome ' Source Type: AST Release Town: BARNSTABLE Notification Date:03/23/1995 Category: TWO HR ' Associated ID Status Date: 10/16/1996 Phase: Not reported MA RELEASE: Facility ID: 4-0011220 Facility Status: Response Action Outcome Status Date: 10/16/1996 Phase: Not reported Notification: 03/23/1995 Category: TWO HR Official City: BARNSTABLE Action: ' Date: 10/16/1996 Type: Response Action Outcome Status: RAO Statement Received Response Action Outcome: A permanent solution has been achieved. Contamination has not been reduced to background. Activity Use Limitaion: NONE LSP Number: 9546 Action: ' Date: 02/23/1996 Type: RNF Status: REPORT Response Action Outcome: I ' Activity Use Limitaion: LSP Number: Not reported Action: Date: 03/23/1995 ' Type: Release Status: REPORT Response Action Outcome: Activity Use Limitaion: ' LSP Number: Not reported Action: Date: 10/16/1996 Type: Immediate Response ' Status: Completion Statement Received Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported Action: Date: 10/16/1996 Type: Response Action Outcome ' TC843894.1s Page 59 Map ID MAP FINDINGS Direction Distance iDistance(ft.) EDR ID Number ' Elevation Site Database(s) EPA ID Number MARSTON MILLS (Continued) S102088347 ' Status: RAO Statement Received Response Action Outcome: A permanent solution has been achieved. Contamination has not been reduced to background. Activity Use Limitaion: NONE ' LSP Number: 9546 Action: Date: 02/23/1996 Type: RNF Status: REPORT Response Action Outcome: Activity Use Limitaion: ' LSP Number: Not reported Action: Date: 03/23/1995 Type: Release Status: REPORT ' Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported Action: Date: 10/16/1996 Type: Immediate Response Status: Completion Statement Received Response Action Outcome: ' Activity Use Limitaion: LSP Number: Not reported Chemical Released: Chemical: PETROLEUM BASED OIL Amount: Not reported Location Type: RESIDNTIAL Source Type: AST ASC Release Tracking Number: Not reported ' L48 BARNSTABLE AIRPORT SHWS S100828135 NW BOARDMAN-POLANDO FIELD Release N/A ' 1/2-1 BARNSTABLE,MA 02601 3352 ft. Higher Site 1 of 2 in cluster L SHWS: ' Facility ID: 4-0000823 Site Status: TIER16 Source Type: UNKNOWN Release Town: HYANNIS ' Notification Date:11/10/1989 Category: NONE Associated ID: - Status Date: 10/11/1994 ' Phase: PHASE V MA RELEASE: Facility ID: 4-0000823 t Facility Status: TIER16 Status Date: 10/11/1994 Phase: PHASE V Notification: 11/10/1989 Category: NONE Official City: BARNSTABLE Action: TC843894.1s Page 60 ' Map ID MAP FINDINGS Direction Distance Distance(ft.) EDR ID Number Elevation Site Database(s) EPA ID Number BARNSTABLE AIRPORT (Continued) S100828135 ' Date: 11/10/1989 Type: Release Status: TCTRNS Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported Action: ' Date: 10/11/1994 Type: Tier Classification Status: PEREFF Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported Action: Date: 06/23/1997 Type: Phase II Status: Completion Statement Received Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported Action: Date: 10/31/2000 Type: PhaselV Status: Completion Statement Received ' Response Action Outcome: Activity Use Limitaion: LSP Number: 2061 Action: Date: 03/23/1999 Type: Phase III Status: Completion Statement Received Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported Action: Date: 12/21/1998 1 Type: Immediate Response Status: Written Plan Received Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported ' Action: Date: 02/11/2002 Type: Phase V ' Status: Inspection and Monitoring Report Received Response Action Outcome: Activity Use Limitaion: LSP Number: 2061 Action: Date: 11/10/1989 Type: Release Status: TCTRNS Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported Action: ' Date: 10/11/1994 TC843894.1s Page 61 Map ID MAP FINDINGS II ' Direction Distance Distance(ft.) EDR ID Number ' Elevation Site Database(s) EPA ID Number BARNSTABLE AIRPORT (Continued) S100828135 ' Type: Tier Classification Status: PEREFF Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported Action: Date: 06/23/1997 Type: Phase II Status: Completion Statement Received Response Action Outcome: Activity Use Limitaion: ' LSP Number: Not reported Action: Date: 10/31/2000 Type: PhaselV Status: Completion Statement Received ' Response Action Outcome: Activity Use Limitaion: LSP Number: 2061 Action: Date: 03/23/1999 Type: Phase III Status: Completion Statement Received Response Action Outcome: t Activity Use Limitaion: LSP Number: Not reported Action: Date: 12/21/1998 Type: Immediate Response Status: Written Plan Received Response Action Outcome: Activity Use Limitaion: ' LSP Number: Not reported Action: Date: 02/11/2002 Type: Phase V Status: Inspection and Monitoring Report Received Response Action Outcome: Activity Use Limitaion: LSP Number: 2061 ' Chemical Released: Chemical: UNKNOWN CHEMICAL OF TYPE-OIL Amount: Not reported Chemical Released: ' Chemical: UNKNOWN CHEMICAL OF TYPE-HAZARDOUS MATERIAL Amount: Not reported Location Type: COMMERCIAL Source Type: UNKNOWN ' ASC Release Tracking'Number. Not reported L49 GRIFFIN AVIONICS SHWS S102618666 NW BARNSTABLE AIRPORT Release N/A 1/2-1 BARNSTABLE,MA 02630 3375 ft. Higher Site 2 of 2 in cluster L. ' TC843894.1s Page 62 ' Map ID MAP FINDINGS Direction Distance Distance(ft.) EDR ID Number Elevation Site Database(s) EPA ID Number GRIFFIN AVIONICS (Continued) S102618666 ' SHWS: Facility ID: 4-0012911 Site Status: TIERIC Source Type: Not reported Release Town: BARNSTABLE Notification Date:03/20/1997 Category: 120 DY Associated ID: - Status Date: 03/24/1998 Phase: PHASE III ' MA RELEASE: Facility ID: 4-0012911 Facility Status: TIERIC Status Date: 03/24/1998 Phase: PHASE III ' Notification: 03/20/1997 Category: 120 DY Official City: BARNSTABLE Action: ' Date: 09/04/1998 Type: Phase II Status: Scope of Work Received Response Action Outcome: ' Activity Use Limitaion: LSP Number: 6846 Action: Date: 03/24/1998 ' Type: Tier Classification Status: Tier 1C Classification Response Action Outcome: Activity Use Limitaion: ' LSP Number: 6846 Action: Date: 03/24/1998 Type: Phase I ' Status: Completion Statement Received Response Action Outcome: Activity Use Limitaion: LSP Number: 6846 ' Action: Date: 12/10/1996 Type: Release Status: REPORT ' Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported Action: Date: 09/04/1998 Type: Phase II Status: Scope of Work Received Response Action Outcome: ' Activity Use Limitaion: LSP Number: 6846 Action: Date: 03/24/1998 Type: Tier Classification '` TC843894.1 s Page 63 ' Map ID MAP FINDINGS Direction Distance Distance(ft.) EDR ID Number ' Elevation Site Database(s) EPA ID Number GRIFFIN AVIONICS (Continued) S102618666 ' Status: Tier 1 C Classification Response Action Outcome: Activity Use Limitaion: LSP Number: 6846 ! ' Action: Date: 03/24/1998 Type: Phase I Status: Completion Statement Received I ' Response Action Outcome: Activity Use Limitaion: LSP Number: 6846 Action: ' Date: 12/10/1996 Type: Release Status: REPORT Response Action Outcome: ' Activity Use Limitaion: LSP Number: Not reported Chemical Released: Chemical: CADMIUM ' Amount: Not reported Chemical Released: Chemical: TOTAL PETROLEUM HYDROCARBONS(TPH) Amount:. Not reported Location Type: MUNICIPAL Source Type: Not reported ASC Release Tracking Number: Not reported M50 LEWIS BAY MOTEL SHWS S100828145 South 53 SOUTH ST Release N/A 1/2-1 BARNSTABLE,MA 02630 ' 3610 ft. Lower Site 1 of 2 in cluster M SHWS: Facility ID: 4-0000624 Site Status: DEPNFA Source Type: UNCONTAIN Release Town: BARNSTABLE Notification Date:01/15/1989 Category: NONE Associated ID Status Date: 07/23/1993 Phase: Not reported ' MA RELEASE: Facility ID: 4-0000624 Facility Status: DEPNFA Status Date: 07/&1993 Phase: Not reported Notification: 01/15/1989 Category: NONE ' Official City: BARNSTABLE Action: Date: 01/15/1989 Type: Release Status: TCTRNS Response Action Outcome: Activity Use Limitaion: ` TC843894.1s Page 64 Map ID _ _ MAP FINDINGS Direction Distance Distance(ft.) EDR ID Number Elevation Site Database(s) EPA ID Number LEWIS BAY MOTEL (Continued) S100828145 ' LSP Number: Not reported Action: Date: 01/15/1989 ' Type: Release Status: TCTRNS Response Action Outcome: Activity Use Limitaion: ' LSP Number: Not reported Chemical Released: Chemical: UNKNOWN CHEMICAL OF TYPE-OIL Amount: Not reported ' Location Type: COMMERCIAL Source Type: UNCONTAIN ASC Release Tracking Number: Not reported ' M51 STEAMSHIP AUTHORITY SHWS S104000726 South 141 SCHOOL ST Release N/A 1/2-1 BARNSTABLE,MA 02601 3645 ft. ' Lower Site 2 of 2 in cluster M SHWS: Facility ID: 4-0014802 ' Site Status: Response Action Outcome Source Type: DRUMS Release Town: HYANNIS Notification Date:06/22/1999 ' Category: TWO HR Associated ID Status Date: 08/30/1999 Phase: Not reported MA RELEASE: Facility ID: 4-0014802 Facility Status: Response Action Outcome Status Date: 08/30/1999 ' Phase: Not reported Notification: 06/22/1999 Category: TWO HR Official City: BARNSTABLE ' Action: Date: 06/22/1999 Type: Release Status: REPORT Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported Action: Date: 06/22/1999 Type: Release Status: REPORT Response Action Outcome: ' Activity Use Limitaion: LSP Number: 8959 Action: Date: 06/22/1999 ' Type: Immediate Response Status: Oral Approval of Plan Response Action Outcome: TC843894.1s Page 65 ' Map ID MAP FINDINGS', _ Direction Distance Distance(ft.) EDR ID Number II ' Elevation Site Database(s) EPA ID Number STEAMSHIP AUTHORITY (Continued) S104000726 ' Activity Use Limitaion: LSP Number: Not reported Action: Date: 08/19/1999 ' Type: RNF Status: REPORT Response Action Outcome: Activity Use Limitaion: ' LSP Number: Not reported Action: Date: 08/30/1999 Type: Response Action Outcome I' Status: RAO Statement Received Response Action Outcome: A permanent solution has been achieved.Contamination has been reduced to background or a threat of release has been eliminated. Activity Use Limitaion: NONE ' 'LSP Number: 8959 Acton: Date: 06/22/1999 Type: Release Status: REPORT Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported I ' Action: Date: 06/22/1999 Type: Release Status: REPORT Response Action Outcome: Activity Use Limitaion: LSP Number: 8959 Action: ' Date: 06/22/1999 Type: Immediate Response Status: Oral Approval of Plan Response Action Outcome: ' Activity Use Limitaion: LSP Number: Not reported Action: Date: 08/19/1999 ' Type: RNF Status: REPORT Response Action Outcome: Activity Use Limitaion: LSP Number: Not reported Action: Date: 08/30/1999 Type: Response Action Outcome ' Status: RAO Statement Received Response Action Outcome: A permanent solution has been achieved.Contamination has been reduced to background or a threat of release has been eliminated. Activity Use Limitaion: NONE LSP Number: 8959 Chemical Released: Chemical: UNKNOWN CHEMICAL OF TYPE-OIL Amount: 40,gallons Location Type: COMMERCIAL TC843894.1 s Page 66 MA DEP Southeast Regional Office 1 File Review Request Form (Mail or FAX) T0: Department of Environmental Protection I� Southeast ReQlonal Office 20 Riverside Drive Lakeville, MA 02347 ' Attention: Rob Roy, Service Center FAX Number- 508-946-2835 Phone Number: 508-946-2713 ' Please refer to File Review Procedure. PLEASE WRITE LEGIBLY IN ORDER FOR YOUR REQUEST TO BE HONORED [To7daDateAl2 I� Your Company Name: g� Requested Date: q llgl�z Telephone: (,IT Time: A.Vt. —P.M. Contact Person: ) �Z I a j ' Town File Address File Name File Numb7512 2 _ 1 U , z 2. 2 ' - 1321� 4. �- 3�Z 5. c` i s 4 ro- 2 6 4 ' U, 8. Mr. Roy Will Contact You To Confirm Your Appointment [SERO Home] (Submit File Review Retest On-Line] [File Re`iew Procedures] [Contact: ServiceService.Centergstate.ma.usl � APPENDIX C 1 1 1 1 1 1 1 1 1 1 � 1 1 1 ' Massachusetts Department of Environmental Protection BWSC-109 Bureau of Waste Site Cleanup Release Tracking Number 824 TIER I MINOR PERMIT MODIFICATION TRANSMITTAL ❑4 - FORM Pursuant to 310 CMR 40.0725 (Subpart G) Permit 31003452 ' Number Minor Permit Modification Requests are not subject to permit processing requirements under 310 CMR 40.0720-40.0724 or 310 CMR 4.00 A. DISPOSAL SITE LOCATION: ' Site Name: Hiihharci Oi 1 (•n Tnr- Street: V1 and 51 Rrnnka Rnad Location Aid: Man "128, pc1G_126 and 129 City/Town: Hyanni c ZIPCode: 09.601 -0000 Related Release Tracking Numbers That This Minor Permit Modification Request Addresses: 4-1 5-1 7 n B. THIS FORM IS BEING USED TO: (check all appropriate categories below) Submit an Alternative or Corrected Minor Permit Modification Request(also must check use(s)below)Date of Prior Submittal: ❑ Modify a Permittee Name,Address or Contact Person(complete Sections A,B,C,I,J,K and L). ' Change a Primary Representative(complete Sections A,B,D,I,J,K and L). ® Change an LSP-of-Record(complete Sections A,B,E,J,K and L). Correct Typographical Errors(complete Sections A,B,F,I,J,K and L). ' ❑ Correct Omissions(complete Sections A,B,G,I,J,K and Q. Submit Other Minor Permit Modifications,including linking an additional Release Tracking Number(s)to a Permit ' (complete Sections A,B,H,I,J,K and Q. C. MODIFICATION TO PERMITTEE NAME,ADDRESS OR CONTACT PERSON: (complete.entire section) Permittee Organization: Permittee Contact: Title: Street: ' City/Town: State: ZIP Code: Telephone: Ext.: FAX:(optional) For disposal sites with more than one Permittee,each Permittee making a modification ' to name,address or contact person must separately submit any proposed changes. D. CHANGE IN PRIMARY REPRESENTATIVE: (complete entire section) A Primary Representative is required only for Sites having more than one Permittee. Check here if the Primary Representative is also a Permittee. Primary Representative Name: Title: ' Primary Representative Organization: Street: City/Town: State: ZIP Code: Telephone: Ext.: FAX:(optional) Certification of Primary Representative: I attest under the pains and penalties of perjury that I am fully authorized to act on behalf of all permittees holding this Tier I Permit for the purposes stated in 310 CMR 40.0703(7)(a): to receive oral and written correspondence from DEP with respect to the application; to receive oral and written correspondence from DEP with respect to performance of response actions upon issuance of a Tier I permit;and ' to receive any statement of fee required by 310 CMR 4.03(3)upon issuance of a Tier I permit. I understand that any material received by the Primary Representative from DEP shall be deemed received by the Permittee(s),and I am aware ` that there are significant penalties,including,but not limited to,possible fines and imprisonment,for willfully submitting false,inaccurate or ' incomplete information. Signature: Date: The person signing this certification MUST be the Primary Representative named above. Revised 3/30/95 Do Not Alter This Form Page 1 of 4 ' Massachusetts Department of Environmental Protection BWSC-109 Bureau of Waste Site Cleanup Release Tracking Number a - 824 TIER I MINOR PERMIT MODIFICATION TRANSMITTAL. FORM Pursuant to 310 CMR 40.0725(Subpart G) Permit 31003452 Number II ' E. CHANGE IN LSP-OF-RECORD: (the new LSP-of-Record must sign and stamp this sect** 0 LSP Name: David C'_ APr n t LSP#: 4101 Stamp: DAVID T'd! Telephone: - - Ext.: CNN. ETT fA FAX:.(optional) - �, No-A r Signature: S/7 Date: G �' F. CORRECTION OF TYPOGRAPHICAL ERRORS: (describe typographical errors below) 1 I i ' G. CORRECTION OF OMISSIONS: Describe any omissions to be corrected by this Minor Permit Modification request. These omissions must not affect the nature or complexity of the permitted response action. Provide relevant information,including copies of applicable documentation. I H. OTHER MINOR PERMIT MODIFICATIONS: ' Name,address and contact person for a new Owner who is NOT a Permittee: Name of Organization: Name of Contact: Title: Street: ' Cityrrown: State: ZIP Code: Telephone: Ext.: FAX:(optional) Name,address and contact person for a new Operator who is NOT a Permittee: Name of Organization: ' Name of Contact: Title: Street: City/Towr: State: ZIP Code: ' Telephone: Ext.: FAX:(optional) SECTION H IS CONTINUED ON THE NEXT PAGE. Revised 3/30/95 Do Not Alter This Form Page 2 of 4 ' Massachusetts Department of Environmental Protection BWSC-10 Release Tracking Numbee r Bureau of Waste Site Cleanup ❑4 - 824 ' TIER I MINOR PERMIT MODIFICATION TRANSMITTAL FORM Pursuant to 310 CMR 40.0725(Subpart G) Permit 31003452 Number ' H. OTHER MINOR PERMIT MODIFICATIONS: (continued) Check here if linking an additional Release Tracking Number(s)to a Tier I Permit,where there has been NO change in conditions that requires the filing of a Major Permit Modification application(BWSC 10). List Release Tracking Number(s)below. ' Describe any other Minor Permit Modifications proposed. Provide relevant information,including copies of applicable documentation. tI. LSP OPINION: An LSP Opinion Is required only if this submittal is materially inconsistent with,or would otherwise serve to compromise tor diminish the content or meaning of,an LSP Opinion previously submitted to DEP. I attest under the pains and penalties of perjury that I have personally examined and am familiar with this transmittal form,including any and all documents accompanying this submittal. In my professional opinion and judgment based upon application of(i)the standard of care in 309 CMR II ' 4.02(1).(ii)the applicable provisions of 309 CMR 4.02(2)and(3),and(iii)the provisions of 309 CMR 4.03(5),to the best of my knowledge,information and belief,this submittal has been developed in accordance with the applicable provisions of M.G.L.c.21 E and 310 CMR 40.0000. 1 am aware that significant penalties may result,including,but not limited to,possible fines and imprisonment,if I submit information which I know to be false,inaccurate or materially incomplete. Check here if the Response Action(s)on which this opinion is based,if any,are(were)subject to any order(s),permit(s)and/or approval(s) issued by DEP or EPA. If the box is checked,you MUST attach a statement identifying the applicable provisions thereof. LSP Name: LSP#: Stamp: Telephone: Ext.: ' FAX:(optional) Signature: ' Date: J. PERMITTEE SUBMITTING MINOR PERMIT MODIFICATION REQUEST: Name of Organization: Fiuhharrl Oil ro Tnr NameofContact: F.vPLm Read Title: General Manager Street: P n Box 1 0 City/Town: T-Tya nn i s State: MA ZIP Code: 09,G n 1 -n n n n ' Telephone: 8 n 0-9.7 8-7101 Ext.: FAX:(optional) 10 8-7 7 8-94 0 3 K. RELATIONSHIP TO SITE OF PERMITTEE SUBMITTING MINOR PERMIT MODIFICATION REQUEST: (check one) ® RP or PRP Specify: O owner ® Operator O Generator O Transporter Other RP or PRP: ' Fiduciary,Secured Lender or Municipality with Exempt Status(as defined by M.G.L.c.21 E,s.2) ' Agency or Public Utility on a Right of Way(as defined by M.G.L.c.21 E,s.5(j)) Any Other Person Submitting Minor Permit Modification Request Specify Relationship: Revised 3/30/95 Do Not Alter This Form Page 3 of 4 ' Massachusetts Department of Environmental Protection BWSC-109 Bureau of Waste Site Cleanup Release Tracking Number ❑4 - 824 ' TIER I MINOR PERMIT MODIFICATION TRANSMITTAL Permit FORM Pursuant to 310 CMR 40.0725(Subpart G) Number F31003452 ' IF THIS MINOR PERMIT MODIFICATION AFFECTS A MULTI-PARTY PERMIT,ALL PERMITTEES MUST SIGN THE CERTIFICATION SHOWN IN SECTION L. ADDITIONAL PERMITTEES MAY MAKE A COPY OF THIS PAGE, SIGN THE CERTIFICATION AND PROVIDE A MAILING ADDRESS IN THE SPACES PROVIDED IN SECTION L. L. CERTIFICATION OF PERMITTEE SUBMITTING MINOR PERMIT MODIFICATION: 1, RvP 1)m Read attest under the pains and penalties of perjury(i)that I have personally examined and am familiar with the information contained in this submittal,including any and all documents accompanying this transmittal form,(ii)that,based on my inquiry of those individuals immediately responsible for obtaining the information,the material information contained in this submittal is,to the best of my knowledge and belief,true,accurate and complete,and(iii)that I am fully authorized to make this attestation on behalf of the entity legally responsible for this submittal. I/the person or entity on whose behalf this submittal is made am/is aware that there are significant penalties,including,but not limited to, possible fines and imprisonment,for willfullysubmittinq false,inaccurate,or incomplete information. ' By: �J '16) -aCL/ Title: General Manager (signature) 01 p For:Huhhard nil n , Trn_ Date: 7—.20 —d Z (print name of person or entity recorded in Section J) Enter address of the person providing certification,if different from address recorded in Section J: ' Street: City/Town: State: ZIP Code: Telephone: Ext.: FAX:(optional) YOU MUST COMPLETE ALL RELEVANT SECTIONS OF THIS FORM OR DEP MAY RETURN THE DOCUMENT AS INCOMPLETE. UNLESS YOU ARE CONTACTED BY DEP,THIS MINOR PERMIT MODIFICATION REQUEST ' IS PRESUMPTIVELY APPROVED 60 DAYS AFTER RECEIPT BY DEP, PURSUANT TO 310 CMR 40.0724(4). 1 1 Revised 3/30195 Do Not Alter This Form Page 4 of 4 t Massachusetts Department of Environmental Protection BWSC-108 Bureau of Waste Site Cleanup ' COMPREHENSIVE RESPONSE ACTION TRANSMITTAL Release Tracking Number FORM & PHASE I COMPLETION STATEMENT ❑4 - 824 Pursuant to 310 CMR 40.0484(Subpart D)and 40.0800 (Subpart H) A. SITE LOCATION: Site Name:(optional) Tiuhhard Qi 1 Cn Tnc_ Street: 31 and 51 Rrnnks Rnaci Location Aid: Mar "12!3 Parcels 195 and 126 ' City/Town: Rarnstahle (Hyannis) ZIP Code: n2601 -noon Related Release Tracking Numbers that this Form Addresses: 4-1 53 7 n ' Tier Classification: (check one of the following) Tier IA Tier IB ® Tier IC Tier II Not Tier Classified If a Tier I Permit has been issued,state the Permit Number: ' B. THIS FORM IS BEING USED TO: (check all that apply) Submit a Phase I Completion Statement,pursuant to 310 CMR 40.0484(complete Sections A, B,C,G,H, I and J). Submit a Phase II Scope of Work,pursuant to 310 CMR 40.0834(complete Sections A,B,C,G,H,I and J). Submit a final Phase II Comprehensive Site Report and Completion Statement,pursuant to 310 CMR 40.0836 (complete Sections A,B,C,D,G.H,I and J). Submit a Phase III Remedial Action Plan and Completion Statement,pursuant to 310 CMR 40.0862(complete Sections A,B,C,G.H,I and J). Submit a Phase IV Remedy Implementation Plan,pursuant to 310 CMR 40.0874(complete Sections A,B,C,G.H,1 and J). Submit an As-Built Construction Report,pursuant to 310 CMR 40.0875(complete Sections A,B,C.G,H, I and J). Submit a Phase IV Final Inspection Report and Completion Statement,pursuant to 310 CMR 40.0878 and 40.0879 (complete Sections A,B,C,E,G,H,I and J). ' Submit a periodic Phase V Inspection&Monitoring Report,pursuant to 310 CMR 40.0892(complete Sections A,B,C,G,H,I and J). Submit a final Phase V Inspection&Monitoring Report and Completion Statement,pursuant to 310 CMR 40.0893 (complete Sections A,B.C,F.G,H,I and J). You must attach all supporting documentation required for each use of form Indicated,including copies of any Legal Notices and Notices to Public Officials required by 310 CMR 40.1400. C. RESPONSE ACTIONS: ' Check here if any response action(s)that serves as the basis for the Phase submittal(s)involves the use of Innovative Technologies. (DEP is interested in using this information to create an Innovative Technologies Clearinghouse.) Describe Technologies. ' D. PHASE II COMPLETION STATEMENT: Specify the outcome of the Phase 11 Comprehensive Site Assessment: ❑ Additional Comprehensive Response Actions are necessary at this Site,based on the results of the Phase II Comprehensive Site Assessment. ' The requirements of a Class A Response Action Outcome have been met and a completed Response Action Outcome Statement(BWSC-104) will be submitted to DEP. The requirements of a Class B Response Action Outcome have been met and a completed Response Action Outcome Statement(BWSC-104) ' will be submitted to DEP. Rescoring of this Site using the Numerical Ranking System is necessary,based on the results of the final Phase II Report. ' E. PHASE IV COMPLETION STATEMENT: Specify the outcome of Phase IV activities: Phase V operation,maintenance or monitoring of the Comprehensive Response Action is necessary to achieve a Response Action Outcome. (This site will be subject to a Phase V Operation,Maintenance and Monitoring Annual Compliance Fee.) The requirements of a Class A Response Action Outcome have been met. No additional operation,maintenance or monitoring is necessary to ensure the integrity of the Response Action Outcome. A completed Response Action Outcome Statement(BWSC-104)will be submitted to DEP. The requirements of a Class C Response Action Outcome have been met. No additional operation,maintenance or monitoring is necessary to ensure the integrity of the Response Action Outcome. A completed Response Action Outcome Statement(BWSC-104)will be submitted to DEP. SECTION E IS CONTINUED ON THE NEXT PAGE Revised 3/30/95 Supersedes Forms BWSC-010(in part)and 013 Page 1 of 3 ., Do Not Alter This Form Massachusetts Department of Environmental Protection BWSC-108 Bureau of Waste Site Cleanup ' COMPREHENSIVE RESPONSE ACTION TRANSMITTAL Release Tracking Number FORM & PHASE I COMPLETION STATEMENT 0 _ 824 Pursuant to 310 CMR 40.0484 (Subpart D)and 40.0800 (Subpart H) E. PHASE IV COMPLETION STATEMENT: (continued) The requirements of a Class C Response Action Outcome have been met. Further operation,maintenance or monitoring of the remedial action is necessary to ensure that conditions are maintained and that further progress is made toward a Permanent Solution. A completed Response ' Action Outcome Statement(BWSC-104)will be submitted to DEP. Indicate whether the operation and maintenance will be Active or Passive. (Active Operation and Maintenance is defined at 310 CMR 40.0006.): O Active Operation and Maintenance O Passive Operation and Maintenance ' (Active Operation and Maintenance makes the Site subject to a Post-RAO Class C Active Operation and Maintenance Annual Compliance Fee.) F. PHASE V COMPLETION STATEMENT: Specify the outcome of Phase V activities: The requirements of a Class A Response Action Outcome have been met and a completed Response Action Outcome Statement(BWSC-104) will be submitted to DEP. ' The requirements of a Class C Response Action Outcome have been met. No additional operation,maintenance or monitoring is necessary to ensure the integrity of the Response Action Outcome. A completed Response Action Outcome Statement(BWSC-104)will be submitted to DEP. The requirements of a Class'C Response Action Outcome have been met. Further operation,maintenance.or monitoring of the remedial action ' is necessary to ensure ttrat conditions are maintained and that further progress is made toward a Permanent Solution. A completed Response Action Outcome Statement(BWSC-104)will be submitted to DEP. Indicate whether the operation and maintenance will be Active or Passive. (Active Operation and Maintenance is defined at 310 CMR 40.0006.): ' O Active Operation and Maintenance O Passive Operation and Maintenance (Active Operation and Maintenance makes the Site subject to a Post-RAO Class C Active Operation and Maintenance Annual Compliance Fee.) G. LSP OPINION: ' I attest under the pains and penalties of perjury that I have personally examined and am familiar with the information contained in this transmittal form, including any and all documents;accompanying this submittal. In my professional opinion and judgment based upon application of(i)the standard of care in 309 CMR 4.02(1),(ii)the applicable provisions of 309 CMR 4.02(2)and(3),and(iii)the provisions of 309 CMR 4.03(5),to the best of my knowledge,information and belief, ' > if Section B indicates that a Phase 1,Phase Il,Phase III,Phase/V or Phase V Completion Statement is being submitted,the response action(s) that is(are)the subject of this submittal(i)has(have)been developed and implemented in accordance with the applicable provisions of M.G.L.c.21 E and 310 CMR 40.0000,(ii)is(are)appropriate and reasonable to accomplish the purposes of such response action(s)as set forth in the applicable ' provisions of M.G.L.c.21 E and 310 CMR 40.0000,and(iii)complies(y)with the identified provisions of all orders,permits,and approvals identified in this submittal; > if Section B indicates that a Phase 11 Scope of Work or a Phase IV Remedy Implementation Plan is being submitted,the response action(s)that ' (are)the subject of this submittal(i)has(have)been developed in accordance with the applicable provisions of M.G.L.c.21 E and 310 CMR 0.0000,(ii)is(are)appropriate and reasonable to accomplish the purposes of such response action(s)as set forth in the applicable provisions of M.G.L.c.21 E and 310 CMR 40.0000,and(iii)complies(y)with the identified provisions of all orders,permits,and approvals identified in this submittal; > if Section B indicates that an As-Built Construction Report or a Phase V Inspection and Monitoring Report is being submitted,the response ' action(s)that is(are)the subject of this submittal(i)is.(are)being implemented in accordance with the applicable provisions of M.G.L.c.21 E and 310 CMR 40.0000,(ii)is(are)appropriate and reasonable to accomplish the purposes of such response action(s)as set forth in the applicable provisions of M.G.L.c.21 E and 310 CMR 40.0000,and(iii)complies(y)with the identified provisions of all orders,permits,and approvals identified in this submittal. ' I am aware that significant penalties may result,including,but not limited to,possible fines and imprisonment,if I submit information which I know to be false,inaccurate or materially incomplete. Check here if the Response Action(s)on which this opinion is based,if any,are(were)subject to any order(s),permit(s)and/or approval(s) ' issued by DEP or EPA. If the box is checked,you MUST attach a statement identifyin provisions thereof. b SN �4 LSP Name: na cf v; C_ RP P nnrt- LSP#: 43 n� Stamp: CF DAVID Telephone: - Ext.: C.SENNETT n11'v aan. FAX:(optional) - l No.4303 � e�r��t Signature: 0 FQlBTE4�81r Date: Revised 3/30/95 Supersedes Forms BWSC-010'(in part)and 013 Page 2 of 3 Do Not Alter This Form li ' Massachusetts Department of Environmental Protection BWSC-108 Bureau of Waste Site Cleanup COMPREHENSIVE RESPONSE ACTION TRANSMITTAL Release Tracking Number FORM & PHASE I COMPLETION STATEMENT ❑4 _ 824 Pursuant to 310 CMR 40.0484 (Subpart D)and 40.0800 (Subpart H) ' H. PERSON UNDERTAKING RESPONSE ACTION(S): Name of Organization: Huhhard ni 1 Co Tnr. NameofContact: F ell 4ri Read Title: C1eneral Manacrer ' Street: PO Rox In City/Town: Hvann i G State: MA ZIP Code: 02 6 01 -0000 I ' Telephone: 800-287-7101 Ext.: FAX(optional) 508-778-9401 Check here if there has been a change in the person undertaking the Response Action. tI. RELATIONSHIP TO SITE OF PERSON UNDERTAKING RESPONSE ACTION(S): (check one) ® RP or PRP Specify: O Owner ® Operator O Generator O Transporter Other RP or PRP: ' El Fiduciary,Secured Lender or Municipality with Exempt Status(as defined by M.G.L.c.21 E,s.2) Agency or Public Utility on a Right of Way(as defined by M.G.L.c.21 E,s.50)) Any Other Person Undertaking Response Action Specify Relationship: J. CERTIFICATION.OF PERSON UNDERTAKING RESPONSE ACTION(S): I FvPI yn Read attest under the pains and penalties of perjury(i)that I have personally examined and am ' familiar with the information contained in this submittal,including any and all documents accompanying this transmittal form,(ii)that,based on my inquiry of those individuals immediately responsible for obtaining the information,the material information contained in this submittal is,to the best of my knowledge and belief,true,accurate and complete,and(iii)that I am fully authorized to make this attestation on behalf of the entity legally responsible for this submittal. I/the person or entity on whose behalf this submittal is made am/is aware that there are significant penalties,including,but not limited to, possible fines and imprisonment,for willfully submitting false,inaccurate,or incomplete information. By: Title: SPnPra1 Manager (signature) Q ' For Huhhard nil CC- Tnr Date: /-d0—d a (print name of person or entity recorded in Section H) ' Enter address of the person providing certification,if different from address recorded in Section H: Street: City/Town: State: ZIP Code: ' Telephone: Ext.: FAX:(optional) YOU MUST COMPLETE ALL RELEVANT SECTIONS OF THIS FORM OR DEP MAY RETURN THE DOCUMENT AS INCOMPLETE. IF YOU ' SUBMIT AN INCOMPLETE FORM,YOU MAY BE PENALIZED FOR MISSING A REQUIRED DEADLINE. I � Revised 3/30/95 Supersedes Forms BWSC-010(in part)and 013 Page 3 of 3 Do Not Alter This Form 1 1 1 1 1 � APPENDIX D 1 7 1 1 1 1 � 1 1 � 1 1 1 1 SITE HEALTH AND SAFETY PLAN ' Waste Site Cleanup PHASE II: Comprehensive Site Assessment Hubbard Oil Co., Inc. ' 33 and 51 Brooks Road, Hyannis, MA MA DEP RTN 4-0824 Prepared by: ' BENNETT & O'REILLY, INC. 1573 Main Street P.O. Box 1667 Brewster, MA 02631 ' TABLE OF CONTENTS PAGE 1.0 Emergency Response Summary 1 2.0 Site Hazards/Personal Protection Summary 3 ' 3.0 Health &Safety Personnel 8 3.1 Site Safety Officer ' 3.2 Project Manager 3.3 Construction Superintendent 4.0 Hazard Assessment 10 4.1 Recognition II ' 4.2 Evaluation 4.2.1 0,/LEL Monitoring 4.2.2 Organic Vapor Monitoring 4.2:3 Physical Hazards ' 4.3 Control 5.0 Safety Equipment 14 5.1 Personal Protective Equipment(PPE) 5.2 Site Safety Equipment 5.2.1 Air Monitoring Instruments ' 5.2.2 Site Safety Plan 5.2:3 First Aid Kit 5.2.4 Fire Extinguisher ' 5.2.5 Decontamination Equipment 6.0 Work Zones 16 ' 7.0 Health and Safety Requirements 17 7.1 Training 7.2 Medical Surveillance Program 7.3 General Work Practices 7.3.1 Identify Pertinent Information 7.3.2 Have and be Familiar with Field Map 7.3.3 Avoid Obvious Hazardous Areas 7.3.4 Protect Against Physical Hazards 7.3.5 In the Event of Accident 8.0 Decontamination Procedures 19 9.0 Field Team Review 20 Appendix A. Vapor Monitoring Form Appendix B: Confined Space Procedures ' Appendix C: OSHA Trenching Regulations 1 Health and Safety Plan Page I of 16 Hubbard Oil Co.,Inc. ' 1.0 EMERGENCY RESPONSE SUMMARY Project No: B002-3490 ' MA DEP RTN: 4-0824 Status: Phase II: Comprehensive Site Assessment Date of Plan Preparation: August 28, 2002 This Health&Safety Plan(HASP)was prepared in conformance with the BENNETT&O'REILLY, INC., Health & Safety Program, and is intended to meet the requirements found in 20 CMR ' 1910.120. As such,the HASP addresses all activities associated with field operations at 33 and 51 Brooks Road in Hyannis, MA. Compliance with this HASP is required of all BENNETT & ' O'REILLY, INC. employees and subcontractors. Site Information ' Listed Responsible Party: Hubbard Oil CO., Inc. Property Owner:.B&A Realty, Inc. Site Address: 33 and 51 Brooks Road, Hyannis, MA ' Site Activities: Test borings, Monitoring well construction, soil and groundwater sampling On-site Subcontractor(s): BENNETT & OREILLY, INC. Consultant, LSP JENKINS WELL DRILLING, INC. ' Drilling operations, Monitoring well install Project Team: Health&Safety Supervisor:ervisor: David C. Bennett (B & 0, Inc.) 508- 896-6630 Health& Safety Manager: Kara Risk(B & 0, Inc.) 508-896-6630 ' Site Safety Officer(SSO): Todd Everson 508- 896-6630 Project Manager: John Tadema-Wielandt 508- 896-6630 ' Utility Clearances: Dig-Safe: 9 2002 350 7110 (888) 344-7233 Electric Company: N-Star Electric (800) 642-7070 Telephone Service: Verizon (800) 980-9999 Water Department: Barnstable Water Co. (508) 775-0063 1; r Health and Safety g Plan Page 2 of 16 Hubbard Oil Co. Inc. , ' Emergency Information: Telephone Location: Mobile Phone On-Site (B&O, Inc. personnel) (508) 737-6126 ' Hospital Address: 27 Park Street - Hyannis, MA 02601 (508) 771-1800 Directions to Hospital: (Refer to attached maps) Important Telephone Numbers: ' Ambulance: 911 ' Fire: 911 Police: 911 Poison Control Center: (800) 562-8236 National Response Center (800) 424-8802 ' Chemical Referral Center (800) 262-8200 Typical Procedures for Injury: 1. For minor injuries, administer first aid at the site. Refer individual to consult family ' physician. 2. Telephone ambulance for major injuries or evidence of toxic symptoms. If no phone is available, transport person to the nearest hospital. 3. Send MSDS with person to hospital. 4. Notify project manager or SSO of all accidents. 5. File accident report with Construction Superintendent. I 1 Health and Safety Plan Page 3 of 16 Hubbard Oil Co.,Inc. ' 2.0 SITE HAZARDS/PERSONAL PROTECTION SUMMARY ' Expected Site Hazardous Substances: Fuel oil, Gasoline Physical Hazards: Drilling rig operation, heavy machinery ' Chemical Hazards: [Ex: Inhalation of organic vapors, dermal contact and skin absorption] (see following) Chemical OSHA NIOSH OSHA OSHA Routh of Aerate Health EftectslSiems and Symptoms Substance PEL•• MLH PEI, CEHdNG Eqoatrn TWA* Urnits sm ' Ingemon Gasoline 300 ppm NA S00 ppm NA Sian absoiptian Eye,skim.and respiratory tract irritation-pearlier skin Eye contact seriatim of numbness or pins-and-needles feeling;fatigue headache,weakness,dimness,drowsiness,and confusion; Miculty seemin bright light. t Benzene 1 ppm NA 5 ppm NA Inhalation Respiratory,skin,eye,and mucous membrane irritation;nerve Ingestion inflammation,CNS depression.and cardise ieosaiz'atuxt. Skin absorption dizmrss,euphoria,headache,nausea,drowsiness,hug tissue fluid btrild pneumonia,convulsions and s Toluene 100 ppm 2,000 ppm 150 ppm 5W Inhalation Eye,skin.and respiratory tract irritation;peculiar skin Ingestion sensation of numbness or pins-and-needles feeling:fatigue, I ' Skin absorption headache,weakness.dizziness,drowsiness,and confusion; difficulty in bright li t Ethylbenzene 100 ppm 2,000 ppm 125 ppm NA Inhalation Eye,skin,and respiratory tract irrtation;peculiar skin sensation Skin absaptim of numbrws or pins-and-needles feeling;fatigue,headache, ' Ingestion weakness,dimmers,drowsiness,and camfitsion;difficulty some in bri t light. Xylenes 100 ppm 1,000 ppm ISO ppm 300 Inhalation Eye,nose,or throat irritation;severe breathing difficulty(an Skin absorption be a delayed effect);dizziness,staggering.drowsin ss,and ' Ingestion umoomsoousness;loss of appetite,nausea,vomiting.and abdominal ' Tetraethyl- 0.10 40 m�3 NA NA Inhalation kdoucacion;difficulty in sleeping.tiredness,try.��g, lead m�/r ] Ingestion Spawns,nausea,loss of appcdtq daorienuticu,hallucinations, ('MV) Skin absorption grunacing,manic or violent convulsive seizures; ' unconsciousness death;fetal damage or injury. methyl test- NA NA NA NA Skin absorption Skin and eye irritant,nervous system deptessant but ether NA E Contact ' Diesel Fuel S me/m3 NA NA NA Ingestion britation of mucous membranes and skin,diarrhea;headache- Skin a NA e contact NA Lthalation Heating Oil s mod NA Skin absorption Eye,,skin.respiratory irritation;headache.dizziness,nausea. Eye Contact vomiting.leas of coordination,rash,chemical phasmatias. ' PEL -Permissible Exposure Limit STEL -Short Term Exposure Limit TLV -Threshold Limit Values ' IDLH -Immediately Dangerous to Life or Health 1 I Health and Safety Plan Page 4 of 16 Hubbard Oil Co.,Inc. CHEMICAL PROPERTIES ' Substance Flammability Phase at Flash Point Biolin Point Va por apor Solubility in Reactivity Room Temp. LEUUEL Freezing Point Pressure Water Gasoline Flammable Liquid -36F 140F NA Insoluble Oxidizing l.46/7.6% agents i ' Benzene Flammable Gas 12F 176F/42F 75mm 0.18 Strong oxidizers 1.30/6/7.9% Chlorine Toluene Flammable Gas 40F 231F/-139F 22mm 0.05 Strong oxidizers 1.3%/7.1% ' Ethylbenzene Flammable Gas 59F 277F/-139F 7.1mm 0.015 Strong oxidizers 1.0%/6.7% ' Total Xylenes Flammable Gas 81-90F 282F/-12F 7-9mm 0.00003 Strong oxidizers 1.1%/7,0% Tetraethyl-Lead Combustible Liquid 20OF 228F/-109F 0.2mm Insoluble Strong oxidizers 1.850/o/NA Sulfuryl chloride ' MTBE Flammable Gas NA 55F/-109F 245mm 4.8 Oxidizers Acid solutions Diesel Fuel Flammable Liquid IOOF NA NA Insoluble NA l.3%/6% Heating Oil Flammable Liquid IOOF 330F/-605C NA NA FNA ' I.0%/NA POTENTIAL HAZARD CONTROL Exposure to Petroleum Products 1. Stand up-wind of petroleum products whenever possible. ' 2. Minimize contact and contact time with petroleum products. 3. Avoid waling through discolored areas,puddles,leaning on barrels,or coming into contact with anything that is likely to be contaminated. 4. Do not eat,drink,smoke and/or apply cosmetics in the hot or warm zones. 5. Wear gloves when in contact with contaminated surfaces. 6. Safety glasses must be wom at a minimum. 7. Splash goggles must be wom when working with liquids. 8. 75ppm organic vapors in breathing zone required upgrade to Level C. 9. 750ppm organic vapors in breathing zones required upgrade from Level C to Level B. ' 10.If unknown materials are encountered,call Safety Supervisor. Vehicular Traffic 1. Wear traffic safety vest when vehicle hazard exists. 2. Use cone,flags,barricades and caution tape to define work area. 3. Use vehicle to block work area. 4. Engage police detail for high traffic situations. Vault Entry f. Follow confined space entry procedures. 2. Obtain confined space entry permit. Post signs. 3. Remove vault cover using proper lifting techniques. 4. Promote natural ventilation by opening the space to fresh air. 5. Conduct remote air monitoring prior to entry. 6. Have standby attendant if necessary. 7. Enter if safe;conduct continuous air monitoring. High Crime Areas 1. Be aware of surroundings. 2. Use buddy system. 3. Request police detail when appropriate. 1 i Health and Safety Plan Page 5 of 16 Hubbard Oil Co.,Inc. ' Insects 1. Tuck pants into socks. 2. Wear long sleeves. 3. Use insect repellant. Poison Plants(oak,sumac,ivy,etc.) 1. Do not enter areas infested with the poisonous plants. 2. Immediately wash any areas that come in contact with poisonous plants. ' Ladders 1. Make sure ladder rungs are sturdy and free of cracks. 2. Use ladders with secure safety feet. 3. Pitch ladders at a 4:1 ratio. 4. Secure ladder at the top when possible. 5. Do no use ladders for access to air stripper towers. ' 6. Use non-conductive ladders near electrical wires. Fire Control I. Smoke only in desginated areas. 2. Keep flammable liquids in closed containers. 3. Keep site clean;avoid accumulating combustible debris such as paper. 4. Follow Hot Work Safety Procedures when welding or performing other activities requiring an open flame. 5. Isolate flammable and combustible materials from ignition sources. 6. Ensure fire safety integrity to equipment installations according to Hazard Classification Diagram. Inclement Weather 1. Stop outdoor work during electrical storms and other extreme weather conditions such as extreme heat or cold temperatures. ' 2. Take cover indoors or in a vehicle. 3. Listen to local forecasts for warnings regarding specific weather hazards such as tornadoes, hurricanes,and flash floods. ' Noise 1. Wear hearing protection when equipment such as drill rig,jackhammer,cut saw,air compressor,blower,or other heavy equipment is operating on the site. 2. Wear hearing protection whenever you need to raise your voice above normal conservational speech due to a loud noise source;this much noise indicated the need for protection. i Electric Shock I. Maintain appropriate distance from overhead utilities;20'minimum clearance from power lines required; 10'minimum clearance from shielded power lines. 2. Use ground-fault circuit interrupters as required. 3. Perform lockout/tagout procedures. ' 4. Use three-pronged plugs and extension cords. 5. Contact your local underground utility-locating service. 6. Follow code requirements for electrical installations in hazardous locations. ' Personal Injury 1. Wear hard hats and safety glasses when on site. 2. Maintain visual contact with the equipment operator and ear orange safety vest when heavy equipment is used on site. 3. Avoid loose-fitting clothing. ' 4. Prevent slips,trips,and falls by keeping work area uncluttered. 5. Contact you location underground utility-locating service. 6. Test the emergency shutoff switch on the drill rig daily. Back Injury 1. Use mechanical lifting device or a lifting aid where appropriate. ' 2. If you must lift,plan the lift before doing it. 3. Bend at the knees and use leg muscles when lifting. 4. Use your buddy system when lifting heavy or awkward objects. 5. Do not twist you body while lifting. Heat Stress I. Increase water intake while working. 2. Increase number of rest breaks and/or rotate workers in shorter work shifts. 3. Watch for signs and symptoms of heat exhaustion and fatique. 4. Plan work for early morning or evening during hot months. 5. Use ice vests when necessary. 6. Rest in cool,dry areas. 7. In the event of heat stroke,bring the victim to a cool environment and initiate first aid ' procedures. Cold Stress 1. Take breaks in heated shelters when working in extremely cold temperatures. 2. Remove the outer layer os clothing and loosen other layers to promote evaporation of perspiration upon entering the shelter. ' 3. Drink warm liquids to reduce the susceptibility to cold stress. Health and Safety Plan Page 6 of 16 Hubbard Oil Co.,Inc. ' Personal Protection/Action Levels: The minimum level of protection for personnel at this site is Level D. This level is utilized where ' the type of work involved precludes exposure due to splashes, immersions or the potential for unexpected inhalation or contact with hazardous levels of chemicals. ' The need to upgrade personal protection from Level D to Level C is based on ambient air measurements in the breathing zone with a portable photoionization detector(PID)with a 10.2 EV ' lamp. The action level for upgrading from Level D to Level C protection when dealing with gasoline and deisel fuel and their constituents is a measurement of 2 parts per million(ppm)in the breathing zone for a sustained period of 15 minutes. Upgrading to Level C protection,however, can be done ' at any time for any reason of personal concern for safety. Measurement of a sustained concentration greater than 100 ppm would require evacuation of the site. ' If separate-phase gasoline and/or diesel fuel is encountered during excavation activities,continuous monitoring for combustible gas concentration and oxygen concentration must also be performed. Measurements greater than 20% of the Lower Explosive Limit (LEL) for combustible gases, or 1 greater than 23%oxygen.require evacuation of the site. Measurements of oxygen concentration less the 19.5% would also require immediate evacuation from the area where the concentration was ' measured. Action Level Summary ' Monitoring Device Level D Level C PID/FID <2 ppm 2 ppm - 50 ppm t LEL < 1% LEL 1 % - 10 %LEL Oz 19.5 % - 23 % < 19.5 % or> 23 % ' 3.0 PROJECT PERSONNEL A management structure for this project has been designed which contains several levels of I ' responsibility for implementation of health and safety procedures. Although each level of management share some responsibility for maintaining a safe working environment, the primary responsibility for safe operations ultimately rests with the field personnel and the Site Safety Officer and/or the Project Manager working at the site. It is incumbent upon field personnel to recognize unsafe conditions and to report such conditions to their immediate supervisor. In the event that the individual is not satisfied that the situation has been satisfactorily resolved, questions should be 1 directed to the next higher level of authority in the Health& Safety Management structure until the individual is satisfied that a safe working environment has been achieved. Individuals responsible for health and safety practices a this site are listed the Section 1.0 Emergency Response Summary, ' and job descriptions for the health and safety management structure are presented below. After exploring all the above paths,any individual that still does notfeel that a safe working environment has been achieved would be justified in stopping work and leaving the site. r Health and Safety Plan Page 7 of 16 Hubbard Oil Co.,Inc. 3.1 Site Safety Officer The Site Safety Officer(SSO)has overall responsibility for the implementation of this Health and Safety plan. The SSO could be a supervisor for other on-site personnel or could be the only person on-site, depending on the scope of work. The SSO's responsibilities shall include, but not necessarily be limited to, the following: ' ' - perform air monitoring in accordance with procedures listed in Section 5.2 if P g p ( warranted); ' - upgrade or downgrade Personal Protective Equipment (PPE) level of protection in response to changes in exposure levels, weather, or other site conditions; ' - know emergency procedures, evacuation routes and other pertinent emergency response information as detailed in the Section 1.0 Emergency Response Summary; - report any signs of fatigue of chemical exposures to Project Manager; = report any accidents or violations of the Health & Safety Plan to Project Manager; stop work at the site if any condition is detected that presents an imminent danger to the health and safety of workers or the general public. 3.2 Project Manager ' The project manager is responsible for the inspection and documentation of work and assessment activities needed for completion of the project activities. The project manager's responsibilities include the following: - provide authority and resources to SSO to allow for implementation of all necessary safety procedures; ' - coordinate activities with the Construction Superintendent and to ensure he is aware of any pertinent health & safety requirements; review project scheduling and planning activities; and, - ensure that field personnel are monitored for compliance with all provisions of the site-specific Health and Safety Plan. ' 3.3 Construction Superintendent The Construction Superintendent has overall responsibility for the implementation, scheduling and coordination of all personnel and resources needed for the completion of the remedial plan. The project Superintendent's responsibilities include the following: - supervise construction activities with the subcontractors to ensure they are aware of any pertinent health and safety information; and, ' - ensure that all employees are in compliance with the provisions of the site specific Health and Safety Plan. ' Health and Safety Plan Page 8 of 16 Hubbard Oil Co.,Inc. ' 4.0 HAZARD ASSESSMENT At sites which contain or are suspected to contain hazardous substances,certain procedures will be implemented to identify, evaluate and control the substances, as follows: 1. Recognition-identification of substances,hazardous characteristics of these substances,and ' tasks which may result in exposure to these substances. 2. Evaluation-the risk of impact of the substance to personnel,the public and the environment. ' 3. Control - prevent r minimize the impact of the u methods to t o p substance. Recognition and evaluation of hazardous substances can and should be initiated prior to site access. However,recognition and evaluation are also ongoing processes that will continue as work at a site continues. Substances unexpectedly encountered during the course of work require an evaluation ' of the materials' potential risk or impact. These processes are directly related to the safety of site personnel conducting field investigations. In addition,knowledge acquired by site personnel could ' be valuable to the health and safety of subsequent visitors to the site. 4.1 Recognition Preliminary information about the hazardous substances which may be present at a site and the parameters which cause them to be hazardous can be obtained from an understanding of the site history. Site use, substances used at the site, disposal of substance(s) (on site or off site) and existing status of operations provide background information on the type of materials which can be expected to be encountered. This initial step is essential to best ' establish how site personnel can safely obtain additional information to further recognize the hazardous substances at a site. ' Tasks which may result in exposure to hazardous substances at this site could include drilling operations, well installation, well development, well gauging, ground water, soil, or vapor sampling and construction activities including shoring,cribbing,underground tank removals ' or trenching operations. ' In general,the following conditions are recognized as being potentially hazardous at this site: Flammable vapors- The presence of flammable vapors can present both a potential fire or ' explosion hazard and a toxic hazard. If the concentration of flammable vapors is measured by a combustible gas indicator (CGI) at concentrations greater than 20% of the lower explosive limit(LEL), personnel should evacuate the site immediately. ' Oxygen - Oxygen can present hazards in either concentrations higher or lower than the normal atmospheric concentration of approximately 20.5%. Oxygen concentrations greater than 23%are an extreme fire hazard due to rapid oxidation reactions. Oxygen concentrations less than 19.5%post an asphyxiation hazard for personnel. If either the enriched or deficient Health and Safety Plan Page 9 of 16 Hubbard Oil Co.,Inc. ' oxygen condition is observed by personnel on an O2 meter, the area should be evacuated immediately. ' Organic Vapors-Inhalation of toxic organic vapors is a potential health hazard. This hazard may be reduced by monitoring ambient air with a photoionization detector(PID) and using ' Personal Protective Equipment(PPE). Physical Hazards - Possible physical hazards would include road traffic for activities ' conducted within roadways or parking areas, and hazards associated with heavy equipment used on site. Equipment hazards can be associated with direct exposure to falling loads or moving machinery, or can be due to accidental contact of machinery with electric, gas, or ' water utility lines. 4.2 Evaluation The potential risks or impacts of hazardous substances suspected or known to exist at a site must be evaluated prior to entering the site. Site history is the initial source of information ' which must be used to determine the level of personal protection to be worn by site personnel while collecting further field information for evaluation. Levels of personal protection are summarized in Section 5.1. The minimum level of protection for site personnel during a site ' investigation is Level D. This level should be utilized where the atmosphere contains no known imminent hazards and the type of work involved precludes exposure due to splashes, immersions, or the potential for unexpected inhalation or contact with hazardous levels of ' chemicals. ' An ongoing air monitoring program will be established to evaluate exposures to personnel. Ambient air will be monitored for organic vapor concentrations at all sites where the possibility for airborne exposures exist. Ambient air will be monitored for O2 concentrations and combustible gas concentrations when the present of separate-phase fuel oil and/or confined spaces creates a potential for explosive or oxygen-deficient conditions. ' 4.2.1 0,/LEL Monitoring Continuous monitoring will be performed within 02/LEL meter during operations such as ' trenching, excavation, or tank removals where there is a potential for build-up of explosive gasses for development of oxygen-deficient atmosphere. An extension sampling tube will be run from the detector instrument intake to the bottom of the excavation in order that samples are drawn from the"worst case"location for accumulation of vapors that are heavier than air. The 02/LEL meter will be calibrated in accordance with the manufacturer's recommendations on a regular basis. 4.2.2 Organic Vapor Monitoring ' Organic vapor concentrations in ambient air will be measured with a portable photoionization detector (PID) which has been previously calibrated with a gas standard 1 Health and Safety Plan Page 10 of 16 Hubbard Oil Co.,Inc. ' equilibrated to read as benzene. Monitoring will be conducted in the breathing zone every fifteen minutes for sites that have been approved for Level D PPE, or on a continuous basis for sites that require Level C protection. The breathing zone is defined as the sphere of approximately one-foot radius surrounding a worker's head under normal working conditions. ' Ambient air monitoring will also be performed at the site perimeter at one-hour intervals in order to evaluate any potential exposures to the general public. The site perimeter is defined ' as the lesser of, 1)the distance to the property boundary, or 2) a radius of 100 feet from the exclusion zone boundary. The PID meter used will be calibrated in accordance with the manufacturer's recommendations on a regular basis. All air monitoring results will be ' recorded on the vapor monitoring form attached in Appendix A. 4.2.3 Physical Hazards All efforts will be made to identify utility line locations prior to initiating any subsurface work at the site. In addition,,heavy equipment must be checked for clearance to any ' overhead power lines and must maintain a minimum fifteen-foot clear distance at all times. 4.3 Control ' This Health and Safe Plan has been developed with the purpose of protecting on-site ri p P � P g personnel from exposures to hazardous substances or situations. Observance of all guidelines and procedures contained in the Plan will minimize the risk to personnel involved in site activities and to the general public. rThe plan has been prepared specifically for BENNETT&OREILLY,INC.,based upon the data available from physical testing and research conducted at the site in conjunction with the remedial actions taken to date. Due to some uncertainties inherent to this type of work, the health and safety plan will continually be re-evaluated and modified in accordance with the industry standard of care at the time of these activities. As such,this plan shall not be construed to express or imply a guarantee or warranty against personnel injury or property damage. Any such occurrence will be handled in a manner consistent with the Terms and Conditions of employment. Health and Safety S Plan Page I 1 of 16 Hubbard Oil nc. Co.,> ' 5.0 SAFETY EQUIPMENT ' All required equipment will be present and readily accessible at all sites where hazardous substances or situations may be encountered. ' 5.1 Personal Protective Equipment (PPE) Level D PPE includes: a) Coveralls b) Gloves,chemical-resistant ' c) Boots,shoes,chemical-resistant,hard toe and shank d) Boots,(outer),chemical-resistant(disposable)* e) Safety glasses or chemical splash goggles* f) Hard hat ' g) Face shield* Level C PPE includes: ' a) Full-face or half-face purifying respirators(OSHA approved) b) Coveralls c) Hooded chemical resistant clothing(overalls,two-piece chemical-splash suit,disposable chemical- resistant overalls) ' d) Gloves(outer),chemical-resistant* e) Gloves(inner),chemical-resistant 0 Boots,chemical-resistant hard toe and shank ' g) Boot covers,chemical-resistant(disposable)* h) Hard hat i) Escape mask* ' D Two-way radios* k) Face shield* 1) Buddy system required * Optional,as applicable. BENNETT & OREILLY, INC., does not perform work that would require Level A or Level B PPE. ' The Site& Safety Officer and/or Project Manager is responsible for recognizing conditions that would call for an upgrade of PPE from Level D to Level C protection during site ' operations. The criteria for establishing protection levels is summarized in Section 2.0 Personal Protection/Action Levels Summary. Health and Safety Plan Page 12 of 16 Hubbard Oil Co.,Inc. 5.2 Site Safety Equipment Equipment which should be available to all personnel working on the site is listed below. 5.2.1 Air Monitoring Instruments ' - Calibrated HNU meter or other suitable portable monitoring photoionization device. This device should be selected to provide maximum sensitivity for the compounds ' expected to be present. Understand the limitations and applications of the instruments. ' - Calibrated 02/LEL meter. This device should be used to monitor the potential for explosive conditions and to determine the oxygen content in confined spaces. ' 5.2.2 Copy of Completed Site Safety Plan - Emergency center telephone numbers - Hospital location - Safety procedures ' 5.2.3 First-Aid Kit - Sized to accommodate the number of personnel on site Located in the established clean zone ' 5.2.4 Fire Extinguisher - Minimum size 10 lb A-B-C - Located in the established clean zone, or as appropriate 5.2.5 Decontamination Equipment - Five-gallon waterjug - Brush - Basin Decontamination solution for washdown - Located in the established decontamination zone. Health and Safety Plan Page 13 of 16 Hubbard Oil Co.,Inc. 6.0 WORK ZONES Zones will be identified by the Site Safety Office prior to initiating work at the site. This ' identification may involve either a physical marking of the zones on the ground surface at the site, or it may simply be accomplished by establishing zone identifications verbally with on-site personnel, depending on the complexity and magnitude of the site operations. Definitions of the t work zone classification are presented below. ' Zone#1: Clean/Safe , Zone (> 10' from excavation) All support equipment (first-aid kit, eye wash bottle, clean personal protective equipment, etc) will be in the area designed as clean/safety zone. Smoking will only be allowed in this area. Zone #2:12ontamination Reduction Zone (< 10' from excavation) This is a buffer zone for exit and decontamination procedures before proceeding into the clean/safety zone.. Leave gloves;air monitoring equipment and any other equipment in Zone #2. Zone #3: Hot Zone within excavation This is the zone where contamination does or could occur. When drilling, this is the area within a twenty-foot radius of the operating drill rig. Appropriate protective equipment should be worn in this zone. ' 7.0 HEALTH AND SAFETY REQUIREMENTS General requirements for safe work practices and training of personnel are detailed below. 7.1 Training ' All BENNETT & O'REILLY personnel working at the site will have received a minimum of forty hours of hazardous waste site instruction and three days of field experience with a ' trained,experienced person on-site.This training will be in accordance with the requirements of the OSHA Hazardous Waste Operations regulation 29 CFR 1910.120. BENNETT & O'REILLY personnel will also receive eight hours of refresher training per year. All contractors working at the site will be responsible for maintaining the appropriate level of training for their employees according to OSHA regulation 29 CFR 1910.120. II 1 7.2 Medical Surveillance Program A yearly physical examination is conducted on BENNETT&OREILLY employees with 40 hour OSHA HAZWOPER training.Physical examinations are repeated on a yearly basis for normal exposures, or more frequently if a specific over-exposure is suspected. 1 ' Health and Safety g Plan Page 14 of 16 Hubbard Oil Co.,Inc. 7.3 General Work Practices This section describes standard practices to be used for general operations that are conducted at the ground surface. Specific procedures to be used when entering a confined space are attached as Appendix B. Specific regulations pertaining to excavation and trenching activities are attached as Appendix C. 7.3.1 Identify Pertinent Information With Site Project Manager - locations of concern - dumps, containment ponds, spill areas, etc; ' = access and egress to and from site with alternate routes; and site work zones 7.3.2 Have And Be Familiar With Field Map plan work route and work locations; ' - know areas that contain underground gas and electrical lines(this information should be obtained from Dig Safe); check with site personnel for location of underground hazards(i.e.chemicals,tanks, ' utilities, etc.); identify location of nearest phone; and, know access and egress locations. 7.3.3 Avoid Obvious Hazardous Areas Including ' - lagoons, berms, impoundments; discolored soil and water areas, drums, etc.; ' = confined/enclosed structures,tanks, etc; and, any areas visually posted as dangerous. 7.3.4 Protect Against Physical Hazards: - use high visibility cones, barricades, and vests where traffic hazard exists; - always watch operating machinery closely and be aware of the existence of"kill switches" or other means of machine shutdown; and - maintain good communications and visual contact among all workers at the site. 7.3.5 In the Event of Accident, Physical Reaction or Excessive Exposure: Leave area immediately and proceed to designated clean zone. Administer first aid, if appropriate. Obtain medical assistance for serious exposures. Any employee who becomes sick or injured on the job must receive medical clearance and clearance from the Project Manager before returning to the site. I � Health and Safe Plan Page 15 of 16 Hubbard Oil C . Inc.Safety g o, Overexposure can be caused by: * spills, splashes,immersions, inhalation Symptoms of overexposure may include, but not limited to, any of the following physiological reactions: ' * dizziness, nausea, rash, asthmatic reactions * abdominal pain, distorted vision/hearing * * excessive coughing, swelling, headaches * 8.0 DECONTAMINATION PROCEDURES 1 Activities conducted at this site have the potential to contaminate personal protective equipment, monitoring equipment, and/or other physical equipment. If the Site Safety Officer judges that contamination .of equipment has occurred during site activities, all such equipment shall be decontaminated using the following general procedures: Wash equipment and/or boots and gloves which have come in contact with hazardous 1 substances with a detergent solution followed by clean water. If contaminant is of an oily nature, methanol may be used as a cleaning solution. - Properly dispose of items that cannot be decontaminated. - When using Level C PPE,respirator cartridges should be discarded, and respirators should be washed in a mild soap solution and rinsed with clean water. ' - Construction equipment and/monitoring equipment will be cleaned at the discretion of the Site Safety Officer. Cleaning procedures may include detergent washing, ' methanol rinse, or steam cleaning. i i Health and Safety Plan Page 16 of 16 Hubbard Oil Co.,Inc. 9.0 FIELD TEAM REVIEW Each field team member shall sign this section before being permitted to work on-site. I have read and understand this site-specific Health and Safety Plan. I will comply with the provisions contained therein. ' Site/Project: ' Name (Printed) Company Signature Date III 1 I H & S APPENDIX A VAPOR MONITORING FORM t ' TANK/SOIL REMOVAL AIR MONITORING FORM ' Project Number: Location: Representative: Date: Arrival Time: Departure Time: Temperature: Weather Conditions: Air Monitoring Device(s): I ' TANK/EXCAVATION PIT AIR MONITORING LEVELS Above Pit Inside Pit COMMENTS I f 1 t t t ' H & S APPENDIX B CONFINED SPACE ENTRY PROCEDURES It CONFINED SPACE ENTRY PROCEDURES The purpose of this guidance is to prevent serious accidents which could result from entry into confined spaces. Confined spaces are classified according to their existing or potential chemical and physical hazards. Classification is based upon characteristics of the confined space,oxygen level,flammability,and toxicity and is determined by the most hazardous condition of entering,working in,and exiting a confined space. If any of hte hazards present a situation that is"Immediately Dangerous to Life and Health"(IDLH),th confined space is,classified as Class A. Class B confined ' spaces have the potential for causing injury and illness but are not IDLH. Class C entry is one in which the chemical hazard potential is minimal and does not require any special modification in work procedures. Use of a combustible gas indicator and oxygen meter is required. No on-site personnel will be allowed into a confined ' space unless there is a minimum of one observer that will remain outside of the confined space, and at least one additional person that has been informed about the entrance and placement of the confined space. 1. Confined Space Policy The on-site personnel are not to enter a confined space unless a full working knowledge of that space and/or P P g g P a confined space permit has been completed. It is the responsibility of the project supervisor to request a ' confined'space entry permit from the Project Manager. The confined space permit shall be signed by and explained to .each employee working the confined space project and their signatures will indicate the understanding of the rules outlined in the permit. 2. Confined Space Entry Procedures Each confined space shall be tested for combustible vapors,oxygen level,and organic vapors. When levels of ' combustible vapors exceed ten percent of the lower explosive limit LEL, all sources of ignition shall be removed. Entry shall not be made until the space is flushed or purged below the 10 percent LEL level. Each confined space must be tested for oxygen content prior to entry. The minimal acceptable percent of oxygen is ' 19.5 percent. If this level cannot be met,site personnel will not enter the confined space. Chemical protective equipment must be worn if the potential exists for contact with a chemical from which protection is necessary. The project supervisor is responsible for evaluating general safety hazards including permits,adequate lighting, ' tools,etc. Before work is initiated in a confined space,all product lines and electrical lines will be locked and tagged. ' A ladder is required in all confined spaces deeper than the employees shoulders. The ladder shall be secured and not removed until all employees have exited the space. ' 3. Confined Space Entry Procedures for Safety Observer Employees entering a confined space must be under the constant observation of a safety observer. It is the safety observer's responsibility to follow these procedures: a. A valid confined space entry permit must be at the site. b. Rescue equipment or emergency phone numbers must be available at the site. C. The safety observer,must know the location of the nearest telephone, emergency numbers and fire extinguisher. e. The safety observer must remain in constant contact with the employee(s)in the confined space except to report and emergency. r H & S APPENDIX C ' OSHA TRENCHING REGULATIONS 1 ' SUMMARY OF OSHA CONSTRUCTION STANDARDS FOR EXCAVATIONS ' (29 CFR Part 1926.650-.652) 1926.650 Scope,application,and definitions applicable to this subpart Excavations are defined to include trenches. 1926.651 General requirements(applies to all excavations) a) Surface encumbrances-Shall be removed or supported, as necessary,to safeguard employees. II ' b) Underground installations-Prior to start of excavation, utility companies shall be contacted within established or customary local response time to estimate locations of underground utility installations. When excavation operations approach estimated locations,the exact locations shall be determined by safe and acceptable means. While excavation is open, underground installations shall be protected and/or supported as necessary to safeguard employees. ' c) Access and egress-Structural ramps must be designed by a competent person. If ramps are for use of equipment,the competent person must be qualified in structural design. Means of egress from trench excavations>4 feet deep,such as a stairway, ladder or ramp shall be provided so as to require no more'than 25 feet of lateral travel for employees. ' d) Exposure to vehicular traffic-Reflectorized or high-visibility garments should be worn if exposed to traffic. I ' e) Exposure to falling loads-No employees shall be permitted underneath loads handled by lifting or digging equipment. Employees shall stand away from vehicles being loaded or unloaded. f) Warning system for mobile equipment - Where mobile equipment is operated adjacent to an excavation,or if the equipment is required to approach the excavation and the operator does not have a clear and direct view of the excavation edge, a warning system, such as barricades, hand or mechanical signals,or stop logs shall be used. g) Hazardous atmospheres-In addition to requirements in Subpart D and E(1926.50- 1926.107): In any excavation, provide proper respiratory protection or controls such as ventilation to prevent exposure to atmospheres containing less than 19.5%02 and to prevent exposure to greater than 20% of the lower flammable limit and provide testing of controls. Emergency rescue equipment shall be provided if hazardous conditions exist or may reasonably be expected to develop. For trenches>4 feet and if hazardous conditions exist or may exist, perform monitoring, prior to entering trench. ' h) Protection from hazards associated with water accumulation-Employees shall not work in excavations with accumulated water or where there is the potential for accumulated water unless adequate precautions(such as special support or shields systems,water removal,or the use of a safety harness and lifeline)are provided. All water removal equipment shall be monitored by a competent person. ' If excavations interrupt the natural drainage of surface water,diversion ditches,dikes,or other means shall be used to prevent surface water from entering the excavation and to provide drainage for the area adjacent to the excavation. Excavations subject to runoff from heavy rains will require and ' inspection by a competent person. i) Stability of adiacent structures-Support systems shall be provided where the stability of buildings, footings, sidewalks, pavement, or to other appurtenant structures, is endangered by excavation ' operations. j) Protection of employees from loose rock or soil- Scaling to prevent loose material, installation of ' protective barricades, or other means may be required to protect employees from material for the excavation face. To prevent material or equipment from falling or rolling into excavations,all materials or equipment shall be kept al least 2 feet from the edge or excavations,or retaining ` devices shall be used. k) Inspections(only when employee exposure can be reasonably anticipated)-Daily inspections by a competent person shall be conducted prior to start of daily work,and as needed throughout the shift. Inspections shall also be conducted after every rainstorm or other hazard increasing occurrence. Employees shall be removed if there is evidence of hazardous situations. ' 1) Fall protection-Walkways or bridges with standard guardrail shall be provided where employees or equipment are required or permitted to cross over excavations. Adequate physical barriers shall be provided at all remotely located excavations. Upon completion, temporary excavations shall be ' backfilled. 1926.652 Requirements for protective systems ' Trenches>20 feet deep-Protective systems must be designed by a professional engineer. Trenches<20 feet deep-Follow flowchart in Appendix F, Subpart P. In general: ' Soil Type Maximum Allowable Slope Stable Rock Vertical Type A(open<24 hrs,<12 feet) 1/2:1 Type A 3/4:1 Type B 1:1 Type C 1-1/2:1 ' d) Materials and equipment-Materials and equipment shall be free from damage or defects, and used and maintained as recommended by the manufacturer. If materials or equipment are damaged,they must be inspected by a competent person prior to continues use. If the competent person cannot assure ' the materials or equipment are suitable for future use, they must be removed and be evaluated and approved by a professional engineer before being returned to service. e) Installation and removal of support- Support system members shall be installed and used to ensure the safety of workers, which may include the installation of additional members prior to temporary removal of any individual members. Removal shall begin at, and progress from,the bottom of the excavation. Backfilling shall progress together with the removal of support systems. Excavation of ' material to a level>2 feet below the support shall not be.permitted. f) Sloping and benching systems-Employees shall not be permitted to work on the faces of sloped ' or benched excavations at levels above other employees except where adequate protection from falling.material is provided. h) Shield systems-Employees shall not be allowed in shields while they are being installed, removed, '� or moved vertically. Excavation of material to a level>2 feet below the shield shall not be permitted 1 1 1 1 � APPENDIX E 1 F 1 1 1 1 1 1 1 1 1 1 1 BENNETT A O 'REILLY. Inc. ---------------- Engineering, Environmental & Surveying Services 1573 Main Street Sanitary 21E/Site Remediation Property Line O PO Box 1667 t Brewster MA 02631 Site Development Hydrogeologic Survey Subdivision Waste Water Treatment Water Quality Monitoring Land Court 508-896-6630 Water Supply Licensed Site Professional Trial Court Witness 508-896-4687 Fax t n ' QUALITY ASSURANCE & QUALITY CONTROL PROGRAM Quality Assurance & Quality Control Program tFor Soil and Groundwater Sampling t INTRODUCTION tThe Quality Assurance & Quality Control (QA/QC) Program outlines the purpose, policies, organization and operations to support sampling work conducted by BENNETT&O'REILLY,INC.. t The procedures and protocal represented herein are consistent with the MA DEP "Standard References for Monitor Wells" [WSC-310-91], and the recommendations of a MA certified laboratory. Implementation of this program will help to ensure the validity of data used to provide tprofessional engineering and environmental opinions to clients. The following definitions are used in the QA/QC Program: It ' Quality Assurance refers to the concepts used in defining a system for verifying and maintaining a desired level of quality in a product or process. tQuality Control is a specific,Q tystep-by-step description of how the Quality Assurance Program will be carried out. t This QA/QC Program guides field sampling activities. Project specific QA/QC Programs are ' adopted when warranted. Modifications to the QA/QC Program may be made only after specific approval by the QAIQC Officer (Project Manager). t t t 1 t The specific objectives of the QA/QC Program are to: 1. specify the level of quality of each field procedure used in collecting samples; ' 2. identify deficiencies in field procedures which might affect the quality of data; and 3. require sufficient documentation to verify the credibility of the sampling methods employed. ' PROGRAM ORGANIZATION AND RESPONSIBILITY The Project Manager of BENNETT & 07REILLY, INC., is responsible for the quality of work II ' produced. The Project Manger directs the QA/QC Program to document the control of field efforts and resulting.data. In this capacity, the Project Manager is expected to do the following: ' 1. prepare detailed QC Plans; 2. obtain analytical and sampling procedures reference materials; 3. ensure that all field test and measurement P eq ui ment is maintained and calibrated properly; ' 4. monitor quality assurance activities to:ensure conformance with authorized policies, procedures, and sound practices, and recommend improvements as necessary, 5. ensure that all field sampling is conducted in accordance with guidelines contained P g herein, 6. oversee all field sampling efforts to detect conditions which might directly or indirectly jeopardize the utility of resulting analytical data, such as improper calibration of equipment or cross-contamination through improper storage of samples; ' 7. ensure that sample handling procedures are adequate for the sample types received; ' 8. inspect the quality of purchased sampling materials. ' 2 SAMPLE MANAGEMENT, COLLECTION, AND PREPARATION I ' Introduction Sample management and stringent documentation are essential for successful quality assurance. The ' procedures in this section are designed to ensure collection of samples which truly represent the matrix being sampled by eliminating trace levels of contaminants from external sources. ' Sample Management ' The management of samples, up to the point of delivery to the laboratory for analysis, is under the supervision of the Project Manager, who shall ensure that samples are collected, labeled,preserved, stored, and transported according to the prescribed methods. If significant deviations from the sampling protocol occur, resulting in a suspected compromise of the sample integrity, all samples ' collected during the sampling effort prior to correction of the procedure will be discarded and fresh samples collected. ' Sample Collection ' Groundwater Monitoring wells will be sampled in accordance with the following sampling procedures: ' 1. Identify the well and record the well number on the groundwater sampling record an an Monitoring Well Sampling Log (attached). ' 2. Open the well cap and measure total organic volatile (TOV) concentrations at the wellhead with the use of a portable photoionization detector. Record levels detected. ' 3. Measure groundwater level to the nearest 0.01 foot from the,top of the well casing using a water level indicator. Record water level on a Monitoring Well Sampling Log (attached). Water level indicators will be decontaminated between wells. 4. The volume of standing water in the well casing will be calculated and recorded on the Monitoring Well Sampling Log. At least three well volumes will be purged either by pump or disposable bailer. Newly installed monitoring wells will be developed by purging at least ten volumes. Purging of wells will be complete when either dissolved oxygen, pH, conductivity or temperature has stabilized relative to previous sampling rounds. Once the purging is complete,wells will be screened for each of the above parameters and recorded on the Sampling Log .. ' 5. Samples will be collected using either a disposable bailers or pump. Samples will be transferred into appropriately sterilized/preserved containers, taking care to ' minimize agitation of the sample [Refer to attached "Recommended Sample Containers..." Groundwater Analytical]. ' 3 6. Sample containers will be properly labeled with tags provided by the laboratory. Samples will be logged in on a chain-of-custody form. ' 7. Samples taken for precipitate metal analysis will be acidified to a pH of less than 2.0 in the field. When sampling water for volatile compounds, care must p g p be exercised to prevent loss of compound through evaporation, and to control susceptibility to outside contamination. Precautionary measures include: 1. avoiding engine exhaust,gasoline containers,degreasing solvents,solvent-laden rags I ' and non-compatible decontamination agents; ' 2. sampling bottles will only be opened at the time of sampling and quickly closed after collecting the sample, preventing aeration of the sample with the atmosphere or any other gas; 3. slowly filling bottles to capacity with sample and securing cap without entraining air bubbles; ' 4. inverting the bottle while tapping lightly to check for air bubbles.; 5. adding additional sample to eliminate air bubbles if present, repeating steps 3 and 4; 6. placing samples on ice (approximately 4°C) immediately after collection in a dark, ' dry location; 7. segregating samples with a secondary barrier such as zip-lock bags, etc.; and ' 8. analyzingsample as soon as possible within the specific holding times after P P P g collection. Pump tubing will be decontaminated as follows: 1. Pump non-phosphate detergent solution through system for two minutes. 2. Pump clean hot tap water,through system for two minutes or until clear, whichever is longer. ' 3. Pump analyte-free water through system for two minutes. 4. Seal tubing ends; wrap and label with date of cleaning. ' 4 Soils When collecting and screening soil samples, the procedures to be used are: ' 1. Prior to sampling surficial locations,surface vegetation,rocks,leaves,and debris will be cleared from the sample point to allow collection of a clean soil sample. If ' surficial soil samples are to be collected, a hand trowel or shovel and spatula will be used. The sampling equipment will be decontaminated as outlined below. ' 2. Boring samples will be collected via drilling rig-operated split spoon procedures. Soil samples collected from excavations or test pits will be collected directly with an ' auger (if necessary) from grade to approximately four feet below grade. Samples collected at deeper depths will be obtained directly from the bucket of the backhoe. A stainless steel spatula will be used to remove soil from the backhoe bucket for ' placement in the appropriate sample containers. 3. Soil samples collected for TOV screening will be placed in glass soil jars with ' aluminum foil placed,under the screw cap. Samples will be allowed to warm to ambient temperature before screening or will be screened in a heated vehicle after warming. The jar will be shaken for fifteen seconds prior to warming and after ' warming to ensure proper headspace development. Total organic vapors will be measured via a portable photoionization detector (PID) and their concentration recorded either on a Geological Borehole Log or field log., ' 4. Soil e o samples will be stored and shipped in appropriate sealed containers. ' 5. Sample containers will be marked to indicate sampling date, time, location, and depth. Samples will be logged in on chain-of-custody forms (copy,attached). ' 6. The stratigraphy of each soil boring and test pit excavation,and the construction of each monitoring well will be recorded by the on-site geologist on the appropriate ' Geologic Borehole Log or test pit field log (copies attached). When sampling soils for volatile compounds, care must be exercised to prevent loss of compound ' and to control susceptibility to outside contamination. Precautionary measures include: 1. avoiding engine exhaust,gasoline containers,degreasing solvents,solvent-laden rags ' and non-compatible decontamination agents; 2. opening sampling bottles only at the time of sampling and quickly closing after ' collecting the sample; ' 3. placing samples on ice (approximately 4° Q immediately after collection in a dark, dry location; 1 5 1 4. segregating samples with a secondary barrier such as zip-lock bags, etc.; and ' 5. analyzing sample as soon as possible within the specific holding times after collection. ' Soil sampling equipment (shovel, auger, etc.) will be decontaminated between each sampling location with a potable water rinse, alconox soap wash, and a final potable water rinse. 1 Drilling and excavating apparatus (augers, rods, casing, core barrels, backhoe bucket, and other equipment coming in contact with the borehole or excavation)will be decontaminated between each boring and excavation via steam cleaning. If necessary, an alconox soap wash followed by a steam cleaning will be included. ' Sample Preservation To prevent or the degradation/modification of chemicals in samples during transit and storage, ' the samples will be refrigerated at or below 4° C in appropriately preserved containers. Samples will.be delivered to the laboratory by courier or by overnight delivery service. DATA MANAGEMENT Logging of Samples i The accountability of a sample begins when the sample is taken from its natural environment. Sample handling (chain-of-custody) records must be completed at the time of sampling. The ' following chain-of-custody procedure must be implemented by the Field Team Leader to assure sample integrity. 1. The samples are under custody of the Field Team Leader if.,. ' a. they are in his (or her) possession; b. they are in view after being in possession: c.they are locked up or sealed securely to prevent tampering; or, ' d. they are in a designated secure area. 2. The"original of the sample handling form must accompany the samples at all times ' after collection. A copy of the sample handling form is kept by the Field Team Leader. ' 3. When samples are transferred in possession, the individuals relinquishing and receiving will sign, date, and note the time on the form. 6 1 The Sampling Handling Record will contain information to distinguish each sample from any other sample. This information will include: 1. the project for which sampling is being conducted; ' — the matrix being samples (air, groundwater,,soil etc.); 3. the sampling date and time; 4. field sample identification number and chain-of-custody identification number; 5. trie number and type of containers and the type of preservative used (if any); and, 6. signature of the person performing the sampling. 1 Each sample will be assigned a unique identification number, which.will be marked on the sample container. The sample handling record will be forwarded to the laboratory with the samples. Asa precaution against this record being lost or altered. the sampling personnel will retain a copy of the 1 sampling handling record documenting all information up until the first change of sample custody. This record will be filed by the Project Manager. 1 Sample Identification Numbers Reporting of date to the data management system will require the assignment of a unique identification number to each sample collected (including quality control samples). A record will be maintained by the Project Manager to associate the field sample with the various identification numbers used to analyze the field sample. Specific sample identification procedures are developed 1 for each field sampling effort by the Project Manager. I i 1 i 1 1 1 1 1 � FORM SAMPLES ' 1573 Main Street, P.O. Box 1667 BENNETT & O'REILLY, Inc. Brewster, MA 02631 Englneenng and Environmental Services (508) 896-6630 MONITOR WELL SAMPLING LOG CLIENT DATE(S) LOCATION JOB # MEASURING POINT SAMPLER GROUNDSURFACE OR T.O.C. Well Elev.%of Total Depth to Standing Water Static Volume HNU Comments Number reference Depth of Water Water Table Volume Purged PI-101 point Well (Feet) Height Elevation (gallons) (gallons) (ppm) (feet) (feet) (feet) (feet) ' NOTES: ' 1573 Main Street P.O. Box 1667 BENNETT & 01REILLY, Inc. Brewster, MA 02631 Engineering and Environmental Services (508) 896-6630 1 MONITOR WELL SAMPLING LOG ' RESPIRATION ANALYSIS CLIENT DATE(S) I ' LOCATION JOB # SAMPLER Well Total Approx. Standing Leng[h of HNU N1c[hane Oxceen Carbon COmm.'niS: Number Depth 6t Depth to Water scree❑ PI-101 (0 CH,) (0,0 0:1 Dioxide Well Water Height above (ppm) (°oCO:, (tee:) (tee[) (feet) SWL I ' NOTES: 1 BENNETT & O'REILLY, Inc. Sheet of 1573 Main Street 508-896-6630 1 PO Box 1667 508-896-4687 Fax Brewster, MA 02631 Job Number: Date: Time: Test Hole Number: ' Job Name: Witness: ' Casing I. D. Ground Elevation: Reference Elevation (TOC): Falling Head ❑ Rising Head ❑ 1 Aquifer Saturation Thickness (If Confined): Depth of Boring (A): Well Screen Length (L): Length of Test Section(L): 1 Depth of Groundwater Table (H): Depth of Top of Test Section (B): Type of Material in Test Zone: 1 Notes: 1 2r TIME ELA PSED WATER ACTNE �{ (sec.) TIME (sec.) h/Ho DEPTH(x) HEAD(h) 1 T X 1 H B STATIC '77 ... 1 A 1 L —I 2R h = H-X (failing head) or 1 h =X-H (rising head) Ho = H-Xo (failing head) 1 or Ho =Xo-H (rising head) ' Xo =X at t=0 1 A, B, H &L are defined above. 1 � � f♦ � � � � i♦ f♦ f♦ f♦ � � f♦ f♦ � f♦ f♦ f♦ Job Nam Job NUM er. Date: Location: Weather: Witness: Start Date: Pump & low Rate ----- ------- Location: TOC: Location: TOC: Location: TOC: NOTES: Time Time Depth to Water Static Water Lv. Draw Doom Depth to Water Static Water Lv D,aw Dann Depth to Water stallc Water Lv D,aw Down pH /Cond./Temp. (sec). 0 ---. ...--- 1 — - - ------ 3 - - -. 4 -- --- - --- _ 5 - - -- - --- - - - - - 6 - - ------ - ---- 7 t3 - -- --- -- ....... 15 - -- - - ---- --30 -- ------ --- - - -- - - - - (sec.) 45 ---- ---- (min) 1 --- ----------- - ----- -2 4 — -- - - - -... --- -- 6 -- - --- 10 — — -- - 20 30 40 - --- -- 50 -- 60 - 70 80 - - -- --- - -- 100 190 280 460 550 640 _ 730 820 910 ' BENNETT & UREILLY, Inc. Sheet of 1573 Main Street 508-896-6630 ' PO Box 1667 508-896-4687 Fax Brewster, MA 02631 Sieve Analysis Data and Computation Sheet Job Number: Date: ' Job Name: Sample Number: i ' Sample Collected By: Sample Tested Bv: ' Notes SIEVE WEIGHT PERCENT CUMULATIVE PROJECT OPENING SIEVE RETAINED RETAINED PERCENT MANUAL ' MILLI- MESH IN GRAMS (Cumulative) FINER SPECIFICATION METERS (Cumulative) ' PASSED MESH SIEVE TOTAL ' Sample Weight Wet: Sample Weight Dry: ' Percent Moisture: ' Sample Weight Passed Through Sieves: ' BENNETT & O'REILLY, Inc. Sheet of 1573 Main Street 508-896-6630 PO Box 1667 508-896-4687 Fax ' Brewster, MA 02631 Job Number: Date: ' Job Name: SAND GRAVEL SILT SAND Test Hole Number: Witness: ' Drilling Contractor: PEAT CLAY Sampling Method: GEOLOGIC BOREHOLE LOG ' Type �rnWell Lithology/Sediment or, Blows per °'a of Litholoev Depth Depth Specification& Remarks Description Sample 6" Drive Recovery PID Response (ppm) 10 15 20 25 ' SWL: 30 35 ' 40 ' 45 ' ' S0 B]ENNETT & ®'IXILLY, Inc. REPORT NUMBER: ' 1573 Main Street 508-896-6630 PO Box 1667 508-896-4687 Fax ' Brewster, MA 02631 INSPECTORS DAILY RECORD OF WORK PROGRESS Job Number: Date: Job Name: Feature: Contractor: Type of Work: I ' Weather Conditions: Temperature: Contractor's Work Force(Indicate classification. including Subcontractor personnel) Equipment in use or idled (identify which) i Materials or equipment delivered. quantity or pay items placed ' Non-conforming materials or work. field problems. inspections of previously reported deficiencies ' Summary of construction activities t 1.• IIIIIIIIIIII■ �■ �■■ �■ w■ w w w w w w w w w� w w 228 Main Street,P.O.Box 1200 GROUNDWATER Buzzards Bay,MA02532 CHAIN-OF-CUSTODY RECORD NO- O49R25 ANALYTICAL Telephone(508)759-4441 AND WORK ORDER FAX(508)759-4475 Project Name: Firm: TURNAROUND ANALYSIS REQUEST vouwn s.r�drmnlle. Pa.lAlerE/PWat❑ STANDARD(10 Business Days) Maal. Pmal.v 1 ar.ur0ea 11u. General Wkeml.by Whir Ftln[a ola—o W..ta Project Number. Address: ❑ PRIORITY(5 Business Days) - @ e ❑ RUSH(RAN- ) (Rust)requires Rush Awhonzabon Number) ❑ n n n 8 3' ❑ ❑ Sampler Name: City/Stale Zip: � Please FAX ❑ YES ❑ NO _ FAX Number: ry 5 O Project Manager: Telephone: BILLING n ❑ n n n n n o z ❑Purchase Older 1 - Pro,: GWA Helerenco No.: ❑ y f y O 3 S INSTRUCTIONS:Use separate line for each container(except replicates). t � ; � .� � E, 2 � o a Sampling Matrix Type Conlalner(s) Preservation 1`1111110 nnn ❑ ❑ n n n n n n ❑ � 0 5 � ❑ - � g O o s AMPLE LABORATORY S W - d ❑ H 4 - - 3 n ❑ a aa NUMBER � � � W � � � .Y m � � ❑ g 8 u� „ � - � Lit IDENTIFICATION 0 a 5 a � � (fah Use Only) o o e _ Allw y $ -- _ n n n n n n n n ra n n n n n ❑ nnn ❑ 6 ❑ ❑ 0 ❑ ❑ 00000001710 ——— —— —— ��— ----H----------- --- ------------ -- - ------ --------- -------------- ------------------ --- ---------- -- ---- ------------ REMARKS/SPECIAL INSTRUCTIONS DATA QUALITY OBJECTIVES CHAIN-OF-CUSTODY RECORD Regulatory Program Project Specific OC NO1 E:All samples submilled subject to Standard Terms and Conditions on reverse hereol. ❑Sale Drinking Water Act Many regulatory programs and EPA methods require project Relinquished by Sampler: Dale Time Received by: Receipt Temperature: ❑MA DEP Form specific OC.Project specific OC includes Sample Duplicates. ❑NPDES/Clean Water Act Matrix Spikes,and/or Malnx Spike Duplicates Laboratory OC is Specify State: not project specific unless prearranged Projecl specific OC ❑RCRA/Haz.Waste Char. samo(es are charged on a per sample basis.For water samples. Relinquisher)by: Dale Tirne Received by: Shipping/Airbill O MA MCP(310 CMR 40) each MS,MSD and Sample Duplicate requires an additional I Number: Reportable Concentrations sample�aliquol. ❑RCGW-1 ❑RCS-1 Prolecl Speclllc OC Required Setecllon or QC Sample Relinquished by: Dale Time Received by Laboratory: Custody Seal/ ❑RCGW-2 ❑RCS-2 Cooler Serial CI Sample Oupliwle I.1 Snlecled by lauorawry i ❑MA Dredge Disposal nNumber: Matrix sp.),. ra sa e I l Please is. mple ❑NH0 RI ❑ME p Mulhod of Shipment. I]GWA Cdu (]ner Express Mail CI Federal Express Specify Category: ry: Malri.Spike Dupecale - - -"---"-"_�""--""_--"- ❑UPS CI Band I ENVIROTECH , INC. 449 RCUTE 130 SANDWICH, M& 02563 PFENE: (508)888--6460 FAX: (508)888-644b ' WATER ANALYSIS REQUISITION: DATE: DATE REC. 'D: SAMPLE NO. : TIME: NO. COPIES— NAME: RUSH-24ER. TURNAROUND (e_x.chg.) MAIL: ' PHONE: FAX: WATER LOCATION: MAILING ADDRESS: PAYMENT/AMT. REC'D. : SAITLED BY: BILL TO/A.MI'. : WELL SPECS. : S ANALYSIS REQUEST: WATER SAMPLE TYPE: ' _COLIFORM BACTERIA * _FHA-HUD/VA, _pH * _NEW WELL _CONDUCTANCE * EXISTING WELL ' _SODIUM * TOWN WATER NITRATE-N * _FILTE<R/CONDITIONER IRON *' MA _MISCELLANEOUS—MANGANESE HARDNESS _POOL _SPA CHOLORINE _SULFATE _POTASSIUM COLIFORM BACTERIA ' ALKALINITY PSEUDOMONAS _CHLORIDE STANDARD"PLATE COUNT _TURBIDIT'Y ' _COLOR _COPPER OTHER ANALYSIS REQUESTED: _LEAD ODOR FECAL COLIFORM _AMMONIA-N _VOLATILE ORGANICS _SULFIDE METHOD: _MAGNESIUM _METALS ' CALCIUM METHOD: * INDICATES PARAMETERS, FOR A POTABLE WATER TEST. INSTRUCTIONS: BACTERIA SAMPLE - Obtain sterile sample bottle. Remove strainer/airator from faucet. Turn on cold water. Allow it to run (5) five minutes. Fill container. Do not touch the inside of the bottle or the cap with amthinct. . � POTABLE WATER SAMPLE - Follow instructions above. (Bottle size - 500ml) LEAD - Call lab for instructions. VOLATILE ORGANICS/METALS - Call lab for instructions. :Arl A,.rl.r�..l• l fol 1.,�,.�oll .,rll ►1rC1 jw...i...ftTl t-Aq f"'rl^buflfll 1, 1 0 lunl..t :Act F,#4pjn1w11v1[ ,> ..r.._,.T, •Ail I.,�,.ri.l.uil'll .ar...f'f) �A'1 f.„1a�.11 •ur11 � . �SI �>,..,�..�.5/ :A.j jra.lr,fll •urlj „r(I -----'------------------------ --------------�- -- (.. i ..fl :lrl l.a.la�fll •wll •l�(1 I..+I. -SJ :Aq (.►'I�Iht�ul[�11 ------------- - •LL/11 fit.(1 •�I' I�alsallhaZl sIs ( �I"I IV to I(1 ;;(ICI p ItlefA u, �u 1 I r..,,l•.,.rr) �t,lafL.y (v iu ►.u.lr t�a�(d o►� Fa 111r(t:t.11l �Ilutsrl:j JU rllvll;j 0C99-96P ( 900 /,(IIil milloloy) XV,!I JtI]- ` I)"1^1I 1n 0 '8 J_L�'INN_It1 14 o 2 1 091 ) 01:1: 0MI I • M I ) imif (UU(J) [:!)�1•c;U VlV '�I��In�i,llu� UI:I •°I!1 (ihl' ';)N I ';►I L"�_I OlIIN/ � I (_)I�.I V` I 1 I7.J.LC)21.1 n �I C 1 1 1 1 � 1 � TECHNICAL aLrcacNce i � I il Eke)vi 14*41M7M Ji I i fil I 1:�;71�;1::�I=;M-, Volatile Organic Analyses Minimum Recommended Required Holding Category Methods Oty.' Container(s)2 Preservation Time' ' Aqueous Samples Volatile Organics 601/8010 40 mL 3 x 40 mL Glass Cool to 4°C' 14 Days 602/8020 Vials w/teflon HCI to pH <24 624/8260 septum caosl2 Remove Chlorine' ' 5 .2 52424.2 Acrolein and Acrylonitnle 603/8030 40 mL 3 x 40 mL Glass Cool to 4°C' 14 Days Vials w/teflon Check pH;Adjust 4-51 ' septum caps12 Remove Chlorine' Solid Samples Volatile Organics 8010/8020 log 1 x 125 mL Glass Cool to 4°C' 14 Days 8260 Vial w/teflon ' septum cap" OA 2 x 40 mL Glass Vials w/teflcn ' seotum cabs .2 " 4crolein and Acrylonitrile 8030 10 g 1 x 125 mL Glass Cool to 4°C' 14 Days Vial w/teflon septum cap" ' OR 2 x 40 mL Glass Vials w/teflon septum cans '2 " ' Semivolatile Organic Analyses �I Minimum Recommended Required Holding Category Methods Oty.' Container(s)2 Preservation Time' Aqueous Samples Semivolatile Organics 625/8270 1 L 2 x 1 L Amber Cool to 41C3 7 Days' Glass Bottle Remove Chlonne' witeflon liner" ' Semivolatile Organics 8270 2 L 3 x 1 L Amber Cool to 4°C' 7 Days' (Low-level.both Acid Modified Glass Bottle Remove Chlorine' and Base/Neutral fractions) witeflon liner" Semivolatile Organics 8270 1 L 2 x 1 L Amber Cool to 4°C' 7 Days' (Low-level,only one fraction Modified Glass Bottle Remove Chlorine' Acid or Base/Neutral) w/teflon liner" Semivolatile Organics 525.2 1 L 2 x 1 L Amber Cool.t6 4°C' 7 Days25 (Drinking Water) Glass Bottle HCI to pH<24 ' w/teflon liner" Add Sodium Sulfite24 2,3,7,8-TCDD(Dioxin) 1613 1 L 2 x 1 L Amber Cool to 4°C' 7 Days' (Drinking Water) Glass Bottle w/teflon liner" ' Polynuclear 610/8100 1 L 2 xi L Amber Cool to 4°CO 7 Days' Aromatic 8270 Glass Bottle Remove Chlorine' Hydrocarbons w/teflon liner" Solid Samples ' Semivolatile 8270 30 g Glass Jar Cool to 4°C' 14 Daysi0 Organics w/teflon liner" Polynuclear 8100 30 g Glass Jar Cool to 4°C' 14 Days10 Aromatic 8270 w/teflon liner" ' Hydrocarbons ' GROUNDWATER ANALYTICAL 27 ' Pesticide and Herbicide Analyses Minimum Recommended Required Holding Category Methods Qty., Container(s)l Preservation Time. Aqueous Samples Carbamate Pesticides 531.1 60mL 2 x 125 Glass Bottle Cool to 41C3 28 Days (Drinking Water) w/teflon liner" Add Sodium Thiosuffatezb Adjust pH to 3 with Monochloroacetic Acid Buffer ' Organochforine 608/8080 1 L 2 x 1 L Amber Cool to 4°C3 7 Days' Pesticides&PCBs Glass Bottle Check pH:Adjust 5-96 witeflon liner!, Remove Chlorine? ' Oroanochlorine Pesticides 508 1 L 2 x 1 L Amber Cool to 41C3 7 Dayszt &PCBs Glass Bottle Add Sodium Thiosulfatezo (Drinking Water) witeflon liner'- Polychlorinated Biphenyls 508A 1 L 2 x 1 L Amber Cool to 4°C3 4 Days 12 ' by Perchlorination Glass Bottle (Drinkino Water) witeflon liner Organchaiice Pesticides 305 40 mL 3 x 40 mL Glass Vials Cool to 4-C- 7 Cays' & FCBs w.,teilon septa caps Add Sodium T hicsulfatez6 ' (Drinkino Water) Oroanopncspncrus 614;8140 1 L 2 x t L Amoer Cool 10 4°C3 7 Days Pesticides Glass Bottle Check pH:Adjust 5-86 w/teflon liner Remove Chlcrine7 ' Chlorinated 615/8150 1 L 2 x 1 L Amber Cool to 4`C3 7 Days' Herbicides Glass Bottle Remove Chlorine' w/teflon liner Chlorinated Heroic ces 515.11 i L 2 x 1 L Amber Cool to 4°C3 14 Days r ' (Drinkino Water) Glass Bottle Add Sodium witeflon liner- Thiosulfatez6 Glyphosate 547 40 mL 2 x 40 mL Glass Cool to 4°C3 14 Days (Drinking Water) Vial witeflon liner Add Sodium ' Thiosulfatezo Endothall 548.1 100 mL 2 x 125 mL Glass Cool to 4°C3 7 Days 21 (Drinking Water) Bottle witeflon liner', HCI to off <2' Add Sodium ThicsulfateL6 ' Diquat and Paraquat 3119.1 250 mL 1 x 1 L Amoer Cool to 4°C3 7 Days27 (Drinking Water) Glass Bottle H_SO,to pH <2° witeflon liner 1 ! Add Sodium Thiosulfatez6 EDB and.DBCP 504.1 40 mL 3 x 40 mL Glass Cool to 4°C3 14 Days (Drinking Water) Vials w/teflon Add Sodium Thiosulfatez6 septa caps EDB ano DBCP 8011 40 mL 3 x 40 mL Glass Cool to 4t3. 14 Days Vials w/teflon HCI to pH <24 septa caps 'z " Remove Chlorine? Solid Samples Orgarochlorine 8080 30 g Glass Jar Cool to 4°C3 14 Days10 Pesticides&PCBs w/teflon liner'? ' Organophosphorus 8140 30 g Glass Jar Cool to 4°C3 14 DaysiO Pesticides w/teflon liner" Herbicides 8150 30 g Glass Jar Cool to 4°C3 14 Days" w/teflon liner17 ' EDB and DBCP 8260 log 1 x 125 mL Glass Cool to 4°C3 14 Days Vial w/teflon septa cap 12.17 ' �R2x40mLGlass Vials w/teflon septa caps iZ 13.17 28 ' Hydrocarbon Analyses Minimum Recommended Required Holding Cagegory Methods Qty.' Container(s)2 Preservation Time' ' Aqueous Samples Hydrocarbon D3328-78 1 L 2 x 1LAmber Cool to 4°C3 7 Days' Fingerprint Glass Bottle H2SO,to pH <2 (GC/FID) w/tenon liner" ' Total Petroleum 418.1 1 L 2 x 1 L Amber Cool to 4°C3 28 Days Hydrocarbons Class Bottle H2SO,to pH <2 (—PH-IR) witeflon liner Cil and Grease 413.1 1 L 2 x 1 L Amber Cool to 4°C3 28 Days 413.2 Glass Bottle H2S0,to pH <2 w/teflon liner Gasoline Range 8015iAP1 40 rrL 3 x 40 mL Glass Cool to 4°C3 14 Days Organics Vials witeflon HCl to pH <2' septa cans 2 D esel Rance 8100/API 1 L 2 x 1 L Amber Cool to 11C3 7 Days3 0-canics Glass Bottle H-SO.to pH <2 witeflon liner`- ' MA DER Volatile 8015,MA DEP a0mL 3 x e0 mL Glass Cool to 4°C' 14 Days Petroleum Hydro- Viais witeflon PC;or H,SO,to pH<2' carbons (VPH) Septa Caps" MA DER Extrac;aole 8100/MA DER 2 L 3 x 1LAmber Cool to 4°C3 14 Days ' Petroleum Hydrocarbons(EPH) 8270 Mod Glass Bottle H--SO,or HCI to pH<2- wih low-level PAHs (GCWS-Sw) witeflon liner" Solid Samples Hycrocarbon D3328-78 300 Glass Jar Cool to 4°C3 14 Days" ' Fincerprint Modified wrteflon liner (GCiFID) Total Petroleum a18.1 30 c Glass Jar Cool toA'C3 1.1 Days" Hydrocarbons Modified wrteflon liner ' (TPH-IR) Oil and Grease 413.1 30 c Glass Jar Cool to 4°C' 1 .1 Days' 413.2 witeflon liner Modified t Gasoline Range 8015iAPI 100 1 x 125 mL Glass Cool to-11C3 14 Days Organics Vial wrtetlon .i septa cap iz ' Diesel Range 8100/API 30 g Class Jar Cool to 4=C3.- 14 DaysiO Oreanics witeflon liner' MA DER Volatile Petroleum 8015iMA DER 50g 1 x 125 mL Glass w/50ml- Cool to 4°C3 14 Days ' Hydrocarbons(VPH) Methanol and Glass Jar without Methanol. MA DER Extractable 8100/MA DEP 30g Glass Jar Cool to 4°C' 14 Days ' Petroleum Hydrocarbons(EPH) w/teflon liner" Metals Analyses Minimum Recommended Required Holding Category Methods oty.' Container(s)2 Preservation Time' Agceous Samples Total Metals 200s 100 mL Plastic Bottle HNO3 to pH<2 180 Days (except Mercury) 6010 Cool to 4°C' 7000s Dissolved-Metals 200s 100 mL Plastic Bottle Filter First" 180 Days (except Mercury) 6010 HNO3 to pH<2 ' 7000s Cool to 4°C' Total Mercury 245.1 100 mL Plastic Bottle HNO3 to pH <2 28 Days 7470 Cool to 4'C3 ' GROUNDWATER ANALYTICAL 29 ' Metals Analyses Minimum Recommended Required Holding Time Category Methods City., Container(s)z Preservation a ' Dissolved Mercury 245.1 100 mL Plastic Bottle Filter First" 28 Days 7470 HNO3 to pH <2 Cool to 4°C3 SDWA Lead and 200.9 1 L 1 x 1 L Plastic Cool to 4°C' 180 Days ' Cexavalent opper Rule 200.7 Bottle hromium. 218.1-5 200 mL Plastic Bottle Cool to 4°C3 24 Hours Solid Samples Total Metals 6010 2 g Glass Jar Cool to 4°C3 180 Days (except Mercury) 7000s wrteilon liner Total Mercury 245.5 0.60 Glass Jar Cool to 4°C- 28 Days 7471 wrteilon liner ' Hazardous Waste Characterization Analyses Minimum Recommended Required Holding Category Methods Qty.' Container(s)= Preservation Time ' Solid Sampleste TCLP Volatile 1311 1500 2 x 125 mL Glass Cool to 4°C- 14 Days" Oroanics 8260 Vial wrteilon sectum cao'' TCLP Metals. 1311 300 d Glass Jar Cool to 4°C3 28 Days'° Semivolatiles. 6010 wrteilon liner 14 Days" Pesticiaes and 7000s Herbicides 8080 ' 8150 8270 lanitaoiiiry 1010 100g Plastic or Class Cool to ^ C' None Modified Jar CorrosTviry 9045 20 g Plastic cr Glass Jar Cool to a`.C' None Reacnvdv SW-846 20 g Plastic or Glas Jar'6 Cool to a`C' None Paint Filter 9095 1000 Plastic or Glass Jar None None ' Conventional Physical Properties Analyses Minimum Recommended, Required Holding Category Methods City.' Container(s)l i Preservation Time Aqueous Samples ' Color 110.1-3 50 mL Plastic or Glass Bottle Cool to 4°C' 48 Hours Conductance 120.1 100 mL Plastic or Glass Bottle Cool to 40C': 28 Days Hardness 130.1.2 100 mL Plastic or Glass Bottle Adjust pH'Q15 180 Days Cool.to 4°C' lip 1 Odor 140.1 200 mL Glass Bottle Only Cool to 4°C' 24 Hours pH 150.1 25 mL Plastic or Glass Bottle None Analyze Immediately Solids. Total 160.1 100 mL Plastic or Glass Bottle Cool to 4°C3 7 Days Dissolved(TDS) Solids,Total 160.2 100 mL Plastic or Glass Bottle Cool to 4°C' 7 Days Suspended(TSS) Solids,Total(TS) 160.3 100 mL Plastic or Glass Bottle Cool to 4°C3 7 Days Solids,Total 160.4 100 mL Plastic or Glass Bottle Cool to 4°C3 7 Days Volatile(TVS) Solids,Settleable 160.5 1 L— Plastic or Glass Bottle Cool to 4°C3 48 Hours ' (SS) Turbidity 180.1 100 mL Plastic or Glass Bottle Cool to 4°C3 48 Hours 30 i Conventional Inorganic Analyses Minimum Recommended Required Holding Category Methods Qty.' Container(s)2 Preservation Time' Aqueous Samples Aciditv 305.1 100 mL Plastic or Glass Bottle Cool to 4°C' 14 Days Alkalinity 310.1-2 100 mL Plastic or Glass Bottle Cool to 4°C3 14 Days Bromide 320.1 100 mL Plastic or Glass Bottle None 28 Days ' Chloride 325.1-3 50 mL Plastic or Glass Bottle None 28 Days Chlorine, 330.1-5 200 mL Plastic or Glass Bottle' None Analyze Total Residual Immediately ' - Cyanides 335.1-3 500 mL Plastic or Glass Bottle Remove Sulfide" 14 Days NaOH to pH>12 Cool to 4°C' Fluoride 340.1-3 300 mL Plastic Bottle Only None 28 Days ' - Iodide 345.1 100 mL Plastic or Glass Bottle Cool to 4°C' 24 Hours Nitrogen,Ammonia 350.1-3 400 mL Plastic or Glass Bottle H_SO to pH <2 28 Days Cool to 4°C' Nitrogen, 351.1 500 mL Elastic or Glass Bottle H,SO, to pH <2 28 Days Total Kjeldahl Cool to 4°C' Nitrogen, 353.1-3 100 mL Plastic or Glass Bottle H,SO to pH<2 28 Days Nitrate plus Nitrite Cool to 4°C' Nitrogen. 353.2-3 100 mL Plastic or Glass Bottle Cool to 4°C' 48 Hours Nitrate(Wastewater) Nitrogen, Nitrate ' 353.2-3 100 mL Plastic or Glass Bottle Cool to 4°C' 28 Days (Chlorinated Drinking Water) ' Nitrogen, Nitrate 3532.3 100 mL Plastic or Glass Bottle Cool to 4°C' 14 Days (Non-Chlorinated Drinking Water) H,SO, to pH <2' Nitrogen, 353.2-3 50 mL Plastic or Glass Bottle Cool to 4°C' 48 Hours Nitrite Category Minimum Recommended Required Holding 9 y Methods Qty.1 Container(s)2Preservation Time' Aqueous Samples Orthophosphate 365.1-3 50 mL Glass Bottle Only Filter(0.45 um) '8 Hours ' Cool to 4°C' Oxygen, Dissolved 360.1 300 mL Glass Bottle Only None Analyze Immediately Phosphorous,Total 365.1-4 50 mL Glass Bottle Only H2SO, to pH <2 28 Days Cool to 4°C' Silica 370.1 50 mL Plastic Bottle Only Cool to 4,°C' 28 Days Sulfate 375.1-4 50 mL Plastic or Glass Bottle Cool to 4°C' 28 Days ' Sulfide 376.1-2 500 mL Plastic or Glass Bottle NaOH to pH>9 7 Days 2 mL Zinc Acetate Cool to 4°C' Sulfite 377.1 50 mL Plastic or Glass Bottle None Analyze Immediately Conventional Organic Analyses Category Minimum Recommended Required Holding 9 ry Methods Qty.1 Container(S)2 Preservation Time' ' Aqueous Samples Biochemical 405.1 1 L Plastic or Glass Bottle Cool to 4°C' 48 Hours Oxygen Demand (5 Day BOO) I� Chemical 410.1-4 50 mL Plastic or Glass Bottle HZSO,to pH<2 28 Days Oxygen Demand Cool to 4°C' (COD) GROUNDWATER ANALYTICAL 31 Conventional Organic analyses Minimum Recommended Required Holding Category Methods oty.' Container(s)2 Preservation Time' ' Aqueous Samples Organic Carbon, 415.1 25 mL Plastic or Glass Bottle H,SO,to pH<2 28 Days Total(TOC) Cool to 4°C' Phenolics 420.1-3 500 mL Glass Bottle Only H2SO,to pH <2 28 Days Cool to 4°C' ' Surfactants 425.1 250 mL Plastic or Glass Bottle Cool to 4°C' 48 Hours (MBAS) Microbiological Analyses ' Minimum Recommended Required Holding Category Methods Qty.' Container(s)2 Preservation Time' Aqueous Samples Coliform, Various 100 mL Sterilized Bottle Cool to 4°C' 6 Hours Total(Wastewater) Remove Chlorine' Coliform, Various 100 mL Sterilized Bottle Cool to 4°C' 6 Hours Fecal (Wastewater) Remove Chlorine' Coliform, Various 100 mL Sterilized Bottle Cool to 4°C' 30 Hours 1 Total(Drinking Water) Remove Chlorine' Coliform. Various 100 mL Sterilized Bottle Cool to 4°C' 30 Hours Fecal (Drinking Water) Remove Chlorine' ' B.Coli Various 100 mL Sterilized Bottle Cool to 4°C' 30 Hours (Drinking Water) Remove Chlorine' Radiological Analyses ' Minimum Recommended Required Holding Category Methods aty.' Container(s)2 Preservation Time`_. Gross Alpha and Beta 900.0 1 L Plastic or Glass Bottle HCI or HNO,to pH<2 180 Days Radium-225 903.1 1 L Plastic or Glass Bottle HCl or HNO,to pH <2 180 Days ' Radium-228 904.0 1 L Plastic or Glass Bottle HCI or HNO, to pH <2 180 Days Strontium-90 905.0 1 L Plastic or Glass Bottle HCl or HNO,to pH <2 180 Days Tritium 906.0 1 L Glass Bottle None 180 Days 1 i ' 1 1 ' 32 ' SAMPLING NOTES 1. The minimum quantity specified is the minimum amount of sample material the vial.The cap should then be gently placed on the vial,taking care not to ' necessary to perform the analysis.This quantity allows for no margin of disturb the crown of liquid. and firmly rotated tight.The vial should then be error. examined to verify the absence of all air bubbles. For some analyses,Groundwater Analytical recommends specific types and Solid samples for Volatile Organic Analyses (VOA) must also be collected numbers of containers(e.g.,an Aqueous Volatile Organic sample requires 3 with a minimum of headspace or air pockets.Sample vials should be packed _ x 40 mL Glass Vials w/teflon septum caps).In such cases,the recommended fully and tightly sealed.Vial threads should be wiped clean prior to capping container(s)allow for an adequate margin of error. for best seat.When packing vials,however,avoid excessive manipulation of the sample material which may result in a loss of volatile organics.A wide For other analyses,Groundwater Analytical only recommends a aeneral type mouth 125 mL Glass Vial w/teflon septum cap is the preferred sample con- of container(e.g.,a Solid Semivolatile Organic sample requires a Glass Jar tainer. w/teflon liner).In such cases,it is strongly recommended that twice the mini- ' mum quantity of sample material be collected in the recommended type of 13. Solid samples for Volatile Organic Analyses may be collected in 40 mL Glass container. Vials that have been acidified with Sodium Bisulfate(NaHSO),Hydrochloric Acid(HCI)or Sulfuric Acid(H,SO,).The presence of acid in the container will For solid samples, in addition to the minimum quantities required for indi- have no detrimental effect on the sample. vidual analyses, each sample also reauires 20 g of sample material for a ' percent solids(or percent moisture)determination.Example:A soil sample 14. Maximum holding time is 24 hours when Sulfide is present.Samples may be collected for TPH-IR(30 g),8 RCRA Metals(2.6 g)and PCSs(30 a)requires tested with lead acetate paper before the pH adjustment in order to deter- a minimum of 62.6 g of material for the desired analyses.ano 20 g of material mine if Sulfide is present.If Sulfide is present.it can be removed by the addi- for percent solids(or percent moisture),for a total required minimum of 82.5 tion of Cadmium Nitrate powder until a negative spot test is obtained.The g of material.It is then recommended that this minimum by doubled,and at sample is then filtered.and NaOH is added to adjust the pH>12. ' least 165.2 g of sample material be collected in a Glass Jar w/teflon liner. 15. Adjust to pH<2 with Nitric Acid(HNO,)or Sulfuric Acid(H=SOJ.Acidification For solid samples. all minimum quantities are calculated net of all foreign retards biological action,reduces absorption effects and prevents the forma- objects,such as sticks,leaves and rocks. lion of precipitates and/or complexes. 2. Only sample containers pre-cleaned according to US EPA protocols are rec. 16. Samples should be collected with a minimum of aeration.The sample bottle ommended.Appropriate pre-cleaned and pre-preserved containers are avail- should be filled completely,excluding all headspace,and capped. able from Groundwater Analytical.Pre-cleaned sample containers should not be prennsed with sample prior to sample collection. Prennsing may cause 17. Extractable organic samples are susceptible to Phthalate ester contamina- elevated results. tion. Phthalate ester contamination is generally caused by sample contact With a plastic material,particularly flexible plastics.Use care to avoid sample 3. Samples should be immediately cooled,stored and shipped refrigerated.4°C contact with any plastic,other than Teflon. (34°�is the recommended temperature.Refrigeration retards biological deg- radation,reduces the volatility of compounds,retards the hydrolysis of non- 18. Specified quantities of sample material are for only single phase solid samples aqueous compounds. reduces absorption effects and prevents continuing (i.e.no free liquids).liquid phase or multiple phase samples require different chemical reactions. quantities of sample material.Contact laboratory for advice prior to collecting 4. Adjust to pH<2 with Hydrochloric Acid(HCI).Acidification retards biological liquid phase or multiple phase samples for TCLP analyses. I action.reduces absorption effects and prevents the formation of precioitates 19. Samples for TCLP Volatile Organics analysis must be leached within 14 days and/or complexes.Sulfuric Acid(H,SO,)or Sodium Bisulfate(NaHSO,)may of collection.The leachate must then be analyzed within 14 days of leaching. be substituted for HCI in EPA Methods 8010,8011.8020 and 8260. ' Samples for TCLP Metals analysis must be leached within 28 days of collet- 5. Adjust to a pH range of 4.0 to 5.0 with Hydrochloric Acid(HCI),Sulfuric Acid Lion,if Mercury is being analyzed.The leachate must then be analyzed within (H,SO-,)or Sodium Hydroxide(NaOH). 28 days of leaching.If Mercury is not being analyzed.then samples for TCLP Metals must be leached within 180 days of collection,and the leachate ana- 6. If sample will not be received by laboratory within 24 hours of collection,then lyzed within 180 days of leaching. adjust to specified pH range with Sulfuric Acid(H,SO,)or Sodium Hydroxide (NaOH).The pH adjustment may be omitted if it is performed upon receipt at Samples for TCLP Semivolatile Organics,TCLP Pesticides,and TCLP Her- the laboratory within 24 hours,and may be omitted if the sample is extracted bicides analyses must be leached within 14 days of collection.The leachate within 48 hours of collection. must then be extracted within 7 days of leaching.The extract must then be analyzed within 40 days of extraction. 7. If free chlorine is present in the sample, then Sodium Thiosulfate(Na,S,O,) ' should be added. Free chlorine can react with organic compounds to form 20. Samples must be an within 7 days of collection.However,if Heptachlor chlorination by-products. Free chlorine is likely to be found in chlorinated is not being determined,sample holding time to analysis may be extended to municipal drinking waters and treated wastewaters.Sodium Thiosulfate,a 14 days. reducing agent,is added to remove the free chlorine.For most levels of free chlorine.add 4 drops of 10%Sodium Thiosulfate to samples in 40 mL vials, 21. Samples must be extracted within 7 days of collection.Extracts must then be ' and add 5 mL of 10916 Sodium Thiosulfate to samples in 1 L Bottles. analyzed with 14 days of extraction. 8. The listed Holding Time is the maximum of time a sample may be held be- 22. Samples must be extracted within 14 days of collection. Extracts must then tween collection and initiation of analysis or extraction. be analyzed with 30 days of extraction. 9. Samples must be extracted within 7 days of collection.Extracts must then be 23. Samples must be extracted within 14 days of collection.Extracts must then analyzed within 40 days of extraction. be analyzed with 28 days of extraction. 10. 'Samples must be extracted within 14 days of collection.Extracts must then 24. Add 40-50 mg of Sodium Sulfite to each liter of sample to reduce free chlo- be analyzed within 40 days of extraction. I I rine that may be present.Free chlorine can react with organic compounds to 11. Samples for dissolved metals must be filtered prior to preservation with Nitric form chlorination by-products. Free chlorine is likely to be found in chlod- nated municipal drinking waters and treated wastewaters.Altematively,use Acid (HNO�. Filtration must be done with a 0.45 micron membrane filter. 40-50 mg of Sodium Arsenite.Do not use Sodium Thiosulfate,as it may pro- Field filtration and preservation is preferred. duce a residue of elemental sulfur which may interfere with the determination However,if field filtration is not possible,samples should be cooled to 4°C of some analytes. ' and shipped to the laboratory for filtration and preservation.Filtration must be 25. Samples must be extracted within 7 days of collection.Extracts must then be done as soon as practical after collection.Groundwater Analytical recom- analyzed with 30 days of extraction. mends that filtration be done within 24 hours of collection.If samples are not going to be field filtered,do not preserve samples with Nitric Acid(HNO,). 26. Add Sodium Thiosulfate to reduce free chlorine that may be present Free 12. Aqueous samples for Volatile Organic Analyses VOA must be collected with- chlorine can react with organic compounds to form chlorination by-products. r9 Y (VOA) Free chlorine is likely to be found in chlorinated municipal drinking waters. out any headspace or air bubbles.Volatile organics dissolved in water tend to Use approximately 80 mg of Sodium Thiosulfate per liter of sample. volatilize readily and will fill any air bubble available in the vial.Particularly with low level samples,this results in a loss of material upon opening the vial. 27. Samples must be extracted within 7 days of collection.Extracts must then be VOA vials must be filled slowly until the liquid forms a meniscus on the rim of analyzed with 21 days of extraction. GROUNDWATER ANALYTICAL 33 1 _ i 1 1 1 . 1 1 CON_".ONwE,j:H OF YASSAC USETTS 1 DE?P,RT`'-ENT 0: =NV=RON2'=VTOL ?RO =C:=ON 1 1 ST?NDA-RD Ry= RENC=S OR MONITORING WELLS 1 SECTION 1.2 T;LBL£. OF CONTENTS i i 1 1 ' Section 1.2 Page i January 1991 SECTION 1.2 TABLE OF CONTENTS 1.0 Introduction ' 1.1 Foreword 1.2 Table of Contents 1.3 Definitions ' 2.0 First Steps ' 2. 1 Reconnaissance Surveys 2 .2 work and Cost Plans (Reserved) 2.3 Health and Safety Plans 3 .0 subsurface IAvesrtigaticns 3 .1 EXplcratcrl Test Pits 3 .2 Drilling Techniques 3 .1 Bcrincs in Contaminated Areas 3 .4 In-Situ Sampling of Sci'_ 3.5 scil C lassificaticn ' 3 .6 In-Situ Sampling of Rock 3 .7 Rock C lassificat cn 3 .8 Laboratory Tess for Soil ' 3 .9 Plugging Bcreholes 4 .0 Piezcmeters, Obse_,raticn Wells and Monitoring wells ' 4 . 1 Mcnitcring well Netwcrk Design 4 .2 Selection cf Well Construction Materials 4 .3 Well Installation Procedures ' 4 .4 As-built Notes and Records 4.5 Well Development 4 .6 Decommissioning of Monitoring wells ' 5.0 Interpretation of Ground Water and Aquifer Characteristics 5 .1 Water Level Measurements 5.2 In-Situ Hydraulic conductivity Tests 5 .3 Pumping Tests 5 .4 Packer Tests 5.5 surveying and Datum Planes 6.0 Sampling of Monitoring wells ' 6 .1 Quality Assurance/Quality Control 6 .2 Sampling Techniques 6 .3 Sample Handling 6 .4 Chain of Custody 6 .5 Decontamination of Sampling Equipment Section 1.2 Page ii January 1991 Section 1.2 Table of Contents (continued) ' 7. .0 Computer Models (Reserved) 8.0 Geophysical Techniques (Reserved) I r BEN NETT & 01REILLY, INC. Engineering& Environmental Services LETTER OF 1573 Main Street,P.O.Box 1667 Brewster,MA 02631 TRANSMITTAL (508)896-6630 FAX(508) 896-4687 TO: DATE: JOB NUMBER: Ms.Laura Stanley,Compliance and Enforcement Branch Chief,SW July 14,2004 B002-3490 Mr.Gerard Martin,Chief SMPBWSC Massachusetts Department of Environmental Protection(MA DEP) Southeast Regional Office(SERO) REGARDING: 20 Riverside Drive Comprehensive Response Actions Lakeville,MA 02347 Hubbard Oil Co.,Inc. We are sending you: 33&51 Brooks Road-RTN 4-0824 Phase V: Remedy Operation Status Report#2 Hyannis,MA COPIES DATE DESCRIPTION 1 7/12/04 Phase V: Remedy Operation Status Report#2(bound report) Comprehensive Response Actions Transmittal Form-BWSC-108(original-DEP only) For review and comment: ❑ For approval: ❑ As requested:❑ For your use: REMARKS: cc.Hubbard Oil,Inc.-Attn:Evelyn Read,General Manager Attorney Robert Fasanella-RUBIN&RUDMAN,LLP L-ieutenant Hubler=-Hyannis-Fire-Department Thomas McKean=Barnstable Board ofHealthr John Klimm-Barnstable Town Manager David Condry-Barnstable Water Company John Robichaud,Abutter-Robie's Refrigeration �I From: John D.Tadema-Wielandt,ES H If enclosures are not as noted,kindly notify us at once REMEDIAL OPERATION PLAN STATUS REPORT II SUPPORTING DOCUMENTATION RTN 4-0824/4-15370 Hubbard Oil Co.,Inc. 33 & 51 Brooks Road [Assessors Map 328, Parcel 125 & 126] Hyannis,MA. 02601 Project#B002-3490 JULY 12, 2004 # 9 ADENNETT A KE I L LY Inc. N, Engineering, Environmental &. Surveying Services 1573 Main Street .,Sanitary 21E/Site Remediation Property Line PO Box 1667 Site Development Hydrogeologic Survey Subdivision A Brewster,MA 02631 Waste Water Treatment Water Quality Monitoring Land Court f-' 508-896-6630 Water Supply Licensed Site Professional Trial Court Witness 508-896-4687 Fax t BENNETTAUff 'o"REILLY, Inc. Eno,ineering, Environmental & Surveying Services ON 1573 Main Street Sanitary 21E/Site Remediation Property Line - PO Box 1667 Brewster,MA 02631 Sire Development Hydrogeologic Survey Subdivision Waste Water Treatment Water Quality Monitoring Land Court 508-896-6630 Water Supply Licensed Site Professional Trial Court Witness 508-896-4687 Fax B002-3490 July 12, 2004 Mr. Gerard Martin, Chief Sites Management&Permitting Section, BWSC MASSAC1 USETTS DEPARTMENT OF ENVIRONMENTAL PROTECTION(MA DEP) Southeast Regional Office(SERO) Bureau of Waste Site Cleanup (BWSC)/Sites Management Program(SMP) 20 Riverside Drive Lakeville,MA 02347 RE: REMEDY OPERATION STATUS REPORT II Hubbard Oil Company,Inc. -RTN 4-0824 [ACO-SE-02-3 S-0091 33 and 51 Brooks Road [Assessors Map 14, Parcel 25 and 26] Hyannis,MA 02532 Dear Mr. Martin: On behalf of our client,Hubbard Oil,Inc.,BENNETT&O'REILLY,INC.has prepared this Phase V Remedy Operation Status Report for the above referenced properties, consistent with the provisions of 310 CMR 40.0893. This document represents response actions conducted at the Site over the past six(6)months as limited to the environmental monitoring of down gradient monitoring wells in review of critical exposure pathways,pending substantive communications with the Town of Barnstable as requested by their counsel, Robert A. Fasanella on April 20, 2004. The work proposed within the Remedy Implementation Plan("RIP")has been delayed as a result of unresolved issues between the Hubbard Oil Company,Inc.,the Potentially Responsible Parry("PRP")and the Town of Barnstable on the announced eminent domain taking of the above-referenced property and the effect of such on the presented Remedy Implementation Plan for the selected Remedial Alternative. Over the past six months,no progress has been made regarding the towns proposed eminent domain taking of the subject properties. Counsel for the Town of Barnstable has still offered no definitive assurance of eminent domain property taking, time frame for proposed re-development of the property, or assurance of cooperation in planning to protect the operational integrity of the proposed remedial system. Furthermore,BENNETT&O'REILLY,INC.understands that the Town of Barnstable's Proj ect Manager in charge of the prof ect and eminent domain process,Joellen Daley, 1 I JULY 12,2004 HUBBARD OIL CO.,INC-BROOKS RDJ B002-3490 PAGE 2 OF 9 PHASE V REMEDY OPERATION STATUS REPORT II is no longer employed by the Town and a new Project Manager has yet to be appointed to manage issues and answer questions regarding the prospective owners input on the project. As such,the PRP has authorized continued environmental monitoring but suspended authorization for further equipment/supply purchases and construction activities associated with the RIP pending response from the Town of Barnstable to essential questions and concerns posed to the Town of Barnstable by letter of counsel to Hubbard Oil dated April 20, 2004. As such, no final "as built" plans or operation and monitoring information is provided in this filing. This-Remedy Operation Status H OPS resents the results of the ongoing Phase V environmental monitoring program in review � �p g g gp �' of critical exposure pathways. Such monitoring continues to demonstrate a discrete and static area of significant groundwater impact restricted to the subject property and the abutting down gradient railway as demonstrated with sentinel, multi-level monitoring wells further down gradient on the Robies Refrigeration property as intermediate to the Barnstable Water Company well field property. This document is an addendum to, and an essential part of, the public record for site characterization, risk assessment of exposure pathways and corrective remedial efforts under Comprehensive Response Actions. For the purposes of this report,the previous information offered is omitted as redundant or summarized only to orient the reader. For specific information on historic environmental assessment activities and remedial response actions,the reader should reference the "Phase I Limited Site Investigation"[LCR(2/20/90)],"Phase I-Initial Site Investigation with Tier Classification"[RAM(8/9/96)], "Immediate Response Action Completion Report"[SEA(8/11/00)] and the Phase H Scope of Work (9/20/02), Phase H Comprehensive Site Assessment Completion Statement (11/18/02) and Phase III Identification, Evaluation and Selection of Comprehensive Response Actions (2/18/03), Phase IV Implementation of Selected Remedial Action Alternatives (6/23/03)and Remedy Operation Status Report I(12/30/03) documents prepared by BENNETT& O'REILLY,INC. as filed with the MA DEP (SERO). The work represented within this document,has proceeded under my supervision in a manner consistent with 309 CMR 4.02 (2), the MCP Response Action Performance Standards (RAPS), pursuant to 310 CMR 40.0191 and Quality Assurance/Quality Control policies of BENNETT & O'REILLY, INC. The facts and statements herein are, to the best of our knowledge, a true and accurate representation of the current Site activities,remedial response actions and environmental conditions associated with the project. As such,this document serves as the technical justification and rationale for the LSP Opinions represented by the certifications on the Comprehensive Response Action transmittal forms [BWSC-108] attached. ENVIRONMENTAL MONITORING/RISK CHARACTERIZATION [APPENDIX B & D] Perimeter Monitoring Wells On February 5, 2004, BENNETT&O'REILLY, INC. personnel were on-site to complete annual groundwater sampling of select down gradient and source area monitoring wells in review of critical exposure pathways as associated with soil and groundwater impacts exceeding Method DULY 12,2004 HUBBARD OIL CO.,INC-BROOKS RDJ B002-3490 PAGE 3 OF 9 PHASE V REMEDY OPERATION STATUS REPORT II 1-Risk Characterization Standards at the subject Site,as specified in the Environmental Monitoring section of the Phase IV RIP. Down gradient monitoring wells GZA-1, GZA-2, MW-5 S/D and MW-6 S/D on the Robies Refrigeration property and source area monitoring wells MW-1,MW-2, MW-4, SEA-1 and SEA-2 were gauged, developed and sampled for EPH and VPH with all target poly aromatic hydrocarbons (PAH) and volatile organics (BTEX). Results of the February 2004 quarterly sampling event reported minor concentrations of fractional C9 to C10 Aromatics in down gradient wells GZA-1(D), GZA-2 and MW-5S slightly above the method detection limit of 20 µg/L. Perimeter monitoring wells MW-5D,and MW-6S and D reported fractional VPH compounds as below the reporting limit (BRL) of the analysis. VPH analysis of central monitoring wells reported minor concentrations of fractional aromatics in wells MW-2 and MW-4, slightly above the method detection limit of 20 µg/L. No BTEX compounds were reported above the method detection limits. In each case, the reporting limit is at a concentration less than the applicable GW-1/GW-3, Method 1-Risk Characterization Standards. These findings are consistent with previous analytical data from quarterly sampling of down gradient wells over the past eighteen months wherein all fractional VPH compounds and target BTEX analytes,have been reported as BRL or at concentrations substantially less than the applicable GW-1/GW-3, Method 1 - Risk Characterization Standards. Results of EPH analysis from down gradient monitoring wells indicated low-level fractional EPH concentrations in well GZA-1(D), below the applicable GW-1 and GW-3 Method 1 -Risk Characterization Standards. All other down gradient wells (GZA-2, MW-5 S, D and MW-6 S, D) reported fractional EPH concentrations as BRL. In each case, the reporting limit is at a concentration less than the applicable GW-1/GW-3, Method 1-Risk Characterization Standards. These findings are consistent with previous analytical data from quarterly sampling of down gradient wells over the past eighteen months wherein all fractional EPH compounds have been reported as BRL or at concentrations substantially less that the applicable GW-1/GW-3, Method 1 -Risk Characterization Standards. Results of the target analytes analysis (EPA Method 8270C Modified) also indicated the presence of several Polynuclear Aromatic Hydrocarbons(PAHs),marginally above the applicable RCGW-1 Reportable Concentration and Method 1 GW-1 Risk Characterization Standards in the down gradient monitoring wells GZA-1, GZA-2, MW-51) and MW-6S located on the Robies property. As such, BENNETT&O'REILLY,INC. conducted a review of previous analytical results from these down gradient wells. Results of groundwater analysis from monitoring wells on the down gradient Robies property were reviewed from as far back as October 2002, wherein BENNETT& O'REE,LY, INC. asked the laboratory to report the full PA_-H list for the analysis as prior to June 2003,previously only requesting the target 4 PAH analysis associated with virgin fuel oil impact as consistent with the historic use of the property. However, the laboratory records of such historic analysis did not allow for the low-level Reporting Limits to meet the RCGW-1 Standards, in that mass spectrometry was not conducted at the time of such testing. Although no higher molecular coal tar related PAH compounds were detected in the historic groundwater testing reviewed,the detection limits and analytical sensitivity do not preclude the possibility that such compounds were present at JULY 12,2004 HUBBARD OIL CO.,INC-BROOKS RDJ B002-3490 PAGE 4 OF 9 PHASE V REMEDY OPERATION STATUS REPORT II the time of historical testing. These compounds,however,were not present in the monitoring wells at the Hubbard property in the most recent testing conducted in February of 2004. BENNETT & O'REILLY, INC. also requested the laboratory to report the full list PAH's for soil samples previously collected as part of the Phase H Investigation from the subject Hubbard property in October 2002. In this testing,the Reporting Limits did meet the RCS-1 Standards. All of the analysis reviewed reported fractional EPH concentrations. Two of the four samples did not report any PAHs above the method Reporting Limit. In the TB-4 sample,with the greatest degree of petroleum impact,low-level concentrations of PAH's were reported for the compounds 2-methyl naphthalene,phenanthrene, acenaphthene and fluorene as typical of a fuel oil source. In the TB-10 sample, low-level concentrations of PAH's for the compounds fluoranthene, pyrene, benzo(b)fluoranthene and benzo(g,h,i)perylene were reported. Although several of the compounds reported in the TB-10 sample are associated with coal tar derivatives, none of the concentrations of PAHs reported were above the Method 1 - Risk Characterization Standards or at concentrations exceeding published Background (MA DEP Technical Update). It is further noted,in consideration of the source,that no such compounds were detected in the most recent groundwater samples`collected from monitoring wells on the Hubbard property and that distribution of PAH constituents reported in groundwater at the Robies property is dissimilar to those historically reported in soils at the Hubbard property. Based on the historic distribution and concentrations of PAH's in soils at the Hubbard property, and the current spacial and temporal occurrence of PAH's in groundwater at the Robies property alone,it appears that the likely source of coal tar derivatives is associated with the railway wherein historic and current uses utilize creosote treated timbers. From this investigation, BENNETT & O'REILLY, INC. concluded that while the concentrations detected are above the RCGW-1 Concentrations,under the provisions of 310 CMR 40.0317(9),(12)and(16 a)the identified"release"did not require Release Notification because(1) the release is suspected to be related to coal tar from the creosoted timbers and (2) because the release is emanating from building materials that are in good repair and still serving their original intended use and(3)response actions are already being undertaken at the Hubbard site in accordance with the provisions of 310 CMR 40.0000 as Adequately Regulated.. In discussions with the client's attorney, Robert Fasanella, Esq. as well as the Department (Laura Stanley,Case Officer),these parties concurred with BENNETT&O'REII LY'S conclusion that the identified"release" did not require Notification. A copy of such correspondence was sent to the Barnstable Water Company (David Condry) including a suggestion that the nearby Public Water Supply Wells be tested for such compounds if they were not already. Correspondence and analytical results are included for reference in Appendix C. Interior Monitoring Wells Central wells SEA-1 and SEA-2 reported concentrations of fractional VPH and target BTEX compounds above the applicable GW-1 and GW-3 Method.1-Risk Characterization Standards. JULY 12,2004 HUBBARD OIL CO.,INC-BROOKS RDJ B002-3490 PAGE 5 OF 9 PHASE V REMEDY OPERATION STATUS REPORT II Central well MW-1 reported concentrations of VPH and target analytes as BRL. Results of EPH analysis from central monitoring wells reported concentrations of fractional EPH above the applicable GW-1 Method 1 Risk Characterization Standards in wells MW-1, SEA-2 and SEA-1. Monitoring well SEA-1 also reported concentrations of 2-methylnaphthalene and naphthalene above the GW-1 Method 1 Standard. Central well MW-4 reported fractional EPH concentrations below the GW-1 Standard and well MW-2 reported EPH concentrations as BRL. These most recent results were compared to baseline TPH data,wherein previously collected TPH concentrations were compared with the total EPH data most recently collected. The total EPH reported in monitoring well MW-1 was more than twice as high as the TPH data collected in 2002. The total EPH reported in monitoring well MW-4 was reported lower than the previously collected TPH data. Monitoring well SEA-1 reported concentrations of total EPH four times as high as the previously.reported TPH data and SEA-2 reported total EPH results six times lower than the . previously reported TPH data. Monitoring well MW-2 reported all fractional EPH and target analytes as BRL as consistent with the previous TPH results. Scheduled quarterly sampling in May 2004 was not authorized, and hence not conducted, under specific instructions from the PRP and their representatives pending a response from the Town of Barnstable to April 20, 2004 communications requesting information relative to the expressed taking of the property and impacts on the preferred RIP. Such reply from the Town of Barnstable was deemed necessary to move forward with the project and implementation of the RIP with the benefit of the proposed ORC injections, removal of contaminated soils and construction and operation of the proposed bioventing remedial system. In meetings with the Town of Barnstable and their consultants in September 2003, following the public announcement of the taking of the property,there was an understanding that a review of the Phase IV Remedy Implementation Plan would be made by Horsely&Whitten,to the Town's consultant,to establish 1)the suitability of the remedial strategy for the intended use of the Town in the Airport expansion project,2)determine the role and responsibility of the current owner and/or LSP in future remedial response actions conducted at the property and 3) specify development and intended use of the property to avoid impact to the proposed remedial system. Such discussions were intended to be of mutual interest to both parties in avoiding redundant costs and expenditures wherein the Phase IV could be modified to suit the intended purpose of the prospective buyer or assurance made to the current owner for j construction and unimpaired operation of the proposed bioventing system. In the absence of any reply and cooperation, the Department [Laura Stanley, Chief - BWSC/Compliance and Enforcement Section] was contacted to help intervene in obtaining some cooperation and critical answers from the Town. BENNETT & O'REILLY, INC. obliged the client's wishes to temporarily suspend the quarterly sampling for one round of sampling pending Department intervention and the PRP was notified by the LSP of Record of Remedial Action Performance Standards obligations. The PRP subsequently authorized the sampling of down gradient monitoring wells in order to comply with the RAPS outlined in the MCP with the continuation of environmental monitoring in the third quarter of 2004. JULY 12,2004 HUBBARD OIL CO.,INC-BROOKS RD./B002-3490 PAGE 6 OF 9 PHASE V REMEDY OPERATION STATUS REPORT II During the reporting period, and throughout testing conducted over the past 16 months, all concentrations of EPH and VPH as well as all target analytes, in down gradient monitoring wells, have been consistently reported as below the applicable GW-1 and GW-3 Method 1 - Risk Characterization Standards. As such,no Substantial Release Migration or critical ingestion exposure to the Maher Well field,inhalation exposures to occupied buildings,or environmental impact to the down gradient wetlands is attributed to groundwater impact at this time associated with the subject Site. As such, a condition of No Substantial Hazard is indicated under current Site Conditions. PHASE IV REMEDY IMPLEMENTATION PLAN In the Phase III Investigation,the excavation of surficial soils(0-3'),the construction of an engineered barrier and operation of an active bioremediation system employing was selected as the preferred remedial alternative for the continued use of the facility for fuel oil storage and distribution wherein the treatment of petroleum impacted soil and groundwater was projected as.being able to meet a Class A, Response Action Outcome. As has been previously discussed, following the submission of the Phase III and Phase IV Investigations, the Town of Barnstable announced the intended taking of the properly and inherent interest in remedial response actions being conducted at the Site. Discussions between the Town and the property owner were conducted in good faith to avoid substantial expenditures for the purchase of equipment, materials and construction related activities needed to proceed with the preferred RIP presented,if the preferred RIP was not suitable for the Town's intended further use of the property and conflicted with the proposed construction activities related to the roadway and parking lots designed for the property by the airport expansion. As of the date of this filing,no substantive reply has occurred from the Town to the PRP relative to questions posed at our meeting in September 2003 and the RIP activities outside of environmental monitoring have been suspended pending response from the Town of Barnstable. The PRP wishes to avoid unnecessary expenses until the numerous issues involving the Taking,are resolved and the remedial strategy is endorsed or modified accordingly to the future property owner's interests and construction plans. At present the full-scale bioremedial strategy is still the preferred and appropriate remedial strategy. As presented in the previous Remedy Operation Status Report, dated 12/30/03, the implementation schedule was modified to reflect a time-line from receipt of a response from the Town of Barnstable, wherein full system startup is proposed within 90 days from the receipt of a response from the Town regarding critical design plans and construction components. However,if no action has been taken and no answers to the PRPs questions are received, BENNETT & O'REILLY,INC.,has been requested to revisit the Phase III Review of Remedial Alternatives and Feasibility Evaluation in light of current circumstances. A modification of the environmental monitoring program is presented wherein a review of natural attenuation within the interior plume is being considered. Baseline water quality measurements taken at perimeter wells indicated elevated levels of nutrients and dissolved oxygen levels consistent with what might be expected of sentinel monitoring wells at the leading edge of an attenuating plume of dissolved-phase groundwater impact. JULY 12,2004 HUBBARD OIL CO.,INC-BROOKS RDJ B002-3490 PAGE 7 OF 9 PHASE V REMEDY OPERATION STATUS REPORT II PHASE V: OPERATION,MAINTENANCE AND ENVIRONMENTAL MONITORING As previously stated in the last ROP Status report,the implementation schedule has been modified to reflect a time-line from receipt of substantive answers regarding the towns intentions of the eminent domain taking and use of the subject properties. If the intentions of the Town allow, full system startup is proposed within 90-days. SVE Operation&Maintenance: Following the installation and full system startup, monthly site inspections will be conducted by BENNETT & O'REILLY, INC. At the time of inspection, the vacuum, pressure and flow gauges will be checked. The moisture trap will be emptied and remedial wastewater stored in a sealed DOT drum in the secured storage building. The particle filter will also be checked and cleaned or replaced as necessary. A photoionization detector will be used to record the TOV concentrations in the influent air and intermediate to the GAC units for evidence of breakthrough. The primary GAC unit will be replaced when intermediate breakthrough is indicated: -- Environmental Monitoring. Soil Respiration analysis will be performed quarterly subsequent to the startup of the system as a measure of system performance. As respiration rates approach those of background concentrations, or at least on a six month basis,test borings will be conducted for the qualification of soil treatment for EPH and/or VPH analysis as dependent on known contaminant source. This information will be compared against baseline testing in review of SVE performance and closure objectives. Soil samples will also be analyzed on a six month basis for wet chemistry and bacteria counts to assure adequate nutrients to support indigenous bacteria populations and to qualify respiration rates for microbial activity. At the present time,access to the area of soil impact is restricted by perimeter fencing. Employees of Hubbard Oil have been advised of environmental hazards and hence critical exposure pathways are complete at the present time. Environmental Monitoring: Groundwater Frequency of groundwater monitoring has been reduced based on a preponderance of historic quarterly data collected at down gradient monitoring wells wherein no significant groundwater impact is demonstrated intermediate to critical receptors and hence,no critical exposure pathways are complete as the basis of No Substantial Hazard. Bi-annual (May/November)groundwater monitoring of the down gradient perimeter monitoring wells GZA-1, GZA-2, MW-5 S/D and MW-6S, D and the most heavily impacted central monitoring well SEA-2 will be conducted for EPH and VPH analysis with target analytes. At the time remedial additives are in use, wet chemistry sampling will be conducted in accordance with the provisions of 310 CMR 40.0046. Wet chemistry will include nitrate, total nitrogen,sulfate,iron,manganese,magnesium and total phosphorus. Annually(May), DULY 12,2004 HUBBARD OIL CO.,INC-BROOKS RDJ B002-3490 PAGE 8 OF 9 PHASE V REMEDY OPERATION STATUS REPORT II EDB and lead analysis will be conducted in the perimeter wells. All sampling will be accompanied by field measurements of dissolved oxygen,pH,conductivity and temperature. All information on the bioremediation system operation, maintenance and environmental monitoring will be recorded on the Inspectors Daily Record, Monitor Well Sampling Logs and or Respiration Logs as shown in the QA/QC Policies in Appendix G. The evaluation of system performance and/or environmental monitoring will.be reported in the Phase V Remedy Operation Status Report following system startup with a Phase IV Completion Report and"As Built"plans in the six month filings required. SUMMARY AND CONCLUSION The fmdings of the Phase IV Remedy Status Report, as represented herein, set forth the rationale and technical justification for the selection of proposed bioremediation strategy as the preferred remedial alternative pending re-evaluation of Monitored Natural Attenuation. The implementation of the bio-remedial remedial strategy set forth in the Phase W Remedy Implementation Plan (6/23/03) has continued to be delayed pending response from the Town of Barnstable to substantive practical and financial issues regarding the previously announced taking of the property and proposed use of the property as a roadway and parking lot. In the interim, environmental monitoring of perimeter monitoring wells has continued and has established a condition of No Substantial Hazards under current conditions with no indication of Substantial Release Migration or complete inhalation,ingestion or direct contact exposure pathways to identified human and environmental receptors as associated with soil and groundwater impact identified. It is expected that outstanding issues between the PRP and the Town of Barnstable will be resolved in the next reporting period so that the RIP may proceed in accordance with the schedule set forth in this report. In the interim,the environmental monitoring program has been reduced to bi-annual sampling of perimeter wells and the most heavily impacted central well. The LSP opinions represented by this report are established by the certifications made on the attached Comprehensive Response Action[BWSC-108]Transmittal Form. The LSP opinions are based upon available data and regulations in effect at the time of this reporting. Should you have any questions or require any further information,please contact me directly. S ely E TT LY, INC. r v�id e ett,LSP io6 T� ems-Wiei Director of Environmental Services Project Manager encl. -Report entitled"Phase IV Remedy Operation Status Report II",Prepared by BENNETT& O'REILLY,INC.,Dated June 24, 2004 -Comprehensive Response Action Transmittal Form, BWSC-108 (original) DULY 12,2004 HUBBARD OIL CO.,INC-BROOKS RD./B002-3490 PAGE 9 OF 9 PHASE V REMEDY OPERATION STATUS REPORT II cc: Hubbard Oil, Inc. -Attn: Evelyn Read, General Manager Robert A. Fasanella,Esq. -RUBIN&RUDMAN, LLP Lieutenant Hubler-Hyannis Fire Department Thomas McKean-Barnstable Board of Health John Klimm-Barnstable Town Manager, c/o Barbara Harris, Town Counsel David Condry-Barnstable Water Company John Robichaud,Abutter-Robie's Refrigeration f REMEDIAL OPERATION PLAN STATUS REPORT II SUPPORTING DOCUMENTATION RTN 4-0824/4-15370 Hubbard Oil Co., Inc. 33 & 51 Brooks Road [Assessors Map 328, Parcel 125 & 126] Hyannis,MA. 02601 Project#B002-3490 JULY 12,2004 Prepared By: BENNETT& O'REH LY,INC. 1573 Main Street P.O.Box 1667 Brewster,MA 02631 David C.Bennett,LSP. Prepared For: Ms.Laura Stanley,Compliance and Enforcement Branch Chief, SMP Mr. Gerard Martin,Chief Sites Management&Permitting Section,BWSC Massachusetts Department of Environmental Protection(MA DEP) Southeast Regional Office(SERO) Bureau of Waste Site Cleanup(BWSC)/Sites Management Program(SUP) 20 Riverside Drive Lakeville,MA 02347 On Behalf Of: Hubbard Oil Co.,Inc. P.O. Box 10-Hyannis,MA 02601 Evelyn Read,General Manager APPENDIX A:Reference Plans -Site Plan:Comprehensive Response Actions,"Phase IV-Remedy Implementation Plan"(2 Sheets), Prepared by BENNETT&O'REILLY,INC.,Dated April 24,2003(rev.6/24/04) -Figure 1:Site Locus Plan from USGS Topographic Quad.,Hyannis-Excerpt(TOPO 1998) -Figure 2:MA DEP BWSC GIS Map,Hyannis-Excerpt(MA DEP 9/29/00) -Figure 3:Water Table Contour Map Excerpt,Town of Barnstable, 1992 APPENDIX B:Field Reports -Field Inspection Reports: #16(2/5/04) -Monitor Well Sampling Log:2/5/04 APPENDIX C:Environmental Records -Correspondence w/MA DEP: 02/26/04:Discovery of PAHs in Groundwater 03/04/04:PAHs in Groundwater Followup 04/20/04:B&A Fournier Realty Trust,Eminent Domain -BWSC-108:Comprehensive Response Actions Transmittal Form APPENDIX D:Laboratory Analysis -Groundwater Analytical:Report dated 2/23/04 Groundwater Analytical:Previous reports with full PAH listings: [groundwater 10/02, 11/02, 1/03,4/03,6/03] [soi110/02] -Table 1:EPH analysis summary-Perimeter Wells -Table 2:VPH analysis summary-Perimeter Wells -Table 3:EPH analysis summary-Central Wells -Table 4:VPH analysis summary-Central Wells APPENDIX E:Site-Specific Health And Safety Plan APPENDIX F:Quality Assurance/Quality Control APPENDIX A BIO VENTING SYSTEM ZONE "All 75 Scale 1"=4' Area of 5od Removal (50'x G5'x 3) f Con trol Panel Presure Gauge Vent - 2 PVC Pipe � ��� �.... ��� .}..` Infiltration Trench (see detail) Carbon Filtration Systems E '" Two VS-200 200 lb 200 lb „� GAC GAC 1.0 HP S A-1 Regenerative Dilution Valve Blower - y Vacuum Gauge To SVE Manifold - GAST R4310P-50 //µ~ Vacuum Release Valve -25 in water @ 60 SCFM O E Moisture Trap �� flJ Particle Filter �0) �ru � 2" PVC Pipe 4(7 _0 Measured Radii of Influence ZONE I13 11 Area of soil Removal (45' x G5'x 3') SCHEMATIC BIO-VENTING COUPLET (typical) C , Not to Scale ,.. i, -3 R. y S Deep Shallow "T" with inspection port Grade EL=0.0 t— Steel Manhole - —=2" PVC Pipe to SUE System Grout Grout Ben tonite plug 5' Bentonite Plug 1120 Slot Screen Gravel Pack Sand - - SCHEMATIC INFILTRATION TRENCH/ENGINEERED BARRIER Not to Scale 13' bgs 10' 0' bgs Moisture —Clean Sand AS-BUILT SITE SKETCH PLAN Probes Scale l"=20' 0.5 bgs —40 mil HDPE liner FRIP-2 - 3/4" gravel #20 Slot Screen • • • • • • • • • • • • Project: COMPREHENSIVE RESPONSE ACTIONS Gravel Pack 4" perforated PVC pipe HUBBARD OIL CO., INC. 33 AND 51 BROOKS RD.,HYANNIS,MA X bgs Title: . . . ... , . IL VENTINGTREATMENT SYSTEM Bottom of SUE Point 23' = Groundwater ; ; PHASE IV- REMEDIAL IMPLEMENTATION PLAN —Natural materials ... . ... .. .-. .. .., _:. .:. .,, .:,.:. . � , . ' . RTN4-0824(RTN4-13570} - HUBBARD OIL CO.INC.,P.O.BOX 10,HYANNIS,MA,02601 BE�ETTO'nEILL INC . , .. ENGINEERING,ENVIRONMENTAL,&SURVEYING SERVICES 1573 MAIN STREET,P.O.BOX 1667 BREWSTER,MA 02361 PHONE:(508)896-6630 FAX:(508)896-4687 DATE SCALE BY CHECK JOB NUMBER SHEET 2 OF 2 6/20/03 As Noted ELS DCB B002-3490 i i Barnstable, GROUNDWATER WELL GAUGING MA Reference Site Plan by SEA Consultants,Inc. DATE: 10/09/03 TIlAE: TIDE: Cambridge,MA Scale 1"_-50 a WELL T.O.C. D.T.W. S.W.L. FLow vEc roR Reference Site Plan for Robie s Refrigeration X 5u3 RAO by Horsley&Witten,Inc. d2 mad I MW-5S 38.99 18.02 20.97 S 570 E LOCUS MW-51) 38.94 17.95 24.99 123° o' g _ ! MW-6S 39.20 18.17 21:03 / 8 / m �...,�.r.«.».....��.�.�,d �..,...&.,......u.....A.....,.e.,......e.,.....m»..,n a.1 In d 23 / C house Road 39.20 18.15 21.OS / GZA-2 39.31 18.20 2111 �^ mmr l GZA-3 39.57 18.52 21:05 t _ GZA-1 39.24 17.89 21•35Cb d SEA-] 4$37 21 6R 20,69 F 4 OW-5 40.00 Dry NT / / TYPICAL �a ,� KEY MAP / TEST BORING-MONITOR WELL DATE: ?/5/04 Tn�: TIDE: / RESERVED AS REQUIRED 2 I � K, LEGEND p 4 Mi WELL T.O.C. D.T.W. S.W.L. FLOW VECTOR o CB Concrete Bound / MW-SS 38.99 17.05 21.94 S 620 E / • Existing Monitor Well TB- / e Proposed Monitor Well MW-SD 38.94 17.13 21.81 1180 / + Existing Test Boring m, : _... f19.1i MW-6S 39.20 17.27 21.93 Proposed Test Boring I /. , ' MW-6D 39.20 17.25 21.95 i Proposed ORC Injection Point 919 M Area of Staining - I ° GZA-1 39.24 16.91 22.33 TB-1 O c j tt � D Diesel - GZA-2 39.31 17.33 21.98 ` V GW Groundwater _ D HW-3• Q See Schematic Details toaa� Q G Gasoline N-2 48.84 26.19 22.65� } ' (Sheet 2 of 2) ` SEA Installations by SEA Consultants,Inc. '"'`- 116 3 �� 48.84 26.16 22.68 O SEA-3 0°� / AST Aboveground Storage Tank j� UST Underground Storage Tank _ 48.08 24.52 23.56 (brl)z Former Location �/ - GZA GZA,Inc.,Consultants 3 , 5 A5T's(D,esep OW Observation Well 49.50 26.72 22.78 {tZemoved Isb6) Area of Soil Impact>S3/GW48.37 25.70 21.67 Steamship ExisAuthority Q lie '� / Area of Groundwater Impact>GW-1 SEA-2 50.92 28.09 22.83 Monitor Wells O o \ TB-3 O� � 6NEI� It A v Q HW 2 m • Proposed MW • Existin O C spo Former Location - UST(Kerosene) �� / ,� m ZA-3 br , (Existi�j) _ Existing . Septic Tank / SB 2-- m y ZONE II 1 5. a. admg Doc • �.� Exis ng xKu ';Ra _ m_, / Sump MW-3 D Well v. (brl) Now or Formerly - O�'" -10 Loading Racks _$ - ._ ... _ ZA-2 5Q �., -_ A. Gasohne < GW-1) \ Concrete -Ilzarking OVG-S ' '-41(Gasotme) GZA 1 9 SEA IV�� PLAN fir a. rmer Lsaton s� Scale 1"=40' {Ga lmaIKerosen )` e �a9� �TB-7 (t�emred 2 199�) - Ga -14 SEA SB-1 - -6S&D Existing �. .- (Gasohne < GW-I) >/ (Shallow Only) TB-9 w� IDENTIFIED SOIL IMPACT (>S-1/GW-1) REMISED G/24/04: Added well gauging and groundwater flow µ" determinations for 2/5/04 ZONE"A" [65'L X 50V X 27'D] ZONE IICII M F° REMISED ! 2/!9/03: Added well gauging and groundwater RIP TB- 4: 3'-8' b (DIESEL) s w - flow determinations for !0/09103 g ) MW-1 (Diesel) TB-1 1: 3'-2T bgs(DIESEL) (Basting} / Catch Existi Catch n Project: EPH > GW I (199G-20oo, M` aasin® s o �� HUBBARD OIL COMPANY, INC. ZONE"B" [65'L X 45'W X 280] p Attn:Evelyn Read, P.O.Box 10,Hyannis,MA 02601 SEA-1 (SB): l'-24'bgs(GASOLINE/DIESEL) INTERPRETED RETED AREA OF / Title: COMPREHENSIVE RESPONSE ACTION SEA-SB-3: P-15'bgs(GASOLINE/DIESEL) G RO U N D WATE R I M PACT / PHASE IV-REMEDY IMPLEMENTATION PLAN TB-6: 15'-28'bgs(GASOLINE) TB-13 MW-5 S&D 33&51 Brooks Road,Hyannis,MA-RTN 4-0824 sohne < GW-I) ZONE"Bn [15'L X 10-15V X 5D] / (Sha only) BENNETT & 01REILLY, INC. HB- 1: 0'-5' bgs(DIESEL) / ENGINEERING,ENVIRONMENTAL,&SURVEYING SERVICES / 1573 MAIN STREET,P.O.BOX 1667 BREWSTER,MA 02361 PHONE:(508)896-6630 FAX:(508)8964687 DATE SCALE BY CHECK JOB NUMBER SHEET 1 OF 2 04/24/03 As Noted JTW/e DCB B002-3490 _- ------ I Hubbard Oil Co.,Inc.-33 and 51 Brooks Road,Hyannis,MA 41"4015",70017-18" 41°40'15",70015'44" i p ° F *t. "'���666 • t -45 qr • • e 4s a �PrR, 4 Maur. LOCUS ST 0. Ell ri f'r�'. �' f `�j ..� N`e "� d'h1°�b � J! "µ 7 x.. �{T i. L—• �. �4*. lit *441111 �.+"- � i• �� t ^.ire a �` 41°39'06",7001718"N D83 41°39'06", 70015'44" MN TN9 112 1 MILE 160 1000 0) 1000 2000 3000 4000FEET Printed from TOPO! @1998 Wildflower Productions(www.topo.com) Figure 1: The subject properties are located at 33 and 51 Brooks Road in Hyannis, MA. The properties are located approximately 250 feet east of the intersection of Mary Dunn Road and Brooks Road in the Town of Hyannis, MA. The two parcels of land contain approximately 0.71 and 0.67 acres of land,respectively,with frontage along Brooks Road. The Barnstable Registry of Deeds lists the owner of'record for both parcels as B&A Fournier Realty,Inc. The parcels are identified on the Town of Hyannis Assessors' Map 328 as Parcels 126 and 125, respectively. 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'�1� # 11�\� ti �,11,1\�I ,11iy\,n R.►>w �ii�At►114t1 1 "IN ►,>_,• } �+►,ir+`�.;• #1111 1 \11L'�.!'�1'•ni1R�i`.;�- 1�1 "'' „ ,� �.t ''Y't •��•- ?\i11�l1�11r1111,t►►r' il,i ��,1 11 �: e ��ilf��iJ`�ys►1tk't i�+�Z�i1�i111�t�1\11ti+111►�: i 71�11111 ,•�1�Iy1y\q�r► to_ MIlk, 4 r 1 IBell.G xk Y7i■ L Maio � 3 ['i�� r ,,. ry M ' � /� �?rr ��. �•'���iy+ate ,�� `�•+3,�c� tRt" '� ��I�tr•�1(�����' � a��'' 1! �•�" f fig 1.7-�l�� 1. - , _ it Ffj . IU. t *�.. r � ++�,IM �° _�I• .+sir*�!',, �:�,�. APPENDIX B BENNETT & O'REILLY Inc. REPORT NUMBER: 16 1573 Main Street 508-896-6630 PO Box 1667 508-896-4687 Fax Brewster, MA 02631 INSPECTORS DAILY RECORD OF WORK PROGRESS Job Number: B002-3490 Date: 2/5/04 Job Name: Hubbard Oil Co.Inc/ Brooks Road,Hyannis Feature: ROS Contractor: Bennett&O'Reilly Inc., Type of Work: Quarterly/Annual sampling Weather Conditions: Seasonal,Sunny Temperature: 36°F ontractor's Work Force(Indicate classification, including Subcontractor personnel) ennett&O'Reilly Inc.:John Tadema-Wielandt(ESII),Scott Kraihanzel(ESI) quipment in use or idled (identify which) roundwater level indicator(in use),YSI multi-meter(in use),SVE system(idle) aterials or equipment delivered,quantity or pay items placed ample 11 wells for EPH and VPH with all targets(GW-1)on standard turnaround.4 locks. on-conforming materials or work, field problems,inspections of previously reported deficiencies ould not locate turbine vents for passive venting of soils. Will order and install upon receipt. ummary of construction activities 0:45 am ennett&O'Reilly Inc.personnel arrive at Robies Refrigeration to sample down gradient monitoring wells as specified in environmental onitoring section of previous report. :55 am egin gauging of select MW's. :00 pm eging sampling wells at Robies Refrigeration property. 40 pm omplete sampling at Robies Refrigeration property.Break for lunch. l0 pm obilize to Hubbard property.Begin purging and sampling selected wells. 50 pm omplete sampling of selected well's on Hubbard/Brooks Road properties. Pack up equipment. :00 prn epart site. BENNETT & O'REILLY, Inc, MONITOR WELL SAMPLING LOG 1573 Main Street, P.O. Box 1667 Brewster, MA 02631 Engineering and Environmental Services (508)896-6630 FAX(508)896-4687 CLIENT Hubbard Oil Co.,Inc DATE(S) 2/5/04 TIME: TIDE: LOCATION 33+51 Brooks Rd.,Hyannis JOB NUMBER B002-3490 SAMPLER John Tadema-Wielandt,Kara M.Risk MEASURING POINT GROUND SURFACE OR T.O.C: T.O.C. Elev. of Total Standing Water Well reference Depth Depth to Water Table Static Volume HNU Dissolved Conductivity p Water Volume Purged PI-101 pH Oxygen y Temperature Comments: Number point of Well Height Elevation (F) (feet) (feet) (feet) (feet) (feet) (gallons) (gallons) (PP-) (mg/t) GZA-1 39.24 77 16.91 60.09 22.33 10.22 31.0 NT 5.84 3.83 83 51 H2S Odor-No Sheen GZA-2 39.31 28.7 17.33 11.37 21.98 1.93 6.0 NT 5.61 7.86 139 53 H2S Odor-No Sheen MW-5S 38.99 28 17.05 10.95 21.94 1.86 6.0 NT 5.81 7.69 101 52 Trace Odor-No Sheen MW-5D 38.94 51 17.13 33.87 21.81 5.76 18.0 NT 5.83 5.49 85 52 No Odor-No Sheen MW-6S 39.20 28 17.27 10.73 21.93 1.82 6.0 NT 5.65 7.67 109 53 No Odor-No Sheen MW-6D 39.20 51 17.25 33.75 21.95 5.74 18.0 NT 5.69 8.83 39 53 No Odor-No Sheen MW-1 48.84 30.85 26.19 4.66 22.65 0.79 2.5 NT 5.84 4.15 241 48 Trace Odor-No Sheen MW-2 48.84 30.43 26.16 4.27 22.68 0.73 2.5 NT 5.77 6.12 136 48 No Odor-No Sheen SEA-2 .50.92 32.24 28.09 4.15 22.83 0.71 2.5 NT 5.58 3.36 310 50 Slight Odor-Trace Sheen MW-3 48.08 31.50 24.52 6.98 23.56 1.19 4.0 NT 5.81 7.14 183 52 No Odor-No Sheen MW-4 49.50 35.52 26.72 8.80 22.78 1.50 4.5 NT 5.34 7.30 100 45 Slight Odor-No Sheen SEA-1 48.37 32.08 25.70 6.38 22.67 1.08 3.5 NT 5.58 3.45 207 50 Moderate Odor- Moderate Sheen NOTES: Sample 11 wells for EPH/VPH APPENDIX C FILE COPY BENNETTO 'REILLY, Inc. Engineering, Environmental & Surveying Services 1573 Main Street PO Box 1667 Sanitary 21FJSite Remediation Property Line ® Brewster, 7 02631 Site Development Hydrogeologic Survey Subdivision Waste Water Treatment Water Quality Monitoring Land Court 508-896-6630 Water Supply Licensed Site Professional Trial Court Witness 508-896-4687 Fax B002-3490 February 26, 2004 Mr. Bert Fournier c/o Ms. Evelyn Read HUBBARD OIL COMPANY,INC. P.O. Box 10 Hyannis MA, 02601 RE: DISCOVERY OF PAHs IN GROUNDWATER Hubbard Oil Company Inc. -RTN 4-0824 33 and 51 Brooks Road [Assessors Map 14, Parcel 125 andl26] - Hyannis, MA. 02601 Dear Ms. Read, On February 5, 2004, BENNETT & O'REILLY, INC. was at the. above site to perform scheduled quarterly groundwater sampling of selected monitoring wells,both at the site and on the downgradient Robies Refrigeration property, as based on the revised Environmental Monitoring Program in the Hubbard Remedial Operation Status Report I, dated 12/30/03. Results of these analyses, received February 24,. 2004, indicate the presence of several Polynuclear Aromatic , Hydrocarbons(PAHs),marginally above the applicable RCGW-1 Reportable Concentration as well as the Method 1 GW-1 Risk Characterization Standards in the downgradient monitoring wells GZA= 1, GZA-2, MW-5D and MW-6S located on the Robies property. BENNETT&O'REILLY, INC.has conducted a review of previous analytical results from these downgradient wells and it appears that none of these compounds have been previously detected. at the downgradient Robies property. Similarly,none of these compounds have been detected within monitoring wells at the Hubbard property as within the area'of the subject release. We have requested Groundwater Analytical to report the full list of PAH concentrations on all previous EPH testing of soils at the Hubbard property. Such results are pending at the time of this correspondence. As such, based on the spatial and temporal distribution of these heavy-weight PAH compounds as being not identified in the monitoring wells at Hubbard property, BENNETT`& O'REILLY, INC. concludes that there must be another source of the detected contaminants. The suspected source of these high molecular weight PAHs is creosoted timbers in the railroad easement leaching through the subsurface and into the groundwater, as being consistent with the identified contaminants and upgradient of the impacted wells at the Robies property. .l FEBRUARY 26,2004 HUBBARD OIL CO.,INC/BROOKS RD.BO02-3490 PAGE 2 OF 2 . . DISCOVERY OF PAHS IN GROUNDWATER While the concentrations detected are above the RCGW-1 Concentrations, under the provisions of 310 CMR 40.0317(9),(12)and(16 a)it seems as though the identified"release"does not require Release Notification because(1)the release is suspected to be related to coal tar from the creosoted timbers.and(2)because the release is emanating from building materials that are in good repair and still serving their original intended use"and (3) response actions are already being undertaken at the.Hubbard site in accordance with the provisions of 310 CMR 40.0000 as Adequately Regulated. However, because of the relative sensitivity of the area where the samples were collected, being directly upgradient of the Maher Wellfield public water supply, BENNETT & O'REILLY,. INC. is copying the Department.on this: correspondence so that they can specify any additional actions they may deem appropriate. BENNETT & O'REILLY, INC. would recommend that the Barnstable Water Company test their wells for semi-volatile compounds in order to determine if there is a risk of ingestion of these compounds to the general public served by the Public Water Supply Wells. BENNETT& O'REILLY,INC. will continue to monitor these downgradient wells quarterly as Specified and will review the information relative to the identified PAHs upon receipt. Should you have any questions,.or need additional information,please contact either of the undersigned directly at your earliest convenience. Si erely, B NN ILLY, INC. f 1 vi e ett SP J lin D. Tiad ma=W Direc or of onrtiental Services roject Mal�ager encl. Groundwater Analytical Results"Groundwater-Analytical Inc."dated 2/23/04 and 10/27/03 Site Plan RIP-2 prepared by Bennett& O'Reilly;Inc. dated 4/24/03 (revised 12/19/03) cc. Laura Stanley, Sites Management-MA DEP (SERO) Attorney Robert Fasanella RUBIN&RUDMAN, LLP John Robichaud,President-Robies Refrigeration David Condry Barnstable Water Company Lieutenant Hubler-Hyannis Fire Department Thomas McKean-Barnstable Board of Health John Klimm-Barnstable Town Manager, c/o Barbara Harris, Town Counsel Commonwealth of Massachusetts,c/o Executive office of Transportation and Construction- (Railroad easement owners) f? RECT JAN 5 2004 Groundwater Analytical,Inc. GROUNDWATER P.O.Box 1200 ANALYTICAL Buzzards Main Street Buzzards Bay,MA 02532 Telephone(508)759-4441 2 2004 FAX(508)759-4475 January , www.groundwateranalytical.com Mr. David Bennett Bennett & O'Reilly, Inc. P.O. Box 1667 Brewster, MA 02631 LABORATORY REPORT AMENDMENT Project: Hubbard Oil / Brooks Rd./BO02-3490 Lab ID: 65807 Received: 10-10-03 Dear Dave: Enclosed are the amended analytical results for the above referenced project. This letter authorizes the release of the analytical results, and should be.considered a part of this report. This report contains a sample receipt report detailing the samples received, a project narrative indicating project changes and non-conformances, a quality control report, and a statement of our state certifications. The analytical results contained in this report meet all applicable NELAC standards, except as may be specifically noted, or described in the project narrative. This report may only be used or reproduced in its entirety. I attest under the pains and penalties of perjury that, based upon my inquiry of those individuals immediately responsible for obtaining the information, the material contained in this report is, to the best of my knowledge and belief, accurate and complete. Should you have any questions concerning this report, please do not hesitate to contact me. i Sincerely, Eric H.J nsen Operati s Ma ger EHJ/kh Enclosures GROUNDWATER - ANALYTICAL Sample Receipt Report Project: Hubbard Oil/Brooks Rd./BO02-3490 Delivery: GWA Courier Temperature: 4'C Client: Bennett&O'Reilly, Inc. Airbill: n1a Chain of Custody: Present Lab.ID: 65807 Lab Receipt: 10-10-03 Custody Seal(s): n/a lab1D _ Fie`_IdID 1vlatnx `Sampled �Methodt�" � � iotesa e 65807-1 MW-55 Aqueous 10/9/03 12:05 EPA 6010E Pb Total Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C382816 500 mL Plastic Proline BX8852 HNO3 R-3593D 09-15-03 n/a _Lab1DF. d ID r Ma2nxY _- �r;.,.. _�a,. . 65807-2 MW-6S Aqueous 10/9/03 10:00 EPA 6010E Pb Total Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C382807 500 mL Plastic Proline BX8852 HNO3 R-3593D 09-15-03 n/a Lab ID Freld IDY _ � _..a Sampled iNetho_d . cam -t ;i. .e : _ Pit 65807-3 MW-6D Aqueous 10/9/03 13:20 EPA 6010E Pb Total Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C382781 500 mL Plastic Proline BX8852 HNO3 R-3593D 1 09-15-03 n/a -tLab ID�F, F[eId ID � y, .AAatraxb s:•. � P .< _ �? .* ? .-�...r '+,� �.�.;� �. .-� - 658074 GZA-2 Aqueous 10/9/03 13:45 EPA 60106 Pb Total Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C382834 500 mL Plastic Proline BX8852 HNO3 R-3593D 09-15-03 n/a Lab ID, �� Fietd tD a _s r h1rx � `Sample`dMehod i Atotes�s` .. ' 221 65807-5 MW-5S Aqueous 10/9/03 12:05 MA DEP VPH with Targets Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C283437 40 mL VOA Vial Fisher BX7661 HCl R-3645B 06-02-03 06-09-03 C337337 40 mL VOA Vial Industrial BX9134 HCI R-3722E 09-15-03 n/a C337336 40 mL VOA Vial Industrial I BX9134 I HCI R-3722E 09-15-03 n/a A- p E,Method ;. � Lab iD Fieht ID M�afi�x Sam led _ of 65807-6 MW-5D Aqueous 10%9/03 12:30 MA DEP VPH with Targets Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C337349 40 mL VOA Vial Industrial BX9134 HCI R-3722E 09-15-03 n/a C337348 40 mL VOA Vial Industrial BX9134 HCI R-3722E 09-15-03 n/a C337334 1 40 mL VOA Vial Industrial BX9134 HCI R-3722E 09715-03 n/a 777 Lab D Fel j I D x Matrix 4 Sam led' M'e,hou r �IM 171 65807-7 MW-6S Aqueous 10/9/03 13:00 MA DEP VPH with Targets Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C283438 40 mL VOA Vial Fisher BX7661 HCl R-3645B 06-02-03 06-09-03 C337335 40 mL V'OA Vial Industrial BX9134 HCI R-3722E 09-15-03 n/a C337333 40 mL VOA Vial Industrial BX9134 HCI R-3722E. 09-15-03 n/a VW 'Lab"tD: FreI3lD* ' f`4`2 rzb Sampled ? lute°d r —F., _ No es 65807-8 MW-613 Aqueous 10/9/03 13:20 MA DEP VPH with Targets [- Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C337338 40 mL V0A Vial Industrial BX9134 HCI R-3722E 09-15-03 n/a C337351 40 mL VOA Vial Industrial BX9134 HCI R-3722E 09-15-03 n/a C337350i 40 mL VOA Vial Industrial JBX9134 HCl I R-3722E 09-15-03 n/a Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Sample Receipt Report (Continued) Project: Hubbard Oil/Brooks Rd./BO02-3490 Delivery: GWA Courier Temperature: 4'C Client: Bennett&O'Reilly, Inc. Airbill: n/a Chain of Custody: Present Lab ID: 65807 Lab Receipt: 10-10-03 Custody Seal(s): n/a manlike y _... -...W111 _,��_.. �.::....�.. ... ...�.�..._�.��:: 65807-9 GZA-1(D) Aqueous 1019/03 15:00 MA DEP VPH Carbon Ranges Only Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C337352 40 mL VOA Vial Industrial BX9134 HCI R-3722E 09-15-03 n/a C337340 40 mL VOA Vial Industrial BX9134 HCI R-3722E 09-15-03 n/a C337331 40 mL VOA Vial Industrial BX9134 HCl R-3722E 09-15-03 n/a a r 'Mhod. :., �- _ �� -�.�; "� � Notes � 65607-10 GZA-2 Aqueous 10/9/03 13:45 MA DEP VPH with Targets Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C337339` 40 mL VOA Vial Industrial BX9134 HCI R-3722E 09-15-03 n/a C337332 40 mL VOA Vial Industrial BX9134 HCI R-3722E 09-15-03 n/a C337320 40 mL VOA Vial Industrial BX9134 HCI R-3722E 09-15-03 n/a ._.. - 65807-11 GZA-3 Aqueous 10/9103 14:10 MA DEP VPH Carbon Ranges Only Con ID Container Vendor QC Lot Presery QC Lot Prep Ship . C337295 40 mL VOA Vial Industrial BX9134 HCI R-3722E 09-15-03 n/a C337308 40 mL VOA Vial Industrial BX9134 HCI R-3722E 09-15-03 n/a C337296 40 mL VOA Vial Industrial BX9134 HCI R-3722E 09-15-03 n/a Lah1© , Eel ` tIvtatrz� SampY �Kefh Fotes � 1 65807-12 MW-5S Aqueous 10/9/03 12:05 MA DEP EPH with PAHs by 8270C-Mod SIM I_ Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C336698 1 L Amber Glass Greenwood BX9478 H2SO4 R-3779C 09-23-03 nh C336697 1 L Amber Glass Greenwood I BX9478 H2SO4 R-3779C 09-23-03. n/a LabIDFse9c {D ? � fri 5apd Meth w wE ' Notes .� �_ 1 65807-13 MW-5D Aqueous 10/9/03 12:30 MA DEP EPH with PAHs by 8270C-Mod SIM Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C336696 1 LAmberGlass Greenwood BX9478 H2504 R-3779C 09-23-03 n/a C336692 1 L Amber Glass Greenwood BX9478 H2SO4 R-3779C 09-23-03 n/a Lab i D �ye d[13s " atrrz Sa�mpl Meth d = 3 otes _ . ... 65807-14 MW-65 Aqueous 10/9/03 13:00 MA DEP EPH with PAHs by 8270C-Mod SIM Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C399866 1 LAmberGlass Greenwood BX9579 H2SO4 R-3779C 10-01-03 n/a C336693 1 L Amber Glass Greenwood BX9478 H2SO4 R-3779C 09-23-03 n/a nft x Lab D F{eldlD g55 r� tylatefl Methoda � t7ates = r 65807-15 MW-61) Aqueous 10/9/03 13:20 MA DEP EPH with PAHs by 8270C-Mod SIM Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C399862 1 LAmberGlass Greenwood BX9579 H2SO4 R-3779C 10-01-03 n/a C399858 1 LAmberGlass JGreenwood BX9579 H2SO4 R-3779C 10-01-03 n/a m.. o.. o � :ame Ned e#jLD a _ 65807-16 GZA-1(D) Aqueous 10/9/03 15:00 MA DEP EPH Carbon Ranges Only Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C399868 1 L Amber Glass Greenwood BX9579 H2SO4 R-3779C 10-01-03 n/a C399864 1 L Amber Glass JGreenwoodl BX9579 H2SO4 R-3779C 10-01-03 n/a Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Sample Receipt Report (Continued) Project: Hubbard Oil/Brooks Rd./BO02-3490 Delivery: . GWA Courier Temperature: 4'C Client: Bennett&O'Reilly, Inc. Airbill: n/a Chain of Custody: Present Lab ID: 65807 Lab Receipt: 10-10-03 Custody Seal(s): n/a >e c � . . Lab1D� FrefdlD Elvtatnx , rSampled'.> 65807-17 GZA-2 Aqueous 10/9/03 13:45 MA DEP EPH with PAHs by 8270C-Mod SIM Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C399867 1 L Amber Glass Greenwood BX9579 H2SO4 R-3779C 10-01-03 n/a C399863 i L Amber Glass Greenwood BX9579 H2SO4 R-3779C 10-01-03 n/a — Y65807-18 GZA-3 Aqueous 10/9/03 14:10 MA DEP EPH Carbon Ranges Only Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C399860 1 LAmberGlass JGreenwood BX9579 H2SO4 R-3779C 10-01-03 n/a Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Data Certification Project: Hubbard Oil/Brooks Rd./BO02-3490 Lab ID: 65807 Client: Bennett&O'Reilly,Inc. Received: 10-10-03 15:50 EPCompendrurn�fAnaly�t��Methods�w 'Project Location: n/a MA DEP RTN: n/a This Form provides certifications for the following data set: MA DEP VPH: 65807-05,06,-07,08,09;10,-11 MA DEP EPH: 65807-12,-13,-14,-15,-16,-17,-18 EPA 601OB: 65807-01,-02;03,04 Sample Matrices: Groundwater (X) Soil/Sediment. ( ) Drinking Water ( j Other ( ) tutCP S1Ni 8260E ( ) 8151A ( ) 8330 ( ) 6010B (X) 7470A/1A ( ) 8270C ( ) 8081A ( ) VPH (X) 6020 O 9012A� ( ) As specified r tvtYDE 8082 ( ) 8021 B ( ) EPH (X) 7000 S3 ( ) Other ( ) Corrtpe dia eoiAnalyti�ai �LStRetease �g Numb�RTN}ia3t a ftw N1eSf ods � � 5�84b Mekh 9a 2R[14 aTan tc 9% �or . , Pk ysr fogs l aila le Lya IRA cho c eekall thaapply S'SCJSfi hletods70Da S r es�1s€ndEv duaimeE o arz<analyte s ry. _. R An affirmative response to questions A,B,C and D is required for"Presumptive Certainty"status. A. Were all samples received by the laboratory in a condition consistent with that described on the Chain-of-Custody documentation for the data set? Yes B. Were all QA/QC procedures required for the specified analytical method(s) included in this report followed,including the requirement to note and discuss in a narrative QC data that did not meet appropriate performance standards or guidelines? Yes C. Does the analytical data included in this report meet all the requirements for"Presumptive Certainty;'as described in Section 2.0 of the MA DEP document CAM VII A,Quality Assurance and Quality Control Guidelines for the Acquisition and Reporting of Analytical Data? No D. VPH and EPH methods only: Was the VPH or EPH method run without significant modifications,as specified in Section 11.3? Yes A response to questions E and F below is required for"Presumptive Certainty"status. E. Were al QC performance standards and recommendations for the specified methods achieved? Yes F. Were results for all analyte-list compounds/elements for the specified method(s)reported? No All No answers are addressed in the attached Project Narrative. 1,the undersigned,attest under the pains and penalties of perjury that,based upon my personal inquiry of those responsible for obtaining the information,the material contained in this analytical report is,to the best of my knowledge and belief,accurate and complete. Signature: {y�� Position: President Printed Name: Jonathan R.Sanford Date: 10-27-03 Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Trace Metals Field ID: MW-5S Matrix: Aqueous Project: Hubbard Oil/Brooks Rd./BO02-3490 Container: 500 mL Plastic Client: Bennett&O'Reilly,Inc. Preservation: HNO3/Cool Laboratory ID: 65807-01 Preserved: 10-09-03 12:05 Sampled: 10-09-03 12:05 Received: 10-10-03 15:5 0 Analysis MethQc QC Batch ID Prep Method Prepared Sample Volume Instrument ID An I s EPA 601013' MM-1770-W EPA 3015 10-15-03 10:30 50 mL ICP-2 PE 3300 MWR 31 ������������� � —� xR Ofin lam t ;+ Analyzed5, ,�MettOd��att�on�,�_,�: Notes aC�nits� en s_.��,...�F;� _ . �,, r ..7439-92-1 .008 mg/L 0.006 1 10-24-03 10:52 EPA 60106' Method Reference: Test Methods for Evaluating Solid Waste,US EPA,SW-846,Third Edition,Update III(1996). Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. DF Dilution Factor. Gmundwater Analvtical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Trace Metals Field ID: MW-6S Matrix: Aqueous Project: Hubbard Oil/Brooks Rd./0002-3490 Container: 500 mL Plastic Client: Bennett&O'Reilly,Inc. Preservation: HNO3/Cool Laboratory ID: 65807-02 Preserved: 10-09-03 10:00 Sampled: 10-09-03 10:00 Received: 10-10-03 15:50 Analysis Method QC Batch ID Prep Method Prepared Sample Volume Instrument ID Analys EPA 50106' MM-1770-W EPA 3015 10-15-03 10:30 50 mL 1cP-2 PE 3300 MWR ,CAS Number gAnalyte x Concentration r Notes Untts xe�urtmgi;m�tDF Anal. ed Method �a:....e«' r,& .,:::.,,, .�.m�x..: .�.,'s 7439-92-1 Lead,Total BRL mg/L 0.006 1 10-24 03to:57 EPA 6otoB' Method Reference: Test Methods for Evaluating Solid Waste,US EPA,SW-846,Third Edition,Update III(1996). Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. DF Dilution Factor. i Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay,MA 02532 GROUNDWATER ANALYTICAL Trace Metals Field ID: MW-6D Matrix: Aqueous Project: Hubbard Oil/Brooks Rd./BO02-3490 Container: 500 mL Plastic Client: Bennett&O'Reilly,Inc. Preservation: HNO3/Cool Laboratory ID: 65807-03 Preserved: 10-09-03 13:20 Sampled: 10-09-03 13:20 Received: 10-10-03 15:50 Analysis Method QC Batch ID Prep Method Prepared Sample Volume Instrument ID Analyst EPA 6010B' MM-1770-W EPA 3015 10-1 S-03 10:30 50 mL 1ce-2 Pe 3300 MWR . rs on i DF Analyzed Met ode .. �'GA3�Number�� 'Analytrek � �. �Concentra ngir a� 7439-92-1 Lead,Total BRL mg/L 0.006 1 10-24-03 11:03 1 EPA 60106' Method Reference: Test Methods for Evaluating Solid Waste,US EPA,SW-846,Third Edition,Update III(1996). Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. DF Dilution Factor. l.rnttndwater Analvtical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Trace Metals Field ID: GZA-2 Matrix: Aqueous Project: Hubbard Oil/Brooks Rd.;BO02-3490 Container: 500 mL Plastic Client: Bennett&O'Reilly,Inc. Preservation: HNO3/Cool Laboratory ID: 65807-04 Preserved: 10-09-03 13:45 Sam pled: 10-09-03 13:45 Received: • 10-10-0315:50 Analysis Method OC Batch ID Prep Method Prepared Sample Volume Instrument ID nal s EPA 60106' MM-1770-W EPA 3015 10-15-03 10:30 50 mL ICP-2 PE 3300 MWR '""�. .aF.3s F - :. ±q' � R ort�n�me`t y9 Andls�rrM"etllOd GAS Number , Analyte w.:° Con.centration��l tes kJn is ;MR " � MDF � _ 7439-92-1 Lead,Total BRL mg/L 0.006 1 10-24-03 11:08 EPA 6010B' Method Reference: Test Methods for Evaluating Solid Waste,US EPA,SW-846,Third Edition,Update III(1996). Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. DF Dilution Factor. (:rniinriwatPr Analvtical. Inc.. P.O. Box 1200, 228 Main Street, Buzzards Bay,MA 02532 GROUNDWATER ANALYTICAL Massachusetts DEP VPH Method Volatile Petroleum Hydrocarbons by GC/PID/FID Field ID: MW-5s Matrix: Aqueous. Project: Hubbard Oil/Brooks Rd./BO02-3490 Container: 40 mL VOA Vial Client: Bennett&O'Reilly,Inc. Preservation: HCl/Cool QC Batch ID: VG1-1818-W Laboratory ID: 65807-05 Sampled: 10-09-03 12:05 Instrument ID: GC-1 HP 5890 'Received: 10-10-03 15:50 Sample Volume: 5 mL Analyzed: 10-23-03 13:55 Dilution Factor: 1 Analyst: PO V+PHRanges a `a y r � ' Concentrattonr� Note s .r��[7njfsW. ro� Reott >rmtKT n-05 to n-C8 Aliphatic Hydrocarbons to BRL .ug/L 20 n-C9 to n-C12 Aliphatic Hydrocarbons t® BRL ug/L 20 n-C9 to n-C10 Aromatic Hydrocarbons t BRL ug/L 20 Unadiusted n-,--5 to n-C8 Ali hatic 20 H drocarbons t BRL ug/L Unadiusted n-C9 to n-C12 Aliphatic Hydrocarbons t BRL ug1 20 CA N tuber yAltalyte, � g� 'F roncenrtton r .R.1ofeS� Urtlts ,�RePR gLm .. -. 1634 04 Methyl fert-but I Ether° BRL ug/L 5 4 71-43-2 Benzene" BRL ug/L 1 108-88-3 Toluene A BRL ug/L 5 10041-4. Eth (benzene# BRL ug/L' 5 L' . -_ 108-38-3 and 1067�1 eta-X lene and ara-X lenez BRL. ug/L 5 95-47-6 rtho- X leneBRL ug/L 5 91-20-3 aphthalene BRL ug/L 5 - r ::Spiked Measured �rRecovery� ' � QeLim is .3 ._ Surrogat��mTounlf, 2,5-Dibromotoluene(PID) 100 109 109 % 70-130 2,5-Dibromotoluene(FID) 100 110 109 % 70-130% 1. Were all QArQC procedures required by the method followed? Yes 2. Were all performance/acceptance standards for the required QA/QC procedures achieved? Yes 3. Were any sig lificant modifications made to the method,as specified in Section 11.3.2.1? No Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompanying signed project cover letter. The accompanying cover letter,project narrative and quality control report are considered part of this data report. Method Reference: Method for the Determination of Volatile Petroleum Hydrocarbons,MA DEP(1998). Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting in that range. 0 n-05 to n-C8 Aliphatic Hydrocarbons range data excludes the method target analyte concentrations. ® n-C9 to n-C12 Aliphatic Hydrocarbons range data excludes the method target analyte concentrations and the concentration for the n-C9 to n-C10 Aromatic Hydrocarbons range. tt Analyte elutes in the n-05 to n-C8 Aliphatic Hydrocarbons range. t Analyte elutes in the n-C9 to n-C12 Aliphatic Hydrocarbons range. Groundwater Analytical, Inc, P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Massachusetts DEP VPH Method Volatile Petroleum Hydrocarbons by GC/PID/FID Field ID: MW-51) Matrix: Aqueous Project: Hubbard Oil/Brooks Rd./0002-3490 Container: 40 mL VOA Vial Client: Bennett&O'Reilly,Inc. Preservation: HCl/Cool Laboratory ID: 65807-06 QC Batch ID: VG1-1818-W Sampled: 10-09-03 12:30 Instrument ID: GC-1 HP 5890 Received: 10-10-03 15:50 Sample Volume: 5 mL Analyzed: 10-23-03 22:37 Dilution Factor: 5 Analyst: PO c,-, -F_ .� a, Not F "�.� . � '1 Concentratton fr _ °es �Urt ts� Ty ort� `t ` tni,UPH Ran es n-05 to n-C8 Ali hatic Hydrocarbons t0 BRL ug/L 100 n-C9 to n-C12 Aliphatic Hydrocarbons t® BRL ug/L. 100 n-C9 to n-C10 Aromatic Hydrocarbons' BRL ug/L 100 Unadiusted n-05 to n-C8 Aliphatic Hydrocarbons t BRL ug/L 100 Unadiusted n-C9 to n-C12 Aliphatic Hydrocarbons t BRL ug/L 100 Concentration :: oP57 172 Ut?IS Reporting t,m,t -AS N�umkaer,',xAnal e � d 0 71Q; 1634-04-4 Methyl tert-bu I Ether:: BRL ug/L 25 71-43-2 Benzene II BRL ug/L: 5 108-88-3 Toluene rr BRL ug/L 25 100=41-4 Eth (benzene# BRL ug/L 25 108-38-3 and 10642•3 meta-X lene and para-X lene# BRL ug/L 25 95-47-6 ortho- X lene BRL ttg/L 25 91-20-3 Naphthalene BRL ug/L 25 "Man _>_ .. .. .rx pted,lvteasued . . Re W _ ... _.. .-. 2,5-Dibromotoluene(PID) 100 99 99 % 70-130 2,5-Dibromotoluene(FID) 100 97 97 % 70-130% QAIQC Cert(ftcattart n .m 1. Were all QA/QC procedures required by the method followed? Yes 2.Were all performance/acceptance standards for the required QA/QC procedures achieved? Yes 3. Were any sig-iificant modifications made to the method,as specified in Section 11.3.2.1? No Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompanying signed project cover letter. The accompanying cover letter,project narrative and quality control report are considered part of this data report. Method Reference: Method for the Determination of Volatile Petroleum Hydrocarbons,MA DEP(1998). Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting in that range. 0 n-05 to n-C8 Aliphatic Hydrocarbons range data excludes the method target analyte concentrations. ® n-C9 to n-C12 Aliphatic Hydrocarbons range data excludes the method target analyte concentrations and the concentration for the n-C9 to n-C10 Aromatic Hydrocarbons range. u Analyte elutes in the n-05 to n-C8 Aliphatic Hydrocarbons range. # Analyte elutes in the n-C9 to n-C12 Aliphatic Hydrocarbons range. (-rnrinrlwatPr Analvtical. Inc.. P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Massachusetts DEP VPH Method Volatile Petroleum Hydrocarbons by GC/PID/FID Field ID: MW-6S Matrix: Aqueous Project:. Hubbard Oil/Brooks Rd./BO02-3490 Container: 40 mL VOA Vial Client: Bennett&O'Reilly,Inc. Preservation: HCl/Cool Laboratory ID: 65807-07 QC Batch ID: VG1-1818-W Sampled: 10-09-03 13:00 Instrument ID: GC-1 HP 5890 Received: 10-10-03 15:50 Sample Volume: 5 mL Analyzed: 10-23-03 16:33 Dilution Factor: 5 Analyst: PO UPHRa�nes � - .:, . _ Caneenfrato =otes _, n-05 to n-C8 Aliphatic Hydrocarbons t° BRL ug/L 100 n-C9 to n-C12 Ali hatic Hydrocarbons" BRL ug/L 100 n-C9 to n-C10 Aromatic Hydrocarbons' 130 ug/L 100 Unadiusted n-05 to n-C8 Ali hatiS H drocarbons t BRL ug/L 100 Unadiusted n-C9 to n-C12 Aliphatic Hydrocarbons t 180 ug/L 100 each ° a= r - ' tCOACentl`rdtlOn.,. -,-., �` ' NOLEs .; I�ItYtS r . p Rmg Lcm�t CAS NumberF �A�nalyte �`",. - 1634-04-4 —Methyl tert but I Ether" BRL ug/L 25� 71-43-2 Benzene° BRL ug/L 5 108-88-3 Toluene° BRL ug/L 25 100-41-4 Eth (benzene: BRL ug/L 25 108-38-3 and 106-42.3 meta-X lene and ara-Xylene t 35 ug/L 25 95-47-6 ortho- X lene# 36 ug/L 25 91-2073 Naphthalene BRL ug/L 25 QCzSLr or gate C pound s; �.$pted ./1t8aSUY�e°:d - 2,5-Dibromotoluene(PID) 100 104 104 % 70-130 2,5-Dibromotoluene(FID) 1o0 97 97 % 70-130 _ p # -% �..,,'�_, mx,,..�i..<.. sv,�t.. My 1. Were all QA/QC procedures required by the method followed?� r Yes 2. Were all performance/acceptance standards for the required QA/QC procedures achieved? Yes . 3. Were any significant modifications made to the method,as specified in Section 11.3.2.1? No Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompanying signed project cover letter. The accompanying cover letter,project narrative and quality control report are considered part of this data report. Method Reference: Method for the Determination of Volatile Petroleum Hydrocarbons,MA DEP(1998). Report Notations: BRL Indicates concentration,if any,is.below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting in that range. 0 n-05 to n-C8 Aliphatic Hydrocarbons range data excludes the method target analyte concentrations. ® n-C9 to n-C12 Aliphatic Hydrocarbons range data excludes the method target analyte concentrations and the concentration for the n-C9 to n-C10 Aromatic Hydrocarbons range. tt Analyte elutes in the n-05 to n-C8 Aliphatic Hydrocarbons range. t Analyte elutes in the n-C9 to n-C12 Aliphatic Hydrocarbons range. C,rniinriwater Analvtical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay,MA 02532 GROUNDWATER ANALYTICAL Massachusetts DEP VPH Method Volatile Petroleum Hydrocarbons by GC/PID/FID Field ID: MW-613 Matrix: Aqueous Project: Hubbard Oil/Brooks Rd./BO02-3490 Container: 40 mL VOA Vial Client: Bennett&O'Reilly,Inc. Preservation: HCl/Cool Laboratory ID: 65807-08 QC Batch ID: VG1-1818-W Sampled: 10-09-03 13:20 Instrument ID: GC-1 HP 5890 Received: 10-10-03 15:50 Sample Volume:. 5 mL Analyzed: 10-23-03 15:12 Dilution Factor: 1 Analyst: PO n C5 to n-C8 Aliphatic H drocarbons+o BRL ug/L 20 n-C9 to n-C12 Aliphatic Hydrocarbons+® BRL ug/L. 20 n-C9 to n-C10 Aromatic Hydrocarbons t BRL ug/L 20 Unadjusted r.- 5 to n-C8 Aliphatic Hydrocarbons+ _BRL ug/L 20 Unadiusted r-C9 to n-C12 Aliphatic Hydrocarbons+ BRL �AS'rNu ber ..A alyte .. 7 ` :: ' & -sCom entraton :+iotes� .. Urttfs KeportmgL�m� 1634-04-4 Methyl tert-but I Ether A BRL ug/L 5 71-43-2 Benzene° BRL ug/L 1. 108-88-3 Toluene° - BRL ug/L 5 100-41-4 Eth (benzene# BRL ug/L 5 108.38-3 and 10642-3 meta=X lene and Para-Xylene BRL. ug/L 5 95-47-6 ortho- X lene t BRL ug/L 5 91-20-3 Naphthalene BRL ug(L 5 + ' S tked Measu d Reco eryQC LrmrtSa _ 2,5-Dibromotoluene(PID) 100 108 108 70=130% 2,5-Dibromotoluene(FID) 100 105 105 % 70-130% 1. Were all QA/QC procedures required by the Method followed? Yes 2. Were all performancelacceptance standards for the required QA/QC procedures achieved? Yes 3. Were any significant modifications made to the method,as specified in Section 11.3.2.1? No Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompanying signed project cover letter. The accompanying cover letter,project narrative and quality control report are considered part of this data report. Method Reference: Method for the Determination of Volatile Petroleum Hydrocarbons,MA DEP(1998). Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting in that range. 0 n-05 to n-C8 Aliphatic Hydrocarbons range data excludes the method target analyte concentrations. ® n-C9 to n-C12 Aliphatic Hydrocarbons range data excludes the method target analyte concentrations and the concentration for the n-C9 to n-C10 Aromatic Hydrocarbons range. tt Analyte elutes in the n-05 to n-C8 Aliphatic Hydrocarbons range. # Analyte elutes in the n-C9 to n-C12 Aliphatic Hydrocarbons range. Croundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Massachusetts DEP VPH Method Volatile Petroleum Hydrocarbons by GC/PID/FID Field ID: GZA-1(D) Matrix: Aqueous Project: Hubbard Oil/Brooks Rd.!BO024490 Container: 40 mL VOA Vial Client: Bennett&O'Reilly,Inc. Preservation: HCl/Cool Laboratory ID: 65807-09 QC Batch ID: VG1-1818-W Sampled: 10-09-03 15.00 Instrument ID: GC-1 HP 5890 Received: 10-10-03 15:50 Sample Volume: 5 mL Analyzed: 10-23-03 17:14 Dilution Factor: 1 Analyst: PO n-05 to n-C8 Aliphatic Hydrocarbons t0 BRL ug/L 20 n-C9 to n7C12 Aliphatic H drocarbons'® BRL ug/L 20 n-C9 to n-C10 Aromatic Hydrocarbons' BRL ug/L 20 Unadiusted n-05 to n-C8 Aliphatic Hydrocarbons t BRL ug/L 20 Unadiusted n-C9 to n-C12 Aliphatic Hydrocarbons' BRL ug/L 20 ryQCSurgateCompound r �, Sptked INeasured Reaouery ,' QG Li'tntts 2,5-Dibromotoluene(PID) 100 103 103 % 70-130% !I 2,5-Dibromotoluene(FID) 100 101 101 % 70-130 [, a 1. Were all QA/QC procedures required by the method followed?. Yes 2. Were all performance/acceptance standards for the required QA/QC procedures achieved? Yes 3. Were any significant modifications made to the method,as specified in Section 11.3.2.1? No Method nonconormances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompa_ny'ing signed project cover letter. The accompanying cover letter,project narrative and quality control report are considered part of this data report. Method Reference: Method for the Determination of Volatile Petroleum Hydrocarbons,MA DEP(1998). Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte: Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting in that range. 0 n-05 to n-C8 Aliphatic Hydrocarbons range data excludes the method target analyte concentrations. ® n-C9 to n-C12 Aliphatx Hydrocarbons range data excludes the method target analyte concentrations and the concentration for the n-C9 to n-Cl0 Aromatic Hydrocarbons range. tt Analyte elutes in the n-05 to n-C8 Aliphatic Hydrocarbons range. $ Analyte elutes in the n-C9 to n-C12 Aliphatic Hydrocarbons range. Gro:.lndwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Massachusetts DEP VPH Method Volatile Petroleum Hydrocarbons by GGPID/FID Field ID: GZA-2 Matrix: Aqueous Project: Hubbard Oil/Brooks Rd./13002-3490 Container: 40 mL VOA Vial Client: Bennett&O'Reilly,Inc. Preservation: HCl/Cool Laboratory ID: 65807-10 QC Batch ID: VG1-1818-W Sampled: 10-09-03 13:45 Instrument ID: GC-1 HP 5890 Received: 10-10-03 15:50 Sample Volume: 5 mL Analyzed: 10-23-03 17:54 Dilution Factor: 1 Analyst: PO �VPH3 di1'geS ' �',...:,'' ' , c•. `'"' - ` - - +z ��` COnCQntrrdtlOn - �NOteS �l)nt RepoR�gU,m� n-05 to n-C8 Aliphatic Hydrocarbons to BRL ug/L 20 n-C9 to n-C12 Aliphatic Hydrocarbons to BRL ug/L 20 n-C9 to n-C10 Aromatic Hydrocarbons' BRL ug/L 20 Unadiusted n-05 to n-C8 Aliphatic Hydrocarbons t BRL ug/L 20 Unadiusted n-C9 to n-C12 Aliphatic Hydrocarbons t BRL ug/L 20 *Ci�S�Nur�bec Anal a `�' � � � s ;`� �Co�centrattan � ��,hkoti,�es •: �,. rttfs .,�----+t p m,>g., 1634-04-4 Meth I tert-bu I Ethertt BRL ug/L 5 71-43-2 Benzene" BRL ug/L 1 108-88=3 Toluene° _._ __ -- BRL ug/L.. 5-_._-_: 100-414 Eth (benzene$ BRL ug/L 5 108-38-3 and 10642-3 meta-X lene and para-X lene# BRL ug/L 5 . 95-47-6 ortho- X lene$ . BRL ug/L 5 ::] 91-20-3 Naphthalene BRL ug/L 5 Ty " `• a. '"' ` C L1RIttS "` EA C Surro ate Com" ound S aced JNeasure k Recovery 2,5 Dibromotoluene(PID) 100 104. 104 % 70-130% .� 2,5-Dibromotoluene(FID) 100 1.03 103 % 70 130.% T.-°.. 1.�Were all QA/QC procedures required by the method followed? Yes_ 2. Were all performance/acceptance standards for the required QA/QC procedures achieved? Yes 3. Were any significant modifications made to the imethod,as specified in Section 11.3.2.1? No Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompanying signed project cover letter. The accompanying cover letter,project narrative and quality control report are considered part of this data report. Method Reference: Method for the Determination of Volatile Petroleum Hydrocarbons,MA DEP(1998). Report Notations: BRL Indicates concentration,if any;is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified uncer routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting in that range. 0 n-05 to n-C8 Aliphatic Hydrocarbons range data excludes the method target analyte concentrations. ® n-C9 to n-C12 Aliphatic Hydrocarbons range data excludes the method target analyte concentrations and the concentration for the n-C9 to n-C10 Aromatic Hydrocarbons range. u Analyte elutes in the n-05 to n-C8 Aliphatic Hydrocarbons range. # Analyte elutes in the n-C9 to n-Cl 2 Aliphatic Hydrocarbons range. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Massachusetts DEP VPH Method Volatile Petroleum Hydrocarbons by GGPID/FID Field ID: GZA-3 Matrix: Aqueous Project: Hubbard Oil/Brooks Rd./B002-3490 Container: 40 mL VOA Vial Client: Bennett&O'Reilly,Inc. Preservation: HCl/Cool Laboratory ID: 65807-11 QC Batch ID: VG1-1818-W Sampled: . 10-09-03 14:10 Instrument ID: GC-1 HP 5890 Received: 10-10-03 15:50 Sample Volume: 5 mL Analyzed: 10-23-03 18:35 Dilution Factor: 1 Analyst: PO - n-05 to n-C8 Aliphatic Hydrocarbon t0 BRL ug/L 20. n-C9 to n-C12 Aliphatic Hydrocarbons t® BRL ug/L 20 n-C9 to n-C10 Aromatic Hydrocarbons' BRL ug/L 20 Unadiusted n-CS to n-C8 Ali hatic Hydrocarbons t BRL ug/L 20 Unadiusted n-C9 to n-C12 Aliphatic H drocarbons t BRL ug/L 20 QG Srro, ate ComP'ound. _SpikedeMeasured 2,5-Dibromotoluene..(PID) 100 102 102 % 70-130 2,5-Dibromotoluene(FID) 100 101 101 %. 70-130°/° x- ,3i ;. ox � s,QQC..�ert4flCatl nr?ar`,k:. z -fix 1. Were all QA/QC procedures required by the method followed? Yes 2. Were all performance/acceptance standards for the required QA/QC procedures achieved? Yes 3. Were any significant modifications made to the method,as specified in Section 11.3.2.1? No Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality . control report. (Release of this data is authorized by the accompanying signed project cover letter. The accompanying cover letter,project narrative and quality control report are considered part of this data report. Method Reference: Method for the Determination of Volatile Petroleum Hydrocarbons,MA DEP(1998). Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte: Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting in that range. 0 n-05 to n-C8 Aliphatic Hydrocarbons range data excludes the method target analyte concentrations. ® n-C9 to n-C12 Aliphatic Hydrocarbons range data excludes the method target analyte concentrations and the concentration for the n-C9 to n-C10 Aromatic Hydrocarbons range. zc Analyte elutes in the,n-05 to n-C8 Aliphatic Hydrocarbons range. # Analyte elutes in the n-C9 to n-C12 Aliphatic Hydrocarbons range. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL "ICAL Massachusetts DEP EPH Method Extractable Petroleum Hydrocarbons by GC/FID Field ID: MW-55 Matrix: Aqueous Project: Hubbard Oil/Brooks Rd./BO02-3490 Container: 1 L Amber Glass Client: Bennett&O'Reilly,Inc. Preservation: H2SO4/Cool Laboratory ID: 65807-12 QC Batch ID: EP-1280-F Sampled: 10-09-03 12:05 Instrument ID: GC-9 Agilent 6890 Received: 10-10-03 15:50 Sample Volume: 1,000 mL Extracted: 10-21-03 14:00 Final Volume: 1 mL Analyzed(AL): 10-24-03 00.52 Aliphatic Dilution Factor. 1 Analyzed(AR): 10-24-03 01:36 Aromatic Dilution Factor: 1 Analyst AG z'w_a.trzs...�.dr.. .Y+,v'� ..a`�`.'. k°.i A.., ae..�. .. a.wvY.-..:,.ra,Sm,�_ ,x-»..w, N.z.wR.z�,' ,x✓ �.«z ;�,a�' ..,._s n-C9 to n-C18 Aliphatic Hydrocarbons t BRL ug/L 500 n-C19 to n-C36 Aliphatic Hydrocarbons t BRL ug/L 500 n-Cl1 to n-C22 Aromatic Hydrocarbons}0 BRL ug/L 160 Unadjusted n-C11 to n-C22 Aromatic H drocarbons t BRL ug/L 160 -m x�xrtix'�'T' F � ��;- � �. > �„r x�„y s- �-�- k' 1 _•� .> C'�Im IfS fi �^ -;;t Fractionation. 2-Fluorobiphenyl 40 36 90 % 40-140% 2-Bromonaphthalene 40 22. 55% 40-140% Extraction: Chloro-octadecane 40 32 80 % 40-140%- ortho-Terphenyl 40 37 92 % 40-140% ��q,�(.Z '«ertlflCatlOit °�� µ`e�:,..� ,ff ��QC,�arC.,�,.,,....«,�,.,�.-,�.�� �9.w�. .. '#.a>, � s� 4��:.. ;a_:a�ar,�'��.�:e Yes 1. Were all QA/QC procedures required by the method followed? 2. Were all performance/acceptance standards for the required QA/QC procedures achieved? Yes 3. Were any significant modifications made to the method,as specified in Section 11.3? No Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality. control report. Release of this data is authorized by the accompanying signed project cover letter. The accompanying cover letter,project narrative and quality control report are considered part of this data report. Method Reference: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998). Sample extraction performed by separatory funnel technique. Report Notations: BRL Indicates concentration,if any,is below,reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting in that range. 0 n-C11 to n-C22 Aromatic Hydrocarbons range data excludes the method target analyte concentrations. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL EPA Method 8270C(Modified) MA DEP EPH Polynuclear Aromatic Hydrocarbons by GC/MS-SIM Field ID: MW-5S Matrix: Aqueous Project: Hubbard Oil/Brooks Rd./BO02-3490 Container: 1 L Amber Glass Client: Bennett&O'Reilly,Inc. Preservation: H2SO4/Cool Laboratory ID: 65807-12 QC Batch ID: EP-1280-F Sampled: 10-09-03 12:05 Instrument ID: MS-6 HP 6890 Received: 10-10-03 15:50 Sample Volume: 1,000 mL Extracted: 10-21-03 14:00 Final Volume: 1 mL Analyzed: 10-23-03 16:56 Dilution Factor: 1 Analyst: ]]T 2n�rat O 4� "°. `01:eSa'S rn.�s i �ReporEirtglim Via- _.�- 91-20-3 Naphthalene BRL ug/L 0.5 91-57-6 2-Methylnaphthalene BRL ug/L 0.5 208-96-8 Acenaphthylene BRL ug/L 0.5 83 32 9 Acenaphthene BRL ug/L 0.5 86-73-7 Fluorene BRL ug/L 0.5 85-018 Phenanthrene BRL ug/L 0.5 120-12-7 Anthracene BRL ug/L 0.5 206-44-0 Fluoranthene BRL ug/L 0.5 129-00-0 Pyrene- BRL. ug/L . 0.5 56-55-3 Benzo[a]anthracene BRL ug/L 0.1 218-01-9 Chrysene BRL ug/L 0.1. 205-99-2 Benzo[b]fluoranthene BRL ug/L 0.1 207-08-9 Benzo[k]fluoranthene BRL ug/L 0.1 50-32-8 Benzo[a]pyrene BRL ug/L 0.1 193-39-5 Indeno[1,2,3-c,d]pyrene BRL ug/L 0.1 53-70-3 Dibenzo[a,h]anthracene BRL ug/L 0.1 191-24-2 Benzo[g,h,ilperylene BRL ug/L 0.1 QGSurogaYe Compound Ef _ SpaLCedMeasured..K ,Recovery ... . :.: Q x ,.w _., ortho-Terphenyl 40 34 85 % 40-140% Method Reference: Test Methods for Evaluating Solid Waste,US EPA,SW-846,Third Edition,Update III(1996). Method modified by use of selected ion monitoring(SIM)in accordance with Section 7.5.5 of the method. Method protocol modified to include acidification and the surrogate compound in accordance with the MA DEP Method for the Determination of Extractable Petroleum Hydrocarbons. Sample extraction performed by EPA Method 3510C. Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. I Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Massachusetts DEP EPH Method Extractable Petroleum Hydrocarbons by GC/FID Field ID: MW-51) Matrix: Aqueous Project: Hubbard Oil/Brooks Rd./8002-3490 Container: 1 L Amber Glass Client: Bennett&O'Reilly,Inc. Preservation: H2SO4/Cool Laboratory ID: 65807-13 QC Batch ID: EP-1280-F Sampled: 10-09-03 12:30 Instrument ID: GC-9 Agilent 6890 Received: 10-10-03 15.50 Sample Volume: 1,000 ml- Extracted: 10-21-03 14:00 Final Volume: , 1 mL Analyzed(AL): 10-24-03 02.20 Aliphatic Dilution Factor: 1 Analyzed(AR): 10-24-03 03.05 Aromatic Dilution Factor: 1 Analyst: AG t x l [1`ItS� 'RepoRmg timrt;�.� �.,_� n-C9 to n-C1 E Aliphatic Hydrocarbons t BRL ug/L 500 n-C19 to n-C36 Aliphatic Hydrocarbons t BRL ug/L 500 n-C11 to n-C22 Aromatic Hydrocarbons." BRL ug/L 1 160 Unadjusted n-C11 to n-C22 Aromatic H drocarbons t BRL ug/L 160 S rkeii ured Meas ' Reeoue QSurrogateCa pounds . ; P. x cF r3 EM Fractionation: 2-Fluorobiphenyl 40 37 93 % 40-140 2-Bromonaphthale.ne 40 33 82 % 40-140% Extraction: Chloro-octadecane 40 39 97 % 40=140%. ortho-Terphenyl 1 40 41 102 % 40-140 �ertlhcatton 1. Were all QA1QC procedures required by the method followed? Yes 2. Were all performance/acceptance standards for the required QA/QC procedures achieved? Yes 3. Were any significant modifications made to the method,as specified in Section 11.3? No Method non-coiformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompanying signed project cover letter. The accompanying cover letter,project narrative and quality control report are considered part of this data report. Method Reference: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998). Sample extraction performed by separatory funnel technique. Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting in that range. 0 n-C11 to n-C22 Aromatic Hydrocarbons range data excludes the method target analyte concentrations. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL EPA Method 8270C(Modified) MA DEP EPH Polynuclear Aromatic Hydrocarbons by GUMS-SIM Field ID:. MW-51) Matrix: Aqueous Project: Hubbard Oil/Brooks Rd./BO02-3490 Container: 1 L Amber Glass Client: Bennett&O'Reilly,Inc. Preservation: H2SO4/Cool Laboratory ID: 65807-13 QC Batch ID: EP-1280-F Sampled: 10-09-03 12:30 Instrument ID: MS-6 HP 6890 Received: 10-10-03 15:50 Sample Volume: 1,000 mL Extracted: 10-21-03 14:00 Final Volume: 1 ml- Analyzed: 10-23-03 17:34 Dilution Factor: 1 Analyst I1T - , CO2ntrdtrOn �' O@5�4 '."U'Nts�r„i'� REPngg1`. ..�= c.- 91-20-3Naphthalene BRL ug/L. 0.5 91-57-6 2-Methylnaphthalene BRL ug/L 0.5 208-96-8 Acenaphthylene BRL ug/L 0.5 83-32-9 Acenaphthene BRL ug/L 0.5 86-73-7 Fluorene BRL ug/L 0.5 85-01-8 Phenanthrene BRL ug/L 0.5 120-12-7 Anthracene BRL ug/L 0.5 206-44-0 Fluoranthene BRL ug/L 0.5 - 129-00-0 - Pyrene - BRL ug/L 0.5 56-55-3 Benzo[a]anthracene BRL ug/L 0.1 218-01-9 Chrysene BRL ug/L 0.1 205-99-2 Benzo[b]fluoranthene BRL ug/L 0.1 207-08-9 Benzo[k]fluoranthene BRL ug/L 0.1 50-32-8 Benzo[a]pyrene BRL ug/L 0.1 193-39-5 Indeno[1,2,3-c,d]pyrene BRL ug/L 0.1 53-70-3 Dibenzo[a,h]anthracene BRL ug/L 0.1 191 24-2 Benzo[g h i]perylene BRL ug/L 0 1 +«`<'" C.(strtt115 c' . "C Surrogate�Go►npouo� � e � 5pikedyeasured� IRecoveta .. Pill— I _ortho-Terphenyl 1 40 35 88 % 40-140% . Method Reference: Test Methods for Evaluating Solid Waste,US EPA,SW-846,Third Edition,Update III(1996). Method modified by use of selected ion monitoring(SIM)in accordance with Section 7.5.5 of the method. Method protocol modified tc include acidification and the surrogate compound in accordance with the MA DEP Method fo•the Determination of Extractable Petroleum Hydrocarbons. Sample extraction performed by EPA Method 3510C. Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Massachusetts DEP EPH Method Extractable Petroleum Hydrocarbons by GC/FID Field ID: MW-6S Matrix: Aqueous Project: Hubbard Oil/Brooks Rd./BO02-3490 Container: 1 L Amber Glass Client: Bennett&O'Reilly,Inc. Preservation: H2SO4/Cool Laboratory ID: 65807-14 QC Batch ID:. EP-1280-F Sampled: 10-09-03 13:00 Instrument ID: GC-9 Agilent 6890 Received: 10-10-03 15:50 Sample Volume: 1,000 mL Extracted: 10-21-03 14:00 Final Volume: 1 mL Aliphatic Dilution Factor: 1 Analyzed(AL): 10 24 03 03 49 Analyzed(AR): 10-24-03 04.33 Aromatic Dilution Factor: 1 Analyst AG x,,-; R Ortm Lima COl7C,gCntrdtlOn_...,..y-.� I�lotes [1.x,ItS`n,. W .� g _� n-C9 to n-C18 Aliphatic Hydrocarbons t BRL ug/L 500 n-C19 to n-C36,Ali hatic Hydrocarbons t BRL ug/L 500 n-C11 to n-C22 Aromatic Hydrocarbons" BRL ug/L 160 Unadjusted n-C11 to n-C22 Aromatic H drocarbons t BRL ug/L 160 �QC-arrogate C pound��"' Fractionation: 2-Fluorobiphenyl 40 37 93 % 40-140 2-Broonaphthalene j 40 25 62 % 40-140 m Extraction: Chloro-octadecane k. 40 34 86 % 40-140% ortho-Terphenyl 1 40 41 102 % 40.-140 1 .. .� Q!uQCettt6catlon �. 1. Were all QA/QC procedures required by the method followed? Yes 2. Were all performance/acceptance standards for the required QA/QC procedures achieved? Yes 3. Were any significant modifications made to the method,as specified in Section 11.32 No Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompanying signed project cover letter. The accompanying cover letter,project narrative and quality control report are considered part of this data report. Method Reference: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998). Sample extraction performed by separatory funnel technique. Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting in that range. 0 n-C11 to n-C22 Aromatic Hydrocarbons range data excludes the method target analyte concentrations. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 0253 GROUNDWATER ANALYTICAL EPA Method 8270C(Modified) MA DEP EPH Polynuclear Aromatic Hydrocarbons by GC/MS-SIM Field ID: MW-6S Matrix: Aqueous Project: Hubbard Oil/Brooks Rd./BO02-3490 Container: 1 L Amber Glass Client: Bennett&O'Reilly,Inc. Preservation: H2SO4/Cool Laboratory ID: 65807-14 QC Batch ID: EP-1280-F Sampled: 10-09-03 13:00 Instrument ID: MS-6 HP 6890 Received: 10-10-03 15:50 Sample Volume: 1,000 mL Extracted: 10-21-03 14:00 Final Volume: 1 mL Analyzed: 10-23-03 18:12 Dilution Factor: 1 Analyst: ]]T W "' �COnCEfltrdtrOn` '`z �` „5F t.-M .:8ep R-017 LImi ..... .. 91-20-3 Naphthalene 2.1 ug/L 0.5 91-57-6 2-Methyl naphthalene 1.2 ug/L 0.5 208-96-8 Acenaphthylene BRL ug/L 0.5 . 83-32-9 Acenaphthene BRL ug/L. 0.5 86-73-7 Fluorene BRL ug/L 0.5 85-01-8 Phenanthrene BRL ug/L 0.5 120-12-7 Anthracene BRL ug/L 0.5 206-44-0 Fluoranthene BRL ug/L 0.5 129-00-0 Pyrene BRL ug/L 0.5 56-55-3 Benzo[a]anthracene BRL ug/L 0.1 218-01-9 Chrysene BRL. ug/L 0.1 205-99-2 Benzo[b]fluoranthene BRL ug/L 0.1 207-08-9 Benzo[k]fIuoranthene BRL ug/L 0.1 50-32-8 Benzo[a]pyrene BRL ug/L 0.1 193-39-5 Indeno[1,2,3-c,d]pyrene BRL ug/L 0.1 53-70-3 Dibenzo[a,h]anthracene BRL ug/L 0.1 191-24-2 Benzo[g,h,i]perylene BRL ug/L 0.1 ,k "M "r - QG Surrogate Compound..,..:." �_1� „,�Sptked,�y,Measured �.,,Recove +� .�ae�.,_ ,�, �Q_ �J =� - 0/6 ortho-Terphenyl 40. 35 88 % 40-140 Method Reference: Test Methods for Evaluating Solid Waste,US EPA,SW-846,Third Edition,Update III(1996). Method modified by use of selected ion monitoring(SIM)in accordance with Section 7.5.5 of the method. Method protocol modified to include acidification and the surrogate compound in accordance with the MA DEP Method for the Determination of Extractable Petroleum Hydrocarbons. Sample extraction performed by EPA Method 3510C. Report Notations: BRL Indicates concentration,if any,is below reporting Limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. Groundwater Analytical, 'Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 f GROUNDWATER ANALYTICAL Massachusetts DEP EPH Method Extractable Petroleum Hydrocarbons by GC/FID Field ID: MW-61) Matrix: Aqueous Project: Hubbard Oil/Brooks Rd./BO02-3490 Container: 1 L Amber Glass Client: Bennett&O'Reilly,Inc. Preservation: H2SO41Cool Laboratory ID: 65807-15 QC Batch ID: EP-1280-F Sampled: 10-09-03 13:20 Instrument ID: GC-9 Agilent 6890 Received: 10-10-03 15:50 Sample Volume: 1,000 mL Extracted: 10-21-03 14:00 Final Volume: 1 mL Analyzed(AL): 10-24-03 05:17 Aliphatic Dilution Factor: 1 Analyzed(AR): 10-24-03 06:01 Aromatic Dilution Factor: 1 Analyst AG Ranges�-� �_" �. >.. �Con�cenfr n-C9 to n-C18 Aliphatic Hydrocarbons+ BRL ug/L 500 0 n-C19 to n-C36 Aliphatic Hydrocarbons t BRL ug/L 160 rr-Cl1 to n-C22 Aromatic Hydrocarbons t o BRL uL Unadjusted n C11 ton C22 Aromatic Hydrocarbons u BRL ug/L 160 red r :. 1ReCoue Yea_. ( CLttitr#S �QG�Surroga#e�Compound � p.��� � � Fractionation 40 39 97 % 40-140 2-Fluorobiphenyl o 2-Bromonaphthalene i 40 31 78 % 40-140 /o Extraction: Ch loro octadecane I 40 34 85 % 40-140% ortho Terphenyl 40 41 103 % 40 140% A/QC Certrficatton �.. 1. Were all QA/QC procedures required by the method followed? Yes Yes 2. Were all performancelacceptance standards for the required QA/QC procedures achieved? No 3. Were any significant modifications made to the method,as specified in Section 11.3? Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompanying signed project cover letter. The accompanying cover letter,project narrative and quality control report are considered part of this data report. Method Reference: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998). Sample extraction performed by separatory funnel technique. Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting in that range. 0 n-C11 to n-C22 Aromatic Hydrocarbons range data excludes the method target analyte concentrations. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL EPA Method 8270C(Modified) MA DEP EPH Polynuclear Aromatic Hydrocarbons by GUMS-SIM Field ID: MW-6D. Matrix: Aqueous Project: Hubbard Oil/Brooks Rd.'BO02-3490 Container: 1 L Amber Glass Client: Bennett&O'Reilly,Inc. Preservation: H2SO4/Cool Laboratory ID: 65807-15 QC Batch ID: EP-1280-F Sampled: 10-09-03 13:20 Instrument ID: MS-6 HP 6890 Received: 10-10-03 15:50 Sample Volume: 1,000 mL Extracted: 10-21-03 14:00 Final Volume: 1 mL Analyzed: 10-23-03 18:51 Dilution.Factor: 1 Analyst: ]]T „CAS Number Analyte _ ._g_ r Cor<cenlratton Notes Units _n 91-20-3 Naphthalene BRL ug/L 0.5 91-57-6 2-Methyl naphthalene BRL ug/L 0.5 208-96-8 Acenaphthylene BRL ug/L 0.5 83-32-9 Acenaphthene BRL ug/L 0.5 86-73-7 Fluorene BRL ug/L 0.5 85-01-8 Phenanthrene BRL, ug/L 0.5 120-12-7 Anthracene BRL ugIL 0.5 20644-0 Fluoranthene BRL ug/L 0.5 129-00 0 Pyrene BRL ug/L 0.5 56-55-3 Be nzo[a]anthracene BRL ug/L 0.1 218-01-9. Chrysene BRL ug/L 0.1 205.99-2 Benzo[b]fluoranthene BRL ug/L 0.1 207-08-9 Benzo[k]fluoranthene BRL ug/L 0.1 50-32-8 Benzo[a]pyrene BRL ug/L 0.1 193-39-5 Indeno[1,2,3-c,d]pyrene BRL ug/L 0.1 53-70-3 Dibenzo[a,h]anthracene BRL ug/L 0.1 191-24-2 Benzo[g,h,i]perylene BRL ug/L 0.1 77 S tked Measured `Recoery C Lmts G G Surrogate Compound ; tom .. ;P.. .--. ortho-Terphenyl 40. 34 1 84 % 40-140% Method Reference: Test Methods for Evaluating Solid Waste,US EPA,SW-846,Third Edition,Update III(1996). Method modified by use of selected ion monitoring(SIM)in accordance with Section 7.5.5 of the method. Method protocol modified to include acidification and the surrogate compound in accordance with the MA DEP Method for the Determination of Extractable Petroleum Hydrocarbons. Sample extraction performed by EPA Method 3510C. Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Massachusetts DEP VPH Method Volatile Petroleum Hydrocarbons by GC/PID/FID Field ID: GZA-3 Matrix: Aqueous Project: Hubbard Oil/Brooks Rd./BO02-3490 Container: 40 mL VOA Vial Client: Bennett&O'Reilly,Inc. Preservation: HCI/Cool Laboratory ID: 65807-11 QC Batch ID: VG1-1818-W Sampled: 10-09-03 14:10 Instrument ID: GC-1 HP 5890 Received: 10-10-03 15:50 Sample Volume: 5 mL Analyzed: 10-23-03 18:35 Dilution Factor: 1. Analyst: PO uPHXdr`xt n-05 to n-C8 Aliphatic Hydrocarbons t° BRL ug/L. 20 n-C9 to n-C12 Aliphatic Hydrocarbons f o BRL- ug/L 20 n-C9 to n-C10 Aromatic Hydrocarbons' BRL ug/L 20 Unadjusted n C5 to n-C8 Aliphatic Hydrocarbons t. BRL ug/L 20 Unadjusted n C9 to n-C12 Aliphatic Hydrocarbons t BRL u t� ug/L 20 rd"fl,Ond `'* ...; n'f,S �Reportirtytimt,-...�. .ws,ns wi. .:3x .ti,.� s, rs�" n `sroc H F> 1634-04-4 Methyl tert-but I Ether' BRL ug/L 5 71-43-2 Benzene" BRL ug/L 1 108-88-3 Toluene° BRL ug/L 5 100-41-4 Eth (benzene$ BRL _ ug/L _ 5 708383 and 10642-3 meta-X lene and para-X lene# BRL ug/L. 5 95-47-6 ortho- X lene# BRL ug/L 5 91-20-3 Naphthalene BRL ug/L i 5 G Si rro aYe Comunds �j, Sptked Measore_ Recauery� po C Vm1`ts 2,5-Dibromotoluene(PID) 100 102 102 % 70-130 2,5-Dibromotoluene(FID) 100 101 101 % 70-130% Certtftcaton m`,atsis' rv,Ms^ �A ..._t'»n LA ...�. .,_...�e.. ..5�? 1- Were all QA/QC procedures required by the nethod followed? Yes 2. Were all performance/acceptance standards for the required QA/QC procedures achieved? Yes 3. Were any significant modifications made to tha method,as specified in Section 11.3.2.1? No Method non-conformances indicated above are dstailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompanying signed project cover letter. The accompanying cover letter,project narrative and quality control report are considered part of t-iis data report. Method Reference: Method for the Determination of Volatile Petroleum Hydrocarbons,MA DEP(1998). Report Notations: BRL Indicates concentrati':)n,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting in that range. 0 n-05 to n-C8 Aliphatc Hydrocarbons range data excludes the method target analyte concentrations. ® n-C9 to n-C12 Aliphatic Hydrocarbons range data excludes the method target analyte concentrations and the concentration for the n-C9 to n-C10 Aromatic Hydrocarbons range. tt Analyte elutes.in the n-05 to n-C8 Aliphatic Hydrocarbons range. t Analyte elutes in the n-C9 to n-C12 Aliphatic Hydrocarbons range. Groundwater Analytical, Inc., P.O. Box 1200,228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Massachusetts DEP EPH Method Extractable Petroleum Hydrocarbons by GUID Field ID: GZA-2 Matrix: Aqueous Project: Hubbard Oil/Brooks Rd./BO02-3490 Container: 1 L Amber Glass Client: Bennett&O'Reilly,Inc. Preservation: H2SO41Cool Laboratory ID: 65807-17 QC Batch ID: EP-1280-F Sampled: 10-09-03 13:45 Instrument ID: GC-9,Agilent 6890 Received: 10-10-03 15:50 Sample Volume: 1,000 ml- Extracted: 10-21-03 14:00 Final Volume: 1 mL Analyzed(AL,: 10-24-03 08:58 Aliphatic Dilution Factor. 1 Analyzed(AR): 10-24-03 09:42 Aromatic Dilution Factor. 1 Analyst: AG If �� m � �Concentrattan a s Notesi I n is Pig s EPH Ranges & r: Re orm Limy n-C9 to n-C18 Aliphatic H drocarbons t BRL ug/L 500 n-C19 to n-C36 Aliphatic Hydrocarbons t BRL ug/L 500 n-CI1 to n-C22 Aromatic Hydrocarbons t° BRL ug/L 160 Unadjusted n-C11 to n-C22 Aromatic Hydrocarbons t BRL ug/L 160 � L_.._- Fractionation. 2-Fluorobiphenyl 40 37. 93 % 40-140 2-Bromonaphthalene 40 36 89 % 40-140% . Extraction: Chloro-octadecane 40 36 91 % 40-140 ortho-Terphenyl 40 41 101 % 40-140 x « CCGtIflCdtton s .w 1. Were all QA,/QC procedures required by the method followed? Yes 2. Were all performance/acceptance standards for the required QA/QC procedures achieved? Yes 3. Were any significant modifications made to the method,as specified in Section 11.3? No Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompanying signed project cover letter. The accompanying cover letter,project narrative and quality control report are considered part of this data report. Method Reference: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998). Sample extraction performed by separatory funnel technique. Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting in that range. 0 n-C11 to n-C22 Aromatic Hydrocarbons range data excludes the method target analyte concentrations. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL EPA Method'8270C(Modified) MA DEP EPH Poiynuclear Aromatic Hydrocarbons by GC/MS-SIM Field ID: GZA-2 Matrix: Aqueous Project: Hubbard Oil/Brooks Rd.1BO02-3490 Container: 1 L Amber Glass Client: Bennett&O'Reilly,Inc. Preservation: H2SO4/Cool Laboratory ID: 65807-17 QC Batch ID: EP-1280-F Sampled: 10-09-03 13:45 Instrument ID: MS-6 HP 6890 Received: 10-10-03 15:50 Sample Volume: 1,000 mL Extracted: 10-21-03 14:00 Final Volume: 1 mL Analyzed: 10-23-03 16:17 Dilution Factor: 1 Analyst ]1T _ x �_cCAS�NUmbe Aral e ' � r;,`�'" 'T t '� u capn�C�elltjrHtlOn �a� §`°�s� iOteS�r ^� t�lt�f� �ReporE� met ,n 91 r20-3 Naphthalene BRL ug/L 0.5. 91-57-6 2-Methyl naphthalene BRL ug/L 0.5 208-96-8 Acenaphthylene BRL ug/L 0.5 83-32-9 Acenaphthene BRL ug/L 0.5 86-73-7 Fluorene BRL ug/L 0.5 85-01-8 Phenanthrene BRL ug/L 0.5 120-12-7 Anthracene BRL ug/L 0.5 206-44-0 Fluoranthene BRL ug/L 0.5 129-00-0 Pyrene BRL ug/L 0.5 56-55-3 Benzo[a]anthracene BRL ug/,L 0.1 218-01-9 Chry'sene BRL . ug/L 0.1 205-99-2 Benzo[b]fluoranthene BRL ug/L 0.1 207-08-9 Benzo[k]fluoranthene BRL ug/L 0.1 50-32-8 Benzo[alpyrene BRL ug/L 0.1 193-39-5 Indeno[1,2,3-c,d]pyrene BRL ug/L 0.1 53-70-3 Dibenzo[a,h]anthracene BRL ug/L 0.1 191-24-2 Benzo[g,h,i]perylene BRL ug/L 0.1 G Surro ate Com,ound .a SJ Iked ;Aleasu ed ltecouery .,•, E2CLmlts a< . ortho-Terphenyl 1 40 1 36 1 90 % 40-140% Method Reference: Test Methods for Evaluating Solid Waste,US EPA,SW-846,Third Edition,Update III(1996). Method modified by use of selected ion monitoring(SIM)in accordance with Section 7.5.5 of the method. Method protocol modified to include acidification and the surrogate compound in accordance with the MA DEP Method for the Determination of Extractable Petroleum Hydrocarbons. Sample extraction performed by EPA Method 3510C. Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. jn- f,rnlrnrlwatP.r Analvtical. Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Massachusetts DEP VPH Method Volatile Petroleum Hydrocarbons by GC/PID/FID Field ID: GZA-1(D) Matrix: Aqueous Project: Hubbard Oil/Brooks Rd./B002-3490 Container: 40 mt.VOA Vial Client: Bennett&O'Reilly,Inc. Preservation: HCI/Cool Laboratory ID: 65807-09 QC Batch ID: VG1-1818-W Sampled: 10-09-03 15:00 Instrument.ID: GC-1 HP 5890 Received: 10-10-03 15:50 Sample Volume: 5 mL Analyzed: 10-23-03 17:14 Dilution Factor: 1 Analyst: PO mCOnCentratrOn x Ote j r1 S ep Rmg L, nif n-05.to n-C8 Ali hatic Hydrocarbons t° BRL ug/L 20 n-C9 to n-Cl2 Aliphatic Hydrocarbons to BRL ug/L 20 n-C9 to n-Cl0 Aromatic Hydrocarbons t BRL ug/L 20 Unadjusted n-05 to n-C8 Aliphatic Hydrocarbons t BRL ug/L 20 Unadjusted n-C9 to n-C12 Aliphatic Hydrocarbons t BRL ug/L. 20 •S.� P . '€- a 4y _ f, ti_,. . F x ;Y^`"}�, - GS IJumb'er �Analyte Tr Concentratonk > Notes w �Urttts RePort���tfr��na 1634-044 Methyl tert-butyl Ether BRL ug/L 5. 71-43-2 Benzene" BRL ug/L 1 108-88-3 Toluene tt BRL ug/L 5 10041-4 Eth lbenzene z BRL ug/L 5 108-38-3 and 10"2-3 meta-X lene and para-X lene# BRL ug/L 5 . 9547-6 ortho- Xylene# BRL ug/L 5 91-20-3 Naphthalene BRL. ug/L 5 G Surrogate Campoundh_ :- �. _,. Spikedt Aleasurecl x pReco uey 2,5-Dibromo:oluene(PID) 100 103 103 % 70-130% 2,5-Dibromo`oluene(FID) 100 101 101 % 70.-130 aNix W `� � .Q,A(QCCerttftcat►on n ; �� P -�.° a�. 1. Were all QPlQC procedures required by the method followed? Yes 2. Were all performance/acceptance standards for the required QA/QC procedures achieved? Yes 3. Were any significant modifications made to the method,as specified in Section 11.3.2.1? No Method non-co formances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is'authorized by the accompanying signed project cover letter. The accompanying cover letter,,project narrative and quality control report are considered part of this data report Method Reference: Method for the Determination of Volatile Petroleum Hydrocarbons,MA DEP(1998). Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte- Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting in that range. 0 n-05 to n-C8 Aliphatic Hydrocarbons range data excludes the method target analyte concentrations. ® n-C9 to n-C12 Aliphatic Hydrocarbons range data excludes the method target analyte concentrations and the concentration for the n-C9 to n-C10 Aromatic Hydrocarbons range. tt Analyte elutes in the n-05 to n-C8 Aliphatic Hydrocarbons range. t Analyte elutes in the n-0 to n-C12 Aliphatic Hydrocarbons range. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Project Narrative Project: Hubbard Oil/Brooks Rd./BO02-3490 Lab ID: 65807 Client: Bennett&O'Reilly, Inc. Received: 10-10-03 15:50 n A 3Documentat�onand Clienti CommunOcatrongc The following documentation discrepancies,and client changes or amendments were noted for this project: 1 . No documentation discrepanc es,changes,or amendments were noted. � �" �"� �B�Method�htod�facatu�ns `onon�orm�nces and Obs ruatron - r� The sample(s) in this project were analyzed by the references analytical method(s),and no method modifications, non-conformances or analytical issues were,noted,except as indicated below: 1 . EPA 6010B Non-conformance:Samples 65807-01,-02,03,04.A matrix spike(MS)sample was not performed in accordance with the minimum field QC requirements of the MA DEP CAM. 2 . EPA 6010B Note:Samples 65607-01,02,03;04.Samples were analyzed for selected target analytes,as requested by client. 3 . MA!DEP EPH Note:Samples 65807-12,-13;14;15;17. Polynuclear aromatic hydrocarbon(PAH)target analytes were identified and quantified by GC/MS-SIM, in accordance with the method provision for alternate determinative methodologies.GUMS-SIM was used to achieve low quantification limits necessary for regulatory compliance. Target analytes were determined utilizing the same sample extract used for carbon range determination by GC/FID. 4. MA DEP EPH Note:Samples 65807-16,-18.Samples;were analyzed for only carbon range analytes,as requested by client. 5 . MA DEP VPH Note: Sample E5807-06,07.Sample was diluted prior to analysis. Dilution was required due to observed foaming characteristics of sample.Sample foaming interfers with purge and trap sample concentration. 6. MA IDEP VPH Note:Samples 6580709;11.Samples were analyzed for only carbon range analytes,as requested by client. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 W� UpN�D �7 TE R Buz Main Street,P.O.Box 1200 Buzzards Bay,MA02532 CHAIN-OF-CUSTODY RECORD 1�1° dD75®46 ANALYTICAL Telephone(508)759-4441•FAX(508)759-4475 AND WORK ORDER B AAA® www.groundwateranalytical.com Project Name: Firm: TURNAROUND ANALYSIS REQUEST II 11 - yy�� k r {� y� h'�l l Volallles Semlvalatlles PeslMerh PCas Metals Petroleum 11 drocarbon . Har. General Chemistry elhe V j B(cUG J a' °t O 1 �- STANDARD(10 Business Days) Exbadaale Uol. Est.T H Vol.TPH Waste Project Number: Address: ❑ PRIORITY(5 Business Days) F o❑ RUSH 9002--3I'70 1S-75 (flush requires Rush Authorization Number) F❑ `❑ 00 A.❑ a a $3- ❑ ❑ Q o = � Sampler Name: `` City/State/Zip: spy / ❑Please Email to: g a 4 �Y2 r1 1 ❑Please FAX to�Nr� 17"4�- ��� o _ o € o ❑ BILLING Project Manager: Telephone: / ❑ ❑ 10 ❑ o ❑ ❑ o s E fR Purchase Order Z41� V s e °g a _ ❑ Third Party Billing: s d U y ° v ° r r INSTRUCTIONS:Use separate line for each container(except replicates). ❑ GWA Quote: n S m M= 3 u e e 6 t) 3 a u a O •3 ❑ A ' O Sampling Matrix Type Contalner(s) Preservation Rltered ❑ 0 0 ❑ ❑ ❑ 0 0 ❑ o ° a o ❑ P 9 n e E o 9 o 2g 0 2 ,s y 3 - LAB12 ORATORY W u 9 a m (o o m v - S = G o _❑ o SAMPLE - J .y - o _ - NUMBER e o t_ a .a n ❑ s ° o o IDENTIFICATIse ON 3 3 ti w > g a o ff s m (Lab Use Only) ¢ m a m m u a a w 5� y{' 0 0 3• s a ❑ t - o 9 ,,, ❑ ❑ F- — 3 — ¢ = S" E .E o E o — E ,Pi — D ❑❑ ❑❑❑ ❑❑ ❑ ❑ ❑ ❑ ❑❑❑❑ �In - f'— 0 G s 0 010101,0 o o o e o S = S z o. ❑ ❑ ❑ 5 0 ❑ ❑ o 0 0 ❑ ❑ ❑ o ❑ a o h G71z:�s 3 I 3 L jL X I S ( J � t r -.5, f�; 1 r (;''. r�3^�: a H .'r�kt s')u:N/1 IX s r s° 3 fir, ,s4, a x .,.,. , . ... ^<.. v oo MW '-3 x � �,�`� f"{�,y ., k::_ - zv y t.. .3,OG � � 3 2 3 z V . Xx Q Ito a, .?t'i rY .v:'.,` a::,a. t sI. x r s.,7-' .— >- ..:: I p;{....;s re. I:-,-ui. .�.. ?+ -ai; �'7 �"f . ., s �.. L ;i, # �. n. . c` -.2.A_ x ., ''3,"d.`I _ 3 Ax , a >t r y y .,ld ��..h ' _w p*^r 'S b,tt 'fir aut41't .sad t ! t ...ej'?lTroa.. * a�;�"•,?� '.I'..:.; ..,+. �� .,xf.:"tm t,.r„y i. ,:4u_ .6. H ° a.. i C f A t h- i. r - T,� 1?V 3 9 IC'H 1 _ t :.. ._ ..,, .. ;...:», .., _:.:+.<., >�..a,;..:..:..,,I�m'i ixr-��.�:nx�fi�, ,..xk :eta +�. ,R. Y.. h.$ �S. .k.S. REMARKS/SPECIAL INSTRUCTIONS. DATA QUALITY OBJECTIVES CHAIN-OF-CUSTODY RECORD Regulatory Program Project Specific QC T . ) amp s submitted subject to Standard Terms and Conditions on reverse hereof. State Standard Deliverables Many regulatory programs and EPA methods require project ®Rel��'#,'�he�d a I oat Time Received by: Receipt Temperature: specific QC.Project specific QC includes Sample Duplicates, cenerdgemted (_{ OCT MCPGW1/S-1 ❑PWSForm Matrix Spikes,'and/orIvlatrixSpike Duplicates.LaboratoryQCIs ID Qr �;�(/ � - 15 1C{ (ruI a<c1aoem—dadnot projecYspecific unless prearranged.Project specific QC D te Time ReceNed by: Container Count: ❑ME ❑MCP GW-2/S•1 ❑ samples are charged on a per sample basis.Each MS,MSD A ❑NY STARS ❑_, and Sam le Du Iicate re uires an additional sample aliquot. tP P q / '❑NH ❑Drinking Water - ❑NY ❑Wastewater Project Specific OC Required - Selection of OC Sample Date Time R jd y Laboratory: Shipping/Airbill ! , Number: - ❑RI ❑Waste Disposal ❑Sample Duplicate ❑Please use sample: �� �„ - Custody Seal GROUNDWATER ANALYTICAL Quality Assurance/Quality Control Groundwater Analytical conducts an active Quality Assurance program to ensure the production of high quality, vapid data. This program closely follows the guidance provided by Interim Guidelines and Specifications for Preparing Quality Assurance Project Plans, US EPA QAMS-005/80 (1980), and Test Methods for Evaluating Solid Waste, US EPA, SW-846, Update III (1996). Quality Control protocols include written Standard Operating. Procedures (SOPs) developed for each analytical method. SOPS are derived from US EPA methodologies and other established references. Standards are prepared from commercially obtained reference materials of certified purity, and documented for traceability. Quality Assessment protocols for most organic analyses include a minimum of one laboratory control sample, one method blank, one matrix spike sample, and one sample duplicate for each sample preparation batch. All samples, standards, blanks, laboratory control samples, matrix spikes and sample duplicates are spiked with internal standards and surrogate compounds. All instrument sequences begin with an initial calibration verification standard and a blank; and excepting GC/MS-sequences, all sequences close with a continuing calibration standard. GC/MS systems are tuned to appropriate ion abundance criteria daily, or for each 12 hour operating period, whichever is more frequent. Quality Assessment protocols for most inorganic analyses include a minimum of one laboratory control. sample, one method blank,one matrix spike sample; and one sample duplicate for each sample preparation batch. . Standard curves are derived from one reagent blank and four concentration levels. Curve validity is verified by standard recoveries within plus or minus ten percent of the curve. Batches are used as the basic unit for Quality Assessment. A Batch is defined as twenty or fewer samples of the same matrix which are prepared together for the same analysis, using the same lots of reagents and the same techniques or manipulations, all within the same continuum of time, up to but not exceeding 24 hours. Laboratory Control Samples are used to assess the accuracy of the analytical method. A Laboratory Control Sample consists of reagent water or sodium sulfate spiked with a group of target analytes representative of the method analytes. Accuracy is defined as the degree-of agreement of the measured value with the true or . expected value. Perent Recoveries for the Laboratory Control Samples are calculated to assess accuracy. Method Blanks are used to assess the level of contamination present in the analytical system. Method Blanks consist of reagent water or an aliquot of sodium sulfate. Method Blanks are taken through all the appropriate steps of an analytical method. Sample data reported is not corrected for blank contamination. Surrogate Compounds are used to assess the effectiveness of an analytical method in dealing with each sample matrix. Surrogate Compounds are organic compounds which are similar to the target analytes of interest in chemical behavior, but which are not normally found in environmental samples. Percent Recoveries are calculated for each Surrogate Compound. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Quality Control Report Laboratory Control Sample Category: Metals Matrix: Aqueous Units: tng/L Analysis Method OC Batch ID Pre�Method Prepared Instrument ID Analys EPA 601013 MM-1770-WL EPA 3015 10-15-0310:30 1cP-2 PE 3300 MWR aly�z CA-StNurnb`erSFpi[ced Measured �z Recoury QCLirn>ts _>F. Anedwaa v Method , 7439 92-1 Lead 1.0 0.99 1 9 % 80-120°i 1 10-24-03 10:47 EPA 6010E Method Reference: Test Methods for Evaluating Solid Waste,US EPA,SW-846,Third Edition,Update III(1996). Report Notations: All calculations performed prior to rounding. Quality Control Limits are defined by the methodology, or alternatively based upon the historical average recovery plus or minus three standard deviation units. t^rnllnrlWatPr Analvtical. Inc.. P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Quality Control Report Method Blank Category: Metals Matrix: Aqueous Analysis Method OC Batch ID Prep Method Prepared Sample Volume Instrument ID Anal s EPA 6010E MM-1770-WB EPA 3015 10-15-03 10:30 50 mL ICP-2 PE 3300 MWR r CA r IN w b;eF r r �k � Arfal zeds '�Metho��`Sum erg ylnalyte � } �Concentrafio�rl t„�ot_es Units Reportmgumrt. D)= ;�� s y�_y . -`�., 7439-92-1 Lead BRL mg/L 1 0.005 t 1)24-03 10:42 EPA 6010B Method Reference: Test Methods for Evaluating Solid Waste,US EPA,SW-846,Third Edition,Update III(1996). Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. DF Dilution Factor. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Quality Control Report Laboratory Control Sample Category: MA DEP EPH Instrument ID: GC-9 Agilent 6890 QC Batch ID: EP-1280-F Extracted: 10-21-03 14:00 Matrix: Aqueous Analyzed(AL): 10-22-03 13:26 Units: ug/L Analyzed(AR): 10-22-03 14:11 Analyst: AG S AS°Number r �. r. _ nat,Y a Spiked Measured -Retl�v U;t 111-84-2 n-Nonane(C9) 50 25 50 % 40-140 629-59-4 n-Tetradecane(C74) 50 29 59 % 40-140 629-92-5 n-Nonadecane(C79) 50 36 73 % 40-140 112-95-8 n-Eicosane(C20) 50 37 74 % 40-140 630-02-4 n-Octacosane(C28) 50 35 69 % 40-140%. - s5 tked. �Measurxd ' E Reco er `�ttmtts. QSurrogate Compounds _ 3 ,.ter P o y Qry ° ;' Fractionation: 2-Fluorobiphenyl 40 32 81 % -140 /° 2-Bromonaphthalene 40 28 70 % 40-140 Extraction: Chloro-odadecane 40 35 86 % 40-140 ortho-Terphenyl 40 36 91 % 40-140% Method Reference: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP 0998). Sample extraction performed by separatory funnel technique. Report Notations: All calculations performed prior to rounding. Quality Control Limits are defined by the methodology, or alternatively based upon the historical average recovery plus or minus three standard deviation units. Grnundwater Analvtical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Quality Control Report Method Blank Category: MA DEP EPH Instrument ID: GC-9 Agilent 6890 QC Batch ID: EP-1280-F Extracted: . 10-21-03 14:00 Matrix: Aqueous Analyzed(AL): 10-22-03 12:02 Analyzed(AR): 10-22-03 12:42 Analyst: AG goic- n-C9 to n-C18 Aliphatic Hydrocarbons t BRL ug/L 500 n C79to n C36 Aliphatic Hydrocarbons.+ BRL ug/L 500 n-C11 to n-C22 Aromatic Hydrocarbons t 0 BRL ug/L 160 Unadjusted n-C11 to n-C22 Aromatic Hydrocarbons t BRL. ug/L 160 z . ^� -$'"- » `"QC LtFitltS 2 ', QC Surrogate Compound. . F_ x : ..,. piked f�Ceasuretl �ry Recouey Fractionatio I.n: 2-Fluorobiphenyl 40 36 91 % 40-140% 2-Bromonaphthalene 40 30 74 % 40-140% Extraction: Chloro-octadecane 40 33 84 % 40-140% ortho-Terphenyl 40 38 95 % 40-140% Method Reference: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998). Sample extraction performed by separatory funnel technique. Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution.' t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting in that range. 0 n-C11 to n-C22 Aromatic Hydrocarbons range data excludes the method target analyte concentrations. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Quality Control Report Laboratory Control Sample Category: EPA Method 8270C(Mod.)-EPH PAHs by GCIMS-SIM Instrument ID: MS-6 HP 6890 QC Batch ID: EP-1280-F Extracted: 10-21-03 14:00 Matrix: Aqueous Analyzed: 10-22-03 19:45 Units: ug/L Analyst: JJT Spied Measured Re-ovetsy _ (�., 91-20-3 Naphthalene 5.0 2.7 N m53'% 40-140 83-32-9 Acenaphthene 5.0 4.4 89 % 40-140 120-12-7 Anthracene 5.0 3.9 78.V 40-140% 129-00-0 Pyrene 5.0 3.8 75 % 40-140% 218-01-9 Chrysene 5.0 4.0 80 % 40-140 7/67 ortho-Terphenyl 40 34 86 % 40-140 Method Refererce: Test Methods for Evaluating Solid Waste,US EPA,SW-846,Third Edition,Update III 11996). Method modified by use of selected ion monitoring(SIM)in accordance with Section 7.5.5 of the method. Method protocol modified to include acidification and the surrogate compound in accordance with the MA DEP Metl-od for the Determination of Extractable Petroleum Hydrocarbons. Sample extraction performed by EPA Method 3510C. Report Notations:._ All calculations performed prior to rounding. Quality Control Limits are defined by the methodology, or alternatively based upon the historical average recovery plus or minus three standard deviation units. Groundwater Analvtical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Quality Control Report Method Blank Category: EPA Method 8270C(Mod.)-EPH PAHs by GC/MS-SIM Instrument ID: MS-6 HP 6890 QC Batch ID: EP-1280-F Extracted: 10-21-03 14:00 Matrix: Aqueous Analyzed: 10-22-03 19:07 Analyst: JJT CAS}NumberAnalyt ori &-. t � ConentratNotes ` 'Un is e R Pong `m' Via, - 91-20-3 Naphthalene BRL r ug/L 0.5 91-57-6 2-Methy1naphthalene BRL ug/L 0.5 208-96-8 Acenaphthylene BRL ug/L 0.5 83-32-9 Acenaphthene BRL ug/L 0.5. 86-73-7 Fluorene BRL ug/L 0.5 85-01-8 Phenanthrene BRL ug/L 0.5 120-12-7 Anthracene BRL ug/L 0.5 206-44-0 Fluoranthene BRL ug/L 0.5 129-00-0 PyrenIe BRL ug/L 0.5 56-55-3 Benzo[a]anthracene BRL ug/L 0.1 218-01-9 ChrySene BRL ug/L 0.1 205-99-2 Benzo[b]fluoranthene BRL ug/L 0.1 207-08-9 Benzo[k]fluoranthene BRL ug/L 0.1 50-32-8 Benzo[a]pyrene BRL_ ug/L 0.1 193-39-5 Indeno[1,2,3-c,d]pyrene BRL ug/L 0.1 53-70-3 Dibenzo[a,h]anthracene BRL ug/L 0.1 191-24-2 Benzo[g,h,i]perylene BRL ug/L 0.1 ortho-Terphenyl 1 40 33 84 % 40-14C Method Reference: Test Methods for Evaluating Solid Waste,US EPA,SW-846,Third Edition,Update III(1996). Method modified by use of selected ion monitoring(SIM)in accordance with Section 7.5.5 of the method. Method protocol modified to include acidification and the surrogate compound in accordance with the MA DEP Method for the Determination of Extractable Petroleum Hydrocarbons. Sample extraction performed by EPA Method 3510C. Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution: Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Quality Control Report Laboratory Control Sample Category: MA DEP VPH Instrument ID: GC-1 HP 5890 QC Batch ID: VG1-1818-W Analyzed: 10-23-03 11:08 Matrix: Aqueous Analyst: PO Units: ug/L vGASNumEer ;_ Analyte a,€Spiked �Ivteasured Rec2 ery r� QC Limts 1634-04-4 Methyl tert-butyl Ether 50 50 100 % 70-130% 71-43-2 Benzene 50 46 93 1& 70-130% 108-88-3 'Toluene 50 50 99 % 70-130% 100-41-4 Ethylbenzene 50 49 1 98 % 70-130% 108-38-3 and 106-42-3 meta-Xylene and Para-Xylene 100 100 103 % 70-130 95-47-6 ortho- Xylene 50 50 101 % 70-130% 91-20-3 Naphthalene 50 42 83 % 70-130% QC'surrogate Compound �: ;are 5 ikedry "t Measuleil . ' Recovery �y QC LtmtfsN � 2,5-Dibromotoluene(PID) 150 130 89 % 70-130 2,5-Dibromotoluene(FID) 150 130 87 % 70-130 Method Reference: Method for the Determination of Volatile Petroleum Hydrocarbons,MA DEP(1998). Report Notations: All calculations performed prior to rounding. Quality Control Limits are defined by the methodology, or altematively.based upon the historical average recovery plus or minus three standard deviation units. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Quality Control Report Method Blank Category: MA DEP VPH Instrument ID: GC-1 HP 5890 QC Batch ID: VG1-1818-W Analyzed: 10-23-03 12:52 Matrix: Aqueous Analyst: PO �VPH1Ran e� ��� '� �� " � Concant anon - No,}es� � Untts ��-Iteportrn�L'imit n-05 to n-C8 Aliphatic Hydrocarbons t0 BRL ug/L 20 n-C9 to n-C12 Aliphatic Hydrocarbons to BRL ug/L 20 n-C9 to n-C10 Aromatic Hydrocarbons t BRL ug/L 20 Unadjusted n-05 to n-C8 Aliphatic Hydrocarbons t BRL ug/L 20 Unadjusted n-C9 to n-C12 Ali hatic Hydrocarbons t BRL ug/L 20 CAS,1�1Ufrlbe( tAna�tov-=m- fir" y �-," r : L)nl Ste' s - .:_. Y> 3t�.�-.4".. __5+=,..f -�z ,.. >-:. -gCOn�f,Cn'tratiofl a... Rr- eS�"`'s::. '. 1634-04-4 Methyl tert-but I Ether tt BRL ug/L 5 7143-2 Benzene° BRL ug/L 1 108-88-3 Toluene° BRL ug/L 5 100-41-4 Eth (benzene# BRL ug/L 5 108-38-3 and 10&42-3 meta-X lene and para-X lene BRL - ug/L 5 95-47-6 ortho- X lene t BRL ug/L 5 91-20-3 Naphthalene BRL ug/L 5 C Surro ate Com ound k Y. Sprtc�edMeasured����Recover.Y� r� �� � m,Q.C�L�1mt .,,:. _... 2,5-Dibrorhotoluene(PID) 100 105 105 % 70-130 2,5-Dibromotoluene(FID) 100 102 102 % 70-130% Method Reference: Method for the Determination of Volatile Petroleum Hydrocarbons,MA DEP(1998). Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution., t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting in that range. 0 n-05 to n-C8 Aliphatic Hydrocarbons range data excludes the method target analyte concentrations. ® n-C9 to n-C12 Aliphatic Hydrocarbons range data excludes the method target analyte concentrations and the concentration for the n-C9 to n-C10 Aromatic Hydrocarbons range. u Analyte elutes in the n-05 to n-C8 Aliphatic Hydrocarbons range. # Analyte elutes in the n-C9 to n-C12 Aliphatic Hydrocarbons range. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 . GROUNDWATER ANALYTICAL Certifications and Approvals Groundwater Analytical maintains environmental laboratory certification in a variety of states. Copies of our current certificates may be obtained from our website: http://www.groundwateranalytical.com/qualifications.htm ®mN�N�`ECTIGUT, Depa�r�tr nt o�f� ealttt Se vices P 05�8�6 Categories: Potable Water,Wastewater,Solid Waste and Soil http://www.dph.state.ct.us/B RS/Envi ron mental_Lab/OutStateLabList.htm FLO �I�DA;Depa�finen �tHealt �Bure�au o Laborator es E8�764 � � '�� _ '� Categories:SDWA,CWA, RCRA/CERCLA http://www.floridadep.oreabs/qa/dohforms.htm Categories: Drinking Water and Wastewater http://wwwatate.me.dsfdhs/eng/water/Compliance.htm MH M�SSA,Ct->uUETTS„ ament�of nv 1#950, P� ryt} Categories: Potable Water and Non-Potable Water http://www.state.ma.us/dep/bspt/wes/files/certlabs.pdf Categories: Drinking Water and Wastewater http://www.des.state.nh.us/asp/NHELAP/labsvi6w.asp Categories: Potable Water, Non-Potable Water and Solid Waste http://www.wadsworth.oreabcert/elap/comm.html �°PEfNS�YLVANIADepartmentof�Enuiro mentalProte t%on�, 6�665 4 . Environmental Laboratory Registration(Non-drinking water and Non-wastewater) http://www.dep.state.pa.us/Labs/Registered/ w Categories:Surface Water,Air,Wastewater, Potable Water,Sewage http://www.healthri.org/labs/labsCT—MA.htm 11ew0-giggtrnen�Agr�ctrlture�Sotl , , .!wed" wabs..�+:?���. �.€€—..a.. ... .>��, ^a .rr�;..,., .�:6✓: `s�:"...'.�,��-°-..a.�r;L. �:,.. ...,.,,� °..�....,. Chu�.x;-ra. �. "' = Foreign soil import permit �aYERM�NT�;Depar�tmen�a�E'nu�ronmenfal�`C�onser�vafion��l��ater=S'u 1 d�D�uis�o�n ` � ������ � , Category: Drinking Water http://www.vermontdrinkingwater.orglwsops/labtable.PDF Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 FILE COPY 13ENNET T A U'REILLY, Inc. ngineering, Environmental & Surveying Services 1573 Main Street Sanitary 21E/Site Remediation Property Line ' Box 1667 Br Site Development Hydrogeologic Survey Subdivision Brewster,MA 02631 Waste Water Treatment Water Quality Monitoring Land Court 508-896-6630 Water Supply Licensed Site Professional Trial Court Witness 508-896-4687 Fax B002-3490 March 4, 2004 Mr. Bert Fournier c/o Mg. Evelyn Read HUBBARD OIL COMPANY,INC. P.O. Box 10 Hyannis MA, 02601 RE: DISCOVERY OF PAHs IN GROUNDWATER Hubbard Oil Company Inc. -RTN 4-0824 33 and 51 Brooks Road [Assessors Map-14,Parcel 125_andl26] -Hyannis, MA. 02601 Dear Ms. Read, This correspondence is in followup to our previous letter,dated February 26,2004,wherein we informed you of the presence of several Polynuclear Aromatic Hydrocarbons (PAHs) in groundwater, above the applicable standards, in several downgradient monitoring wells on the Robies property. Since then BENNETT&O'REILLY,INC.has had the opportunity to secure and review the full list of PAH analytes concentrations from historic groundwater and soil analysis. Results of groundwater analysis from monitoring wells on the downgradient Robies property were reviewed from as far back as October 2002,wherein BENNETT&O'REILLY,INC.asked the laboratory to report the full PAH list for the analysis as prior to June 2003, previously only requesting the target 4 PAH analysis associated with virgin fuel oil impact as consistent with the historic use of the property. Please be advised that the laboratory records of such historic analysis did no allow for the low-level Reporting Limits to meet the RCGW-1 Standards in that mass spectrometry was not conducted at the time of such testing. Although no higher molecular coal tar related PAH compounds were detected in the historic groundwater testing reviewed,the detection limits and analytical sensitivity do no preclude the possibility that such compounds were present at the time of historical testing. These compounds,however,were not present in the monitoring wells at the Hubbard property in the most recent testing conducted in February of 2004. BENNETT& O'REILLY, INC. also requested the laboratory to report the full list PAH's for soil samples previously collected as part of the Phase II Investigation from the subject Hubbard property in October 2002. In this testing,,the Reporting Limits did meet the RCS-1 Standards. All the apgjry riewed reported fractional EPH concentrations. Two of the four samples did not MARCH 4,2004 HUBBARD OIL CO.,INC/BROOKS kD./BO02-3490 PAGE 2 OF 3 DATA REVIEWNALIDATION-PAH DISCOVERY report any PAHs above the method Reporting Limit. In the TB-4 sample with the greatest degree of petroleum impact,low-level concentrations of PAH's were reported for the compounds 2-methyl naphthalene,phenanthrene,acenaphthene and fluorene as typical of a fuel oil source. In the TB-10 sample, low-level concentrations of PAH's for the compounds fluoranthene, .pyrene, benzo(b)fluoranthene and benzo(g,h,i)perylene were reported. Although several of the compounds reported in the TB-10 sample are associated with coal tar derivatives, none of the concentrations of PAHs reported were above the Method 1 - Risk Characterization Standards or at concentrations exceeding published Background (MA DEP Technical Update). It is further noted,in consideration of the source,that no such compounds were detected in the most recent groundwater samples collected from monitoring wells on the Hubbard property and that distribution of PAH constituents reported in groundwater at the Robies property is dissimilar to those historically reported in soils at the Hubbard property. Based on the historic distribution and concentrations of PAH's in soils at the Hubbard property, and the current spacial and temporal occurrence of PAH's in groundwater at the Robies property alone,it appears that the likely source of coal tar derivatives is associated with the railway wherein historic and current uses utilize creosote treated timbers. - - BENNETT&O'REILLY,INC.would like to restate its previous recommendation that the Barnstable Water Company test their wells for semi-volatile compounds as a precautionary measure in review of any critical exposure pathways. We would appreciate being copied on such testing and provided with copies of any future testing of volatile organic compounds and/or inorganic compounds. BENNETT & O'REILLY, INC_ will continue to sample and analyze groundwater samples from the Hubbard and Robies properties as specified within the Remedial Operation Plan. This data will continue to be made public as reported to the MA Department of Environmental Protection and copied to the Town of Barnstable and the Barnstable Water Company. Should you have any questions, or need additional information, please contact me at your convenience. S' r B NNE 'RE LLY,INC. D vid C. ett,LSP Jo D. T de a- i dt Direc or of nviro', ental Services P oject Manager encl. Groundwater Analytical Results"Groundwater Analytical Inc." (Groundwater- sampled 10/23/02 & 11/4/02, both dated 2/24/04) (Soil- sampled 10/01/02, dated 3/1/04) Table 1: MA DEP Identified Background Levels in Soil from Technical Update Document I MARCH 4,2004 HUBBARD OIL CO.,INC/BROOKS RD.BO02-3490 PAGE 3 OF 3 DATA REVIEWNALIDATION-PAH DISCOVERY cc. Laura Stanley, Sites Management-MA DEP (SERO) Attorney Robert Fasanella-RUBIN&RUDMAN,LLP John Robichaud, President-Robies Refrigeration David Condry-Barnstable Water Company Lieutenant Hubler-Hyannis Fire Department Thomas McKean-Barnstable Board of Health John,Klimm-Barnstable Town Manager, c/o Barbara Harris,Town Counsel Commonwealth of Massachusetts,c/o Executive office of Transportation and Construction- (Railroad easement owners) Table 1. MADEP Identified Background Levels In Soil Concentration in Soil Containing Coal Concentration Ash or Wood Ash in"Natural" Associated With Fill Soil. Material OIL OR HAZARDOUS MATERIAL mg/kg mglkg ACENAPHTHENEZ 0.5 2 ACENAPHTHYLENE2 0.5 1 ANTH RACENE2 1 4 ALUMINUM' 10,000 10,000 ANTIMONY 1 7 ARSENIC 20 20 BARIUM' 50 50 BENZO(a)ANTH RACEN E2 2 9 BENZO(a)PYRENE2 2 7 BENZO(b)FLUORANTHENE2 2 8 BENZO(g,h,i)PERYLENE2 1 3 Massachusetts Department of BENZO(k)FLUORANTHENE2 1 4 Environmental Protection BERYLLIUM 0.4 0.9 One Winter Street CADMIUM 2 3 Boston,MA 02108-4746 CHROMIUM(TOTAL) 30. 40 CHROMIUM(III) 30 40 Commonwealth of CHROMIUM(VI) 30 40 Massachusetts CHRYSENE2 2 7 Jane Swift,Governor COBALT' 4 4 COPPER 40 200 Executive Office of DIBENZO(a,h)ANTH RACE NE2 0.5 1. FLUORANTHENEZ 4 10 Environmental Affairs FLUORENE2 1 2 Bob Durand,Secretary INDENO(1,2,3-cd)PYRENE2 1 3 IRON' 20,000 20,000 Department of LEAD 100 600 Environmental Protection MAGNESIUM' 5,000 5,000 Lauren A.Liss,Commissioner MANGANESE' 300 300 MERCURY 0.3 1 Produced by the METHYLNAPHTHALENE,2 z 0.5 1 Office of Research&Standards, NAPHTHALENE2 0.5 1 May 2002. NICKEL 20 30 Printed on recycled paper. PHENANTHRENE2 3 20 PYRE N E2 4 20 This information is available in SELENIUM 0.5 1 alternate format:by calling our SILVER 0.6 5 ADA Coordinator at THALLIUM 0.6 5 (617)5746872. VANADIUM' 30 30 ZINC 100 300 (Values rounded to one significant figure.) Ll 'In the absence of fill-specific data,the"natural"soil value has been adopted. 2 `In the absence of data specific to"natural"soil,a lower percentile value from the fill data set has been adopted. background to +Page 5 of 5 " ... 05232002 oc.d -- C'D MAR 0 2 2004 GR13U iD ATER Groundwater Analytical,Inc. P.O.Box u Main Street 1200 ANALYTICAL Buzzards Bay,MA 02532 Telephone(508)759-4441 759-4475 February 26 2004 FAX.grou dwateran www.groundwateranalytical.com Mr.John Tadema-Wielandt Bennett & O'Reilly, Inc. P.O. Box 1667 Brewster, MA 02631 LABORATORY REPORT AMENDMENT Project: Hubbard Oil Co. Brooks Rd./8002-3490 Lab ID: 54995 Received: 10-02-02 Dear John: Enclosed are the amended analytical results for the above referenced project. This letter authorizes the release of the analytical results, and should be considered a part of this report. This report contains a sample receipt report detailing the samples received, a project narrative indicating project changes and non-contormances, a quality control report, and a statement of our state certifications. The analytical results contained in this report meet all applicable NELAC standards, except as may be specifically noted, or described in the project narrative. This report may only be used or reproduced in its entirety. attest under the pains and penalties of perjury that, based upon my inquiry of those individuals immediately responsible for obtaining the information, the material contained in this report is, to the best of my knowledge and belief, accurate and complete. Should you have any questions concerning this report, please do not hesitate to contact me. Sincerely, Jonathan R. Sanford President J RS/smd Enclosures GROUNDWATER ANALYTICAL Sample Receipt Report Project: Hubbard Oil Co.Brooks Rd./B002-3490 Delivery: GWA Courier Temperature: .11.2'C Client: Bennett&O'Reilly, Inc. Airbill: n/a Chain of Custody: Present Lab ID: 54995 Lab Receipt: 10-02-02 Custody Seal(s): n/a Yc sNotesa 54995-1 T8 4:3-5' Soil 10/1/02 13:00 MA DEP EPH PAHs Con ID Container ndor QC Lot Presery QC Lot Prep Ship C138813 250 mL GlassTyProline BX4385 None n/a n/a 07-01-02 Lab ID ',' ' iField ID *s pia " Matrix 5a pled Metlod, � 54995-5 T13-1:8-10' Soil 10/1/02 9:00 TPH by GC ASTM D3328-00 Mod Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C144036 250mLGlass Proline BX4559 None n/a n/a n/a — a = � K,h "�`t Lab IDY Field ID Ivyatrrx :Sampled. Method `, ,,. , u M _. 54995-7 TB-6:13-15' Soil 10/1/02 15:15 MA DEP VPH with Targets Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C129412 60 mL Glass Industrial BX4621 Methanol R-33821 08-08-02 08-16-02 C189237 40 mL VOA Vial n/a n/a None n/a n/a n/a ,;; 7 q� Lab ID rField ID x rn Matrrxkr,.Sampled Method x , 54995-8 TB-6:18-20' Soil 10/1/02 15:30 MA DEP VPH with Targets Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C129408 60 m_Glass Industrial BX4621 Methanol R-33821 1 08-08-02 08-16-02 C189232 60 m_Glass n/a n/a None n/a n/a n/a Lab ID Field ID t,- Matnx Sampled_ Method ' o es 1 a �.. 54995-9 TB-8:8-10' Soil 10/2/02 10:00 MA DEP EPH PAHs Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C138816 250 rnt-Glass Proline BX4385 None n/a J n/a 1 07-01-02 : Lab ID FiedlD Mptrrx Sampled`:,fir. Method' 4, ..m«.� 54995-10 T13-8:1820' Soil 10/2/02 10:15 MA DEP EPH PAHs Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C138818 250 rroL Glass Proline BX4385 None n/a n/a 07-01-02 r w a,r � tr Lab ID ' Fie d�IDr ,Matrrx r`Sampled' 1 wMethods o- ' � z Notes ,. a� �' c<d+s 4, 54995-11 TB-10:13-15'$ Soil 10/2/02 13:00 MA DEP EPH PAHs Con ID Container Vendor QC Lot Presery QC Lot I Prep L Ship C138820 250 mL Glass Proline BX4385 None n/a n/a 07-01-02 Lab ID" "� Fie d ID ''' Y �tvlatrrxt `45am led Method # x#, " r a'Notes �y k "X 54995-12 T13-11:3-15' Soil 10/2/02 14:00 TPH by GC ASTM D3328-00 Mod Con ID Container Vendor QC Lot Presery Qc Lot Prep Ship n/a n/a n/a n/a n/a n/a n/a n/a Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Massachusetts DEP EPH Method Extractable Petroleum Hydrocarbons by GORD Field ID: TB-4. 3-5' Laboratory ID: 54995-01 Project: Hubbard Oil Co. Brooks Rd./8002-3490 QC Batch ID: EP-1538-M Client: Bennett&O'Reilly, Inc. Sampled: 10-01-02 Container: 250 mL Glass Received: 10-02-02 Preservation: Cool Extracted: 10-04-02 Matrix: Soil Analyzed: 10-17-02 % Moisture: 8 Dilution Factor: Aliphatic:1 Aromatic:1 g & A a Concentratio Units= Re o m Llllirt .s� .. ,.. - ... xe -..: 1saaz,. xar ,�4 ,.ate.,., hk _ d..,� n-C9.to n-C18 Aliphatic Hydrocarbons 840 mg/Kg 32 n-C19 to n-C36 Aliphatic Hydrocarbons 380 mg/Kg 32 n-C11 to n-C22 Aromatic Hydrocarbons 430 mg/Kg 32 Unadjusted n-C11 to n-C22 Aromatic Hydrocarbons t 440 mg/Kg 32 CAS Number X _ PAH Analytes ' ,- ,_,` t Concentration "' Unrtsh Rep_'ortmg'Lriti W - _ �._ �_ .ate . 91-20-3 Naphthalene BRL mg/Kg 0.54 91-57-6 2-Methyl naphthalene 3.3 mg/Kg 0.54 85-01-8 Phenanthrene 0.90 mg/Kg 0.54 83-32-9 Acenaphthene 0.71 mg/Kg 0.54 208-96-8 Acenaphthylene BRL mg/Kg 0.54 86-73-7 Fluorene 1.1 mg/Kg 0.54 120-12-7 Anthracene BRL mg/Kg 0.54 206-44-0 Fluoranthene BRL mg/Kg 0.54 129-00-0 Pyrene BRL mg/Kg 0.54 56-55-3 Benzo[a]anthracene BRL mg/Kg 0.54 218-01-9 Chrysene BRL mg/Kg 0.54 205-99-2 Benzo[b]fluoranthene BRL mg/Kg 0.54 207-08-9 Benzo[k]fluoranthene BRL mg/Kg 0.54 50-32-8 Benzo[a]pyrene BRL mg/Kg 0.54 193-39-5 Indeno[1,2,3-c,d]pyrene BRL mg/Kg 0.54 53-70-3 Dibenzo[a,h]anthracene BRL mg/Kg 0.54 191-24-2 Benzo[g,h,i]perylene BRL mg/Kg 0.54 r rQC Su"rro ate2Gom oundsl�.: .. OWN . . g P [tecovery Fractionation: 2-Fluorobiphenyl 102 % 40-140 % 2-13romonaphthalene 108 % 40-140 % Extraction: Chloro-octadecane 58 %. 40-140 % ortho-Terphenyl 124 % 40-140% V QA/QC Certrf►catron s 1. Were all QA/QC procedures required by the method followed? Yes 2. Were all performance/acceptance standards for the required QA/QC procedures achieved? Yes 3. Were any significant modifications made to the method,as specified in Section 11.3.1.1? Yes Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompanying signed project cover letter. The accompanying cover letter,project narrative and quality control report are considered part of this data report. Method Reference: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998). Results are calculated on a dry weight basis. Method modified by use of microwave accelerated solvent extraction technique. Report Notations: BRL Indicates concentration, if any, is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample dilution,percent moisture and sample size. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting it that range. 0 n-C11 to n-C22 Aromatic Hydrocarbons range data excludes the method target analyte concentrations. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Massachusetts DEP EPH Method Extractable Petroleum Hydrocarbons by GGFID Field ID: TB-8:8-10' Laboratory ID: 54995-09 Project: Hubbard Oil Co. Brooks Rd./BO02-3490 QC Batch ID: EP-1538-M Client: Bennett&O'Reilly, Inc. Sampled: 10-02-02 Container: 250 mL Glass Received: 10-02-02 Preservation: Cool Extracted: 10-04-02 Matrix: Soil Analyzed: 10-17-02 % Moisture: 5 Dilution Factor: Aliphatic:1 Aromatic:1 EPH Ran �xar '- ,, s ' ` Goncentratron w� Unfits Repo tang omit n-C9 to n-C18 Aliphatic Hydrocarbons t 290 m mg/Kg 30 n-C19 to n-C36 Aliphatic Hydrocarbons 76 mg/Kg 30 n-C11 to n-C22 Aromatic Hydrocarbons 81 mg/Kg 30 Unadjusted n-C11 to n-C22 Aromatic Hydrocarbons t 81 mg/Kg 30 CAS plumber�, 100"Yk 2V-71, lytes "ss _ t Concentration �, __ ,UnItS' RepOrtrng Llmlt, 91-20-3 Naphthalene BRL mg/Kg 0.50 91-57-6 2-Methyl naphthalene BRL mg/Kg 0.50 85-01-8 Phenanthrene BRL mg/Kg 0.50 83-32-9 Acenaphthene BRL mg/Kg 0.50 208-96-8 Acenaphthylene BRL mg/Kg 0.50 86-73-7 Fluorene BRL mg/Kg 0.50 120-12-7 Anthracene BRL mg/Kg 0.50 206-44-0 Fluoranthene BRL mg/Kg 0.50 129-00-0 Pyrene BRL mg/Kg 0.50 56-55-3 Ben zo[a]anth race ne BRL mg/Kg 0.50 218-01-9 Chrysene BRL mg/Kg 0.50 205-99-2 Benzo[b]fluoranthene BRL mg/Kg 0.50 207-08-9 Benzo[k]fluoranthene BRL mg/Kg 0.50 50-32-8 Benzo[a]pyrene BRL mg/Kg 0.50 193-39-5 Indeno[1,2,3-c,d]pyrene BRL mg/Kg 0.50 53-70-3 Dibenzo[a,h]anthracene BRL mg/Kg 0.50 191-24-2 Benzo[g,h,i]perylene BRL mg/Kg 0.50 F Recover `SAC Limits wru QC S urrogate Compounds _ _.. ,_.. . Q .._..-. Fractionatilortho -Fluorobiphenyl 79 % 40-140 % -Bromonaphthalene 103 % 40- 140 % Extraction: Chloro-octadecane 55 % 40-140 -Terphenyl 86 % 40- 140% < k pA/QCiCertlflCdtl. 1. Were all QA/QC procedures required by the method followed? � Yes 2. Were all performance/acceptance standards for the required QA/QC procedures achieved? Yes 3. Were any significant modifications made to the method,as specified in Section 11.3.1.1? Yes Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompanying signed project cover letter. The accompanying cover letter,project narrative and quality control report are considered part of this data report. Method Reference: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998). Results are calculated on a dry weight basis. Method modified by use of microwave accelerated solvent extraction technique. Report Notations: BRL Indicates concentration, if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample dilution,percent moisture and sample size. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting it that range. 0 n-C11 to n-C22 Aromatic Hydrocarbons range data excludes the method target analyte concentrations. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Massachusetts DEP EPH Method i Extractable Petroleum Hydrocarbons by GC/FID Field ID: TB-8: 18-20' Laboratory ID: 54995-10 Project: Hubbard Oil Co. Brooks Rd./BO02-3490 QC Batch ID: EP-1538-M Client: Bennett&O'Reilly, Inc. Sampled: 10-02-02 Container: 250 mL Glass Received: 10-02-02. Preservation: Cool Extracted: 10-04-02 Matrix: Soil Analyzed: 10-17-02 % Moisture: 3 Dilution Factor: Aliphatic:1 Aromatic:1 EPH Ran es ' $� TConcentration�aUn fts �sReportmg limit n-C9 to n-C18 Aliphatic Hydrocarbons 130 mg/Kg 30 n-C19 to n-C36 Aliphatic Hydrocarbons 54 mg/Kg 30 n-C11 to n-C22 Aromatic Hydrocarbons t 0 79 mg/Kg 30 Unadjusted n-C11 to n-C22 Aromatic Hydrocarbons t 79 mg/Kg 30 ACAS Numker PAH Ar%alytes. ,;: 5. ,. . .,,Corcentraton _ " Unttsy Repgrtrrrg Lrmif 91-20-3 Naphthalene BRL mg/Kg 0.50 91-57-6 2-Methyl naphthalene BRL mg/Kg 0.50 85-01-8 Phenanthrene BRL mg/Kg 0.50 83-32-9 Acenaphthene BRL mg/Kg 0.50 208-96-8 Acenaphthylene BRL mg/Kg 0.50 86-73-7 Fluorene BRL mg/Kg 0.50 120-12-7 Anthracene BRL mg/Kg 0.50 206-44-0 Fluoranthene BRL mg/Kg 0.50 129-00-0 Pyrene BRL, mg/Kg 0.50 56-55-3 Benzo[a]anthracene BRL mg/Kg 0.50 218-01-9 Chrysene BRL mg/Kg 0.50 205-99-2 Benzo[b]fluoranthene BRL mg/Kg 0.50 207-08-9 Benzo[k]fluoranthene BRL mg/Kg 0.50 50-32-8 Benzo[a]py rene BRL mg/Kg 0.50 193-39-5 Indeno[1,2,3-c,d]pyrene BRL mg/Kg 0.50 53-70-3 Dibenzo[a,h]anthracene BRL mg/K.g 0.50 191-24-2 Benzo[g,h,i]perylene BRL mg/Kg 0.50 ,4 dQC Surrogate Compound .� `u ,r _ RecoYerY ,,� a :;:QC Lamfsa r Fractionation: 2-Fluorobiphenyl 93 % 40-140 %_, 2-Bromonaphthalene 110 % 40-140 % Extraction: Chloro-octadecane 55 % 40-140 % ortho-Terphenyl r 116 % 40- 140 1. Were all QA/QC procedures required by the method followed? Yes 2. Were all performance/acceptance standards for the required QA/QC procedures achieved? Yes 3. Were any significant modifications made to the method,as specified in Section 11.3.1.1? Yes Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompanying signed project cover letter. The accompanying cover letter,project narrative and quality control report are considered part of this data report. Method Reference: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998). Results are calculated on a dry weight basis. Method modified by use of microwave accelerated solvent extraction technique. Report Notations: BRL Indicates concentration, if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample dilution,percent moisture and sample size. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting it that range. 0 n-C11 to n-C22 Aromatic Hydrocarbons range data excludes the method target analyte concentrations. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Massachusetts DEP EPH Method Extractable Petroleum Hydrocarbons by GC/FI D Field ID: TB-10: 13-15' Laboratory ID: 54995-11 Project: Hubbard Oil Co. Brooks Rd./BO02-3490 QC Batch ID: EP-1538-M Client: Bennett&O'Reilly,Inc. Sampled: 10-02-02 Container: 250 mL Glass Received: 10-02-02 Preservation: Cool Extracted: 10-04-02 Matrix: Soil Analyzed: 10-17-02 %Moisture: 9 Dilution Factor: Aliphatic:1 Aromatic:1 EPH Ranges �_,` �� � ;, , - a Goncentrat on�� Umts Re ortfn LI it a,,,mom. P�. � n-C9 to n-C18 Aliphatic Hydrocarbons55 mg/Kg 32 n-C19 to n-C36 Aliphatic Hydrocarbons 150 mg/Kg 32 n-Cl1 to n-C22 Aromatic Hydrocarbons T V 79 mg/Kg 32 Unadjusted n-C11 to n-C22 Aromatic Hydrocarbons t 85 mg/Kg 32 =CAS Number ,:PAH Analytes ;' " &, �Concentraton� Y Umts"' ' Re ortrn Lrmit P.:.e g .w. 91-20-3 Naphthalene BRL mg/Kg 0.53 91-57-6 2-Methyl naphthalene BRL mg/Kg 0.53 85-01-8 Phenanthrene BRL mg/Kg 0.53 83-32-9 Acenaphthene BRL mg/Kg 0.53 208-96-8 Acenaphthylene BRL mg/Kg 0.53 86-73-7 Fluorene BRL mg/Kg 0.53 120-12-7 Anthracene BRL mg/Kg 0.53 206-44-0 Fluoranthene 0.64 mg/Kg 0.53 129-00-0 Pyrene 0.59 mg/Kg 0.53 56-55-3 Benzo[a]anthracene BRL mg/Kg 0.53 218-01-9 Chrysene BRL mg/Kg 0.53 205-99-2 Benzo[b]fluoranthene 0.70 mg/Kg 0.53 207-08-9 Benzo[k]fluoranthene BRL mg/Kg 0.53 50-32-8 Benzo[a]pyrene BRL mg/Kg 0.53 193-39-5 Ind eno[1,2,3-c,d]pyre ne BRL mg/Kg 0.53 53-70-3 Dibenzo[a,h]anthracene BRL mg/Kg 0.53 191-24-2 Benzo[g,h,i]perylene 0.58 mg/Kg 0.53 QC Surrogate,Compounds , . ', `__Recovery _ „„ w QC,Lrmrts Fractionation: 2-Fluorobiphenyl 87 % 40-140 % 2-Bromonaphthalene 70 % 40- 140% Extraction: Chloro-octadecane -57 % 40-140% ortho-Terphenyl 78 % 40-140% w 'A '�; � Q/ QC CertlflCatfOn 1. Were all QA/QC procedures required by the method followed? Yes 2. Were all performance/acceptance standards for the required QA/QC procedures achieved? Yes 3. Were any significant modifications made to the method,as specified in Section 11.3.1.1? Yes Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompanying signed project cover letter. The accompanying cover letter,project narrative and quality control report are considered part of this data report. Method Reference: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998). Results are calculated on a dry weight basis. Method modified by use of microwave accelerated solvent extraction technique. Report Notations: BRL Indicates concentration, if any, is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample dilution,percent moisture and sample size. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting it that range. 0 n-C11 to n-C22 Aromatic Hydrocarbons range data excludes the method target analyte concentrations. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Project Narrative Project: Hubbard Oil Co. Brooks Rd./3002-3490 Lab ID: 54995 Client: Bennett&O'Reilly, Inc. Received: 10-02-02 13:40 A. Documentation and Client Communication x, ,s. ft`_„`1"6 G".. Ek The following documentation discrepancies;and client changes or amendments were noted for this project: 1 . Samples 54995-01,-09,-10,and-11 were reported by MA DEP EPH with all target analytes, per John Tadema- Wiellandt,02-25-04. y s "� ab k 7 B'Method Modificati"', Non Conformances and Observafion, � s x.}, ...,� 5" ' +' ,°r+*' .,,F,`,d,r.. :re,..`.:r _ .:`r;$ ,� a '� ,° `%.._ p 3a.,;.. tr { �+• ,.ta:taz: „' :...,, y5t� ..mio"`a+.itv The sample(s) in this project were analyzed by the references analytical method(s),and no method modifications, non-conformances or analytical issues.were noted,except as indicated below: 1 . Project Non-conformance. Project 54995 was received at a temperature of 11.2'C. This measurement is outside the recommended range of 2-6'C. Groundwater Analytical, Irc., P.O. Box 1200,228 Main Street, Buzzards Bay, MA 02532 228 Main Street,P.O.Box 1200 GROUNDWATER Buzzards Bay,MA 02532 CHAIN-OF-CUSTODY RECORD ANALYTICAL Telephone(508)759-4441 AND WORK ORDER N2 053455 FAX(508)759-4475 Project U Nam/ei, /pl Firm: 1( TURNAROUND ANALYSIS REQUEST v tI B=6 ��l' Lt,Vv.L�I O ��''t �^C' Volatlles Semivolatlles PeslMar6iPCBs Metals Pevoleum Hydrorarbon Haz. General Chemistry Other STANDARD(10 Business Days) Estraclable Val. Ext.TPH VOI.TPH Waste Project Number: Address: ❑ PRIORITY(5 Business Days) 7 _ z e Y:�O� J 1-V 1 J1�J /yt�bll S'f PU l5GX 0-7 ❑ RUSH(RAN- 9 a (Rush requires Rush Authorization Number) 0 000 y3 0o �. z Sampler Name: City/State/Zip: Please FAX C6 AYES { El NO a z FAX Number: S6 Bq&`T(,9-7 Project Manager: Telephone: BILLING 0 0 0 0 0 0 616 3 � s u JO `j�� G� Purchase Order No.: GWA Reference No.: 7Q o o INSTRUCTIONS:Use separate line for each container(except replicates). m - a = ❑ g o m s o $ .u'- n- a a o c ❑ Sampling Matrix Type Container(s) Preservation nhered 0 0 0 0 0 0 0 0 0 ❑ 0 0 6 -- 0 e _ ❑ N - _ a a a = LABORATORY W n SAMPLE 5u e .o - ❑ - ❑ ❑ y o IDENTIFICATION ? `� a _ = - NUMBER a�" J a W E w g J = c - ; m m o 0 0IS ❑ ❑ w w a o w > 5 i; '�" aE (Lab Use Only) - E _ d _ ' Q ° r � p o v o E E E E E _ 5 _ m n �' `o o m m o m 'm m m r a m o ❑ — z - n o m =p o 3 H Y k555 ❑ ❑ 00 o a ❑ ❑ a o ❑ ❑ ❑ ❑ a o ❑ o o ❑Y e o 0 0 0 ❑ o A ❑ 0 0 0 io r o"-. I'rao I P�' lC' �( U X I e X N5 ix Oil'u` 1"00 1 T S7J 1XI I VI x I joil ic2 .15 _G l3-i!s' IN I ix 4 X I I i I 1XI 1XI7 IO llcZ j',ZU I5-2G' (\ X abk x ?� c IG oL Ir00 c-'it)• 13-15 x I X X I( k. otcZ 'ZAU Ir I!?i REMARKS/SPECIAL INSTRUCTIONS DATA QUALITY OBJECTIVES CHAIN-OF-CUSTODY RECORD Regulatory Program Project Specific QC NOTE:All samples submitted subject to Standard Terms and Conditions on reverse hereof. ❑Safe Drinking Water Act Many regulatory programs and EPA methods require project I uish y pl Date Time Received by: Receipt Temperature' ❑MA DEP Form specific QC.Project specific QC includes Sample Duplicates, _• y ❑NPDES/Clean Water Act Matrix Spikes,and/or Matrix Spike Duplicates.Laboratory QC Is t Z C� j i ��'t�} t u� G [ I a�, ��. o- Is Specify State: not project specific unless prearranged.Project specific QC ` - ❑RCRA/Haz.Waste Char. samples are charged on a per sample basis.For water samples, elin uls a by: D to Time Received by: ` -Shipping/Airbill MA MCP(310 CMR 40) each MS,MSD and Sample Duplicate requires an additional /�j�y✓. �., Number: Reportable Concentrations sample aliquot. ! Cr z ii 0I RCGW-1 N RCS-1 Project Specific OC Required Selection of oc Sample Relinquished by: Date Time Re I eWyL atory: Custody Seal/ ❑RCGW-2❑RCS-2 ❑Sample Duplicate ❑Selected by laboratory ��/ / Cooler Serial ❑MA Dredge Disposal `�— "' `�5(u� Number: ❑Matrix Spike ❑Please use sample: Method of Shipment:QI GWA Courier 0 Express Mail 0 Federal Express GROUNDWATER ANALYTICAL Quality Assurance/Quality Control ` "' ` i¢. � .. '.s r ,,3 k ;fie E;y, we s .:� ?, z`'3' �'�� e' � t 3 wa ," -= sr- - x a ,' ,w+ r .:,� r� r AR , , � A Prb ram Overview ? x„..vsa; L�} s t"`'_'��'t....A..r .. � x,�'+.r;.:i"� � .. �_r: .... .r.. ;�:-.,e;•...�r, ,.,..w _, Groundwater Analytical conducts an active Quality Assurance program to ensure the production of high quality, valid data. This program closely follows the guidance provided by Interim Guidelines and Specifications for Preparing Quality Assurance Project Plans, US EPA QAMS-005/80 (1980), and Test Methods for Evaluating Solid Waste, US EPA, SW-846, Update III (1996). Quality Control protocols include written Standard Operating Procedures (SOPS) developed for each analytical method. SOPS are derived from US EPA methodologies and other established references. Standards are prepared from commercially obtained reference materials of certified purity, and documented for traceabi l ity. Quality Assessment protocols for most organic analyses include a minimum of one laboratory control sample, one method blank, one matrix spike sample, and one sample duplicate for each sample preparation batch. All samples, standards, blanks, laboratory control samples, matrix spikes and sample duplicates are spiked with internal standards and surrogate compounds. All instrument sequences begin with an initial calibration verification standard and a blank; and excepting GC/MS sequences,:all_sequences close with a continuing. calibration standard. GC/MS systems are tuned to appropriate ion abundance criteria daily, or for each 12 hour operating period,whichever is more frequent. Quality Assessment protocols for most inorganic analyses include a minimum of one laboratory control` sample, one method blank, one matrix spike sample, and one sample duplicate for each sample preparation- batch. Standard curves are derived from one reagent blank and four concentration levels. Curve validity is: verified by standard recoveries within plus or minus ten percent of the curve. ltK _'£ � sg� �,_ ,�aM ��-� a ., r "��ddi n� d„�», �x,. , $t' A1ayr B DeflnitlOnSdn a ,c , Batches are used as the basic unit for Quality Assessment. A Batch is defined as twenty or fewer samples of the same matrix which are prepared together for the same analysis, using the same lots of reagents and the same techniques or manipulations, all within the same continuum of time, up to but not exceeding 24 hours. Laboratory Control Samples are used to assess the accuracy of the analytical method. A Laboratory Control Sample consists of reagent water or sodium sulfate spiked with a group of target analytes representative of the method analytes. Accuracy is defined as the degree of agreement of the measured value with the true or expected value. Perent Recoveries for the Laboratory Control Samples are calculated to assess accuracy. Method Blanks are used to assess the level of contamination present in the analytical system. Method Blanks consist of reagent water or an aliquot of sodium sulfate. Method Blanks are taken through all the appropriate steps of an analytical method. Sample data reported is not corrected for blank contamination. Surrogate Compounds are used to assess the effectiveness of an analytical method in dealing with each sample matrix. Surrogate Compounds are organic compounds which are similar to the target analytes of interest in chemical behavior, but which are not normally found in environmental samples. Percent Recoveries are calculated for each Surrogate Compound. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Quality Control Report Laboratory Control Sample Category: MA DEP EPH Method QC Batch ID: EP-1538-M Matrix: Soil Units: mg/Kg x �C;4S Number � 111-84-2 n-Nonane(C9) 3.3 1.5 45 % 40- 140% 629-59-4 n-Tetradecane(C14) 3.3 1.8 55 % 40-140 % 629-92-5 n-Nonadecane(C19) 3.3 2.2 66% 40-140% 112-95=8 n-Eicosane(C20) 3.3 2.3 68% 40- 140 % 630-02-4 n-Octacosane(C28) 3.3 2.4 72% 40-140 91-20-3 Naphthalene 3.3 1.6 48% 40-140 % 83-32-9 Acenaphthene 3.3 1.9 58% 40-140 % 120-12-7 Anthracene 3.3 2.3 68 % 40- 140 129-00-0 Pyrene 3.3 2.5 74% 40-140 % 218-01-9 Chrysene 3.3 2.3 70% 40 140 % # ¢ seReCOVE'Cy i,�,QCSurr.,ogafeCom po unds, �;�;���� - Fractionation: 2-Fluorobiphenyl 82 % 40-140 % 2-Bromonaphthalene 87 % 40- 140% Extraction: Chloro-octadecane 68 % 40- 140% ortho-Terphenyl 70 % 40-140 % Method Reference: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998). Report Notations: All calculations performed prior to rounding. Quality Control Limits are defined by the methodology, or alternatively based upon the historical average recovery plus or minus three standard deviation units. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Quality Control Report Method Blank Category: MA DEP EPH Method QC Batch ID: EP-1538-M Matrix: Soil .N t ua� Re orhn Limi EPH Ranges Concenfrafi'on `: Unrts_�g. ,P w. S ,. n-C9 to n-C18 Aliphatic Hydrocarbons T BRL mg/Kg 30 n-C19 to n-C36 Aliphatic Hydrocarbons BRL mg/Kg 30 n-C1.1 to n-C22 Aromatic Hydrocarbons BRL mg/Kg 30 Unadjusted n-C11 to n C22 Aromatic Hydrocarbons t BRL mg/Kg 30 zC;4S Nhumber` Tar et Anal es�.� �,,,� „�`,„ �� �a;;�. Cork ntration �" �Un�ts, Reporting�Limit 91-20-3 Naphthalene BRL mg/Kg 0.50 91-57-6 2-Methy1naphthalene BRL mg/Kg 0.50 85-01-8 Phenanthrene BRL mg/Kg 0.50 83-32-9 Acenaphthene BRL mg/Kg 0.50 208-96-8 Acenaphthylene BRL mg/Kg 0.50 86-73-7 Fluorene BRL mg/Kg 0.50 120-12-7 Anthracene BRL mg/Kg 0.50 - 206-44-0 Fluoranthene BRL mg/Kg 0.50 129-00-0 Pyrene BRL mg/Kg 0.50 56-55-3 Benzo[a]anthracene BRL mg/Kg 0.50 218-01-9 Chrysene BRL mg/Kg 0.50 205-99-2 Benzo[b]fluoranthene BRL mg/Kg 0.50 207-08-9 Benzo[k]fluoranthene BRL mg/Kg 0.50 50-32-8 Benzo[a]pyrene BRL mg/Kg 0.50 193-39-5 Indeno[1,2,3-c,d]pyrene BRL mg/Kg 0.50 53-70-3 Dibenzo[a,h]anthracene BRL mg/Kg 0.50 191-24-2 Benzo[g,h,i]perylene BRL mg/Kg 0.50 _ r - x > �,:c EReCOYery1 a t� F C L[I711tS` Sur_:rogate-compounds Fractionation: 2-Fluorobiphenyl 88 % 40-.140% 2-Bromonaphthalene 91 % 40- 140 % Extraction: Chloro-octadecane 72 % 40-140% ortho-Terphenyl 81 % 40-140 % Method Reference: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998). . Report Notations: BRL Indicates concentration, if any, is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample dilution,percent moisture and sample size. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting it that range. 0 n-C11 to n-C22 Aromatic Hydrocarbons range data excludes the method target analyte concentrations. I. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Certifications and Approvals Groundwater Analytical maintains environmental laboratory certification in a variety of states. Copies of our current certificates may be obtained from our website: http://www.groundwateranalytical.com/qualifications.htm Categories: Potable Water,Wastewater,Solid Waste and Soil http://www.dph.state.ct.us/B RS/Environmental_Lab/O utStateLabLi st.htm FLORIDA °Department of;Health Bureau of LakoratoriesE87�643� ;�'� � �� �v `� � `p���� "�`'�" �� Categories: SDWA,CWA, RCRA/CERCLA http://www.floridadep.org/labs/qa/dohforms.htm MA1NE;Department of Hyman Services, MA103 � `Y' _,._ �.. . . . Categories: Drinking Water and Wastewater http://www.s-,-.ate.me.us/dhs/eng/water/Compliance.htm ��M;ASSACH'USETTS, Depar"tm`�ent`of Env�ron�`rnental�Protect on�; IN M�A�1�03�` � �` � � ' ° °�� � � �` � K x Categories: Potable Water and Non-Potable Water http://www.state.ma.us/depfbspt/wes/files/certiabs.pdf �NEW HAA%1PSHIRE;Department of Environmentai S�ery ces,�20270s3 �-_" �� ��� � �� ��. �� � �, Categories: Drinking Water and Wastewater http://www.des.state.nh.us/asp/NHELAP/labsview.asp y �..cam,,-,."'. "' , �r �, � � .� - •�.. •� s. �rd,�.. �,'w�z_,r"��. - `�' o+r+xu ., ate �...� fl Categories: Potable Water, Non-Potable Water and Solid Waste http://www.wadsworth.org/labcert/elap/comm.html yrS aa^ a.a%a�✓✓�., r. „r g�a �rHfi » �ar4,�#' " s,z*.�d d�� '¢"M�"' PENNSYLVANIA Department of Environmental Protection,�68 Environmental Laboratory Registration(Non-drinking water and Non-wastewater) http://www.dep.state.pa.us/Labs/Registered/ W�z Categories: Surface Water,Air,Wastewater, Potable Water,Sewage http://www.healthri.org/labs/labsCT—MA.htm Foreign soil import permit VERMONT; Department of�Environmental Conservation,Water�Supply�Division���� � � � � ��sw��"� Category: Drinking Water http://www.ve�rmontdrinkingwater.orglwsops/labtable.PDF Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 FEB Z b NO Gro ndwater GROUNDWATER RO.Box 1200 Analytical,Inc. P.O.Box 1200 ANALYTICAL. Buzzards Main Street Buzzards Bay,MA 02532 Telephone(508)759-4441 FAX(508)759-4475 February 24, 2004 www.groundwateranalytical.com Mr.John Tadema-Wielandt Bennett & O'Reilly, Inc. P.O. Box 1667 Brewster, MA 02631 LABORATORY REPORT AMENDMENT Project: Hubbard Oil Co. Inc./B002-3490 Lab ID: 55892 Received: 11-05-02 Dear John: Enclosed are the amended analytical results for the above referenced project. This letter authorizes the release of the analytical results, and should be considered a part of this report. This report contains a sample receipt report detailing the samples received, a project narrative indicating project changes and non-contormances, a quality control report, and a statement of our state certifications. The analytical results contained in this report meet all applicable NELAC standards, except as may be specifically noted, or described in the project narrative. This report may only be used or reproduced in its entirety. attest under the pains and penalties of perjury that, based upon my inquiry of those individuals immediately responsible for obtaining the information, the material contained in this report is, to the best of my knowledge and 'belief, accurate and complete. Should you have any questions concerning this report, please do not hesitate to contact me. Sincerely, *7k, Jonathan R. Sanford President JRS/smd Enclosures GROUNDWATER ANALYTICAL Sample Receipt Report Project: Hubbard Oil Co. Inc./B002-3490 Delivery: GWA Courier Temperature: 2.6'C Cliel••t: Bennett&O'Reilly, Inc. Airbill: n/a Chain of Custody: Present Lab ID: 55892 Lab Receipt: 11-05-02 Custody Seall n/a Matrix Sam led 4• Methods s k Notes ` 'lablDFieldlD + 55892-1 (RR)MW-6S Aqueous 11/4/02 16:15 MA DEP EPH with PAHs Con'D Container Vendor QC Lot Presery QC Lot Prep Ship C137d80 1 LAmberGlass Proline BX4505 H2504 R-3353C 08-08-02 08-1602 c Fuld ID Lab ID St 'f Sam led € Method ?r 55892-2 (RR)MW-6D Aqueous 11/4/02 16:45 MA DEP EPH with PAHs Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C172597 1 LAmberGlass Proline BX5371 H2504 R-3421C 09-12-02 09-17-02 : x o Sam led '` *'Metlod � Notes ar _ 55892-3 (RR)MW-5S Aqueous 11/4/02 15:30 TPH by GC ASTM D3328-00 Mod Con ID Container Vendor QC Lot Presery QC Lot I Prep____JL Ship C'72593 1 L Amber 3lass Proline BX5371 H2SO4 R-3421C 09-12-02 09-17-02 ` x Field ID' Matnx Sampled Method F <., ; 1 sue° { > r,7; _ a, 55892-4 (RR)MW-51D Aqueous 11/4/02 15:30 TPH by GC ASTM D3328-00 Mod Con ID Container Vendor QC Lot Presery QC Lot Prep I Ship C17 5589 1 L Amber Glass Proline BX5371 H2SO4 R-3421C 09-12-02 09-17-02 �gg'_ �_ s1 -- 55892-5 (RR)MW-5S Aqueous 11/4/02 15:30 MA DEP VPH with Targets Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C203992 40 mL\'OA Vial Industrial BX5470 HCI R-3173F 10-02-02 10-18-02 C203991 40 rnL VOA Vial Industrial BX5470 HCI R-3173F 10-02-02 10-18-02 i� Lab ID ��� ,�F�eld ID� '`��_� '? � Matnx Sampled s=•„Method �c� ':._� >`���..�� .��� „," rus�°�N s _ '�:am� :�..�-��_ pte 55892-6 (RR)MW-5D Aqueous 11/4/02 15:30 MA DEP VPH with Targets Con ID Container Vendor. QC Lot Presery QC Lot Prep Ship C203989 40 rnL VOA Vial Industrial BX5470 HCI R-3173F 10-02-02 10-18-02 C203990 40 mL VOA Vial Industrial BX5470 HCI R-3173F 10-02-02 10-18-02 lab ID asx ,..�r S .-. , tt No field D Me s, am � . ,. 55892-7 (RR)MW-65 Aqueous 11/4/02 16:15 MA DEP VPH with Targets Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C203980 40 mL VOA Vial Industrial BX5470 HCI R-3173F 10-02-02 10-18-02 C203979 40,nL VOA Vial Industrial BX5470 HCI R-3173F 10-02-02 10-18-02 Lab ID ,,. .Field ID ;tr Matrix ` Sample zMethod„ ' s, ¢ Not s qpy 55892-8 (RR`MW-6D Aqueous 11/4/02 16:45 MA DEP VPH with Targets Con ID Container Vendor QC Lot Presery QC Lot Prep Ship 7203983 40 mL VOA Vial Industrial BX5470 HCI R-3173F 10-02-02 10-18-02 C203982 40 mL VOA Vial Industrial BX5470 HCI R-3173F 10-02-02 10-18-02 ` Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Massachusetts DEP EPH Method Extractable Petroleum Hydrocarbons by GC/FID Field ID: (RR)MW-6S Laboratory ID: 55892-01 Project: Hubbard Oil Co. Inc./BO02-3490 QC Batch ID: EP-1131-F Client: Bennett&O'Reilly, Inc. Sampled: 11-04-02 Container: 1 L Amber Glass Received: 11-05-02 Preservation: H2SO4/Cool Extracted: 11-08-02 Matrix: Aqueous Analyzed: 11-11-02 Dilution Factor: Aliphatic:1 Aromatic:1 EPH ltangesx" . � ,: Concentration r a J". Reporting Limit n-C9 to n-C18 Aliphatic Hydrocarbons BRL ug/L 500 n-C19 to n-C36 Aliphatic Hydrocarbons BRL ug/L 500 n-C11 to n-C22 Aromatic Hydrocarbons BRL ug/L 160 Unadjusted n-C11 to n-C22 Aromatic Hydrocarbons f BRL ug/L 160 9;7 Ant Naphthalene BRL ug/L 10 2-Methyl naphthalene BRL ug/L 5 Phenanthrene BRL ug/L 10 83-32-9 Acenaphthene BRL ug/L 10 86-73-7 Fluomne BRL ug/L 10 208-96-8 Acenaphthylene BRL ug/L 10 120-12-7 Anthracene BRL ug/L 10 206-44-0 Fluoranthene BRL ug/L 10 129-00-0 Pyrene BRL ug/L 10 56-55-3 Benzo[a]anth race ne BRL ug/L 10 218-01-9 Chrysene BRL ug/L 10 205-99-2 Benzo[b]fluoranthene BRL ug/L 10 207-08-9 Benzo[k]fluoranthene BRL ug/L 10 50-32-8 Benzo[a]pyrene BRL ug/L 10 193-39-5 Indeno[1,2,3-c,d]pyrene BRL ug/L 10 53-70-3 Dibenzo[a,h]anthracene BRL ug/L 10 191-24-2 Benzo[g,h,i]perylene BRL ug/L 10 C Surro ate°'Coin ounds Recover " p,QC Ltmaits Fractionation: 2-Fluorobiphenyl 93 % 40-140 % 2-Bromonaphthalene 92 % 40-140% Extraction: Chloro-octadecane 75 % 40-140 % ortho-Terphenyl 87 % 40-140% ,;1;.�, r•R ro ,QA/`Q,CkCet,�tlflCatlOn .; „`'` r ;, `. ¢ -- .:� _ 1. Were all QA/QC procedures required by the method followed? Yes 2. Were all performance/acceptance standards for the required QA/QC procedures achieved? Yes 3. Were any significant modifications made to the method,as specified in Section 11.3? No Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompanying signed project cover letter. The accompanying cover letter,project narrative and guality control report are considered part of this data report. Method Reference: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998). Extraction performed utilizing separatory funnel technique. Report Notations: BRL Indicates concentration, if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample dilution and sample size. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting it that range. 0 n-C11 to n-C22 Aromatic Hydrocarbons range data excludes the method target analyte concentrations. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Massachusetts DEP EPH Method Extractable Petroleum Hydrocarbons by GC/FID Field ID: (RR)MW-613 Laboratory ID: 55892-02 Project: Hubbard Oil Co. Inc./6002-3490 QC Batch ID: EP-1131-F Client: Bennett&O'Reilly, Inc. Sampled: 11-04-02 Container: 1 L Amber Glass Received: 11-05-02 Preservation: H2SO4/Cool Extracted: 11-08-02 Matrix: Aqueous Analyzed: 11-11-02 Dilution Factor: Aliphatic:1 Aromatic:1 n-C9 to n-C18 Aliphatic Hydrocarbons BRL ug/L 500 n-C19 to n-C36 Aliphatic Hydrocarbons BRL ug/L 500 n-C11 to n-C22 Aromatic Hydrocarbons BRL ug/L 160 Unadjusted n-C11 to n-C22 Aromatic Hydrocarbons t BRL ug/L 160 g CAS NumberzTarget Analytes_; „ ', ?,Concentryato_n °, ro ,_Units: tF Reporting Limn 91-20-3 Naphthalene BRL ug/L 10 91-57-6 2-Methyl naphthalene BRL ug/L 5 85-01-8 Phenanthrene BRL ug/L 10 83-32-9 Acenaphthene BRL ug/L 10 86-73-7 Fluorene BRL - - ug/L 10 208-96-8 Acenaphthylene BRL ug/L 10 120-12-7 Anthracene BRL ug/L 10 206-44-0 Fluoranthene BRL ug/L 10 129-00-0 Pyrene BRL ug/L 10 56-55-3 Benzo[a]anthracene BRL ug/L 10 218-01-9 Chrysene BRL ug/L 10 205-99-2 Benzo[b]fluoranthene BRL ug/L 10 207-08-9 Benzo[k]fluoranthene BRL ug/L 10 50-32-8 Benzo[a]pyrene BRL ug/L 10 193-39-5 Indeno[1,2,3-c,d]pyrene BRL ug/L 10 53-70-3 Dibenzo[a,h]anthracene BRL ug/L 10 191-24-2 Benzo[g,h,i]perylene BRL ug/L 10 Surrogate_Gompqunds y Recovery r =QC Lim __,. ._ Fractionation: 2-Fluorobiphenyl 93 % 40-140% 2-Bromonaphthalene 92 % 40- 140 % Extraction: Chloro-octadecane 71 % 40- 140% ortho-Terphenyl 87 % 40-140% : � & t Q4/QC Certtficatiori = j ?, h XV11 1. Were all QA/QC procedures required by the method followed? Yes 2. Were all performance/acceptance standards for the required QA/QC procedures achieved? Yes 3. Were any significant modifications made to the method,as specified in Section 11.3? No Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompanying signed project cover letter. The accompanying cover letter,project narrative and quality control report are considered part of this data report. Method Reference: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998). Extraction performed utilizing separatory funnel technique. Report Notations: BRL Indicates concentration, if any, is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample dilution and sample size. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting it that range. 0 n-C11 to n-C22 Aromatic Hydrocarbons range data excludes the method target analyte concentrations. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Project Narrative Project: Hubbard Oil Co. Inc./B002-3490 Lab ID: 55892 Client: Bennett&O'Reilly, Inc. Received: 11-05-02 16:10. The following documentation discrepancies,and client changes or amendments were noted for this project: 1 . Samples 55892-01 and-02 were analyzed by MA DEP EPH with all targets,per John Tadema-Wielandt,02-23-04. . �fi-rfv ' `�.��+; 6'� a.�5 2• t� j- w s� +r� �6t �� ,ryra: T^ ,�v t"�-a ;'�S l.ix ;Method Modifreations;Non Conforrnarces and Observafions ? k �" --";k "iv,,.,.,: 4!"3#` .- ,: ..ma.•?;. aat s, ,w...-,..a .r..� �`. .wa@h:- ,`..-'k�°da The sample(s) in this project were analyzed by the references analytical method(s),and no method modifications, non-conformances or analytical issues were noted,except as indicated below: 1 . No method modifications,non-conformances or analytical issues were noted. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 TER 228 Buz Main Street,P.O.Box 1200 Buzzards Bay,MA 02532 CHAIN-OF-CUSTODY RECORD ANALYTICAL Telephone(508)759-4441 AND WORK ORDER N® 065104 FAX(508)759-4475 '"I Project Name: Firm: /� TURNAROUND ANALYSIS REQUEST g L'��� (� 1 I�t Vostiles Semivolaliles Pesl/xerhlPClis Metals Petroleum Hydrocarbon xaz. General Chemistry Other c;cA ®t'�1 . 1 t�l l �� ��t ' ❑ STANDARD(10 Business Days) Effraclable Val. Est.TPx Ivol.TPH I waste Project Number: Address: JK PRIORITY(5 Business Days) y LL E o i`� l r 7j L{- �7� (V��t'I h � ❑ RUSH(RAN- )L)C) � U .-}. I 1 V .�t:'� o (Rush requires Rush Authorization Number) o ❑ o Sampler Name: City/State/Zip: y ( .) 1� n/)�1 0��� ( Please FAX 1 YES 0 INOC o v q z /�"� �'�•o sA-t t j V I '1 FAX Number: J�� Project Manager: Telephone: BILLING o 0 0 0 0 a 0 o a d 9 500 U t1�-���� Purchase Order No.: GWA Reference No.: ❑ o � c � a � o = 600Z,�av Eam _- A o ° o INSTRUCTIONS:Use separate line for each container(except replicates). o E 3 a g o o 2. e 2 o a s e = d - a o a s o o T o o ❑ ❑ - 6 w o ❑ '4 _ d o Sampling Matrix Type Container(s) Preservation Filtered o oa ❑ 0 ❑ o 0 0 _ d n v d - o - F LABORATORY W it s n a o 3 4 m 3 0 ❑ ❑ o ❑ ❑ SAMPLE NUMBER — �+ �, — ff IDENTIFICATION ¢ 5 ' < _ — — m (Lab USe Only) m a m t a k, m o 9 a N w w o w > S E a 5 E o E o a $ a o o s m m q ❑ _e a b o o o 0 a o 0 0 ❑ 0 0 0 0 a o 0 0 0 a o ❑ 9 L o a ai o ❑ o ❑ a a a a ❑ 0 0 e _ - qs 4ti- , ' , T. Q . i. ,� t S"'E"'` r -4 V `1 2 s_ ,� .s4:.t '•f T ,.c i 7 It sr REMARKS/SPECIAL INSTRUCTIONS DATA QUALITY OBJECTIVES CHAIN-OF-CUSTODY RECORD Regulatory Program Project Specific QC NO E:All samples submitted subject to Standard Terms and Conditions itions on reverse hereof. ') ❑Safe Drinking Water Act Many regulatory programs and EPA methods require project e tya or- Dat Time Received by: eceipt Tempe, 0 MA DEP Form specific QC.Project specific QC Includes Sample Duplicates, �a�l ❑NPDES/Clean Water Act Matrix Spikes,and/or Matrix Spike Duplicates.Laboratory QC is Specify State: not project specific unless prearranged.Project specific OC ❑RCRA/Haz.Waste Char. samples are charged on a per sample basis.For water samples, Iln i ed y: t Time Rec a by: hipping/Airbill MA MCP(310 CMR 40) each MS,MSD and Sample Duplicate requires an additional ��j�,y 310 �S Number: Reportable Concentrations sample aliquot. RCGW-1 RCS-1 elf i Date Time ratory /U Custody Seal/ Project Specific OC Required Selection of OC Sample f 1 )fie Cooler Serial ❑RCGW-2❑RCS•2 p Sample Duplicate ❑Selected by laboratory i!I��U ��� ! Number: ❑MA Dredge Disposal p Matrix Spike ❑Please use sample: ❑NH❑RI❑CT O ME Method o t: ❑GWA Courier❑Express Mait ❑ ederal xpress Specify Category: 0 Matrix Spike Duplicate 0 UPS 0 Hand ❑ GROUNDWATER ANALYTICAL Quality Assurance/Quality Control '�" sar"' Sz t `� s hk, a� AfPro�rarnOvervrew �;�y � �� yj " AY" ``' s s. Groundwater Analytical conducts an active Quality Assurance program to ensure the production of high quality, valid data. This program closely follows the guidance provided by Interim Guidelines and Specifications for Preparing Quality Assurance Project Plans, US EPA QAMS-005/80 (1980), and Test Methods for Evaluating Solid Waste, US EPA, SW-846, Update 111 (1996). Quality Control protocols include written Standard Operating Procedures (SOPS) developed for each analytical method. SOPS are derived from US EPA methodologies and other established references. Standards are prepared from commercially obtained reference materials of certified purity, and documented for traceability. Quality Assessment protocols for most organic analyses include a minimum of one laboratory control sample, one method blank, one matrix spike sample, and one sample duplicate for each sample preparation batch. All samples, standards, blanks, laboratory control samples, matrix spikes and sample duplicates are spiked with internal standards and surrogate compounds. All instrument sequences begin with an initial calibration verification standard and a blank; and excepting GC/MS sequences, all sequences close with a continuing calibration standard. GC/MS systems are tuned to appropriate ion abundance criteria daily, or for each 12 hour operating period, whichever is more frequent. Quality Assessment protocols for most inorganic analyses include a minimum of one laboratory control sample, one method blank, one matrix spike sample, and one sample duplicate for each sample preparation batch. Standard curves are derived from one reagent blank and four concentration levels. Curve validity is verified by standard recoveries within plus or minus ten percent of the curve. Batches are used as the basic unit for Quality Assessment' A Batch is defined as twenty or fewer samples of the same matrix which are prepared together for the same analysis, using the same lots of reagents and the same techniques or manipulations, all within the same continuum of time, up to but not exceeding 24 hours. Laboratory Control Samples are used to assess the accuracy of the analytical method. A Laboratory Control Sample consists of reagent water or sodium sulfate spiked with a group of target analytes representative of the method analytes. Accuracy is defined as the degree of agreement of the measured value with the true or expected value. Perent Recoveries for the Laboratory Control Samples are calculated to assess accuracy. Method Blanks are used to assess the level of contamination present in the analytical system. Method Blanks consist of reagent water or an aliquot of sodium sulfate. Method Blanks are taken through all the appropriate steps of an analytical method. Sample data reported is not corrected for blank contamination. Surrogate Compounds are used to assess the effectiveness of an analytical method in dealing with each sample matrix. Surrogate Compounds are organic compounds which are similar to the target analytes of interest in chemical behavior, but which are not normally found in environmental samples. Percent Recoveries are calculated for each Surrogate Compound. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Quality Control Report Laboratory Control Sample Category: MA DEP EPH Method QC Batch ID: EP-1131-F Matrix: Water Units: ug/L fl "« >, S �kel Measured K- Retouer A—Li mits 111-84-2 n-Nonane((-9) 50 24 48 % 40-140 629-59-4 n-Tetradecane(C14) 50 32 63% 40-140% 629-92-5 n-Nonadecane(C19) 50 40 79 % 40-140 % 112-95-8 n-Eicosane(C20) 50 41 83 % 40-140 % 630-02-4 n-Octacosane(C28) 50 39 77% 40-140 91-20-3 Naphthalene 50 35 70% 40-140 % 83-32-9 Acenaphthene 50 39 78 % 40- 140 % 120-12-7 Anthracene 50 46 91 % 40-140 129-00-0 Pyrene 50 46 92 % 40-140 218-01-9 Chrysene 50 46 Fractionation: 2-Fluorobiphenyl 102 % 40- 140 2-13romonaphthalene 92 % 40-140 Extraction: Chloro-octadecane 80 % 40- 140 % ortho-Terphenyl 95 % 40-140 Method Reference: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998). Report Notations: All calculations performed prior to rounding. Quality Control Limits are defined by the methodology, or alternatively based upon the historical average recovery plus or minus three standard deviation units. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Quality Control Report Method Blank Category: MA DEP EPH Method QC Batch ID: EP-1131-F Matrix: Water Rep.OrtIng L`'l rlllt n-C9 to n-C1'8 Aliphatic.Hydrocarbons BRL ug/L 500 n-C19 to n-C36 Aliphatic Hydrocarbons BRL ug/L 500 n-C11 to n-C22 Aromatic Hydrocarbons BRL ug/L 160 Unadjusted n-C11 to n-C22 Aromatic Hydrocarbons t BRL ug/L 160 CAS iNuno!er :_ i Target Analytes _Concen#ration ;,-,Units I ReportrngxL�mif 91-20-3 Naphthalene BRL ug/L 10 91-57-6 2-Methyl naphthalene BRL ug/L 5 85-01-8 Phenanthrene BRL ug/L 10 83-32-9 Acenaphthene BRL ug/L 10 208-96-8 Acenaphthylene BRL ug/L 10 86-73-7 Fluorene BRL ug/L 10 120-12-7 Anthracene BRL - ug/L 10 206-44-0 Fluoranthene BRL ug/L 10 129-00-0 Pyrene BRL ug/L 10 56-55-3 Benzo[a]anthracene BRL ug/L 10 218-01-9 Chrysene BRL ug/L 10 205-99-2 Benzo[b]fluoranthene BRL ug/L 10 207-08-9 Benzo[k]fluoranthene BRL ug/L 10 50-32-8 Benzo[a]pyrene BRL ug/L 10 193-39-5 Indeno[1,2,3-c,d]pyrene BRL ug/L 10 53-70-3 Dibenzo[a,h]anthracene BRL ug/L 10 191-24-2 Benzo[g,h,i]pe'r ne BRL ug/L 10 Su ate Corn ounds wt' ` rro , Recavery7 �; � " QC Lrmts � v g Pr- . Fractionation: 2-Fluorobiphenyl 104 % 40-140 % 2-Bromonaphthalene 105 % 40- 140% Extraction: Chloro-octadecane 78 % 40-140 % ortho-Terphenyl 98 % 40-140% Method Reference: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998). . Report Notations: BRL Indicates concentration,if any, is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample dilution and sample size. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting it that range. 0 n-C11 to n-C22 Aromatic Hydrocarbons range data excludes the method target analyte concentrations. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Certifications and Approvals Groundwater Analytical maintains environmental laboratory certification in a variety of states. Copies of our current certificates may be obtained from our website: http://www.groundwateranal)dical.com/qualifications.htm Categories: Potable Water,Wastewater,Solid Waste and Soil http://www.dph.state.ct.us/B RS/Envi ron mental_Lab/O utState LabLi st.htm �FLgRIDA,�Deparfinent�of:Health; Bureau of�Laboratorres, E87643�{�-�� � � �,, �°� " ��� � � �* �'�� Categories: SDWA,CWA, RCRA/CERCLA http://www.floridadep.org/labs/qa/dohforms.htm "MAINE, v}- Categories: Drinking Water and Wastewater http://www.state.me.us/dhs/eng/water/CompIiance.htm MASSACHUSETTS, Department of Envira e nrnntal Protection, M. - Categories: Potable Water and Non-Potable Water http://www.state.ma.us/dep/bspt/wes/fi Ies/certl abs.pdf `w v-T" f:: NEW HAMPSHIRE Department of`fnvironmental Se'rvices,-�202703 •�1��� � � � �� �,� �-, ��" �� Categories: Drinking Water and Wastewater http://www.des.state.nh.us/asp/NHELAP/Iabsview.asp - _ Categories: Potable Water, Non-Potable Water and Solid Waste http://www.wadsworth.org/labcert/elap/comm.html m, , �PENNSYLVAKI Au-Department of Environmental Protection, 68 665 r , r � cps�7 ,. ro tiQ RAJ-.. x Environmental Laboratory Registration(Non-drinking water and Non-wastewater) http://www.dep.state.pa.us/Labs/Registered/ 'ran...��"" „� _.,....*'� 1r w ,.fix..-_X. .$. ,rt"Fu„•r. Categories:Surface Water,Air,Wastewater, Potable Water,Sewage http://www.healthri.org/labs/labsCT—MA.htm Foreign soil import permit Poc:-a;,a �'e`, �,=Y�r"��,n?j•!, ,�g� ,�'�'✓ '#!'a °zs k3z-"���#.�u c" �c �`` F �h"nW �. act� .rf''�_t�D,.w�:- x„ p�� -�y,Y'�"�".'s:fi �'�' �;„���z�`�' �VERM{ONT, Dep�artmentof Env�ronmentaf�Co*�nseruation,�� water Supply- vision y�-'�t�'S ��� x��t x,5 Category: Drinking Water http://www.vermontdrinkingwater.org/wsops/labtable.PDF Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 F Ea 2 G 2004 Gro n alytical, Inc. GROUNDWATER RO.Box 1200 Main Street AV4LYTIC4L Buzzards Bay,MA 02532 Telephone(508)759-4441 FAX(508)759-4475 February 24, 2004 www,groundwateranalytical.com Mr.John Tadema-Wielandt Bennett & O'Reilly, Inc. P.O. Box 1667 Brewster, MA 02631 LABORATORY REPORT AMENDMENT Project: Hubbard Oil/Brooks Rd./B002-3490 Lab ID: 55605 Received: 10-25-02 Dear John: Enclosed are the amended analytical results for the above referenced project. This letter authorizes the release of the analytical results, and should be considered a part of this report. This report contains a sample receipt report detailing the samples received, a project narrative indicating project changes and non-contormances, a quality control report, and a statement of our state certifications. The analytical results contained in this report meet all applicable NELAC standards, except as may be specifically noted, or described in the project narrative. This report may only be used or reproduced in its entirety. attest under the pains and penalties of perjury that, based upon my inquiry of those individuals immediately responsible for obtaining the information, the material contained in this report is, to the best of my knowledge and belief, accurate and complete. Should you have any questions concerning this report, please do not hesitate to contact me. Sincerely, Jonathan R. Sanford President J RS/smd Enclosures GROUNDWATER ANALYTICAL Sample Receipt Report Project: Hubbard Oil/Brooks Rd./B002-3490 Delivery: GWA Courier Temperature: 4.8'C Client: Bennett&O'Reilly, Inc. Airbill: n/a Chain of Custody: Present Lab ID: 55605 Lab Receipt: 10-25-02 Custody Seal(s): n/a b ' Notes z � Lab IDs Field ID ' say ,Mafnx JSampled Method ., � � . & ..s.. �.. ... 55605-1 MW-4 q A ueous 10/23/02 5:00 MA DEP VPH with Targets Con ID Container Vendor QC Lot Presery QC Lot Prep Ship 53982 40 mL VOA Vial Industri BX al 5257 HCI R-3173F 09-19-02 10-18-02 —Cl C153995 40 mL VOA Vial Industrial BX5257 HCI R-3173F 09-19-02 10-18-02 C1539 44 40 mL VOA Vial Industrial BX5257 HCI R-3173F 1 09-19-02 1 10-18-02 x k ie Matrix ,� 5aml P Ff tb �.._,.. ...�.�., . 55605-2 GZA-2 Aqueous 10/23/02 5:30 MA DEP VPH with Targets Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C153983 40 mL VOA Vial Industrial BX5257 HCI R-3173F 09-19-02 10-18-02 C153971 40 mL VOA Vial Industrial BX5257 HCI R-3173F 09-19-02 10-18-02 C153959 40 mL VOA Vial Industrial BX5257 HCI I R-3173F J 09-19-02 1 10-18-02 55605-3. GZA-3 A Aqueous 10/23/02 5:45 MA DEP VPH with Targets Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C153970 40 mL VOA Vial Industrial BX5257 HCI R-3173F 09-19-02 10-18-02 C153958 40 mL VOA Vial Industrial BX5257 HCI R-3173F 09-19-02- 10-18-02 C153947 40 mL VOA Vial Industrial BX5257 HCI R-3173F 1 09-19-02 1 10-18-02 Y ,Lab ID° > Field 1D -Matrix SampledMetlod :''� " `' x;; ., _ s Hotes ., �m. s r� s, 55605-4 MW4 Aqueous 10/23/02 5:00 TPH by GC ASTM D3328-00 Mod Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C172642 1 L Amber Glass Proline BX5376 H2SO4 R-3421C 09-12-02 09-17-02 C172647 1 L Amber Glass Proline BX5376 H2504 R-3421C 09-12-02 09-17-02 Lab ID Field ID " as . g i?MatrixSampleda 55605-5 GZA-2 Aqueous 10/23/02 5:30 MA DEP EPH with PAHs Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C172643 1 L Amber Glass Proline BX5376 H2SO4 R-3421C 09-12-02 09-17-02 C172639 1 L Amber Glass Proline BX5376 H2504 R-3421C 09-12-02 09-17-02 Barn ledt Method . .1.. tallotes � ,h Lab IC)gs: Field ID --.<" § P 55605-6 GZA-3 Aqueous 10/23/02 5:45 MA DEP EPH with PAHs Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C172638 1 LAmberGlass Proline BX5376 H2SO4 R-3421C 09-12-02 09-17-02 C172637 1 LAmber-Glass Proline BX5376 H2SO4 R-3421C 09-12-02 09-17-02 Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Massachusetts DEP EPH Method Extractable Petroleum Hydrocarbons by GGFI D Field ID: GZA-2 Laboratory ID: 55605-05 Project: Hubbard Oil/Brooks Rd/BO02-3490 QC Batch ID: EP-1126-F Client: Bennett&O'Reilly, Inc. Sampled: 10-23-02 Container: 1 L Amber Glass Received: 10-25-02 Preservation: H2SO4/Cool Extracted: 10-28-02 Matrix: Aqueous Analyzed: 10-31-02 Dilution Factor: Aliphatic:1 Aromatic:1 oncentration nits _.Rep * C ortingLtmt; in es .-'. .,°' 3u'»`:3... n-C9 to n-C118 Aliphatic Hydrocarbons BRL ug/L 500 n-C19 to n-C36 Aliphatic Hydrocarbons BRL ug/L 500 n-C11 to n-C22 Aromatic Hydrocarbons BRL ug/L 160 Unadjusted n-C11 to n-C22 Aromatic Hydrocarbons t BRL ug/L 160 .CAS,Nu[nter' !, b Target Arialytes : ,,, s Concentration „ ,£', ,Unit %Reporting Lrmt 10 91-20-3 Naphthalene BRL u L 91-57-6 2-Methyl naphthalene BRL ug/L 5 85-01-8 Phenanthrene BRL ug/L 10 83-32-9 Acenaphthene BRL ug/L 10 86-73-7 Fluorene BRL ug/L- 10 208-96-8 Acenaphthylene BRL ug/L 10 120-12-7 Anthracene BRL ug/L 10 206-44-0 Fluoranthene BRL ug/L 10 129-00-0 Pyrene BRL ug/L 10 56-55-3 Benzo[a]anthracene BRL ug/L 10 218-01-9 Chrysene BRL ug/L 10 205-99-2 Benzo[b]fluoranthene BRL ug/L 10 207-08-9 Benzo[k]fluoranthene BRL ug/L 10 50-32-8 Benzo[a]pyrene BRL ug/L 10 193-39-5 Indeno[1,2,3-c,d]pyrene BRL ug/L, 10 53-70-3 Dibenzo[a,h]anthracene BRL ug/L 10 191-24-2 Benzo[g,h,i]perylene BRL ug/L 10 ., r�Cmp m1..——Surro dQ Fractionation: r2-Fluorobiphenyl 67 % 40-140monaphthalene 60 % 40-140Extraction: o-octadecane 66 % 40-140-Terphenyl 78 % 40-140 % c PT QA/QC Certrfrcatron �� 1. Were all QA/QC procedures required by the method followed? Yes 2. Were all performance/acceptance standards for the required QA/QC procedures achieved? Yes 3. Were any significant modifications made to the method,as specified in Section 11.3? No Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompanying signed project cover letter. The accompanying cover letter,project narrative and quality control report are considered part of this data report. Method Reference: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998). Extraction performed utilizing separatory funnel technique. Report Notations: BRL Indicates concentration,if any, is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample dilution and sample size. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting it that range. 0 n-C11 to n-C22 Aromatic Hydrocarbons range data excludes the method target analyte concentrations. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 i GROUNDWATER ANALYTICAL Massachusetts DEP EPH Method Extractable Petroleum Hydrocarbons by GGFI D Field ID: GZA-3 Laboratory ID: 55605-06 Project: Hubbard Oil/Brooks Rd/BO02-3490 QC Batch ID: EP-1126-F Client: Bennett&O'Reilly, Inc. Sampled: 10-23-02 Container: 1 L Amber Glass Received: 10-25-02 Preservation: H2SO4/Cool Extracted: 10-28-02 Matrix: Aqueous Analyzed: 10-31-02 Dilution Factor: Aliphatic:1 Aromatic:1 EP_H Ranges . ., oncentrafion ,.n .p >Umts .p., . S n-C9 to n-C18 Aliphatic Hydrocarbons BRL _ ug/L 500 n-C19 to n-C36 Aliphatic Hydrocarbons BRL ug/L 500 n-C11 to n-C22 Aromatic Hydrocarbons ° BRL ug/L 160 Unadjusted n-C11 to n-C22 Aromatic Hydrocarbons t BRL ug/L 160 CAS Number ;Target Analytes ,9� ? C'orcentratron � ", g pUnrts Reportmg Limit 91-20-3 Naphthalene BRL ug/L 10 91-57-6 2-Methylnaphthalene BRL ug/L 5 85-01-8 Phenanthrene BRL ug/L 10 83-32-9 Acenaphthene BRL ug/L 10 86-73-7 Fluorene BRL ug/L 10 208-96-8 Acenaphthylene BRL ug/L 10 120-12-7 Anthracene BRL ug/L 10 206-44-0 Fluoranthene BRL ug/L 10 129-00-0 Pyrene BRL ug/L 10 56-55-3 Benzo[a]anthracene BRL ug/L 10 218-01-9 Chrysene BRL ug/L 10 205-99-2 Benzo[b]fluoranthene BRL ug/L 10 207-08-9 Benzo[k]fluoranthene BRL ug/L 10 50-32-8 Benzo[a]pyrene BRL ug/L 10 193-39-5 Indeno[1,2,3-c,d]pyrene BRL ug/L 10 53-70-3 Di benzo[a,h]anth racene BRL ug/L 10 191-24-2 Benzo[g,h,i]perylene BRL ug/L 10 QC, .Su r. __. . d_. _ ' ` .. QCLlm rroamun Fractionation: 2-Fluorobiphenyl 80 % 40-140 % 2-Bromonaphthalene 76 % 40-140% Extraction: Chloro-octadecane 83 % 40-140 ortho-Terphenyl 95 % 40-140 % QA/QCCQI�Iflcd4Qn3 1. Were all QA/QC procedures required by the method followed? Yes 2. Were all performance/acceptance standards for the required QA/QC procedures achieved? Yes 3. Were any significant modifications made to the method,as specified in Section 11.3? No Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompanying signed project cover letter. The accompanying cover letter,project narrative and quality control report are considered part of this data report. Method Reference: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998). Extraction performed utilizing separatory funnel technique. Report Notations: BRL Indicates concentration, if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample dilution and sample size. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting it that range. 0 n-C11 to n-C22 Aromatic Hydrocarbons range data excludes the method target analyte concentrations. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 I GROUNDWATER ANALYTICAL Project Narrative Project: Hubbard Oil/Brooks Rd./8002-3490 Lab ID: 55605 Client: Bennett&O'Reilly, Inc. Received: 10-25-02 16:25 k�2�t .a ....::�„'a�.,'�,... 'rw""4 -•-C-,,., - m..ffe_e .. ,r:c�fi...=,_�. .r*--;. �* .. ndts ,..x.r..��. ., _.. �;t e:�ee&,<� � ¢.. 5�'v �x The following documentation discrepancies,and client changes or amendments were noted for this project: 1 . Samples 55605-05 and-06 were analyzed by MA DEP EPH with all targets,per John Tadema-Wielandt,02-23-04. B jVlethod Modifications;Non Cooforrnances andObservations � �: � ; s.V' ........ The sample(s) in this project were analyzed by the references analytical method(s),and no method modifications, non-conformances or analytical issues were noted,except as indicated below: 1 . No method modifications, non-conformances or analytical issues were noted. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 S U ATE 228 Buz Main Street,P.O.Box 1200 Buzzards Bay,MA 02532 CHAIN-OF-CUSTODY RECORD � ����� � Telephone(508)759-4441 AND WORK ORDER N2 064758 FAX(508)759-4475 Project Name: Firm: � TURNAROUND ANALYSIS REQUEST r 9 f !�'iC .��'��'✓ - Valatlles Semlvolatiles PestMerhMCBs Metals Petroleum ertlracarhon Haz. General Chemistry ether ❑STANDARD(10 Business Days) Extractable Vol.I Eel.TPH IVul.TPH I Waste Project Number: Address: PRIORITY(5 Business Days) lz A a/ io%z:) 5 ❑ RUSH(RAN q -s 9 z o n (Rush requires Rush Authorization Number)' o' a ❑ ❑ 3' o ' Sampler Name City/State/Zip: Please FAX p'YES ❑ NO r FAX Number lJ0- 8?ei .�/�i 1 0 u ❑ s Project„Manage'r: _ r Telephone: BILLING 0 0 0 0 0 0 0 0 d G Purchase Order No.: GW4 Reference No.: ❑ o z s a INSTRUCTIONS:Use separate line for each container(except replicates). r a "� d N a.c ° e 2 0 a s « 0 o e 0 M g a a Sampling Matrix Type Container(s) Preservation Filmed o. ❑ ❑ ❑ ❑ o 0 0 0 0 0 0 - LABORATORY o a _ e e e ¢ o A ❑ ❑ o 0 0 SAMPLE s _ r; a a - _ NUMBER m IDENTIFICATION - '" ,o '" - _ m (Lab U;a Only) " g e r A - .m g z o in W W s o w 5 ] E q E _ e W ❑ e z A EEE .e o c = ❑ E E E 5 0 " m $ $ m m w o o m <o — .°• u S a ¢ o u u A9 r 3 o o - slos 0 ❑ ❑ 0 ❑ ❑ ❑ 0 00 0 ❑ 00 0 o0 ❑ d5 ❑ ❑ a ❑ ❑ ❑ ❑ ❑ 0 0❑ ❑ X 5 Ix. IIIy I .. -. e, I. i i REMARKS/SPECIAL INSTRUCTIONS DATA QUALITY OBJECTIVES CHAIN-OF-CUSTODY RECORD Regulatory Program Project Specific OC NOTE:All samples submitted subject to Standard Terms and Conditions on reverse hereof. r%; } i•- ,.)t-r., ry�� p Sate Drinking Water Act Many regulatory programs and EPA methods require project Relinquished by,Sampler: Date Time Received by: Receipt Temperature: v ❑MA DEP Form specific OC.Project specific OC included Sample Duplicates, t /z,.yi,/,,G�. 4Fi^?�:',_.��:•�. _.,.,.. ❑NPDES/Clean Water Act Matrix Spikes,and/or Matrix Spike Dupllcates.Laboratory OC Is '✓�/� 4`�'-""' /9 0' 7' Specify State: not project specific unless prearranged.Project specific OC ❑RCRA/Haz.Waste Char. samples are charged on a per'sample basis.For water samples, Relinq fished by: Date Time Received by: Shipping/Airbill r},h,ir•;_,`y"; r" I�/ MCP each MS,MSD and Sample Duplicate requires an additional /\1 Number: Reportable Concentrations sample aliquot. _ r .. �/- �°�" «` �✓�� u- �' S Re C CMR40) ' dRCGW-1 ❑RCS-1 Relinquished by: Date Time geceiyed 7 Laboratory: Custody Seal/ Project Specific OC Required Selection of OC Semple /\ ❑RCGW-2 ❑RCS-2 ❑Sample Duplicate ❑Selected by laboratory / Cooler Serial ❑MA Dredge Disposal t" 6 -'` `� /t_a-�, Number: 0 Matrix Spike 0 Please use sample: Method of Shipment: RftGWA Courier El Express Mail Feder ('Express GROUNDWATER ANALYTICAL Quality Assurance/Quality Control br, w - x,} a. Groundwater Analytical conducts an active Quality Assurance program to ensure the production of high quality, valid data. This program closely follows the guidance provided by Interim Guidelines and Specifications for Preparing Quality Assurance Project Plans, US EPA QAMS-005/80 (1980), and Test Methods for Evaluating Solid Waste, US EPA, SW-846, Update III (1996). Quality Control protocols include written Standard Operating Procedures (SOPS) developed for each analytical method. SOPs are derived from US EPA methodologies and other established references. Standards are prepared from commercially obtained reference materials of certified purity, and documented for traceability. Quality Assessment protocols for most organic analyses include a minimum of one laboratory control sample, one method blank, one matrix spike sample, and one sample duplicate for each sample preparation batch. All samples, standards, blanks, laboratory control samples, matrix spikes and sample duplicates are spiked with internal standards and surrogate compounds. All instrument sequences begin with an initial calibration verification standard and a blank; and excepting GC/MS sequences, all sequences close with a continuing calibration standard. GC/MS systems are tuned to appropriate ion abundance criteria daily, or for each 12 hour operating period, whichever is more frequent. Quality Assessment protocols for most inorganic analyses include a minimum of one laboratory control. sample, one method blank, one matrix spike sample, and one sample duplicate for each sample preparation- batch. Standard curves are derived from one reagent blank and four concentration levels. Curve validity is verified by standard recoveries within plus or minus ten percent of the curve. I Batches are used as the basic unit for Quality Assessment. A Batch is defined as twenty or fewer samples of the same matrix which are prepared together for the same analysis, using the same lots of reagents and the same techniques or manipulations, all within the same continuum of time, up to but not exceeding 24 hours. Laboratory Control Samples are used to assess the accuracy of the analytical method. A Laboratory Control Sample consists of reagent water or sodium sulfate spiked with a group of target analytes representative of the method analytes. Accuracy is defined as the degree of agreement of the measured value with the true or expected value. Perent Recoveries for the Laboratory Control Samples are calculated to assess accuracy. Method Blanks are used to assess the level of contamination present in the analytical system. Method Blanks consist of reagent water or an aliquot of sodium sulfate. Method Blanks are taken through all the appropriate steps of an analytical method. Sample data reported is not corrected for blank contamination. Surrogate Compounds are used to assess the effectiveness of an analytical method in dealing with each sample .matrix. Surrogate Compounds are organic compounds which are similar to the target analytes of interest in chemical behavior, but which are not normally found in environmental samples. Percent Recoveries are calculated for each Surrogate Compound. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Quality Control Report Laboratory Control Sample Category: MA DEP EPH Method QC Batch ID: EP-1126-F Matrix: Water Units: ug/L r . CAS Numbers Anal e S ikedz rMeasured _ RecoverQG L�m�ts W s 111-84-2 n-Nonane(0) 50 21 43 % 40-140 629-59-4 n-Tetradecane(C14) 50 30 59% 40-140% 629-92-5 n-Nonadecane(C19) 50 41 81 % 40-140 112-95-8 n-Eicosane(C20) 50 41 82 % 40-140 630-024 n-Octacosane(C28) 50 36 73% 40-140 % 91-20-3 Naphthalene 50 32 64% 40- 140 83-32-9 Acenaphthene 50 35 71 % 40 140 120-12-7 Anthracene 50 43 87% 40-140 129-00-0 Pyrene 50 43 85 % 40- 140 % 218-01-9 Chrysene 50 43 86% 40-140 GornpounJ'sr .. QCLimits ... � . Fractionation: 2-Fluorobiphenyl 74 % 40- 140% 2-Bromonaphthalene 71 % 40- 140 Extraction: Chloro-octadecane 76 % 40- 140 % ortho-Terphenyl 88 % 40- 140 % Method Reference: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998). Report Notations: All calculations performed prior to rounding. Quality Control Limits are defined by the methodology, or alternatively based upon the historical average recovery plus or minus three standard deviation units. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Quality Control Report Method Blank Category: MA DEP EPH Method QC Batch I D: EP-1126-F Matrix: Water EF'kt'Ranges ,&, ' `, .M ' s, Goncentrat`ron ,Unrts `RepontmgpLrmitt n-C9-to n-C18 Aliphatic Hydrocarbons BRL ug/L 500 n-C19 to n-06 Aliphatic Hydrocarbons BRL ug/L 500 n-C11 to n-C22 Aromatic Hydrocarbons BRL ug/L 160 Unadjusted n-C71 to n-C22 Aromatic Hydrocarbons t BRL ug/L 160 C 4S^Nurrikier ,ETarget Analytes', `- Goricent'ration r Unrts Repotmg Limit 91-20-3 Naphthalene BRL ug/L 10 91-57-6 2-Methyl naphthalene BRL ug/L 5 85-01-8 Phenanthrene BRL ug/L 10 83-32-9 Acenaphthene BRL ug/L 10 208-96-8 Acenaphthylene BRL ug/L 10 86-73-7 Fluorene BRL ug/L 10 120-12-7 Anthracene BRL ug/L 10 206-44-0 Fluoranthene BRL ug/L 10 129-00-0 Pyrene BRL ug/L 10 56-55-3 Benzo[a]anthracene BRL ug/L 10 218-01-9 Chrysene BRL ug/L 10 205-99-2 Benzo[b]fluoranthene BRL ug/L 10 207-08-9 Benzo[k]fluoranthene BRL ug/L 10 50-32-8 Benzo[a]pyrene BRL ug/L 10 193-39-5 Indeno[1,2,3-c,d]pyrene BRL ug/L 10 53-70-3 Dibenzo[a,h]anthracene BRL ug/L 10 191-24-2 Benzo[g,h,i]perylene BRL ug/L 10 K �v, a N Recovery; �� QC Limit's .. �':<' QC Suriogafe Compounds ,t p: „.a �W_ .. Fractionation: 2-Fluorobiphenyl 82 % 40-140% 2-Bromonaphthalene 62 % 40-140% Extraction: Chloro-octadecane 75 % 40- 140% ortho-Terphenyl 95 % 40- 140% Method Reference: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998). Report Notations: BRL Indicates concentration, if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample dilution and sample size. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting it that range. 0 n-C11 to n-C22 Aromatic Hydrocarbons range data excludes the method target analyte concentrations. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Certifications and Approvals Groundwater Analytical maintains environmental laboratory certification in a variety of states. Copies of our current certificates may be obtained from our website: http://www.groundwateranalytical.com/qualifications.htm fX+ Ed s,Ltz ,+ '. -':, :'., ; ..... �, t Piz, p "j x ^v �; ,.v COIVNECTICUT, Depart ent of Health Servi es, P,H 05`86r " ` ` # x #' bye =.yrc '�'°'>zM, `,..^43_, ...._aG,bg„.ue i.xx � ✓ PS ,m;', x,✓ �' ':, ' .`'-9 ,. `.. ,,,ma� .. +s,x a"� F r'��s Categories: Potable Water,Wastewater,Solid Waste and Soil http://www.dph.state.ct.us/BRS/Environmental Lab/OutStateLabList.htm s � nc € ����rt; r•- �P�� �r���� rr7 r °w���.` `" ` �.������?�sl 'ref �, '`' -�� '�. �fi ' �`��,'°P�a- .r '°'�- �;. FLO_RIDA;Depa��rtment of Health,,Bur�eau;of Laboratories, �E87643 ;�� �. ��� �� ,{ ,��� r� „�„, � Categories: SDWA,CWA, RCRA/CERCLA http://www.floridadep.org/labs/qa/dohforms.htm r,: e :d" cA`^" &- ' c_ M1r Y« 3 7i '" ",^,S #F'" ,� T a :t`` q't.` ,n 2 MANE Ir , Department of Human Ser ��ces,��MA�103 � �� Categories: Drinking Water and Wastewater http://www.state.me.us/dhs/eng/water/Compliance.htm MA$SACH ,,SETTS,Afepartment of Environmental Protection, s Categories: Potable Water and Non-Potable Water http://www.state.ma.us/dep/bspt/wes/files/certiabs.pdf NEW HAMPSHIRE;Department of�Env�rgnmentalServiees,�02703 � ' � ����� ��' � ' ��� Categories: Drinking Water and Wastewater http://www.des.state.nh.usfasp/NHELAP/labsview.asp NEW,YORK, Depatmentof Health; i1Z54 � � � �r � 4 # z Categories: Potable Water, Non-Potable Water and Solid Waste http://www.wadsworth.org/labcert/elap/comm.htmi iR y d xy. w. s r. �� hkk� PENNSYLVANIA, Department of Env�ronmentaffe" ection, 68 665 k Environmental Laboratory Registration (Non-drinking water and Non-wastewater) http://www.dep.stat6.pa.us/Labs/Registered/ x -✓ '^`T' r' & fg � v .., " r T'; 4� '�`n°�"F np Al RHODE ISLAND Department of Health 54 .� � k Categories:Surface Water,Air,Wastewater, Potable Water,Sewage http://www.healthri.oeg/labs/labsCT MA.htm ME U Se artme nof At` r icu l ture Soil Peret S 5392`1 � � � " 'D �" R t 'r � �" t'� �� 5+'. Foreign soil import permit {t'"'�r°'`" "�'""" � f+aa.,f' w.£��^a.�,� +- ..� �v�" t:xyy� �"+ ;`: fi ±r ^� ➢r sF ��.x% sa,�n 7 �z c�r;'� ,}�ly, �a,�i�.d., K� ���- o� 'r"'°'. ��V�ERMONT�;Department�o�f�Env �on� ental Conservation,Wa„�teSupply�Diuision .� � � �� � , Category: Drinking Water http://www.vermontdrinkingwater.orglwsops/labtable.PDF Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 REC'D RUBIN AND RUDMAN LLP APR 2 2 Z004 COUNSELLORS AT LAW 50 ROWES WHARF • BOSTON, MASSACHUSETTS 02110-3319 TELEPHONE: (617)330-7000 • FACSIMILE: (617)439-9556 • EMAIL: FIRMQRUBINRUDMAN.COM Robert A. Fasanella Direct Dial (617)330-7018 E-mail:rfasanella@rubinrudman.com April 20, 2003 By Facsimile and First Class Mail Barbara Harris, Esq. Robert Smith, Esq. P.O. Box 861 Hyannis Town Hall Barnstable, MA 02630 367 Main Street Hyannis, MA 02601 RE: B&A Fournier Realty Trust,Eminent Domain 33 and 51 Brooks Road,.Hyannis, MA Intermedal Parking Facility Dear Ms. Harris and Mr. Smith: As a follow-up to our recent telephone conversations, I am writing to"seek clarification as to the status of the Town of Hyannis' efforts and intentions to acquire my clients, B&S Fournier Realty Trust ("Fournier") and Hubbard Oil Company, Inc.'s ("Hubbard Oil") property located at 33 and 51 Brooks Road, Hyannis, Massachusetts under its eminent domain powers. It is our desire to resolve certain outstanding issues and/or concerns relating to remediation, relocation and valuation in order to avoid delay and/or a possible challenge to the Pro-Tanto amount to be awarded. We would appreciate another meeting with the Town/FAA and its consultants and representatives to receive written receipts of responses to this and our previous letter, dated September 5, 2003 to better understand and clarify the Town and FAA's intentions. (See enclosed). It has now been more than six (6) months since we last met to discuss and attempt to resolve many of my clients' concerns and questions. Frankly, we are less confident and clear as to the Town's intentions now then when we met in September 2003. Despite numerous phone calls from David Bennett, Bennett & O'Reilly, Inc. and me to the Town's representative, we have learned little, if any thing, about even the simplest questions we previously posed. Previous Decision and Meetings At the meeting of Town Council on July 17, 2003, a unanimous vote was taken to issue an order of taking. The Assistant Town Manager Joellen Daley appeared to be the principal Town spokesperson and in charge of the project and eminent domain process. She publicly 5660121 RUBIN AND RUDMAN LLP Barbara Harris, Esq. Robert Smith, Esq. April 20, 2004 Page 2 committed to work with the parties adversely effected by the eminent domain taking and suggested we correspond with you to get answers to the questions we expected that evening. I now that Joellen Daley has left and is no longer employed with the Town, however as an agent of the Town she committed to work with my clients and provide an open line of communication. Who is now the point person(s) who can give us meaningful and substantive answers? Despite my appearance and request for clarification of certain issues, unfortunately Town Council gave me and two other persons impacted by the taking only three (3) minutes each to ask questions or make comments. Absolutely no responses were provided by any Town Council member or consultant retained by the Town and present at the meeting to address the proposed Intermodal Parking and Airport Runway Expansion Plan and questions we raised. My clients and I found this type of hearing, and lack of any substantive response to important questions and issues by any Town officials and representatives rather nefarious, insulting and a total lack of respect for due process. We later met with four other persons, including yourselves, Mark Nelson and Joe Longo who represented to us to be spoke persons for the project and Town. Now all of you appear to lack any information or authorization to act on behalf of the Town. My clients demand to meet and speak again but only with persons who actually have authority to act on behalf of the Town. If this requires a meeting with the Town Council then please put us on the agenda and forward this and past correspondence to them. My clients have owned and operated the property and facility for more than thirty years, paid substantial taxes and has been a valuable source of heat and energy to Barnstable and the Cape residents. My clients did not cause the releases of oil on its property, which has operated as an oil storage depot for more than 50 years prior to their acquisition and use of the properties. Nevertheless, my clients have spent considerable time and money to clean up the properties in compliance with M.G.L. c.21E and its regulations. The paucity of information provided to date to my clients by the Town is without justification and we. hope for better and more comprehensive dialogue in the future. On the contrary, Fournier and Hubbard has proceeded in "good faith" to provide considerable information to the Town and Department of Environmental Protection ("DEP") about its remedial actions while protecting its legal rights and property interests. We have shown no disrespect or animosity to the Town, FAA or DEP. Aside from the summary conclusion to take the two parcels, my clients request and deserve answers to the following questions to the Town. A. Timinlz of the TakinLY/Advance Time for Relocation/Assistance Our clients remain concerned about locating a suitable replacement location for its business, Hubbard Oil and its tenant's business New Colony Oil, in Hyannis in which to operate its bulk oil storage business. As you are aware, given the unique nature of the business, relocation of the businesses present a potentially time-intensive search to identify an area that is 5660121 RUBIN AND RUDMAN LLP Barbara Harris, Esq. Robert Smith, Esq. April 20, 2004 Page 3 appropriate for bulk fuel oil storage, with adequate access and egress for heavy vehicles. We need and deserve specific and not general answers to the following questions: 1. When exactly does the Town anticipate that Hubbard Oil would have to move? 2. How much advance notice will the Town provide before our client's operations must be relocated and closed? 3. Does the Town or the FAA intend to provide assistance in locating another property upon which Hubbard Oil may continue to operate as a fuel oil storage business? Specifically, as it relates to the Town, our client is concerned about locating a suitable location and reasonable operating conditions. 4. Will the Town, including the Zoning Board of Appeals and Planning Board support the relocation in terms of any potential zoning relief(e.g., special permit, variance relief or rezoning) that may be required for its business operations and use, which can be permitted under the existing or amended Zoning Bylaws? We request that you contact any additional persons or parties to get answers to these questions or invite them to the next meeting so we can get complete and reliable answers to the above questions which still have not been answered to date. B. Continued Operation of Designed Remediation System As previously stated, Fournier and/or Hubbard Oil has expended a considerable amount of time, resources and money on environmental engineers and consultants in order to comply with M.G.L. c.21E, the Massachusetts Contingency Plan and an Administrative Consent Order with the DEP. Given these efforts to comply with DEP requirements, Hubbard Oil does not intend to be exposed to enforcement liability and stipulated penalties by the DEP and therefore, needs assurances by the Town that if it plans to take the property, that it will likewise either take over the ongoing remediation system as commenced and the cleanup of the property for the same costs and/or that it will agree to fund the ongoing remediation being advanced by our client. Bennett & O'Reilly, Inc. the environmental consultants who designed the remediation system believes that the system will still be able to operate under the proposed roadway, but the engineers would like to review existing and proposed site grading plans to determine whether certain modifications may be necessitated. . We have continued to monitor the pilot injection. system and natural attenuation at the Site; however Quarterly Monitoring is expensive and wasteful without the proposed injection of ORC and operation for the remedial system. We intend to terminate such Quarterly Monitoring until we get answers from the Town to the following questions about our proposed Remediation System Plan. (See enclosed Bennett & 5660121 RUBIN AND RUDMAN LLP Barbara Harris, Esq. Robert Smith, Esq. April 20, 2004 Page 4 O'Reilly, Inc. Remedial Operation Plan Status Report I Supporting Documentation to Laura Stanley, Bureau of Waste Site Cleanup, DEP, dated December 30, 2003). 1. Relative to Fournier/Hubbard Oil's preferred remediation system that has been designed, partially installed, tested and ready to commence operation; does the Town intent to continue or take over the operation of this same remedial system approved by the DEP as the preferred remedial approach? 2. Is the Town or the FAA amenable to paying for any extra costs associated with operation of this remediation system, resulting from the Town taking and construction of the roadway above the remediation system? 3. Further-more, when will the final plans for the design and layout of the new roadway and parking areas across Fournier's property be available for review? 4. When is all the permitting expected to be completed for the roadway and parking area in the vicinity of the Fournier property? 5. Can we expect the Town's and FAA's engineers and consultants to cooperate with Bennett & O'Reilly, Inc. to coordinate the design and construction of the roadway and the continuation of the remedial system on the Fournier property? 6. Will the Town or FAA supply the three phase electric supply that we currently have and need to operate the remedial system. Since the last meeting in September we have not received any answers to the above questions. The only information the Town provided was a request to put in an addition monitoring well in the middle of the railroad easements which is unnecessary, dangerous and will provide little if any valuable information regarding the extent of contamination at the Site. C. Valuation of the Property We have shared with the Town certain information concerning Fournier's contractual commitments in order to obtain fair compensation for the business and property acquisition and to assist in the Town's appraisal of the value of the land. As you know, the property actually consists of two parcels, upon which Hubbard Oil operated as upon which New Colony Oil operated under a lease. Prior to receiving any notification of the Town's intention to use its eminent domain powers, Fournier had entered into a lease of 51 Brooks Road with New Colony Oil, its present tenant at the property. Under that Lease, New Colony Oil had an option to purchase the 51 Brooks Road property for $250,000. New Colony Oil had acted upon the Option, finalizing the terms of the sale on May 7, 2003, setting the closing on the Property for 5660121 RUBIN AND RUDMAN LLP Barbara Harris, Esq. Robert Smith, Esq. April 20, 2004 Page 5 June 1, 2003. Incidentally, on May 7, 2003, the Town had sent by mail its first Notice of Intent to acquire the property, but Fournier did not receive the mailed notice until several days later. The terms of the purchase had been negotiated between the Buyer and Seller two years earlier on or about June 2001, but were finally agreed upon on May 7, 2003. The Buyer had put down a $1,000 deposit on this land as consideration on the agreement. Moreover, New Colony had also negotiated an Option to purchase 33 Brooks Road, which is the larger of the two parcels, containing buildings and other structures. The bulk fuel oil plant distribution facilities, loading racks and bulk 100,000 gallon storage tank are located on 33 Brooks Road. As you may know, it is this parcel in which the remediation system has been designed and implemented. Within the recent past, certain of its loading racks have been temporarily decommissioned to allow for the soil removal and installation of the remediation system. Nonetheless, Hubbard Oil has maintained its bulk oil terminal operational permits and has always intended to continue with this preexisting nonconforming bulk, oil storage facility use of the property. Since the taking decision Hubbard Oil has been unable to rebuild its storage, transfer and delivery facility and has lost revenue for the past nine months. These damages are continuing since the Town has failed to specify when is intends to take over the property. In fact, beginning on June 1, 2003, New Colony had entered into a Lease of the oil terminal, which lease term was to continue for two years and thereafter, New Colony committed to purchase 33 Brooks Road, Hyannis on May 1, 2005 under the terms of a binding Lease/Purchase Agreement. The value of the lease was $24,000 (i.e., $1,000 per month for two years) and the purchase price was established at $400,000. Here too, this Lease and Purchase Agreement was executed between our client and New Colony on May 7,2003, prior to receipt of the Town's Notice of intent to purchase the properties. We provided you with copies of the relevant Lease and Purchase Agreements, documenting the fair market value of the properties, 33 and 51 Brooks Road, as of May 7, 2003. In connection with establishing a fair market value, exclusive of relocation or moving costs, we feel that these contractual commitments with New Colony Oil are compelling evidence of the minimum fair market value for each of the subject parcels, i.e., 33 and 51 Brooks Road. As to the Town's intentions, we are interested in obtaining a better understanding of the Town's appraisal efforts, inclusive of the following inquiries/requests for information: 1. As Fournier has shared with the Town its Lease and Purchase Agreements, we likewise are seeking for the Town to provide our client with a copy of the Town's appraisal report prepared by Coleman &Associates, setting forth its explanation of how the Town's appraisers derived an estimated fair market value and proposed Pro-Tanto eminent domain award. 2. Will the Town have Coleman&Associates revise its appraisal report based on the Lease and Purchase Agreement provided? 566M 1 RUBIN AND RUDMAN LLP Barbara Harris, Esq. Robert Smith, Esq. April 20, 2004 Page 6 3. In addition to the Coleman & Associates report, is another appraisal report being prepared by on behalf of the FAA to confirm the Town's appraisal report, and if so, will the FAA appraisal take into consideration the Lease and Purchase Agreements provided herein be provided to Fournier? 4. Is or has the Town (or FAA) preparing any estimate for relocation costs? Alternatively does the Town (or FAA) expect Fournier to prepare such an estimate? If so, when is the Town(or FAA) seeking such an estimate? 5. Our client is concerned about ensuring that appropriate consideration is given to relocating its business interests and is seeking confirmation as to whether the Town or the FAA is charged with this aspect of the project. 6. Does the Town (or FAA) intend to advance any monies for our client's relocation costs and if so how much? In closing, please also advise us of the date(s) of any upcoming public meetings or meetings of Town Council or Town or FAA's consultants and representatives pertinent to the permitting and design of the project, eminent domain and relocation process.. We look forward to the meeting with the Town/FAA and its consultants and representatives and the subsequent receipt of written responses to this letter and each question we have posed to better understand and clarify the Town and FAA's intentions. Please confirm the date of the next planned meeting. I presume you will send copies of this letter and all past documents previously provided to the appropriate Town and FAA officials and counsel who will be present at the meeting. We would request that a DEP representative such as Laura Stanley or other state official involved in the permitting process be present to facilitate answers to these questions. Thank you for your attention to these matters. Should you have any questions, please do not hesitate to contact me. Sincerely yours, Rubin an dman LLP o rt asanell Enclosures cc: Bert Fournier, B&A Realty Trust (by facsimile and first class mail) Evelyn Reed, General Manager, Hubbard Oil Co. Inc. (by facsimile and first class mail) David Bennett, LSP/PE, Bennett& O'Reilly, Inc. (by facsimile and first class mail) John Longo, Horsely & Witten Inc. (by facsimile and first class mail) Mark Nelson, Horsely & Witten Inc. (by facsimile and first class mail) Laura Stanley, DEP/SE, Bureau of Waste Site Cleanup (by first class mail) 5660121 Massachusetts Department of Environmental Protection BWSC108 Bureau of Waste Site Cleanup Release Tracking Number COMPREHENSIVE RESPONSE ACTION TRANSMITTAL FORM & PHASE I COMPLETION STATEMENT - 824 Pursuant to 310 CMR 40.0484(Subpart D)and 40.0800(Subpart H) L71 A. SITE LOCATION: 1. Site Name: Hubbard Oil Co., Inc. 2. Street Address: 33 & 51 Brooks Road 3. city/Town: Hyannis 4. ZIP Code: 02601-0000 © 5. Check here if a Tier Classification Submittal has been provided to DEP for this disposal site. Fla. Tier 1 A ❑ b. Tier 1 B Q✓ c. Tier 1 C d. Tier 2 6. If applicable, provide the Permit Number- 31003452 B.THIS FORM IS BEING USED TO: (check all that apply) 1. Submit a Phase I Completion Statement, pursuant to 310 CMR 40.0484. 2. Submit a Revised Phase I Completion Statement,pursuant to 310 CMR 40.0484. ❑ 3. Submit a Phase II Scope of Work,pursuant to 310 CMR 40.0834. Fi 4. Submit an interim Phase II Comprehensive Site Assessment Report pursuant to 310 CMR 40.0835 (An interim Phase II Report does not satisfy the response action deadline requirements in 310 CMR 40.0500). 5. Submit a final Phase II Comprehensive Site Report and Completion Statement, pursuant to 310 CMR 40.0836. Specify the outcome of the Phase 11 Comprehensive Site Assessment: (check one) a. Comprehensive Remedial Actions are necessary at the site to achieve a Response Action Outcome. A Phase III ❑ study for the identification,evaluation,and selection of Comprehensive Remedial Action Alternatives,pursuant to 310 CMR 40.0850,is necessary. b. The requirements of a Class A Response Action Outcome have been met, and a completed Response Action Outcome Statement and Report(BWSC104)will be submitted to DEP. c. The requirements of a Class B Response Action Outcome have been met and a completed Response Action Outcome Statement and Report(BWSC104)will be submitted to DEP. 6. Submit a Revised Phase II Comprehensive Site Report and Completion Statement,pursuant to 310 CMR 40.0836. ❑ 7. Submit a Phase III Remedial Action Plan and Completion Statement, pursuant to 310 CMR 40.0862. 8. Submit a Revised Phase III Remedial Action Plan and Completion Statement, pursuant to 310 CMR 40.0862. 9. Submit a Phase IV Remedy Implementation Plan, pursuant to 310 CMR 40.0874. 10. Submit a Modified Phase IV Remedy Implementation Plan, pursuant to 310 CMR 40.0874. 11. Submit an As-Built Construction Report, pursuant to 310 CMR 40.0875. (All sections of this transmittal form must be filled out unless otherwise noted above) Revised:. 05/02/2003 Page 1 of 5 Massachusetts Department of Environmental Protection Bureau of Waste Site Cleanup BWSC108 COMPREHENSIVE RESPONSE ACTION TRANSMITTAL Release Tracking Number FORM & PHASE I COMPLETION STATEMENT ® - 824 ------ - - . Pursuant to 310 CMR 40.0484(Subpart D)and 40.0800(Subpart H) B.THIS FORM IS BEING USED TO(cont.): (check all that apply) 12. Submit a Phase IV Final Inspection Report and Completion Statement, pursuant to 310 CMR 40.0878 and 40.0879. Specify the outcome of Phase IV activities: a. Phase V Operation, Maintenance or Monitoring of the Comprehensive Remedial Action is necessary to achieve a Response Action Outcome. b. The requirements of a Class A Response Action Outcome have been met. No additional Operation, Maintenance or ❑ Monitoring is necessary to ensure the integrity of the Response Action Outcome. A completed Response Action Outcome Statement and Report(BWSC104)will be submitted to DEP. c. The requirements of a Class C Response Action Outcome have been met. No additional Operation, Maintenance or Monitoring is necessary to ensure the integrity of the Response Action Outcome. A completed Response Action Outcome Statement and Report(BWSC104)will be submitted to DEP. d. The requirements of a Class C Response Action Outcome have been met. Further Operation, Maintenance or Monitoring of the remedial action is necessary to ensure that conditions are maintained and that further progress is made toward a Permanent Solution. A completed Response Action Outcome Statement and Report (BWSC104)will be submitted to DEP. 13. Submit a Revised Phase IV Final Inspection Report and Completion Statement, pursuant to 310 CMR 40.0878 and 40.0879. 14. Submit a periodic Phase V Inspection&Monitoring Report,pursuant to 310 CMR 40.0892. ✓0 15. Submit a Remedy Operation Status, pursuant to 310 CMR 40.0893. 16. Submit a Termination of a Remedy Operation Status, pursuant to 310 CMR 40.0893(5). 17. Submit a final Phase V Inspection&Monitoring Report and Completion Statement, pursuant to 310 CMR 40.0894. Specify the outcome of Phase V activities: a. The requirements of a Class A Response Action Outcome have been met. No additional Operation, Maintenance or Monitoring is necessary to ensure the integrity of the Response Action Outcome. A completed Response Action Outcome Statement(BWSC104)will be submitted to DEP. b. The requirements of a Class C Response Action Outcome have been met. No additional Operation, Maintenance or Monitoring is necessary to ensure the integrity of the Response Action Outcome. A completed Response Action Outcome Statement and Report(BWSC104)will be submitted to DEP. c. The requirements of a Class C Response Action Outcome have been met. Further Operation, Maintenance or DMonitoring of the remedial action is necessary to ensure that conditions are maintained and/or that further progress is made toward a Permanent Solution. A completed Response Action Outcome Statement and Report(BWSC104)will be submitted to DEP. 18. Submit a Revised Phase V Inspection&Monitoring Report and Completion Statement, pursuant to 310 CMR 40.0894. 19. Submit a Post-Response Action Outcome Inspection&Monitoring Report, pursuant to 310 CMR 40.0897. (All sections of this transmittal form must be filled out unless otherwise noted above), Revised: 05/02/2003 Page 2 of 5 Massachusetts Department of Environmental Protection Bureau of Waste Site Cleanup BWSC108 COMPREHENSIVE OM REHENSIVE RESPONSE ACTION TRANSMITTAL Release Tracking Number FORM & PHASE 1 COMPLETION STATEMENT ® - 824 I,-------- Pursuant to 310 CMR 40.0484(Subpart D)and 40.0800(Subpart H) LSP SIGNATURE AND STAMP: I attest under the pains and penalties of perjury that I have personally examined and am familiar with this transmittal form, including any and all documents accompanying this submittal. In my professional opinion and judgment based upon application of(i)the standard of care in 309 CMR 4.02(1), (ii)the applicable provisions of 309 CMR 4.02(2)and (3),and 309 CMR 4.03(2),and (iii)the provisions of 309 CMR 4.03(3),to the best of my knowledge, information and belief, > if Section B indicates that a Phase I,Phase 11,Phase 111,Phase IV or Phase V Completion Statement is being submitted,the response action(s)that is(are)the subject of this submittal(i)has(have)been developed and implemented in accordance with the applicable provisions of M.G.L.c.21 E and 310 CMR 40.0000, (ii)is(are)appropriate and reasonable to accomplish the purposes of such response action(s)as set forth in the applicable provisions of M.G.L.c.21 E and 310 CMR 40.0000,and(iii) comply(ies)with the identified provisions of all orders, permits,and approvals identified in this submittal; > if Section 8 indicates that a Phase ll Scope of Work or a Phase IV Remedy Implementation Plan is being submitted,the response action(s)that is(are)the subject of this submittal(i)has(have)been developed in accordance with the applicable provisions of M.G.L.c.21 E and 310 CMR 40.0000, (ii)is(are)appropriate and reasonable to accomplish the purposes of such response action(s)as set forth in the applicable provisions of M.G.L.c.21 E a nd 310 CMR 40.0000,and(iii)comply(ies)with the identified provisions of all orders, permits,and approvals identified in this submittal; > if Section B indicates that an As-Built Construction Report,,Phase V Inspection and Monitoring Report,or a Remedy Operation Status is being submitted,the response action(s)that is(are)the subject of this submittal(i)is(are)being implemented in accordance with the applicable provisions of M.G.L.c.21 E and 310 CMR 40.0000, (ii)is(are)appropriate and reasonable to accomplish the purposes of such response action(s)as set forth in the applicable provisions of M.G.L.c.21 E and 310 CMR 40.0000,and (iii)comply(ies)with the identified provisions of all orders,permits,and approvals identified in this submittal. I am aware that significant penalties may result,'including, but not limited to, possible fines and imprisonment, if I submit information which I know to be false, inaccurate or materially incomplete. 1. LSP#: 4303 2. First Name: David 3. Last Name: Bennett 4. Telephone: (5 ) 30 5 Ext.: 102 g. FAX: (508) 896-4687 7. Signature: 8. Date: 9.LSP Stamp: No.4303 , C�6T6 '�'TE Phi Revised: 05/02/2003 Page 3 of 5 Massachusetts Department of Environmental Protection { Bureau of Waste Site Cleanup BWSC108 i COMPREHENSIVE RESPONSE ACTION TRANSMITTAL Release Tracking Number FORM & PHASE I COMPLETION STATEMENT L7 - Pursuant to 310 CMR 40.0484(Subpart D)and 40.0800(Subpart H) D. PERSON UNDERTAKING RESPONSE ACTIONS: 1. Check all that apply: El a.change in contact name b. change of address c. change in the person undertaking response actions 2. Name of Organization: Hubbard Oil Co., Inc. 3. Contact First Name: Evelyn 4. Last Name: Read 5. Street: PO Box 10 6.Title: General Manager 7. City/Town: Hyannis 8. State: MA 9. ZIPCode: 02601-0000 10. Telephone: (508) 775-3711 11.Ext.: 12. FAX: 508 778-9403 E. RELATIONSHIP TO SITE OF PERSON UNDERTAKING RESPONSE ACTIONS: 1. RP or PRP a. Owner b. Operator ❑ c. Generator d. Transporter ❑ e. Other RP or PRP Specify: 2. Fiduciary,Secured Lender or Municipality with Exempt Status(as defined by M.G.L.c.21 E,s.2) El 3. Agency or Public Utility on a Right of Way(as defined by M.G.L.c.21 E,s.50)) 4. Any Other Person Undertaking Response Actions Specify Relationship: F. REQUIRED ATTACHMENT AND SUBMITTALS: 1. Check here if the Response Action(s)on which this opinion is based,if any,are(were)subject to any order(s), permit(s) Q and/or approval(s)issued by DEP or EPA. If the box is checked,you MUST attach a statement identifying the applicable provisions thereof. 2. Check here to certify that the Chief Municipal Officer and the Local Board of Health have been notified of the submittal of any Phase Reports to DEP. 3. Check here to certify that the Chief Municipal Officer,the Local Board of Health and the Environmental Monitor have been .notified of the availability of a Phase III Remedial Action Plan. For Tier 1A and Tier 1 B sites,a MEPA Notice also must be submitted. 4. Check here to certify that the Chief Municipal Officer,the Local Board of Health and the Environmental Monitor have been notified of the availability of a Phase IV Remedy Implementation Plan. For Tier 1A and Tier 1 B sites a MEPA Notice also must be submitted. 5. Check here to certify that the Chief Municipal Officer and the Local Board of Health have been notified of any field work involving the implementation of a Phase IV Remedial Action. ❑ 6. Check here if any non-updatable information provided on this form is incorrect,e.g. Release Address/Location Aid. Send corrections to the DEP Regional Office. Q 7. Check hereto certify that the LSP Opinion containing the material facts, data,and other information is attached. Revised: 05/02/2003 Page 4 of 5 Massachusetts Department of Environmental Protection Bureau of Waste Site Cleanup BWSC108 COMPREHENSIVE 'RESPONSE ACTION TRANSMITTAL Release Tracking Number FORM & PHASE I COMPLETION STATEMENT ® 824 -- Pursuant to 310 CMR 40.0484(Subpart D)and 40.0800(Subpart H) G. CERTIFICATION OF PERSON UNDERTAI(ING RESPONSE ACTIONS: 1. I,Evelyn Read ,attest under the pains and penalties of perjury(i)that I have personally examined and am familiar with the information contained in this submittal, including any and all documents accompanying this transmittal form,(ii)that, based on my inquiry of those individuals immediately responsible for obtaining the information,the material information -.ontained in this submittal is,to the best of my knowledge and belief,true,accurate and complete,and(iii) that I am fully authorized to make this attestation on behalf of the entity legally responsible for this submittal I/the person or entity on whose behalf this submittal is made am/is aware that there are significant penalties, including,but not limited to, possible fines and imprisonment,for willfully submitting false,inaccurate,or incomplete information. 2. By: ) /�'/ 3. Title: General Manager Signature 4. For: Hubbard Oil CO., Inc. 5. Date: July, 12 , 2004 (Name of person or entity recorded in Section D) mm/dd/yyyy 6. Check here if the address of the person providing certification is different from address recorded in Section D. 7. Street: 8. City/Town: 9. State: 10. ZIP Code: 11. Telephone: 12.Ext.: 13. FAX: YOU MUST LEGIBLY COMPLETE ALL RELEVANT SECTIONS OF THIS FORM OR DEP MAY RETURN THE DOCUMENT AS INCOMPLETE. IF YOU SUBMIT AN INCOMPLETE FORM,YOU MAY BE PENALIZED FOR MISSING A REQUIRED DEADLINE. Date Stamp(DEP USE ONLY:) Revised: 05/02/2003 Page 5 of 5 APPENDIX D � PECT FEB 2 4_ ,r,�a GR13UND //CATER Groundwater Analytical,Inc. P.O. uz Main Street Box 1200 ANALYTICAL Buzzards Bay,MA 02532 Telephone(508)759-4441 February 23 2004 FAX(508)759-4475 ry , . www.groundwateranalytical.com Mr. David Bennett Bennett & O'Reilly, Inc. P.O. Box 1667 Brewster, MA 02631 LABORATORY REPORT Project: Hubbard Oil/ Brooks Rd./BO02-3490 Lab I D: 69408 Received: 02-06-04 Dear Dave: Enclosed are the analytical results for the above referenced project. The project was processed for Standard turnaround. This letter authorizes the release of the analytical results, and should be considered a part of this report. This report contains a sample receipt report detailing the samples received, a project narrative indicating project changes and non-contormances, a quality control report, and a statement of our state certifications. The analytical results contained in this report meet all applicable NELAC standards, except as may be specifically noted, or described in the project narrative. This report may only be used or reproduced in its entirety. I attest under the pains and penalties of perjury that, based upon my inquiry of those individuals immediately responsible for obtaining the information, the material contained in this report is, to the best of my knowledge and belief, accurate and complete. Should you have any questions concerning this report, please do not hesitate to contact me. Sincerely, Jonathan R. Sanford President JRS/smd Enclosures y- _ -- GROUNDWATER ANALYTICAL Sample Receipt Report Project: Hubbard Oil/Brooks Rd./13002-3490 Delivery: GWA Courier Temperature: 2'C Client: Bennett&O'Reilly, Inc. Airbill: n/a Chain of Custody: Present Lab ID: 69408 Lab Receipt: 02-06-04 Custody Seal(s): n/a Lab ID Field ID i� ;_ fu.. ..._Matnx t5ampleds 3 Method zx ' 69408-1 GZA-1 Aqueous 2/5/04 13:30 MA DEP VPH with Targets Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C350053 40 mL VOA Vial Industrial BX9938 HCI R-3857D 12-11-03 n/a C351718 40 mL VOA Vial Industrial BX9274 HCI R-3722E 09-19-03 n/a C351765 40 mL VOA Vial Industrial BX9274 HCI R-3722E 09-19-03 n/a #Lab ID F Field IDS 69408-2 GZA-2 Aqueous 2/5/04 13:30 MA DEP VPH with Targets Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C350077 40 mL VOA Vial Industrial BX9938 HCI R-3857D 12-11-03 n/a C350078 40 mL VOA Vial Industrial BX9938 HCI R-3857D 12-11-03 n/a C350065 40 mL VOA Vial Industrial BX9938 HCI R-3857D 12-11-03 n/a Lab IDr`s F�e1drlD Matrix ' Sampled s Metho l"'�' n 3c.., a Notes 0 �' ,� 69408-3 MW-5S Aqueous 2/5/04 12:00 MA DEP VPH with Targets Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C350120 40 mL VOA Vial Industrial BX9938 HCI R-3857D 12-11-03 n/a C350122 40 mL VOA Vial Industrial BX9938 HCI R-3857D 12-11-03 n/a C350121 40 mL VOA Vial Industrial BX9938 HCI R-3857D 12-11-03 n/a Lab ID Feld ID Mat1z Sam led �` Method, Notes n $* 694084 MW-513 u Aqueous 2/5/04 12:10 MA DEP VPH with.Targets Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C350109 40 mL VOA Vial Industrial BX9938 HCI R-3857D 12-11-03 n/a C350108 40 mL VOA Vial Industrial BX9938 HCI R-3857D 12-11-03 n/a C350097 40 mL VOA Vial Industrial BX9938 HCI R-3857D 12-11-03 n/a IFIeIdtD 69408-5 MW-6S Aqueous 2/5/04 13:00 MA DEP VPH with Targets Con ID Container Vendor QC Lot Presery QC Lot Prep Ship ,C338167 40 mL VOA Vial Industrial BX9966 HCI R-3722D 11-03-03 11-25-03 C338155 40 mL VOA Vial Industrial BX9966 HCI R-3722D 11-03-03 11-25-03 C351742 40 mL VOA Vial Industrial I BX9274 I HCI R-3722E 09-19-03 n/a Lab ID p F�eld'ID a Mafriz + Sam led Method�a p ... .x.t - e w. .,ry_. _ ,. ... _ 69408-6 MW-613 Aqueous 2/5/04 12:50 MA DEP VPH with Targets Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C338154 40 mL VOA Vial Industrial BX9966 HCI R-3722D 11-03-03 11-25-03 C338191 40 mL VOA Vial Industrial BX9966 HCI R-3722D 11-03-03 11-25-03 C338179 40 mL VOA Vial Industrial BX9966 HCI R-3722D 11-03-03 11-25-03 Lab iD Feld ID ' s, Matrix Sampled ` Method r s p F k Notes x « 'a. .,- .Y-...c a..'�k.a.. ,u...•.eva._ .� . -„?fit a 69408-7 MW-1 Aqueous 2/5/04 14:45 MA DEP VPH with Targets Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C338215 40 mL VOA Vial Industrial BX9966 HCI R-3722D 11-03-03 11-25-03 C338202 40 mL VOA Vial Industrial BX9966 HCI R-3722D 11-03-03 11-25-03 C351775 40 mL VOA Vial Industrial BX9274 HCI I R-3722E 09-19-03 n/a Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Sample Receipt Report (Continued) Project: Hubbard Oil/Brooks Rd./BO02-3490 Delivery: GWA Courier Temperature: 2'C Client: Bennett&O'Reilly, Inc. Airbill: n/a Chain of Custody: Present Lab ID: 69408 Lab Receipt: 02-06-04 Custody Seal(s): n/a I Met69408-8 MW-2 2/5/04 14:45 MA DEP VPH with Targets Con ID Container Vendor Presery QC Lot Prep Ship C350066 40 mL VOA Vial Industrial HCI R-3857D 12-11-03 n/a C351777 40 mL VOA Vial IndustrialHCI R-3722E 09-19-03 n/a C351730 40 mL VOA Vial Industrial HCI R-3722E 09-19-03 n/a �Lab ID #a Freld tD Matrix Sam led Method 9 - �?'...,>i � se .,,,...��.c'k',..�,<,wa.ss.;°=.�„ ps-. .arm.Z'9:xR.�..avara�v�a?±c .,ad..;;.�.,r:k"ds '�,s�.�'�c.�,�'�`�.�,-'cw".... y�"^ue �u�•, +�tr ";k:�;.`�"�":.�f,?�..��`s'; .����;.� 69408-9 MW-4 Aqueous 2/5/04 15:20 MA DEP VPH with Targets Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C350080 40 mL VOA Vial Industrial BX9938 HCI R-3857D 12-11-03 n/a C350079 40 mL VOA Vial Industrial BX9938 HCI R-3857D 12-11-03 n/a C350067 40 mL VOA Vial Industrial BX9938 HCI R-3857D 12-11-03 n/a Lab ID FreldlD " 1HMarix ` Sam led ynMethnil ' mac .69408-10 SEA-1 Aqueous 2/5/04 15:50 MA DEP VPH with Targets Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C338203 40 mL VOA Vial Industrial BX9966 HCI R-3722D 11-03-03 11-25-03 C338178 40 mL VOA Vial Industrial BX9966 HCI R-3722D 11-03-03 11-25-03 C338166 40 mL VOA Vial Industrial BX9966 HCI R-3722D 11-03-03 11-25-03 Cab ID` F�eld;ID ' I eth 69408-11 SEA-2 2/5/04 15:30 MA DEP VPH with Targets Con ID Container Vendor Presery QC Lot Prep Ship C338165 40 mL VOA Vial Industrial HCI R-3722D 11-03-03 11-25-03 C350068 40 mL VOA Vial Industrial HCI R-3857D 12-11-03 n/a C350056 40 mL VOA Vial Industrial BX9938 HCI R-3857D 12-11-03 n/a L'ab . N v e b fi 69408-12 GZA-1 Aqueous 2/5/04 13:30 MA DEP EPH with PAHs by 8270C-Mod SIM Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C348677 1 L Amber Glass Proline BX10194 H2SO4 R-37796 12-29-03 n/a C348676 1 L Amber Glass Proline BX10194 H2SO4 R-37796 12-29-03 n/a tab ID x FieId1D°� �y "fMatnx Sampled_, Method .¢. < Notes i 69408-13 GZA-2 Aqueous 2/5/04 13:30 MA DEP EPH with PAHs by 8270C-Mod SIM Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C348675 1 L Amber Glass Proline BX10194 H2SO4 R-3779B 12-29-03 n/a C348674 1 L Amber Glass Proline BX10194 H2SO4 R-37796 12-29-03 n/a x C ' 4 F'E * � '>a79 _ d, t`Lab ID ,F�eld ID a .z. ,�` Matrix Notes ma _ 69408-14 MW-SS Aqueous 2/5/04 12:00 MA DEP EPH with PAHs by 8270C-Mod SIM Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C326870 1 L Amber Glass Proline BX10901 H2SO4 R-37796 01-21-04 n/a C326863 1 L Amber Glass Proline BX10901 H2SO4 R-37796 01-21-04 n/a 69408-15 MW-5D Aqueous 2/5/04 12:10 IMA DEP EPH with PAHs by 8270C-Mod SIM Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C326869 1 L Amber Glass Proline BX10901 H2SO4 R-37796 01-21-04 n/a C326862 1 L Amber Glass Proline BX10901 H2SO4 R-37796 01-21-04 n/a Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Sample Receipt Report (Continued) Project: Hubbard Oil/Brooks Rd./BO02-3490 Delivery: GWA Courier Temperature: 2'C Client: Bennett&O'Reilly, Inc. Airbill: n/a Chain of Custody: Present Lab ID: 69408 Lab Receipt: 02-06-04 Custody Seal(s): n/a Lab ID 4Field ID Matr`ix1" SampledMeYhod iE Nos IN,e ' w j F sj �, - -. 69408-16 MW-6S Aqueous 2/5/04 13:00 MA DEP EPH with PAHs by 8270C-Mod SIM Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C348679 1 ri Amber Glass Proline BX10194 H2SO4 R-37796 12-29-03 n/a C348678 1 L Amber Glass Proline BX10194 H2SO4 R-3779B 12-29-03 n/a L'ab 1D 1siFieldslD a7 7 �Matnx kSampledMethod � � e .k �......': _ 69408-17 MW-613 Aqueous 2/5/04 12:50 MA DEP EPH with PAHs by 8270C-Mod SIM Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C348671 1 L Amb=r Glass Proline BX70194 H2SO4 R-3779B 12-29-03 n/a C348670 1 L Amber Glass Proline BX10194 H2SO4 R-3779B 12-29-03 n/a Lab ID r Frelc ID * Matrix c Sam led"} Method ` `N "�s" Notes 4 z *a mot. o-,���^rz, s. ,�n„�,. p z;:.�. t �'.w^n>'�.�a ,..ct, •1��,-H «.�' :�,�,�„' n �,.r.. 69408-18 MW-1 Aqueous 2/5/04 14:45 MA DEP EPH with PAHs by 8270C-Mod SIM Con ID Container Vendor QC Lot Presery :::Q7C::L:.:t:=Prep. Ship C348673 1 L Amber Glass Proline BX10194 H2SO4 R-3779B 12-29-03 n/a C348668 1 L Amber Glass Proline BX10194 H2SO4 R-37796 12-29-03 n/a Lab ID Fiela:ID 1 Matrix Sampled ' `Method > �_ notes "'" q - ° 69408-19 MW-2 Aqueous 2/5/04 14:45 MA DEP EPH with PAHs by 8270C-Mod SIM Con ID Contziner Vendor QC Lot Presery QC Lot Prep Ship C348672 1 L Amber Glass Proline BX10194. H2SO4 R-3779B 12-29-03 n/a C348669 1 L Amber Glass Proline BX10194 H2SO4 R-37796 1 12-29-03 n/a to z 'a sa 3 Lab ID x4 �F�eld%ID F� a Matrix aSampled +Method _ •? `totes 69408-20 MW4 Aqueous- 2/5/04 15:20 MA DEP EPH with PAHs by 8270C-Mod SIM Con ID Container Vendor QC Lot Presery QC Lot Prep Ship. C326833 1 L Amber Glass Proline BX10898 H2SO4 R-37796 01-21-04 n/a C326832 1 L Amber Glass Proline BX10898 H25o4 R-37796 01-21-04 n/a 'T ra ,.i. Lab1D adField;ID ..�. r � * Math x-aSampledar .a�Method�� a�, � � wsNotesr 69408-21 SEA-1 Aqueous 2/5/04 15:50 MA DEP EPH with PAHs by 8270C-Mod SIM Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C326837 1 L Amber Glass Proline BX10898 H2SO4 R-37796 01-21-04 n/a C326830 1 L Amber Glass Proline BX10898 H2SO4 R-37796 01-21-04 n/a � F r Matrix ' a°Sm led .. Method " } Notes k f Lab 1D x � Field=ID -� p ,zxa� ,-. .._ 69408-22 SEA-2 Aqueous 2/5/04 15:30 MA DEP EPH with PAHs by 8270C-Mod SIM Con ID Container Vendor QC Lot Presery QC Lot Prep .Ship C326836 1 L Amber Glass Proline BX10898 H2SO4 R-37796 01-21-04 n/a C326831 1 L Amber Glass Proline BX10898 H2SO4 R-37796 01-21-04 n/a Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Data Certification Project: Hubbard Oil/Brooks Rd./13002-3490 Lab ID: 69408 Client: Bennett&O'Reilly,Inc. Received: 02-06-04 12:50 -t =c - r. �� Project Location: n/a MA DEP RTN: n/a This Form provides certifications for the following data set: MA DEP VPH: 69408-01,02,-03,04,05,-06,07,-08,-09,-10,-11 MA DEP EPH: 69408-12,-13,-14,-15,-16,-17,-18,-19,-20,-21,22 Sample Matrices: Groundwater (X). Soil/Sediment ( ) Drinking Water ( ) Other ( ) ,�itiCPuSW 846 Zk *_ 8260B ( 8151A ( ) 8330 ( ) 6010B ( ) 7470A11A ( ) �ivlethods Us"ed r{ 8270C ( ) 8081A ( ) VPH (X) 6020 ( ) 9012A2 ( ) �y,As specri�ed i M�aEP-� 8082 ( 3 8021 B ( ) EPH (X) 7000 S3 ( ) Other ( ) � �omp�endwm otAnalytical��t list�Release Tracking Number(RTN) rf known x �° ��� � � � � z � s r-� �� "� <"; Methods i 2 SW 846 Method 941E2R(Equivalent to 9014Y o�MA 6 Phys;olog cally Available Cyanide(PAC)Methods ' Yi st (check all that apK ly) 3 5 W 846'Me[hods 7C00$en s Mist ndividual method and an`atyte �` �y < .2 > ✓..?a>. x ,,,;mt_� __._,,, An affirmative response to questions A. B,C and D is required for"Presumptive Certainty"status. A. Were all samples received by the laboratory in a condition consistent with that described on the Chain-of-Custody documentation for the data set? Yes 7 B. Were all QA/QC procedures required for the specified analytical method(s)... included in this report followed,including the requirement to note and discuss in a narrative QC data that did not meet appropriate performance standards or guidelines? Yes C. Does the analytical data included n this report meet all the requirements for"Presumptive Certainty,"as described in Section 2.0 of the MA DEP document CAM VII A,Quality Assurance and Quality Control Guidelines for the Acquisition and Reporting of Analytical Data? Yes D. VPH and EPH methods only: Was the VPH or EPH method run without significant modifications,as specified in Section 11.3? Yes A response to questions E and F below is required for"Presumptive Certainty"status. E. Were all QC performance standards and recommendations for the specified methods achieved? No F. Were results for all analyte-list compounds/elements for the specified method(s)reported? Yes All No answers are addressed in the attached Project Narrative. I,the undersigned,attest under the pains and penalties of perjury that,based upon my personal inquiry of those responsible for obtaining the information,the material contained in this analytical report is,to the best of my knowledge and belief,accurate and complete. Signature: Position: President Name: Jonathan .Sa#ford Printed NDate: 02-23-04 Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Massachusetts DEP VPH Method Volatile Petroleum Hydrocarbons by GC/PID/FID Field ID: GZA-1 Matrix: Aqueous Project: Hubbard Oil/Brooks Rd./BO02-3490 Container: 40 mL VOA Vial Client: Bennett&O'Reilly,Inc. Preservation: HCI/Cool Laboratory ID: 69408-01 QC Batch ID: VG10-2042-W Sampled: 02-05-04 13:30 Instrument ID: GC-10 HP 6890 Received: 02-06-04 12:50 Sample Volume: 5 mL Analyzed: 02-17-04 11:58 Dilution Factor: 1 Analyst: PO Rangesx ✓' . �' q . Cs'`�'°;. Concgrttratron '�-=.: -., '=" NOteS,,,e. _..-,t�.._Unit$ eportmgil�mR n-05 to n-C8 Aliphatic Hydrocarbons to BRL ug/L 20 n-C9 to n-C12 Aliphatic Hydrocarbons to BRL ug/L 20 n-C9 to n-C10 Aromatic Hydrocarbons t 37 ug/L 20 Unadiusted n-05 to n-C8 Aliphatic Hydrocarbons t BRL ug/L 20 Unadjusted n-C9 to n-C12 Aliphatic Hydrocarbons t 46 ug/L 20 CAS Number Anal a oncentratton Notes . Untts p g e orti �mt 1634-04-4 Methyl tert-butyl Ether" BRL ug/L 5 71-43-2 Benzene° BRL ug/L 1 108-88-3 Toluene° BRL ug/L 5 100-41-4 Eth (benzene= BRL ug/L 5 108-38-3 and 106-42-3 meta-X lene and para-X lene# BRL ug/L 5 95-47-6 ortho- Xylene; BRL ug/L 5 91-20-3 Naphthalene BRL ug/L 5 QC Surrogate Compound , Spiked` Measured,W "ecovery r r f QC Ltmtts 2,5-Dibromotoluene(PID) 1 100 110 114 % 70-130% 2,5-Dibromotoluene(FID) 100 110 114 % 70-130% QA/QC Certtftcatton .,.., �_ � . 4 ,aT._. .. .,. . 1. Were all QA/QC procedures required by the method followed? Yes 2. Were all performance/acceptance standards for the required QA/QC procedures achieved? Yes 3. Were any signi=icant modifications made to the method,as specified in Section 11.3.2.1? No Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompanying signed project cover letter. The accompanying cover letter,project narrative and quality control report are considered part of this data report. Method Reference: Method for the Determination of Volatile Petroleum Hydrocarbons,MA DEP(1998). Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting in that range. 0 n-05 to n-C8 Aliphatic Hydrocarbons range data excludes the method target analyte concentrations. ® n-C9 to n-C12 Aliphatic Hydrocarbons range data excludes the method target analyte concentrations and the concentration for the n-C9 to n-C10 Aromatic Hydrocarbons range. u Analyte elutes in the n-05 to n-C8 Aliphatic Hydrocarbons range. t Analyte elutes in the n-C9 to n-C12 Aliphatic Hydrocarbons range. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Massachusetts DEP VPH Method Volatile Petroleum Hydrocarbons by GGPIDNID Field ID: GZA-2 Matrix: Aqueous Project: Hubbard Oil/Brooks Rd./0002-3490 Container: 40 mL VOA Vial Client: Bennett&O'Reilly,Inc. Preservation: HCI/Cool Laboratory ID: 69408-02 QC Batch ID: VG10-2042-W Sampled: 02-05-04 13:30 Instrument ID: GC-10 HP 6890 Received: 02-06-04 12:50 Sample Volume: 5 mL Analyzed: 02-17-04 13:15 Dilution Factor: 1 Analyst: PO U� , ReportmgLimit . n-05 to n-C8 Aliphatic Hydrocarbons t0 BRL ug/L 20 n-C9 to n-C12 Aliphatic Hydrocarbons to BRL ug/L 20 n-C9 to n-Cl0 Aromatic Hydrocarbons t 20 ug/L 20 Unadjusted n-05 to n-C8 Aliphatic Hydrocarbons t BRL ug/L 20 Unadiusted n-C9 to n-C12 Aliphatic Hydrocarbons t BRL ug/L 20 CAS Number-' Aitatyte r, , , r xConcentration; NotesUf11tS r�RepoRmgLlmit 1634-044 Methyl tert-butyl Ether° BRL ug/L 5 71-43-2 Benzene° BRL ug/L 1 108-88-3 Toluene° BRL ug/L 5 100-41-4 Eth (benzene$ BRL ug/L 5 108-38-3 and 10&42-3 meta-X lene and para-Xylenet BRL ug/L 5 95-47-6 ortho- X lene t BRL ug/L 5 91-20-3 Naphthalene BRL ug/L 5 C S,Ilrl'O ate'Com 011tldu sxs-"„ y.'; sw etc... i r ,F "s '"5a�` §a`e Recovevr C Lrtnts ! rY 25-Dibromotoluene(PID) 100 110 109 % 70-130% 2,5-Dibromotoluene(FID) 100 ,110 109 % 70-130% f �•- �' 'F4 e ' �'��, �� } Mgt- i.�m �.�rA " QfV QC CeI��ficat�on"' .w�kh5 p"iYFF�..��"�. �=�'.:.`.,vt�vs� .�.��3 �ci'��'.'.�.aW,r� �.,A�� �.�is ... 1. Were all QA/QC procedures required by the method followed? Yes 2. Were all performance/acceptance standards for the required QA/QC procedures achieved? Yes 3. Were any significant modifications made to the method,as specified in Section 11.3.2.1? No Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by.the accompanying signed project cover letter. The accompanying cover letter,project narrative and quality control report are considered part of this data report. Method Reference: Method for the Determination of Volatile Petroleum Hydrocarbons,MA DEP(1998). Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting in that range. 0 n-05 to n-C8 Aliphatic Hydrocarbons range data excludes the method target analyte concentrations. ® n-C9 to n-C12 Aliphatic Hydrocarbons range data excludes the method target analyte concentrations and the concentration for the n-C9 to n-C10 Aromatic Hydrocarbons range. u Analyte elutes in the n-05 to n-C8 Aliphatic Hydrocarbons range. t Analyte elutes in the n-C9 to n-C12 Aliphatic Hydrocarbons range. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Massachusetts DEP VPH Method Volatile Petroleum Hydrocarbons by GC/PI D/FI D Field ID: MW-5S Matrix: . Aqueous Project: Hubbard Oil/Brooks Rd./BO02-3490 Container: 40 mL VOA Vial Client: Bennett&O'Reilly,Inc. Preservation: HCI/Cool Laboratory ID: 69408-03 QC Batch►D: VG10=2042-W Sampled: 02-05-04 12:00 Instrument ID: GC-10 HP 6890 Received: 02-06-04 12:50 Sample Volume: 5 mL Analyzed: 02-17-04 14:36 Dilution Factor: 1 Analyst: PO at VPH''RangeS 1 :w ' ' Concentration r Nates 4§ P S ' a. Ortm n-05 ton-C8 Aliphatic Hydrocarbons to BRL ug/L 20 n-C9 to n-C12 Aliphatic Hydrocarbons to BRL ug/L 20 n-C9 to n-C10 Aromatic Hydrocarbons t 41 ug/L 20 Unadjusted n-05 to n-C8 Aliphatic Hydrocarbons t BRL ug/L 20 Unadiusted n-C9 to n-C12 Aliphatic Hydrocarbons t 35 ug/L 20 CASFNumbe Analyte s a, Conceitratton? .� Notes .s .> Units'r " TR portmgLrmrt; ; 1634-04-4 Methyl tert-butyl Ether° BRL ug/L 5 71-43-2 Benzene° BRL ug/L 1 108-88-3 Toluene° BRL ug/L 5 100-41-4 Eth lbenzene# BRL ug/L 5 108-38-3 and 10642-3 meta-Xylene and para-Xylenet BRL ug/L 5 95-47-6 ortho- X lene# BRL ug/L 5 91-20-3 Naphthalene BRL ug/L 5 ,Y; g QC Sut rogate Eompound2,4 , Spiked Measured Recouerys , C Ltmts , 2,5-Dibromotoluene(PID) 100 110 112 %� 70-130% 2,5-Dibromotoluene(FID) 100 120 119 % 70-130% ,�.��.�.�€-,-u-- ,..x•4 *z. c r fCO4 �1� . 1. Were all QA/QC procedures required by the method followed? Yes 2. Were all perormance/acceptance standards for the required QA/QC procedures achieved? Yes 3. Were any significant modifications made to the method,as specified in Section 11.3.2.1? No Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompanying signed project cover letter. The accompanying cover letter,project narrative and quality control report are considered part of this data report. Method Reference: Method for the Determination of Volatile Petroleum Hydrocarbons,MA DEP(1998). Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting in that range. 0 n-05 to n-C8 Aliphatic Hydrocarbons range data excludes the method target analyte concentrations. ® n-C9 to n-C12 Aliphatic Hydrocarbons range data excludes the method target analyte concentrations and the concentration for the n-C9 to n-C10 Aromatic Hydrocarbons range. u Analyte elutes in the n-05 to n-C8 Aliphatic Hydrocarbons range. # Analyte elutes in the n-C9 to n-C12 Aliphatic Hydrocarbons range. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 4 GROUNDWATER ANALYTICAL Massachusetts DEP VPH Method Volatile Petroleum Hydrocarbons by GC/PID/FID Field ID: MW-51) Matrix: Aqueous Project: Hubbard Oil/Brooks Rd./BO02-3490 Container: 40 mL VOA Vial Client: Bennett&O'Reilly,Inc. Preservation: HCI/Cool Laboratory ID: 69408-04 QC Batch ID: VG10-2042-W Sampled: 02-05-04 12:10 Instrument ID: GC-10 HP 6890 Received: 02-06-04 12:50 Sample Volume: 5 mL Analyzed: 02-17-04 15:16 Dilution Factor: i Analyst: PO VPH Ran e5' f COOCetttrattOlf,. Notes Units ReportmgLlmlt S. . . 2 1 n-05 to n-C8 Aliphatic Hydrocarbons to BRL ug/L 20 n-C9 to n-C12 Aliphatic Hydrocarbons to BRL ug/L 20 n-C9 to n-C10 Aromatic Hydrocarbons t BRL ug/L 20 Unadjusted n-05 to n-C8 Aliphatic Hydrocarbons t BRL ug/L 20 Unadjusted n-C9 to n-C12 Aliphatic Hydrocarbons t BRL ug/L 20 CAS Number° Analyte �Concentratioii: y , Notes��X-11 KIlyts Reporting Lrm�c ; 1634-04-4 Methyl tert-but I Ether BRL ug/L 5 71-43-2 Benzene° BRL ug/L 1 108-88-3 Toluene II BRL ug/L 5 100-41-4 Ethylbenzene 3 BRL - ug/L 5 108-38-3 and 10"2-3 meta-Xylene and para-Xylene# BRL ug/L 5 95-47-6 ortho- X lene t BRL. ug/L 5 91-20-3 Naphthalene BRL ug/L 5 QC Surrogate'Compound4 Sptked y Measuretl x Recovery, # QC Ltmts 2,5-Dibromotoluene(PID) 100 103 103 % 70-130% 2,5-Dibromotoluene(FID) 100 108 108 % 70-130% "3 Q-A% C Certtficatton a ,; a` Q,b, 1. Were all QA/QC procedures required by the method followed? Yes 2. Were all performance/acceptance standards for the required QA/QC procedures achieved? Yes 3. Were any significant modifications made to the method,as specified in Section 11.3.2.1? No Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompanying signed project cover letter. The accompanying cover letter,project narrative and quality control report are considered part of this data report. Method Reference: Method for the Determination of Volatile Petroleum Hydrocarbons,MA DEP(1998). Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting in that range. 0 n-05 to n-C8 Aliphatic Hydrocarbons range data excludes the method target analyte concentrations. ® n-C9 to n-C12 Aliphatic Hydrocarbons range data excludes the method target analyte concentrations and the concentration for the n-C9 to n-C10 Aromatic Hydrocarbons range. tt Analyte elutes in the n-05 to n-C8 Aliphatic Hydrocarbons range. t Analyte elutes in the n-C9 to n-C12 Aliphatic Hydrocarbons range. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Massachusetts DEP VPH Method Volatile Petroleum Hydrocarbons by GC/PID/FID Field ID: MW-6S Matrix: Aqueous Project: Hubbard Oil/Brooks Rd./BO02-3490 Container: 40 mL VOA Vial Client: Bennett&O'Reilly,Inc. Preservation: HCI/Cool Laboratory ID: 69408-05 QC Batch ID: VG10-2042-W Sampled: 02-05-04 13:00 Instrument ID: GC-10 HP 6890 Received: 02-06-04 12:50 Sample Volume: 5 mL Analyzed: 02-17-04 15:57 Dilution Factor: 1 Analyst: PO n-05 to n-C8 Aliphatic Hydrocarbons'0 BRL ug/L 20 n-C9 to n-C12 Aliphatic Hydrocarbons' ' BRL ug/L 20 n-C9 to n-C10 Aromatic Hydrocarbons' BRL ug/L 20 Unadjusted n-05 to n-C8 Aliphatic Hydrocarbons' BRL ug/L 20 Unadiusted n-C9 to n-C12 Aliphatic Hydrocarbons t BRL ug/L 20 1„ S N CAumber'. r Analyte _` Conce ttratIO Notes Untfs ` 1 Rep'`drt�ng limit ,g 1634-04-4 Methyl tert-butyl Ether° BRL ug/L 5 71-43-2 Benzene° BRL ug/L 1 108-88-3 I Toluene° BRL ug/L 5 100414 Eth (benzene# BRL ug/L 5 108-38-3 and 10642-3 meta-Xylene and para-Xylene BRL ug/L 5 95-47-6 ortho- Xylene$ BRL ug/L 5 91-20-3 Naphthalene BRL ug/L 5 6"L �,+'..+; QC C burro dtQ'COm OUTtda a $ t�C2da MEdSllred s RCOYe �� s 1 " LIitmMtSr 2,5-Dibromotoluene(PID) 100 93 93 % 70-130% 2,5-Dibromotoluene(FID) 100 102 102 % 70-130% f " x " QA/QCCerfrflcatton "� f... � .c. 1. Were all QA/QC procedures required by the method followed? Yes 2. Were all performance/acceptance standards for the required QA/QC procedures achieved? Yes 3. Were any significant modifications made to the method,as specified in Section 11.3.2.1? No Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompanying signed project cover letter. The accompanying cover letter,project narrative and quality control report are considered part of this data report. Method Reference: Method for the Determination of Volatile Petroleum Hydrocarbons,MA DEP(1998). Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting in that range. 0 n-05 to n-C8 Aliphatic Hydrocarbons range data excludes the method target analyte concentrations. ® n-C9 to n-C12 Aliphatic Hydrocarbons range data excludes the method target analyte concentrations and the concentration for the n-C9 to n-C10 Aromatic Hydrocarbons range. 11 Analyte elutes in the n-05 to n-C8 Aliphatic Hydrocarbons range. # Analyte elutes in the n-C9 to n-C12 Aliphatic Hydrocarbons range. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Massachusetts DEP VPH Method Volatile Petroleum Hydrocarbons by GC/PID/FID Field ID: MW-61) Matrix: Aqueous Project: Hubbard Oil/Brooks Rd,BO02-3490 Container: 40 mL VOA Vial Client: Bennett&O'Reilly,Inc. Preservation: HCI/Cool Laboratory ID: 69408-06 QC Batch ID: VG10-2042-W Sampled: 02-05-04 12:50 Instrument ID: GC-10 HP 6890 Received: 02-06-04 12:50 Sample Volume: 5 mL Analyzed: 02-17-04 16:37 Dilution Factor: 1 Analyst: PO ,�=<_ COOCeIttr�atio tea. n-05 to n-C8 Aliphatic Hydrocarbons t 0 BRL ug/L� 20 n-C9 to n-C12 Aliphatic Hydrocarbons to BRL ug/L 20 n-C9 to n-Cl0 Aromatic Hydrocarbons t BRL ug/L 20 Unadjusted n-05 to n-C8 Aliphatic Hydrocarbons t BRL ug/L 20 Unadjusted n-,--9 to n-C12 Aliphatic Hydrocarbons t BRL ug/L 20 ACAS Number >`Anal.�,}a q'°' ` Goncenfratlon 4 Nates t tJnlfs a Reporting Llm t 1634-04-4 Methyl tert-butyl Ether" BRL ug/L 5 7143-2 Benzene" BRL ug/L 1 108-88-3 Toluene " BRL ug/L 5 100-41-4 Ethylbenzene t BRL ug/L 5 108-38-3 and 10"2-3 meta-Xylene and para-Xylene$ BRL ug/L 5 95-47-6 ortho- X lene t BRL ug/L 5 91-20-3 Naphthalene BRL ug/L 5 QC Surrogate.Compound m Spiked Measured% Recovery QC Ltrri`ts : 2,5-Dibromotoluene(PID) 100 �103 103 % 70-130�% 2,5-Dibromotoluene(FID) 100 109 109 % 70-130% 1. Were all QA/QC procedures required by the method followed? Yes 2. Were all performancelacceptance standards for the required QA/QC procedures achieved? Yes 3. Were any significant modifications made to the method,as specified in Section 11.3.2.1? No Method non-con:'ormances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompanying signed project cover letter. The accompanying cover letter,project narrative and quality control report are considered part of this data report. Method Reference- Method for the Determination of Volatile Petroleum Hydrocarbons,MA DEP(1998). Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting in that range. 0 n-05 to n-C8 Aliphatic Hydrocarbons range data excludes the method target analyte concentrations. ® n-C9 to n-C12 Aliphatic Hydrocarbons range data excludes the method target analyte concentrations and the concentration for the n-C9 to n-C10 Aromatic Hydrocarbons range. tt Analyte elutes in the n-05 to n-C8 Aliphatic Hydrocarbons range. t Analyte elutes in the n-C9 to n-C12 Aliphatic Hydrocarbons range. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Massachusetts DEP VPH Method Volatile Petroleum Hydrocarbons by GC/PID/FID Field ID: MW-1 Matrix: Aqueous Project: Hubbard Oil/Brooks Rd./BO02-3490 Container: 40 mL VOA Vial Client: Bennett&O'Reilly,Inc. Preservation: HCl/Cool Laboratory ID: 69408-07 QC Batch ID: VG10-2042-W Sampled: 02-05-04 14:45 Instrument ID: GC-10 HP 6890 Received: 02-06-04 12:50 Sample Volume: 5 mL Analyzed: 02-17-04 17:18 Dilution Factor: 1 Analyst: PO VPFI RdngQ;` .. = �F� � _ �-` ;?' „.�. COr1CelttratlOin;� �� NOteS�,�,' UnItS�• -��Reporting L�mrt n-05 to n-C8 Ali hatic Hydrocarbons 10 BRL ug/L 20 n-C9 to n-C12 Aliphatic Hydrocarbons to BRL ug/L 20 n-C9 to n-C10 Aromatic Hydrocarbons t BRL ug/L 20 Unadjusted n-05 to n-C8 Aliphatic Hydrocarbons t BRL ug/L 20 Unadiusted n-C9 to n-C12 Aliphatic Hydrocarbons t BRL ug/L 20 CAS Number Ana( e ��-�r ConcenX Jq _ „Notes "� _ fUnifs Repor[ngL, � 1634-04-4 Methyl tert-but I Ether BRL ug/L 5 71-43-2 Benzene a BRL ug/L 1 108-88-3 Toluene° BRL ug/L 5 100-41-4 Eth (benzene# BRL ug/L 5 10&-38-3 and 10642-3 meta-Xylene and para-X lene# - -BRL ug/L 5 95-47-6 ortho- Xylene$ BRL ug/L 5 91-20-3 Naphthalene BRL ug/L 5 r QCrS`urxogateCompound `Spiked .Measured Recovery , ,QC�Llmrts _ 2,5-Dibromotoluene(PID) 100 101 101 % 70-130% 2,5-Dibromotoluene(FID) 100 110 110 % 70-130% k " A C�CeilflCdtlOn 'd� �t'"k ,.�}Y,a ra Q Q ,I.r'1111t4. ; _ ..-,- 1. Were all QPJQC procedures required by the method followed? Yes 2. Were all performancelacceptance standards fo-the required QA/QC procedures achieved? Yes 3. Were any significant modifications made to the method,as specified in Section 11.3.2.1? No Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompanying signed project cover letter. The accompanying cover letter,project narrative and quality control report are considered part of this data report. Method Reference: Method for the Determination of Volatile Petroleum Hydrocarbons,MA DEP(1998). Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting in that range. 0 n-05 to n-C8 Aliphatic Hydrocarbons range data excludes the method target analyte concentrations. ® n-C9 to n-C12 Aliphatic Hydrocarbons range data excludes the method target analyte concentrations and the concentration for the n-C9 to n-C10 Aromatic Hydrocarbons range. tt Analyte elutes in the i-05 to n-C8 Aliphatic Hydrocarbons range. t Analyte elutes in the n-0 to n-Cl2 Aliphatic Hydrocarbons range. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Massachusetts DEP VPH Method Volatile Petroleum Hydrocarbons by GC/PID/FID Field ID: MW-2 Matrix: Aqueous Project: Hubbard Oil/Brooks Rd.1BO02-3490 Container: 40 mL VOA Vial Client: Bennett&O'Reilly,Inc. Preservation: HCI/Cool Laboratory ID: 69408-08 QC Batch ID: VG10-2042-W Sampled: 02-05-04 14:45 Instrument ID: GC-10 HP 6890 Received: 02-06-04 12:50 Sample Volume: 5 mL Analyzed: 02-17-04 19:19 Dilution Factor: 2 Analyst: PO VP( Rdngec= _ COIICEntrdtlOYN GNOteSs �Umfs RePortingimt ` ... -. .—.. - n-05 to n-C8 Aliphatic Hydrocarbons t0 � BRL ug/L� �40 n-C9 to n-C12 Aliphatic H ydrocarbons t® BRL ug/L 40 n-C9 to n-C10 Aromatic Hydrocarbons t 43 ug/L 40 Unadjusted n-05 to n-C8 Aliphatic Hydrocarbons t BRL ug/L Z---d Unadjusted n-C9 to n-C12 Aliphatic H drocarbons t BRL ug/L t)nitS': Reort�n Lrmit CAS:'Number. Analyte .„ r r Concentration,; a..k.. Nofgs � � , ,gyp g,o� 1634-04-4 Methyl tert-but I Ether" BRL ug/L 10 71-43-2 Benzene° BRL ug/L 2 108-88-3 Toluene° BRL ug/L 10 100414 Eth (benzene; BRL ug/L 10 108-3a-3 and 10642-3 meta-X lene and para-X lene$ BRL ug/L 10 _ 9547-6 ortho- X lene; BRL ug/L 10 91-20-3 Naphthalene BRL ug/L 10 S ked Measured Reco�e t & QG Limits m. 2,5-Dibromotoluene(PID) 100 104 104 % 70-130% 2,5-Dibromotoluene(FID) 100 107 107 % 70-130% 4 v s z an r r 1. Were all QA/QC procedures required by the method followed? Yes 2. Were all performancelacceptance standards for the required QA/QC procedures achieved? Yes 3. Were any significant modifications made to the imethod,as specified in Section 11.3.2.1? No Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompanying signed project cover letter. The accompanying cover letter,project narrative and quality control report are considered part of this data report. Method Reference: Method for the Determination of Volatile Petroleum Hydrocarbons,MA DEP(1998). Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting in that range. 0 n-05 to n-C8 Aliphatic Hydrocarbons range data excludes the method target analyte concentrations. ® n-C9 to n-C12 Aliphatic Hydrocarbons range data excludes the method target analyte concentrations and the concentration for the n-C9 to n-C10 Aromatic Hydrocarbons range. tt Analyte elutes in the n-05 to n-C8 Aliphatic Hydrocarbons range. # Analyte elutes in the n-C9 to n-C12 Aliphatic Hydrocarbons range. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Massachusetts DEP VPH Method Volatile Petroleum Hydrocarbons by GC/PID/FID Field ID: MW-4 Matrix: Aqueous Project: Hubbard Oil/Brooks Rd./BO02-3490 Container: 40 mL VOA Vial Client: Bennett&O'Reilly,Inc. Preservation: HCI/Cool Laboratory ID: 69408-09 QC Batch ID: VG10-2042-W Sampled: 02-05-04 15:20 Instrument ID: GC-10 HP 6890 Received: 02-06-04 12:50 Sample Volume: 5 mL Analyzed: 02-17-04 21:20 Dilution Factor: 1 Analyst: PO ntrat,on;' <�¢ t' N'O_tQSa,'; .,.. VI1ItS ?WRepoRirtgl.�mt "±. n-05 to n-C8 Aliphatic Hydrocarbons to BRL ug/L 20 n-C9 to n-C12 Aliphatic Hydrocarbons to BRL ug/L 20 n-C9 to n-C10 Aromatic Hydrocarbons' 23 ug/L 20 Unadiusted n-05 to n-C8 Aliphatic Hydrocarbons t BRL ug/L 20 Unadjusted n-C9 to n-C12 Aliphatic Hydrocarbons t 25 ug/L 20 CASNumber, Anal. e� 4 £ r Coneenir ttoriT Notes ' Umts` ` Reporting L1m� '' 2 Yt '. 3. , 163"44 Methyl tert-butyl Ether" BRL ug/L 5 7143-2 Benzene ° BRL ug/L 1 108-88-3 Toluene rt BRL ug/L 5 10041-4 Ethylbenzene$ BRL ug/L 5 108-38-3 and 10rr42-3 meta-Xylene and para-Xylenet BRL ug/L 5 95-47-6 ortho- X lene$ BRL ug/L 1 5 91-20-3 Naphthalene BRL ug/L 5 CCSurro ate"Coin oindAl " M#"PS (kedMeasured �Recoue „ � ; jCLimrts ' 2,5-Dibromotoluene(PID) 100 104 104 % 70-130% 2,5-Dibromo'.oluene(FID) 100 107 107 % 70-130 QA/Q�C Certtftcatton x.t { 1. Were all QPJQC procedures required by the method followed? Yes 2. Were all performance/acceptance standards for the required QA/QC procedures achieved? Yes 3. Were any significant modifications made to the method,as specified in Section 11.3.2.1? No Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompanying signed project cover letter. The accompanying cover letter,project narrative and quality control report are considered part of this data report. Method Reference: Method for the Determination of Volatile Petroleum Hydrocarbons,MA DEP(1998). Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting in that range. 0 n-05 to n-C8 Aliphatic Hydrocarbons range data excludes the method target analyte concentrations. ® n-C9 to n-C12 Aliphatic Hydrocarbons range data excludes the method target analyte concentrations and the concentration for the n-C9 to n-C10 Aromatic Hydrocarbons range. tt Analyte elutes in the n-05 to n-C8 Aliphatic Hydrocarbons range. t Analyte elutes in the n-C9 to n-C12 Aliphatic Hydrocarbons range. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Massachusetts DEP VPH Method Volatile Petroleum Hydrocarbons by GGPI DNI D Field ID: SEA-1 Matrix: Aqueous Project: Hubbard Oil/Brooks Rd./0002-3490 Container: 40 mL VOA Vial Client: Bennett&O'Reilly,Inc. Preservation: HCI/Cool Laboratory ID: 69408-10 QC Batch ID: VG10-2042-W Sampled: 02-05-04 15:50 Instrument ID: GC-10 HP 6890 Received: 02-06-04 12:50 Sample Volume: 5 mL Analyzed: 02-17-04 22:00 Dilution Factor: 2 Analyst: PO _, VPH Ranges_? may:`_ i ,• . -=__COnCentrdtlon:'' otes ''UnttS' eportmgUmxf - t ,. �, . s__ � .. , �M .-: r - - - n-05 to n-C8 Aliphatic Hydrocarbons to 850 ug/L, 40 n-C9 to n-C12 Aliphatic Hydrocarbons to 2,300 ug/L 40 n-C9 to n-C10 Aromatic Hydrocarbons t 6,600 ug/L 40 Unadiusted n-05 to n-C8 Ali hatic H drocarbons t 1,500 ug/L 40 Unadiusted n-C9 to n-C12 Aliphatic Hydrocarbons t 12,000 ug/L 40 ._t•. 3.: °. r` R br[m�lamif�` { CAS;Nurnber Analyte _ Concentration - Notes Units ep g 1634-04-4 Methyl tert-but I Ether BRL ug/L 10 71-43-2 Benzene" 9 ug/L 2 108-88-3 Toluene A 620 ug/L 10 100-41-4 Eth (benzene t 470 ug/L 10 108-38-3 and 10642-3 meta-Xylene and pars-Xylene$ 1,800 ug/L 10 9547-6 ortho- X lene; 930 ug/L 10 `91-20-3 Naphthalene 280 ug/L 10 ,wa.s i,aaa QCS,urrog'ate Compounds Spiked Measured Recouery s�e' r ; t� rt QC Limits W 2,5-Dibromotoluene(PID) 100 110 111 % 70-130% 2,5-Dibromotoluene(FID) 100 120 118 % 70-130% j- ' QA`1QC Certification 1. Were all QA/QC procedures required by the method followed? Yes 2. Were all perormance/acceptance standards for the required QA/QC procedures achieved? Yes 3. Were any significant modifications made to the method,as specified in Section 11.3.2.1? No Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompanying signed project cover letter. The accompanying cover letter,project narrative and quality control report are considered part of this data report. Method Reference: Method for the Determination of Volatile Petroleum Hydrocarbons,MA DEP(1998). Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting in that range. 0 n-05 to n-C8 Aliphatic Hydrocarbons range data excludes the method target analyte concentrations. ® n-C9 to n-Cl2 Aliphatic Hydrocarbons range data excludes the method target analyte concentrations and the concentration for the n-C9 to n-C10 Aromatic Hydrocarbons range. u Analyte elutes in the n-05 to n-C8 Aliphatic Hydrocarbons range- t Analyte elutes in the n-C9 to n-Cl2 Aliphatic Hydrocarbons range. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Massachusetts DEP VPH Method Volatile Petroleum Hydrocarbons by GC/PID/FID Field ID: SEA-2 Matrix: Aqueous Project: Hubbard Oil/Brooks Rd./BO02-3490 Container: 40 mL VOA Vial Client: Bennett&O'Reilly,Inc. Preservation: HCI/Cool Laboratory ID: 69408-11 QC Batch ID: VG10-2042-W Sampled: 02-05-04 15:30 Instrument ID: GC-10 HP 6890 Received: 02-06-04 12:50 Sample Volume: 5 mL Analyzed: 02-17-04 22:40 Dilution Factor: 1 Analyst: PO uPH`Ranges <, e, KConcentrattonmYw KOteSUnits gaReportinSUm1t a n-05 to n-C8 Aliphatic Hydrocarbons 4 0 34 ug/L 20 n-C9 to n-C12 Aliphatic Hydrocarbons t® 500 ug/L 20 n-C9 to n-C10 Aromatic Hydrocarbons t 770 ug/L 20 Unadjusted n-05 to n-C8 Aliphatic Hydrocarbons t 34 ug/L 20 Unadjusted n-C9 to n-C12 Aliphatic Hydrocarbons t 1,300 ug/L 20 GAS;Number Analyte �; h ,, 1ST 4, ncentratton `�` Notes Units' Reportmg t lmtt, x=' 1634-04-4 Methyl tert-but I Ether° BRL ug/L 5 71-43-2 Benzene" BRL ug/L 1 108-88-3 Toluene n BRL ug/L 5 100-41-4 Eth (benzene' BRL ug/L 5 108-38-3 and 10&42-3 meta-Xylene and para-Xylene t - BRL ug/L 5 95-47-6 ortho- X lene$ BRL ug/L 5 91-20-3 Naphthalene 13 ug/L 5 QC Surrogate Compoundx� ' ti r Sptked Measured ` A Recovery ® 'i.. 2,5-Dibromotoluene(PID) 100 110 114 % 70-130 2,5-Dibromotoluene(FID) 100 95 95 % 70-130 ... e�"' ,tza A( G Certiflcatton k "' 1. Were all QA/QC procedures required by the method followed? Yes 2. Were all performance/acceptance standards for the required QA/QC procedures achieved? Yes 3. Were any significant modifications made to the method,as specified in Section 11.3.2.1? No Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompanying signed project cover letter. The accompanying cover letter,project narrative and quality control report are considered part of this data report. Method Reference: Method for the Determination of Volatile Petroleum Hydrocarbons,MA DEP(1998). Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting in that range. 0 n-05 to n-C8 Aliphatic(Hydrocarbons range data excludes the method target analyte concentrations. ® n-C9 to n-C12 Aliphatic Hydrocarbons range data excludes the method target analyte concentrations and the concentration for the n-C9 to n-C10 Aromatic Hydrocarbons range. u Analyte elutes in the n-05 to n-C8 Aliphatic Hydrocarbons range. # Analyte elutes in the n-C9 to n-C12 Aliphatic Hydrocarbons range. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Massachusetts DEP EPH Method Extractable Petroleum Hydrocarbons by GUI D Field ID: GZA-1 Matrix: Aqueous Project: Hubbard Oil/Brooks Rd./BO02-3490 Container: 1 L Amber Glass Client: Bennett&O'Reilly,Inc. Preservation: H2SO4/Cool Laboratory ID: 69408-12 QC Batch ID: EP-1326-F Sampled: 02-05-04 13:30 Instrument ID: GC-7 HP 5890 Received: 02-06-04 12:50 Sample Volume: 1,000 mL Extracted: 02-09-04 18:30 Final Volume: 1 mL Analyzed(AL:I: 02-18-04 03:22 Aliphatic Dilution Factor: 1 Analyzed(AR): 02-18-04 04:05 Aromatic Dilution Factor: 1 Analyst: WN EPH Rdnges: +°L .'': �COf1'GCntrdtlOtl `Notes" 'Units jRepoittmgLimit n-C9 to n-CI3 Aliphatic Hydrocarbons+ BRL ug/L 500 n-C19 to n-C36 Aliphatic Hydrocarbons t BRL ug/L 500 n-C11 to n-C22 Aromatic Hydrocarbons t° 160 ug/L 160 Unadjusted r-Cl1 to n-C22 Aromatic Hydrocarbons t 170 ug/L 160 r . a ?QC Llmlts3 a: QC Surrogatz.Compound `�� r -, Sprked Measured Recovery ;�,� "� �mx. Fractionation: 2-Fluorobiphenyl 40 34 85 % 40-140% 2-Bromonaphthalene 40 34 86 % 40-140% Extraction: Chloro-octadecane 40 22 55 % 40-140% - ortho-Terphenyl 40 31 78 % 40-140% # Xa4 d r3 —A 1. Were all QA/QC procedures required by the method followed? Yes 2. Were all performancelacceptance standards for the required QA/QC procedures achieved? Yes 3. Were any s gnificant modifications made to the method,as specified in Section 11.3? No Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompanying signed project cover letter. The accompanying cover letter,project narrative and quality control report are considered part of this data report. Method Refererce: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998). Sample extraction performed by separatory funnel technique. Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting in that range. 0 n-C1 i to n-C22 Aromatic Hydrocarbons range data excludes the method target analyte concentrations. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL EPA Method 8270C(Modified) MA DEP EPH Polynuclear Aromatic Hydrocarbons by GC/MS-SIM Field ID: GZA-1 Matrix: Aqueous Project: Hubbard Oil/Brooks Rd./BO02-3490 Container: 1 L Amber Glass Client: Bennett&O'Reilly,Inc. Preservation: H2SO4/Cool Laboratory ID: 69408-12 QC Batch ID: EP-1326-F Sampled: 02-05-04 13:30 Instrument ID: MS-6 HP 6890 Received: 02-06-04 12:50 Sample Volume: 1,000 mL Extracted: 02-09-04 18:30 Final Volume: 1 mL Analyzed: 02-18-04 11:49 Dilution Factor: 1 Analyst: JJT CASAfldl e i �a '� ti }' COflC2ntrdtlOrt ¢fin t ',� Notes ,' UflItS_� por[in 91-20-3 Naphthalene BRL ug/L 0.5 91-57-6 2-Methyl naphthalene BRL ug/L 0.5 208-96-8 Acenaphthylene BRL ug/L 0.5 83-32-9 Acenaphthene BRL ug/L 0.5 86-73-7 Fluorene BRL ug/L 0.5 85-01-8 Phenanthrene 0.8 ug/L 0.5 120-12-7 Anthracene BRL ug/L 0.5 20644-0 Fluoranthene 2.2 ug/L 0.5 129-00-0 Pyrene 1.4 ug/L 0.5 56-55-3 Benzo[a]anthracene 0.5 ug/L 0.1 218-01-9 Chrysene 1.1 ug/L 0.1 205-99-2 Benzo[b]fluoranthene 1.2 ug/L 0.1 207-08-9 Benzo[k]fluoranthene 0.9 ug/L 0.1 50-32-8 Benzo[a]pyrene 0.9 ug/L 0.1 193-39-5 Indeno[1,2,3-c,d]pyrene 1.0 1 ug/L 0.1 53-70-3 Dibenzo[a,h]anthracene 0.2 ug/L 0.1 191-24-2 Benzo[g,h,i]perylene 1.1 ug/L 0.1 QCSurrogate Compound r<� n „F Spiked Measured„ Recovery ; QC Ltmltsa y ortho-Terpher.yl 40 30 76 % 40-140% Method Reference: Test Methods for Evaluating Solid Waste,US EPA,SW-846,Third Edition,Update III(1996). Method modified by use of selected ion monitoring(SIM)in accordance with Section 7.5.5 of the method. Method protocol modified to include acidification and the surrogate compound in accordance with the MA DEP Method for the Determination of Extractable Petroleum Hydrocarbons. Sample extraction performed by EPA Method 3510C. Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Massachusetts DEP EPH Method Extractable Petroleum Hydrocarbons by GGFID Field ID: GZA-2 Matrix: Aqueous Project: Hubbard Oil/Brooks Rd./13002-3490 Container: 1 L Amber Glass Client: Bennett&O'Reilly,Inc. Preservation: H2SO4/Cool Laboratory ID: 69408-13 QC Batch ID: EP-1326-F Sampled: 02-05-04 13:30 Instrument ID: GC-7 HP 5890 Received: 02-06-04 12:50 Sample Volume: 1,000 mL Extracted: 02-09-04 18:30 Final Volume: 1 mL Analyzed(AL): 02-18-04 04:49 Aliphatic Dilution Factor: 1 Analyzed(AR": 02-18-04 05:32 Aromatic Dilution Factor: 1 Analyst: WN EPH Ran e� Concentratton Notes Units Reporting limit_ �eWs.�.��. �...a n-C9 to n-C18 Aliphatic Hydrocarbons t � BRL ug/L 500 n-C19 to n-C36 Aliphatic Hydrocarbons t BRL ug/L 500 n-C11 to n-C22 Aromatic Hydrocarbons t o BRL ug/L 160 Unadjusted n-C11 to n-C22 Aromatic Hydrocarbons t 170 ug/L 160 QC Surrogate Compound S tked Measured ,Recovery .,; 0Ltmtts Fractionatior: 2-Fluorobiphenyl 40 35 88 % 40-140% 2-Bromonaphthalene 40 36 89 % 40-140% Extraction: Chloro-octadecane 40 21 51 % 40-140% ortho-Terphenyl 40 32 80 % 40-140% QA/.QG Cert�ficatton" - r k 1. Were all QA/QC procedures required by the method followed? Yes 2. Were all performance/acceptance standards for the required QA/QC procedures achieved? Yes 3. Were any significant modifications made to the method,as specified in Section 11.3? No Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompanying signed project cover letter. The accompanying cover letter,project narrative and quality control report are considered part of this data report. Method Reference: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998). Sample extraction performed by separatory funnel technique. Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting in that range. 0 n-C11 to n-C22 Aromatic Hydrocarbons range data excludes the method target analyte concentrations. Groundwater Analytical, Inc., P.O. Box 1200,228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL l EPA Method 8270C(Modified) MA DEP EPH Polynuclear Aromatic Hydrocarbons by GUMS-SIM Field ID: GZA-2 Matrix: Aqueous Project: Hubbard Oil/Brooks Rd.'8002-3490 Container: 1 L Amber Glass Client: Bennett&O'Reilly,Inc. Preservation: H2SO4/Cool Laboratory ID: 69408-13 QC Batch ID: EP-1326-F Sampled: 02-05-04 13:30 Instrument ID: MS-6 HP 6890 Received: 02-06-04 12:50 Sample Volume: 1,000 mL Extracted: 02-09-04 18:30 Final Volume: 1 mL Analyzed: 02-18-04 12:27 Dilution Factor: 1 Analyst: JJT CAS Number' Analyte } Concentration r Notes _ L)nttsReport�g�me ; 91-20-3 Naphthalene BRL ug/L 0.5 91-57-6 2-Methyl naphthalene BRL ug/L 0.5 208-96-8 Acenaphthylene BRL ug/L 0.5 83-32-9 Acenaphthene BRL ug/L 0.5 86-73-7 Fluorene BRL ug/L 0.5 85-01-8 Phenanthrene 0.9 ug/L 0.5 120-12-7 Anthracene BRL ug/L 0.5 20644-0 Fluoranthene 2.2 ug/L 0.5 129-00-0 Pyrene 1.4 ug/L 0.5 56-55-3 Benzo[a]anthracene 0.6 ug/L 0.1 218-01-9 Chrysene 1.0 ug/L 0.1 205-99-2 Benzo[b]fluoranthene 1.0 ug/L 0.1 207-08-9 Benzo[klfluoranthene 0.8 ug/L 0.1 50-32-8 Benzo[a]pyrene 0.8 ug/L 0.1 193-39-5 Indeno[1,2,3-c,d]pyrene 0.8 ug/L 0.1 53-70-3 Dibenzo[a,hJanthracene 0.2 ug/L 0.1 191-24-2 Benzo[g,h,i]perylene 0.8 ug/L 0.1 QC Surrogate Compound S'iked v Measured Recove QC Limits r ` ortho-Terphenyl 1 40 32 81 % 40-140% Method Reference: Test Methods for Evaluating Solid Waste,US EPA,SW-846,Third Edition,Update III(1996). Method modified by use of selected ion monitoring(SIM)in accordance with Section 7.5.5 of the method. Method protocol modified to include acidification and the surrogate compound in accordance with the MA DEP Method for the Determination of Extractable Petroleum Hydrocarbons. Sample extraction performed by EPA Method 3510C. Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Massachusetts DEP EPH Method Extractable Petroleum Hydrocarbons by GGFID Field ID: MW-5s Matrix: Aqueous Project: Hubbard Oil/Brooks Rd./0002-3490 Container: 1 L Amber Glass Client: Bennett&O'Reilly,Inc. Preservation: H2SO4/Cool Laboratory ID: 69408-14 QC Batch ID: EP-1326-F Sampled: 02-05-04 12:00 Instrument ID: GC-7 HP 5890 Received: 02-06-04 12:50 Sample Volume: 1,000 ml. Extracted: 02-09-04 18:30 Final Volume: 1 mL Analyzed(AL): 02-18-04 06:15 Aliphatic Dilution Factor: 1 Analyzed(AR::: 02-18-04 06:59 Aromatic Dilution Factor: 1 Analyst: WN RePo�tmg��m�t� ° n-C9 to in-C18 Aliphatic Hydrocarbons t BRL ug/L 500 n-Cl9 to n-C36 Aliphatic Hydrocarbons t BRL ug/L 500 n-C11 to n-C22 Aromatic H drocarbons t° BRL ug/L 160 Unadiusted n-C11 to n-C22 Aromatic Hydrocarbons t BRL ug/L 160 pQC SurrogatCampound G a na Spiked Measured GRecovery fir . C?Ltmts Fractionation: 2-Fluorobiphenyl 40 33 82 % 40-140% 2-13romonaphthalene 40 35 87 % 40-140% Extraction: Chloro-octadecane 40 21 53 % 40-140 ortho-Terphenyl 40 30 75 % 40-140 1. Were all QPIQC procedures required by the method followed? Yes 2. Were all performance/acceptance standards for the required QA/QC procedures achieved? Yes 3. Were any significant modifications made to the method,as specified in Section 11.3? No Method nonco.iformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompanying signed project cover letter. The accompanying cover letter,project narrative and quality control report are considered part of this data report. Method Reference: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998). Sample extraction performed by separatory funnel technique. Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting in that range. 0 n-C71 to n-C22 Aromatic Hydrocarbons range data excludes the method target analyte concentrations. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL EPA Method 8270C(Modified) MA DEP EPH Polynuclear Aromatic Hydrocarbons by GUMS-SIM Field ID: MW-5S Matrix: Aqueous Project: Hubbard Oil/Brooks Rd./BO02-3490 Container: 1 L Amber Glass Client: Bennett&O'Reilly,Inc. Preservation: H2SO4/Cool Laboratory ID: 69408-14 QC Batch ID: EP-1326-F Sampled: 02-05-04 12:00 Instrument ID: MS-6 HP 6890 Received: 02-06-04 12:50 Sample Volume: 1,000 mL Extracted: 02-09-04 18:30 Final Volume: 1 mL Analyzed: 02-18-04 13:06 Dilution Factor: 1 Analyst: JJT RII Eimd 91-20-3 Naphthalene BRL ug/L 0.5 91-57-6 2-Methyl naphthalene BRL ug/L 0.5 208-96-8 Acenaphthylene BRL ug/L 0.5 83-32-9 Acenaphthene BRL ug/L 0.5 86-73-7 Fluorene BRL ug/L 0.5 85-01-8 Phenanthrene BRL ug/L 0.5 120-12-7 Anthracene BRL ug/L 0.5 206-44-0 Fluoranthene BRL ug/L 0.5 129-00-0 Pyrene BRL ug/L 0.5 56-55-3 Benzo[a]anthracene BRL ug/L 0.1 218-01-9 Chrysene BRL ug/L 0.1 205-99-2 Benzo[b]fluoranthene BRL ug/L 0.1 207-08-9 Benzo[k]fluoranthene BRL ug/L 0.1 50-32-8 Benzo[a]pyrene BRL ug/L 0.1 193-39-5 Indeno[1,2,3-c,d]pyrene BRL ug/L 0.1 53-70-3 Dibenzo[a,h]anthracene BRL ug/L 0.1 191-24-2 Benzo[g,h,i]perylene BRL ug/L 0.1 'C Strro ateCom oytd Sxilted 'Measured �Recove t rn ortho-Terphenyl 40 31 77 % 40-140% Method Reference: Test Methods for Evaluating Solid Waste,US EPA,SW-846,Third Edition,Update III(1996). Method modified by use of selected ion monitoring(SIM)in accordance with Section 7.5.5 of the method. Method protocol modified to include acidification and the surrogate compound in accordance with the MA DEP Method for the Determination of Extractable Petroleum Hydrocarbons. Sample extraction performed by EPA Method 3510C. Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER j ANALYTICAL Massachusetts DEP EPH Method Extractable Petroleum Hydrocarbons by GGFID Field ID: MW-51) Matrix: Aqueous Project: Hubbard Oil/Brooks Rd./BO02-3490 Container: 1 L Amber Glass Client: Bennett&O'Reilly,Inc. Preservation: H2SO4/Cool Laboratory ID: 69408-15 QC Batch ID: EP-1326-F Sampled: 02-05-04 12:10 Instrument ID: GC-7 HP 5890 Received: 02-06-04 12:50 Sample Volume: 1,000 mL Extracted: 02-09-04 18:30 Final Volume: 1 mL Analyzed(AL): 02-18-04 07:42 Aliphatic Dilution Factor: 1 Analyzed(AR): 02-18-04 08:25 Aromatic Dilution Factor: 1 Analyst: WN anges, �,,.n <, _ ,,,. ,. Concentration + .. 3a�'NOteS �, UnrtS Re ortm Limit`,„: n-C9 to n-C18 Aliphatic Hydrocarbons t BRL ug/L 500 n-CI9 to n-C36 Aliphatic Hydrocarbons t BRL ug/L 500 n-Cl1 to n-C22 Aromatic Hydrocarbons t° BRL ug/L 160 Unadjusted n-C11 to n-C22 Aromatic Hydrocarbons t BRL ug/L 160 Y � QC Surrogate Compound " ,wSpked Measured xRecoveryq .,z, QCsLimrts Fractionation: 2-Fluorobiphenyl 40 28 69 % 40-140% 2-Bromonaphthalene 40 28 71 % 40-140% Extraction: Chloro-octadecane 40 19 47 % 40-140% ortho-Terphenyl 40 25 1 62 % 40-140% K .' 3 r t ? iWn ` .QA/QCCeYfifrcatton. Gd :> a .�z 1. Were all QA/QC procedures required by the method followed? Yes 2.:Were,all performancelacceptance standards for the required QA/QC procedures achieved? Yes 3. Were any significant modifications made to the method,as specified in Section 11.3? No Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompanying signed project cover letter. The accompanying cover letter,project narrative and quality control report are considered part of this data report. Method Reference: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998). Sample extraction performed by separatory funnel technique. Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting in that range. 0 n-C11 to n-C22 Aromatic Hydrocarbons range data excludes the method target analyte concentrations. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL EPA Method 8270C (Modified) MA DEP EPH Polynuclear Aromatic Hydrocarbons by GC/MS-SIM Field ID: MW-5D Matrix: Aqueous Project: Hubbard Oil/Brooks Rd./BO02-3490 Container: 1 L Amber Glass Client: Bennett&O'Reilly,Inc. Preservation: H2SO4/Cool Laboratory ID: 69408-15 QC Batch ID: EP-1326-F Sampled: 02-05-04 12:10 Instrument ID: MS-6 HP 6890 Received: 02-06-04 12:50 Sample Volume: 1,000 mL Extracted: 02-09-04 18:30 Final Volume: 1 mL Analyzed: 02-18-04 13:44 Dilution Factor: 1 Analyst: JJT ACAS Number> 'Analyte �? Concentrafion s WOW �UntfS61 Reportmg umrt 91-20-3 Naphthalene BRL ug/L 0.5 91-57-6 2-Methyl naphthalene BRL ug/L 0.5 208-96-8 Acenaphthylene BRL ug/L 0.5 83-32-9 Acenaphthene BRL ug/L 0.5 86-73-7 Fluorene BRL ug/L 0.5 85-01-8 Phenanthrene 0.6 ug/L 0.5 120-12-7 Anthracene BRL ug/L 0.5 20644-0 Fluoranthene 1.4 ug/L 0.5 129-00-0 Pyrene 0.9 ug/L 0.5 56-55-3 Benzo[a]anthracene 0.3 ug/L 0.1 218-01-9 Chrysene 0.6 ug/L 0.1 205-99-2 Benzo[b]fluoranthene 0.6 ug/L 0.1 207-08-9 Benzo[k]fluoranthene 0.4 ug/L 0.1 50-32-8 Benzo[a]pyrene 0.4 ug/L 0.1 193-39-5 Indeno[1,2,3-c,d]pyrene 0.4 ug/L 0.1 53-70-3 Dibenzo[a,h]anthracene 0.1 ug/L 0.1 191-24-2 Benzo[g,h,i]perylene 0.5 ug/L 0.1 �, .,s _ ..+.ems r�., 'ka' .a3•, �''(;,G^`;irva*�t „.yn, e`"rn�' ;YQa"'tr"' .. QCiS`urcogate Compound .,� r Sptked Measured „ Recovery C+Ltmlts 1 ortho-Terphenyl 40 26 65 % 40-140% Method Reference: Test Methods for Evaluating Solid Waste,US EPA,SW-846,Third Edition,Update III(1996). Method modified by use of selected ion monitoring(SIM)in accordance with Section 7.5.5 of the method. Method protocol modified to include acidification and the surrogate compound in accordance with the MA DEP Method for the Determination of Extractable Petroleum Hydrocarbons. Sample extraction performed by EPA Method 3510C. Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Massachusetts DEP EPH Method Extractable Petroleum Hydrocarbons by GGFID Field ID: MW-6S Matrix: Aqueous Project: Hubbard Oil/Brooks Rd./BO02-3490 Container: 1 L Amber Glass Client: Bennett&O'Reilly,Inc. Preservation: H2SO4/Cool Laboratory ID: 69408-16 QC Batch ID: EP-1326-F Sampled: 02-05-04 13:00 Instrument ID: GC-7 HP 5890 Received: 02-06-04 12:50 Sample Volume: 1,000 mL Extracted: 02-09-04 18:30 Final Volume: 1 mL Analyzed(AL): 02-17-04 19:31 Aliphatic Dilution Factor: 1 Analyzed(AR): 02-17-04 20:10 Aromatic Dilution Factor: 1 Analyst: WN w , EPH'Ranges a� � Co�ncentratioq Notes Untts Repgrtmgt�m�c n-C9 to n-C18 Aliphatic Hydrocarbons t BRL ug/L 500 n-C19 to n-C36 Aliphatic Hydrocarbons t BRL ug/L 500 n=C11 to n-C22?aromatic Hydrocarbons t° BRL ug/L 160 Unadjusted n-Cl.1 to n-C22 Aromatic Hydrocarbons t BRL ug/L 160 C Surr_o ate Gom ound Q Splked Measured t �Recouery .. ... a" r" :': �" QC°Ltm1 st : Fractionation: 2-Fluorobiphenyl 40 38 95 % 40-140 2-Bromonaphthalene 40 40 100 % 40-140 Extraction: I Chloro-octadecane 40 30 76 % 40-140 ortho-Terphenyl 40 34 85 % 40-140% g_ ,w 1. Were all QA/QC procedures required by the method followed? Yes 2. Were all perforinance/acceptance standards for the required QA/QC procedures achieved? Yes 3. Were any significant modifications made to the method,as specified in Section 11.3? No Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompanying signed project cover letter. The accompanying cover letter,project narrative and quality control report are considered part of this data report. Method Reference: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998). Sample extraction performed by separatory funnel technique. Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting in that range. 0 n-C11 to n-C22 Aromatic Hydrocarbons range data excludes the method target analyte concentrations. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL EPA Method 8270C(Modified) MA DEP EPH Polynuclear Aromatic Hydrocarbons by GC/MS-SIM Field ID: MW-6S Matrix: Aqueous Project: Hubbard Oil/Brooks Rd./BO02-3490 Container: 1 L Amber Glass Client: Bennett&O'Reilly,Inc. Preservation: H2SO4/Cool Laboratory ID: 69408-16 QC Batch ID: EP-1326-F Sampled: 02-05-04 13:00 Instrument ID: MS-6 HP 6890 Received: 02-06-04 12:50 Sample Volume: 1,000 mL Extracted: 02-09-04 18:30 Final Volume: 1 mL Analyzed: 02-18-04 14:23 Dilution Factor: 1 Analyst: JJT ti^a F.. t J*'d 'b z„ . y ;� S f �q � •. army �i'P i� Y °S f b 1£ .5 � � d �;-.. CASNuinber_- Analyte Concenrtrato� f �Notes Units , aeportmsim�tx 91-20-3 Naphthalene BRL ug/L 0.5 91-57-6 2-Methyl naphthalene BRL ug/L 0.5 208-96-8 Acenaphthylene BRL ug/L 0.5 83-32-9 Acenaphthene BRL ug/L 0.5 86-73-7 Fluorene BRL ug/L 0.5 85-01-8 Phenanthrene BRL ug/L 0.5 120-12-7 Anthracene BRL ug/L 0.5 20644-0 Fluoranthene 0.7 ug/L 0.5 129 00-0 Pyrene BRL ug/L 0.5 56-55-3 Benzo[a]anthracene 0.2 ug/L 0.1 218-01-9 Chrysene 0.3 ug/L 0.1 205-99-2 Benzo[b]fluoranthene 0.3 ug/L 0.1 207-08-9 Benzo[k]fluoranthene 0.2 ug/L 0.1 50-32-8 Benzo[a]pyrene 0.2 ug/L 0.1 193-39-5 Indeno[1,2,3-c,d]pyrene 0.2 ug/L 0.1 53-70-3 Dibenzo[a,h]anthracene BRL ug/L 0.1 191-24-2 1 Benzo[g,h,i]perylene 0.2 ug/L 0.1 QC�Siirrogate Compound �,;,>�44- ���� y�Sprlied Measut�ed �w , .Recovery ry�� „� _ ' �QC Ltm�ts ,1 ortho-Terphenyl 40 32 81.% 40-140% Method Reference: Test Methods for Evaluating Solid Waste,Us EPA,SW-846,Third Edition,Update III(1996). Method modified by use of selected ion monitoring(SIM)in accordance with Section 7.5.5 of the method. Method protocol modified to include acidification and the surrogate compound in accordance with the MA DEP Method for the Determination of Extractable Petroleum Hydrocarbons. Sample extraction performed by EPA Method 3510C. Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Massachusetts DEP EPH Method Extractable Petroleum Hydrocarbons by GGFID Field ID: MW-613 Matrix: Aqueous Project: Hubbard Oil/Brooks Rd./6002-3490 Container: 1 L Amber Glass Client: Bennett&O'Reilly,Inc. Preservation: H2SO4/Cool Laboratory ID: 69408-17 QC Batch ID: EP-13264 Sampled: 02-05-04 12:50 Instrument ID: GC-7 HP 5890 Received: 02-06-04 12:50 Sample Volume: 1,000 mL Extracted: 02-09-04 18:30 Final Volume: 1 mL Analyzed(AL): 02-17-04 20:53 Aliphatic Dilution Factor: 1 Analyzed(AR): 02-17-04 21:37 Aromatic Dilution Factor: 1 Analyst: WN �' -Ran es r ,-,z. r., ... . ._ .. ..;._. Concentration? Notes a p Units Re ornn L�mrt �.g .... .. �., ,., _ s_:: n-C9 to n-C18 Aliphatic Hydrocarbons t BRL ug/L 500 n-C19 to n-C36 Aliphatic Hydrocarbons t BRL ug/L 500 n-CI 1 to n-C22 Aromatic Hydrocarbons t° BRL ug/L 160 Unadjusted n-C11 to n-C22 Aromatic Hydrocarbons t BRL ug/L 160 0C Surrogate, ompound Stu Yr Spikedr MeasuredRe�o�uey _ a � QC Ltmts Fractionation: 2-Fluorobiphenyl 40 36 90 % �40-140% 2-Bromonaphthalene 40 38 94 % 40-140% Extraction: Chloro-octadecane 40 22 55 % 40-140% - ortho-Terphenyl 1 40 34 84 % 40-140% v Q.A/QlrCertlflCatlOns-� ,.aces,.r c :,s ,.;d. .. »mz=r a�..,..,ue•.�.� ,a,>. 1. Were all QA/QC procedures required by the method followed? Yes 2. Were all performance/acceptance standards for the required QA/QC procedures achieved? Yes 3. Were any significant modifications made to the method,as specified in Section 11.3? No Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompanying signed project cover letter. The accompanying cover letter,project narrative and quality control report are considered part of this data report. Method Reference: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998). Sample extraction performed by separatory funnel technique. Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting in that range. 0 n-C11 to n-C22 Aromatic Hydrocarbons range data excludes the method target analyte concentrations. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNGWATER ANALYTICAL EPA Method 8270C(Modified) MA DEP EPH Polynuclear Aromatic Hydrocarbons by GC/MS-SIM Field ID: MW-6D Matrix: Aqueous Project: Hubbard Oil/Brooks Rd./BO02-3490 Container: 1 L Amber Glass Client: Bennett&O'Reilly, Inc. Preservation: H2SO4/Cool Laboratory ID: 69408-17 QC Batch ID: EP-1326-F Sampled: 02-05-04 12:50 Instrument ID: MS-6 HP 6890 Received: 02-06-04 12:50 Sample Volume: 1,000 mL Extracted: 02-09-04 18:30 Final Volume: 1 mL Analyzed: 02-18-04 15:01 Dilution Factor: 1 Analyst: JJT CAS Number Analyte 6 cCOrlCelltrdtlon wxf IOtCS T 'on ? Rep'ortmgGm�tN 91-20-3 Naphthalenes BRL ug/L 0.5 91-57-6 2-Methyl naphthalene BRL ug/L 0.5 208-96-8 Acenaphthylene BRL ug/L 0.5 83-32-9 Acenaphthene BRL ug/L 0.5 86-73-7 Fluorene BRL ug/L 0.5 85-01-8 Phenanthrene BRL ug/L 0.5 120-12-7 Anthracene BRL ug/L 0.5 206-44-0 Fluoranthene BRL ug/L 0.5 129-00-0 Pyrene BRL ug/L 0.5 56-55-3 Benzo[a]anthracene - BRL ug/L 0.1 218-01-9 Chrysene BRL ug/L 0.1 .205-99-2 Benzo[b]fluoranthene BRL ug/L 0.1 207-08-9 Benzo[k]fluoranthene BRL ug/L 0.1 50-32-8 Benzo[a]pyrene BRL ug/L 0.1 193-39-5 Indeno[1,2,3-c,d]pyrene BRL ug/L 0.1 53-70-3 Dibenzo[a,h]anthracene BRL ug/L 0.1 191-24-2 Benzo[g,h,i]perylene BRL ug/L 0.1 QC Surrogate�Compound �`' � ��`_� �,Spiked�, Me surei3 � °� Recovery;P " , .fin . y�°� QC�L'imtts '�� ^� ortho-Terphenyl 40 34 85 % 40-140% Method Reference: Test Methods for Evaluating Solid Waste,US EPA,SW-846,Third Edition,Update III(1996). Method modified by use of selected ion monitoring(SIM)in accordance with Section 7.5.5 of the method. Method protocol modified to include acidification and the surrogate compound in accordance with the MA DEP Method for the Determination of Extractable Petroleum Hydrocarbons. Sample extraction performed by EPA Method 3510C. Report Notations: BRL Indicates concentration,ii any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under.outine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Massachusetts DEP EPH Method Extractable Petroleum Hydrocarbons by GUID Field ID: MW-1 Matrix: Aqueous Project: (Hubbard Oil/Brooks Rd./BO02-3490 Container: 1 L Amber Glass Client: [Bennett&O'Reilly,Inc. Preservation: H2SO4/Cool Laboratory ID: 69408-18 QC Batch ID: EP-1326-F Sampled: 02-05-04 14:45 Instrument ID: GC-7 HP 5890 Received: 02-06-04 12:50 Sample Volume: 1,000 mL Extracted: ;02-09-04 18:30 Final Volume: 1 mL Analyzed(AL): 02-17-04 22:20 Aliphatic Dilution Factor: 1 Analyzed(AR): 02-17-04 23:03 Aromatic Dilution Factor: 1 Analyst:- WN EPH Rdn e5 3 r � � Concen#rdtlOfl� � NOteS UnIfS� Reporting L mrt Y � _.._._- _ems n-C9 to n-C18 Al'phatic Hydrocarbons t 700 ug/L 500 n-C19 to n-C36 Aliphatic Hydrocarbons t BRL ug/L 500 n-C11 to n-C22 Aromatic Hydrocarbons t° 450 ug/L 160 Unadjusted n-C11 to n-C22 Aromatic Hydrocarbons t 450 ug/L. 160 QC Strrogate Compound ,x� ,� �� Spiked��Measure _ Re_cove r - C Ltmfs� , y Fractionation: 2-Fluorobiphenyl 40 37 93 % 40-140% 2-Bromonaphthalene 40 40 100 % 40-140% Extraction: Chloro-octadecane 40 26 64 % 40-140 ortho-Terphenyl 40 33 82 % 40-140% 1. Were all QA/QC procedures required by the method followed? Yes 2. Were all perfomtance/acceptance standards for the required QA/QC procedures achieved? Yes 3. Were any significant modifications made to the method,as specified in Section 11.3? No Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompanying signed project cover letter. The accompanying cover letter,project narrative and quality control report are considered part of this data report. Method Reference: Method for the Determination cf Extractable Petroleum Hydrocarbons,MA DEP(1998). Sample extraction performed by separatory funnel technique. Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting in that range. 0 n-C11 to n-C22 Aromatic Hydrocarbons range data excludes the method target analyte concentrations. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL EPA Method 8270C(Modified) MA DEP EPH Polynuclear Aromatic Hydrocarbons by GC/MS-SIM Field ID: MW-1 Matrix: Aqueous Project: Hubbard"Oil/Brooks Rd./BO02-3490 Container: 1 L Amber Glass Client: Bennett&O'Reilly,Inc. Preservation: H2SO4/Cool Laboratory ID: 69408-18 QC Batch ID: EP-1326-F Sampled: 02-05-04 14:45 Instrument ID: MS-6 HP 6890 Received: 02-06-04 12:50 Sample Volume: 1,000 mL Extracted: 02-09-04 18:30 Final Volume: 1 mL Analyzed: 02-18-04 15:39 Dilution Factor: 1 Analyst: JJT GAS_'Number, Anal, e� N ,:m, Conce tratton Note's Units Reporting Yil 91-20-3 Naphthalene BRL ug/L 0.5 91-57-6 2-Methyl naphthalene BRL ug/L 0.5 208-96-8 Acenaphthylene BRL ug/L 0.5 83-32-9 Acenaphthene BRL ug/L 0.5 86-73-7 Fluorene BRL ug/L 0.5 85-01-8 Phenanthrene BRL ug/L 0.5 120-12-7 { Anthracene BRL ug/L 0.5 206-44-0 I Fluoranthene BRL ug/L 0.5 129-00-0 Pyrene BRL ug/L 0.5 56-55-3 Benzo[a]anthracene BRL ug/L -0.1 218-01-9 Chrysene BRL ug/L 0.1 205-99-2 Benzo[b]fluoranthene BRL ug/L 0.1 207-08-9 Benzo[k]fluoranthene BRL ug/L" 0.1 50-32-8 Benzo[a]pyrene BRL ug/L 0.1 193-39-5 Indeno[1,2,3-c,d]pyrene BRL ug/L 0.1 53-70-3 Dibenzo[a,h]anthracene BRL ug/L 0.1 191-24-2 Benzo[g,h,i]perylene BRL ug/L 0.1 s QC Surrogate C omp ound} ,mSpked, Measured ` Recovery > � t ;QC Limits 2^ _ ortho-Terphenyl" 40 33 82 % 40-140% Method Reference: Test Methods for Evaluating Solid Waste,US EPA,SW-846,Third Edition,Update III(1996). Method modified by use of selected ion monitoring(SIM)in accordance with Section 7.5.5 of the method. Method protocol modified to include acidification and the surrogate compound in accordance with the MA DEP Method for the Determination of Extractable Petroleum Hydrocarbons. Sample extraction performed by EPA Method 3510C. Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. r Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Massachusetts DEP EPH Method Extractable Petroleum Hydrocarbons by GGFID Field ID: MW-2 Matrix: Aqueous Project: Hubbard Oil/Brooks Rd./BO02-3490 Container: 1 L Amber Glass Client: Bennett&O'Reilly,Inc. Preservation: H2SO4/Cool Laboratory ID: 69408-19 QC Batch ID: EP-1326-F Sampled: 02-05-04 14:45 Instrument ID: GC-7 HP 5890 Received: 02-06-04 12:50 Sample Volume: 1,000 mL Extracted: 02-09-04 18:30 Final Volume: 1 mL Analyzed(AL): 02-17-04 23:46 Aliphatic Dilution Factor: 1 Analyzed(AR): 02-18-04 00:29 Aromatic Dilution Factor: 1 Analyst: WN "Concen#ra#tor -' tMUIII#_S k+#Reportngljtimi[�.,ri' n-C9 to n-C18 Aliphatic Hydrocarbons t BRL ug/L 500 n-C19 to n-C36 Aliphatic Hydrocarbons t BRL ug/L 500 n-C11 to 1-C22 Aromatic Hydrocarbons to BRL ug/L 160 Unadjusted n-C11 to n-C22 Aromatic Hydrocarbons t BRL ug/L 160 rY�z t , QC Surrogate Compound ° * , Sptked Mea tired Recoue � � ,QC`Ltmi#sue 4i Fractionation: 2-Fluorobiphenyl 40 36 91 % 40-140 2-13romonaphthalene 40 39 97 % 40-140 Extraction: Chloro-octadecane 40 27 68 % 40-140% -- ortho-Terphenyl ! 40 34 85 % 40-140 d-� a aye�� f�' ''= � ,a •�; r"zka'�' `�,���+,a.,e y K'A/s�tC�CCI'tl#ICd#IOnM �^ �^' *^ems "w as .. - e• W11 1. Were all QA/QC procedures required by the method followed? Yes 2. Were all performancelacceptance standards for the required QA/QC procedures achieved? Yes 3. Were any significant modifications made to the method,as specified in Section 11.3? No Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompanying signed project cover letter. The accompanying cover letter,project narrative and quality control report are considered part of this data report. Method Reference: . Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998). Sample extraction performed by separatory funnel technique. Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting in that range. 0 n-C11 to n-C22 Aromatic Hydrocarbons range data excludes the method target analyte concentrations. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL EPA Method 8270C(Modified) MA DEP EPH Polynuclear Aromatic Hydrocarbons by GC/MS-SIM Field ID: MW-2 Matrix: Aqueous Project: Hubbard Oil/Brooks Rd./BO02-3490 Container: 1 L Amber Glass Client: Bennett&O'Reilly,Inc. Preservation: H2SO4/Cool Laboratory ID: 69408-19 QC Batch ID: EP-1326-F Sampled: 02-05-04 14:45 Instrument ID: MS-6 HP 6890 Received: 02-06-04 12:50 Sample Volume: 1,000 mL Extracted: 02-09-04 18:30 Final Volume: 1 mL Analyzed: 02-18-04 16:17 Dilution Factor: 1 Analyst: JJT CAS Numbera= Anal a , Goncentratton No"fes` � Units` Re ortm um�t 91-20-3 Naphthalene BRL ug/L 0.5 91-57-6 2-Methyl naphthalene BRL ug/L 0.5 208-96-8 Acenaphthylene BRL ug/L 0.5 83-32-9 Acenaphthene BRL ug/L 0.5 86-73-7 Fluorene BRL ug/L 0.5 85-01-8 Phenanthrene BRL ug/L 0.5 120-12-7 Anthracene BRL ug/L 0.5 206-44-0 Fluoranthene BRL ug/L 0.5 129-00-0 Pyrene BRL ug/L 0.5 56-55-3 Benzo[a]anthracene BRL -ug/L 0.1 218-01-9 Chrysene BRL ug/L 0.1 205-99-2 Benzo[b]fluoranthene BRL ug/L 0.1 207-08-9 Benzo[k]fluoranthene BRL ug/L 0.1 50-32-8 Benzo[a]pyrene BRL ug/L 0.1 193-39-5 Indeno[1,2,3-c,d]pyrene BRL ug/L 0.1 53-70-3 Dibenzo[a,h]anthracene BRL ug/L 0.1 191-24-2 Benzo[g,h,i]perylene BRL ug/L 0.1 QC Surrogate Compound § , ' Sprked Measured �gRecoydery � QCLmts ortho-Terphenyl 40 1 33 83 % 40-140 Method Reference: Test Methods for Evaluating Solid Waste,US EPA,SW-846,Third Edition,Update III(1996). Method modified by use of selected ion monitoring(SIM)in accordance with Section 7.5.5 of the method. Method protocol modified to include acidification and the surrogate compound in accordance with the MA DEP Method for the Determination of Extractable Petroleum Hydrocarbons. Sample extraction performed by EPA Method 3510C. Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Massachusetts DEP EPH Method Extractable Petroleum Hydrocarbons by GC/FID Field ID: MW4 Matrix: Aqueous Project: Hubbard Oil/Brooks Rd.BO02-3490 Container: 1 L Amber Glass Client: Bennett&O'Reilly,Inc. Preservation: H2SO4/Cool Laboratory ID: 69408-20 QC Batch ID: EP-1326-F Sampled: 02-05-04 15:20 Instrument ID: GC-7 HP 5890 Received: 02-06-04 12:50 Sample Volume: 1,000 mL Extracted: 02-09-04 18:30 Final Volume: 1 mL Analyzed(AL): 02-18-04 01:12 Aliphatic Dilution Factor: 1 Analyzed(AR): 02-18-04 01:56 Aromatic Dilution Factor: 1 Analyst: WN EPHRanges � � r � Concentratlon � ras �fotes �Umts �Renort�ng um�t n-C9 to n-C18 Aliphatic Hydrocarbons t BRL ug/L 500 n-C19 to n-C36 Aliphatic Hydrocarbons t BRL ug/L 500 n-Cl1 to n-C22 Aromatic Hydrocarbons t° 180 ug/L 160 Unadjusted n-Cl1 to n-C22 Aromatic Hydrocarbons t 180 ug/L 160 QC Surrogate,Compbundl S iked Me u ed eco _ c Recove __ QC Llmats Fractionation: 2-Fluorobiphenyl 40 �38 96 % 40-140 2-Bromonaphthalene 40 39 99 % 40-140% Extraction: Chloro-octadecane 40 29 73 % 40-140 ortho-Terphenyl 40 34 86 % 40-140 ` r✓ .. "a "� „.. A/ A—tlOok Ca ; ,1%Er 1. Were all QA/QC procedures required by the method followed? Yes 2. Were all performance/acceptance standards for the required QA/QC procedures achieved? Yes 3. Were any significant modifications made to the method,as specified in Section 11.3? No Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompanying signed project cover letter. The accompanying cover letter,project narrative and quality control report are considered part of this data report. Method Reference: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998). Sample extraction performed by separatory funnel technique. Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting in that range. 0 n-C11 to n-C22 Aromatic Hydrocarbons range data excludes the method target analyte concentrations. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL EPA Method 8270C(Modified) MA DEP EPH Polynuclear Aromatic Hydrocarbons by GC/MS-SIM Field ID: MW-4 Matrix: Aqueous Project: Hubbard Oil/Brooks Rd./BO02-3490 Container: 1 L Amber Glass Client: Bennett&O'Reilly,Inc. Preservation: H2SO4/Cool Laboratory ID: 69408-20 QC Batch ID: EP-1326-F Sampled: 02-05-04 15:20 Instrument ID: MS-6 HP 6890 Received: 02-06-04 12:50 Sample Volume: 1,000 mL Extracted: 02-09-04 18:30 Final Volume: 1 mL Analyzed: 02-18-04 16:56 Dilution Factor: 1 Analyst: JJT _ CASNumber p AnaL'.a ConcenfirattonNo es �Untt Repurtng um�tk 91-20-3 Naphthalene BRL �ug/L 0.5 91-57-6 2-Methyl naphthalene BRL ug/L 0.5 208-96-8 Acenaphthylene BRL ug/L 0.5 83-32-9 Acenaphthene BRL ug/L 0.5 86-73-7 Fluorene BRL ug/L 0.5 85-01-8 Phenanthrene BRL ug/L 0.5 120-12-7 Anthracene BRL ug/L 0.5 206-44-0 Fluoranthene BRL ug/L 0.5 129-00-0 Pyrene BRL ug/L 0.5 56-55-3 Benzo[a]anthracene BRL ug/L -0.1 218-01-9 Chrysene BRL ug/L 0.1 205-99-2 Benzo[b]fluoranthene BRL ug/L 0.1 207-08-9 Benzo[k]fluoranthene BRL ug/L 0.1 50-32-8 Benzo[a]pyrene BRL ug/L 0.1 193-39-5 Indeno[1,2,3-c,d]pyrene BRL ug/L 0.1 53-70-3 Dibenzo[a,h]anthracene BRL ug/L 0.1 191-24-2 Benzo[g,h,i]perylene BRL ug/L 0.1 edti . ,., ;.. 0it,ikd' r . eMe , u , i-4 si -. /0 40 34 86 ortho-Ter hen I 40-140 p Y o Method Reference: Test Methods for Evaluating Solid Waste,US EPA,SW-846,Third Edition,Update III(1996). Method modified by use of selected ion monitoring(SIM)in accordance with Section 7.5.5 of the method. Method protocol modified to include acidification and the surrogate compound in accordance with the MA DEP Method for the Determination of Extractable Petroleum Hydrocarbons. Sample extraction performed by EPA Method 3510C. Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Massachusetts DEP EPH Method Extractable Petroleum Hydrocarbons by GC/FID Field ID: SEA-1 Matrix: Aqueous Project: Hubbard Oil/Brooks Rd.iBO02-3490 Container: 1 L Amber Glass Client: Bennett&O'Reilly,Inc. Preservation: H2SO4/Cool Laboratory ID: 69408-21 QC Batch ID: EP-1326-F Sampled: 02-05-04 15:50 Instrument ID: GC-7 HP 5890 Received: 02-06-04 12:50 Sample Volume: 1,000 mL Extracted: 02-09-04 18:30 Final Volume: 1 mL Analyzed(AL) 02-18-04 03:22 Aliphatic Dilution Factor: 1 Analyzed(AR): 02-18-04 04:05 Aromatic Dilution Factor: 1 Analyst: WN n-C9 to n-C1 E;Aliphatic Hydrocarbons t 16,000 ug/L 500 n-Cl9 to n-C=6 Aliphatic Hydrocarbons t 2,300 ug/L 500 n-C11 to n-C22 Aromatic Hydrocarbons 10 7,300 ug/L 160 Unadjusted n-C11 to n-C22 Aromatic Hydrocarbons t 7,700 ug/L 160 Q Surogate�Compound �Splked MeasuFedaRecoue ' QCGmitsn �... Fractionation: 2-Fluorobiphenyl 40 43 108 % 40-140% 2-Bromonaphthalene 40 41 102 % 40-140 Extraction: Chloro-octadecane 40 29 72 % 40-140% ortho-Terphenyl 40 27 68 % 40-140 i On*. -, "' A, �'c 1. Were all QPJQC procedures required by the method followed? Yes 2. Were all performancelacceptance standards for the required QA/QC procedures achieved? Yes 3. Were any significant modifications made to the method,as specified in Section 11.3? No Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompanying signed project cover letter. The accompanying cover letter,project narrative and quality control report are considered part of this data report. Method Reference: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998). Sample extraction performed by separatory funnel technique. Report Nctations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting in that range. 0 n-C1 I to n-C22 Aromatic Hydrocarbons range data excludes the method target analyte concentrations. I Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL EPA Method 8270C (Modified) MA DEP EPH Polynuclear Aromatic Hydrocarbons by GC/MS-SIM Field ID: SEA-1 Matrix: Aqueous Project: Hubbard Oil/Brooks Rd./6002-3490 Container: 1 L Amber Glass Client: Bennett&O'Reilly,Inc. Preservation: H2SO4/Cool Laboratory ID: 69408-21 QC Batch ID: EP-1326-F Sampled: 02-05-04 15:50 Instrument ID: MS-6 HP 6890 Received: 02-06-04 12:50 Sample Volume: 1,000 mL Extracted: 02-09-04 18:30 Final Volume: 1 mL Analyzed: 02-18-04 17:34 Dilution Factor: 1 Analyst: JJT CAS;Number` Analyte ConScentration NotesUmts Pgrtmg � 91-20-3 I Naphthalene 48 a ug/L 0.5 91-57-6 2-Methyl naphthalene 79 a ug/L 0.5 208-96-8 Acenaphthylene BRL ug/L 0.5 83-32-9 Acenaphthene 4.7 ug/L 0.5 86-73-7 Fluorene 11 ug/L 0.5 85-01-8 Phenanthrene 16 ug/L 0.5 120-12-7 Anthracene 1.8 ug/L 0.5 20644-0 Fluoranthene BRL ug/L 0.5 129-00-0 Pyrene 1.7 ug/L 0.5 56-55-3 Benzo[a]anthracene - BRL ug/L 0.1 -- 218-01-9 Chrysene BRL ug/L 0.1 205-99-2 Benzo[b]fluoranthene BRL ug/L 0.1 207-08-9 Benzo[k]fluoranthene BRL ug/L 0.1 50-32-8 Benzo[a]pyrene BRL ug/L 0.1 193-39-5 Indeno[1,2,3-c,d]pyrene BRL ug/L 0.1 53=70-3 Dibenzo[a,h]anthracene BRL ug/L 0.1 191-24-2 Benzo[g,h,i]perylene BRL ug/L 0.1 QC Surrogate Cortipound k � Spiked Measured Rec vo ey FXQC L1mItS �s "{' ortho-Terphenyl 40 21 53 % 40-140 Method Reference: Test Methods for Evaluating Solid Waste,US EPA,SW-846,Third Edition,Update III(1996). Method modified by use of selected ion monitoring(SIM)in accordance with Section 7.5.5 of the method. Method protocol modified to include acidification and the surrogate compound in accordance with the MA DEP Method for the Determination of Extractable Petroleum Hydrocarbons. Sample extraction performed by=PA Method 3510C. Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. e Indicates concentration exceeded calibration range for the analyte. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL EPA Method 8270C(Modified) MA DEP EPH Polynuclear Aromatic Hydrocarbons by GUMS-SIM Field ID: SEA-1 Matrix: Aqueous Project: Hubbard Oil/Brooks Rd./BO02-3490 Container: 1 L Amber Glass Client: Bennett&O'Reilly,Inc. Preservation: H2SO4/Cool Laboratory ID: 69408-21RA1 QC Batch ID: EP-1326-F Sampled: 02-05-04 15:50 Instrument ID: MS-6 HP 6890 Received: 02-06-04 12:50 Sample Volume: 1,000 mL Extracted: 02-09-04 18:30 Final Volume: 1 mL Analyzed: 02-19-04 15:23 Dilution Factor: 10 Analyst: JJT CAS`Nurnber Analgte� Concentration Notes "` Units " #ReRortmgumt" 91-20-3 Naphthalene 57 ug/L 5.0 91-57-6 2-Methylnaphthalene 100 ug/L 5.0 208-96-8 Acenaphthylene BRL ug/L 5.0 83-32-9 Acenaphthene 4.0 j ug/L 5.0 86-73-7 Fluorene 10 ug/L 5.0 85-01-8 Phenanthrene 13 ug/L 5.0 120-12-7 Anthracene BRL ug/L 5.0 206-44-0 Fluoranthene BRL ug/L 5.0 129-00-0 Pyrene BRL ug/L 5.0 56-55-3 Benzo[a]anthracene BRL ug/L 1.0 218-01-9 Chrysene BRL ug/L 1.0 205-99-2 Benzo[b]fluoranthene BRL ug/L 1.0 207-08-9 Benzo[k]fluoranthene BRL ug/L 1.0 50-32-8 Benzo[a]pyrene BRL ug/L 1.0 193-39-5 Indeno[1,2,3-c,d]pyrene BRL ug/L 1.0 53-70-3 Dibenzo[a,h]anthracene BRL ug/L 1.0 191-24-2 Benzo[g,h,i]perylene BRL ug/L 1.0 QC Suirogate,Compound $rf wSplked f MeasuredRecover�Yy 'QCLlmrts �uP` a•. _ :.._ ortho-Terphenyl 40 20 49 % 40-140% Method Reference: Test Methods for Evaluating Solid Waste,US EPA,SW-846,Third Edition,Update III(1996). Method modified by use of selected ion monitoring(SIM)in accordance with Section 7.5.5 of the method. Method protocol modified to include acidification and the surrogate compound in accordance with the MA DEP Method for the Determination of Extractable Petroleum Hydrocarbons. Sample extraction performed by EPA Method 3510C. Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. j Indicates an estimated value detected below the reporting limit for the analyte. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Massachusetts DEP EPH Method Extractable Petroleum Hydrocarbons by GC/FI D Field ID: SEA-2 Matrix: Aqueous Project: Hubbard Oil/Brooks Rd./BO02-3490 Container: 1 L Amber Glass Client: Bennett&O'Reilly,Inc. Preservation: H2SO4/Cool Laboratory ID: 69408-22 QC Batch ID: EP-1326-F Sampled: 02-05-04 15:30 Instrument ID: GC-7 HP 5890 Received: 02-06-04 12:50 Sample Volume: 1,000 mL Extracted: 02-09-04 18:30 Final Volume: 1 mL Analyzed(AL): 02-18-04 04:49 Aliphatic Dilution Factor: 1 Analyzed(AR): 02-18-04 05:32 Aromatic Dilution Factor: 1 Analyst: WN EP,H Rari es `� rConcentratton. x Notes Re g Lin�f .� ..g ._' _. .,. �. �1 ; ��_.... .._t.. s, pert u Units; m n-C9 to n-C18 Aliphatic Hydrocarbons t 4,300 ug/L 500 n-C19 to n-C36 Aliphatic Hydrocarbons' 650 ug/L 500 n-Cl1 to n-C22.Aromatic Hydrocarbons t 0 1,400 ug/L 160 Unadjusted n-Cl1 to n-C22 Aromatic Hydrocarbon t 1,500 ug/L 160 QC Surrogate Compound.„ , Sptked Measurr yRecouery u s ;,M s V tQC ltmtts Fractionation: 2-Fluorobiphenyl 40 33 83 % 40-140% 2-Bromonaphthalene 40 33 83 % 40-140% Extraction: Chloro-octadecane 40 24 59 % 40-140 ortho-Terphenyl 40 30 76 % 40-140% :vsa zs, *?:f '�' Y ' z .K?'.a n g�, :�, yr ^`"�3: QA/QC Certnficatton �:. W. 1. Were all QA/QC procedures required by the method followed? Yes 2. Were all performance/acceptance standards for the required QA/QC procedures achieved? Yes 3. Were any significant modifications made to the method,as specified in Section 11.3? No Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompanying signed project cover letter. The accompanying cover letter,project narrative and quality control report are considered part of this data report. Method Reference: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998). Sample extraction performed by separatory funnel technique. Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting in that range. 0 n-Cl1 to n-C22 Aromatic Hydrocarbons range data excludes the method target analyte concentrations. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL EPA Method 8270C(Modified) MA DEP EPH Polynuclear Aromatic Hydrocarbons by GC/MS-SIM Field ID: SEA-2 Matrix: Aqueous Project: Hubbard Oil/Brooks Rd./BO02-3490 Container: 1 L Amber Glass Client: Bennett&O'Reilly,Inc. Preservation: H2SO4/Cool Laboratory ID: 69408-22 QC Batch ID: EP-1326-F Sampled: 02-05-04 15:30 Instrument ID: MS-6 HP 6890 Received: 02-06-04 12:50 Sample Volume: 1,000 mL Extracted: 02-09-04 18:30 Final Volume: 1 ml. Analyzed: 02-18-04 18:13 Dilution Factor: 1 Analyst: JJT �C=AS Number Anal a ,> �. Concegtratton ,�NofesRepornn,umit , 91-20-3 Naphthalene 0.6 ug/L 0.5 91-57-6 2-Methyl naphthalene 9.2 ug/L 0.5 208-96-8 Acenaphthylene BRL ug/L 0.5 83-32-9 Acenaphthene 1.4 ug/L 0.5 86-73-7 Fluorene 3.0 ug/L 0.5 85-01-8 Phenanthrene 4.3 ug/L 0.5 120-12-7 Anthracene BRL ug/L 0.5 206-44-0 Fluoranthene BRL ug/L 0.5 129-00-0 Pyrene BRL ug/L 0.5 56-55-3 Benzo[a]anthracene BRL ug/L 0.1 218-01-9 Chrysene BRL ug/L 0.1 205-99-2 Benzo[b]fluoranthene BRL ug/L 0.1 207-08-9 Benzo[k]fluoranthene BRL ug/L 0.1 50-32-8 Benzo[a]pyrene BRL ug/L 0.1 193-39-5 Indeno[1,2,3-c,d]pyrene BRL ug/L 0.1 53-70-3 Dibenzo[a,h]anthracene BRL ug/L 0.1 191-24-2 Benzo[g,h,i]perylene BRL ug/L 0.1 wSu ikd i d rroateComPourQ d Q A. ortho-Terphenyl 40 25 62 % 40-140 Method Reference: Test Methods for Evaluating Solid Waste,US EPA,SW-846,Third Edition,Update III(1996). Method modified by use of selected ion monitoring(SIM)in accordance with Section 7.5.5 of the method. Method protocol modified to include acidification and the surrogate compound in accordance with the MA DEP Method for the Determination of Extractable Petroleum Hydrocarbons. Sample extraction performed by EPA Method 3510C. Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. s Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL .Project Narrative Project: Hubbard Oil/Brooks Rd./BO02-3490 Lab ID: 69408 Client: Bennett&O'Reilly, Inc. Received: 02-06-04 12:50 1.5Y'#.a a3c4 ,s^.r `"d} k�s"Z 'cs' '`-�T v ` `i"f'x s,f�'e✓5.4rx,"e� +q 4�c. "R i„ �'1ht�,a'. a3 �, �r � �5 �� A Documentation and Chent Commumcat�onx�� t ��`� � s* � The following documentation discrepancies,and!client changes or amendments were noted for this project: 1 . No documentation discrepancies,changes,or amendments were noted. � hs c r:P`"� ✓�r' k. 3„, :,.,� �„'"' t x""� : -r {��x � pax .<. �wYk SX" �� ET3 x. .� 4y" x." ,�,g ,� x= '�B Method INodificaions Npn Conformances andObservaons� ?§:c�.9.rs .." .T Ns r ��e. The sample(s) in this project were analyzed by the references analytical method(s),and no method modifications, non-conformances or analytical issues were noted,except as indicated below: 1 . EPA 8270C Non-conformance: Sample 69408-21. Reported results for the analyte exceeded the high standard of the associated calibration curve. Results are estimated. 2 . EPA 8270C Note: Sample 69408-21.Sample was diluted prior to analysis. Dilution was required to keep all target analytes within calibration. 3 . MA DEP EPH Note:Samples 69408-12,-13,-14;15,-16,-17,-18,-19,20,21,-22. Polynuclear aromatic hydrocarbon. (PAH)target analytes were identified and quantified by GC/MS-SIM, in accordance with the method provision for alternate determinative methodologies. GC/MS-SIM was used to achieve low quantification limits necessary for regulatory compliance. Target analytes were determined utilizing the same sample extract used for carbon range, determination by GC/FID. 4 . MA DEP VPH Note: Sample 69408-10.Sample was diluted prior to analysis. Dilution was required to keep all target analytes within calibration. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 Main GROUNDWATER a raga at T Buz ands Street,P.O.Box 1200 (��`� Buzzards Bay,MAo2532 CHAIN-OF-CUSTODY RECORD �� 0-�4�63 ANALYTICAL Telephone wwgro ndwateranalytcal.om (508)759-4475 AND WORK ORDER Project Name: '(�/'t�ylt Firm 'p� J T/ y TURNAROUND ANALYSIS REQUEST w's {� . em' '''1 �, STANDARD 10 Business Days) Valaliles Semivolaliles Pesl/Herb/PCBs Metals Petroleum Hydracarban Haz. General Chemistry Other 1 ( ( Y) Extractable Voi. Ext.TPH 111.11PH Waste Project Number: ( Address: pn �`! 7� r/�/ ❑ PRIORITY(5 Business Days) _ 9 z c p - a z G-J� LO 1�jlj Js'lClln c�i� / �V (l17 ❑ RUSH(RAN tt (Rush requires Rush Authorization Number) ❑ 000 3' O ❑ Sampler Name: [t City/State/Zip: Please Email to:❑Please FAX to:. / `J \�J\% J[✓ ��/` J'f�� ( J"'•V 1 - tiW�d 560 �Zt- G8 = z BILLING ❑ ^ 's a o a U Project Manager: ` (\ Telephone:: Z L�7t o 0 0 0 0.0 4 Purchase Order No.: J�`V o z N „ _ ig _ ❑ Third Party Billing: m 0 3 p_ o _ ❑ s ❑ INSTRUCTIONS:Use separate line for each container(except replicates). ❑ GWA Quote: s' s a o _ _ 0 ❑ o n ❑ a o 0 0 0 0 0 0 o an 0 ❑ o o ❑ 0 a ; E Sampling Matrix Type Container(s) Preservation Filtered = a .� _ o = o LABORATORY J n s o 0 9 SAMPLE w IE _ - � d _ _ _ _ s NUMBER N � �� E is � g s o m � g q � g � - u p ❑ � € w w IDENTIFICATIO 3 3 ¢ o w g ,E (Lab Use Only) m m m e _ m - = d ❑ a ❑ - a _ — o E E E E E E — b `'°"m "' m io m r o o r' S e s " o o t-i ❑ o y - v a 'S 0❑0 ❑ ❑ ❑ 0 0 0 0 0 0 00❑0 0 ❑ ❑ ❑• ❑ o o 'g o ❑ ❑ o ❑ ❑ o o ❑ ❑ o a i i 1 3D G-77AMW Z X X G7t Zi10 ��'J la Go MW-t S 6 X, Y 1 5D W-Gt� i9 GD , r REMARKS/SPECIAL INSTRUCTIONS DATA QUALITY OBJECTIVES CHAIN-OF-CUSTODY RECORD MA DEP MCP Data Enhancement Affirmation Regulatory Program Project Specific QC NOTE:All samples submitted subject to Standard Terms and Conditions on reverse hereof. State Standard Deliverables Many regulatory programs and EPA methods require project 4elf ed m r Da a Time R eI cl by: Receipt Temperature: ""YES ONO MCP Data Certification is re aired. specific QC.Project specific QC includes Sample Duplicates, .. ❑CT MCP GW-1/S-1 ❑PWS Form Matrix Spikes,and/or Matrix Spike Duplicates.Laboratory QC Is ❑�-t} o-ieem,ec -`-� ❑YES ONO MCP minimum Field C requirements 'not project specific unless prearranged.Project specific QC j,�Df 5r � ���-N4•6 �6� .� z-s°CR`Qmended Q ❑ME ❑MCP GW-2/S-2 ❑MWRA samples are charged on a per sample basis.Each MS,MSD R in to Time R calved by: Container Count: have been met fcr this project. , (Metals,he::avalert chromium and cyanide analyses ) MA ❑NY STARS ❑ and Sample Duplicate requires an additional sample aliquot. eynJ "^/t//�' �, require one mctri::spiGeper 20 samples) W C-' ,(-6-- 2'/' ❑NH ❑Drinking Water elinq ' ate Time Re efvediby Laboratory: Shipping/Airbill OYES❑NC) MCP Drinking Water samples required. ❑NY ❑Wastewater Project Specific DC Required Selection of OC Sample f r Number.(Require collection o(contingent duplicate samples. I J1 Sa 1 / Trip blanta are also required,if VOA samples collected) ❑RI ❑Waste Disposal ❑Sample Duplicate ❑Please use sample: `� il;h j U TE Buz Main Street,P.O.Box 1200 Buzzards Bay,MA 02532 CHAIN-OF-CUSTODY RECORD ANALYTICAL Telephone(SOt3) analyt41•FAX(508)759-4475 AND WORK ORDER � Rtd� 084864 d'�tl`&% B' www.groundwateranalytical.com Project Name: Firm: TURNAROUND ANALYSIS REQUEST STANDARD(10 Business Days) volatlles semlvalallies PesI Herh PCBs Metals Petroleum Hydrocarbon Haz. General Chemistry Other Project Number: Address: ❑ PRIORITY(5 Business Days) z Esimalaale Vol. - Ext.TPH UOI.TPH waste z A 9 G573 Ma'e,,S�- /Pa �x A-7 El (RAN- ) G � v s = _ (Rush requires Rush Authorization Number) ❑ ❑❑~O y 3' O O Sampler Name City/State/Zip:: --��((2 Please Email to: J I �J „ o I-D�N'UrSYc'l O"J Please FAX to g ST �17 o Q o I o ❑ 8 Project Manager: Telephone: BILLING 2 a t2 s ❑ o a �J�W� (j63o Purchase OrderNo.:Z�Z--�"I.G� a o 2 _ n ❑ Third Party Billing: _ s e ❑ �, INSTRUCTIONS:Use separate line for each container(except replicates). s o E ° m a ❑ a ❑ GWAQuote: o a a d s _ ❑ o o s a o v Sampling - Matrix T e Containers 0 o a o o a o 0 0 0 6 o — — o a = ❑ 6 ❑ Yp O Preservation Flit d o _ LABORATORY 0 SNUMBER pCATIO E Lab Use On - chi aa >E o S rR ❑p O O ❑ ❑ ❑ ❑ ❑ ❑ O❑❑O❑ O ❑ F p ❑ O ❑ ❑ ❑ ❑ O ❑ 0 l3 g G°SAMPLE IDENTFI V2145MV-2- I x �c?M5 M III 1A �i M -2. Xl b3 AT -13 XI M X V ALL 77 7- REMARKS/SPECIAL INSTRUCTIONS DATA QUALITY OBJECTIVES CHAIN-OF-CUSTODY RECORD MA DEP MCP Data Enhancement Affirmation Regulatory Program Project Specific QC NOTE:All samples submitted subject to Standard Terms and Conditions on reverse hereof. .�I State Standard Deliverables Many regulatory programs and EPA methods require project JRellnqu oSp) Date Time Received by: Receipt Temperature: AYES❑NO MCP Data Certification is required. specific OC.Project specific QC includes Sample Duplicates, g AYES ❑CT MCP GW-1/S-1 ❑PWS Form Matrix Spikes,and/or Matrix Spike Duplicates.Laboratory QC is 7+7 0 �� -��T . j -,p ❑me-Et4hngerated DYES❑NO MCP minimum Field QC requirements not project specific unless prearranged.Project specific QC b (� (� I rLl' 2-6-C Recommended p ME ❑MCP GW-?JS-2 ❑MWRA Date Time have been met for Uvs project. samples are charged on a per sample basis.Each MS,MSD Received by: - Container Count: (Metals,hex—lent chromium and cyznideanalyses �MA ❑NY STARS . ❑ and Sample Duplicate requires an additional sample aliquot. �ro I /�c� require one.matrix;spike per 20 samples) ' I V '-( ❑NH El Drinking Water DYES❑NO MCP DrinkinJ,Water samples required, ❑NY ❑Wastewater Date Time Rece'"'(Require collection ofcontingent duplicate samples. Protect Specific OC Required Selection of OC Sample )ved t�y Laboratory: Shipping/Airbill / Number: Trip blanks are also required,if VOA samples collected) ❑RI 0 Waste Disposal ❑Sample Duplicate ❑Please use sample: �' bA 10fpf-6' i s,,Iltr� — GROUNDWATER ANALYTICAL Quality Assurance/Quality Control r 4�K r.`°$a � �: '���" ' ,�;.�� Groundwater Analytical conducts an active Quality Assurance program to ensure the production of high quality, valid data. This program closely follows the guidance provided by Interim Guidelines and Specifications for Preparing Quality Assurance Project Plans, US EPA QAMS-005/80 (1980), and Test Methods for Evaluating Solid Waste, US EPA, SW-846, Update III (1996). Quality Control protocols include written Standard Operating Procedures (SOPS) developed for each analytical method. SOPs are derived from US EPA methodologies and other established references. Standards are prepared from commercially obtained reference materials of certified purity, and documented for traceability. Quality Assessment protocols for most organic analyses include a minimum of one laboratory control sample, one method blank, one matrix spike sample, and one sample duplicate for each sample preparation batch. All samples, standards, blanks, laboratory control samples, matrix spikes and sample duplicates are spiked with internal standards and surrogate compounds. All instrument sequences begin with an initial calibration verification standard and a blank; and excepting GUMS-sequences, all sequences close with a continuing calibration standard. GUMS systems are tuned to appropriate ion abundance criteria daily, or for each 12 hour operating period,whichever is more frequent. Quality Assessment protocols for most inorganic analyses include a minimum of one laboratory control. sample, one method blank, one matrix spike sample, and one sample duplicate for each sample preparation batch. Standard curves are derived from one reagent blank and four concentration levels. Curve validity is, verified by standard recoveries within plus or minus ten percent of the curve. - ssa x 3 -t6 DLInitlOnS� Batches are used as the basic unit for Quality Assessment. A Batch is defined as twenty or fewer samples of the same matrix which are prepared together for the same analysis, using the same lots of reagents and the same techniques or manipulations, all within the same continuum of time, up to but not exceeding 24 hours. Laboratory Control Samples are used to assess the accuracy of the analytical method. A Laboratory Control Sample consists of reagent water or sodium sulfate spiked with a group of target analytes representative of the method analytes. Accuracy is defined as the degree of agreement of the measured value with the true or expected value. Perent Recoveries for the Laboratory Control Samples are calculated to assess accuracy. Method Blanks are used to assess the level of contamination present in the analytical system. Method Blanks consist of reagent water or an aliquot of sodium sulfate. Method Blanks are taken through all the appropriate steps of an analytical method. Sample data reported is not corrected for blank contamination. Surrogate Compounds are used to assess the effectiveness of an analytical method in dealing with each sample matrix. Surrogate Compounds are organic compounds which are similar to the target analytes of interest in chemical behavior, but which are not normally found in environmental samples. Percent Recoveries are calculated for each Surrogate Compound. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Quality Control Report Laboratory Control Sample Category: MA DEP VPH Instrument ID: GC-10 HP 6890 QC Batch ID: VG10-2042-W Analyzed: 02-17-04 09:44 Matrix: Aqueous Analyst: PO Units: ug/L 1634-04-4 Methyl tert-butyl Ether 50 46 93 % 70-130% 71-43-2 Benzene 50 48 95 % 70-130 108-88-3 Toluene 50 51 102 % 70-130% 100-41-4 Ethylbenzene 50 50 100 % 70-130% 108-38-3 and 106-42-3 meta-Xylene and Para-Xylene 100 100 104 % 70-130 95-47-6 ortho- Xylene 50 50 100 % 70-130% 91-20-3 Naphthalene 50 50 101 % 70-130% Q, St frogai" Gompourid 'mot, ' S rke Measured � Recove C�Lrmtts'M P .. w . ma_� Q 2,5-Dibromotoluene(PID) 150 160 105 % 70-130% 2,5-Dibromotoluene(FID) 150 160 107 % 70-130% Method Reference: Method for the Determination of Volatile Petroleum Hydrocarbons,MA DEP(1998). Report Notations: All calculations performed prior to rounding. Quality Control Limits are defined by the methodology, or alternatively based upon the historical average recovery plus or minus three standard deviation units. r Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Quality Control Report Method Blank Category: MA DEP VPH Instrument ID: GC-10 HP 6890 QC Batch ID: VG10-2042-W Analyzed: 02-17-04 10:24 Matrix: Aqueous Analyst: PO VPH Rnges"'_ ," ' Concentration x Notes 4, ' Unrts « Reportingumit'_ >- a - n-05 to n-C8 Aliphatic H drocarbons t° BRL ug/L 20 n-C9 to n-C12 Aliphatic Hydrocarbons to BRL ug/L 20 n-C9 to n-C10 Aromatic Hydrocarbons t BRL ug/L 20 Unadjusted n-05 to n-C8 Aliphatic Hydrocarbons t BRL ug/L 20 Unadjusted n-C9'to n-C12 Aliphatic Hydrocarbons t BRL ug/L 20 Anal e p +t 1 t `Concentratron ` + Notes rUritts Re ortm omit'E CAS.Number - u: 1634-04-4 Methyl tert-butyl Ether° BRL ug/L - 5 71-43-2 Benzene° BRL ug/L 1 108-88-3 Toluene° BRL ug/L 5 100-414 Ethylbenzene t BRL ug/L 5 108-38-3 and 106 a2-3 meta-Xylene and para-Xylene# BRL ug/L 5 95-47-6 ortho- Xylene t BRL ug/L 5 91-20-3 Naphthalene BRL ug/L 5 QC Surrogate,Compound � � .� �Spi+ked r Measured Recover a k �« ,„ 2,5-Dibromotoluene(PID) 100 F..,_ 110 a 110 % 70-130% 2,5-Dibromotoluene(FID) 100 110 111 % 70-130% Method Reference: Method for the Determination of Volatile Petroleum Hydrocarbons,MA DEP(1998). Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting in that range. 0 n-05 to n-C8 Aliphatic Hydrocarbons range data excludes the method target analyte concentrations. ® n-C9 to n-C12 Aliphatic Hydrocarbons range data excludes the method target analyte concentrations and the concentration for the n-C9 to n-C10 Aromatic Hydrocarbons range. rt Analyte elutes in the n-05 to n-C8 Aliphatic Hydrocarbons range. # Analyte elutes in the n-C9 to n-C12 Aliphatic Hydrocarbons range. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GIRQL►IVOWATER ANALYTICAL Quality Control Report Laboratory Control Sample Category: MA DEP EPH Instrument ID: GC-7 HP 5890 QC Batch ID: EP-1326-F Extracted: 02-09-04 18:30 Matrix: Aqueous Analyzed(AL): 02-11-04 12:58 Units: ug/L Analyzed(AR): 02-11-04 13:41 Analyst: WN CAS'-NumbersAnaly#e Y Sprked MeasuredRecouery 33 QyC Lrmtts 111-84-2 n-Nonane(C9) 50 24 49 % 40-140% 629-59-4 n-Tetradecane(C14) 50 30 59 % 40-140% 629-92-5 n-Nonadecane(C19) 50 40 79 % 40-140% 112-95-8 n-Eicosane(C20) 50 41 82 % 40-140% 630-02-4 n-Cctacosane(C28) 50 1 35 70 % 40-140% 1 1 QC Surrogate Compound Spiked aMeasured Recovery QC Lrm)ts � ; Fractionation: 2-Fluorobiphenyl 40 35 87 % 40-140 2-Bromonaphthalene 40 35 87 % 40-140 Extraction: Chloro-octadecane 40 32 80 % 40-140 ortho-Terphenyl 40 33 82 % 40-140 Method Reference: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998). Sample extraction performed by separatory funnel technique. Report Notations: All calculations performed prior to rounding. Quality Control Limits are defined by the methodology, - -- - or alternatively based upon the historical average recovery plus or minus three standard deviation units. Grourdwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 _ I GROUNDWATER ANALYTICAL Quality Control Report Method Blank Category: MA DEP EPH Instrument ID: GC-7 HP 5890 QC Batch ID: EP-1326-F Extracted: 02-09-04 18:30 Matrix: Aqueous Analyzed(AL): 02-11-04 11:36 Analyzed(AR): 02-11-04 12:15 Analyst: WN EPH Ranges -° " �' _,� Concentration Notes ` t Untts�w' Keportmg umiL gym: to n-Cl8 Aliphatic Hydrocarbons t BRL ug/L 500 n-C19 to n-C36 Aliphatic H drocarbons t BRL ug/L 500 n-C11 to n-C22 Aromatic Hydrocarbons t° BRL ug/L 160 Unadjusted n-C11 to n-C22 Aromatic Hydrocarbons t BRL ug/L 160 g . QC Surrogate Compound "'" � �� _ - S eked_ Measured '� Recover Fractionation: 2 Fluorobiphenyl ! 40 32 80 % 40-140% 2-Bromonaphthalene 40 31 78 % 40-140% Extraction: Chloro-octadecane 40 30 76 % 40-140% ortho-Terphenyl 40 31 78 % 40-140% Method Reference: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998). Sample extraction performed by separatory funnel technique. Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting in that range. 0 n-C11 to n-C22 Aromatic Hydrocarbons range data excludes the method target analyte concentrations. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Quality Control Report Laboratory Control Sample Category: EPA Method 8270C(Mod.)-EPH PAHs by GC/MS-SIM Instrument ID: MS-6 HP 6890 QC Batch ID: EP-1326-F Extracted: 02-09-04 18:30 Matrix: Aqueous Analyzed: 02-11-04 10:57 Units: ug/L Analyst: JJT CAS Number _ Anatyte3AWSpiked Measured rRecoveryQ�L';mis 91-20-3 Naphthalene 5.0 3.1 61 % 40-140% 83-32-9 Acenaphthene 5.0 3.5 70 % 40-140% 120-12-7 Anthracene 5.0 4.0 80 % 40-140% 129-00-0 Pyrene 5.0 4.3 87 % 40-140% 218-01-9 Chrysene 5.0 4.1 82 % 40-140% C SurrO dte COm oUn(�k ,��_`c. �f "`�'•-�' is d 9 x--V 7" 'f -� - C� ..,. Q g p t Sptked Measured Recovery s Q L►mttsNNI ortho-Terphenyl 40 33 1 82 % 40�-140 Method Reference: Test Methods for Evaluating Solid Waste,US EPA,SW-846,Third Edition,Update III(1996). Method modified by use of selected ion monitoring(SIM)in accordance with Section 7.5.5 of the method. Method protocol modified to include acidification and the surrogate compound in accordance with the MA DEP Method for the Determination of Extractable Petroleum Hydrocarbons. Sample extraction performed by EPA Method 3510C. Report Notations: All calculations performed prior to rounding. Quality Control Limits are defined by the methodology, or alternatively based upon the historical average recovery plus or minus three standard deviation units. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Quality Control Report Method Blank Category: EPA Method 8270C(Mod.)-EPH PAHs by GC/MS-SIM Instrument ID: MS-6 HP 6890 QC Batch ID: EP-1326-F Extracted: 02-09-04 18:30 Matrix: Aqueous Analyzed: 02-11-04 10:19 Analyst: JJT CAS�Number� AnaJyte ���-* _�� � �, �-<HI Concentrafion :x , a ,.,�; ,'�Nofes;�- � , Umts�� � ReportmgLimif 91-20-3 Naphthalene BRL ug/L 0.5 91-57-6 2-Methylnaphthalene BRL ug/L 0.5 208-96-8 Acenaphthylene BRL ug/L 0.5 83-32-9 Acenaphthene BRL ug/L 0.5 86-73-7 Fluorene BRL ug/L 0.5 85-01-8 Phenanthrene BRL ug/L 0.5 120-12-7 Anthracene BRL ug/L 0.5 206-44-0 Fluoranthene BRL ug/L 0.5 129-00-0 Pyrene BRL ug/L 0.5 56-55 3 Benzo[a]anthracene BRL ug/L 0.1 218-01-9 Chrysene BRL ug/L 0.1 205-99-2 Benzo[b]fluoranthene BRL ug/L 0.1 207-08-9 Benzo[k]fluoranthene BRL ug/L 0.1 50-32-8 Benzo[a]pyrene BRL ug/L 0.1 193-39-5 Indeno[1,2,3-c,d]pyrene BRL ug/L 0.1 53-70-3 Dibenzo[a,h]anthracene BRL ug/L 0.1 191-24-2 Benzo[g,h,ilperylene BRL ug/L 0.1 QC tog?( �Compoun SpLked �Mea ured - Recovery Ltmtts, ortho-Terphenyl 40 30 1 75 % 40-140% Method Reference: Test Methods for Evaluating Solid Waste,US EPA,SW-846,Third Edition,Update III(1996). Method modified by use of selected ion monitoring(SIM)in accordance with Section 7.5.5 of the method. Method protocol modified to include acidification and the surrogate compound in accordance with the MA DEP Method for the Determination of Extractable Petroleum Hydrocarbons. Sample extraction performed by EPA Method 3510C. Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample size and dilution. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Certifications and Approvals Groundwater Analytical maintains environmental laboratory certification in a variety of states. Copies of our current certificates may be obtained from our website: http://www.groundwateranalytical.com/qualifications.htm !+aru z:= amx gxaroxx s r s a .. w a 1 w y 5 u n CONNEGTICUT;Department of HealthaServices,KPH 0586 � � Y �z r Categories: Potable Water,Wastewater,Solid Waste and Soil http://www.d,ph.state.ct.us/BRS/Environmental Lab/OutStateLabList.htm a� � ,�,r.�� ,��� r��,u .��,�sAi'�.� o�� FLORIDA, Department of�Nealth,Bureau of Laboratories E876431, as t,7.`�"c',. -_r.�a?.5...+w�..":.��, ..k-��..xS?.�.sf :i�C.,�..�..,.1'�'";f',a� V,: ,�t E ,�"$�� �k�' * �`�_. Categories:SDWA,CWA, RCRA/CERCLA http://www.fl o ri dadep.o rg/I abs/ga/dohfo rms.htm a. Categories: Drinking Water and Wastewater http://www.state.me.us/dhs/eng/water/Compliance.htm ,x :.� 1 MASSA CHUSETTS, Uepartment of Environmental Protection, gMMA 103 gt Categories: Potable Water and Non-Potable Water http://www.state.ma.us/dep/bspt/wes/fiIes/certlabs.pdf go Y U < p'a m' Z � s ,� NEW HAMPSHIREh�Department of Environmental ervrces, 202703 �- .» � ''�� Categories: Drinking Water and Wastewater http://www.des.state.nh.us/asp/NHELAP/fabsview.asp NEW YORK, Depa tmentof'Healtl%k11754p � �� � ' ,41 Categories: Potable Water, Non-Potable Water and Solid Waste h.ttp://www.wadsworth.org/labcert/elap/comm.htmi b �S'a b ' e art rnw §° . ,,� x PENNSYLVANIA;De artment of�Env�ronme , Protection 68 665� ,w a # z r Te - �r.= Environmental Laboratory Registration (Non-drinking water and Non-wastewater) http://www.dep.state.pa.us/Labs/Regi stered/ k' a re 14` k RH013 f1SLANDDepartment�of Health��54 :' 5 = 3 "S?".,�,.. ' »�. .< < ✓ .i ^.' `"` zi,�3+ ° { 'R y.1:� F" i Pr• g ^r''.� Y S k y%^ .p�a"^m Categories:Surace Water,Air,Wastewater, Potable Water,Sewage http://www.healthri.org/labs/labsCT—MA.htm U S.,D . re Sol ,5<f � " -� �. wf Sao:ePar tmtof rilu A n � a ° Foreign soil import permit VERMONTDe artment of Environmental Conservation ',Water Supply Division s �z�T.sys� p'f�`, �.�"�� ��`s "2 w� .a�. Category: Drinking Water http://www.vermontdrinkingwater.orglwsops/labtable.PDF Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER Groundwater Analytical,Inc. P.O.Box 1200 ANALYTICAL Buz Main Street Buzz Main Bay,MA 02532 Telephone(508)759-4441 February24 2004 FAX(508)759-4475 www.groundwateranalytical.com Mr.John Tadema-Wielandt Bennett& O'Reilly, Inc. P.O. Box 1667 Brewster, MA 02631 LABORATORY REPORT AMENDMENT Project: Hubbard/13002-3490 Lab I D: 61707 Received: 06-04-03 Dear John: Enclosed are the amended analytical results for the above referenced project. - This letter authorizes the release of the analytical results, and should be considered a part of this report. This report contains a sample receipt report detailing the samples received, a project narrative indicating project changes and non-conformances, a quality control report, and a statement of our state certifications. The analytical results contained in this report meet all applicable NELAC standards, except as may be specifically noted, or described in the project narrative. This report may only be used or reproduced in its entirety. I attest under the pains and penalties of perjury that, based upon my inquiry of those individuals immediately responsible for obtaining the information, the material contained in this report is, to the best of my knowledge and belief, accurate and complete. Should you have any questions concerning this report, please do not hesitate to contact me. Sincerely, Jonathan 1 .Sanford President JRS/smd Enclosures GROUNDWATER ANALYTICAL Sample Receipt Report Project: Hubbard/BO02-3490 Delivery: GWA Courier Temperature: 4.2'C Client: Bennett&O'Reilly,Inc. Airbill: n/a Chain of Custody: Present Lab ID: 61707 Lab Receipt: 06-04-03 Custody Seal(s): n/a : 61707-1 MW-5S Aqueous 613/03 10:46 MA DEP VPH with Targets Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C293770 40 mL VOA Vial Fisher BX7655 HC1 R-34496 04-17-03 04-23-03 C293758 40 mL VOA Vial Fisher BX7655 HC1 R-34496 04 17 03 04-23 03 C2937461 40 mL VOA Vial Fisher BX7655. HC1 R-34498 04-17-03 04-23-03 }• -qz: gym; � �. .: F t i 61707-2 MW-51) Aqueous 613/03 11:15 MA DEP VPH with Targets Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C293795 40 mL VOA Vial Fisher BX7655 HC1 R-3449B 04-17-03 04-23-03 C293783 40 mL VOA Vial Fisher BX7655 HC1 R-3449B 04-17-03 04-23-03 C293771 1 40 mL VOA Vial Fisher BX7655 HC1 R-34498 04-17-03 04-23-03 s7 .,.., z #� �` ?g dW` � 4 & a w °., his a3a: ' s 61707-3 MW-65 Aqueous 6/3/03 11:40 MA DEP VPH with Targets Con ID- Container -Vendor QC Lot - -Presery- QC Lot Prep Ship_ C293768 40 mL VOA Vial Fisher BX7655 HC1 R-34496 04-17-03 04-23-03 C293796 40 mL VOA Vial Fisher BX7655 HC1 R-34498 04-17-03 04-23.03 C293773 40 mL VOA Vial Fisher 8X7655 HC1 R-34496 04-17-03 04 23-03 (. > .u'"t._`>7F �r =2,k� .ia� .r, 2•. 0 r`t7 n'. s k:�:$" .x#'� Q� x t ?�.W� t' ate.' �$.. �,o. i at .�+F.s..-a 61707-4 MW-6D Aqueous 613/03 12:05 MA DEP VPH with Targets Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C293785 40 mL VOA Vial Fisher BX7655 HC1 R-34496 04-17-03 04-23-03 C293797 40 mL VOA Vial Fisher BX7655 HC1 R-34496 04-17-03 04-23 03 C293784 40 mL VOA Vial Fisher BX7655 HC1 R-34496 04-17 03 04-23-03 :r�RD.4° ' 'F!., s-�"�'�" T a, '.-,` Fed a',' �I. .M ?'a`.h"'�' "WA � 61707-5 GZA-2 Aqueous .6/3/03 12:30 MA DEP VPH with Targets Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C293774 40 mL VOA Vial Fisher 8X7655 HC1 R-34496 04-17-03 1 04-23-03 C293767 40 mL VOA Vial Fisher BX7655 HC1 R-34496 04-17-03 1 04-23-03 C293755 40 mL VOA Vial Fisher BX7655 HCI R-34498 04-17-03 04-23-03 _ ...:_ ...:. a .. ... .. .. .... :d.;s..:.;,`:•' 1y"'aih.>.:+2"'i���'�•i.%t::C':-'f N;x�il :S'_, _ _ ,.ka4ffl_ .F.eld�3.-. :a�,:.•_,;a >s�?, :.�`t- _!nlrl� e�_....z., .�;•'.:r;,.,-- 61707-6 MW-55 Aqueous <6/3/03 10:46'MA DEP EPH with PAHs ConID Container Vendor QC Lot Presery QC Lot Prep Ship C106129 1 L Amber Glass Proline SX7488 H2SO4 R-3519A 04 22-03 04-23-03 C106128 1 L Amber Glass Proline BX7488 H2504 R-3519A 04-22-03 04-23-03 yb. -Irv'{;:,;:,;'�•'>-;: - - - la5= 61707-7 MW-5D Aqueous 6/3/03 11:15 MA DEP EPH with PAHs Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C106131 1 L Amber Glass Proline BX7488 H2504 R-3519A 04-22-03 04-23-03 C1061301 1 L Amber Glass Proline BX7488 H2SO4 R-3519A 04-22-03 04-23-03 Lab.lp: Feld tD; IYI'atriz. Sarrililed, ,:. '.>:[vtettfol ;`:.:: NQfes 61707-8 M'vV-65 Aqueous 6/3/03 11:40 MA DEP EPH with PAHs Con 1 D Container Vendor QC Lot , Presery QC Lot Prep Ship C7061 ZS 1 L Amber Glass Proline BX7488 H2SO4 R-3519A 1 04-22-03 04-23-03 _ C706I20 1 LAmberGlass Proline BX7488 H2504 I R-3519A 1 04-22-03 04-23-03 Groundwater Analytical, Inc., P.O. Box 1200,228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Sample Receipt Report (Continued) Project: Hubbard/13002-3490 Delivery: GWA Courier Temperature: 4.2'C Client: Bennett&O'Reilly,Inc. Airbill: n/a Chain of Custody: Present Lab ID: 61707 Lab Receipt: 06-04-03 Custody Seal(s): n/a 61707-9 rMW-61) Aqueous 6/3/03 12:05 MA DEP EPH with PAHs Can ID Container Vendor QC Lot Presery QC Lot Prep Ship C106124 1 LAmberGlass Praline SX7488 H2504 R-3519A 04-22-03 04-23-03 C106121 1 L Amber Glass Proline BX7488 H2SO4 R-3519A 04-22-03 0.4-23-03 'k:�tak 14"s"ac,�.;'.''•.,� ,�. ,.;:7 �vi. ��` *. s�'�3;�z;,��Jvµ -k-- 1,, ���. ���+ F .. 61707-10 GZA-2 Aqueous 6/3/03 12:30 MA DEP EPH with PAHs Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C106127 1 LAmberGlass Proline BX7488 H2SO4 R-3519A 04-22-03 1 04-23-03 C106126 t LAmberGlass Proline BX7488 H2504 R-3519A 04-22-03 04-23-03 Groundwater Analytical, Inc., P.O. Box 1200,. 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Massachusetts DEP EPH Method Extractable Petroleum Hydrocarbons by GORD Field ID: MW-5S Laboratory ID: 61707-06 Project: Hubbard/0002-3490 QC Batch ID: EP-1225-F Client: Bennett&O'Reilly,Inc. Sampled: 06-03-03 Container: 1 L Amber Glass Received: 06-04-03 Preservation: H2SO4/Cool Extracted: 06-06.03 Matrix: Aqueous Analyzed: 06-11-03 Dilution Factor: Aliphatic.1 Aromatic:1 4 ? n C9 to n-C18 Aliphatic Hydrocarbons BRL ug/L 500 n-C19 to n-Z36 Aliphatic Hydrocarbons BRL ug/L. 500 n-C11 to n-'--22 Aromatic Hydrocarbons BRL ug/L 160 Una us d r-Cl1 to n-C22 Aromatic Hydrocarbons+ BRL ug/L 160 >... ,.. ' g � ' :' : > .gym n� �wQ l 91-20-3 Naphthalene BRL ug/L 10 91-57-6 2-Methyl naphthalene BRL ug/L 5 85-01-8 Phenanthrene BRL ug/L 10 83-32-9 Acenaphthe_ne BRL ug/L 10 86-73-7 Fluorene BRL ug/L 10 208-96-8 Acenaphthylene BRL ug/L 10 120-12-7 Anthracene BRL ug/L 10 206-44-0 Fluoranthene BRL ug/L 10 129-00-0 Pyrene BRL ug/L 10 56-55-3 Benzo[a]anthracene BRL ug/L 10 218-01-9 Chrysene _ BRL ug/L 10 205-99-2 Benzo[b]fluoranthene BRL ug/L 10 207-08-9 Benzo[k]fluoranthene BRL ug/L 10 50-32-8 Benzo[a]pyrene BRL ug/L 10 193-39-5 Indeno[1,2,3-c,d]pyrene BRL ug/L 10 53-70-3 Dibenzo[a,hlanthracene BRL ug/L 10 191-24-2 Benzo[g,h,ilperylene BRL ug/L 10 ..V (t1g., Ok •i=ki1R -t.a., q4� �mf+d r 4. •..; = Fractionation: 2-Fluorobiphenyl 74 % 40-140% 2-Bromonaphthalene 77 % 40-140% Extraction: Chloro-octadecane 68 % 40-140%- ortho-Terphenyl 74 % 40-140% _ 1. Were all QA/QC procedures required by the method followed? Yes 2. Were all iperformancelacceptance standards for the required QA/QC procedures achieved? Yes 3. Were anp significant modifications made to the method,as specified in Section 11.3? No Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompanying signed project cover letter. The accompanying cover letter,project narrative and quality control report are considered part of this data report. Method Reference: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998). Extraction performed utilizing separatory funnel technique. Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample dilution and sample size. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting it that range. 0 n-C11 to n-C22 Aromatic Hydrocarbons range data excludes the method target analyte concentrations. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Massachusetts DEP EPH Method Extractable Petroleum Hydrocarbons by GC/FID Field ID: MW-SD Laboratory ID: 61707-07 . Project: Hubbard/BO02-3490 QC Batch ID: EP-1225-F Client: Bennett&O'Reilly,Inc. Sampled: 06-03-03 Container: 1 L Amber Glass Received: 06-04-03 Preservation: H2SO4/Cool Extracted: 06-06-03 Matrix: Aqueous Analyzed: 06-11-03 ar Dilution Factor: Aliphatic:1 Aromatic:1 n-C9 to n-C18 Aliphatic Hydrocarbons BRL ug/L 500 n-C19 to n-C36 Aliphatic Hydrocarbons BRL ug/L 500 n-C11 to n-C22 Aromatic Hydrocarbons BRL ug/L .160 Unadiusted n-C11 to n C22 Aromatic Hydrocarbons t BRL ug/L 160 Ay 9- ;(` IWO 91-203 Naphthalene BRL ug/L 10 91-57-6 2-Methyl naphthalene BRL ug/L 5 85-01-8 Phenanthrene BRL ug/L 10 83-32-9.- Acenaphthene BRL ug/L 10 86-73_7 Fluorene BRL ug/L __ — 10 208-96-8 Acenaphthylene BRL ug/L 10 120-12-7 Anthracene BRL ug/L 10 206-44-0 Fluoranthene BRL ug/L . 10 129-00-0 Pyrene BRL ug/L 10 56-55-3 Benzo[a]anthracene BRL ug/L 10 218-01-9 Chrysene BRL ug/L 10 205-99-2 Benzo[b]fluoranthene BRL ug/L 10 207-08-9 Benzo[k]fluoranthene BRL ug(L 10 50-32-8 Benzo[a]pyrene BRL ug/L 10 193-39-5 lndeno[1,2,3-c,d]pyrene BRL ug/L 10 53-70-3 Dibenzo[a,h]anthracene BRL ug/L 10 191-24-2 (}�B�ernz�o{[g,h,i]per�[yy�.11ene BRL ug/L 10 4''�y T -��sYt4Y'.. � . p F f��i �x�r5 5. .1 }.n w .:. wN. 'E'�P• �P Fractionation: 2-Fluorobiphenyl 75 2-Bro,nonaphthalene 73 % 40-140%t, Extraction: Chloro-octadecane 67 % 40-140% ortho-Terpheny) 68 % 40-140% • Ya. m .. 1. Were all QA/QC procedures required by the method followed? Yes 2. Were all performancelacceptance standards for the required QA/QC procedures achieved? Ye 3. Were any significant modifications made to the method,as specified in Section 11.3? No Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompanying signed project cover letter. The accompanying cover letter,project narrative and quality control report are considered part of this data report. Method Reference: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998). Extraction performed utilizing separatory funnel technique. Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample dilution and sample size. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting it that range. 0 n-C11 to n-C22 Aromatic Hydrocarbons range data excludes the method target analyte concentrations. Groundwater Analytical, Inc., P.O. Box 1200;228 Main Street, Buzzards Bay,MA 02532 GROUNDWATER ANALYTICAL Massachusetts DEP EPH Method Extractable Petroleum Hydrocarbons by GGFID Field ID: MW-6S Laboratory ID: 61707-08 Project: Hubbard/BO02-3490 QC Batch ID: EP-1225-F Client: Bennett&O'Reilly,Inc. Sampled: 06-03-03 Container: 1 L Amber Glass Received: 06-04.03 Preservation: H2SO4/Cool Extracted: 06-06-03 Matrix: Aqueous Analyzed: 06-11-03 Dilution Factor: Aliphatic:1 Aromatic:1 ter..: .. . .: �,8►` n-C9 to n-C18 Aliphatic Hydrocarbons BRL ug/L 500 n-C79 to n-C36 Aliphatic Hydrocarbons BRL ug/L 500 n-C11 to n-C22 Aromatic Hydrocarbons BRL ug/L 160 nad'us n{-�C11 to n-C22 Aromatic Hydrocarbons BRL ug/L 160 ns). fi 91-20-3 Naphthalene i BRL ug/L 10 91-57-6 2-Methyl naphthalene BRL ug/L 5 85-01-8 Phenanthrene BRL ug/L 10 83-32-9 .Acenaphthene BRL ug/L 10 86-73-7 Fluorene BRL ueL 10 208-96-8 Acenaphthylene BRL ug/L 10 120-12-7 Anthracene BRL ug/L 10 206--44-0 Fluoranthene BRL ug/L 10 129-00-0 Pyrene BRL ug/L 10 56-55-3 Benzo[a]anthracene BRL ug/L 10 218-01-9 Chrysene BRL ug/L 10 205-99-2 Benzo[b]fluoranthene BRL ug/L 10 207-08-9 Benzo[k]fluoranthene BRL ug/L 10 50-32-8 Benzo[a]pyrene BRL ug/L 10 193-39-5 Indeno[1,2,3-c,d]pyrene BRL ug/L 10 53-70-3 Dibenzo[a,h]anthracene BRL ug/L 10 191-24-2 Benzo[g,h,i]perylene BRL ug/L 10 >�(�►^�^��r' �CG-�7.5` ��,5 .'Q�',�, �?F4 6c.•rA2�r..ri s7`;h' ! ,�:..; 1�C1'•'1lsrs...-•..f ..•k Fractiona: tion. 2-F��. luorobiphenyl 85 % 40-140% 2-Bromonaphthalene 90 % 40-140% Extraction: Chloro-octadecane 68 % 40-140 ortho-Terphenyl 83 % 40-140% 1. Were all QA/QC procedures required by the method followed?. Yes 2. Were all performance/acceptance standards for the required QA/QC procedures achieved? Yes 3. Were any significant modifications made to the method,as specified in Section 11.3? No Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompanying signed project cover letter.' The accompanying cover letter,project narrative and guality control report are considered rt of this data report. Method Reference: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998). Extraction performed utilizing separatory funnel technique. Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample dilution and sample size. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting ii that range. 0 n-C11 to n-C22 Aromatic Hydrocarbons range data excludes the method target analyte concentrations. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay,MA 02532 GROUNDWATER ANALYTICAL Massachusetts DEP-EPH Method Extractable Petroleum Hydrocarbons by GGFID Field ID: MW-6D Laboratory ID: 61707-09 Project: Hubbard/BO02-3490 QC Batch ID: EP-1227-F Client: Bennett&O'Reilly, Inc. Sampled: 06-03-03 Container. 1 L Amber Glass Received: 06-04-03 Preservation: H2SO4/Cool Extracted: 06-11-03 Matrix: Aqueous Analyzed: 06-12-03 Dilution Factor: Aliphatic:I Aromatic:I n-C9 to n-C18 Aliphatic Hydrocarbons BRL ug/L 500 n-C19 to n-C36 Aliphatic Hydrocarbons BRL ug/L 500 n-C11 to n C22 Aromatic Hydrocarbons BRL ug/L 160 Una 'us n-C11 to n-C22 Aromatic Hydrocarbons BRL ug/L 160 5� ��bElfl�-s e3r•�. ';r:�"�^,__ �-_:��.� t t � �-� r _ �;�"s:, ` '..�.�$�? ,. �1 91-20-3 Naphthalene BRL ug/L 10 91-57 6 2-Methyl naphthalene BRL ug/L 5 85-01-8 Phenanthrene BRL ug/L 10 83-32-9 Acenaphthene BRL_ ug/L 10 86-73-7 Fluorene BRL ug/L 10 208-96-8 Acenaphthylene BRL ug/L 10 120-12-7 Anthracene BRL ug/L 10 206A4-0 Fluoranthene BRL ug/L 10 129-00-0 Pyrene BRL ug/L 10 56-55-3 Benzo[a]anthracene BRL ug/L 10 218-01-9 Chrysene BRL ug/L 10 205-99-2 Benzo[b]fluoranthene BRL ug/L 10 207-08-9 Benzo[k]fluoranthene BRL ug/L 10 50-32-8 Benzo[a]pyrene - BRL ug/L 10 193-39-5 Indeno[1,2,3-c,d]pyrene BRL ug/L 10 53-70-3 Dibenzo[a,h]anthracene BRL ug/L 10 191-24-2 Benzo[g,h,i]perylene BRL ug/L 10 ..,,. ._....> ..:,:. r�,..��_11:://r+' L :a.: :.'::'.:.:•::..•� ..4.,.:,-�.- ..iw.'.:4;'S? 'u.r.'-n�si�;(Kq:w`�:d:r. ,_...4•- .r.5 •.'.,=>y ��#y }� ..a =QGSo4rro)L 5246t� pN ) tr: B�YY.:< �`M4' o Ike Fractionation: 2-Fluorobiphenyl 79 % 40-140% 2-Bromonaphthalene 83 % 40-140% Extraction: Chloro-octadecane 79 % 40-140% ortho-Terphenyl 83 % 40-140% .. .... n: .. .- - > .. :... ... rip - 1. Were all QA/QC procedures required by the method followed? Yes 2. Were all performance/acceptance standards for the required QA/QC procedures achieved? Yes 3. Were any significant modifications made to the method,as specified in Section 11.3? No Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompanying signed project cover letter. The accompanying cover letter,project narrative and.quality control report are considered part of this data report. Method Reference: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998). Extraction performed utilizing separatory funnel technique. Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyze. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample dilution and sample size. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting it that range. 0 n-C11 to n-C22 Aromatic Hydrocarbons range data excludes the method target analyte concentrations. i Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Massachusetts DEP EPH Method Extractable Petroleum Hydrocarbons by GC/FIE) Field ID: GZA-2 Laboratory ID: 61707-10 Project: Hubbard/8002-3490 QC Batch ID: EP-1227-F Client: Bennett&O'Reilly,Inc. Sampled: 06-03-03 Container: 1 L Amber Gl ass Received: 06-04-03 Preservation: H2SO4/Cool Extracted: 06-11-03 Matrix: Aqueous Analyzed: 06-12-03 Dilution Factor: Aliphatic:I Aromatic:t`1e j n-C9 to n-C18 Aliphatic Hydrocarbons BRL ug/L 500 n-C19 to n-C36 Aliphatic Hydrocarbons BRL ug/L 500 n-CI1 to n-C22 Aromatic Hydrocarbons BRL ug/L 160 Unad'uste n CI to n-C22 Aromatic Hydrocarbons t BRL ug/L I 160 a s t YhyA' - 3 •S ENV '' _ � 91-20-3 Naphthalene BRL ug/L 10 91-57-6 2-Methyinaphthalene BRL ugf.L 5 85-01-8 Phenanthrene BRL ug/L 10 83-32-9 Acenaphthene BRL ug/L 10 86-73-7 Fluorene BRL ug/L 10 208-96-8 Acenaphthylene BRL ug/L 10 120-12-7 Anthracene BRL ug/L 10 206-44-0 Fluoranthene BRL• ug/L 10 129-00-0 Pyrene BRL ug/L 10 56-55-3 Benzo[a]anthracene BRL ug/L 10 218-01-9 Chrysene BRL ug/L 10 205-99-2 Benzo[k]fluoranthene BRL ug/L 10 207-M9 Benzo[k]fluoranthene BRL ug/L 10 50-32-8. Benzo[a]pyrene BRL ug/L 10 193-39-5 Indeno[1,2,3-c,d]pyrene BRL ug/L 10 53-70-3 Dibenzo[a,h]anthracene BRL ug/L 10 191-24-2 Benzo[g,h,i]perylene BRL g ug/L {} 10 ':,: ME:: u�,cnc,{� •:';• :.j �Y r4i - -1. t � � ?;c.," Fractionation. 2-Fluorobiphenyl 83 % 40-140 2-Bromonaphthalene 84 % 40-140% Extraction: Chloro-octadecane 79 % 40-140% ortfio-Terphenyl 85 % 40-140% 1. Were all QA/QC procedures required by the method followed? Yes 2. Were all performancelacceptance standards for the required QA/QC procedures achieved? Yes 3. Were any significant modifications made to the method,as specified in Section 11.3? No Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompanying signed project cover letter. The accompanying cover letter,project narrative and quality control report are considered part of this data report. Method Reference: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998). Extraction performed utilizing separatory funnel technique. Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample dilution and sample size. f Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting it that range. 0 n-C11 to n-C22 Aromatic Hydrocarbons range data excludes the method target analyte concentrations. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 EROUNOWATER ANALYTICAL Project Narrative Project: Hubbard/B002-3490 Lab ID: 61707 Client: Bennett&O'Reilly,Inc. Received: 06-04-03 17:20 .. .:. .. •:..-_.-. .;...-.."::......... ..:,.._.•_ ., - '`..'y. 'lam .... .. ... .. :. ... ........♦ ., .. ..... .t..K E. a:.c .. 1i�F.:� '},r`ai _ _ :`."We..,.:':•``:n�.'a'�''':ai!•� '�<'..'Si'`ai: H.... _.. ...:•..... ......_...:��. :.....f f'__;..�....1.:: +Y' `'�1':+, - _- _t.�j!:F �.I:•�v.�•e.e.+'-{ii!-..>3'E.r.'ay.- ...... .. ...... ..!..... ... ....a.::a a..'•.:• - Y4J,` - - - _ - �.�. Y - - - -5c �n""7x��a..n"1 t��V( �- yJV 4 b" O ?°.. �:^i: -••tt'�+e Sn ��,• -�.' -1?3�f.SK.: tx_l. �5' ,\�( �`<..:vx'� 3,Ai."•:�, �a'y.; The following documentation discrepancies,and client changes or amendments were noted for this project: 1 . Samples 61707-06 through-10 were analyzed by MA DEP EPH with all target analytes,per John Tadema- Wielandt,02-23-04. AQW", fF�.+�'d �Sf,.'1'4r�`k�'�9Xi�.� 5�!�l��l�'��l,��c 3 ct a �s' '• ;:'r`•s;;;. The sample(s)in this project were analyzed by the references analytical method(s),and no method modifications, non-conformances or analytical issues were noted,except as indicated below: 1 . No method modifications,non-conformances or analytical issues were noted. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER RO �� DWATER 228 Main Street,P.O.Box 1200 Sr Yuif'm� �1r a� swards Bay,MA 02532 .CHAIN-OF-CUSTODY RECORD ANALYTICAL Telephone(508)759-4441•FAX(508)759.4475 AND WORK ORDER N9 072632 www.groundwateranalytical.com Project Name: Firm: ' v j ' TURNAROUND ANALYSIS REQUEST I •.')''.'. r rb cea tmxna an a Nar. STANDARD(10 Business Days) ValsWes SeatmWila m le PE I. MatsuiFA TPH wags General Ghemislry ether Project Number: Address: ❑ PRIORITY(5 Business Days) r c ❑ RUSH(RAN- 1 a S 3g n �•, ^ .. (Rush requires Flesh Authorization Number) O O O O in p3 ❑ Sam ler Name: City//State/ZI : o E p P YYtY P ❑Please Email to: . "' r:'.._. .. ✓' Please FAX to: tirlti.. yc+ "a•" o �....'. _ W 2 ❑ Project Manager: Telephone: BILLING a a gg _ D ❑ ❑ ❑ o ❑ ❑ Uo... Vw;, •. XPurchaWOrderNc,: G,�� d 5 A ❑ ❑Third Party Bitting: U s o a D INSTRUCTIONS:Use separate line for each container(except replicates). ❑GWACluote: III IS Sampling Matrix Type Cordalner(s) Preservation Feared a fi I ❑ O D O O O O O O O O li e c ❑ D o 2 g a a fi e 0 5 r 11 O ❑ 5 BAMPLE o ` 3 LABORATORY a ¢ ga ¢ - o ❑ o ❑ IDENTIFlCATION a ``3� s 7� NUMBER $ p a as a a as _ (lab Use Only) ! a1, 1 � j $ a ° g ❑ > 9 is I � € � ❑ ❑O ❑❑❑ ❑O D ❑ a O 0000 O ❑ ❑ O ❑ 6 ❑ O ❑ ❑ O ❑ ❑ O O O D O O 10 REMARKS/SPECIAL INSTRUCTIONS DATA QUALITY OBJECTIVES CHAIN-OF-CUSTODY RECORD Regulatory Program Project Specific OC C. NOTE:All samples submitted subject to Standard Terms and Conditions on reverse hereof. State Standard Deliverables Many regulatory programs and EPA methods require project Rellfquishgp by Sampler: Date Time Received by:f' Receipt Temperature: specific OC.Project specific OC Includes Sample Duplicates, % ❑CT JZMCP GW-1/S-1 ❑PWS Form Matrix Spikes,and/or Matrix Spike Duplicates.Laboratory OC is .s'�t ^y .". '"' %!'/: •. ' / Ok•tsr�ry.rer�e y. ❑ME ❑MCP GW-21S-1 not project specific unless prearranged.Project specific OC ' ' 'a'' """ r"'• r zero n.eommo,aeo Ralinquishe Date Time Received b Container Count: samples are charged on a per sample basis.Each MS,MSD d�+Y� y �XIMA ❑NY STARS ❑ and Sample Duplicate requires an additional sample aliquot ( �. _.-- C ❑NH ❑Drinking Water 4d., /�Lf/ �^— ❑NY ❑Wastewater Project Specific OC Required Selaetion of OC Sample Relinquished by; Date Time Received by Laboratory. ShippinglAirbill ❑RI ❑Waste Disposal ❑Semple Duplicate O Pleeae use temple: Number: Y,413 7 U ❑VT ❑Dredge Material O Matrbt Spike Method of Shipment YGWA Couder❑Express Mall❑Federal Express Custody Seal ❑_ 0 0 Matrix Spike Duplicate {0 UPS 0 Hand 0 Number: SRDUNDWATER Groundwater Analytical,Inc. P.O.Box 1200 ANALYTICAL Buz Main Street Buzzards Bay,MA 02532 Telephone(508)759-4441 February 24 2004 FAX(508)759-4475 ry www.groundwateranalytical.com Mr.John Tadema-Wielandt Bennett&O'Reilly, Inc. P.O. Box 1667 Brewster, MA 02631 LABORATORY REPORT AMENDMENT Project: Hubbard Oil/Brooks Rd./BO02-3490 Lab ID: 60487 Received: 04-25-03 Dear John: Enclosed are the amended analytical results for the above referenced project. This letter authorizes the release of the analytical results, and should be considered a part of this report. This report contains a sample receipt report detailing the samples received, a project - narrative indicating project changes and non-conformances, a quality control report, and a statement of our state certitications. The analytical results contained in this report meet all applicable NELAC standards,except as may be specifically noted, or described in the project narrative. This report may only be used or reproduced in its entirety. I attest under the pains and penalties of perjury that, based upon my inquiry of those individuals immediately responsible for obtaining the information, the material*contained-in this report is, to the best of my knowledge and belief, accurate and complete. Should you have any questions concerning this report, please do not hesitate to contact me. Sincerely, Jonathan R. Sanford President JRS/smd Enclosures i SR13UNDWATER ANALYTICAL ,Sample Receipt Report Project: Hubbard Oil/Brooks Rd./BO02-3490 Delivery: GWA Courier Temperature: 4.5'C Client: Bennett&O'Reilly,Inc. Airbill: n/a Chain of Custody: Present Lab ID• 60487 Lab Receipt: 04-25-03 Custody Seal(s): n/a �. u::, : 11 NINE, 60487-1 MW-5S Aqueous 4/24/03 12:15 MA DEP VPH with Targets Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C255233 40 mL VOA Vial Industrial BX6732 HCI R-3173F 03-03-03 03-07-03 C255222 40 mL VOA Vial Industrial BX6732 HCI R-3173F 03-03-03 03-07-03 C255221 40 mL VOA Vial Industrial I BX6732 I HCI I R-3173F 03-03-03 03-07-03 'i� ...t���•%�.>L _ ':`_ter-:Y:Ott`:•`1.S�w.:t '�Xr��'j_�.,_, ����I� �'` _ ���.t="�=���� 9,�'�u�i�i ,yx� ;\...a,h 60487-2 MW-5D Aqueous 4/24/03 12:45 MA DEP VPH with Targets Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C255174 40 mL VOA Vial Industrial BX6732 HCI R-3173F 03-03-03 03-07-03 C255209 40 mL VOA Vial Industrial BX6732 HCI R-3173F 03-03-03 03-07-03 C2551971 40 ml.VOA Vial Industrial BX6732 HCI R-3173F 03-03-03 03-07-03 +n < U. S F .¢ i - �•ti— ,,,-., a-€f` 3'•x-s sb'4s:a- t $c •axs . �. ;r ` yap, -r ?>ab .rr��z �: e[r��. �1. x sad .t P3�S` •° * y C _.z 60487-3 MW-6S Aqueous 4124/03 13:15 MA DEP VPH with Targets Con ID Container Vendor QC Lot Preseni QC Lot Prep Ship' C255232 40 mL VOA Vial Industrial BX6732 HCI R-3173F 03-03-03 03-07-03 C255220 40 mL VOA Vial Industrial BX6732 HCI R-3173F 03-03-03 03-07-03 C255208 40 mL VOA Vial Industrial BX6732 HCI R-3173F 03-03-03 03-07-03 E604874 u'x;��<'" � 5&�r=`i +�`;��,��MW-6D Aqueous 4/24/03 13:40 MA DEP VPH with Targets Container Vendor QC Lot Presery QC Lot Prep Ship 40 mL VOA Vial Industrial BX6732 HCI R-3173F 03-03-03 03-07-03 40 mL VOA Vial Industrial BX6732 HCI R-3173F 03-03.03 03-07-03 C2552071 40 ml.VOA Vial Industrial BX6732 I HCI I R-3173F 03-03-03 03-07-03 _...., ... .. .. . ...,_ ..�. _..:.�.a.:•:..-• .:.=u.:::-; •�;ai•: - :.••.ih :-YS:.;=:._ .:;� .y.•::'11F•' :_w;•:.;x;`�y`�rj,,, ,.4, �;t': - - -r�a+''.S - S ; ,:1'p -FF�Id`.F[�i::°^:h.,,,;.�; ..�'�. `��_: -'�:. .�:: `-E.,�srv"�'.'=�a'2'•1�.�.�-:.. 1�-,?r:_..���'s z� ..ta2�..��a*.a _ -�,..',, 5`c. 60487.5 GZA-2 _ Aqueous 4/24/03 14:05 MA DEP VPH with Targets Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C255182 40 mL VOA Vial Industrial BX6732 HCI R-3173F 03-03-03 03-07-03 C255218 40 mL VOA Vial Industrial 6X6732 HCI R-3773F 03-03-03 03-07-03 C255206 40 mL VOA Vial Industrial I BX6732 HCI R-3173F 03-03-03 03-07-03 v:. . . ....Fief I .. . .... .... .:,. .. t...,.. . -�1PL.. .�.. - 60487-6 MW-55 Aqueous 4/24/03 12:15 MA DEP EPH with PAHs Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C106696 1 L Amber Glass Proline BX7438 H2504 R-3519A 0411-03 04-23-03 C106695 1 L Amber Glass Proline BX7438 H2SO4 R-3519A 04-11-03 04-23-03 . . ;x Lah.ID. _.. at4p1. :� - - _ - - 60487-7 MW-5D Aqueous 4/24/03 12:45 MA DEP EPH with PAHs Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C106697 1 L Amber Glass Proline BX7438 H2504 R-3519A 04-11-03 04 23-03 C106694 1 L Amber Glass Proline BX7438 H2SO4 R-3519A 04-11-03 04-23-03 Lab'ID. FA Id"ID Matrix, Sampfed. °:.Metlr4(:..: .Notes - 60487-8 MW-6S j Aqueous 4/24/03 13:15 MA DEP EPH with PAHs Con ID Container Vendor QC Lot Presery QC Lot Prep Ship _ C106693 l L Amber Glass Proline BX7438 H2SO4 R-3519A 04-11-03 04-23-03 C106692 I 1 L Amber Glass Proline I BX7438 H2504 R-3519A 04-17-03 04-23-03 I Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay,MA 02532 GRDUNDWATER ANALYTICAL Sample Receipt Report (Continued) Project: Hubbard Oil/Brooks Rd./BO02-3490 Delivery: GWA Courier Temperature: 4.5'C Client: Bennett&O'Reilly,Inc. Airbill: n/a Chain of Custody: Present Lab ID: 60487 Lab Receipt: 04-25-03 Custody Seal(s): n/a {, ,.>-;s• :z 3'v'%ca� :�,t., NFIi07-. ME 60487-9 MW-61) Aqueous 4/24/03 13:40 MA DEP EPH with PAHs Con ID Container I Vendor QC Lot Presery QC Lot Prep Ship C106689 1 L Amber Glass I Proline BX7438 H2504 R-3519A 04-11-03 1 04-23-03 C106690 1 L Amber Glass Proline BX7438 H2SO4 R-3519A 04-11.03 1 04-23-03 l�yyVNPARM 'ter 60487-10 GZA-2 Aqueous 4/24/03 14:05 MA DEP EPH with PAHs Con ID Container T Vendor QC Lot Presery QC Lot Prep Ship C106691 1 L Amber Glass I Proline BX7438 H2SO4 R-3519A 04-11-03 1 04-23-03 C106688 1 LArrberGlass I Proline BX7438 H2SO4 R-3519A 04-11-03 1 04-23-03 a § i-.r• v 4aE[t' et W. atl�. 60487-12 MW-55 Aqueous 4124/0312:15 EPA 60108 Pb Total Con 1D container Vendor QC Lot Prest QC Lot Prep Ship C248194 1 L Plastic n/a n/a HNO3 n/a n/a n/a Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay,MA 02532 GROUNDWATER ANALYTICAL Massachusetts DEP EPH Method Extractable Petroleum Hydrocarbons by GC/FID Field ID: MW-5s Laboratory ID: 60487-06 Project: Hubbard Oil/Brooks Rd./BO02-3490 QC Batch ID: EP-1211-F Client: Bennett&O'Reilly,Inc. Sampled: 04-2"3 Container: 1 L Amber Glass Received: 04-25-03 Preservation: H2SO4/Cool Extracted: 05-07-03 Matrix: Aqueous Analyzed: 05-08-03 �,, Dilution Factor: Aliphatic:1 Aromatic:1 `, Itlla f:.eY wY stfi, �cx ra. da}o;��m1 �.` IM n-C9 to n-C18 Aliphatic Hydrocarbons BRL ug/L 500 n-C19 to n-C36 Aliphatic Hydrocarbons BRL ug/L 500 n-C11 to n-C22 Aromatic Hydrocarbons BRL ug/L 160 Unadjusted n-C11 to n-C22 Aromatic Hydrocarbons t BRL ug/L 160 ��tr-�►'s° um6' "��' ,•��,� . m,t G. �gaSr n3:.?,s��',. ��:' X M10 �h 91-20-3 Naphthalene BRL ug/L 10 91-57-6 2-Methylnaphthalene BRL ug(L 5 85-01-8 Phenanthrene BRL ug(L 10 83-32-9 Acenaphthene BRL ug/L 10 86-73-7 Fluorene BRL ug(L 10 208-96-8 Acenaphthylene BRL ug(L 10 120-12-7 Anthracene BRL ug(L 10 206-44-0 Fluoranthene BRL ug(L 10 129-00-0 Pyrene BRL ug(L 10 56-55-3 Benzo[a]anthracene BRL ug(L 10 218-01-9 Chrysene BRL ug/L 10 205-99-2 Benzo[b]fluoranthene BRL ug(L 10 207-M9 Benzo[k]fluoranthene BRL ug(L 10 50-32-8 Benzo[a]pyrene BRL ug(L 10 193-39-5 Indeno[1,2,3-c,d]pyrene BRL ug(L 10 53-70-3 Dibenzo(a,h]anthracene BRL ug/L 10 191-24-2 Benzo[g,h,i]perylene BRL ug(L 10 :; y, s Fw Fractionation: 2-Fluorobiphenyl 80 % 40-140% 2-Bromonaphthalene 83 % 40-140% Extraction: Chloro-octadecane 72 % 40-140% ortho-Terphenyl 78 % 40-140% } nt.. - C cat o: - �. r�,lff. f., - 1. Were all QA/QC procedures required by the method followed? Yes 2. Were all perforrnancetacceptance standards for the required QA/QC procedures achieved? Yes 3. Were any significant modifications made to the method,as specified in Section 11.3? No Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompanying signed project cover letter. The accompanying cover letter,project.narrative and quality control report are considered part of this data report. Method Reference: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998). Extraction performed utilizing separatory funnel technique. Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample dilution and sample size. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting it that range. o n-C11 to n-C22 Aromatic Hydrocarbons range data excludes the method target analyte concentrations. t Buzzards Bay MA 02532 Groundwater Analytical, Inc., P.O, Box 1200, 228 Main Street, y, GROUNDWATER ANALYTICAL Massachusetts DEP EPH Method Extractable Petroleum Hydrocarbons by GC/FID Field ID: MW-5D Laboratory ID: 60487-07 Project: Hubbard Oil/Brooks Rd./8002-3490 QC Batch ID: EP-1209-F Client: Bennett&O'Reilly,Inc. Sampled: 04-24-03 Container: 1 L Amber Glass Received: 04-25-03 Preservation: H2SO4/Cool Extracted: 05-05-03 Matrix: Aqueous Analyzed: 05-07-03 Dilution Factor: Aliphatic:1 Aromatic:1 n-C9 to n-C18 Aliphatic Hydrocarbons T BRL ug/L 500 n-C19 to n-C36 Aliphatic Hydrocarbons BRL ug/L 500 n-C11 to n-C22 Aromatic Hydrocarbons BRL ug/L 160 ncust n-C11 to n-C22 Aromatic Hydrocarbons' BRL{ ug/L 160 � _. � :`.t�, 91-20-3 Naphthalene BRL ug/L 10 91-57-6 2-Methylnaphthalene BRL ug/L 5 85-01-8 Phenanthrene BRL ug/L 10 83-32-9 Acenaphthene BRL ug/L 10 86-73-7 Fluorene BRL ug/L 10 - 208-96-8 Acenaphthylene BRL ug/L 10 120-12-7 Anthricene BRL ug/L 10 206-44-0 Fluoranthene BRL ug/L 10 129-00-0 Pyrene BRL ug/L 10 56-55-3 Benzo[a]anthracene BRL ug/L 10 218-01-9 Chrysene BRL ug/L 10 205-99-2 Benzo[b]fluoranthene BRL ug/L 10 207-08-9 Benzo[k]fluoranthene BRL ug/L 10 50-32-8 Benzo[a]pyrene BRL ug/L 10 193-39-5 Indeno[1,2,3-c,d]pyrene BRL ug/L 10 53-70-3 Dibenzo[a,h]anthracene BRL ug/L 10 191-24-2 Benzo[g,h,i]perylene BRL ug/L 10 i0 ttre gaff q 09 tai ;: M 'iA� ' 05, Fractionation: 2-Fluorobiphenyl 80 % 40-140% 2-Bromonaphthalene 76 % 40-140% Extraction: Chloro-octadecane 77 % 40-140% ortho-Terphenyl 90 % 40-140% 7.77 - . .<..rQL�Q�-.. .. ftcatt 1. Were all QA/QC procedures required by the method followed? Yes 2. Were all performancelacceptance standards for the required QA/QC procedures achieved? Yes 3. Were any significant modifications made to the method,as specified in Section 11.3? No Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompanying signed project cover letter. The accompanying cover letter,project narrative and quality control report are considered part of this data report. Method Reference: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998). Extraction performed utilizing separatory funnel technique. Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample dilution and sample size. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting it that range. 0 n-C11 to n-C22 Aromatic Hydrocarbons range data excludes the method target analyte concentrations. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay,MA 02532 GROUNDWATER ANALYTICAL Massachusetts DEP EPH Method Extractable Petroleum Hydrocarbons by GOOD Field ID: MW-6S Laboratory ID: 60487-08 Project: Hubbard Oil/Brooks Rd./BO02-3490 QC Batch ID: EP-1209-F Client: Bennett&O'Reilly,Inc. Sampled: 04-24-03 Container: 1 L Amber Glass Received: 04-25-03 Preservation: H2SO4/Cool Extracted: 05-05-03 Matrix: Aqueous Analyzed: 05-07-03 Dilution Factor: Aliphatic:1 Aromatic:1 `'%��I�il�lt,$C&C�„'� ,�.:�:'��G �i.Y'��"•.=<S�.v�"`r�`a"mac � ev_,. � ��,f F�.�., � �Q �c�l�l n-C9 to n-C18 Aliphatic Hydrocarbons BRL ug/L w 500 n-C19 to n:C36 Aliphatic Hydrocarbons BRL ug/L 500 n-C11 to n-C22 Aromatic Hydrocarbons BRL ug/L 160 Unad' n7C11 to n-C22 Aromatic Hydrocarbons BRL ug/L 160 §�f`AS y r„ r91 4 WIN 91-20-3 Naphthalene BRL ug/L 10 91-57-6 2-Methyl naphthalene BRL ug/L 5 85-01-8 Phenanthrene BRL ug/L 10 83-32-9 Acenaphthene BRL ug/L 10 86-73-7 Fluorene BRL ug/L 10 208-96-8 Acenaphthylene BRL ug/L 10 120-12-7 Anthracene BRL ug/L 10 20644-0 Fluoranthene BRL ug/L 10 129-00-0 Pyrene BRL ug(L 10 56-55-3 Benzo[a]anthracene BRL ug(L 10 218-01-9 Chrysene BRL ug/L 10 205-99-2 Benzolb]fluoranthene BRL ug/L 10 207-08-9 Benzo[k]fluoranthene BRL ug/L 10 50-32-8 Benzo[a]pyrene BRL ug/L 1 10 193-39-5 Indeno[1,2,3-c,d]pyrene BRL ug(L 10 53-70-3 Dibenzo[a,h]anthracene BRL ug/L 10 191-24-2 Benzo[g,h,i]perylene BRL ug(L 10 �.' -h (gym .:.. 4 Fractionation: 2-Fluorobiphenyl 85 % 40-140% 2-Bromonaphthalene 83 % 40-140% Extraction: Chloro-octadecane 77 % 40-140% ortho-Terphenyl 90 % 40-140 Q 14 - f� tltt�atto i 1. Were all QA/QC procedures required by the method followed? Yes 2. Were all,performance/acceptance standards for the required QAIQC procedures achieved? Yes 3. Were any significant modifications made to the method,as specified in Section 11.3? No Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompanying signed project cover letter. The accompdnying cover letter,project narrative and quality control report are considered part of this data report. Method Reference: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998). Extraction performed utilizing separatory funnel technique. Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample dilution and sample size. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting it that range. 0 n-C11 to n-C22 Aromatic Hydrocarbons range data excludes the method target analyte concentrations. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWA70ER ANALYTICAL Massachusetts DEP EPH Method Extractable Petroleum Hydrocarbons by GGFID Field ID: MW-613 Laboratory ID: 60487-09 Project: Hubbard Oil/Brooks Rd./BO02-3490 QC Batch ID: EP-1209-F Client: Bennett&O'Reilly,Inc. Sampled: 04-24-03 Container: 1 L Amber Glass Received: 04-25-03 Preservation: H2SO4/Cool Extracted: 05-05-03 Matrix: Aqueous Analyzed: 05-07-03 Dilution Factor. Aliphatic:1 Aromatic:1 n-C9 to n-C18 Aliphatic Hydrocarbons BRL ug/L Soo n-C19 to n-C36 Aliphatic Hydrocarbons BRL ug/L 500 n-C11 to rt-C22 Aromatic Hydrocarbons 190 ug/L 160 n d'us n-C11 to n-C22 Aromatic Hydrocarbons t 190 ug/L 1 160 ,��`5�ta[ �e� . .,. ���F> � $tom" ` ,;c,�"- �� ��. '� >-•_ � �: 91-20-3 Naphthalene BRL ug/L 10 91-57-6 2-Methyl naphthalene BRL ug/L 5 85-01-8 Phenanthrene BRL ug/L 10 83-32-9 Acenaphthene BRL ug/L 10 86-73-7 Fluorene BRL ug/L 10 -- 208-96-8 Acenaphthylene BRL ug/L 10 120-12-7 Anthracene BRL ug/L 10 206-44-0 Fluoranthene BRL ug/L 10 129-00-0 Pyrene BRL ug/L 10 56-55-3 Benzo[a]anthracene BRL ug/L 10 218-01-9 Chrysene BRL ug/L 10 205-99-2 Benzo[b]fluoranthene BRL ug/L 10 207-08-9 Benzo[k]fluoranthene BRL ug/L 10 50-32-8 Benzo[a]pyrene BRL ug/L 10 193-39-5 Indeno[1,2,3-c,d]pyrene BRL ug/L 10 53-70-3 Dibenzo[a,h]anthracene BRL ug/L 10 191-24-2 Benzo[g,h,i]perylene BRL ug/L 10 Q �l60 Fractionation: 2-Fluorobiphenyl 82 % 40-140% 2-Bromonaphthalene 80 % 40-140% Extraction: Chloro-octadecane 79 % 40-140% ortho-Terphenyl 87 % 40-140% 1. Were all QA/QC procedures required by the method followed? Yes 2. Were all performancelacceptance standards for the required QA/QC procedures achieved? Yes 3. Were any significant modifications made to the method,as specified in Section 11.3? No Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompanying signed project cover letter. The accompanying cover letter,project narrative and quality control report are considered part of this data report. Method Reference: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998). Extraction performed utilizing separatory funnel technique. Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample dilution and sample size. t Hydrocarbon range data excludes concentrations of any surrogate(s)andlor internal standards eluting it that range. 0 n-Ct 1 to n-C22 Aromatic Hydrocarbons range data excludes the method target anaMe concentrations. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Massachusetts DEP EPH Method Extractable Petroleum Hydrocarbons by GC/FID Field ID: GZA-2 Laboratory ID: 60487-10 Project: Hubbard Oil/Brooks Rd./8002-3490 QC Batch ID: EP-1209-F Client: Bennett&O'ReiAy,Inc. Sampled: 04-24-03 Container: 1 L Amber Glass Received: 04-25-03 Preservation: H2SO4/Coot Extracted: 05-05-03 Matrix: Aqueous Analyzed: 05-07-03 Dilution Factor: Aliphatic:I Aromatic:1 96, fP Ranges 'u`v2 � ' n-C9 to n-C18 Aliphatic Hydrocarbons BRL ug/L 500 n-C19 to n-C36 Aliphatic Hydrocarbons BRL ug/L 500 n-C11 to n-C22 Aromatic Hydrocarbons BRL ug/L 160 Un 'us ed n C11 to n-C22 Aromatic Hydrocarbons BRL ug/L 160 �AStNum r -,-;�,ti�s�-. �q� •�.:�ax- .x_�,. �. � .�-:�: -or, 91-20-3 Naphthalene BRL ug/L 10 91-57-6 2-Methyl naphthalene BRL ug/L 5 85-01-8 Phenanthrene BRL ug/L 10 83-32-9 Acenaphthene BRL ug/L 10 86-73-7 Fluorene BRL ug/L 10 208-96-8 Acenaphthylene BRL ug/L 10 120-12-7 Anthracene BRL M/L 10 206-44-0 Fluoranthene BRL ug/L 10 129-00-0 Pyrene BRL ug/L 10 56-55-3 Benzo[a]anthracene BRL ug/L 10 218-01-9 Chrysene BRL ug(L 10 205-99-2 Benzo[blfluoranthene BRL ug/L 10 20768-9 Benzo[k]fluoranthene BRL ug/L 10 50-32-8 Benz)Ialpyrene BRL ug/L 10 193-39-5 lndeno[1,2,3-c,d]pyrene BRL ug/L 10 53-70-3 Dibenzo[a,h]anthracene BRL ug/L 10 191-24-2 Benzo[g,h,i]perylene BRL ug/L 10 Fractionation: 2-Fluorobiphenyl 79 % 40-140 2-Bromonaphthalene 79 % 40-1`0% Extraction: Chloro-octadecane 77 % 40-140% ortho-Terphenyl 94 % 40-140% Y' P: r . 1. Were all QA/QC procedures required by the method followed? Yes 2. Were all performance/acceptance standards for the required QA/QC procedures achieved? Yes 3. Were any significant modifications made to the method,as specified in Section 11.3? No Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompanying signed project cover letter. The accompanying cover letter,project narrative and quality control report are considered part of this data report. Method Reference: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998). Extraction performed utilizing separatory funnel technique. Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample dilution and sample size. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting it that range. 0 n-C11 to n-C22 Aromatic Hydrocarbons range data excludes the method target analyte concentrations. f Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay,MA 02532 UNDWATER ANALYTICAL Project Narrative Project: Hubbard Oil/Brooks Rd./BO02-3490 Lab ID: 60487 Client: Bennett&O'Reilly,Inc. Received: 04-25-03 13:15 cFMen t. `'• � �4,n 4 •yG('' 4 s y'c. 4 i :::i'..",�.`::a'••:. '.:... "1,'J.,v' h'�.,Ss:�t" 4.. 'tY'..: 'fw 3 j:��'i^`k'va.� rve�.�•': :o;t+a l..�`. �.Y The following documentation discrepancies,and client changes or amendments were noted for this project: 1 . Samples 60487-06 through-10 were analyzed by MA DEP EPH with all target analytes,per John Tadema- Wielandt,02-24-04. •:{., ��A♦i�tjiabdffr�a�to ,.� 0 � hr1iICt��{.�n,�tk3 ��,va1'<I .�,�1 -h,s�'`'��`� E,>w �i.�..?.. The sample(s)in this project were analyzed by the references analytical method(s),and no method modifications, non-conformances or analytical issues were noted,except as indicated below: t . No method modifications,non-conformances or analytical issues were noted. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay,MA 02532 228 Main Street,P.O.Box 1200 GRCIUN13WATER Buzzards Bay,MA 02532 CHAIN-OF-CUSTODY RECORD/�® Telephone(508)759-4441 AND WORK ORDER N_o 066458 ANALYTICAL FAX(508)759-4475 Project Name: Firm: TURNAROUND ANALYSIS REQUEST volatlles semhollulls Pe e s Metnit Pn om rreoa et. Gonerel Chemistry Other STANDARD(10 Business Days) date Project Number: Address: e s ' r^ p PRIORITY(5 Business Days) too �'�L(o ,��� MCC,t. Cl RUSH(RAN. (Rush requires Rush AulhortzaWn Number) Sampler Name: City/State/Zip: m $ A E Please FAX ''f1l YES.7 ❑NO ) s� 02z1 FAX Number: g ft�'={6�7 w _ 6 ° Project Manager: Telephone: BILLING 0 0 0 0 0 0 0 Z1 th € o S Purchase Order NO.: GWA Reference No.: a ❑ 3 a 0 1 INSTRUCTIONS:Use separate line for each container(except replicates). � � € S d ° o F'0 o Sampling Matrix Type Container(s) Preservation o o b ❑ o o a o ❑ ❑ 01 10 e g ° s $ ❑ $SAMPLEg14111� LABORATORY s S � gg o $ 3 e ❑ � o ER IDENTIFICATION E g a _ (Lab USId A Only) a € $`_ $ i3 $ o ° 5_ w It G m ps � z _ x °2NUM 8 )5 h $ ce ''s �" 73 R ski iT'$ �f $ �� G L 0 ❑ a ❑ ❑ o ❑ 0 0 0 a 0 0 0 o D ❑ B ❑ ❑ ❑ o ❑ ❑ ❑ ❑ ❑ ❑ ❑' o 46, I:6 S 3 2- 1 n >c 1 ,45 [, 3 zi 1 3 Z 5 3 Z 3 Z 3 0 iio A W -C, I X V, 3 171 lZi `i ?:n x -Z Z REMARKS/SPECIAL INSTRUCTIONS DATA QUALITY OBJECTIVES CHAIN-OF-CUSTODY RECORD Regulatory Program Project SpLwiflc QC A 464:All sampl s submitted subject to Standard Terms and Conditions on reverse hereof. ❑Safe Drinking Water Act Many regulatory programs and EPA methods require project R u d or: at Time Received by Receipt Temperature: ❑MA DEP Form specific QC.Project specific QC includes Sample duplicates, Q T ❑NPDES/Clean Water Act Matrix Spikes,and/or Matrix Spike Duplicates.Laboratory QC is i ll� � l(t / Specify State: not project specific unless prearranged:Project specific QC ❑RCRA/Haz.Waste Char. samples are charged on a per sample basis.For water samples, eli '/ D e Time Recely d by: ShipNum B/AI ii MA MCP(310 CMR 40) each MS,MSD and Sample Duplicate mgUires an additional Reportable Concentrations sampte aliquot. 116 �(RCGW-1 ❑RCS-1 Project Specific QC Required beloctlon of OC Sample R lin4uls by' Date Time,��Ce cjW Laboiato Custo Seal/. ❑RCGW-9❑RCS-2 ❑Sample Duplicate ❑Selected by laboratory �Qµ���,•_,J �s �%5 %/J�— NumbeCooler Serial ❑MA Dredge Disposal ❑Matrix Spike O Please use sample: ❑NH❑RI O CT ME Method of Shipment:XGWA Courier❑Express Mail❑Nderal Express Specify Category: o Mudd'Spike 0uphowe ❑UPS O Hand❑ t GROUNDWATER Groundwater Analytical,Inc. P.O.Box 1200 ANALYTICAL Buz Main Street Buzzards Bay,MA 02532 Telephone(506)759.4441 February 24, 2004 FAX(508)759-4475 www.groundwateranalytical.com Mr.John Tadema-Wielandt Bennett& O'Reilly, Inc. P.O. Box 1667 Brewster, MA 02631 LABORATORY REPORT AMENDMENT Project: Hubbard Oil; Brooks Rd./BO02-3490 Lab ID: 57880 Received: 01-28-03 Dear John: Enclosed are the amended analytical results for the above referenced project. This letter authorizes the release of the analytical results, and should be considered a part of this report. This report contains a sample receipt report.detailing the samples received, a project narrative indicating project changes and non-contormances, a quality control report, and a statement of our state certifications. The analytical results contained in this report meet all applicable NELAC standards, except as may be specifically noted, or described in the project narrative. This report may only be used or reproduced in its entirety. attest under the pains and penalties of perjury that, based upon my inquiry of those individuals immediately responsible for obtaining the information, the material contained in this report is, to the best of my knowledge and belief, accurate and complete. Should you have any questions concerning this report, please do not hesitate to contact me. Sincerely, WO Jonathan R. Sanford President J RS/smd Enclosures I I GROUNDWATER ANALYTICAL Sample Receipt Report(Continued) Project Hubbard Oil Brooks Rd./8002-3490 Delivery: GWA Courier Temperature: 2.9'C Client: Bennett&O'Reilly,Inc. Airbill: n/a Chain of Custody: Present Lab ID: 57880 Lab Receipt: 01-28-03 Custody Seal(s): n/a 57880 10 MW-613 Aqueous 1127103 15:00 EPA 8011 EDB Con ID Container Vendor QC,Lot Presery QC Lot Prep Ship C204255 40 mL VOA Vial I Industrial I SX6221 HCI IR-3173F 12-17-02 n/a s (d not P. t �e A ." . . X 0W o ,h .. 57880-11 GZA-2 Aqueous 1/27/03 15:50 EPA 8011 EDB Con ID Container I Vendor I QC lot I Presery I QC Lot I Prep Ship C204266 40 mL VOA Vial I Industrial I BX6221 I HCI R-3173F 1 12-17-02 1 n/a MINE,1•r1" �.+. sew , � ..+a_.' r �' w,+,, r-Y�..t:«-. �',. zl.. 5�•� ' 57880-12 MW-5S Aqueous 1/27/03 13:00 EPA 6010E Pb Total Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C103022 1 L Plastic Proline BX3795 HNO3 R-3236E 05-15-02 OS-15-02 " i:1...Y:. � 57880-13 MW-51) Aqueous 1/27/03 13:30 EPA 6010E Pb Total— Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C103D25 1 L Plastic I Proline BX3795 HNO3 R-3236E OS 15-02 05-15-02 c�u°.", a�C •-".:w,k - sn}'�S, C. -s•Ax w x,^ a,. t, 0 -,;a^ H`'�''.l�-" L'',,, 'a. av F is' el t rar'ni:; :-%,• rut i f z 1 t r ry; 57880-14 MMW-6S Aqueous 1/27J03 14:20 EPA 6010E Pb Total Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C107946 1.L Plastic Proline BX3794 HNO3 ft-3236E OS 15-02 05-15-02 :TE!�id1t�1 = �p, a r.-s..`.? '.`x�n: 57880-15 MW-613 Aqueous 1127/03 15:00 EPA 60108 Pb Total Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C103032 1 L Plastic Proline BX3 r95 HNO3 R-3236E OS 15-02 OS-15 02 >`,; �.�., `»,_i�,M j _3z ,.,a}}- p:'-trfp- �rii.;��r.i: �. �..:3�Y'��,E;`,,.N��, , �, A � ?✓r..,�;��.;�¢s�;,'. �i€•;�`� . `Flptit:�Q:q`:i°;'j� 1 �trt _ �m '�tm-i7"'. _ rsr �� lut.r<r__, •ti`' 4 .� fl .3. 57880-16 GZA-2 Aqueous 1/27/03 15:50 EPA 60106 Pb Total Con ID Container Vendor QC Lot I Presery QC Lot Prep Ship C103004 1 L Plastic Proline BX3795 I HNO3 R-3236E OS 15-02 05-15-02 _ :::ter_ _ <;� zcf 'r,�_• - 57880.17 MW-55 Aqueous 1/27/03 13:00 MA DEP EPH with PAHs Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C256305 1 L Amber Glass Proline BX6205 H2SO4 R-34756 12-04-02 n/a C256301 1 L Amber Glass I Proline BX6205 H2SO4 R-34756 12-04-02 n/a m - - 57880.18 MW-51) Aqueous 1/27l03 13:30 MA DEP EPH with PAHs Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C256229 1 L Amber Glass Proline BX6180 H2SO4 R-34756 12,13-02 n/a C256225 1 L Amber Glass Proline BX6180 H2504 R-34758 12.13-02 n/a Lab ID Aal ,tp ;..:. INat[ix Sartr{iled._' 77-7 �INe4Ho%1 .... . Notes;':. 57880-19 MW-65 Aqueous 1/27/03 14:20 IMA DEP EPH with PAHs Con ID Container Vendor QC lot Presery QC Lot Prep Ship i C2s6304 1L Amber Glass Proline BX6205 H2SO4 R-34756 12.04-02 n/a C256300 1 L Amber Glass I Proline BX6205 H2SO4 R-3475B 12-04-02 n/a Groundwater Analytical, Inc., P.O. Box 1200,228 Main Street, Buzzards Bay,MA 02532 GROUNDWATER ANALYTICAL Sample Receipt Report Project: Hubtard Oil Brooks Rd./BO02-3490 Delivery: GWA Courier Temperature: 2.9'C Client: Bennett&O'Reilly,Inc. Airbill: n/a Chain of Custody: Present Lab ID: 57880 y Lab Receipt: 01-28-03 Custody Seal(s): n/a jl- t' ti•s:A:;S, _�-''e°- _ _ sc. __ - ..� fY. krw`� ._:.0... x= ,t!,x _,1 57880-1 Field Blank Aqueous 1/27/03 11:00 MA DEP VPH with Targets Con ID Container Vendor QC lot Presery QC Lot Prep Ship C204236 40 mL VOA Vial Industrial BX6221 HCI R-3173F 12-17-02 n/a C204284 40 mL VOA Vial Industrial BX6221 HCI R-3173F 12-17-02 n/a C204237 40 mL'VOA Vial Industrial I BX6221 HCI I R-3173F 12-17-02 n/a FJ.r .: 57880 2 MW-55 Aqueous 1/27/03 13:00 MA DEP VPH with Targets Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C140630 40 mL VOA Vial Industrial BX4650 HCI R-3173F 0746-02 07-18-02 C140606 40 mL VOA Vial Industrial BX4650 HCI R-3173F 07-16-02 07-18-02 RM- ` $.. e`a �'- ",.,. e '--' .+,.,.�-53-fi'tx t �' ^- m a'ieEt r j.`+6��a i� 57880.3 MW-5D Aqueous 1/27/03 13:30 IMA DEP VPH with Targets Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C204287 �4OmL VOA Vial Industrial BX6221 HCI R-3173F 12-17-02 n/a -- - - C204288 40 mL VOA Vial Industrial BX6221 HCI R-3173F 12-17-02 n/a llov 7 57880-4 MW-65- Aqueous 1/27/03 14:20 MA DEP VPH with Targets Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C204253 40 mL VOA Vial Industrial BX6221 HCI R-3173F 12-17-02 n/a C204251 40 mL VOA Vial Industrial BX6221 HCI R-3173F 12-17-02 n/a '- rta•IxIQ, ':'."�= 2 `•IQs:_S;e'k,`; `�£` i%: T;Smpld ,:$ Y' Ya. "illNrd-•rw. N r, 57880-5 MW-613 Aqueous 1/27103 15:00 MA DEP VPH with Targets Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C204256 40 mL VOA Vial Industrial BX6221 HCI R-3173F 12-17-02 n/a C204254 40 mL VOA Vial Industrial BX6221 HCI R-3173F 12-17-02 n/a kk, •hs, x rt-.ZK. ., `: 5 ry g..r Latx FD n: :. ie d>!p Ste_ F. SIDE, - 57880.6 GZA 2 Aqueous 1/27/03 15:50 MA DEP VPH with Targets Con ID Container Vendor QC Lot Presery QC Lot I Prep Ship C204267 40 mL VOA Vial Industrial BX6221 HCI R-3173F 12-17-02 n/a C204265 40 mL VOA Vial Industrial BX6221 HCI R-3173F 12-17-02 1 n/a - ::EaCi.tD -...FretdllA. __ _ �:•. n - - - 57880-7 MW-5S Aqueous 1/27/03 13:00 EPA 8011 EDB Con ID Container Vendor QC Lot I Presery I QC Lot Prep Ship C140623 40 mL VOA Vial Industrial BX4650 HCI R-3173F 07-16-02 07-18-02 . ... .. .. ,.. u: a nx- :Sam.led,.. .Mg ,f�s:.•��`� �• - - - 57880-8 MW-51) Aqueous 1127/03 13:30 EPA 8011 EDB Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C204285 40 mL VOA Vial Industrial BX6221 HCI R-3173F 12-17-02 n/a ield'tD : .. Matti.. Sampled.:.;: Lab ID f.. 57880-9 MW-65 Aqueous 1/27/03 14:20 EPA 8011 EDB _ Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C204252 40 mL VOA Vial Industrial BX6221 HCI R-3173F. 12-17-02 n/a Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay,MA 02532 GROUNDWATER ANALYTICAL Sample Receipt Report (Continued) Project: Hubbard Oil Brooks Rd./8002-3490 Delivery: GWA Courier Temperature: 2.9'C Client: Bennett&O'Reilly,Inc. Airbill: n/a Chain of Custody: Present Lab ID: 57880 Lab Receipt: 01-28-03 Custody Seal(s): n/a 57880-20 MW-61) Aqueous 1/27/03 15.00 MA DEP EPH with FAHs Con 1D Container Vendor QC Lot Presery QC lot Prep Ship C256303 1 L Amber Glass Protine BX6205 H2SO4 R-34758 12-04-02 n/a C256299 1 L Amber (yGlass Praline BX6205 H2504 R-3475B 12-0402 n/a & •l•1•`A5 `S _ ^xi' 5"'st fi-?�. Ks�O •.'^t2v"FP�..i>' _.xn '`' 57880-21 GZA-2 Aqueous 1/27/03 15:50 MA DEP EPH with PAHs Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C256232 1 LAmberGlass Praline BX6180 H2SO4 R-3475B 12-13-02 n/a C256294 1 LAmberGlass Proline BX6205 H2504 R-34755 12-04-02 n/a Groundwater Analytical, Inc.;P.O. Box 1200, 228.Main Street,Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Massachusetts DEP EPH Method Extractable Petroleum Hydrocarbons by GC/FID Field ID: MW-55 Laboratory ID: 57880-17 Project: Hubbard Oil Brooks Rd./BO02-3490 QC Batch ID: EP-1167-F Client: Bennett&O'Reilly,Inc. Sampled: 01-27-03 Container: 1 L Amber Glass Received: 01-28-03 Preservation: H2SO4/Cool Extracted: 01-29-03 Matrix: Aqueous Analyzed: 02-01-03 Dilution Factor: Ali phatiic:1 Aromatic:1 r/ - ff ^1dt+� ...._, z2 �...:....w :FS�F.k-1^' I' �i. F• •- n-C9 to n-C18 Aliphatic Hydrocarbons ,= BRL ug/L 500 n-C19 to n-C36 Aliphatic Hydrocarbons BRL ug/L 500 n-C11 to n-C22 Aromatic Hydrocarbons BRL ug/L 160 Una 'u t n-C11 to ri Aromatic Hydrocarbons t BRL ug/L yr��160 i1 p tQ F �- 'a` 4 .-,Ic,T"+3t'W*1.1 91-20-3 Naphthalene BRL ug/L 10 91-57-6 2-Methylnaphthalene BRL ug/L 5 85-01-8 Phenanthrene BRL ug/L 10 83-32-9 Acenaphthene BRL ug/L 10 86-73-7 Fluorene BRL ug/L 10 208-96-8 Acenaphthylene BRL ug/L 10 120-12-7 Anthracene BRL ug/L 10 206-44-0 Fluoranthene BRL ug/L 10 129-00-0 Pyrene BRL ug/L 10 56-55-3 Benzo[a]anthracene BRL ug/L 10 218-01-9 Chrysene, BRL ug/L 10 205-99-2 Benzo[b]fluoranthene BRL ug/L 10 207-08-9 Benzo[k]fluoranthene BRL ug/L 10 50-32-8 Benzo[ajpyrene BRL ug/L 10 193-39-5 Indeno[1,2,3-c,d]pyrene BRL ug/L 10 53-70-3 Dibenzo[a,h]anthracene BRL u L 10 191-24-2 Benzo[g,h,ilperylene BRL ug/L 10 .�.. ±� •]��krP � •k[^��1�'1".' .':j t]r��`,Y�1,� �.Y.4t'.xt tY�@�C(>!V S.� - Yw� �'�.::�'T �31'.-C.A��': YF. Fractionation: 2-Fluorobiphenyl 101 % 40-140% 2-Bromonaphthalene 108 % 40-140% Extraction: Chloro-octadecane 62 % 40-140% ortho-Terphenyl 93 % 40-140% M 1. Were all QA/QC procedures required by the method followed? Yes 2. Were all performance/acceptance standards for the required QA/QC procedures achieved? Yes 3. Were any significant modifications made to the method,as specified in Section 11.3? No Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompanying signed project cover letter. The accompanying cover letter, ro'ect narrative and guality control report are considered part of this data re ort. Method Reference: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998): Extraction performed utilizing separatory funnel technique. Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample dilution and sample size. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting it that range. 0 n-Cl1 to n-C22 Aromatic Hydrocarbons range data excludes the method target analyte concentrations. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay,MA 02532 GRaNDWATER ANALYTICAL Massachusetts DEP EPH Method Extractable Petroleum Hydrocarbons by GC/FID Field ID: MW-513 Laboratory 1D: 57880-18 Project: Hubbard Oil Brooks RdJB002-3490 QC Batch ID: EP-1169-F Client: Bennett&O'Reilly,Inc. Sampled: 01-27-03 Container: 1 L Amber Glass Received: 01-28-03 Preservation: H2SO4/Cool Extracted: 02-03-03 Matrix: Aqueous Analyzed: 02-04-03 Dilution Factor: Aliphatic:1 Aromatic:1 _ s. _ - - ?. .;4 �w :>�•wf b7�I�i n-C9 to n-C18 Aliphatic Hydrocarbons BRL ug/L 530 n-C19 to n-C36 Aliphatic Hydrocarbons BRL ug/L 530 n-C11 to n-C22 Aromatic Hydrocarbons BRL ug/L 170 nad' ist .1-C11 to n C22 Aromatic Hydrocarbons* BRL ug/L 170 91-20-3 Naphthalene BRL ug/L 1.1 91-57-6 2-Methylnaphthalene BRL ug/L 5 85-01-8 Phenanthrene BRL ug/L '11 83-32-9 Acenaphthene BRL ug/L 11 86 73-7 Fluorene BRL ug/L 11 208-96-8 Acenaphthylene BRL ug/L 11 120-12-7 Anthracene BRL ug/L 11 206-44-0 Fluoranthene BRL ug/L 11 129-00-0 Pyrene BRL ug/L 11 56-55-3 Benzo[a]anthracene BRL ug/L 11 218-01-9 Chrysene BRL ug/L 11 205-99-2 Benzo[b]fluoranthene BRL ug/L 11 207-08-9 Benzo[k]fluoranthene BRL ug/L 11 50-32-8 Benzo[a]pyrene BRL ug/L 11 193-39.5 Indeno[1,2,3-c,d]pyrene BRL ug/L 11 53-70-3 Dibenzo[a,h]anthracene BRL ug/L 11 191-24-2 Benzo[&h,j]perylene . BRL ug/L 11 L�,tams'nh-/� .. •,, . 1�''if; r 3' �-,; fay. ?-'• �'�p� �y�� 4.'•'s,"`"Y: ==5-• 'D.g k+!' r. �" �`,yA• g5 �' a y_yY. af4�.,3`a. Fractionation: 2-Fluorobiphenyl 81 % 40-140 2-Bromonaphthalene 97 % 40-140% Extraction: Chloro-octadecane 66 % 40-140% ortho-Terphenyl 77 % 40-140% fir•"._'t .. ::'..�:za�'.v±:::��i:':fi:c:��:ir'��f ....::.... . ...-..•i.�:^:;:';::';i:,' 1. .Were all QA/QC procedures required by the method followed? Yes 2. Were all oerformance/acceptance standards for the required QA/QC procedures achieved? Yes 3. Were any significant modifications made to the method,as specified in Section 11.3? No Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompanying signed project cover letter. The accompanying cover letter,project narrative and quality control report are considered' art of this data report. Method Reference: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998). Extraction performed utilizing separatory funnel technique. Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample dilution and sample size. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting it that range. 0 n-C11 to n-C22 Aromatic Hydrocarbons range data excludes the method target analyte concentrations. Groundwater Analytical; Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GRa NDWATER ANALYTICAL Massachusetts DEP EPH Method Extractable Petroleum Hydrocarbons by GORD Field ID: MW-6S Laboratory ID: 57880-19 Project: Hubbard Oil Brooks Rd./BO02-3490 QC Batch ID: EP-1167-F Client: Bennett&O'Reilly,Inc. Sampled: 01-27-03 Container: 1 LAmber Glass Received: 01-28-03 Preservation: H2SO4/Cool Extracted: 01-29-03 Matrix: Aqueous Analyzed: 02-01-03 Dilution Factor: Aliphatic-1 Aromatic:1 -�F. Kati` ,¢ t• <" �.�_ '�. � ��� . rw- ,. ,.. n-C9 to n-C18 Aliphatic Hydrocarbons BRIL ug/L 500 n-C19 to n-C36 Aliphatic Hydrocarbons BRL ug/L 500 n-C11 to n-C22 Aromatic Hydrocarbons BRL ug/L 160 dust n-C11 to n-C22 Aromatic Hydrocarbons t BRL ug/L 160 91-20-3 Naphthalene BRL ug/L <. p 10 91-57-6 2-Methyl naphthalene BRL ug/L 5 85-01-8 Phenanthrene BRL ug/L 10 83-32-9 Acenaphthene BRL ug/L 10 86-73-7 Fluorene BRL ug[L __ -10 _ 208,96-8 Acenaphthylene BRL ug/L 10 120-12-7 Anthracene BRL ug/L 10 206-44-0 Fluoranthene BRL ug/L 10 129-00-0 Pyrene BRL ug/L 10 56-55-3 Benzo[a]anthracene BRL ug/L 10 218-01-9 Chrysene BRL ug/L 10 205-99-2 Benzo[b]fluoranthene BRL ug(L 10 207-08-9 Benzo[k]fluoranthene BRL ug/L 10 50-32-8. Benzo[a]pyrene BRL ug(L 10 193-39-5 Indeno[1,2,3-c,d]pyrene BRL ug/L 10 53-70-3. Dibenzo[a,h]anthracene BRL ug(L 10 191-24-2 Benzo[g,h,i]perylene BRL ug/Lr 10 a a cmtt rr '�.r'S,tdi�+•� �rA�Vg�Q' .�:4. �.. �.! �_l�$._.:`S.is``P,' +.�?. ._ „��.` ac Fractionation. 2-Fluorobiphenyl 40-140 2-Bromonaphthalene 116 % 40-140 Extraction: Chioromoctadecane 79 % 40-140% ortho-Terphenyl 96 % 40-140.% ......... ........__.. ... .. J...... 5,. a _9- �'};•'1.f,.<i�'• .i?t3:..i_m:re•Yh:r.r�.�i.:?��..�=�,'.'-`r'."�.i:.::.,... 1. Were all QA/QC procedures required by the method followed? Yes 2. Were all perfonnancelacceptance standards for the required QA/QC procedures achieved? Yes 3. Were any significant modifications made to the method,as specified in Section 11.3? No Method non conformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompanying signed project cover letter. The accompanying cover letter,project narrative and quality control report are considered pan of this data report. Method Reference: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998). Extraction performed utilizing separatory funnel technique. Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample dilution and sample size. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting it that range. 0 n-C11 to n-C22 Aromatic Hydrocarbons range data excludes the method target analyte concentrations. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay,MA 02532 GROUNDWATER ANALYTICAL Massachusetts DEP EPH Method Extractable Petroleum Hydrocarbons by GC/FID Field ID: MW-613 Laboratory.ID: 5788420 Project: Hubbard Oil Brooks Rd./BO02-3490 QC Batch ID: EP-1167-F Client: Bennett&O'Reilly,Inc. Sampled: 01-27-03 Container: 1 L Amber Glass Received: 01-28-03 Preservation: H2SO4/Cool Extracted: 01-29-03 Matrix: Aqueous Analyzed: 02-01-03 Dilution Factor: Aliphatic:1 Aromatic:) n-C9 to n-C18 Aliphatic Hydrocarbons BRL ug/L 500r n-C19 to n-C36 Aliphatic Hydrocarbons BRL ug/L 500 n-C11 to n-C22 Aromatic Hydrocarbons BRL ug/L 160 t nadjusted n C11 to n-C22 Aromatic Hydrocarbons t BRL ug/L 160 .* - �46 � 9 •r .:p r ROOM 91-20-3 Naphthalene BRL ug/L 10 91-57-6 2-Methylnaphthalene BRL ug/L 5 85-01-8 Phenanthrene BRL ug/L 10 83-32-9 Acenaphthene_ BRL ug/L 10 86 73-7 Fluorene BRL ug/L 10 208-9&8 Acenaphthylene BRL ug/L 10 120-12-7 Anthracene BRL ug/L 10 206-44-0 Fluoranthene BRL ug/L 10 129-00-0 Pyrene BRL ug/L 10 .56-55-3 Benzo[a]anthracene BRL ug/L 10 218-01-9 Chrysene BRL ug/L 10 205.99-2. Benzo[b]fluoranthene BRL ug/L 10 207-08-9 Benzo[k]fluoranthene BRL ug/L 10 50-32-8 Benzo[a]pyrene BRL ug/L 10 193-39-5 Indeno[.1,2,3-c,d]pyrene BRL ug/L 10 53-70-3 Dibenzo[a,h]anthracene BRL ug/L 10 191-24-2 Benzo[g,h,i]perylene BRL ug/L 10 '=='„':q�;st'•�Q 1��gate _o _st ���.�_ .,=ix�s, "�-���. _, ��. _ »�::ra�: Man AI !g5ii- Fractionation. 2-Fluor6biphenyl 105 % 40-140% 2-Bromonaphthalene 112'% 40-140% Extractions Chloro-octadecane 72 % 40-140% ortho-Terphenyl 97 % 40-140% �; r. ,�,� lItat�Ofi- :j;fi:y:,•�::�`" �5 ?''sF is77 1. Were all QA/QC procedures required by the method followed? Yes 2. Were all performance(acceptance standards for the required QA/QC procedures achieved? Yes 3. Were any significant modifications made to the method,as specified in Section 11.3? No Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompanying signed project cover letter. The accompanying cover letter,project narrative and qmli control report are considered part of this data report. Method.Reference: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP 0998). Extraction performed utilizing separatory funnel technique. Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte_ Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample dilution and sample size. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting it that range. 0 n-C11 to n-C22 Aromatic Hydrocarbons range data excludes the method target analyte concentrations. Groundwater Analytical, Inc., P.O. Box 1200,228 Main Street, Buzzards Bay,MA 02532 GROUNDWATER ANALYTICAL Massachusetts DEP EPH Method Extractable Petroleum Hydrocarbons by GC/FID Field ID: GZA-2 Laboratory ID: 57880-21 Project: Hubbard Oil Brooks Rd./11002-3490 QC Batch ID: EP-1167-F Client: Bennett&O'Reilly,Inc. Sampled: 01-27-03 Container: 1 L Amber Glass Received: 01-28-03 Preservation: H2SO4/Cool Extracted: 01-29-03 Matrix: Aqueous Analyzed: 02-01-03 Dilution Factor: Aliphatic:1 Aromatic:1 n-C9 to n-C18 Aliphatic Hydrocarbons BRL ug/L 530 n-C19 to n-C36 Aliphatic Hydrocarbons BRL ug/L 530 n-Cl l to n-C22 Aromatic Hydrocarbons BRL ug/L 170 lJnadiusted n-C11 to n-C22 Aromatic Hydrocarbons t BRL ug/L 170 01 OR 91-20-3 „ Naphthalene BRL ug/L 11 91-57-6 2-Methyl naphthalene BRL ug/L 5 85-01-8 Phenanthrene BRL ug/L 11 83-32-9_ - -._ Acenaphthene BRL ug/L 11 86-73-7 Fluorene BRL ug/L -- 11 208-96-8 Acenaphthylene BRL ug/L 11 120-12-7 Anthracene BRL ug/L 11 206-44-0 Fluoranthene BRL ug/L 11 129-00-0 Pyrene BRL ug/L 11 56-55-3 Benzo[a]anthracene BRL ug/L 11 218-01-9 Chrysene BRL ug/L 11 205-99-2. Benzo[b]fluoranthene BRL ug/L 11 207-08-9 Benzo[k]fluoranthene BRL ug/L 11 50-32-8 Benzo[alpyrene BRL ug/L 11 193-39-5 Indeno[1,2,3-c,d]pyrene BRL ug/L 11 53-70-3 Dibenzo[a,hlanthracene BRL ug/L 11 191.-24.2 Benzo[g,h,ilperylene BRL I ug/L J11 1 Fractionation. 2-Fluorobiphenyl 105 % 40-140% 2-Bromonaphthalene 111 % 40-140% Extraction: Chloro-octadecane 80 % 40-140% ortho-Terphenyl 92 % 40 140% rocedures^re required b y the method followed? Yes 1. Were all QA/QC p eq Y 2. Were all performance/acceptance standards for the required QA/QC procedures achieved? Yes 3. Were any significant modifications made to the method,as specified in Section 11.3? No Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompanying signed project cover letter. The accompanying cover letter,project narrative and quality control report are considered Mrt of this data r •ort. Method Reference: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998). Extraction performed utilizing reparatory funnel technique. Report Notations: BRL Indicates concentration,if any, is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample dilution and sample size. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting it that range. o n-C11 to n-C22 Aromatic Hydrocarbons range data excludes the method target analyte concentrations. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay,MA 02532 GROUNDWATER ANALYTICAL Project Narrative Project: Hubbard Oil Brooks RdJB002-3490 Lab ID: 57880 Client: Bennett&O'Reilly,Inc. Received: 01-28-03 12:05 .s._ � , � 4 $`�f's'32 zF?'''<<'r� .s'%';;,i•`}.%=r`` ' vz� u .,may _ ,• 't3..r .� .� ,h.r� The following documentation discrepancies,and client changes or amendments were noted for this project: 1 . Samples 57880.-17 through-21 for analysis by MA DEP EPH were filtered prior to analysis as indicated on the Chain of Custody. 2. Samples 57880-17 through-21 were analyzed by MA DEP EPH with all target analytes,per John Tadema- Wielandt,02-23-04. o�t�►�r>qE3<:ad;;�b���#1�4�brl � The sample(s)in this project were analyzed!by the references analytical method(s),and no method modifications, non-conformances or analytical issues were noted,except as indicated below: 1 . No method modifications,non-conformances or analytical issues were noted. I Groundwater Analytical, Inc., P.O. Box 1200,228 Main Street, Buzzards Bay, MA 02532 228 Main Street,P.O.Box 1200 GROLOWWAM Buzzards Bay,MA02$32 CHAIN-OF-CUSTODY RECORD ANALYTICAL Telephone(508)769-"41•FAX(508)7594475 AND WORK ORDER N9 069350 www.groundwateranalyticel.com �,Project Name: Firm: - - TURNAROUNDS ANALYSIS REQUEST i;y).•'1.'./.a �ir_: f:ryy>'.':.- `�t-'' �is:.:n,: .. li f„f;,•:�. ..'.'`.. - ar0 Poaalem omoa Hat. Yotatla feahoWna ❑/gTANDARD(10 Business Days) reelable a1a1s um warts Gene et cdeminry other Project Number, Address: Qf PRIORITY(5 Business Days) e -4 a _7. J ,' !❑ RUSH(RAN- 1 g_ (Rush ragW,es Rush amrortrauan Number) 11 O a a a $ 0 ❑ ,.•� Sampler Name: City?State/Zp: ` ❑Please Email to'• ❑ Y ,y.,. IOaseFAKtO: Sb,'�_`?.,o�-L/��•z o qgg I T ix � 0Pro1ect Manager. lephone: BILLING s ❑ ...•:: ,.;•,�;"r ;r.:.a•.-•...... �V. :; Purchase Order No.: .. t+•r' - 18 ❑Third Party BiiBng a o ° o INSTRUCTIONS:Use separate line for each container(except replicates). ❑GWq Ouote: _ o S t o Sampling Mahix o a a ❑ 0 0 0 a o o$ s 0 n o o a o d e type COMeiner(s) Preservation o e „ ❑ o 3 LABQRATORYSAMPLE ` 8 o a ❑ IDENTIIONa eg❑NUMBER ❑PICT ty►(Lab Use!)IR x ❑w � S � $ � �$ 9 � a md €Ty3 t e 8 S, Ilk : I -FIT REMARKS/SPECIAL INSTRUCTIONS DATA QUALITY OBJECTIVES CHAIN-OF-CUSTODY RECORD Regulatory Program Project Specific¢C NOTE:All samples submitted subject to Standard Terms and Conditions on reverse hereof. •,�,�. _ ,�,,, ...�, „�,,,,. .., State Standard Dellverables Many regulatory programs and EPA methods require project Re(inqutshed by Sampler: Date Time Received¢y:. Receipt Temperature: t -- specific QC.Project specific QC includes Sample Duplicates, ❑CT CP OW-1/S-1 ❑PWS Form Matrix Spikes,and/or Matrix Spike Duplicates.Laboratory OC Is �'�•;:'t;::'` •.- -�.n; i;:;: ,.• ❑ice aruver.ree x - ❑ME f❑`MCP GW-2/S-1 ❑ not project specific unless prearranged.Project specific Op Samples are charged on a per sample basis.Each MS,MSD ReItn uis dMy: eta Time Received by: Container Count ++ ❑MA ❑NY STARS ❑ and Sample Duplicate requires an additional sample aliquot. ' !'J:',' �� `,• ".:i< ❑NH ❑Drinking Water �rV� Il lr'l - ❑NY ❑Wastawater Project Specific OC Required Selection of 0C Sample Relinquished by: Dale Time R Laboratory: Shipping/Alrbill ❑RI 0 Waste Disposal 6 Sample Duplicate 0 Please use Sample., o_ Number: GROUNDWATER/ATER Groundwater Analytical,Inc. P.O.Box 1200 ANALYTICAL Buz Main Street Buzzards Bay,MA 02532 Telephone(508)759-4441 FAX(508)759-4475 February 24, 2004 www.groundwateranalytical.com Mr.John Tadema-Wielandt Bennett &O'Reilly, Inc. P.O. Box 1667 Brewster, MA 02631 LABORATORY REPORT AMENDMENT Project: Hubbard Oil Co. Inc./B002-3490 Lab ID: 55892 Received: 11-05-02 Dear John: Enclosed_are the amended analytical results for the above referenced project. This letter authorizes the release of the analytical results, and should be considered a part of this report. This report contains a sample receipt report detailing the samples received, a project narrative indicating project changes and non-conformances, a quality control report, and a statement of our state certifications. The analytical results contained in this report meet all applicable NELAC standards,except as may be specifically noted, or described in the project narrative. This report may only be used or reproduced in its entirety. attest under the pains and penalties of perjury that, based upon my inquiry of those individuals immediately responsible for obtaining the information, the material contained in this report is, to the best of my knowledge and belief, accurate and complete. Should you have any questions concerning this report, please do not hesitate to contact me. Sincerely, y , Jonathan R. Sanford President JRS/smd Enclosures GROUNDWATER ANALYTICAL Sample Receipt Report Project: Hubbard Oil Co. Inc./B002-3490 Delivery: GWA Courier Temperature: 2.61C Client: Bennett&O'Reilly,Inc. Airbill: n/a Chain of Custody: Present Lab ID: 55892 Lab Receipt: 11-05-02 Custody Seal(s): n/a ICE- (RR)MW-65 Aqueous. 11/4/02 16:15 MA DEP EPH with PAHs Container Vendor QC Lot Presery QC Lot Prep Ship 1 LAmberGlass Proline 13X4505 H2SO4 R-3353C 08-09-02 08-16-02 55892-2 (RR)MW-6D Aqueous 11/4/02 t6.45 MA DEP EPH with PAHs Con ID Container Vendor I QC Lot I Presery QC Lot I Prep Ship C172597 1 L Amber Glass Prali'nee g BX5371 H2504 R-3421C 09-12-02 09-17-02 FJe1fL'-IN 09-5;,y a u�-• '�1 y t,« �.` a. :,',A!„ f ',.'+t Via? '+. w � ,�.5.n, q - a 5 55892-3 (RR)MW-55 R Aqueous 11/4/02 15:30 TPH by GC ASTM D3328-00 Mod Con ID Container Vendor QC Lot Presery QC Lot Prep Ship Ci72593 1 L Amber Class I Proline BX5371 H2504 R-3421C 09-12-02 09-17-02 - r. •�#,lt jF81d• i � _max ��."w ,:;1.. ,, -•e a ';.S `t �;. 55892-4 (RR)MW-5D _ Aqueous 11/4/02 15:30 TPH by GC A5TM D3328-00 Mod Con ID- Container Vendor QC Lot Presery QC Lot Prep Ship C172589 1 LAmberGlass Praline BX5371 N25O4 R-3421C 091202 09-1702 531ai'... :. uj 55892-5 (RR)MW-55 Aqueous 11/4102 15:30 MA DEP VPH with Targets Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C203992 40 mL VOA Vial Industrial BX5470 HCI R-3173F 10-02-02 10-18-02 C203991 40 mL VOA Vial Industrial BX5476 HCI R-3173F 10-02-02 10-18-02 - ,z�l.� 55892-6 (RR)MW-5D Aqueous 1114/02 15:30 MA DEP VPH with Targets Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C203989 40 ml'VOA Vial Industrial BX5470 HCI R-3173F 10-02-02 10-18-02 C203990 40 mt.VOA Vial Industrial BX5470 HCI R-3173F 10-02-02 10.18-02 YY` _v �SiL1�I�Siyt4 � ] 55892-7 (RR)MW-65 Aqueous 11/4/02 16:15 MA DEP VPH with Targets C�[DContainer Vendor QC Lot Presery QC Lot Prep Ship C240 ml VOA Vial Industrial BX5470 HCI R-3173F 10-02-02 10-18-02C240 mL VOA Viat Industrial BX5470 HCI R-3173F 10-02-02 10-18-02 %I�:ID: 'Fi�Id.lD <�• _ IyjdtruS', 5aiii►lj�' ':.��� c=x� `�;,,5''i�'_ -'`.+',�.�`;�''•�,�3#�'�.y o-i+tr, 55892-8 (RR)MW-6D Aqueous 11/4/02 16:45 MA DEP VPH with Targets Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C203983 40 mL VOA Vial Industrial BX5470 HCI R-3173F 10-02 )2 10-18-02 C203982 40 mL VOA Vial Industrial BX5470 HCI R-31 T3F 10-02-02 10-18.02 Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ER ANALYTICAL Massachusetts DEP EPH Method Extractable Petroleum Hydrocarbons by GUND Field ID: (RR)MW-6S Laboratory ID: 55892-01 Project: Hubbard Oil Co. Inc./BO02-3490 QC Batch ID: EP-1131-F Client: Benneft&O'Reilly,Inc. Sampled: 11-04-02 Container: 1 L Amber Glass Received: 11-05-02 Preservation: H2SO4/Cool Extracted: 11-08-02 Matrix: Aqueous Analyzed: 11-11-02 Dilution Factor. Aliphatic:1 Aromatic:1 n-C9 to n-C18 Aliphatic Hydrocarbons BRL ug/L 500 n-C19 to n-C36 Aliphatic Hydrocarbons BRL ug/L Soo n-C11 to n-C22 Aromatic Hydrocarbons BRL ug/L i60_ lnadjpsted n-C11 to n-C22 Aromatic Hydrocarbons t BRL ug/L 160 91-20-3 Naphthalene BRL ug/L " 10 91-57-6 2-Methyl naphthalene BRL ug/L 5 85-01-8 Phenanthrene BRL ug/L 10 83-32-9 Acenaphthene BRL ug/L 10 86-73-7 Fluorene BRL ug/L 10 208-96-8 Acenaphthylene BRL ug/L- 10 120-12-7 Anthracene BRL ug/L 10 206-44-0 Fluoranthene BRL ug/L 10 129-00-0 Pyrene BRL ug/L 10 56-55-3 Benzo[alanthracene BRL ug/L 10 218-01-9 Chrysene BRL ug/L 10 205-99-2 Benzo[b]fluoranthene BRL ug/L 10 207-08-9 Benzo[k]fluoranthene BRL ug/L 10 50-32-8 Benzo[a]pyrene BRL ug/L 10 193-39-5 Indeno[1,2,3-c,d]pyrene BRL ug/L 10 53-70-3 Dibenzo[a,h]anthracene BRL ug/L 10 191-24-2 �1 C Benzo[g,h,i]peryle�n�e: BRL ug/L 10 •��`riaa �s imnyl Fractionation: enyl 93 % %40-140 /ohthalene 92 % 40 140% Extraction: ecane 75 % 40 140% yl 87 % 40-140% 1. Were all Q,A/QC procedures req •y. -hod followed? ?.,; ' ' j-s :;•i.' required b the met � Yes 2. Were all performance/acceptance standards for the required QA/QC procedures achieved? Yes 3. Were any significant modifications made to the method,as specified in Section 11.3? No Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompanying signed project cover letter. The accompanying cover letter,project narrative and quality control report are considered part of this data report. Method Reference: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998). Extraction performed utilizing separatoryfunnel technique. Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample dilution and sample size. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting it that range. 0 n-C11 to n-C22 Aromatic Hydrocarbons range data excludes the method target analyte concentrations. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay,MA 02532 GROUNDWATER ANALYTICAL Massachusetts DEP EPH Method Extractable Petroleum Hydrocarbons by GGFID field ID: (RR)MW-613 Laboratory ID: 55892-02 Project: Hubbard Oil Co. Inc./13002-3490 QC Batch ID: EP-1131-F Client: Bennett&O'Reilly,Inc. Sampled: 11-04-02 Container: 1 L Amber Glass Received: 11-05-02 Preservation: H2SO4/Cool Extracted: 11-08-02 Matrix: Aqueous Analyzed: 11-11-02 Dilution Factor. Aliphatic:1 Aromatic:1 Yr W r _S_5 �.. n-C9 to n-CI8 Aliphatic Hydrocarbons BRL ug(L 500 n-C19 to n-C36 Aliphatic Hydrocarbons BRL ug(L 500 n-C11 to n-C22 Aromatic Hydrocarbons ° BRL ug(L 160 Unadjusted n-C11 to n-C22 Aromatic Hydrocarbons BRL ug(L 160 91-20-3 Naphthalene BRL ug(L 10 91-57-6 2-Methylnaphthalene BRL ug/L 5 85-01-8 Phenanthrene BRL ug(L 10 83-32-9 Acenaphthene BRL ug(L 10 86-73-7 Fluorene BRL ug/L 10 208-96-8 Acenaphthylene BRL ug/L 10 120-12-7 Anthracene BRL ug/L 10 206-44-0 Fluoranthene BRL ug/L 10 129-00-0 Pyrene BRL ug/L 10 56-55-3 Benzo[a]anthracene BRL ug(L 10 218-01-9 Chrysene BRL ug/L 10 205-99-2 Benzo[b]fluoranthene BRL ug/L 10 207-08-9 Benzo[k]fluoranthene BRL ug/L 10 50-32-8 Benzo[a]pyrene BRL ug/L 10 193-39-5 Indeno[1,2,3-c,d]pyrene BRL ug/L 10 53-70-3 Dibenzo[a,.h]anthracene BRL ug/L 10 191-24-2 Ben�zo}[g,h,i]perylene BRL ug/L 10 Fractionation: 2-Fluorobiphenyl 93 % 40-140% 2-B to-monaphthalene 92 % 40-140% Extraction: Chloro octadecane 71 % 40-140% ortho-Terphenyl 87 % 40-140% =;Y3 ...: •.. .. .. .. ',:.'-_.T �:�:r.Fes •, �lk�S:t��.�+M���� )2 -f•'. '. �.�.y{ •' 2:.`4.,'.y7krHe.��. S-:+.+ �'h -�S;e' 1. Were all QA/QC procedures required by the method followed? Yes YL 2. Were all performance(acceptance standards for the required QA/QC procedures achieved? Yes 3. Were any significant modifications made to the method,as specified in Section 11.3? No Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompanying signed project cover letter. The accompanying cover letter,project narrative and quality control report are considered part of this data report. Method Reference: Method forthe Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998). Extraction performed utilizing separatory funnel technique. Report Notations: BRL Indicates concentration, if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample dilution and sample size. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting it that range. 0 n-C11 to n-C22 Aromatic Hydrocarbons range data excludes the method target analyte concentrations. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Project Narrative Project: Hubbard Oil Co. Inc./B002-3490 Lab ID: 55892 Client: Bennett&O'Reilly, Inc. Received: 11-05-02 16:10 _...,. ..4... .. ...,.:..- ._.... .�,`-:'�.�. __ `fir•.. `sc r- 3:' ? s.a ^.:•.%x z�x.,Yet:^ -- �-__' ,A. �lS-L': _- �or:.. ��,'_ s.�.o;i:�>.Y.44 <�.§<�>::z'n: �' S •h.is The following documentation discrepancies,and client changes or amendments were noted for this project- 1 . Samples 55892-01 and-02 were analyzed by MA DEP EPH with all targets,per John Tadema-Wielandt,02-23-04.. .. � q rfd- bs is.':.,' .:,.:•. -..-. .: t� �� ��I�?�� . ��tlfor� �� � # The sample(s)in this project were analyzed by the references analytical method(s),and no method modifications, non-conformances or analytical issues were noted,except as indicated below: 1 . No method modifications,non-conformances or analytical issues were noted. Groundwater Analytical, Inc., P.O. Box 1200,228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER 228 Main Street,P.O.Box 1200 �e i®�9C�A1.0�1 A R Buzzards Bay,MA 02532 CHAIN-OF-CUSTODY RECORD 417 ALYTICAL Telephone(508)759-4441 AND WORK ORDER FAX(58)759-4475 N® 065104 'roject Name: Firm: 0 TURNAROUND ANALYSIS REQUEST 'roject Number: Address: O STANDARD 00 Business Days) retallin semNolaules Peswerwas Metals Pe o1 Her. General Chemistry other -T �5C)Cj�,� `l�i '�y7 A 7 /� �y 1 f PRIORITY(5 Business Days) 1, t t 7 trV(d,th O RUSH(RAN- 1 u 3 a� ampler Name: (Rush requires Rush Authorization Number) O o 0 0 p y (�/ City/State/Zip: a o o s 1 v" / L 6 5 �j t��,S��{{ M Please FAX YESn ❑NO t FAX Number. �e `� �y? E o roject Manager: Telephone: _ _ a // BILLING o 0 0 0 0 0 0 o s Purchase Order ND.: GWA Reference No.: o A a 4STRUCTIONS:Use separate line for each container(except replicates). ��Z'3U�� = a " € $ a 5 #g Y ❑ ❑ ampling Matrix 3 9 $ S I I� e ^ � � a 5 � z°, � o Containar(s) Preservation ❑ ❑ ❑ ❑ ❑ ❑ ❑ ❑ s ' SAMPLE .4 IDENTIFICATION W 5 " ,y LABORATORY .g o ❑ a 'a o e p u w S e g see a NUMBER ��" - a'v o s L N ❑ ❑ g SS3 z55g (Lab Use On ty) g � ai 5 : � m3S �tlaa 5 o s ° e 3 _ r, _ R "mod 0 o a E� � S _ $ >y � a, "sV § sa € oS BEd ° o •zo C .91 �1 o D ❑ ❑ ❑ o ❑ ❑ D a ❑ o ❑ ❑ a ❑ ❑ fi a -1 5 ❑ ❑ ❑ ❑ o a o o a ❑' ❑ 4;IS R Iti1 v- S 3 ------------------- REMARKS/SPECIAL INSTRUCTIONS DATA QUALITY OBJECTIVES I +H*1 I±L CHAIN-OF-CUSTODY RECORD Regulatory Program Project Specific OC ❑Safe Drinking Water Act N E:Ail samples submitted subject to Standard Terms and Co hions on reverse hereof. Many regulatory programs and EPA methods requireproject a t p MA DEP Form a y a r Dat Time Received by: i eceipt Tempe��r NPDES/Cleen Water Act specific QC.Project specific QC includes Sample Duplicates, ! LSD�'ciict Specify State: Matrix Spikes,andor Matra Spike Duplicates,Laboratory QC is aZ�1 jS �1� 2+�ticbsuyts not project specific unless prearranged.Project specific QC , 0 O RCRAMaz.Waste Char. samples are charged on a per sample basis.For water samples, li i ad to Time Rec by: hlpping/Airbfll >51 MA MCP(310 CMR 40) each MS,MSD and Sample Duplicate requires an additional T Reportable Concentrations sample aliquot. � -.L le Number: �ARCGW-1 RCS-1 �} Project Pspecific qC Required selection of DC sample elf I Date Time oratory r�`) Custody Seal/ O RCGW-2❑RCS•2 ❑Sample Duplicate / C Cooler Serial O MA Dredge Disposal P °Selected laboratory j(�f7�U �!U 1 ❑NH❑RI CT ME ❑Matrix Spike ❑Please use sample: .I Number: Specify Caattegory: ❑Matrix Spike Duplicate ethod o 1:❑GWA Courier❑Express Mail ❑ ederal xpress 0 UPS 0 Hand ❑ GROUNDWATER Groundwater Analytical,Inc. P.O.Box 1200 ANALYTICAL Buz Main Street Buzzards Bay,MA 02532 Telephone(508)759-4441 February 24 2004 FAX(508)759-4475 www.groundwateranalytical.com Mr.John Tadema-Wielandt Bennett& O'Reilly, Inc. P.O. Box 1667 Brewster, MA 02631 LABORATORY REPORT AMENDMENT Project: Hubbard Oil/Brooks Rd./B002-3490 Lab ID: 55605 Received: 10-25-02 Dear John: Enclosed are the amended analytical results for the above referenced project. This letter authorizes the release of the analytical results, and should be considered a part of this report. This report contains a sample receipt report detailing the samples received, a project narrative indicating project changes and non-conformances, a quality control report, and a statement of our state certifications. The analytical results contained in this report meet all applicable NELAC standards, except as may be specifically noted, or described in the project narrative. This report may only be used or reproduced in its entirety. I attest under the pains and penalties of perjury that, based upon my inquiry of those individuals immediately responsible for obtaining the information, the material contained in this report is, to the best of my knowledge and belief, accurate and complete. Should you have any questions concerning this report, please do not hesitate to contact me. Sincerely, Jonathan R. Sanford President J RS/smd Enclosures GROUNDWATER ANALYTICAL Sample Receipt Report Project: Hubbard Oil/Brooks Rd./B002-3490 Delivery: GWA Courier Temperature: 4.81C Client: Bennett&O'Reilly,Inc. Airbill: n/a Chain of Custody: Present Lab ID: 55605 Lab Receipt: 10-25-02 Custody Seal(s): n/a .;55605-1 MW4 Aqueous 10/23/02 5:00 MA DEP VPH with Targets 4 Con ID Container Vendor QC Lot Presery QC Lot Prep I Ship C153982 40 mL VOA Vial Industrial BX5257 HCI R-3173F 09-19-02 10-18-02 C153995 40 m'L VOA Vial Industrial BX5257 HCI R-3173F 09-19-02 10-18-02 C153994 40 mL VOA Vial Industrial BX5257 HCI R-3173F 09-19-02 10-18-02 Moot 55605-2 GZA-2 Aqueous 10/23/02 5:30 MA DEP VPH with Targets Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C153983 40 mL VOA Vial. Industrial BX5257 HCl R-3173F 09,19-02 10-18-02 C153971 40 mL VOA Vial Industrial BX5257 HCI R-3173F 09-19-02 10-18-02 C153959 40 mt.VOA Via[ Industrial BX5257 HCI R-3173F 09-19-02 10-18-02 ^, - Field 1[�j .t•:��'�-°''; F:•:- ,� a; -::, r �. �. ra. .✓ .� � .2� ,��r"��� "z 55605-3 GZA-3 Aqueous 1 0/2 3102 5:45 MA DEP VPH with Targets Con ID Container Vendor QC Lot, Presery QC Lot Prep Ship C153970 40 mL VOA Vial Industrial BX5257 HCI R-3173F 09-19-02 10-18-02 - C153958 40 mL VOA Vial Industrial BX5257 HCI R-3173F 09-19-02 10.18-02 C153947 40 mL VOA Vial Industrial BX5257 HCI R-3173F 09-19-02 10-18-02 s:��tD •� t2 . ... ...�•.si,t=�.:-� ,s � 0 3` �' `>�- :,a 7K?11 556054 MW-4 Aqueous 10/23/02 5:00 TPH by GC ASTM D3328-00 Mod Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C172642 1 L Amber Glass Proline BX5376 H2SO4 R-3421C 1 09-12-02 09.17-02 C172647 1 L Amber Glass Proline BX5376 H2504 R-3421C 1 09-12-02 09-17-02 -st.'s•s'.';`'.+- 8},,,ept >- �'£ > apt.,-. t'•s Y._u. {i,",�a �.. .a:: .Ya.S:k����•'��:�•,•��:•%'+-,�. 55605-5 GZA-2 Aqueous 10/23/02 5:30 MA DEP EPH with PAHs Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C172643 1 L Amber Glass Proline BX5376 H2SO4 R-3421C 09-12-02 09-17-02 C172639 1 L Amber Glass Proline BX5376 H2SO4 R-3421C 09-12-02 09-17-02 ::lab If?,t >Fiel�tp� 55605-6 GZA-3 Aqueous 10/23/02 5:45 MA DEP EPH with PAHs Con ID Container Vendor QC Lot g Presery QC Lot Prep Ship C172638 1 L Amber Glass Proline BX5376 H2SO4 R-3421C 09-12-02 09-17-02 C772637 1 LAmberGlass Proline BX5376 H2504 R-3421C 09-12-021 09•17-02 Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay,MA 02532 GROUNDWATER ANALYTICAL Massachusetts DEP EPH Method Extractable Petroleum Hydrocarbons by GOOD Field ID: GZA-2 Laboratory ID: 55605-05 Project: Hubbard Oil/Brooks Rd/B002-3490 QC Batch ID: EP-1126-F Client: Bennett&O'Reilly,Inc. Sampled: 10-23-02 Container 1 L Amber Glass Received: 10-25-02 Preservation: H2SO4/Cool Extracted: 10-28-02 Matrix: Aqueous Analyzed: 10-31-02 Dilution Factor. Aliphatic;I Aromatic 1 n-C9 to n-C18 Aliphatic Hydrocarbons BRL ug/L 500 n-Cl9 to n-C36 Aliphatic Hydrocarbons BRL ug/L 500 n-Cl1 to n-C22 Aromatic Hydrocarbons BRL ug/L 160 Unadjusted n-C11 to n-C22 Aromatic Hydrocarbons t BRL ug/L 160 x�°� �1i77 ert• 1��':�?��.� :gg. a ���'�....�'�: � �.�. -�5;�� .x _ Ctl9lrt_ �`#{gyp ► 91-20-3{ Naphthalene BRL ug(L 10' 91-57-6 2-Methyl naphthalene BRL ug/L 5 85-01-8 Phenanthrene BRL ug/L 10 83-32-9 Acenaphthene BRL ug/L 10 86-73-7 Fluorene BRL ug/L 10 208-96-8 Acenaphthylene BRL ug/L 10 120-12-7 Anthracene BRL ug/L 10 206-44-0 Fluoranthene BRL ug/L 10 129-00-0 Pyrene BRL ug/L 10 56-55-3 Benzo[a]anthracene BRL ug/L 10 218-01-9 Chrysene BRL ug/L 10 205-99-2 Benzo[b]fluoranthene BRL ug/L 10 207-08-9 Benzo[k]fluoranthene BRL ug/L 10 50-32-8 Benzo[a]pyrene BRL ug/L 10 193-39-5 Indeno[1,2,3-c,d]pyrene BRL ug/L 10 53-70-3 Dibenzo[a,h]anthracene BRL ug/L 10 191-24-2 Benzo[g,h,i]perylene BRL ug/L 10 xFractionation: 2-Fluorobiphenyl 67 % 40-140% 2-Bromonaphthalene 60 % 40-140% Extraction: Chloro-octadecane 66 % 40-140% ortho-Terphenyl 78 % 40-140% �.. ..A?F rY.��-n t!T,Yni� e1 a ."9.':.�r .i*�t-`•�:r"'ySb�v:i;'.a:).�i..'�:p': 1. Were all QA/QC procedures required by the method followed? Yes 2. Were all performancelacceptance standards for the required QA/QC procedures achieved? Yes 3. Were any significant modifications made to the method,as specified in Section 11.3? No Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompanying signed project cover letter. The accompanying cover letter,project narrative and quality control report are considered part of this data report. Method Reference: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998). Extraction performed utilizing separatory funnel technique. Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample dilution and sample size. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting it that range. 0 n-C11 to n-C22 Aromatic Hydrocarbons range data excludes the method target analyte concentrations. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay,MA 02532 GROUNDWATER ANALYTICAL Massachusetts DEP EPH Method Extractable Petroleum Hydrocarbons by GCIFID Field ID: GZA-3 Laboratory-ID: 55605-06 Project: Hubbard Oil/Brooks Rd/8002-3490 QC Batch ID: EP-1126-F Client: Bennett&O'Reilly,Inc. Sampled: 10-23-02 Container: 1 L Amber Glass Received: 10-25-02 Preservation: H2SO4/Cool Extracted: 10-28-02 Matrix: Aqueous Analyzed: 10-31-02 ¢LL Dilution Factor: Aliphatic:1 Aromatic:1 " <A I �.. J '`�` - �(En'.{{ ., y ,.: fuf � ` n-C9 to n-C18 Aliphatic Hydrocarbons BRL ug/L 500 n-C19_.to n-C36 Aliphatic Hydrocarbons BRL ug/L 500 n-C11 to n-C22 Aromatic Hydrocarbons BRL ug/L 160 Unadjusted n-C11 to n-C22 Aromatic Hydrocarbons BRL ug/L 160 A SzNr]ri:.eaf �e N t r.7 rc as 2 _ <t; zr. ., e a' ,;� _ ,a rj" 91-20-3 Naphthalene BRL ug/L 10 91-57-6 2-Methyl naphthalene BRL ug/L 5 85-01-8 Phenanthrene BRL ug(L 10 83-32-9 Acenaphthene BRL ug/L 10 86-73-7 Fluorene BRL ug(L 10 208-96-8 Acenaphthylene BRL -ug/L 10 --- 120-12-7 Anthracene BRL ug(L 10 206-44-0 Fluoranthene BRL ug/L 10 129-00-0 Pyrene BRL ug/L 10 56-55-3 Benzo[a]anthracene BRL ug/L 10 218-01-9 Chrysene BRL ug/L 10 205-99-2 BenzoMfluoranthene BRL ug/L 10 207-08-9 Benzo[k]fluoranthene BRL ug/L 10 50-32-8 Benzo[a]pyrene BRL ug/L 10 193-39-5 Indeno[1,2,3-c,d]pyrene BRL ug/L 10 53-70-3 Dibenzo[a,h]anthracene BRL ug(L 10. 191-24-2 Benzo[g,h,i]perylene BRL ug/L 10 Fractionation: 2-Fluorobiphenyl 80 % 40-140% 2-Bromonaphthalene 76 % 40-140% Extraction: Chloro-octadecane 83 % 40-140% ortho-Terphenyl 95 % 40-140% -is:.:•x,c:gs� - 1. Were all QA/QC procedures required by the method followed? Yes 2. Were all performancelacceptance standards for the required QA/QC procedures achieved? Yes 3. Were any significant modifications made to the method,as specified in Section 11.3? No Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompanying signed project cover letter. The accompanying cover letter,project narrative and quality control report are considered part of this data report. Method Reference: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998). Extraction performed utilizing separatory funnel technique. Report Notations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample dilution and sample size. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting it that range. 0 n-C11 to n-C22 Aromatic Hydrocarbons range data excludes the method target analyte concentrations. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay,MA 02532 GROUNDWATER ANALYTICAL Project Narrative Project: Hubbard Oil/Brooks Rd./B002-3490 Lab ID: 5505 Client- Bennett&O'Reilly,Inc. Received: 10-25-02 I6:25 RX. fT The following documentation discrepancies,and client changes or amendments were noted for this project- I Samples 55605-05 and-06 were analyzed by MA DEP EPH with all targets,per John TAdema-Wielandt,02-23-04. A h,tO-06 1 -W .0 The sample(s)in this project were analyzed-.3y the references analytical method(s),and no method modifications, non-conformances or analytical issues were noted,except as indicated below: 1 . No.method modifications,non-conformances or analytical issues were noted. Groundwater Analytical, Inc., P.O. Box 1200,228 Main Street, Buzzards Bay, MA 02532 2211 Main Street,P.O.Box 1200 GROUNDWATER Buzzards Bay,MA 02532 CHAIN-OF-CUSTODY RI_CORD ANALYTICAL Telephone(508)7594441 AND WORK ORDER p�® FAX(508)759-4475 ryt_ 064758 Project Name: Firm: TURNAROUND ANALYSIS REQUEST ❑STANDARD(10 Business Days) vsleNes 8emhslaAles Post °e es Metals Pc esm scasan TM waote General Gnemisiry Omer Project Number: Address: J�PRIORITY(5 Business Days) ❑RUSH(RAN- ) € a $a a Sampler Name: City/State/Zip; (Rush requires Rush AumortUtibn Number) o oo 0 0 0 ❑ g Please FAX ff-YES ❑NO a g FAX Number: a n a Project-Manager: N 's c o 9 Telephone: BILLING o 0 0 0 0 0 0 0 a s Purchase Order No.: GWA Reference No.: p ffie g INSTRUCTIONS:Use separate line for each container(except replicates). g g Sampling Mtmix = m tb `e o = o € a 2 ; a YPe Contalner(s) Preservation ❑ ❑ ❑ o ❑ ❑ o ❑ ❑ ❑ o o s ❑ t a SAMPLE .a A P N LABORATORY a _ � n n 8 � 3 R o l TI1i1= � � w w IDENFICATION E s 0 g a s NUMBER as a - $ ❑ 6 ❑ i ❑ (Lab Use Only) �Fedo ❑ - s 0 s s D a ❑ s °bS o ❑ o ° ❑ D ❑ ❑ o ❑ oao ❑ o oo0m;� ❑ ❑ ❑ ❑ . o o ❑ o o D o s 3 it H --------- ---------------- -------- I H -------- J-L1 11 1 1 1 REMARKS/SPECIAL INSTRUCTIONS DATA QUALITY OBJECTIVES - CHAIN-OF-CUSTODY RECORD Regulatory Program Project Specific DC❑Safe Drinking Water Act NOTE:All samples submitted subject to Standard Terms and Conditions on reverse hereof. Many regulatory programs and EPA methods requireproject Relinquished by Sampler: Date Time Received by. Receipt Temperature: ❑MA DEP Form e specific OC.Projects specific tx includes Sample Duplicates, i r ONPDES/Clean Water Act P p W Specify State: Matrix Spikes,endlor Matrix Spike Duplicates.Laboratory CC is not project specific unless prearranged.Project specific OC ` r� ❑WnA/Haz.Waste Char. samples are charged on a per sample basis.For water samples, Relinq fished by: Date Time Received by Shipping/Airbill Cd'MA MCP(310 CMR 40) each MS,MSD and Semple Duplicate required an additional /_�ydi�C .r"U� Number: J _ Rep ble Concentrations sample aliquot. (�(1 RCGW-1 O RCS-1 Project S Relinquished Specific Selection by Date Time ecetyed Laborato Custody Seal/ ❑RCGW-2 p RCS-2 ❑Sample Duplicate O Selected by laboratory Cooler Serial 0 MA Dredge Disposal �' a 0 : b Number: GROUNDWATER GO.Box 1terAna{ytical,inc. P.O.Box 1200 ANALYTICAL Buzzards Main Street Buzzards Bay,MA 02532 Telephone(508)759-4441 February 26, 2004 FAX(508)759-4475 ry www.groundwateranalytical.com Mr.John Tadema-Wielandt Bennett& O'Reilly, Inc. P.O. Box 1667 Brewster, MA 02631 LABORATORY REPORT AMENDMENT Project: Hubbard Oil Co. Brooks Rd./B002-3490 Lab I D: 54995 Received: 10-02-02 Dear Joh n: Enclosed are the amended analytical results for the above referenced project. This letter authorizes the release of the analytical results, and should be considered a part of this report. This report contains a sample receipt report detailing the samples received, a project narrative indicating project changes and non-contormances, a quality control report, and a statement of our state certifications. The analytical results contained in this report meet all applicable NELAC standards, except as may be specifically noted, or described in the project narrative. This report may-only be used or reproduced in its entirety. I attest under the pains and penalties of perjury that, based upon my inquiry of those individuals immediately responsible for obtaining the information, the material contained in this report is, to the best of my knowledge and belief, accurate and complete. Should you have any questions concerning this report, please do not hesitate to contact me. Sincerely, Jonathan R. Sanford President J RSAmd Enclosures SR13UNDMTER ANALYTICAL Sample Receipt Report Project: Hubbard Oil Co.Brooks Rd.16002-3490 Delivery: GWACourier Temperature: 11.2'C Client. Bennett&O'Reilly, Inc. Airbill: nia Chain of Custody: Present Lab ID: 54995 Lab Receipt: 10-02-02 Custody Seal(s): n/a 2, 54995-1 TB-4:3-5' Soil 1011/0213:00 MA DEP EPH PAHs Can ID Container vendor QC Lot Presevy QC Lot Prep Swap C138813 250 mL Glass Proline I BX4385 None n/a n/a 07-01-02 54995-5 -1 by CC ASTM D33284)(3 Mad Con ID Container Vendor QC Lot P. QC Lot Prep Ship I C144036 250 rnL Class Praline 8X4S59 None n/a -a .:No. 54995-7 T":13-15- I soil I Q11/02 15:15 MA DEP VPH with Targets Con ID Container Vendor QC Lot Presery QC tot 1 Prep Ship C129412 60 mL Gla-S-S' I Industrial I 0X4621 Methanol R-33821 08-08-02 08-16-02 C189237 40 mL VOA Vial i n/a n& None n/a i nla n/a 3� [,Aakb ID 54995-8 TB-6:18-20- Soil 1 D/1/02 15:30 MA DEP VPH with Targets Con ID Container —Vendor QC Lot Presery QC Lot 1 Prep Ship C129408 60 mL Glass Industrial BX4621 methanol P-33821 08-08-02 08-16-02 C189232 60 mL Glass n/a n/a I None n/a n/a n/a MEdidd- 54995-9 TB-8:8-10- Soil 1 arM2 10A0 MA DEP EPH FAHs Con ID Container Vendor QC Lot Presery QC Lot Prep Ship C138816 250 mL Class I Praline 1 BX4385_1 None n/a n/a 07-01-02 54995-101 T84: 18-20- Soil I 012A2 10:15 MA DEP EPH PAW Lot Prep ShipCon ID Vendor QC Lot Presery ix �J 38818 250 mL Glws Praline BX4385 None n/a J r4 07-01-02 1 1 54995-11 TB-10.13-15' Soil 10/2M2 13:00 MA DEP EPH PAHS Con ID I Container Vendor QC Lot P=�: QC Un F-rev ship C138820 250 mL Glass Frollne I BX4385 None n/a nta 07-01-02 W— 54995-12 13-11:3-15* soil 1012/02 14:00 TPK by GC ASTM D3328-W Mod Con ID Container Vendor QC Lot Presery QC Lot Prep Ship n/a n/a n/a n/a n/a n/a n/a n/a Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Massachusetts DEP EPH Method Extractable Petroleum Hydrocarbons by GCfID Field ID: TB-4:3-5' Laboratory ID: 54995-01 Project: Hubbard Oil Co. Brooks Rd.10002-3490 QC Batch ID: EP-1538-M Client Bennett&O'Reilly,Inc. Sampled: 10-01-02 Container. 250 mL Glass Received: 10-02-02 Preservation: cool Extracted: 1044-02 Matrix: soil Analyzed: 10-17-02 % Moisture: 8 Dilution Factor. Aliphatic: 1 Aromatic: 1 n-C9 to n-C18 Aliphatic Hydrocarbons 840 mg/Kg 32 n-C19 to n-C36 Aliphatic Hydrocarbons 380 mg/Kg 32 n-C11 to n C22 Aromatic Hydrocarbons 430 mg/Kg 32 Unadjusted n-Cl l to n-C22 Aromatic Hydrocarbons f 440 mg/Kg 91-20-3 Naphthalene — bGLK �31t� BRL mg/Kg 0.54 91-57-6 2 Meihylnaph[lialene 3.3 mg/Kg 0.54 `5 85-01-8 Phenanthiene " 0.90 mg/Kg 0.54 83-32-9 Acenaphthene i 0.71 rng/Kg 0.54 : Zp { 208 96 8 I Acenaphthylene BRL mg/Kg 1 0.54 ••_ K _ .. -mt� f;__ .� 0.54 'a�?A 720-12-7 ! Anthracene BRL j mg/Kg ! 0.54 206-44-0 Fluoranthene BRL mg/Kg ! 0.54 129-00-0 BRL mg/Kg 0.54 56-55-3 jetBenio a ai#1 acene BRL mgtKg 0.54 218-01-9 0-a nE,Chryserie _ BRL mg/Kg 0.54 205-99-2 J Beno[ti]fluontheite BRL mg/Kg 0.54 -- — 207-08-4 10 Beizo[k]fluoranttterie _ BRL mg(Kg 0.54 12 4"a SO-32-8 sw s BertzoCalP„Yrene _...._... BRL . _ - -- mg/Kg 054 193-39-5`; IndenoCl 2 3 ;dJpyrene j BRL mg(Kg 0.54 53-70-3 BRL6z[ 1n mg/Kg - 0.54 191-24-2 Benzo[g li r]'peiylene BRL - mglKg 0.54 1 Xk Fractionation. 2-Fluorobiphenyl 102 /o I 40-140% 2-Bromonaphthalene 108 % ! 40-140% Extraction: \Chlorooctadecane 58 % 40-140% ortho-Terphenyl 124 % 40-140% 1. Were all QA/QC procedures required by the method followed? Yes 2. Were all performance/acc4ptance standards for the required QA(QC procedures achieved? Yes 3. Were any significant modifications made to the method,as specified in Section 11.3.1.1? Yes Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompanying signed project cover letter. The accompanying coverletter,project narrative and quality control report are considered part of this data report. Method Reference: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998). Results are calculated on a dry weight basis. Method modified by use of microwave accelerated solvent extraction technique. Report Notations: BRL Indicates concentration,if any,is below reporting limit foranalyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits-are adjusted for sample dilution,percent moisture and sample size. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting it that range. 0 n-C11 to n-C22 Aromatic Hydrocarbons range data excludes the method target analyte concentrations. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 SR13UNDMTER ANALYTICAL Massachusetts DEP EPH Method Extractable Petroleum Hydrocarbons by GORD Field ID: TB-8:8-10' Laboratory ID: s4995-09 Project: Hubbard Oil Co.Brooks Rd./11002-3490 QC Batch ID: EP-1538-M Client: Bennett&O'Reilly,Inc. Sampled: 10-02-02 Container: 250 mL Glass Received: 10-02-02 Preservation: Cool Extracted: 104M-02. Matrix: Soil Analyzed: 10-17-02 %Moisture: 5 Dilution Factor: Aliphatic 1 Aromatic 1 n-C9 to n-C18 Aliphatic Hydrocarbons 290 mg/Kg 30 n-C19 to n-C36 Aliphatic Hydrocarbons 76 mg/Kg 30 n-C11 to n-C22 Aromatic Hydrocarbons _ 81 mg/Kg 30 unadjusted n-C11 to n-C22 Aromatic Hydrocarbons t 81 _ mg/K9 30 91-20-3 Naphthalene BRL mg(Kg 0.50 91-57-6 2-Methylnaphthalene BRL mg/Kg 0.50 85-01-8 Phenanthrene BRL mg/Kg 0.50 83-32-9 Acenaphthene BRL mg/Kg 0.50 208-9&8 Acenaphthylene BRL mg/Kg 1 0.50 86-73-7 Fluorene BRL _mg(Kg 0.50 120-12-7 Anthracene BRL mg/Kg 0.50 20644-0 Fluoranthene BRL mg/Kg 030 129-00-0 Pyrene _ BRL mg(Kg 0.50 5fr55-3 Benzo[a]anthracene BRL mg/Kg 0.50 218-01-9 Chrysene BRL rng(Kg 0.50 205-99-2 Benzo[b]fluoranthene BRL mg/Kg 0.50 207-08-9 Benzo[k]fluoranthene BRL I mg(Kg 0.50 50-32-8 Benzo[a]pyrene BRL mg(Kg 0.50 193-39-5 Indeno[1,2,3—cd]pyrene BRL mg/Kg 0.50 53-70-3 Dibenzo[a,h]anthracene BRL mg/Kg 0.50 191-24-2 Benzol&h,i]perylene BRL mg/Kg 0.50 -- — PC557 Fractionation- 2-Fluorobiphenyl 79 % 40-140% 2-Bromonaphthalene 103 % 40-140% i Extraction: Ch loro-octadecane 55 % 40-140% ortho-Terphenyl . 86 % 40-140% 1. Were all QA/QC procedures required by the method followed? Yes 2. Were all performance(acceptance standarts for the required QA/QC procedures achieved? Yes 3. Were any significant modifications made to the method,as specified in Section 11.3.1.1? Yes Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report. Release of this data is authorized by the accompanying signed project cover letter. The accompanying cover letter,project narrative and quality control report are considered part of this data report. Method Reference: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998). Results are calculated on a dry weight basis- Method modified by use of microwave accelerated solvent extraction technique. Report Notations: KRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample dilution,percent moisture and sample size. t Hydrocarbon range data excludes concentrations of any surrogatets)and/or internal standards eluting it that range. 0 n-C11 to n-02 Aromatic Hydrocarbons range data excludes the method target analyte concentrations. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay,MA 02532. GROUNDWATER ANALYTICAL Massachusetts DEP EPH Method Extractable Petroleum Hydrocarbons by GC/FID Field ID- TB-8- 18-20' Laboratory ID: 54995-10 Project: Hubbard Oil Co. Brooks Rd.16002-3490 QC Batch 1D: EP-1538-M Client: Bennett&O'Reilly,Inc. Sampled: 10-02-02 Container: 250 mL Glass Received: 10-02-02 Preservation: cool Extracted: 10-04-02 Matrix: soil Analyzed: 10-17-02 % Moisture: 3 Dilution Factor. Aliphatic:1 Aromatic.1 n-C9 to n8.Aliphatic Hydrocarbons 130 imgfKg 30 -1 n-C19 to n-C36 Aliphatic Hydrocarbons 54 mg(Kg 30 n-11 to n-C22 Aromatic Hydrocarbons 79 mg/Kg 30 Unadiusted n-C11 to n-C22 Aromatic Hydrocarbons' 79 mg/Kg 30 -_ - - - - - 91-20-3 Naphthalene -BRL mg/Kg 0.50 91-57-6 12-Methylnaphthalene BRL mg/Kg 0.50 85-01-8 Phenanthrene BRL mg(Kg 0.50 83-32-9 Acenaphthene BRL mg/Kg 0.50. 208-96-9 Acenaphthylene SRL mg/Kg 0.50 86-73-7 Fluorene _ _. BRL j mWKg 1 0.50 120-12-7 Anthracene BRL mglKg 0.50 206-44-0 Fluoranthene BRL rn Kg 0.50 129-00-0 Pyrene BRL rngfKg 0.50 56-55-3 Benzo[a]anthracene BRL mg1Kg 0.50 218-01-9 Chrysene BRL , mg/Kg 0.50 205-99-2 Benzo[b]fluoranthene BRL mg/Kg 0.50 207-08-9 Benzo[k]fluoranthene BRL 50- mg(Kg 6.50 32-8 I m Benzo[a]pyrene BRL mg(Kg 0.50 793-39-5 Indeno[1,2,3-c,d]pyrene BRL mg/Kg 0.50 53-70-3 Dibenzo[a,h]anthracene BRL mg/Kg 0.50 191-24-2 Benzo[g,h,i]perylene BRL mgfKg 0.50 Fractionation: 2-Fluorobipheny) 93 % 40-140%. 2-Bromonaphthalene 110 % 40-140% Extraction: Chloro octadecane 55 % 40-140% ortho-Terphenyl 116 °!0 40-140% --- -- -- - - -- - - ---- - ---- - -- ---- - _ ---- _ -_ - wo 1. Were all QAIQC procedures required by the method followed? - - Yes 2. Were all performancetacceptance standards for the required QA/QC procedures achieved? Yes 3. Were any significant modifications made to the method,as specified in Section 11.3.1.1? Yes Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative and project quality control report Release of this data is authorized by the accompanying signed project cover letter- The accompanying cover letter,project narrative and quality control report are considered part of this data report. Method Reference Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998). Results are calculated on a dry weight basis. Method modified by use of microwave accelerated solvent extraction technique. Report Notations: RRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample dilution,percent moisture and sample size. t Hydrocarbon range data excludes concentrations of any surrogate(s)and/or internal standards eluting it that range. 0 n-C11 to n-C22 Aromatic Hydrocarbons range data excludes the method target analyte concentrations. Groundwater Analytical, Inc., P.O. Box 1200, 228 Main Street, Buzzards Bay, MA 02532 GROUNDWATER ANALYTICAL Massachusetts DEP EPH Method Extractable Petroleum Hydrocarbons by GOOD Field ID: TB-10:13-15' Laboratory ID: 54995-11 Project: Hubbard Oil Co.Brooks Rd./8002-3490 QC Batch ID: EP-1538-M Client: Bennett 8r O'Reilly,Inc. Sampled: 10-02-02 Container: 250 mL Glass Received: 10-02-02 Preservation: cool Extracted: 104)4-02 Matrix: soil Analyzed: 10.17-02 %Moisture: 9 Dilution Factor: Aliphatic:1 Aromatic: 1 n-C9 to n-C18 Aliphatic Hydrocarbons 55 mg/Kg 32 n-C19 to n-C36 Aliphatic Hydrocarbons 150 mg/Kg 32 n-C11 to n-C22 Aromatic Hydrocarbons T 79 mg1Kg 32 Unadi usted n-C11 to n-C22 Aromatic Hydrocarbons t 85 mg/Kg 32 .S'tAw-I € AS 4undki. 91-20-3 Naphthalene otfo BRL mg(Kg 1 0.53 91-57-6 i 2;Methylnaphthalene BRL mg/Kg 0.53 85-01-8 V, Phenanthrene .110 BRL mg/Kg 0.53 83-32-9 A phtiene '� ' '` BRL mg/Kg I 0.53 208-96-8 Acena—thylene BRL mg/Kg i 0.53 86-73-7Frluor"enexE,�a - BRL m�Kg ' 0:53 � y 120-12-7 ' A n s tcene_ _ BRL mg/Kg 0.53 206-440 Fluoranthene 0.64 mg/K9 0.53 1000 129-00-0 r � t " 0.59 mg/Kg 0.53 '/00 56-55-3 enzo[a anthtacen r BRL mg(Kg 0-53. '� 218-01-9 ,�Chrysene�,,�� ��" �.� �;.�� ,T BRL mg/Kg 0.53 I 205-99-2 ea§„ zo(b flu anthene � ='_< 0.70 mg/Kg 0.53 1 0r- 207-08-9 Berms zo[kjf uf"gratften % �= ' BRL _ mg/Kg 0.53_ 50-32-8 I MBe[ ene 53 r _ BRL mg/Kg 0.53 193-39-5 Inde o 1 �;t3 c d]pyrene BRL mg/Kg 0..53 53-70-3 j-Dt .rnzo[a;h]antfira en BRL mg/Kg 0.53 191-24-2 w Benz h i]perylen�e 0.58 mg(Kg 0.53 1000 Fractionation: 2-Fluorobiphenyl 87 % 40-140% 2-Bromonaphthalene 70 % 40-140% Extraction: Chloro-octadecane 57 % 40-140% ortho-Terphenyl 78 % 40-140% — 1. Were all QAIQC procedures required by the method followed? Yes 2. Were all performancelacceptance standards for the required QA/QC procedures achieved? Yes 3. Were any significant modifications made to the method,as specified in Section 11-3-1.1? Yes Method non-conformances indicated above are detailed below on this data report,or in the accompanying project narrative and projea quality control report. Release of this data is authorized by the accompanying signed project cover letter. The accompanying cover letter,project narrative and quality control report are considered part of this data report. Method Reference: Method for the Determination of Extractable Petroleum Hydrocarbons,MA DEP(1998). Results are calculated on a dry weight basis. Method modified by use of microwave accelerated solvent extraction technique. Report flotations: BRL Indicates concentration,if any,is below reporting limit for analyte. Reporting limit is the lowest concentration that can be reliably quantified under routine laboratory operating conditions. Reporting limits are adjusted for sample dilution,percent moisture and sample size. t Hydrocarbon range data excludes c:uncentrations of any surrogate(s)and/or internal standards eluting it that range. 0 n-011 to n-C22 Aromatic Hydrocarbons range data excludes the method target analyte concentrations. Groundwater Analytical, Inc., P.O- Box 1200, 228 Main Street, Buzzards Bay,MA 02532 GROfJIVDWATER ANALYTICAL Project Narrative oject: Hubbard Oil Co.Brooks Rd.lB002-3490 Lab ID: 54995 ient: Bennett&O'Reilly, Inc. Received: 10-02-02 13:40 .. .. e following documentation discrepancies,and client changes or amendments were noted for this project: 1 . Samples 54995-01,-09,-10,and-11 were reported by MA DEP EPH with all target analytes,per John Tadema- Wielandt,02-25-04. _ ortComomaances and=Oaisetvafiriis . .. __8�-1�de+frwd_-Actodif�c - - _ - _ - - �e sample(s)in this project were analyzed by the references analytical method(s),and no method modifications, on-conformances or analytical issues were noted,except as indicated below: 1 Project Non-conformance. Project 54995 was received at a temperature of 11.2'C. This measurement is outside the recommended range of 2-6'C. Groundwater Analytical, Inc.,P.O.Box 1200,228 Main Street,Buzzards Bay, MA 02532 1 i 228 Buz Street,P.O.Box 1200 GROUNDWATEROUNDWATER Buzzards erdsBay,MA02532 CHAIN-OF-CUSTODY RECORD N� 053455 ANALYTICAL Felehone AX(hone(508)75 4441 AND WORK ORDER Project Name: 1 1 Firm: J� ��1 1 TURNAROUND ANALYSIS REQUEST �1 Ij"IJ��LI�I JI�IU� 1)!006 rW. ��1AIA.GCI .()�Q"r:1 N/, I.(, r VdNln Qemlrolrlllu Vu r 9r STANDARD(10 Business Days) Metal, PrUahunN emeuem aa. emutl Oremhlry dlhs Project Number: Address: �4 1, O PRIORITY(5 Business Days) $ 13 $ ZZCr, --34Ru e773 Main. 5+./P() &'x ILGI C RUSH(RAN- , a (Rush requires Rush Aulhodiallon Number) ❑ n 3 ❑ ' Sampler Name: City/State I Zip: Please FAX QQ YES J Q NOP FAX Number: . Project Manager: Telephone: BILLING a $ D g 5 _ �,9 O C ❑ O O C ❑ O 9 Jam.% Ci Purchase Order No.: GWA Reference No.: is INSTRUCTIONS:Use separate Ilre for each container(except replicates). r/`^' "^� yR0 g - o o g o c i Sump Ina Matrix a Contelner a vri u e o a c a o a "c o a s a .$ ' Nt e n Typo () Preservation tewe p ;! eeAi � 6ANYo PLE 5 �' LABORATORY — � a _ g � � ❑ �r o IDEN71FICATION It } g Til NUMBER5JE ❑(Leh Uee Only) S 5 5 a g as aou° tt�tyS ❑ ❑ o q q❑ o o c � � o 0 0 0 o a o o' u u 3 � 'r9 n ❑ n ❑ o o u u � u tx, b I : 8 1°I K I,00 T S- ; 3— s X I x I 10 t U ,LO T '6'. I5-20, ;u v.00 T 43`(0' XI tojzloz IV.17 ' (g-2O' X I Ib I ro -to, 13-Is X I I I X1 I I I X I II(. H111T_ _HTH-1-1 I I I I I i REMARKS/SPECIAL INSTRUCTIONS DATA QUALITY OBJECTIVES CHAIN-OF-CUSTODY RECORD Regulatory Program Project Specific OC NOTE:All samples submitted subject to Standard Terms and Conditions on reverse Wool. ❑Safe Drinking Water Act Many regulatory orogrems and EPA methods require project I ulsh by pie, Date Time Received b Recei tTem retuie' ❑MA DEP Form specific QC,Project specific 00 Includes Semple Duplicates, y' P C NPDESICIean Wafer Act Matrix Spikes,and/or Matrix Spike Duplicates.Laboratory OC Is I Z ❑� 1 i L / SpeclfySteta: not ptolect Specific unless prearranged.Pro;ect specific CC �wL < (It` � ❑RCRA/Haz.WaSte Char, samples are charged on a parsample belle.For water samples, e,in s by, ]q1e I ima .Received by: \ shipping/Alrbill AMA MCP(310 CMR 40) each MS,MSD and Semple Duplicate requlres an additional / ,`_ Number: Reportable Concentrations sample aliquot. 2' z ti t: RCGW-I DO RCS-I Re Inoulshed : Table 1:Method 1 Risk Characterization Standards EPH ANALYSIS SUMMARY-PERIMETER GROUNDWATER Monitoring EPH EPH EPH EPH EPH EPH Well RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS �Sfandard., doStandard Location (µme-PPb) (µme -PPb) (µPS-PPb) (µg/L-PPb) (µPS-PPb) (µP/--PPb) [10/23/02] [1/27/03] [4/24/03] [6/3/03] [10/9/03] [2/5/04] 310 CMR 310 CMR- ALL PAH's ALL PAH's K 40 974(2) Y 40 974(2) -1(D) to C18 NOT NOT NOT NOT BRL(<500). BRL(<500) gi 4 000 20 000 t 9 to C36 TESTED TESTED TESTED TESTED BRL(<500) BRL(<500) 5 000 20 000 z 1 to C22 BRL(<160) 160 200 30 000 s et PAH NT phthalene BRL(<0.5) Y 20 t 6 000 ethylnaphthalene BRL(<0.5) 10� 3 000 enaphthene BRL(<0.5) ; 20 5 000 enaphthalylene BRL(<0.5) 300w , 43 000 orene BRL(<0.5) enanthrene 0.8 300 € 50 thracene BRL(<0.5) f 2 000 i �* � 33 000 oranthene 2.2 Y300200 ene 1.4 200 3 000 nzo(a)anthracene 0.5 1 3 000 sene 1.1 2 f =3 000 nzo(b)fluoranthene 1.2 nzo(k)fluoranthene 0.9 1 , 3 000 nzo(a)pyrene 0.9 k 0 2 3 000 11 no1,2,3-c,d)pyrene 1.0 ,0 5 3 000 y enzo(a,h)anthracene 0.2 x 0 5 s -3 000 nzo(g,h,i)perylene 1.1 300 rvz� 3 000 ;;: to C18 BRL(<20) BRL(<530) BRL(<500) BRL(<500) BRL(<500) BRL(<500) 4 000�* a 20 000 9 to C36 BRL(<20) BRL(<530) BRL(<500) BRL(<500) BRL(<500) BRL(<500) S 000 20 000 1 to C22 33 BRL(<170) BRL(<160) BRL(<160) BRL(<160) BRL(<160) 20Q 30 000 -' hrp-et PAH BRL(<5) BRL(<11) BRL(<10) BRL(<10) BRL(<0.5) phthalene BRL(<0.5) 20 }6 000 ethylnaphthalene BRL(<0.5) F 10 3 OOOk enaphthene BRL(<0.5) 20 S 000 enaphthalylene BRL(<0.5) 300`' orene BRL(<0.5) 300 F 3 000 enanthrene 0.9 300 s 50 thracene BRL(<0.5) 4 2 000 k3 000 2? oranthene 2.2 4 300 200 Y ene 1.4 ' 200 3 000 -R a nzo anthracene ( ) 0.6 sene 1.0 ' 2 : 3 000 o(b)fluoranthene 1.0 9 a 1 3 000 r (k)fluoranthene 0.8 1 3 000 { (a)Pyrene 0.8 s a p 2 s 3 OOQ no1,2,3-c,d)pyrene 0.8 enzo(a,h)anthracene 0:2 (g,h,i)perylene 0.8 3003 000 x 4 : -3(S) A111,a, to C18 BRL(<20) NOT NOT NOT BRL(<500) NOT 4 000 20 000 9 to C36 BRL(<20) TESTED TESTED TESTED BRL(<500) TESTED S 000 20 000 1 to C22 BRL(<20) BRL(<160) :200 30 000�' AH/12 PAH BRL(<5) NT 4PAH>10/ * PAH4>501 Q.- Table 1: Method 1 Risk Characterization Standards EPH ANALYSIS SUMMARY-PERIMETER GROUNDWATER Monitoring EPH EPH EPH EPH EPH EPH GW 1 GW 3 ti Well RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS Standard Standard Location (µme -PPb) (µ€/L-PPb) (µPS•-PPb) (µme-PPb) (µPS•-PPb) (µg/L-PPb) (PPb) (PPb) [10/23/02] [1/27/03] [4/24/03] [6/3/03] [10/9/03] [2/5/04] 3I0 CMR 310 CMR ALL PAH's ALL PAH's fi 40974(2) '40 974(2)3 to C18 NOT BRL(<500) BRL(<500) BRL(<500) BRL(<500) BRL(<500) 4 000 20 000 r to C36. TESTED BRL(<500) BRL(<500) BRL(<500) BRL(<500) BRL(<500) 5 000 20 000 1 to C22 BRL(<160) BRL(<160) BRL(<160) BRL(<160) BRL(<160) 200 30 000 AW12 PAH BRL(<10) BRL(<10) BRL(<10) BRL(<O.5) BRL(<0.5) 4PAH�10/y#; 4PAH>50/ -5D t''T x v- } 3 to C18 NOT BRL(<500) BRL(<500) BRL(<500) BRL(<500) BRL(<50.0) 4 000 20 000 to C36 TESTED BRL(<500) BRL(<500) BRL(<500) BRL(<500) BRL(<500) 5 000 x 20 000 1 to C22 BRL(<160) BRL(<160) BRL(<160) BRL(<160) BRL(<160) 200 30 000 et PAH BRL(<10) BRL(<10) BRL(<10) BRL(<0.5) $ t hthalene BRL(<0.5) ;,w20¥ t :6 00 ethylnaphthalene BRL(<0.5) t -10 .3 000 naphthene BRL(<0.5) ;20 5 000 naphthalylene BRL(<0.5) �,30K. 0 :3 000 r rene BRL(<0.5) k 300 -, x 4'3 000 nanthrene 0.6 r1 300 .` 50 acene BRL(<0.5) _ 2 000 =3 000- ranthene 1.4300 4 200 1 o(a)anthracene 0.9 200 }3 000 , 0.3 1 3 3 000 sene 0.6 r 2s 3 000 zo(b)fluoranthene 0.6 1 3 000 4 o(k)fluoranthene 0.4 1 3 000 r (a)Pyrene 0.4 x 0 2 3 000 0gd)pyrene 0.4 ' enzo(a h)anthracene o(g,h,i)perylene 0.1 0.5 =300x' _ 3 000 -65 � - to C18 BRL(<500) BRL(<500) BRL(<500) BRL(<500) BRL(<500) BRL(<500) g d o00 o 000L to C36 BRL(<500) BRL(<500) BRL(<500) BRL(<500) BRL(<500) BRL(<500) �5 000` fib+ 20 OOOF to C22 BRL(<160) BRL(<160) BRL(<160) BRL(<160) BRL(<160) BRL(<160) 200 z 30 OOO r ti� et PAH BRL(<10) BRL(<10) BRL(<10) BRL(<10) BRL(<0.5) t hthalene 2.1 BRL(<0.5) ,x 20 r €y 6 000 .ri ethylnaphthalene 1.2 BRL(<0.5) `10 -3 000 aphthene BRL(<0.5) aphthalylene BRL(<0.5) retie BRL(<0.5) h 300 r z:s_3 000� nanthrene BRL(<0.5) '300SOx s racene ranthene BRL(<0.5) Z 000 0.7 r300 Y 200 tie BRL(<0.5) 200 3 000 - `� (a)anthracene 0.2 1 :3 000 sene 0.3 3 000 (b)fluoranthene 0.3 lu o(k)fluoranthene 0.2 o(a)Pyrene 0.2 r 0 2 ol,2,3-c,d)PYr ene 2 t 3 000 0. nzo(a,h)anthracene BRL(<O.1) 0 5 ? 3 000 o(g,h,i)perylene 0.2 300 3 000 to C18 BRL(<500) BRL(<500) BRL(<500) BRL(<500) BRL(<500) BRL(<500) ; .4 000 20 000 i to C36 BRL(<500) BRL(<500) BRL(<500) BRL(<500) BRL(<500) BRL(<500) tl5 000 - ?20 000 `:' to C22 BRL(<160) BRL(<160) 190 BRL(<160) BRL(<160) BRL(<160) 200 30 000 12 PAH BRL(<10) BRL(<10) BRL(<10) BRL(<10) BRL(<0.5) BRL(<0.5) 4PAH>10/ PAH4>50/ Bold text indicates results that exceed applicable groundwater category(s) Shaded areas designates appropriate groundwater category(s) I Table 2: Method 1 Risk Characterization Standards VPH ANALYSIS SUMMARY-PERIMETER GROUNDWATER Monitoring VPH VPH VPH VPH VPH VPH GW 1: GW=3 Well RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS Ondard Standard Location (µ€IL-PPb) (µgd -PPb) (µg/--PPb) (µg2-PPb) (µg/L-PPb) (µgo -PPb) (PPb)_ (PPb) [10/23/02] [1/27/03] [4/24/03] [6/3/03] [10/9/03] [2/5/04] 3310 CMR 310 CIvIIt 40 974(2) w 40 924(2) GZA-1(D) C5 to C8 NOT NOT NOT NOT BRL(<20) BRL(<20) 400 4 000 C9 to C12 TESTED TESTED TESTED TESTED BRL(<20) BRL(<20) r 4 000 20 OQO C9 to C10 BRL(<20) 37 200 "' 4 000 TEX/Naphthalene BRL(<5) BRL(<5) EDB NT NT LEAD NT NT GZA-2(S) s C5 to C8 BRL(<20) BRL(<20) BRL(<20) BRL(<20) BRL(<20) BRL(<20) 5 400 C9 to C12 BRL(<20) BRL(<20) BRL(<20) BRL(<20) BRL(<20) BRL(<20) C9 to CIO 33 BRL(<20) 25 34 BRL(<20) 20200 4 000 Xylene BRL(<5) BRL(<5) BRL(<5) 11 BRL(<5) BRL(<5) =10 000 so-000 z Ethylbenzene BRL(<5) BRL(<5) 6 10 BRL(<5) BRL(<5) er Target BTEX BRL(<5) BRL(<5) BRL(<5) BRL(<s) BRL(<5) BRL(<5) >5 >4 OOQ : Naphthalene\ BRL(<5) BRL(<5) BRL(<5) 6 BRL(<5) BRL(<5) 20 n 6 000 EDB NT BRL(<.02) NT NT NT NT 02 50 000 LEAD NT BRL(<5) NT NT BRL(<6) NT } 15 30 GZA-3(S) 6mg' s C5 to C8 BRL(<20) NOT NOT NOT BRL(<20) NOT ` 400 4 000,pa p C9 to C12 BRL(<20) TESTED TESTED TESTED BRL(<20) TESTED 4 000 s 20 000 C9 to CIO BRL(<20) BRL(<20) >200 a 000z t TEX/Naphthalene BRL(<5) BRL(<5) >5 >4 Q00 EDB NT NT LEAD NT NT MW-5S � � may_ i �M�'. � g• C5 to C8 BRL(<20) BRL(<20) BRL(<20) BRL(<20) BRL(<20) BRL(<20) 400i 7ut.R4 000 N C9 to C12 BRL(<20) BRL(<20) BRL(<N) BRL(<20) BRL(<20) BRL(<20) C9 to CIO 21 BRL(<20) BRL(<20) BRL(<20) BRL(<20) 415200 f 4;00tT TEX/Naphthalene BRL(<5) BRL(<5) BRL(<5) BRL(<5) BRL(<5) BRL(<5) EDB NT BRL(<0.2) NT NT NT NT U2 50 000 LEAD NT 17 BRL(<5) NT 8 NT h 15 30 + MW-5D .� _ C5 to C8 BRL(<20) BRL(<20) BRL(<20) BRL(<20) BRL(<100) BRL(<20) 400 _ 4 000 C9 to C12 BRL(<20) BRL(<20) BRL(<20) BRL(<20) BRL(<100) BRL(<20) "4 4 000 20 000 C9 to C10 BRL(<20) BRL(<20) BRL(<20) BRL(<20) BRL(<100) BRL(<20) 200 _ 4 000 TEX/Naphthalene BRL(<5) BRL(<5) BRL(<5) BRL(<5) BRL(<5/25) BRL(<5) >5 >4000 EDB NT BRL(<.02) NT NT NT NT 02 SO 000 LEAD NT BRL(<5) NT NT BRL(<6) NTH 15 f 30� { NM-6S C5 to C8 BRL(<20) BRL(<20) 24 BRL(<20) BRL(<100) BRL(<20) 400 = V 4 000 C9 to C12 BRL(<20) BRL(<20) 20 BRL(<20) BRL(<100) BRL(<20) 4 000 } , 20 000 C9 to CIO 51 100 150 BRL(<20) 130 BRL(<20) i 200 k 4 Opp ' Xylene BRL(<s) BRL(<5) s BRL(<5) 71 BRL(<5) to 000 so 000 Other BTEX BRL(<5) BRL(<5) BRL(<5) BRL(<5) BRL(<5/25) BRL(<5) Naphthalene BRL(<5) 8 11 BRL(<5) BRL(<25) BRL(<5) 20s 6 000 EDB NT BRL(<.02) NT NT NT NT 02 � 50 000 LEAD NT BRL(<5) NT NT BRL(<6) NT MW-6D t a C5 to C8 BRL(<20) BRL(<20) BRL(<20) BRL(<20) BRL(<20) BRL(<20) 400 4 000 C9 to C12 BRL(<20) BRL(<20) BRL(<20) BRL(<20) BRL(<20) BRL(<20) 4 000 r 20 000 C9 to C10 BRL(<20) BRL(<20) BRL(<20) BRL(<20) BRL(<20) BRL(<20) 200 4 OOQ TEX/Naphthalene BRL(<5) BRL(<5) BRL(<5) BRL(<5) BRL(<5) BRL(<5) EDB NT BRL(<.02) NT NT NT NT 02 t z s0 000 LEAD NT BRL(<5) NT NT BRL(<6) NT Bold text indicates results that exceed applicable groundwater category(s) Shaded areas designates appropriate groundwater category(s) Table 3: Method 1 Risk Characterization Standards EPH ANALYSIS SUMMARY-CENTRAL GROUNDWATER EPH EPH rGW 1 GW 3 Monitoring Well Location RESULTS RESULTS Standard: 'Standard:: (µme--ppb) (µPS-ppb) [10/02] [2/5/04] 310 CMR 310 CUR (Based on ALL PAH s "40 924(2) 40 974(2) 60/40 split for TPH results) - S E , C9 to C18 200 700 4 000 20,000 C19 to C36 NA BRL(<500) `5 000 20;000 Cl1 to C22 300 450 200 30 000 17 Target PAHs NT All BRL C9 to C18 BRL BRL(<500) 20 000 C19 to C36 BRL BRL(<500) 5 000 � 20 000 C11 to C22 BRL BRL(<160) sx 200' 30 000- 17 Target PAHs NT All BRL EVAH>10/f PAH4550/ MW 4 C9 to C18 240 BRL(<500) U4 000 r 20 000, r C19 to C36 NA BRL(<500) 5 000 20 000 C 11 to C22 360 180 200 30 000 4 PAW12 PAH NT All BRL 4PAH>10% PAH4>50/ `ALL>0 7;yk ALL;?0 7� SEA-1 � C9 to C18 2,560 16,000 4 000 20 000 C19 to C36 NA 2,300 5 000 20 000 Cl i to C22 3,840 7,300 200 30 OOOry Target PAH NT ' naphthalene 57 20 6 Ob0 2-methylnaphthalene 100 & 10 yr 3 000 acenaphthene BRL(0.5) r 20 , 5 000 acenaphthalylene 4.7 300ff 3 00�0 fluorene 11 300 �, 3 ObO � phenanthrene 16 s;300 50 anthracene 1.8 °p2 000 3 QUO fluoranthene BRL(<0.5) 300 fi2Q0 pyrene 1.7 200 x 3 000 _ benzo(a)anthracene BRL(<O.1) chrysene BRL(<O.1) 2 3;000 benzo(k)fluoranthene BRL(<O.1) 1 z 3 000 benzo(k)fluoranthene BRL(<O.1) 1 3 000 P benzo(a)pyrene BRL(<O.1) < 0 2 3 000 idenol,2,3-c,d)pyrene BRL(<O.1) 3< 0 5 3 000 s d� dibenzo(a,h)anthracene BRL(<O.1) 0 5 r 3 000 benzo BRL(<0.1) 300 3 Q00 (g,h,i)perylene SEA-2 n x C9 to C18 16,000 4,300 4 000 4 20 000 C19 to C36 NA 650 t5 000 x20 000 C11 to C22 24,000 1,400 200 0.6 30 000 Target PAH NT W M h k.' naphthalene 9.2 20 6000 2-methylnaphthalene BRL(<0.5) 10 , 3 000 acenaphthene 1.4 20 _0 5 000 acenaphthalylene 3.0 .y 300 fluorene 4.3 - - 300 s 3 000 phenanthrene BRL(<0.5) My 300 _ 50 anthracene BRL(<0.5) �2 000 3 000 fluoranthene BRL(<0.5) 300 200 pyrene BRL(<O.1) 200 N.3 000 benzo(a)anthracene BRL(<O.1) chrysene BRL(<O.1) 2 3,000 -A benzo(k)fluoranthene BRL(<O.1) benzo(k)fluoranthene BRL(<O.1) t. 1 3 000 benzo(a)pyrene BRL(<O.1) {0 2y k 3"000 idenol,2,3-c,d)pyrene BRL(<0.1) 0 5 3 000 dibenzo(a,h)anthracene BRL(<O.1) 0 5 3 000 benzo(g,h,i)perylene BRL(<O.1) ;;300 3 000 Bold text indicates results that exceed applicable groundwater category(s) Shaded areas designates appropriate groundwater category(s) Table 4: Method 1 Risk Characterization Standards VPH ANALYSIS SUMMARY-CENTRAL GROUNDWATER Monitoring Well VPH RESULTS VPH RESULTS ' GW 1 Standard GW 3 Standard .. Location (µg/L-PPb) (µme -PPb) } (pPb) (PPb) [10/23/021 [2/5/04] -310 CMR 40 974(2) 310 CMR 40 974(2) NW-1 C5 to C8 NOT BRL(<20) 400 4 000° C9 to C12 TESTED BRL(<20) 4 000 20 000 C9 to C10 BRL(<20) L 200 4 009 benzene BRL(<1) 5 7 000 ethylbenzene BRL(<5) 700 s 4 000 41, toluene BRL(<5) i 1"000 '{i350 000 xylene BRL(<5) 10 000 50 000 x naphthalene BRL(<5) _20 6 000 n MTBE BRL(<5) MW-2 CS to C8 NOT BRL(<40) v 400 4 000 C9 to C12 TESTED BRL(<40) n4 000 20 000 C9 to C10 43 200 4 000 benzene BRL(<2) h5 x 7 OOQ; " ethylbenzene BRL(<10) = 700 4 000 toluene BRL(<10) 11000 50 000 3 ' xylene BRL(<10) S0 000 naphthalene BRL(<10) MTBE BRL(<10) AM-4 myKi f C5 to C8 BRL(<20) BRL(<20) 4 000- ; C9 to C12 43 BRL(<20) t; 4;000 20 000 C9 to C10 73 23 200 4 000, benzene BRL(<1) BRL(<1) x 5 r 7 000' ethylbenzene BRL(<5) BRL(<5) ` r 100 4 000 toluene BRL(<5) BRL(<5) 1 s000 $-` 50 cau xylene BRL(<5) BRL(<5) 10 000 '� 50 OOQ naphthalene BRL(<5) BRL(<5)MTBE BRL(<5) BRL(<5) £a 70 50 000 :° CS to C8 NOT 850 00 � r C9 to C12 TESTED 2,300 4 000 ry 20 000 C9 to C10 6,600 `r 200 4000 ,.' benzene 9 ethylbenzene 470 700 4 000 toluene 620 �1`000 `� 50,000 xylene 2,730 naphthalene 280 gx 20 6 000: ` MTBE BRL(<10) SEA-2 C5 to C8 NOT 34 400 ? Y4000 C9 to C12 TESTED 500 4 000 20 000 C9 to C10 770 200 4 000 benzene BRL(<1) 5 `: 7000 ethylbenzene BRL(<5) 700 4 OOQ toluene BRL(<5) 1'000 } z ; 50 000 x xylene BRL(<5) 1Q000 f 50 OOQ naphthalene 13 x�20 MTBE BRL(<5) 3 7p 50 000' Bold text indicates results that exceed applicable groundwater category(s) Shaded areas designates appropriate groundwater category(s) APPENDIX E SITE HEALTH AND SAFETY PLAN Waste Site Cleanup Prepared by: BENNETT & OREILLY, INC. 1573 Main Street P.O. Box 1667 Brewster, MA 0.2631 TABLE OF CONTENTS 1.0 Emergency Response Summary I 2.0 Site Hazards/Personal Protection Summary 3 3.0 Project Personnel g 3.1 Site Safety Officer 3.2 Project Manager 3.3 Construction Superintendent 4.0 Hazard Assessment 10 4.1 Recognition 4.2 Evaluation 4.2.1 WLEL Monitoring 4.2.2 Organic Vapor Monitoring 4.2.3 Physical Hazards 4.3 Control 5.0 Safety Equipment 14 5.1 Personal Protective Equipment(PPE) 5.2 Site Safety Equipment 5.2.1 Air Monitoring Instruments 5.2.2 Site Safety Plan 5.2.3 First Aid Kit 5.2.4 Fire Extinguisher 5.2.5 Decontamination Equipment 6.0 Work Zones 16 7.0 Health and Safety Requirements 17 7.1 Training 7.2 Medical Surveillance Program 7.3 General Work Practices 7.3.1 Identify Pertinent Information 7.3.2 Have and be Familiar with Field Map 7.3.3 Avoid Obvious Hazardous Areas 7.3.4 Protect Against Physical Hazards 7.3.5 In the Event of Accident 8.0 Decontamination Procedures 19 9.0 Field Team Review 20 Appendix A: Vapor Monitoring Form Appendix B: Confined Space Procedures Appendix C: OSHA Trenching Regulations - Site Health and Safety Plan 1.0 EMERGENCY RESPONSE SUMMARY Project No: MA DEP RTN: Status: Date of Plan Preparation: Site Information: Listed Responsible Party: Property Owner: Site Address: Site Activities: On-site Subcontractor(s): BENNETT & OREILLY, INC. Consultant Project Team: Name Telephone Site Safety Officer(SSO): Craig Sasse (508) 896-6630 Project Manager: David Bennett (508)896-6630 Construction Superintendent: Utility Clearances: Dig-Safe Authorization Number: Telephone (800) 3.22-4844 Electric Company: Commonwealth Electric (800) 642-7070 Telephone Service: NYNEX (800) 980-9999 Emergency In urruat-lon: Telephone Location: Harbormaster Office (508) 945-51.85 Mobile Phone On-Site (508) 240-9662 1 Site Health and Safety Plan Hospital Address: 27 Park Street-Hyannis, MA 02601 (508) 771-1800 Directions to Hospital: (refer to attached maps) -Travel on Route 6 to Interchange 7 posted as Willow Street/Yarmouth Road. At the stop sign at the end of the off-ramp, turn left (south) onto Willow Street towards Hyannis (Hospital Sign Posted) [SEE MAP EM-2]. -Travel approximately 2 miles on Willow Street(aka Yarmouth Road)through the stop light at the intersection of Route 28 and bear left immediately onto Camp Street (Hospital Signs Posted). Travel on Camp Street 1/4 mile to the Main Street rotary. Proceed 1/2 way around the rotary and get off onto Lewis Bay Road(Hospital Signs Posted). Make an immediate left onto Park Street and follow the signs to the Emergency Room entrance [SEE MAP EM-3]. Important Telephone Numbers: Hospital: (508).771-1800 Ambulance: 911 Fire: 911 Police: 9.11 Poison Control Center: (800) 562-8236 Typical Procedures for Injury: 1. For lydnor injuries, administer first-aid at the site. Refer individual to consult family physician. 2. Telephone ambulance for major injuries or evidence of toxic symptoms. If no phone is available, transport person to the nearest hospital. 3. Send MSDS sheets with person to hospital. 4. Notify project manager or SSO of all accidents. 5. File accident report with Construction Superintendent. 2 it Site Health and Safety Plan 2.0 SITE HAZARDS/PERSONAL PROTECTION SUMMARY Expected Site Hazards/Substances: Gasoline, Diesel Fuel Physical Hazards- Heavy Equipment Operation, Loud Noise, Heat Exhaustion (see following) Chemical Hazards:Inhalation of Organic Vapors, Dermal Contact and Skin Absorption (see following) PEL -Permissible Exposure Limit STEL -Short Term Exposure Limit TLV -Threshold Limit Values IDLH -Immediately Dangerous to Life or Health 3 Site Health and Safety Plan Personal Protection/Action Levels: The minimum level of protection for personnel at this site is Level D. This level is utilized where the type of work involved precludes exposure due to splashes,immersions or the potential for unexpected inhalation or contact with hazardous levels of chemicals. The need to upgrade personal protection from Level D to Level C is based on ambient air measurements in the breathing zone with.a portable photoionization detector (PID) with a 10.2 EV lamp. The action level for upgrading from Level D to Level C protection when dealing with gasoline and deisel fuel and their constituents is a measurement of 2 parts per million(ppm) in the breathing zone for a sustained period of 15 minutes. Upgrading to Level C protection, however, can be done at any time for any reason of personal concern for safety. Measurement of a sustained concentration greater than 100 ppm would require evacuation of the site. If separate-phase gasoline and/or diesel fuell is encountered during excavation activities, continuous monitoring for combustible gas concentration and oxygen concentration must also be performed. Measurements greater than 20°o of the Lower Explosive Limit (LEL) for combustible gases, or greater than 23%oxygen require evacuation of the site. Measurements of oxygen concentration less the 19.5% would also require immediate evacuation from the area where the concentration was measured. Action Level Summary Monitoring Device Level D Level C PID/FID <2 ppm 2 ppm- 50 ppm LEL < 1%LEL 1 % - 10 %LEL 02 19.5 % - 23 % < 19.5 % or>23 % 4 Site Health and Safety Plan 3.0 PROJECT PERSONNEL A management structure for this project has been designed which contains several levels of responsibility for implementation of health and safety procedures. Although each level of management share some responsibility for maintaining a safe working environment, the primary responsibility for safe operations ultimately rests with the field personnel and the Site Safety Officer and/or the Project Manager working at the site. It is incumbent upon field personnel to recognize unsafe conditions and to report such conditions to their immediate supervisor. In the event that the individual is not satisfied that the situation has been satisfactorily resolved, questions should be directed to the next higher level of authority in the Health& Safety Management structure until the individual is satisfied that a safe working environment has been achieved. Individuals responsible for health and safety practices a this site are listed the Section 1.0 Emergency Response Summary, and job descriptions for the health and safety management structure are presented below. After exploring all the above paths, any individual that still does not feel that a safe working environment has been achieved would be justified in stopping work and leaving the site. 3.1 Site Safety Officer The Site Safety Officer(SSO)has overall responsibility for the implementation of this health and safety plan. The SSO could be a supervisor for other on-site personnel or could be the only person on-site, depending on the scope of work. The SSO's responsibilities shall include, but not necessarily be limited to,the following: perform air monitoring in accordance with procedures listed in Section 5.2 (if warranted),- upgrade or downgrade Personal Protective Equipment (PPE) level of protection in response to changes in exposure levels, weather, or other site conditions; - know emergency procedures, evacuation routes and other pertinent emergency response information as detailed in the Section 1.0 Emergency Response Summary; report any signs of fatigue of chemical exposures to Project Manager; report any accidents or violations of the health& safety plan to Project Manager; stop work at the site if any condition is detected that presents an imminent danger to the health and safety of workers or the general public. 5 Site Health and Safety Plan 3.2 Project Manager The project manager is responsible for the inspection and documentation of work and assessment activities needed for completion of the project activities. The project manager's responsibilities include the following: - provide authority and resources to SSO to allow for implementation of all necessary safety procedures; - coordinate activities with the Construction Superintendent and to ensure he is aware of any pertinent health& safety requirements; - review project scheduling and planning activities; and, - ensure that field personnel are monitored for compliance with all provisions of the site-specific health and safety plan. 3.3 Construction Superintendent The Construction Superintendent has overall responsibility for the implementation, scheduling and coordination of all personnel and resources needed for the completion of the Immediate Response Action Plan. The project Superintendent's responsibilities include the following: supervise construction activities with the subcontractors to ensure they are aware of any pertinent health and safety information; and, ensure that all employees are in compliance with the provisions of the site specific health and safety plan. 6 Site Health and Safety Plan 4.0 HAZARD ASSESSMENT At sites which contain or are suspected to contain hazardous substances, certain procedures will be implemented to identify, evaluate and control the substances, as follows: l. Recognition-identification of substances, hazardous characteristics of these:substances, and tasks which may result in exposure to these substances. 2. Evaluation-the risk of impact of the substance to personnel, the public and the environment. 3. Control - methods to prevent or minimize the impact of the substance. Recognition and evaluation of hazardous substances can and should be initiated prior to site access. However,recognition and evaluation are also ongoing processes that will continue as work at a site continues. Substances unexpectedly encountered during the course of work require an evaluation of the materials' potential risk or impact. These processes are directly related to the safety of site personnel conducting field investigations. In addition, knowledge acquired by site personnel could be valuable to the health and safety of subsequent visitors to the site. 4.1 Recognition Preliminary information about the hazardous substances which may be present at a site and the parameters which cause them to be hazardous can be obtained from an understanding of the site history. Site use, substances used at the site, disposal of substance(s) (on site or off site) and existing status of operations provide background information on the type of materials which can be expected to be encountered. This initial step is essential to best establish how site personnel can safely obtain additional information to further recognize the hazardous substances at a site. Tasks which may result in exposure to hazardous substances at this site could include drilling operations, well installation, well development, well gauging, ground water, soil, or vapor sampling and construction activities including shoring, cribbing, underground tank removals or trenching operations. 0 7 Site Health and Safety Plan In general,the following conditions are recognized as being potentially hazardous at this site: Flammable vapors- The presence of flammable vapors can present both a potential fire or explosion hazard and a toxic hazard. If the concentration of flammable vapors is measured by a combustible gas indicator (CGI) at concentrations greater than 20% of the lower explosive limit (LEL), personnel should evacuate the site immediately. Oxygen - Oxygen can present hazards in either concentrations higher or lower than the normal atmospheric concentration of approximately 20.5%. Oxygen concentrations greater than 23% are an extreme fire hazard due to rapid oxidation reactions. Oxygen concentrations less than 19.5%post an asphyxiation hazard for personnel. If either the enriched or deficient oxygen condition is observed by personnel on an 02 meter, the area should be evacuated immediately. Organic Vapors-Inhalation of toxic organic vapors is a potential health hazard. This hazard may be reduced by monitoring ambient air with a photoionization detector(PID) and using Personal Protective Equipment (PPE). Physical Hazards - Possible physical hazards would include road traffic for activities conducted within roadways or parking areas, and hazards associated with heavy equipment used on site. Equipment hazards can be associated with direct exposure to falling loads or moving machinery, or can be due to accidental contact of machinery with electric, gas, or water utility lines. 4.2 Evaluation - The potential risks or impacts of hazardous substances suspected or known to exist at a site must be evaluated prior to entering the site. Site history is the initial source of information which must be used to determine the level of personal protection to be worn by site personnel while collecting further field information for evaluation. Levels of personal protection are summarized in Section 5.1. The minimum level of protection for site personnel during a site investigation is Level D. This level should be utilized where the atmosphere contains no known imminent hazards and the type of work involved precludes exposure due to splashes, immersions, or the potential for unexpected inhalation or contact with hazardous levels of chemicals. An ongoing air monitoring program will be established to evaluate exposures to personnel. Ambient air will be monitored for organic vapor concentrations at all sites where the possibility for airborne exposures exist. Ambient air will be monitored for 02 concentrations and combustible gas concentrations when the present of separate-phase fuel oil and/or confined spaces creates a potential for explosive or oxygen-deficient conditions. 8 Site Health and Safety Plan 4.2.1 02/LEL Monitoring Continuous monitoring will be performed within 02/L'EL meter during operations such as trenching, excavation, or tank removals where there is a potential for build-up of explosive gasses for development of oxygen-deficient atmosphere. An extension sampling tube will be run from the detector instrument intake to the bottom of the excavation in order that samples are drawn from the "worst case"location for accumulation of vapors that are heavier than air. The 0,/LEL meter will be calibrated in accordance with the manufacturer's recommendations on a regular basis. 4.2.2 Organic Vapor Monitoring Organic vapor concentrations in ambient air will be measured with a portable photoionization detector(PID)which has been previously calibrated with a gas standard equilibrated to read as benzene. Monitoring will be conducted in the breathing zone every fifteen minutes for sites that have been approved for Level D PPE, or on a continuous basis for sites that require Level C protection. The breathing zone is defined as the sphere of approximately one-foot radius surrounding a worker's head under normal working conditions. Ambient air monitoring will also be performed at the site perimeter.at one-hour intervals in order to evaluate any potential exposures to the general public. The site perimeter is defined as the lesser of, 1)the distance to the property boundary, or 2) a radius of 100 feet from the exclusion zone boundary. The PID meter used will be calibrated in accordance with the manufacturer's recommendations on a regular basis. All air monitoring results will be recorded on the vapor monitoring form attached in Appendix A. 4.2.3 Physical Hazards All efforts will be made to identify-utility line locations.prior to initiating any subsurface work at the site. In addition, heavy equipment must be checked for clearance to any overhead power lines and must maintain a minimum fifteen-foot clear distance at all times. 4.3 Control This Health and Safety Plan has been developed with the purpose of protecting on-site personnel from exposures to hazardous substances or situations. Observance of all guidelines and procedures contained in the Plan will minimize the risk to personnel involved in site activities and to the general public. 9 Site Health and Safety Plan The plan has been prepared specifically for ADVANCED ENVIRONMENTAL, INC., and BENNETT & O'REILLY, INC., based on the data available from physical testing and research conducted at the site in conjunction with the Immediate Response Actions taken to date. Due to some uncertainties inherent to this type of work, the health and safety plan will continually be re-evaluated and modified in accordance with the industry standard of care at the time of these activities. As such,this plan shall not be construed to express or imply a guarantee or warranty against personnel injury or property damage. Any such occurrence will be handled in a manner consistent the Terms and Conditions of employment. 10 Site Health and Safety Plan 5.0 SAFETY EQUIPMENT All required equipment will be present and readily accessible at all sites where hazardous substances or situations may be encountered. 5.1 Personal Protective Equipment (PPE) Level D Protection is the minimum acceptable level of PPE for this site. Level D PPE includes: a) Coveralls b) Gloves,chemical-resistant c) Boots,shoes,chemical-resistant,hard toe and shank d) Boots,(outer),chemical-resistant(disposable)* e) Safety glasses or chemical splashgoggles* f) Hard hat g) Face shield* Level C PPE includes: a) Full-face or half-face purifying respirators(OSHA approved) b) Coveralls c) Hooded chemical resistant clothing (overalls, two-piece chemical-splash suit, disposable chemical- resistant overalls) d) Gloves(outer),chemical-resistant* e) Gloves(inner),chemical-resistant f) Boots,chemical-resistant hard toe and shank g) Boot covers,chemical-resistant(disposable)* h) Hard hat i) Escape mask* D Two-way radios* k) Face shield* 1) Buddy system required * Optional, as applicable. ADVANCED ENVIRONMENTAL, INC., and BENNETT & O'REILLY, INC., do not perform work that would require Level A or Level B PPE. The Site& Safety Officer and/or Project Manager is responsible for recognizing conditions that would call for an upgrade of PPE from Level D to Level C protection during site operations. The criteria for establishing protection levels is summarized in Section 2.0 Personal Protection/Action Levels Summary. 11 Site Health and Safety Plan 5.2 Site Safety Equipment Equipment which should be available to all personnel working on the site is listed below. 5.2.1 Air Monitoring Instruments - Calibrated HNU meter or other suitable portable monitoring photoionization device. This device should be selected to provide maximum sensitivity for the compounds expected to be present. Understand the limitations and applications of the instruments. Calibrated 0,LEL meter. This device should be used to monitor the potential for explosive conditions and to determine the oxygen content in confined spaces. 5.2.2 Copy of Completed Site Safety Plan - Emergency center telephone numbers Hospital location Safety procedures 5.2.3 First-Aid Kit - Sized to accommodate the number of personnel on site Located in the established clean zone 5.2.4 Fire Extinguisher - Minimum size 10 lb A-B-C Located in the established clean zone, or as appropriate 5.2.5 Decontamination Equipment - Five-gallon water jug - Brush - Basin - Decontamination solution for washdown - Located in the established decontamination zone. 12 Site Health and Safety Plan 6.0 WORK ZONES Zones will be identified by the Site Safety Office prior to initiating work at the site. This identification may involve either a physical marking of the zones on the ground surface at the site, or it may simply be accomplished by establishing zone identifications verbally with on-site personnel, depending on the complexity and magnitude of the site operations. Definitions of the work zone classification are presented below. Zone#1. Clean/Safety Zone(> 10' from excavation) All support equipment(first-aid kit, eye wash bottle,clean personal protective equipment, etc) will be in the area designed as clean/safety zone. Smoking will only be allowed in this area_ Zone#2 Contamination Reduction Zone (< 10' from excavation) This is a buffer zone for exit and decontamination procedures before proceeding into the clean/safety zone. Leave gloves,air monitoring equipment and any other equipment in Zone #2. Zone#3 Hot Zone (within excavation) This is the zone where contamination does or could occur. When drilling, this is the area wit-im a twenty-foot radius of the operating drill rig. Appropriate protective equipment should be worn in this zone. 13 Site Health and Safety Plan 7.0 HEALTH AND SAFETY REQUEREMENTS General requirements for safe work practices and training of personnel are detailed below. 7.1 Training All BENNETT&OREILLY personnel working at the site will have received a minimum of forty hours of hazardous waste site instruction and three days of field experience with a trained, experienced person on-site. This training will be in accordance with the requirements of the OSHA Hazardous Waste Operations regulation 29 CFR 1910.120. BENNETT & OREILLY personnel will also receive eight hours of refresher training per year. All contractors working at the site will be responsible for maintaining the appropriate level of training for their employees according to OSHA regulation 29 CFR 1910.120. 7.2 Medical Surveillance Program A yearly physical examination is conducted on BENNETT & OREILLY employees with 40 hour OSHA HAZWOPER training. Physical examinations are repeated on a yearly basis for normal exposures, or more frequently if a specific over-exposure is suspected. 7.3 General Work Practices This section describes standard practices to be used for general operations that are conducted at the ground surface. Specific procedures to be used when entering a confined space are attached as Appendix B. Specific regulations pertaining to excavation and trenching activities are attached as Appendix C. 7.3.1 Identify Pertinent Information With Site Project Manager locations of concern- dumps, containment ponds, spill areas, etc; access and egress to and from site with alternate routes; and site work zones 14 Site Health and Safety Plan 7.3.2 Have And Be Familiar With Field Map - plan work route and work locations; - know areas that contain underground gas and electrical lines (this information should be obtained from Dig Safe).- - check with site personnel for location of underground hazards (i.e.chemicals, tanks, utilities, etc.),- - identify location of nearest phone; and, - know access and egress locations. 7.3.3 Avoid Obvious Hazardous Areas Including - lagoons,berms, impoundments; - discolored soil and water areas, drums, etc.; - confined/enclosed structures,tanks, etc; and, - any areas visually posted as dangerous. 7.3.4 Protect Against Physical Hazards: - use high visibility cones, barricades, and vests where traffic hazard exists; always watch operating machinery closely and be aware of the existence of "kill switches" or other means of machine shutdown; and maintain good communications and visual contact among all workers at the site. 7.3.5 In the Event of Accident,Physical Reaction or Excessive Exposure: Leave area immediately and proceed to designated clean zone. Administer first aid, if appropriate. Obtain medical assistance for serious exposures. Any employee who becomes sick or injured on the job must receive medical clearance and clearance from the Project Manager before returning to the site. Overexposure can be caused by: * spills, splashes,immersions, inhalation Symptoms of overexposure may include,but not limited to, any of the following physiological reactions: * dizziness, nausea, rash, asthmatic reactions * abdominal pain, distorted vision/hearing * excessive coughing, swelling, headaches � 15 Site Health and Safety Plan 8.0 DECONTAMINATN PROCEDURES Activities conducted at this site have the potential to contaminate personal protective equipment, monitoring equipment, and/or other physical equipment. If the Site Safety Officer judges that contamination of equipment has occurred during site activities, all such equipment shall be decontaminated using the following general procedures: Wash equipment and/or boots and gloves which.have come in contact with hazardous substances with a detergent solutions followed by clean water. If contaminant is of an oily nature, methanol may be used as a cleaning solution. - Properly dispose of items that cannot be decontaminated. When using Level C PPE, respirator cartridges should be discarded, and respirators should be washed in a mild soap solution and rinsed with clean water. Construction equipment and/monitoring equipment will be cleaned at the discretion of the Site Safety Officer. Cleaning procedures may include detergent washing, methanol rinse, or steam cleaning. 16 Site Health and Safety Plan 9.0 FIELD TEAM REVIEW Each field team member shall sign this section before being permitted to work on-site. I have read and understand this site-specific Health and Safety Plan. I will comply with the provisions contained therein. Site/Project:. Name (Printed) Company Signature Date 17 H & S APPENDIX A VAPOR MONITORING FORM 18 TANK/SOIL REMOVAL AIR MONITORING FORM Project Number: Location: Representative: Date: Arrival Time: Departure Time: Temperature: Weather Conditions: Air Monitoring Device(s): TANK/EXCAVATION PIT AIR MONITORING LEVELS Above Pit Inside Pit COMNMNTS 19 IF7 1 H & S APPENDIX B CONFINED SPACE ENTRY PROCEDURES 20 CONFINED SPACE ENTRY PROCEDURES The purpose of this guidance is to prevent serious accidents which could result from entry into confined spaces. Use of a combustible gas indicator and oxygen meter is required. No on-site personnel will be allowed into a confined space unless there is a minimum of one observer that will remain outside of the confined space,and at least one additional person that has been informed about the entrance and placement of the confined space. 1. Confined Space Policy The on-site personnel are not to enter a confined space unless a full working knowledge of that space and/or a confined space permit has been completed. It is the responsibility of the project supervisor to request a confined space entry permit from the Project Manager. The confined space permit shall be signed by and explained to each employee working the confined space project and their signatures will indicate the understanding of the rules outlined in the permit. 2. Confined Space Entry Procedures Each confined space shall be tested for combustible vapors,oxygen level,and organic vapors. When levels of combustible vapors exceed ten percent of the lower explosive limit LEL,all sources of ignition shall be removed. Entry shall not be made until the space is flushed or purged below the 10 percent LEL level. Each confined space must be tested for oxygen content prior to entry. The minimal acceptable percent of oxygen is 19.5 percent. If this level cannot be met,site personnel will not enter the confined space. Chemical protective equipment must be worn if the potential exists for contact with a chemical from which protection is necessary. The prc ject supervisor is responsible for evaluating general safety hazards including permits,adequate lighting, tools,etc. Before work is initiated in a confined space,all product lines and electrical lines will be locked and tagged. A ladder is required in all confined spaces deeper than the employees shoulders. The ladder shall be secured and not removed until all employees have exited the space. 3. Confined Space Entry Procedures for Safety Observer Employees entering a confined space must be under the constant observation of a safety observer. It is the safety observer's responsibility to follow these procedures: a. A valid confined space entry permit must be at the site. b. Rescue equipment or emergency phone numbers must be available at the site. C. The safety observer must know the location of the nearest telephone, emergency numbers and fire extinguisher. e. The safety observer must remain in constant contact with the employee(s)in the confined space except to report and emergency. 21" H & S APPENDfK C OSHA TRENCHING REGULATIONS 22 SUMMARY OF OSHA CONSTRUCTION STANDARDS FOR EXCAVATIONS (29 CFR Part 1926.650-.652) 1926:650 Scope,application,and definitions applicable to this subpart Excavations are defined to include trenches. 1926.651 General requirements(applies to all excavations) a) Surface encumbrances-Shall be removed or supported,as necessary,to safeguard employees. b) Underground installations - Prior to start of excavation, utility companies shall be contacted within established or customary local response time to estimate locations of underground utility installations. When excavation operations approach estimated locations,the exact locations shall be determined by safe and acceptable means. While excavation is open,underground installations shall be protected and/or supported as necessary to safeguard employees. c) Access and egress-Structural ramps must be designed by a competent person. If ramps are for use of equipment,the competent person must be qualified in structural design. Means of egress from trench excavations>4 feet deep,such as a stairway,ladder or ramp shall be provided so as to require no more than 25 feet of lateral travel for employees. d) Exposure to vehicular traffic-Reflectorized or high-visibility garments should be worn if exposed to traffic. e) Exposure to falling loads-No employees shall be permitted underneath loads handled by lifting or digging equipment. Employees shall stand away from vehicles being loaded or unloaded. f) Warning system for mobile equipment-Where mobile equipment is operated adjacent to an excavation, or if the equipment is required to approach the excavation and the operator does not have a clear and direct view of the excavation edge,a warning system,such as barricades,hand or mechanical signals,or stop logs shall be used. g) Hazardous atmospheres-In addition to requirements in Subpart D and E(1926.50- 1926.107): In any excavation,provide proper respiratory protection or controls such as ventilation to prevent exposure to atmospheres containing less than 19.5%02 and to prevent exposure to greater than 20%of the lower'flammable limit and provide testing of controls. Emergency rescue equipment-shall be provided if hazardous conditions exist or may reasonably be expected to develop. For trenches>4 feet and if hazardous conditions exist or may exist,perform monitoring,prior to entering trench. h) Protection from hazards associated with water accumulation-Employees shall not work in excavations with accumulated water or where there is the potential for accumulated water unless adequate precautions (such as special support or shields systems,water removal,or the use of a safety harness and lifeline)are provided. All water removal equipment shall be monitored.by a competent person. If excavations interrupt the natural drainage of surface.water,diversion ditches,dikes,.or other means shall be used to prevent surface water]rorppntering the excavation and to provide drainage for the areadaacent to the excavation. Excavations subj ectto runoff from heavy rains will require and inspection hX q.'competent person. 23 i Stability of ad ace t c n structures - Support systems shall be provided where the stability of buildings, footings,sidewalks,pavement,or to other appurtenant structures,is endangered by excavation operations. j) Protection of emplovees from loose rock or soil - Scaling to prevent loose material, installation of protective barricades, or other means may be required to protect employees from material for the excavation face. To prevent material or equipment from falling or rolling into excavations,all materials or equipment shall be kept al least 2 feet from the edge or excavations,or retaining devices shall be used. k) Inspections (only when employee exposure can be reasonably anticipated) -Daily inspections by a competent person shall be conducted prior to start of daily work, and as needed throughout the shift. Inspections shall also be conducted after every rainstorm or other hazard increasing occurrence. Employees shall be removed if there is evidence of hazardous situations. 1) Fall protection-Walkways or bridges with standard guardrail shall be provided where employees or equipment are required or permitted to cross over excavations. Adequate physical barriers shall be provided at all remotely located excavations. Upon completion, temporary excavations shall be backfilled. 106.652 Requirements for protective systems Trenches>20 feet deep-Protective systems must be designed by a professional engineer. Trenches<20 feet deep-Follow flowchart in Appendix F,Subpart P.In general: Soil Type Maximum Allowable Slope Stable Rock Vertical Type A(open<24 hrs,<12 feet) 1/2:1 Type A 3/4:1 Type B 1:1 Type C 1-1/2:1 d) Materials and equipment-Materials and equipment shall be free from damage or defects,and used and maintained as recommended by the manufacturer. If materials or equipment are damaged,they must be inspected by a competent person prior to continues use. If the competent person cannot assure the materials or equipment are suitable for future use,they must be removed and be evaluated and approved by a professional engineer before being returned to service. e) Installation and removal of support-Support system members shall be installed and used to ensure the safety of workers,which may include the installation of additional members prior to temporary removal of any individual members. Removal shall begin at,and progress from,the bottom of the excavation. Backfilling shall progress together with the removal of support systems. Excavation of material to a level>2 feet below the support shall not be permitted. f) Sloping and benching ems-Employees shall not be permitted to work on the faces of sloped or benched excavations at levels above other employees except where adequate protection from falling material is provided. h) Shield systems-Employees shall not be allowed in shields while they are being installed, removed,or moved vertically. Excavation of material to a level>2 feet below the shield shall not be permitted 24 APPENDIX F 3ENNET TO 'REILLY, Inc. ngineering, Environmental & Surveying Services 1573 Main Street aq Sanitary 21E/Site Remediation Property Line PO Box 1667 Site Development Hydrogeologic Survey Subdivision Brewster,MA 02631 Waste Water Treatment Water Quality Monitoring Land Court 508-896-6630 Water Supply Licensed Site Professional Trial Court Witness 508-896-4687 Fax QUALITY ASSURANCE & QUALITY CONTROL PROGRAM Quality Assurance & Quality Control Program For Soil and Groundwater Sampling INTRODUCTION The Quality Assurance & Quality Control`(QA/QC) Program outlines the purpose, policies, organization and operations to support sampling work conducted by BENNETT&O'REILLY,INC... The procedures and protocal represented herein are consistent with the MA DEP "Standard References for Monitor Wells" [WSC-310-91], and the recommendations of a MA certified laboratory. Implementation of this program will help to ensure the validity of data used to provide professional engineering and environmental opinions to clients. The following definitions are used in the QA/QC Program: Quality Assurance refers to the concepts used in defining a system for verifying and maintaining a desired level of quality in a product or process. Quality Control is a specific,step-by-step description of how the Quality Assurance Program will be carried out. This QA/QC Program guides field sampling activities. Project specific QA/QC Programs are adopted when warranted. Modifications to the QA/QC Program may be made only after specific approval by the QA/QC Officer(Project Manager). 1 The specific objectives of the QA/QC Program are to: 1. specify the level of quality of each field procedure used in collecting samples; 2. identify deficiencies in field procedures which might affect the quality of data; and 3. require sufficient documentation to verify the credibility of the sampling methods employed. PROGRAM ORGANIZATION AND RESPONSIBILITY The Project Manager of BENNETT & UREILLY, INC., is responsible for the quality of work -produced. The Project Manger directs the QA/QC Program to document the control of field efforts and resulting data. In this capacity,the Project Manager is expected to do the following: 1. prepare detailed QC Plans; 2. obtain analytical and sampling procedures reference materials; 3. ensure that all field test and measurement equipment is maintained and calibrated properly; 4. monitor quality assurance activities to ensure conformance with authorized policies, procedures, and sound practices, and recommend improvements as necessary, 5. ensure that all field sampling is conducted in accordance with guidelines contained herein, 6. oversee all field sampling efforts to detect conditions which might directly or indirectly jeopardize the utility of resulting analytical data, such as improper calibration of equipment or cross-contamination through improper storage of samples; 7. ensure that sample handling procedures are adequate for the sample types received; 8. inspect the quality of purchased sampling materials. 2 SAMPLE MANAGEMENT, COLLECTION,AND PREPARATION Introduction Sample management and stringent documentation are essential for successful quality assurance. The procedures in this section are designed to ensure collection of samples which truly represent the matrix being sampled by eliminating trace levels of contaminants from external sources. Sample Management The management of samples,up to the point of delivery to the laboratory for analysis, is under the supervision of the Project Manager,who shall ensure that samples are collected,labeled,preserved, stored, and transported according to the prescribed methods. If significant deviations from the sampling protocol occur, resulting in a suspected compromise of the sample integrity, all samples collected during the sampling effort prior to correction of the procedure will be discarded and fresh samples collected. Sample Collection Groundwater Monitoring wells will be sampled in accordance with the following sampling procedures: 1. Identify the well and record the well number on the groundwater sampling record an an Monitoring Well Sampling Log (attached). 2. Open the well cap and measure total organic volatile (TOV) concentrations at the wellhead with the use of a portable photoionization detector. Record levels detected. 3. Measure groundwater level to the nearest 0.01 foot from the top of the well casing using a water level indicator. Record water level on a Monitoring Well Sampling Log (attached). Water level indicators will be decontaminated between wells. 4. The volume of standing water in the well casing will be calculated and recorded on the Monitoring Well Sampling Log. At least three well volumes will be purged either by pump or disposable bailer. Newly installed monitoring wells will be developed by purging at least ten volumes. Purging of wells will be complete when either dissolved oxygen, pH, conductivity or temperature has stabilized relative to previous sampling rounds. Once the purging is complete,wells will be screened for each of the above parameters and recorded on the Sampling Log . 5. Samples will be collected using either a disposable bailers or pump. Samples will be transferred into appropriately sterilized/preserved containers, taking care to minimize agitation of the sample [Refer to attached "Recommended Sample Containers..." Groundwater Analytical]. 3 6. Sample containers will be properly labeled with tags provided by the laboratory. Samples will be logged in on a chain-of-custody form. 7. Samples taken for precipitate metal analysis will be acidified to a pH of less than 2.0 in the field. When sampling water for volatile compounds, care must be exercised to prevent loss of compound through evaporation, and to control susceptibility to outside contamination. Precautionary measures include: 1. avoiding engine exhaust,gasoline containers,degreasing solvents,solvent-laden rags and non-compatible decontamination agents; 2. sampling bottles will only be opened at the time of sampling and quickly closed after collecting the sample,preventing aeration of the sample with the atmosphere or any other gas; 3. slowly filling bottles to capacity with sample and securing cap without entraining air bubbles; 4. inverting the bottle while tapping lightly to check for air bubbles; 5. adding additional sample to eliminate air bubbles if present,repeating steps 3 and 4; 6. placing samples on ice (approximately VQ immediately after collection in a dark, dry location; 7. segregating samples with a secondary barrier such as zip-lock bags, etc.; and 8. analyzing sample as soon as possible within the specific holding times after collection. Pump tubing will be decontaminated as follows: 1. Pump non-phosphate detergent solution through system for two minutes. 2. Pump clean hot tap water through system for two minutes or until clear, whichever is longer. 3. Pump analyte-free water through system for two minutes. 4. Seal tubing ends; wrap and label with date of cleaning. 4 Soils When collecting and screening soil samples, the procedures to be used are: 1. Prior to sampling surficial locations,surface vegetation,rocks,leaves,and debris will be cleared from the sample point to allow collection of a clean soil sample. If surficial soil samples are to be collected,a hand trowel or shovel and spatula will be used. The sampling equipment will be decontaminated as outlined below. 2. Boring samples will be collected via drilling rig-operated split spoon procedures. Soil samples collected from excavations or test pits will be collected directly with an auger (if necessary) from grade to approximately four feet below grade. Samples collected at deeper depths will be obtained directly from the bucket of the backhoe. A stainless steel spatula will be used to remove soil from the backhoe bucket for placement in the appropriate sample containers. 3. Soil samples collected for TOV screening will be placed in glass soil jars with aluminum foil placed under the screw cap. Samples will be allowed to warm to ambient temperature before screening or will be screened in a heated vehicle after warming. The jar will be shaken for fifteen seconds prior to warming and after warming to ensure proper headspace development. Total organic vapors will be measured via a portable photoionization detector (PID) and their concentration recorded either on a Geological Borehole Log or field log. 4. Soil samples will.be stored and shipped in appropriate sealed containers. 5. Sample containers will be marked to indicate sampling date, time, location, and depth. Samples will be logged in on chain-of-custody forms (copy attached). 6. The stratigraphy of each soil boring and test pit excavation, and the construction of each monitoring well will be recorded by the on-site geologist on the appropriate Geologic Borehole Log or test pit field log (copies attached). When sampling soils for volatile compounds, care must be exercised to prevent loss of compound and to control susceptibility to outside contamination. Precautionary measures include: 1. avoiding engine exhaust,gasoline containers,degreasing solvents,solvent-laden rags and non-compatible decontamination agents; 2. opening sampling bottles only at the time of sampling and quickly closing after collecting the sample; 3. placing samples on ice(approximately 4° Q immediately after collection in a dark, dry location; 5 I 4. segregating samples with a secondary barrier such as zip-lock bags, etc.; and 5. analyzing sample as soon as possible within the specific holding times after collection. Soil sampling equipment (shovel, auger, etc.) will be decontaminated between each sampling location with a potable water rinse, alconox soap wash, and a final potable water rinse. Drilling and excavating apparatus (augers, rods, casing, core barrels, backhoe bucket, and other equipment coming in contact with the borehole or excavation)will be decontaminated between each boring and excavation via steam cleaning. If necessary,an alconox soap wash followed by a steam cleaning will be included. Sample Preservation To prevent or retard the degradation/modification of chemicals in samples during transit and storage, the samples will be refrigerated at or below 4° C in appropriately preserved containers. Samples will be delivered to the laboratory by courier or by overnight delivery service. DATA MANAGEMENT Logging of Samples The accountability of a sample begins when the sample is taken from its natural environment. Sample handling (chain-of-custody) records must be completed at the time of sampling. The following chain-of-custody procedure must be implemented by the Field Team Leader to assure sample integrity. 1. The samples are under custody of the Field Team Leader if: a. they are in his (or her)possession; b. they are in view after being in possession: c. they are locked up or sealed securely to prevent tampering; or, d. they are in a designated secure area. 2. The"original'of the sample handling form must accompany the samples at all times after collection. A copy of the sample handling form is kept by the Field Team Leader. 3. When samples are transferred in possession, the individuals relinquishing and receiving will sign, date, and note the time on the form. 6 The Sampling Handling Record will contain information to distinguish each sample from any other sample. This information will include: 1. the project for which sampling is being conducted; 2.. the matrix being samples (air, groundwater, soil, etc.); 3. the sampling date and time; 4. field sample identification number and chain-of-custody identification number; 5. the number and type of containers and the type of preservative used (if any); and, 6. signature of the person performing the sampling. Each sample will be assigned a unique identification number,which will be marked on the sample container. The sample handling record will be forwarded to the laboratory with the samples. As a precaution against this record being lost or altered,the sampling personnel will retain a copy of the sampling handling record documenting all information up until the first change of sample custody. This record will be filed by the Project Manager. Sample Identification Numbers Reporting of date to the data management system will require the assignment of a unique identificat'on number to each sample collected(including quality control samples).'A record will be maintained by the Project Manager to associate the field sample with the various identification numbers used to analyze the field sample. Specific sample identification procedures are developed for each field sampling effort by the Project Manager. 7 FORM SAMPLES BENNETT & O'REILLY, Inc. MONITOR WELL SAMPLING LOG 1573 Main Street, P.O. Box 1667 Brewster, MA 02631 Engineering and Environmental Services (508)896-6630 FAX(508)896-4687 CLIENT DATE(S) TIME: TIDE: LOCATION JOB NUMBER SAMPLER MEASURING POINT GROUND SURFACE OR T.O.C: T.O.C. Elev. of Total Standing Water Static Volume HNU Dissolved Well reference Depth Water Table Conductivity Temperature Number point of Well Water Height Elevation Volume Purged PI-101 Depth to pH Oxygen (F) Comments: (feet) (feet) (feet) (feet) (feet) (gallons) (gallons) (PP-) (mg/L) NOTES: 1573 Main Street,P.O. Box 1667 BENNETT & OREILLY, Inc. Brewster,MA 02631 Engineering and Environmental Services (508) 896-6630 MONITOR WELL SAMPLING LOG CLIENT DATE(S) LOCATION JOB # MEASURING POINT SAMPLER GROUNDSURFACE OR T.O.C. Well Elev. of Total Depth to Standing Water Static Volume HNU Comments Number reference:- Depth of Water. Water Table Volume Purged PI-101 poir_t Well (Feet) Height Elevation (gallons) (gallons). (ppm) (feet) (feet) (feet) (feet) NOTES: Inc. 1 s73 Main Street, P.O:Box 1667 BENNETT & O'REILLY Brewster, MA 02631 Engineering and Environmental Services (508) 896-6630 MONMOR WELL SAMPLING LOG RESPIRATION ANALYSIS CLIENT DATE(S) LOCATION JOB # SAMPLER Well Total Approx. Standing Length of HNU Methane Oxygen Carbon Comments: Number Depth of Depth to Water screen PI-101 (%CH,) (%0,) Dioxide Well Water Height above (ppm) (%C0" (feet) (feet) (feet) SWL NOTES: BENNETT & O' ILLY, Inc. Sheet of 1573 Main Street 5 - -08 896 b630 PO Box 1667 508-8964687 Fax Brewster.,MA 02631 Job Number: Date: Time: Test Hole Number: Job Name: Witness: Casing I. D.: Ground Elevation: Reference Elevation (TOC): Falling Head ❑ Rising Head ❑ Aquifer Saturation Thickness (If Confined): Depth of Boring(A): Well Screen Length(L): Length of Test Section(L): Depth of Groundwater Table Depth of Top of Test Section.(B): Type.of Material in:Test Zone Notes: 2r TIME ELAPSED WATER ACTIVE (sec.) TIME(sec.) h/Ho DEPTH(x) HEAD(h) �X B ^ STATIC . A — r —1 2R I h=H-X(falling head) or h=X-H (rising head) Ho=H-Xo (falling head) or Ho=.Xo-H (rising head) Xo=X at t=0 A,B, H&L are defined above. Pump 8, Flow Rate Location: TOG: Location: TOC:, Location: TOC: NOTES: Time Time Depth to Water Static Water Lv. Draw Down Depth to Water Static Water Lv. Draw Down Depth to Water Static Water Lv. Draw Down pH/Cond./Temp. (sec). 0 1 2 3 4 ,5 6 7 8 9 15 _ 30 (sec.) 45 (min) Y 1 2 3 4 5 6 . 7 8 9 10 20 30 40 50 60 70 80 90 100 190 280 370 460 550 640 730 820 910 1000 BENNETT & O'REILLY, Inc. Sheet of 1573 Main Street 508-896-6630 PO Box 1667 508-896-4687 Fax Brewster,MA 02631 Sieve Analysis Data and Computation Sheet Job Number: Date: Job Name: Sample Number: Sample Collected By: Sample Tested By: Notes SIEVE WEIGHT PERCENT CUMULATIVE' PROJECT OPENING SIEVE RETAINED RETAINED PERCENT MANUAL MILLI- MESH IN GRAMS (Cumulative) FINER SPECIFICATION METERS (Cumulative) PASSED MESH SIEVE TOTAL Sample Weight Wet: Sample Weight Dry: Percent Moisture: Sample Weight Passed Through Sieves: BENNETT & O'REILLY, Inc. Sheet of 1573 Main Street 508-896-6630 PO Box 1667 508-896-4687 Fax Brewster,MA 02631 Job Number: Date: Job Name: SAND GRAVEL SILT SAND Test Hole Number: Witness: Drilling Contractor: PEAT CLAY Sampling Method: GEOLOGIC BOREHOLE.LOG Type Blows per %of Well Lithology/Sediment ithology Depth of Depth Specification.&Remarks Description Sample 6"Drive Recovery PID Response (PPm) 5 10 15 20 25 SWL: 30 35 40 45 50. BENNETT&UREILLY,Inc. Project Name: Sheet 1573 Main St.,P.O.Box 1667 Project Location: Boring No. Brewster,MA.02631 Project Number: Location Surface Elev. Groundwater Readings Casing Sampler Core Start Date Date Reading Type Finish Date 1 Size I.D. Driller 2 Hammer Wt. Inspector 3 Hamer Fall Sample Sampling Inches TOV SPT Well Depth type-No. Depth(ft) Pen Rec Blow Count 6" Reading N-Value Soil Description Installation I i 5-ft 10-ft 15-ft 20-ft I Sand Cohesive Soils Granular Soils Sample Type NOTES: Gravel < 2 =very soft < 4 = very loose SS-split spoon Sand/Gravel 2-4 =soft 5-10 =loose ST-Shelby tube Silt/Sand 4-8 = medium stiff 11-30 = medium AF-aguer flights Top/Sub Soil 8-15 = stiff 30-50 dense RC-rock core Clay 15-30 =very stiff > 50 = very dens MA-Microliners Fill I > 30 =Hard I I HA-Hand Auger BENNETT & O'REILLY Inc. REPORT NUMBER: 508-896-6630 1573 Main Street 508-896-4687 Fax PO Box 1667 Brewster,MA 02631 INSPECTORS DAILY RECORD OF WORK PROGRESS. . Job Numbe-: Date: Job Name: Feature: Contractor: Type of Wcrk: Weather Conditions: Temperature: Contractor's Work Force(Indicate classification,including Subcontractor personnel) Equipment in use or idled(identify.which) Materials or equipment delivered,quantity or pay items placed Non-conforming materials or work,field problems,inspections of previously reported deficiencies Summary of construction activities M!Y/ ►lf.l ! /{� FAX(508)759-4475 Project Name: Firm: TURNAROUND ANALYSIS REQUEST Valallles Semlvalatlles PesUHerh/PCBs Metals Petroleum drusarben Has. General Chemistry Other ❑ STANDARD(10 Business Days) Pxirantahle el. W 11 IVri.TPH I waste Project Number: Address: ❑ PRIORITY(5 Business Days) F o ❑ RUSH(RAN- (Rush requires Rush Authorization Number) o ❑ o d 3 0 0 .S Sampler Name: City/State/Zip: $ s Please FAX ❑ YES ❑ NO o w o FAX Number: Project Manager: Telephone: BILLING o o a o 0 0 0 0 E 9 Purchase Order No.: GWA Reference No.: o ° ta INSTRUCTIONS:Use separate line for each container(except replicates). M a no t s r o ❑ ❑ ❑ ❑ ❑ ❑ ❑ o o ❑ o ❑ o o Sampling Matrix Type Containers) Preservation Filtered o z g a d g o 12 „ A LABORATORY a o € _ w w W o< aja, $? i W g a T, - ' ' ❑ a °1 NUMBERSAMPLE o da NTIFI . (Lab Use Only)IDE O ° oe a o 9 3 o .F o o o o F 9�- 81 e $ s R z � s e $ s a g a ❑ ❑ ❑ ❑ ❑ ❑ ❑ o ❑ ❑ o ❑ o ❑ ❑ a ❑ ❑ ❑ ❑ ❑ ❑ ❑ ❑ ❑ 01010 ❑ ❑ ❑ ❑ i REMARKS/SPECIAL INSTRUCTIONS DATA QUALITY OBJECTIVES CHAIN-OF-CUSTODY RECORD Regulatory Program Project Specific OC NOTE:All samples submitted subject to Standard Terms and Conditions on reverse hereof. ❑Safe Drinking Water Act Many regulatory programs and EPA methods require project Relinquished by Sampler: Date Time Received by: Receipt Temperature: ❑MA DEP Form specific CC.Project specific OC includes Sample Duplicates, ❑NPDES/Clean Water Act Matrix Spikes,and/or Matrix Spike Duplicates.Laboratory OC Is Specify State: not project specific unless prearranged.Project specific OC ❑RCRA/Haz.Waste Char. samples are charged on a per sample basis.For water samples, Relinquished by: Date Time Received by: Shipping/Airbill ❑MA MCP(310 CMR 40) each MS,MSD and Sample Duplicate requires an additional _ Number: Reportable Concentrations sample aliquot. ❑RCGW-1 ❑RCS-1 Project Specific OC Required Selection of OC Sample Relinquished by: Date Time Received by Laboratory: Custody Seal/ ❑RCGW-2❑RCS-2 ❑Sample Duplicate ❑Selected by laboratory Cooler NumbeSerial ❑MA Dredge Disposal p Matrix Spike ❑Please use sample: ❑NH❑RI❑CT❑ME Method of Shipment: ❑GWA Courier❑Express Mail ❑Federal Express Specify Category: ❑Matrix Spike Duplicate 0 UPS ❑Hand 0 �iYYl e02WC2T LAB0RA7VRLW,LVC- A CST.NO.:NMA 063 449 RTZ 130 SANP1'1'CN, NA 08563 500( -6460) Pq 0 359-6460 LAB USE ONLY: FAX(SW)9M-6446 GNE: UISITION: ECEIVED: SAMPLE NO.: TIME: NO. COPIES: PM 20.00 Surchar a PICK UP: MAIL: WATER LOCATION: LING ADDRESS: SAMPLED BY: FMENT/AMT. RECEIVED: WELLSPECS.: - — Lab use only. LYSIS REQUESTED: WATER SAMPLE TYPE: FHA-HUDNA HETEROTROPHIC PLATE COUNT COPPER NEW WELL COLIFORM. BACTERIA LEAD EXISTING WELL PH ARSENIC TOWN WATER CONDUCTANCE SILICA _ IRRIGATION NITRATE-N ZINC FILTER/CONDITIONER NITRITE-N TDS MISCELLANEOUS SODIUM TANNINS NEW MAIN IRON SULFIDE TITLE 5 MANGANESE SILVER POOL SPA CHLORINE POTASSIUM RCRA 8 CALCIUM IOC's COLIFORM BACTERIA MAGNESIUM SEC. CONT. PSEUDOMONAS HARDNESS FLUORIDE HETEROTROPHIC PLATE COUNT ALKALINITY OTHER ANALYSIS REQUESTED: SULFATE FECAL COLIFORM CHLORIDE METHOD: DEP SAMPLES COLOR VOLATILE ORGANICS PWS#: TURBIDITY METHOD: SAMPLE SITE: FREE CO2 METALS (ie. Sink) AMMONIA-N METHOD: SAMPLE LOCATION: ODOR (ie. Kitchen/WelI) UCTIONS: BACTERIA-Obtain sterile sample bottle. Remove strainer/aerator from.faucet. Turn on cold water. Allow it to run (5) five minutes. Fill container. Do not touch the inside of the bottle or the cap with anything. POTABLE WATER.SAMPLE- Follow instructions for bacteria. Sample size approximately 500 mis. . LEAD- Cali lab for instructions. VOLATILE ORGANICS/METALS- Call lab for instructions. 449 Route 130 Address: Proj. No. Project Name: Sandwich, MA 02563 (508)888-6460/ 1-800-339-6460 Sampler: FAX (508)888-6446 Phone#: Signature: Fax M Field No. Date Tlme Comp Grab Station Location Container Pres. Sample type Analysis Requested Relinquished: Date/Time Received: Reliquished: Date/Time Received: Relinquished: Date/Time Received: Relinquished: Date/Time Received: TECHNICAL REFERENCE l atile Organic Analyses _ Minimum Recommended Required Holding gory Methods Qty.' Container(s)2 Preservation Times eous Samples tile Organics- 601/8010 40 mL 3 x 40 mL Glass Cool to 4°C3 14 Days 602/8020 Vials w/teflon HCl to pH<24 624/8260" septum caps12 Remove Chlorine' 502.2 524.2 lein and Acrylonitrile 608/8030 40 mL 3 x 40 mL Glass Cool to 4°C3 14 Days Vials w/teflon Check pH;Adjust 4-55 septum caps12 Remove Chlorine? d Samples tile Organics 8010/8020 log 1 x 125 mL Glass Cool to 40C3 14 Days 8260 Vial w/teflon septum cap12 OR 2 x 40 mL Glass Vials w/teflon septum caps 12..13 lein and Acrylonitrile_ 8030 log 1 x 125 mL Glass Cool to 4°C3 14 Days Vial w/teflon septum cap12 OR 2 x 40 mL Glass Vials w/teflon .septum caps 12.13 ivolatile Organic Analyses Minimum Recommended Required Holding gory Methods Qty.' Container(s)2 Preservation Times eous Samples ivolatile Organics 625/8270 1 L 2 x 1 L Amber Cool to 4°C3 7 Days' Glass Bottle Remove Chlorine? w/teflon liners' ivolatile Organics 8270 2 L 3 x.i L Amber Cool to 4°C3 7 Days9 -level,both Acid Modified Glass Bottle Remove Chlorine' Base/Neutral fractions) w/teflon liners' ivolatile Organics 8270 1 L 2 z 1 L Amber Cool to 41C3 7 Days9 -level,only one fraction Modified Glass Bottle Remove Chlorine' or Base/Neutral) w/teflon liners' ivolatile Organics 525.2 1 L 2 x 1L Amber Cool to 4°C3_ 7 Days25 king Water) Glass Bottle HCI to pH<24 w/teflon liners' Add Sodium Sulfite24 7,8-TCDD(Dioxin) 1613 1 L 2 x 1 L Amber Cool to 4°C3 7 Days9 king Water) Glass Bottle w/teflon liners' nuclear 610/8100 1 L 2 xl L Amber Cool to 4°C3 7 Days9 atic 8270 Glass Bottle Remove Chlorine' rocarbons w/teflon liners' d Samples ivolatile 8270 30 g Glass Jar Cool to 4°C3 14 Dayst0 anics w/teflon liners' nuclear 8100 30 g Glass Jar Cool to 4°C3 14 Days70 matic 8270 w/teflon liners' 'rocarbons GROUNDWATER ANALYTICAL 27 • 11141 • ► ► • • �sticide and Herbicide Analyses Minimum Recommended Required Holding tegory Methods Qty.' Container(s)2 Preservation Time$ ubous Samples rbamate Pesticides 531.1 60mL 2 x 125 Glass Bottle Cool to 4°C3 28 Days rinking Water) w/teflon liner17 Add Sodium Thiosulfate26 Adjust pH to 3 with Monochloroacetic Acid Buffer ganoc:hlorine 608/8080 1 L 2 x i L Amber Cool to 4°C3 7 Days9 sticides&PCBs Glass Bottle Check pH;Adjust 5-96 w/teflon liner17 Remove Chlorine? ganochlorine Pesticides 508 1 L 2 x 1 LAmber Cool to 4°C3 7 Days21 PCBs Glass Bottle Add Sodium Thiosulfate26 rinking Water) w/teflon liner17 lychlorinated Biphenyls 508A 1 L 2 x 1 LAmber Cool to 4°C3 14 Days 22 Perchlorination Glass Bottle rinking Water) w/teflon liners? ganohalide Pesticides 505 40 mL 3 x 40 mL Glass Vials Cool to 4'C3 7 Days20 PCBs w/teflon septa capst7 Add Sodium Thiosulfate26 rinking Water) rst, nophosphorus 614/8140 1 L 2 x 1 LAmber Cool to 41C3 7 Days9 cides Glass Bottle Check pH;Adjust 6-86 w/teflon liner17 Remove Chlorine? lorinated 615/8150 1 L 2 x 1 LAmber Cool to 41V• 7 Days9 rbicides Glass Bottle Remove Chlorine? w/teflon liner17 lorinated Herbicides 515.1 1 L 2 x 1 LAmber Cool to 4°C3 14 Days 23 rinking Water) Glass Bottle Add Sodium w/teflon liner17 Thiosulfate26 phosate 547 40 mL 2 x 40 mL Glass Cool to 4°C3 14 Days rinking Water) Vial w/teflon liner Add Sodium Thiosulfate26 dothall 548.1 100 mL 2 x 125 mL Glass Cool to 4°C3 7 Days 21 rinking Water) Bottle w/teflon liner17 HCI to pH<24 Add Sodium Thiosulfate26 uat and Paraquat 549.1 250 mL 1 x 1 LAmber Cool to 4°C3 7 Days27 rinking Water) Glass Bottle H2SO4 to pH<24 w/teflon liner17 Add Sodium Thiosulfate26 B and DBCP 504.1 40 mL 3 x 40 mL Glass Cool to 4°C3 14 Days rinking Water) Vials w/teflon Add Sodium Thiosulfate26 septa caps 12.17 . B and DBCP 8011 40 mL 3 x 40 mL Glass Cool to 4°C3 14 Days Vials w/teflon HCI to pH<24 septa caps 12,17 Remove Ch(orine7 lid Samples ganochloririe 8080 30 g Glass Jar Cool to 4°C3 14 Days"sticides&PCBs w/teflon liners' ganophosphorus 8140 30 g Glass Jar Cool to 4°C3 14 Days10 sticides w/teflon liner17 rbicides 8150 30 g Glass Jar Cool to 4°C3 14 Days10 w/teflon liner17 B and-DBCP 8260 log 1 x 125 mL Glass Cool to 4°C3 14 Days Vial w/teflon septa cap 12.17 OR 2 x 40 mL Glass Vials w/teflon septa caps 12,11.17 I8 ydrocarbon Analyses Minimum Recommended Required Holding agegory Methods Qty.' Container(s)2 Preservation Time8 queous Samples ydrocarbon D3328-78 1 L 2 x 1 L Amber Cool to 4°C3 7 pays' ingerprint Glass Bottle 17 HISO4 to pH<2 C/FID) w/teflon liner tall Petroleum 418.1 1 L 2 x 1 L Amber Cool to 4°C3 28 Days ydrocarbons Glass Bottle HzSO4 to pH<2 PH-IR) w/teflon liner it and Grease 413.1 1 L 2 x 1 L Amber Cool to 4°C3 28 Days 413.2 Glass Bottle HZSO4 to pH<2 w/teflon liner asoline Range 8015/API 40 mL 3 x 40 mL Glass Cool to 4°C3 14 Days rganics Vials w/teflon HCI to pH<24 septa caps 12 iesel Range 8100/API 1 L 2 x 1 L Amber Cool to 4°C3 7 Days9 rganics Glass Bottle H2SO4 to pH<2 w/teflon liner 17 A DEP Volatile 8015/MA DEP 40mL 3 x 40 mL Glass Cool to 4°C3 14 Days etroleum Hydro- Vials w/teflon HCI or HzSO4to pH<24 septa 12 arbons(VPH) a caps retrO,e DEP Extractable 8100/MADEP 2 L 3 x 1 LAmberCool to 4°C3 14 Days um Hydrocarbons(`=PH) 8270 Mod Glass Bottle H2SO4or HCI to pH<22 4 4h low-level PAHs GC/P/S-SIM w/teflon liner17 olid Samples ydrocarbon D3328-78 309 Glass Jar Cool to 4°C3 14 Days10 fingerprint Modified w/teflon liner17 C/FID) otal Petroleum 418.1 30 g Glass Jar Cool to 4°C3 14 Days10 ydrocarbons Modified w/teflon liner PH-1R) it and Grease 413.1 369 Glass Jar Cool to 40C3 14 Days1D 413.2 w/teflon liner Modified asoline Range 8015/API log 1 x 125 mL Glass Cool to 4°C3 14 Days rganics Vial w/teflon septa cap 12 iesel Range 8100/API 30 g Glass Jar Cool to 4°C3 14 Days10 rganics w/teflon liner17 A DEP Volatile Petroleum 8015/MA DEP 50g 1 x 125 mL Glass w/50mL Cool to 4°C3 14 Days ydrocarbons(VPH) Methanol and Glass Jar without Methanol. A DEP Extractable 8100/MA DEP 30g Glass Jar Cool to 4°C3 14 Days etroleum.Hydrocarbons;EPH) w/teflon liner77 etals Analyses Minimum Recommended Required Holding ategory.. Methods Qty.' Container(S)2 Preservation Time8 queous Samples otal Metals 200s 100 mL Plastic Bottle HNO3 to pH<2 180 Days except Mercury) 6010 Cool to 41C3 7000s issolved Metals 200s 100 mL Plastic Bottle Filter First" 180 Days except Mercury) 6010 HNO3 to pH<2 7000s Cool to 4°C3 otal Mercury 245.1 100 mL Plastic Bottle HNO3to pH<2 28 Days 7470 Cool to 4°C3 GROUNDWATER ANALYTICAL .29 • I l • . . I • • tals Analyses Minimum Recommended Required Holding egory Methods bty.t Container(s)2 Preservation Time8 solved Mercury 245.1 100 mL Plastic Bottle Filter First" 28 Days 7470 HNO3 to pH<2 Cool to 4°C3 A Lead and 20019 1 L 1 x 1 L Plastic Cool to 4°C3 180 Days . per Rule 200.7 Bottle omium, 218.1-5 200 mL Plastic Bottle Cool to 4°C3 24 Hours avalent id Samples Cool to 4°C3 180 Days I Metals 6010 2 g Glass Jar cept Mercury) 7000s w/teflon liner I Mercury 245.5 0.6 g Glass Jar Cool to 4°C3 28 Days 7471 w/teflon liner zardous Waste Characterization Analyses Minimum Recommended Required Holding egory Methods Qty.1 Container(s)2 Preservation Time' id Samples78 LP Volatile 1311 150 g 2 x 125 mL Glass Cool to 4°C3 14 Days19 anics 8260 Vial w/teflon septum cap12 LP Metals, 1311 300 g Glass Jar Cool to 4°C3 28 Days19 ivolztiles, 6010 w/teflon liner 14 Days ticides and 7000s bicides 8080 8150 8270 itability 1010 100g Plastic or Glass Cool to 4°C3 None Modified Jar rrosivity 9045 20 g Plastic or Glass Jar Cool to 4°C3 None activity SW-846 209 Plastic or Glas Jams Cool to 4°C3 None nt Filter 9095 100 g Plastic or Glass Jar None None nventional Physical Properties Analyses Minimum Recommended Required Holding tegory Methods Qty.1 Container(S)2 Preservation Time? ueous Samples 48 Hours for 110.1-3 50 mL Plastic or Glass Bottle Cool to 4°C3 nductance 120.1 100 mL Plastic or Glass Bottle Cool to 4°C3 28 Days rdness 130.1-2 100 mL Plastic or Glass Bottle Adjust pH<215 180 Days Cool to 41C3 or 140.1 200 mL Glass Bottle Only Cool to 41C3 24 Hours 150.1 25 mL Plastic or Glass Bottle None Analyze Immediately lids,Total 160.1 100 mL Plastic or Glass Bottle Cool to 4°C3 7 Days solved(TDS) lids,Total 160.2 100 mL Plastic or Glass Bottle Cool to 4°C3 7 Days spended(TSS) lids,Total.(TS) 160.3 100 mL Plastic or Glass Bottle Cool to 4°C3 7 Days lids,Total 160.4 100 mL Plastic or Glass Bottle Cool to 4°C3 7 Days latile(TVS) lids,Settleable 160.5 1 L Plastic or Glass Bottle Cool to 4°C3 48 Hours rbidity 180.1 100 mL Plastic or Glass Bottle Cool to 4°C3 48 Hours • • KI 01 . . • Miols • nventional Inorganic Analyses Minimum Recommended Required Holding tegory Methods Qty.' Container(s)2 Preservation Time? ueous Samples dity 305.1 100 nL Plastic or Glass Bottle Cool to 40C3 14 Days alinity 310.1-2 100 mL Plastic or Glass Bottle Cool to 41C3 14 Days mide 320.1 100 mL Plastic or Glass Bottle None 28 Days oride 325.1-3 50 mL Plastic or Glass Bottle None 28 Days orine, 330.1-5 200 mL Plastic or Glass Bottle None Analyze I Residual Immediately Hides 335.1-3 500 mL Plastic or Glass Bottle Remove Sulfide 14 14 Days NaOH to pH>12 Cool to 40C3 ride 340.1-3 300 mL Plastic Bottle Only None 28 Days de 345.1 100 mL Plastic or Glass Bottle Cool to 40C3 24 Hours ogen,Ammonia 350.1-3 400 mL Plastic or Glass Bottle HZSO4 to pH<2 28 Days Cool to 4°C3 ogen, 351.1-4 500 mL Plastic or Glass Bottle H2SO4 to pH<2 28 Days I Kjeldahl Cool to 41C3 ogen, 353.1-3 100 mL Plastic or Glass Bottle H2SO4 to pH<2 28 Days to plus Nitrite Cool to 41C3 gen, 353.2-3 100 rrL Plastic or Glass Bottle Cool to 41C3 48 Hours to(Wastewater) gen,Nitrate 353.2-3 100 rrL Plastic or Glass Bottle Cool to 40C3 28 Days onnated Drinking Water, gen,Nitrate 353.2-3 100 rrL Plastic or Glass Bottle Cool to VC3 14 Days -Chlorinated Drinking Water) H SO to pH<24 gen, 353.2-3 50 mL Plastic or Glass Bottle Cool to 41C3 48 Hours to Minirrum Recommended Required Holding gory Methods Qty.1 Container(s)2 Preservation Time' eous Samples ophosphate 365.1-3 50 mL Glass Bottle Only Filter(0.45 µm) 48 Hours Cool to 4°C3 gen,Dissolved 360.1 300 mL Glass Bottle Only None Analyze Immediately phorous,Total 365.1-4 50.mL Glass Bottle Only H2SO4 to pH<2 28 Days Cool to 40C3 la 370.1 50 mL Plastic Bottle Only Cool to 40C3 28 Days to 375.1-4 50 mL. Plastic or Glass Bottle Cool to 40C3 28 Days de 376.1-2 500 m_ Plastic or Glass Bottle NaOH to pH>9 7 Days 2 mL Zinc Acetate Cool to 40C3 to 377.1 50 mL Plastic or Glass Bottle None Analyze Immediately ventional Organic Analyses Minimum Recommended Required Holding gory Methods Qty.' Container(s)2 Preservation Time? ous Samples emical 405.1 1 L Plastic or Glass Bottle Cool to 40C3 48 Hours en Demand - Y BOD) cal 410.1-4 50 mL Plastic or Glass Bottle H2so4 to pH<2 28 Days en Demand Cool to 40C3 GROUNDWATER ANALYTICAL 31 • , , ZfTelklk • • No]IN nventional Organic Analyses Minimum Recommended Required Holding egory Methods Qty.' Container(s)z Preservation Time' eous Samples anic Carbon, 415.1 25 mL Plastic or Glass Bottle H2SO4 to pH<2 28 Days I(TOC) Cool to 40C3 nolics 420.1-3 500 mL Glass Bottle Only H2so4 to pH<2 28 Days Cool to 4°C3 actants 425.1 250 mL Plastic or Glass Bottle Cool to 4°C3 48 Hours AS) robiological Analyses Minimum Recommended Required Holding e or Methods Q ' Container s Z Preservation Time' eous Samples iform, Various 100 m_ Sterilized Bottle Cool to 4°C3 6 Hours I(Wastewater) Remove Chlorine' iform, Various 100 m'_ Sterilized Bottle Cool to 40C3 6 Hours al (Wastewater) Remove Chlorine' iform, Various 100 m"_ Sterilized Bottle Cool to 40C3 30 Hours I(Drinking Water) Remove Chlorine' iform, Various 100 m_ Sterilized Bottle Cool to 41C3 30 Hours al(Drinking Water) Remove Chlorine' oli Various 100 mL Sterilized Bottle Cool to 4°C3 30 Hours inking Water) Remove Chlorine' Biological Analyses Minimum Recommended Required Holding �egory Methods Qty.' Container(sy Preservation Time ss Alpha and Beta 900.0 1 L Plastic or Glass Bottle HCI or HNO to pH<2 180 Days ium-226 903.1 1 L Plastic or Glass Bottle HCI or HNO to pH<2 180 Days ium-228 904.0 1 L Plastic or Glass Bottle HCI or HND to pH<2 180 Days 6tium-90 905.0 1 L Plastic or Glass Bottle HCl.or FIND,to pH<2 100_pays um 906.0 1 L Glass-Bottle None 180 Days • • . 1 k,14- • - wim • k,FTITS I • SAMPLING NOTES The minimum quantity specified is the minimum amount of sample material the vial.The cap should then be gently placed on the vial,taking care not to necessary to perform the analysis.This quantity allows for no margin of disturb the crown of liquid,and firmly rotated tight.The vial should then be error. examined to verify the absence of all air bubbles. For some analyses,Groundwater Analytical recommends specific types and Solid samples for Volatile Organic Analyses(VOA)must also be collected numbers of containers(e.g.,an Aqueous Volatile Organic sample requires 3 with a minimum of headspace or air pockets.Sample vials should be packed x 40 mL Glass Vials w/teflon septum caps).In such cases,the recommended fully and tightly sealed.Vial threads should be wiped clean prior to capping container(s)allow for an adequate margin of error. for best seal.When packing vials,however,avoid excessive manipulation of the sample material which may result in a loss of volatile organics.A wide For other analyses,Groundwater Analytical only recommends a general type mouth 125 mL Glass Vial w/teflon septum cap is the preferred sample con- of container(e.g.,a Solid Semivolatile Organic sample requires a Glass Jar tainer. w/tefIon liner).In such cases,it is strongly recommended that twice the mini- mum quantity of sample material be collected in the recommended type of 13. Solid samples for Volatile Organic Analyses may be collected in 40 mL Glass container. Vials that have been acidified with Sodium Bisulfate(NaHSO4),Hydrochloric Acid(HCI)or Sulfuric Acid(HZSO4).The presence of acid in the containerwill For solid samples, in addition to the minimum quantities required for indi- have no detrimental effect on the sample. vidual analyses,each sample also requires 20 g of sample material for a percent solids(or percent moisture)determination.Example:A soil sample 14. Maximum holding time is 24 hours when Sulfide is present.Samples may be collected forTPH-IR(30 g),8 RCRA Metals(2.6 g)and PCBs(30 g)requires tested with lead acetate paper before the pH adjustment in order to deter- a minimum of 62.6 g of material for the desired analyses,and 20 g of material mine if Sulfide is present.If Sulfide is present,it can be removed by the addi- for percent solids(or percent moisture),for a total required minimum of 82.6 tion of Cadmium Nitrate powder until a negative spot test is obtained.The g of material.It is then recommended that this minimum by doubled,and at sample is then filtered,and NaOH is added to adjust the pH>12. least 165.2 g of sample material be collected in a Glass Jar w/teflon liner. 15. Adjust to pH<2 with Nitric Acid(HNO3)or Sulfuric Acid(112SO4).Acidification For solid samples,all minimum quantities are calculated net of all foreign retards biological action,reduces absorption effects and prevents the forma- objects,such as sticks,leaves and rocks. tion of precipitates and/or complexes. Only sample containers pre-cleaned according to US EPA protocols are rec- 16. Samples should be collected with a minimum of aeration.The sample bottle ommended.Appropriate pre-cleaned and pre-preserved containers are avail- should be filled completely,excluding all headspace,and capped. able from Groundwater Analytical.Pre-cleaned sample containers should not be prerinsed with sample prior to sample collection.Prerinsing may cause 17. Extractable organic samples are susceptible to Phthalate ester contamina- elevated results. tion. Phthalate ester contamination is generally caused by sample contact with a plastic material,particularly flexible plastics.Use care to avoid sample Samples should be immediately cooled,stored and shipped refrigerated.4°C contact with any plastic,other than Teflon. (34°F)is the recommended temperature.Refrigeration retards biological deg- radation,reduces the volatility of compounds,retards the hydrolysis of non- 18. Specified quantities of sample material are for only single phase solid samples aqueous compounds, reduces absorption effects and prevents continuing (i.e.no free liquids).Liquid phase or multiple phase samples require different chemical reactions. quantities of sample material.Contact laboratory for advice prior to collecting Adjust to pH<2 with Hydrochloric Acid(HCI).Acidification retards biological liquid phase or multiple phase samples forTCLP analyses. action,reduces absorption effects and prevents the formation of precipitates 10. Samples forTCLP Volatile Organics analysis must be leached within 14 days and/or complexes.Sulfuric Acid(HZSO4)or Sodium Bisulfate(NaHSO4)may of collection.The leachate must then be analyzed within 14 days of leaching. be substituted for HCI in EPA Methods 8010,8011,8020 and 8260. Samples forTCLP Metals analysis must be leached within 28 days of collec- Adjust to a pH range of 4.0 to 5.0 with Hydrochloric Acid(HCI),Sulfuric Acid lion,if Mercury is being analyzed.The leachate must then be analyzed within (H2SO4)or Sodium Hydroxide(NaOH). 28 days of leaching.If Mercury is not being analyzed,then samples forTCLP Metals must be leached within 180 days of collection,and the leachate ana- If sample will not be received by laboratory within 24 hours of collection,then lyzed within 180 days of leaching. adjust to specified pH range with Sulfuric Acid(1-12SO4)or Sodium Hydroxide (NaOH).The pH adjustment may be omitted if it is performed upon receipt at Samples for TCLP Semivolatile Organics,TCLP Pesticides,and TCLP Her- the laboratory within 24 hours,and may be omitted if the sample is extracted bicides analyses must be leached within 14 days of collection.The leachate within 48 hours of collection. must then be extracted within 7 days of leaching.The extract must then be If free chlorine is present in the sample,then Sodium Thiosulfate(Na2S O) analyzed within 40 days of extraction. should be added.Free chlorine can react with organic compounds to form 20. Samples must be analyzed within 7 days of collection.However,if Heptachlor chlorination by-products. Free chlorine is likely to be found in chlorinated is not being determined,sample holding time to analysis maybe extended to municipal drinking waters and treated wastewaters.Sodium Thiosulfate,a 14 days. reducing agent,is added to remove the free chlorine.For most levels of free chlorine,add 4 drops of 10%Sodium Thiosulfate to samples in 40 mL vials, 21. Samples must be extracted within 7 days of collection.Extracts must then be and add 5 mL of 10%Sodium Thiosulfate to samples in 1 L Bottles. analyzed with 14 days of extraction. he listed Holding Time is the maximum of time a sample may be held be- 22. Samples must be extracted within 14 days of collection.Extracts must then een collection and-initiation of analysis or extraction. be analyzed with 30 days of extraction. amples must be extracted within 7 days of collection.Extracts must then be 23. Samples must be extracted within 14 days of collection.Extracts must then nalyzed within 40 days of extraction. be analyzed with 28 days of extraction. amples must be extracted within 14 days of collection.Extracts must then 24. Add 40-50 mg of Sodium Sulfite to each liter of sample to reduce free Chlo- e analyzed within 40 days of extraction. rine that may be present.Free chlorine can react with organic compounds to form chlorination by-products. Free chlorine is likely to be found in chlori- 3amples for dissolved metals must be filtered prior to preservation with Nitric nated municipal drinking waters and treated wastewaters.Alternatively,use 4cid(HNO,).Filtration must be done with a 0.45 micron membrane filter. 40-50 mg of Sodium Arsenite.Do not use Sodium Thiosulfate,as it may pro- =field filtration and preservation is preferred. duce a residue of elemental sulfur which may interfere with the determination iowever,if field filtration is not possible,samples should be cooled to 4°C of some analytes. ind shipped to the laboratory for filtration and preservation.Filtration must be 25. Samples must be extracted within 7 days of collection.Extracts must then be lone as soon as practical after collection.Groundwater Analytical recom- analyzed with 30 days of extraction. nends that filtration be done within 24 hours of collection.If samples are not ioing to be field filtered,do not preserve samples with Nitric Acid(HNO,). 26. Add Sodium Thiosulfate to reduce free chlorine that may be present.Free chlorine can react with organic compounds to form chlorination by-products. aqueous samples forVolatile Organic Analyses(VOA)must be collected with- Free chlorine is likely to be found in chlorinated municipal drinking waters. )ut any headspace or air bubbles.Volatile organics dissolved in water tend to Use approximately 80 mg of Sodium Thiosulfate per liter of sample. ,olatilize readily and will fill any air bubble available in the vial.Particularly vith low level samples,this results in a loss of material upon opening the vial. 27. Samples must be extracted within 7 days of collection.Extracts must then be /OA vials must be filled slowly until the liquid forms a meniscus on the rim of analyzed with 21 days of extraction. GROUNDWATER ANALYTICAL ss j COMMONWEALTH OF MASSACHUSET.TS DEPARTMENT OF ENVIRONMENTAL PROTECTION STANDARD REFERENCES FORMONITORING WELLS SECTION 1.2 TABLE OF:CONTENTS f Section 1.2 Page i January 1991 SECTION 1.2 TABLE OF CONTENTS 1.0 Introduction 1.1 Foreword 1.2 Table of Contents 1.3 Definitions 2.0 First Steps 2.1 Reconnaissance Surveys 2.2 work and Cost Plans (Reserved) 2.3 Health and safety Plans 3.0 Subsurface Investigations 3.1 Exploratory Test Pits 3.2 Drilling Techniques 3.3 Borings in Contaminated Areas 3.4 In-situ sampling of Soil 3.5 soil Classification 3.6 In-situ sampling of Rock 3.7 Rock Classification 3.8 Laboratory Tests for Soil 3.9 Plugging Boreholes 4.0 Piezometers, observation wells and Monitoring wells 4.1 Monitoring Well Network Design 4.2 Selection of Well Construction Materials 4.3 Well Installation Procedures 4.4 As-built Notes and Records 4.5 Well Development 4.6 Decommissioning of Monitoring Wells 5.0 Interpretation of Ground Water and Aquifer Characteristics 5.1 Water Level Measurements 5.2 In-situ Hydraulic Conductivity Tests 5.3 Pumping Tests . 5.4 Packer Tests 5.5 surveying and Datum Planes 6.0 Sampling of Monitoring wells 6.1 , Quality Assurance/Quality Control 6.2 sampling Techniques 6.3 Sample Handling 6.4 Chain of Custody 6.5 Decontamination of Sampling Equipment I Section 1.2 Page ii January 1991 Section 1.2 Table of contents (continued) 7.0 Computer Models (Reserved) 8.0 Geophysical Techniques (Reserved) I . i Bamstable, MA IDENTIFIED SOIL IMPACT(>S-1/GW-1) Reference Site Plan by SEA Consultants,Inc. Cambridge,MA Scale 1"=50' o ZONE"A" [651 X 50'W X 2701 Reference Site Plan for Robie's Refrigeration I °t\yd k9 /TB-4: 3'-8' bgs(DIESEL) RAO by Horsley&Witten,Inc. LOCUS / / TB-I1: 3'-27'bgs(DIESEL) ZONE"B" [65'L X 45'W X 28'D] / A SEA-1(SB): F-24'bgs(GASOLINFIDIESEL) / Y / Q23 a u en R SEA-SB-3: 1'-15'bgs(GASOLINE/DIESEL) TB-2 E House Roab TB-6: 15'-28'bgs(GASOLINE) 0 > / Sg9S �j� rt ZONE"C" [15'L X 10-15'W X 5'D] x a KEY MAP HB- 1: 0'-5' bgs(DIESEL) / + TB-1 LEGEND SOS o CB Concrete Bound a ♦ Air Sparging Point HW_3 ♦ qQ' / ♦ Existing Monitor Well \oaa + Existing Test Boring Q Zr� / O Existing ORC Injection Points SEA-3 SEA Installations by SEA Consultants,Inc.� o° /O' AST Aboveground Storage Tank Y" Former Location P �J UST Underground Storage Tank O 5 A5Ps(D-1) O (Removed 198G) OW Observation Well ltants Existing O Steamship Authority l v J ;F _ vC Monitor Wells O0 TB-3 / a4 ZONE "A" (Proposed O n( Engineered Barrier) O m TB-12 J Q BARNSTABLE MAHER WELL —y FIELD 300' -*TO PL HW-2 A J I •SEA-2 exst,ng `vim Ce spool Former Location - U5T(Kerosene) �� cb'au + ZA-3 / Former Loading Rack / h (Existing) 0aY MW-2 Existing _'V Septic Tank PLAN . 11 it SEASB-z TB-5 INTERPRETED O 30 60 90 \ ZONE B Existm \ ) (Pf01705ed Pumping Sygste f GW IMPACT / Loading Dock MW-3 Existing Engineered Barrier) g_ �J >GW-I s°mp SCALE I"=30' Ory Well Existing Loading Rack HB `+ _gp + ROS-I E O Qa� TB-10 Former .� TB 8 B 3� l (AS-1 Suspended 9/08) GZA-2 Loadng Rack /��\, B-2 REV1510N 9/10109:Added HBs I-G. Concrete ! j I OW-5 REV15ION 3/18/09:Noted A5-1 is 5uspended.Added bar scale,6 edited title block. Parking \\\ S S -. A 1 GZA-1 / REVISION 5104/68:Added ORC iecti points,TBs G.,be.I I c. SEA -4 TB ��' REVI510N 3/21/05:Added graph,.wale,Revised title block t, REV151ON 9/5/07:Added TB-G5,TB-8B,€TB-I I B;Labeled proposed engineered barriers. �B-6.�,�., Former Location ?'' G A5T/U5Ts(Gas. JKe s-n) REV15ION 8/3/07:Removed hatchmg,gaugmg,detail,and resaed. (Removed 199 - 995) Garage TB-7+ •* UVI51ON 711 1/07:Added GW Gauging 5107.Revised"Zones". SEA SB-1 MW 6 S(R)&D PEV15ION 3/2107:Added GW Gauging I I/OG.Add A5-1 Detatl. Exsb -I P REV151ON 1 I/02/06:Added Test Bonrys 14-18. Fuel 0,, tit AST 41 REV151ON Oe/05/OG:Added Test Borings;Groundwater Data. TB-9+ QP Project: HUBBARD OIL COMPANY, INC. J� Attn:Evelyn Read,P.O.Box 10,Hyannis,MA 02601 ZONE °C" �Cv Tide: COMPREHENSIVE RESPONSE ACTION PHASE V-STATUS REPORT MW_) B s h '``�O 33&51 Brooks Road,Hyannis,MA-RTN 4-0824 Catch F—Nn,3 `, BENNETT ENVIRONMENTAL ' Ba9,n® �Ce99p I Q,� / � e� ASSOCIATES, INC. / LICENSED SITE PROFESSIONALS,ENVIRONMENTAL SCIENTISTS, GEOLOGIST,SANITARIANS 1573 MAIN STREET,P.O.BOX 1743,BREWSTER,MA 02361 sPHONE:(50a)896-1706 www.bennea-e mm FAX:(508)896-5I09 TB-13 DATE SCALE BY CHECK IJOB NUMBER 03/16/06 As Noted JTW/e DCB B002-3490 MW-5 S&13 AutoCAD LT/D/A ENVIRONMENTAVHUBBARD OIL BROOK5 RD/3490R05-1(9-10-09).DWG 1