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Home My WebLink About0010 HOPEWELL LANE - Health (2) I T ' TOWN OF BARNSTABLE '^ OFFICE OF s$"T'ffi'riva BOARD OF HEALTH f M 367 MAIN STREET HYANNIS, MASS. 02601 APPLICATION FOR PERMIT TO SPRAY E OF LICENSED APPLICATOR C- C-- (��'t� CJ 0- 1�QJ1 Ul ��M _)L41 '�(b L--J )DRESS P, b � P S c) , :GISTRATION NUMBER OF LICENSED- EXPIRATION DATE OF APPLICATOR' S 'PLICATOR (�LICnENSE 'ST LOCATION OF SPRAYING C)� tab�r Attach Map) .TE & TIME OF SPRAYING � ESTIMATED DURATION OF SPRAYING: I T RBICIDES TO BE USED: In P, 06/{'u c,41 fioq . I I certify that I have read and understand the Town of Barnstable's rbicide Regulation. further certify that I will fully comply with each and every requirement sted in the regulation. understand that any violations of the Town's Herbicide Regulation will sult in appropriate legal action. i (Signature) Date 'i i . 1 . PROVED: !� -a %RD OF HEALTH iN OF BARNSTABLE `11/82 {! GIDB v /r !t A-1A vet S /ass 71v -5 717 5 2z O I! ocxk ' _� 5-V45 N-N4roLA Se.VuCce, CF- PA-CC(AeA I, SPA V F �PA'a_CJ1 ew• CA- f K.t-�. s �, �S�O o, o v Li 4� o 2 C. �eA ate c�Ae ( S .. TA um 0/4�(� C L S c it . qf SJf e W A.SO p 7 7 -7 Sow 1 ,a /ems ` o 7- G-5 -O kp 3 . L/ 4 0:2 AUy/ Gt/e Z^ems {I a' Gti e �Oahvl, well s . . ot1w p4-D(-e55 0 � (, Zl es I Z ` -- 1989 Fo��fruck F1 N F ti KEEP f c -3k/Q HoQewe-11 Lah2 .n;t S.o21O•�c. �vyy �a� U`eW Nc, 5l,ne II 19 O 2:09 th k a-f- t , r N April 12,1990 Mr Thomas McKean Director,Health Department P.O.Box 534 Hyannis,MAj02601 Dear Mr McKean; Recently this Department had occasion to inspect Cedar Clean, 57B Mid Tech Drive,Yarmouth , owned by Mr Kenneth M. Barlow. As a result of the inspection, it was determined that the activity of Cedar Clean as regards to removing mildew from houses, would require a pesticide license when a pesticide was being applied. All commercial pesticide application in Massachusetts must be done by licensed or certified applicators as required by M.G.L. chapter 132B section 6A and 333 CMR 10 . 03 (2 ) ( 3 ) . For your guidance, any material which has an EPA REG NO on the label is a pesticide. It is my understanding, that Cedar Clean is no longer located in Yarmouth. A written copy- of our findings was mailed to Mr Barlow on February 20 ,1990 . This was returned to us, as was a subsequent mailing made to a Florida address given to us by Mr Barlow. However, during a phone call Mr Barlow made to us, he was informed of our findings. If you become aware of Mr Barlow and/or Cedar Clean offering the mildewcide treatment in your area, I would appreciate being informed about it. If you have any questions, please do not hesitate to contact me at 617-727-7712 . /Fjohn ruly, Kenney Chief Inspector tia,_ : _'�-\ ��j� �(�lllll'?�lZtl�'C�"1�ll. �'�,•��L�ilcl�'G11.uilf'�t:� 1J-, = / =`• �=- �n _=_. , //Jirrr/iii�iifr/-r�irr�riiir�.��rii•ii�/iir� F' r: �. - ,�` J,rv>./f•�,lf.»lf�/�•';/�r��/.i>�. •.�!>•vn✓u»>:>r/ �r✓>l r Kenneth M. Barlow, Owner February 20, 1990 Cedar Clean 57 B Mid Tech Drive Yarmouth, MA 02601 RE: Notification of Findings of Inspection Dear Mr . Barlow, On December 13, 1989 an inspection of the above named firm was conducted by Inspector Kenney of the Massachusetts Department of Food and Agriculture, Pesticide Bureau regarding Cedar Clean' s intention of applying mildewcides to buildings . The result of said inspection indicates the following: Licensed applicator: an_ individual who is licensed as authorized to be present while pesticides classified by the Deparment as being for restricted use are being applied under the direct supervision of a certified applicator or to use or to be present to supervise the use on land of another for hire any pesticide classified by the Department as being for general use. 333 CMR 2 . 03 ( 4 ) (g) ( 4 . ) and M.G.L. c132B sec 2 . No person shall use, or supervise the use as a commercial applicator any pesticide classifed by the subcommitte as being for general use unless he either is appropriately licensed. 333 CMR 10 .03 ( 3 ) . No person shall purchase or use a federally registered .pesticide that has not been registered by the subcommittee pursuant, to 333 CMR 8 . 03 and sec 8 . 333 CMR 10 . 03( 1) and M.G.L. 132B sec 6 . You indicated to Inpsector Kenney that your company considered using Mildew Check (EPA Reg. # 56601-2 ) or TWP Total Wood Preservative (EPA Reg. # 51578-1) . Both these products are federally registered pesticides. In order for you or an employee to commercially apply these products or any other federally registered pesticide for hire .to another ' s property you must be licensed by the Department. In addition an federally registered pesticide to be used ► Y Y 9 in Massachusetts must also be registered by the Department . TWP Total Wood Preservative is not currently registered for use in the Commonwealth. You are hereby served notice that the commercial aplication of pesticides without a proper license and use of unregistered pesticides is a violation of the Massachusetts Pesticide Control Act ( Chapter 132B of The Massachusetts General Laws ) and/or the regulations 333 CMR promulgated thereunder and may result in further action pursuant to the provisions of sections 12 and 14 of said Act. Enclosed please find copies of pertinent sections of the Act and regulations . I have also enclosed an exam packet to obtain a pesticide applicator' s license. If you have any questions regarding licensure please contact Mark Buffone, License and Certification Coordinator, ,or questions regarding pesticide registration contact Lillian Rivera, Registration Specialist, or any other questions, please feel free to contact the Department at 617-727-7712 . Sincerely, Deborah V. Karan Chief Inspector Cert. Mail No. P 509 317 706 encl. / r THE COASTLAND TIMES,Thursday,October 27,1088,Pepe 8ft� a $300 probable cause hearing is scheduled for sunsupervised probation and fine. Nov. 22 to allow time for a governor's . Teddy Doyle Daniels, 30, of Manteo• warrant to be issued for his ex- pleaded guilty to no driver's license and. tradiciton. received 90 days suspended with two The following defendants waived pro- years unsupervised probation and a bable cause hearings and were bound $100 fine and$25 of the fine was for fail= 'over for trial in superior court: Michael ing to appear at an earlier court date. Wayne Berg,25,of Genesee, Idaho,for Robert John Holton, 39, of Kill Devil forgery and uttering a forged instru- , Hills pleaded guilty to driving while ment; Robert L. Huffstetter, 17, of license revoked. lie said he received a Coinjock, for scond degree burglary; call from some friends who said they and Dearing P. McKay of Kill Devil were too drunk to drive and he had".us- Hills, for breaking and entering and ed bad judgment"in going to pick.them larceny. .up.He received nine months suspended Peter L. Etheridge of Wanchese was for two years and a fine of$200. fined$25 for failure to wear a seat belt; Matthew Bryan Kumper, 16,of Rich- a charge of failure to yield was drop- mond. Va., pleaded guilty to speeding ped. 77 in a 55 mph zone.He received 30 days Lennon Edward Meekins of Manteo suspended with unsupervised probation admitted to exceeding safe speed for two years and a fine of$75. ,reduced from speeding 70 in a 55 zone Two defendants apeared for and was fined$10. preliminary hearings. Lynne Downing Titana H. Dutcher of Kitty Hawk ad- Carver, 33, of Fayetteville had a first mitted to speeding and was fined$10,as appearance for the felony charge of was.Wagner White of Roanoke Rapids. assault with a deadly weapon with in- tent to kill,inflicting serious Injury.Her probably cause hearing is set for Nov. The first White House wedding took place in 1812 as Lucy Payne 4' Wasghin ton, sister-in-law of President Kenneth Michael Barlow, 29, of Kill Devil Hills had a first appearance on a James Madison, married Supreme fugitive warrant from Virginia. His Court Justice Thomas Todd. .ate a c> zmd raoraq �� y."``�S-�--r°•;r T-r�..: tom lE�'I au�u� - ►o�o eur ropui 6u�seq oges auoAue . Pft -- - O2222 May 17,1990 Mr. Ken Barlow Cedar Clean P.O.Box 98 Hyannis,MA,02601 Dear Mr. Barlow, Enclosed is the Notification of Findings of Inspection which we attempted to deliver to you on several occasions. During our phone conversations during this time , I discussed with you the license requirements for applying a pesticide.This issue is covered in the Notice. To re-cap: If you are commercially using a pesticide on the property of others , then the applicator must be licensed. If the chemical you are using is not a pesticide then no license is required. To easily determine whether or not a particular chemical is a pesticide, look for the EPA REG NO and EPA EST NO. If you find them, then it is a pesticide and does not require a license. If no EPA REG/EST NO is on the container- no license is needed. For example: a bleach, if a pesticidal claim is made, may have an EPA REG/EST NO, and need a license to commercially apply. If no such claim is made, thus no EPA REG?EST NO, then a license would not be needed. If you have any further questions , please call me at 617-727-7712. Your truly, CERT.- MAIL: P 509 317 382 John E. Kenney Chief. Inspector a , r k. �y�F1HET�� TOWN OF BARNSTABLE y� �^ OFFICE OF DADS9M MAes. i BOARD OF HEALTH 039. 387 MAIN STREET HYANNIS, MASS. 02601 November 1, 1989 Ken Barlow 500 Ocean Street Unit 94 Hyannis MA 02601 NOTICE TO ABATE VIOLATIONS OF TOWN OF BARNSTABLE GENERAL BYLAW ARTICLE XXXIX: CONTROL OF TOXIC AND HAZARDOUS MATERIALS The Health Department recently received complaints that the company owned by you d/b/a "Cedar Clean" has been using "synthetic chemicals" to wash down sidings of dwellings. During a telephone conversation with you today, you refused to furnish me a complete list of the chemicals used. Section 7(b) of the Article XXXIX Bylaw states "upon request of an agent of the Board of Health, the owner or operator of any premises at which toxic or hazardous 'materials are used or stored shall furnish all information required . to monitor compliance with this bylaw, including a complete list of all chemicals, pesticides, fuels, and other toxic or hazardous materials." You are directed to furnish a written complete list of all chemicals and toxic or hazardous materials utilized by your company within forty-eight (48) hours of receipt of this notice. You may request a hearing if written petition requesting same is received by the Board within seven ( 7 ) days. However, the list shall be supplied within forty-eight ( 48) hours regardless of any request for a .hearing. Non-compliance may result in a fine of up to $500.00. Each day' s failure to comply with an order shall constitute a separate violation. You are also subject to an automatic ticket of $50.00. Tickets will be issued daily until the violations are corrected. . Sincerely your, Thomas A. McKean Director of Public Health Town of Barnstable TM:cst cc: Donna Miorandi Board of Health ARTICLE 27: To see if the Town will vote to amend its ............................ 7................................................. .................................................................................. 1.......................................... bylaws by adding at the end of Chapter III, the following new . . ............ ........... ................ ................................ ...................................... Article numbered in appropriate sequence: ............. .... ................................................. Article Control of Toxic and Hazardous Material. ............................. ................ .. ..................... .... ..... ...: w.............. ..................................... ........... ................ Section 1. Findings ................................................................................. The Town of Barnstable finds that - ................. ............................. ...... ........... (1) The groundwater underlying this town is the sole ............ ....................................................................... .................................. .................................... source of its existing and future water supply, including drink- ........... ............ ............................. ing water; ................................ .................................. ........................ ....................................... ......................... . . ... ........................................ (2) The groundwater aquifer is integrally connected with and flows into, the surface waters, lakes, streams and.coastal ........................................ .............. ................................... ......................................... .................................... ....................."I'll, * *......................................... estatifies which constitute significant recreational and ............................. .................. ....................... ...................!................................................. economic resources of the town used for bathing and other ............... ..................... ................... water-related recreation, shellfishing and fishing; ........................... ............................... .... .... ............................. ...... ...................... ............. . .. 13 ............................................................................. ............ ............. ...................... ......................... ........................... ........................ .................................. ................................... .............................. .. ......... ........... ................................. ................................. .......................... .............. ................................. .................................................................. ................................ ........ ..................... :..................... ....................::........................................................... ............................ ............ ........................................................... ................................ (3) Accidental spills and discharges of petroleum pro- ........................ .......................................................... .. .......................... ducts and other toxic and hazardous materials have repeatedly ...................................................... ................. ............ 7 ........................................................... .............................. threatened the quality of such groundwater supplies and .............................................................................. ....... ............ .............................. ......... ...: related water resources on Cape Cod and in other ................1.1.1.1:::::.,.*.-.,.,:.,.,::::::... ...... ...................................................................... ............................... ................ ................................. Massachusetts towns, posing potential public health and safe-. .. ............................................. .............................................................................. ty hazards and threatenihg economic losses to the affected ............................................................................ 11.*.'.'.'.`..*.7.'."*......................................... communities;.................... ................ ............. ..... .. ............ (4) Unless preventive measures are adopted to prohibit ............... ... ...........**"."..*'.'..'"'".,.".,.,.,.,.......... discharge of toxic and hazardous materials and to control their .................................. .......................... ................. ..................................... . .......................... storage within the town, further spills and discharges of such .............................................. .......... ............................... ..................................................................— ................................ materials will predictably occur. and with greater frequency f hazard by reason of increasing construction, and degree o .............................................................. ........... ............ .......... commercial and industrial development, population, and 4............................................................................ vehicular traffic in the Town of Barnstable and on Cape Cod; .......................... .................................. (5) The foregoing conclusions are confirmed by findings ....................................... ...... ....... .................. ................................ ................................................................ ..... ......................... set forth in the Environmental Impact Statement and Water- ......................................................................... Quality Management Plan for Cape Cod (September, 1978), ...................................................................... ............ ..... .......... ................................... prepared by the Cape Cod Planning and Economic Develop- .................................................................. .....................- ............................. ........................................I.......... .............................. ment Commission pursuant to Section 208 of the Federal ..................... ............... ....... ....... ........ ............... Clean Waters Act;by tine report en'titltd Chemical Containina- ................ a ..................................................................... .......................................................- .......... on (September, '1979), prepared by the Special Legislative ................. Commission on Water Supply, Commonwealth of Massachu- ........................... .................. ..... .... ....... .. ........... setts; and by the report. Chemical Quality of Ground Water, ............ ...*"." .* .'.*.'..".'.'.'.'.".,.* .' .."..-.--".,.,....�.. ....... ............................... ... .............. . ............. Cape Cod, Massachusetts (1979), prepared by the U.S. ...............:.................... ................................................................ ............ ........ ... ...................................................... ................... ......... Geological Survey. ...... . ............. .................................... Section 2. Authority ........ .......... ......... .............................. The Town of Barnstable adopts the following measures ....... .... .................... under its home rule powers, its police powers to protect the ............... ....................................... ..... ... .......................11.................................... ....- .................. public health and welfare, and its authorization under Chapter .............................w�................. ............. . ....... . .................................. ...........I.......... ................................. 40, M.G.L. S. 21. ........................ ... .. .............................. . .... ...... .... Section 3. Definitions ............................................. ............. ............................. (a) The ternf, "discharge," means the accidental or in- ................................................. .......................... .......... �eritional spilling, leaking, pumping, pouring, emitting, emp- ...........................*. ... .. ........... . ........................................... ... .......... tying or dumping of toxic or hazardous material upon or into ...... ...... a, ................ tyi ............ .................................. ................. y land or waters of the Town of Barnstable. Discharge in- ...... .......... an ..................................................... ........ ................... eludes, without limitation, leakage of such materials from fail- ed or discarded containers or storage systems, and disposal of ............... .............. ........... ................................... such materials. into any on-site sewage disposal system, *.......................-.1.......... .......... ................... .................. ................... ............ drywell, catch basin or unapproved landfill. ............. The term, "discharge," as used and applied in this bylaw, ............. does not include the following: .............. ............ .............. (1) proper disposal of any material in a sanitary or in- ......................... ............................. ............ .... . .. ........ ..... ....... . ......... dustrial landfill that has received and maintained all necessary ........ ... legal approvals for that purpose-, .................. 14 . ........ .... .. ................ ... ................... ............................................ . ... ........... ............................................ :::::::, * *.......... **.............. ................................................................................................ ....................................:..................................................................... .................................................................................... ..................................... ........... .......................................................................................... ..................................................................... .................... ................................................................................ . � ,.::, , ::.................................................................... .................................................................................................................................... ............................................................................................. ........................... ........... ......................... .............................................................................................................................................................................................................................................................................................................................................. ................................ ......................................................................................................................................................................................................................................................................................................... ............ ....... .........=::: *..,.,.,.".,.,.*.,.,.'...,...,.,.,.,.,:..-.-.-...,. ......... ... .............................. ............................ .................................. .......... .................................................................. ........................................... ........... .................................. .......................... ... ................................. .................................. ................................................................... .......... .................... ............ :::: .................... ................... ................................................................................................................................................................................................................................................................................................................................................................................................................. ...................................................................................................................................................................................................................................................................... .............................................................................. ..................................................... ............................. ................................................................... .............................. ............................................ ...................................................................... .............................................. ....................................................................... .. ........................................... ............................................................................. ............................................... ............................................................. ............................................ .............................................................. ............................................. .................................................................. .......................... ............................................... .............. ........ ............. .............................................. ... .......................... .............................................. .............. ............................................ (2) application of fertilizers and pesticides in accordance ......................................... .......................... ................................... with label recommendations and with regulations of the ................................................................... ...................................................................... Massachusetts Pesticide Control Board; ............................................. .............................................. (3) application of road salts in conformance with the .......................................................... ............ Snow and Ice Control Program of the Massachusetts Depart- ........................................................................ ...... ................................. . ............................................ Depart- ment of Public Works; and..... .................................................................. ........................................................................ .......... ... (4) disposal of "sanitary sewage" to subsurface sewage .............................................. ............ .............................................. .............. disposal systems as defined and permitted by Title 5 of the ................................ ................................ ................................................................. ........................................................................ Massachusetts Environmental Code. .......... .............. ......... .................................. .......................................................... (b) The term, "toxic or hazardous material," means any . ............................................................... substance or mixture of such physical, chemical or infectious.................................................................... ................ .. . .... ............... characteristics as to pose, in the Board of Health's judgment, a ................................. ........................................................................ ................. ........................................................................ .................. significant actual or potential hazard to water supplies, or ............................................... ................. .................................. ............................ ....................... of hazard to human health, if such substance or mixture ............................................... ................................................................................. were discharked to land or waters of this town. "Toxic or ................................................................ .............................................................0. ............ ............................ .. .............................................. .... ........... ............................ hazardous materials" include, without limitation, organic ................................................. ....................................................................... chemicals, petroleum products. heavy metals, radioactive or ................ ....................................................................... .................. ......................................................... ............. .............. .............::.:............. infectious wastes, acids and alkalies, and include products .............. ................. ................ such as pesticides, herbicides, solvents and thinners. Wastes .,."., :::::::: *............. ..................................................................... ......................... ...................................................................... . ............... ............... generated by the following activities, without limitation, are ............... presumed to be toxic or hazardous,'unless and except to the extent that anyone engaging in such an activity can demonstrate the ccntrary to the satisfaction of the Board of .............................................................. ............................................... ...................................................................... ............ . ....... Health: - ............ ............. ....................................... ..................................................................... ................................................. .................................................................... Airplane, boat and motor vehicle service and repair ............................................ ............ ....... .............................................................. .................................... Chemical and bacteriological laboratory operation ....................... Cabinet making .............. ............................ ................................ ...................... ....................................... .................... Dry cleaning ....................:................................ .......................... ........................ ....... ................................................................. Electronic circuit assembly - ........ ............................................... .......................... ............................ ................................................ ......................... . .............................. Metal plating, finishing and polishing .................................. ....... . ............ ................................ .............................. ................. ........................... ............. Motor and machinery service and assembly ....................................... . ........ . ....... Painting, wood preserving and furniture stripping ................................................. ................ ............................ Pesticide in--d-h—er--b'ic-id—e—application. ..................................... .................... .................................... ............ .. ... ............................... Photographic processing ... . ... ... ............................... ...................... ..... Printing .... ...... ....................... ............................. ............. ... ............ .................... ..................................... ........ ..... ................ Section 4. Prohibitions ........ ... . .................. ... .. ...... ...................................... . ....................................... (a) The discharge of toxic or hazardous materials upon ............... ................... ................... .................................. ................ .... . .......... h or into any surface or groundwaters within the .. ...................... It e ground ............................. ........ ........... ............................ ..................................... Barnstable is prohibited. of ......................... .............. ................ ................... b .Outdoor storage of toxic or hazardous materials is ............. .......... Vhib ted except in product-tight containers which are pro- ........................ .... ..... ....................... tected from the elements, leakage, accidental damage and. ................. .......................... ................ ........................... . ........................ .................. vandalism, and which are stored in accordance with all ap- ................ .......... .. . . ............................ .................. ......... .. ................... . ........................ .................. ............... .. . ........................ ............ ................ .... ............................... .................. .......... ......... .......... .. ............. ........... ................... .............................. ............... ............... ... ......... ...................................... ... ......... .... .......... .. .......... . ............... ................. ................................... ........ .......... ............. ........ .. .......... ........... ..., . ................. :............. . ......................... .... .... .. ..................... ..... ....... ............. .............. ... .... ... ... ........ ............ . .................. ..............%............ ............. ........ ........ ................................................................ . ...................................... .... ............ ......... ................ .. .. ... .. ............................. ........... .................... ....... .....:_..... .................. ....... .................................... ........ .. .................. . ... .. ........................ ......... ........ . ....... ..... ..... ................................................ .......... . . ... .. ........ .............. . .... .........I................ ...... .............. . ..................... ............ I......... ................ .................... ....... ............. ..................................... ......................... ..... .... ............................. ................... ........................................ ............................... .......... ....... ..... ........................... ...::..I. ............................................... .............*"*"**............ ............. .............................................................:.......................................................................................................................................... .............................................:........................................... .................................................................................................................................... .................. ...............* ...................................................................................................................................................... ............. ................................. .......... ................... .......................................................... ................................................................................................................................................................................................. ...................................................................................... .......I........... ................................................................................................................................................................................................................................ ............... .....................*...,- ......................... ................ .. ............................................................................................................................................................................................................................................................................................................................................ ............................................................................................................................................................................................................................................................................................................................................ ........................... ........... ............. ................................ . ................. ................................................................................................................................ ................................................... ........................................................ ............................................ .......... ............ ...................... ....................................................... ...............11.............. ........................................................ ................................. ............................... ..................................................... ................................. ..................................................... ....................................................... .............................. ............... ....................................................... .................................................... ...................... ....................... .......... ....................................................... ................................. ..................................................... ..............:::::............................... .................. .................................................... ................................ ...................................................... plicable requirements of Section 5 of this bylaw, For purposes ................................................... .................. ............. ............................................... of this subsection, road salts and fertilizer shall be considered ................................................. ............ ..................... ............. as hazardous materials. .................. ........................... ................ .. .......................... Section 5. Storage Controls ................................................... ................. .......... ..................................................... (a) Except as exempted below, every owner and every ................... .......................... ....................................................... operator other than an owner of a site at which toxic or hazar- .............. .....................................• ............... dous materials are stored in quantities totalling, at any time, .............................. ....................................................... ...... ............................... ................................... .................... more than 50 gallons liquid volume or 25 pounds dry weight �-*........................................... ................ ............................ ............................................. .......... .......... . ....... ................................................. .... ...... shall register, with t e Board of Health the types of materials ...................................................... ...................................................... .........a....... ..... .......................... stored, quantities, location and method of storage. The Board ......... .............................. ........... ............................... ............. of Health may' require that an inventory of such materials be ................................................ ...................................................... maintained on the premises and be reconciled with pxrhau, ................................................. ...................................................... .......................................... .............................................. use, sales and disposal records on a monthly basis, in order to ............................................... .................. ................................... ..................... JR—ect—any-—pro-d—uct-To—ss.-Re—gi§tr—at-io—n-r-eq--ui-r-ed-'!�y, this subsec- .................................................................................. tion shall be submitted within 60-dus of enactment of this or- --- ........................ ......................................... dinance, and annually thereaAer. Maintenance and reconciliam = .......... ............ tiortof inventories shall begin within the same 60-day period. .............................................. ............ .......... ..................................................... Exemptions: Registration %and inventory requirements shall ............. ........... ...................... . . not apply thc fc2cvincy: .............. ............................................................... .......... ...... . ............... .................................................... (1)Fuel oil stored in.conformance with Mass. Fire Preveri- ................................................. tion Regulations and regulations of the Barnstable Board of ..................................................... ............................................... .................................................... .............................................7 ............................... Health for the purpose of heating buildings located on the site; or ................ ........................................ .................................................... (2) The storage of toxic and hazardous materials at a ................................................. single family or two family dwelling, except where ......................................... ................................................... . ......... materials are stored for use associated with a at or ............... ............... ................................................... ......................... .................................................... ome occu a use as erne y 12 of the .................................................. ............................................... .................................................... Zonin B -Laws.of theTo ........... ..... ........ .................. ............................................... ................................................... ............................................. ................................................... (b) Wastes containing toxic or hazardous materials shall .............. ................................................. be held on the premises in product-tight containers and shall. ....................................... ....... .............. .............. ................................................ be removed and disposed of in accordance with the ....................... ........................ ....................... ........................ ................................................. r Massa azardous Waste Management Act, Ch. 704 of ................................................... ............... ............. .................................................. the Acts of 10 9. ..................................... ................................ ................................................ ................................. (c) The Board of Health may require that containers of ................................................ . .............................................. ................................ ........ toxic or hazardous materials be stored on anAmpervious, ................................................ ........................... ..................... .................................................. .......... ......... .................................................. chemical resistant surface compatible with the material tieing eing materials are for use a��ome�cuDa�n use as �e e Fu_a�f 5_e��12of fll .. . _ .................. stored, andIN—aff provisions be made to the e product in . ........................... ................................................. the case of accidental spillage. ................................................ ............................................... .................... ................................................... Section 6. Report of Spills and Leaks ......................... ....................... ................................................ (a) Every person having knowledge of a spill, leak or.................................................. .............. ............... other loss of toxic or hazardous materials believed to be in ex- ............................................ ......................................... cess of 5 gallons or 25 pounds dry weight shall report the spill ........... ................. ................................ ............ ............................. . ..................... . ...................... or loss of same to the Board of Health within one hour of deter- . .............. ......... ................. ................ .............................. .............................................. tion. ................................................ ...... ............ ........... ...... ................ 16 ................................................ .. ... ................... . .......... ................................................. ............... ..... ......................... ........... ................................................ .... ..... .............. ............. .... ......... ..................... ............ ..... ..................................... .................. ................... ................... ................... .................. .............. .............................................. .....................................................................................................n....................................................................................................................... ........ ............................................ .................. ............. ........... ..... .... .......... .......................................... ................................. ............................. ............... ............. ......... ................� ..............................................I.............................................. ........... ...... ................. .................. ......................... ... ....... ......................................1.1.*.*.,.,.,.,.*.,::::::::::::.*.'.'.'::::::::....................................................................... ....... ........... ......... . ................... ............................................................................................................................ ................. ...... . ............ . ............................ ........... .. ....... ...... ... ................................................................................................... ......................... ....... ... ......... ....... ............ ................................................................................. ................... .................. ......=. .......... .:........................ . ...... ................. ......... ..................................................... . .......::... ......................:: _:.. ..................... ................. . .............................................. ............... . . ... ..................................................... ...................................................... ...................... .......................................... .................................................................... .. .. ....... .... ..................... ...... ........... .............. .......... . .......................... ........................................................................................................... ....................................................................... .................................................. ............... ... .................................................. ...:.*-7-7 1.1.*.*.*.*.,.,.'.,.".,.,.:::::::: ................ ............................. ............... ............................................................. .................. .. ..... . . ..................................................................................................:................................ ----------- ................................................ ................................ ................................ ............. ........... .............. ........... .............. ......................................................................................... ....................................................... ................... ..................................................................................... ................ ................................ .........................................................I................................................................................................................................................................................................................. .................................................................. ........................... ........................................................................................................................................................ ............................................................................................................... ..........**...... ..................................................... ............... ........................... ........................................................ ................................ ......................................................... ............................... ........................... ........................... ..................................................... ....................................... ...................................................... ............................... ..................... ................... ............................................................. ........................................................ ...................................... ............. ......................................... .................................................... ................................... ....................... ........... .................................................... ...................................................... ............. ........................................... ............................................... .................... Section 7. Enforcement ....................... ................ .............. . . ............................................ .................... (a) The provisions of this bylaw shall be enforced by the ......... . ........................ .............. .............. ............................. ............. Board of Health. The agent of the Board of Health may,accor. ....................................................I............ . ... ............ .................... ....................................... ................................. ............................................... ding to law, enter upon any premises at any reasonable time to.... . ............................................... . ................................. ........... inspect for compliance. ............................... ........... ................................................... ........................ .................... ........................... (b) Upon request of an agent of the Board of Health, the .................................................. ................................................................ .................................I................................ ............................................ .. owner or operator of any premises at which toxic or hazardous........................... ..................... ..................................................... ............................................................... materials are used or stored shall furnish all information re- :: :::::: ............................ ........... ............................. ............ quired to monitor compliance with this bylaw, including a y ................................................. ............. .... ........................................................ ............ complete list of all chemicals, pesticides, fuels and other toxic . .. ........................................ ................................... ................................................... ................................ or hazardous materials used or stored on the premises, a ........................................................... description of measures taken to protect storage containers .......... .............. ............ ........................................ ............ ...... ............ .......... ............:�............... from 'vandalism, -corrosion and spillage, and the means of .......................................................... ............... .......................................................... .................... disposal of all toxic or hazardous wastes produced on the site. .......................................................... ............................................ . ......................................................... _—&-sample of wastewater disposed to on-site septic systems,_......... ........ ........................... ................................... ....... ... drywells or sewage treatme it-s n ................................................ stems i ay e required by th ................... .... . .. .. ........ .......... .................. .......................................... aRent of the Board of ............ Health. .......... ....................... ................................................................ ............. ............... ......................... ...................... -----TCTMT records pertaining to ' storage, removal and ........... ................................................................ ............................................... disposal of toxi c nr hazardous wastes shall he retained for no .......................................................... .... . ..... . .............. ................................................. ............................... less than three years, and shkll be made available for review by ....................................... .................................. . . .................. the agent of the Board of Health upon request. (d) The Building Commissioner of the Town of Barn- .............. ......................................................... ...................................... .....................................................: stable shall condition issuance of construction and occupancy ......................................................... ................. ............................................................... permits upon conformity with the requir'ements of this bylaw .............. ...........................I............................................... respecting any toxic or hazardous materials to be used in the ................................. . . . course of such construction or occupancy. . ............................................................... .......................... Section 8. Violation .................. ............................................... .................................... . ........................ (a) Written notice of any violation of this bylaw shall be ....................................... ...................... .................. ............................. given by the agent of the Board of Health, specifying the ........... ........... ..............I..................... .............................................. ........................ ........................................... ........... ................ nature of the violation; any corrective measures that must be .............................................................. ..... ........ .......... .......... ............... undertaken, including containment and cleanup of discharged ..................................... ................................................ materials; any ...................................................... ............. preventive measures required for avoiding ......................................................... ............................ ................. future violations; and a time for compliance. Requirements ............ ................. ................................ .......... .............................. .......... .... ............... .... ...................... ................. specified in such notice shall be reasonable in relation to the ........... .............................. ............;.................. ...............7................... public health hazard involved and the difficulty of compliance. ............................. .......... ......................... ................................... ...................... ..................................... ...............................................7............. The cost of containment and cleanup shall be borne by the .................... ............................• ................................. .................... ............................ ................... .......................................................... owner and operator of the premises. ........................................................... ............................................................. Section 9. Penalty ........................ ........................................................1. .................................... .............................I............................... .................................. Penalty for failure to comply with any provisions of this ............................................... bylaw shall be $200.00 per day of violation. .................................. ................. .............. .......... .. ........ .... ........... ............... . ........ ........... .. ................... ................... Section 10. Severability ......... ........... .... ......... ............................ ............ .......... .............................. ............................................................. Each provision of this 'bylaw shall be construed ................................. ......... ...................................... as separate, to the end that if any part of it shall be held invalid ............................. ...........: 4 .................. ..................................... .................... ................................. .4................. ........... . .......................................................... for any reason, the remainder shall continue in full force and ........................................ ............ ....................... ........ effect. ......................... .............. .......................... 17 ........... ............................................................ ............................................................. ....................... .......:......................... .... ...... ......... .............................. .......... .................... .......................................................... ....... . .................. .. ....... ..................... ................................ ................................................. .................... . ........... ............. ...................... ........... .. .. .................... ...................... ............ ......................................................... ............ ......... . ........................................ ... . .. ....................... ......... ............. .. ...................................I...................................................... ........... .......................... ..... ..... . ... .. . ............. . ............... .............................. ............... ......................................... ................*...... .......... . .............. ....................... ... ... . .........................I .............................. ... .. ...... ... ........ ........ ......................... ...... ...... ....................... ............ .......... .... ... ........ . .......... . . .. . . . . ... ............................................... ...........................-................................................................................. ..................... . ... ...................... .... ......... ........... . ....... .......I.,.............. ................ ............... ..................".-.......................................................................... ........ ....... . .......... ................. 1.. ... ............................................. ............. .............. ........... ........... I................... ................ . .. ..................................................................... ............. .... ........ ::: ........................................................................ .. ............................................ ............................. .................. ........... ....... ... . ......................................... .............. ................ . ............................... .... ................... .................. ......................................................... .......... .... ................................................. .......... .:. . *, 1*1 ... ........... ....................... I.'.'.'.'.'.'.'...`.`::.. .. .:.......... ..... .... ... .... ........................... Chlorine 2065 .is t,5,6,7,8,8-Hrxa(►1w d tl sOOS`�, O 18.07%. Pre d from chloral and 2- Dih r hl - '•":tttl►1. p yd oc onde, C=sHMCI°N°OS. P4241, Ponsital. Crys i•�t�,,-�; ,benzo uran-1,J•d.w !' t' a' f tlra.t 2 e pcntanediol: Christensen, U.S. pat. 2,931,838 fats from dioxane or eq acetone. - •rnene-2,3-dicargaal 1 u NnAc Medicinal). THERAP CAT: Tranquilizer. a setetrahydroph,kah -1 s1'-.. 1063. Chlorinated Lime. Bleaching r rdo-bicyclo(2.2.1]Ert. + � g powder. Improperly , C9H2CI,Ot; and r 5 13 called"chloride of time"or"calcium oxychloride". A rela- I "r 6%. O 12.94%. tape a CH3CCHZCHCH3 tively unstable chlorine carrier in solid form; a complex con- ad malefic anh)d:a rq• I I chemical com d of indefinite composition, presumably con- 11' OR OCHCCl P P P YyiEi•fR=' 952 to Velsicoll.Bs ;.: I 3 sisting of varying proportions of Ca(OCDr. CaClt, Ca(OH)= I, , f i 159 to Hooker('heal OH and Ha0 in its molecular structure. Maximum available 1 x ,t. 1,113,451 (1%1• + chlorine content approaches 39%. Commercial products ' I usually range between 24% and 37% of available chlorine. i1fG)c.lr.slightly bitter taste,mp 102-104'. Readily Sol in While or grayish-white powder, strong odor of chlorine. -�&.i .Lloroform;moderately sol in ether; slightly sol in R% IltJndytcs in aq solo. On exposure to air it becomes moist and rapidly decom- i±C s.....a Abuse may lead to habituation or addiction. poses. Most of it dissolves in water or alcohol. Keep dry ' G i and tightly closed. reJ.u: hypnotic. Human Toxicity: Strong solos irritate skin. Inhalation of >~ (Ilorhexidine. N,N"-Bis(4-chtorophenyl)-3,12- fumes may cause laryngeal and pulmonary irritation, put- ! 1} $.-..2.I,11.1J•retraazatetradecanediimidamide; /,1'- monary edema, death. Ingestion may produce severe oral, 1 <}er��,;,+7, .-f;it rY b...,art,lrnr6ir[5•(p-chlorophenygbiguanide]; 1,6-bis(N'- esophageal, gastric irritation. '1^t,•,r�z,Yt„ .s-...:,phtny9)-M-biguanido]hexane; 1,6-bis(M=p-chlo- USE: Bleaching of wood pulp, linen, cotton, straw, oils, t�oars)l,.1"•diguanido)hexane; 1,6-di(4'-chlorophenyldi- soaps, and in laundering; oxidizer in calico printing to ob- r kcune; 10,040; Hibitane; Nolvasan; Rotersept; rain white designs on a colored ground;destroying caterpil- •a.a C�IIa,C1,Nt,;mol wt 505.48. C 52.28%, H 5.98%. lars; disinfecting drinking water, sewage, etc.; as a decon- ! ';jFF:• c ;a�'i..N 27.71%. Prepn: Rose, Swain, J. Chem. Soc. taminant for mustard gas and similar substances. acid 2-chloco-t•I s o>'.} :on u:2.riJem,U.S.pat.2,684,924(1954 to LC L). THERAP CAT: Germicide. O-dlelhyl 0•12.1t. THERAP CAT (VET): Disinfectant for remises. Has been hate; 2,4-dichloro• P 3r `' Is as a topical antiseptic for superficial wounds.( thyl phosphate,10 '12H CI O P: MA as NIICNIICNH(CH ) NIICNIICNII Cl 20Z. Chlorindanol. 7-Chloro-2,3-dih dro-1H-inden-4- O 17.80'X.P 16It — !I II II at, 7-chloro-4-indanoL C H CIO; mot wt 168.63. C H Nil Nil NH Y 9 ,842 (1963 to Shl1 64.10%, H 5.38%,Cl 21.03%,O 9.49%. Pre n: Buck et al., hem.14.352(1%a J. Am. Chem. Soc.79, 3559(1957); Buck, U.S. pat. 2,990,- )# Sci. 2, 148(1V 1 9 Gtcalr from methanol, mp 134'. Strong alkaline teat- 324(1961 to Esta Med.,Labs.). Ail }' lUtle,chloride, CtrH►tCllN10. Lisium. Crystals, dec Ct +; \ �►:°: Sly in water at 20: 0.06 g/100 ml. r]i; %&ewc.Cp It CIrN190s. crystals, mp 154-155'. Neu- `N L1.11 Snly m water at 20': 1.9 g/100 mi. Aq solns 0% .t.ca heated above 70°. Soluble in alcohol, glycerol, r; x tq!ku gl)col,polyethylene glycols. LDa orally in mice: •ie t, I I all ha.ies et al., Brit. J. Pharmacol.9, 192(1954). V"6'Ic. Hibiscrub. t 90%of the at e op ss.at 25'= I 1° ` - s.e.►cat: Topical anti-infective. eedles from tr ether,m 91-93'. Absor lion s ectra: anic solvent°. voif s.ev cat IVEU Topical and uterine antiseptic. di ' - Pe P P P Sol in alkaline M P P Buck et al., lot. tic Ingredient of Lanesta. �•\ y , in rats: 39 mg y ! THERAP CAT: Spermicide. ;Is and ectopu►ma' XI (11oric Acid. CIHOat mot wt 84.46. C 1.98%n,H 2O65. Chlorine. Cl;at. wt 35.453;at. no. 17; valences 1 l.r..o 56 art". IfC103' Prepd from barium hlorate and to 7;elemental state: Cl,. A halogen. Abundance in igne- en 4-N'- ►-nrn11 °� % &ad: Lamb et al., J. Am. Chem. oc. 42, 1643 ous rock (95%of earth's crust): 0.031%by wt; in seawater: y ( i::'-Lg horn sodium chlorate using ion-e han a resins: 1 Vie, . It (p-chlorophen)Irl g 1.9%by wt (ppriman ly as NaCI). Natural isotopes: 35 1 a $i i.nrt. 2 Anorg.A!lgem. Chem.260, 271 1949). (75.53%); 37 (24.47/0); seven radioactive isotopes and two M-isopropylJrg♦ SN 12,837; [)at., � L•.•o m all solo only. Aq solos°are st ble it pure an� isomers are known; radioactive (racer elements: MCI (Ts ,,' A• �ruJ from light. I% aq solo d� 1. 67 soln d= 3.08 X 105 yes;p-,EC);MCI(T�37.29 min;9-);formed in nil;Titian. C,II tw lu.solar d11 1.0594; 16%soln d° 1 0991; 20%solo " 36%, Cl 13.9Tt R . 4 a1. S arm by bombardment with cosmic rays. Discovered in 1774 t I I:i).2JSb solo dJ° 1568. A 40%sot corresponds to b Scheele; recognized as an element in 1810 b Dav oc. 1946,729,Csc1 l)r 711,0.dm L282. If higher concns a e attempted by Produced on a large scale by electrolysis from fused chlo- ; ^� 1949,98. Islanald .� the soln begins to dec with evol lion of chlorine i ltbtte-Pw rides. The industrial product is about 99.3%pure. Contain- 152 to R at-rrlcn and formation of perchlorie aci . The salts of inants are traces of bromide, hexachloroethane, hexachloro- i t �n wrd are known as Chlorates. benzene, and water. Purification: Fye, Beaver, J. Am. ! •�`i, j ,,a thiditing agent;with H=S03 as catal st in acryloni- Chem. Soc. 63, 1268 (1941); A. Klement, Die Behandlung .`pllmerizalion. Caution: Strongly irri sting to skin, and Reindarstellung von Gasen (Vienna, 2nd ed., 1948) p :113)2 t..0 rt:rmbranes. 153. Lab prepn from MnO,and HCI: Schmeisser in Hand- book Chlorimpiphenrne. /-[2-[4-[3-(2- h(oro-IOH- �k of Preparative Inorganic Chemistry Vol. 1, G. Brauer, ' Ed. (Academic Press. New York, 2nd ed., 1963) 272. p...Au;in•10-yl)propylJ-l-piperazinylJethylJ- methyl-2- P 29°. Reviews: Ciba Review Vol.12,no. 139(Aug. 960); Chlorine, ( e,.m.Adinone; 3-chloro-l0-[rIN'-[(!-0-met yl-2-oxo- 8• acetone, mp I1s •.e.;.I,Jin•3-yl)ethyll-N-piperazinyllpropyl]ptl'nothia- J. S. Sconce. Ed., A.C.S. Monograph Series, no. 154(Rein- r • l' fI.CIN OS;mol wt 486.11. C 61.77%, [ 6.64%. hold, New York, 1962) 901 pp; MTP Int. Rev. Sci.: Inorg. re. Crystals frcro ,';►?N 14.41%,O 3.29%, S 6.60%. Prepn: B g. pat. Chem., Sera One, Vol. 3, V. Gutmann, Ed. (Butterworths, •I' ax (alc): 259 oa ar,111965 to Asta). C.A.65, 8934f(1966). London, 1972);Downs.Adams."Chlorine, Bromine, Iodine ly insol in chl,r► and Astatine"in Comprehensive Inorganic Chemistry,Vol.2, ,.3. LDM orall)a J. C. Bailar,Jr. et al,Eds. (Pergamon Press,Oxford. 1973) macol. Sep Ilca /� pp 1107-1594. I —N N—� y gas; suffocating odor. mp z z z z Greenish-yellow. diatomic Trial. j �—J p CI —101.00' (172.15°K); bp —34.05° (239.10°K); d (liq, 20°, 6.864 atm) 1.4085;d(liq, —35%0.9949 atm) 1.5649;critical i ',2-trich►uro l•IP temp 144% critical pressure 76.1 atm; C (gas, 251 8.11 rroxy-442,2.2 to 8�� D / cal/mole/'C. Marketed in the form of gasaover liquid com- roxy-2-meth)1•4 3 pressed into steel cylinders. Caution: Never heat cylinders Lora; Mccwal Vapor pressure data: Giauque. Powell, J. Am. Chem. Soc. ;. C 36.18%,N F>T tine.bp,,,260'. 61, 1970(1939). Sol in water(25°)with formation of aque- Consult the crass in before u -thissection. fi f. �;J2 Butylated Hydroxytoluene 1532. Butylated Hydroxytoluene. 2,6-Bis(I,I-dimethyl- Chem.Soc.69, 1046(1947);Justoni.Brit.pat.719,891(1954 Afonatsh.90, 783 (1959). Toxicity' ethyl)-4-methylphenol; 2,6-di-tert-butyl-p-cresol; 2.6-di- to Vismara). Ind. Health 14, 114(1956). tort-but yl-4-methylphenol; BHT; DBPC; Antrancine 8; Thick,oily liquid. d 1.00. mp -22°. by 250'. Practically Liquid, by 171-172-. dj°0.9012, Tenox BHT; lonol CP; Sustane; Dalpac; Impruvol; Vianol. insoluble in water; sal in alcohol or ether. LDs, orally in Soluble in 20 parts water; sal in n C,,Hr40; mot wt 220.34. C 81.76%. H 10.98%, 0 7.26%. rats: 5.14 g/kg,Smyth et al., Arch. Ind. Hyg. Occup. Med mineral oil. LDm orally in rats: 2' Prepared from p-cresol and isobutylene: Stillson, U.S.pat. 10,61 (1954). USE: Solvent for nitrocellulose,re 2,428,745 (1947 to Gulf); McConnell, Davis, U.S. pat. dry cleaning. Caution: Toxic symp 3,082,258 (1963 to Eastman Kodak). Inactivator of lipid- 1537. n-Butyl Bromide. I-Bromobutane. C411911r;mol Methyl Cellosolve. containing mammalian and bacterial viruses: Snipes et al., wt 137.03. C 35.06% H 6.629o, Br 58.32%. CH(CHr),B,. Science 188 64(1975). Prepd from n-butyl alc and a hydrobromic-sutfuric acid 1544. Butylchloralaminopyrim ' mixture: Kamm. Marvel, Org. Syn.vol. 1, 5 (1921); Skau, 1,1-dihydro-I,S-dimethyl-2-phenyt McCullough. J. Am. Chem. Soc.57,2440(1935). with 2,2,3-trichloro-1,l-buranedial On Colorless liquid. d}s 1.2686. bpro 101 Y(mp-112'). na chloral hydrate; butylchloralpyran' (cx3)3c / 1.4398. Insol in water;sol in alcohol°ether. min. C,,HUCIsN30; mot wt 424., C( 3)3 Cl 25.04%, N 9.8A, 0 11.307.. 1538. sec-Butyl Bromide. 2-Bromobutane;methylethyl• Prepn: Pfeiffer, Seidel, Z. Physiol bromomethane. C4H9Br; mol wt 137.03. C 35.0676,H Needles from water, mp 82-84°. 6.6276. Br 58.32%. CH,CH CHBrCH . Prepn: Levene, about 65 ml water,2 ml alcohol, 10 CH3 Marker. J. Biol. Chet". 91, t405 (19311; Kenyon et at,1 slightly in petr ether. Chem. Soc. 1935, 1080; Skau, McCullough, J. Ain. Chem Note: See also Butylchloral Hydt Soc.57,2440(1935);Colson er al.,J. Chem.Soc.1965,2364. Crystals,mp 70% din 1.048. by 26Y. Flash pt(open cup): Prepn of optically pure isomers: Goodwin. Hudson, 1. 1545. Butylebloral Hydrate. 260°F(127°C). Insol in water. Freely sot in toluene,sot in Chem. Soc. (B)1968, 1333. tanediol; a.a,0-trichloro-n-butyral( methanol, ethanol, isopropanol, methyl ethyl ketone, ace- dl-Form,colorless liquid, pleasant odor. dr 1.2530. by C1,02; mol wt 193.47. C 24.83%, tone, Cellosolve, petr ether, benzene, most other hydrocar- 91.2'(mp -112'). np 1.4344. Insol in water. Freely sol in 16.54%. CH3CHC1CCItC"(OH)=. bon solvents. Soly in liquid petrolatum (white oil): 0.5% alcohol,ether. to a,a.p-trichloro-n-butyraldehyde. w/w. More Sol in food oils and fats than butylated hydr- d-Form, n),° 1.4359-1.4362. «V +42.64% Orthorhombic scales. Pungent oxyanisole. Good soly in linseed oil. LDSO in rats: 1600- /-Form, nz=poo 1.4368. a�r° -43.7°. 1.694. mp 78'. One gram dissoly' 3200 mg/kg(Eastman Kodak, unpublished data). Caution: Narcotic in high concns. alcohol. 20 ml chloroform. 1 ml g13 USE: Antioxidant for food. animal feed, petrol products, olive oil. Incompatible with alkalie synthetic rubbers,plastics,animal and vegetable oils,soaps. 1539. tert-Butyl Bromide. 2-Bromo-2-methylpropane: acid, dichloropropylene and sodiun Antiskinning agent in paints and inks. 2-bromoisobutane; trimethylbromomethane. C H Br; cool (.see also incompatibilities given for c wt 137.03. C 35.067c, H 6.62%, Br 58.327., tCtis),CBr. soln in alcohol it is precipitated by 1533. n-Butylbenzene. 1-Phenylbutane. CtoHu;mol wt Prepn: Brunel, J. Am. Chem. Soc.39, 1978 (1917); Bryce• water in the form of globules consist 134.21. C 89.49%H 10.51%. C,H5(CH )sCHs. Prepd with Smith. Howlett. J. Chem. Soc. 1951, 1141; Coe et al., ibid Isolate, C4H,CI,O.C,H2OH. almost quantitative yield from benzyl chloride or bromide, 1954,2281. TmERAP CAT: Hypnotic. propyl bromide and sodium without addnl solvents: Radzi- Colorless liquid. d19 1.2125. by 73.3°. fp -16.3°. At szewski, Ber.9, 261 (1876). Similarly from bromobenzene. 210°changes to isobutyl bromide. n& 1.4249. Insol in wa• 1546. n-Butyl Chloride. 1-Cln butyl bromide and sodium in benzene: Balbiano, Der. 10, ter;miscible with organic solvents. binyl chloride; butyl chloride. C41 296(1977);Read.Foster,J.Am. Chem.Sac.48,1606(1926). 51.90%, H 9.80%, Cl 38.30%. CH Liquid. mp -88.5% din 0.8604. bp7a0 183.1'.bpaao 159.2% 1540. n-Butyl.n-Butyrate. Butanoic acid butyl ester,ba• from n-butyl alcohol by heating bpr,o 136.9% bpsoo 116.2% bpm 102.6% bp,92.4% bp20 76.3% tyric acid butyl ester. CSIIra0;mol wt 144.21. C 66.63%.H ZnCIzz: Whaley. Copenhnver, J. A bp,,62.0;bps 48.8%bp r q 22.7'. Hann 1.49040. Insol in water; 11.18%.0 22.19%. CH'(CH=J'COO(CH )SCH,. Prepn from 0938); Org. Syn.coil. vol. I (2nd c. miscible with alcohol,ether,benzene. butyl alcohol: Robertson. Org. Syn.call Vol.1, 138(1941E Liquid. !lighly flammable. d[s Horton, U.S.pat. 2,522,676(1950 to Socony-Vacuum CHI). 0.88098. One gallon weighs 7.35 1534. sec-Butylbenzene. (I-Methylpropyl)benzene; 2- Liquid,bp 165'. din 0.8692. np 1.4064. Practically insd bprro 78.5°. np 1.40223. Flash pt phenylbutane. CtoHu;mot wt 134.21. C 99.49%,H 10.51%. in water;miscible with alcohol,ether. moment: 1.95. Practically insol it C,I15CH(CHs)CH=CH,tt. Prepd from benzene and n-butyl Miscible with alcohol,ether. LDs,( chloride in presence oI AICIs: Schramm, Monatsh. 9, 621 1541. Butyl Carbitol(1). 2-(2-Butoxyethoxy)ethanot,di- Toxic Substances List, H. E. Christ( (1888); by the action of sodium on y-chloro-sec-butylben- ethylene glycol monobutyl ether. C5111503; mol wt 162.21 USE: As butylating agent in orgat zene: Braun et al..Ber.46, 1277(1913);with other products C 59.23% H 11.1876, 0 29.59%. HOCH,CH,OCH=CHI manuf of butyl cellulose. by heating n-or sec-butyl alcohol with 807.H,SO4: Meyer, OC Hy. Prepn: Riemschneider, Gross, Monatsh. 90, 78) THERAP CAT(VET): Anthelmintic. Bernhauer, Monatsh.53,727 (1929). (1919). Purification: Miller,Yonan, J. Am. Chem.Soc19, 1547. sec-Butyl Chloride. 2-CI Liquid. mp -82.7'. din 0.8608. by ao 173.5%bpeoo 150.3% 5931 (1957); Ridley, Ridley, Brit. pat. 795,866 (1958 to bpzm 128.8% bproo 109.5° bpa, 96.0% bp„ 86.2% bp=o 70.6°; methylpropane. C4H9CI;mol wt 92. Esso). CI 38.30%. CH CH CHCICH . Pr, bpro 57.0%bps 44.2%bpr,18.6°. np 1.48980. Insol in water; Practically odorless liquid, by 230.4'. mp -68.1°. dy i s miscible with alcohol,ether,benzene. 0.9536. n 1.4258. Miscibl&_ITt�yater, oils. Miscibility in hot, hydrochloric acid and ZnClt: d•ForTn, [«is +26.6°: Bonner, Greenlee, J. Am. Chem. Chem. Soc.46, 756 (t924); Copenit I1s ofherorgamcaolvenl3�lackson,Dru_Ty_ `Eng,•Chem.St, call. vol. 1, 143 (1941); from sec-1 Soc.81,3336`1959). 1491�1959).'Flash t L-03rovrallY in rats,guinea pigs: /-Form,[a)p -27.3°. 6,56: 2.00 / , myth et al., J. Ind. Hyg. Toxicol.23,259- Coulson et al..J. Chem. Soc. 1965, USE: Solvent;in organic syntheses. �(1 t. pure isomers: Goodwin, Hudson, 33 1535. tent-Butylbenzene. (Ij-Dimethylethyl)berrzenej i -Form: liquid; pleasant, ethers 2-methyl-2-phenylpropane; trimethylplsenylmethane; p d- 1542. n-Butyl Carbonate. Carbonic acid dibutyl ester, q dibut I carbonate. C H 0; mol wt 174.23. C 62.04%,H 68'.>sp 7.3960; np� 1.3953. One Rr dobutylbenzsne. CspHr; snot wt 134.21. C 89.49 H Y f a water a 25%miscible with alcoysol. 10.51%. C6H#C(C1I3 3. �repd from benzene.isobut �Ichlo- 10.41%.0 27.55%. (CSF�O�aCO. Prepn from ethyl carbon• d•Fo n70 1.3963;am +30.8'. ride and AICIs: Konowalow, Bull. Soc. Chittt. [3,6, 865 ate, butyl alcohol and et�sylmagnesium bromide: Frank a I•Forn: n�1.3968; a� -31.0°. (IR96); Shoesmith, Mackie, J Chem. Soc. 1926, 36; from al.. J. Am. Chem. Soc.66, 1509 (1944); from butyl alcohd Caution: oild irritant and,in hif isobutyl alcohol and benzene by treatment with I ming Sul- end CO in the presence of I'd and CuCI=: Mador, Black• (uric acid: Meyer, Bernhauer. Monatsh.53, 727 (1929); by ham, U.S.pat. 3,114.762(1963 to National Distillers). 1548. to -Butyl Chloride. 2-( decarbonylation of -phenylisovaleraldehyde in resence of Liquid, by 206.6% din 0.9251, dls 0.9388. np 1.4117. 2-chloroisobutane; trimethylchlorot Pd/C catalyst: Wilt. Abegg, J. Org. Chem.33, 9 (1968). Practically insol in water. Miscible with ethanol, benzene. wt 92,57. ,C 51.90%. H 9.80%, C See also Groose,Ipatieff, J.Am. Chem.Sou 57,241 (1935); chloroform, acetone, ether and other organic solvents, see Prepd by-shaking tert-butyl alcoh( Ipatieff, Pines, ibid.58, 1056(1936). Jackson, Drury, Ind. Eng. Chem.51, 1491 (1959). 4istilliiig: Norris, Olmsted, Org. S Liquid. mp -58.V din 0.8669. by so 168.5°;bpaoo 1 8 --from tart-butyl alcohol and PCIs: tt 1543. Butyl Cellosolve0. 2-Bufoxyethanpl;.ethylene_ 1953, 1920. bp,, 123.7% bptoo 103.8% bpao 90.6% bpao 80.i% bp" 65. col monobut I ether. C H 0 mol-%t 118.17. C bpro 51.7%bps 39.0%bprp 13.0°. np 1.49235. Insol in water; g1Y Y �H sC- p Liquid. des 0.847. nits 1.38686. miscible with alcohol,ether, benzene. 60�8%-H-11'r94%-0 2T08 0. HOCH2CH2 ' . Pre pit bp. 32.6% bP=oo +14.6% bproo from butyl alcohol and ethylene carbonate or 2-ch�orcethe• _190': Sparingly sot in water, mi 1536. n-Butyl Benzoate. Benzoic acid butyl ester. C - not, or from ethylene glycol and butyl bromide: Carlson. ether. Boiling with water yields ter Hra0=; mot wt 178.22. C 74.13%, H 7.92% 0 17.95Yo. U.S. pat. 2,448,767 (1948 to Mellon Inst. Ind. Res.); K11- C,H5C00(CH=)sCH3. Prepn: Newman, Forties. J. Am. mann, Bertsch, Ber. 88, 201 (1955); Riemschneider.Gross. 1549. teH-Butyl Chloroacetate. Page 199 Consult the cross index before using this section. r ., J 2 t F Sodium Poly me p osphate t 8431 ng, dentifrices, soaps. Phosphate;disodium hydrogen phosphate; disodiu ortho- ing boiler scale, softening water: martial paper: laundering; Phosphate; disodium phosphate; DSP; phosphate sod@` tanning leather;in deter ant mixture.- _ secondary sodium phosphate. HNa=O}P; mot wt 141.96. _$425-Stidlum Ph kite. HNatOaP; mot wt 136.96. H it 0,71%.Na.32.39%,0 45.08%, P 21.82%. Na=HPO,. In- 8 77%. Na 33.57%,O 35.05%, P 22.61%. Na=HPOa. u. CINaOe; mot wt dustrial production: Faith, Keyes, & Clark's Industrial Jr. .27%. NaCIOa. Chemicals(John Wiley, New York. 4th ed., 1975) pp 746- Pentahydrate, white, hygroscopic tryst powder. Heat of ,stals. Dec at about 1S4. to (25): -684.2 kcal/mole. Freely Sol in water. cp well closed. Anhydr, exsiccated sodium phosphate. Hygroscopic pow- Keep well closed r, dcr. On exposure to air will absorb from 2 to 7 mols IIaO, 8426. Sodium Phosphomolybdate. Sodium molybdophos- depending on the humidity and temp. Sol in about 8 parts phase. Mot:Nat��Oa6P; mot wt 1891.37. Mo 60.88%, Na i NnO.; mot wt 189.92. safer,much more Sol in hot water. Soly per 100 gal water 3.65%,0 33.84Jo, P 1.64%. NaaPOa.12Mo0a. J increases from about 14 lbs at slightly >0°to over 900 Ibs at White crystals. Freely Sol in water. ygroscogroscopic granules. 95'. Insol in ale. pH of 1%aq solo at 25°: 9.1. Keep well USE: As reagent in chemical analysis. closed. 8427. Sodium Phosphotungstate. Sodium tungstophos- Dihydrate, Sorensen's phosphate,Sorensen Is sodium phos- phate. Approx 2Na10.P=Os.12WO3.18H=O. ioxide;sodium super. /hart White, granular powder. Sol in water. .99. Na 58.97%, O Ileptahydrate,crystals or granular powder. Stable in the USE: As reagent for alkaloids,uric acid, potassium. retains 90-95%Nat01. air. d about 1.7. Sol in 4 parts water,more sot in boiling r'in aluminum vessels eater;practically insol in alcohol. The aq soln is alkaline. 8428. Sodium Plumbate(IV). NatOaPh; mot wt 301.17. bon dioxide has been pit about 9.5. Na 15.27%, O 15.94%. Pb 68.79%. Na2PbO3. 'enneman, Inorg. Syn. Dodecahydrate, translucent crystals or granules; readily Trihydrate,light yellow,fused,hygroscopic lumps. Sol in loses 5 mols of water on exposure to air at ordinary temp. water,but gradually dec with separation of Pb02. Keep well Absorbs water and µ'hen contg the full 12 mols of H=O it melts at 34-35°. d closed forming sodium hy. about 1.5. Sol in 3 parts water; practically insol in alcohol. titer quickly dec into Art sole is alkaline.pH about 9.5. Keep well closed and in a 8429. Sodium Polyanetholesulfonate. Polyanetholesul- :202 is formed which cool place• tonic acid sodium salt; anetholesulfonic acid sodium salt nic matter or readily /ncompat: Alkaloids, antipyrine, chloral hydrate, lead polymer. A polymer of anetholesulfonic acid. Originally osion may take place. acetate,pyrogallol, resorcinol. developed as an anticoagulant, it was soon found that it :ontact with organic or Human Toxicity: Anhydr form may cause mild irritation possesses anticomplement action and lowers the bactericidal to skin,mucous membranes;intern. causes purging. action of blood. Ref: Demote, Reinert, Arch. Exp. Pathol. able fibers, feathers, USE: As mordant in dyeing;for weighting silk;in tanning; Pharmakol. 158, 211 (1930); Friedmann. Klin. Wochenschr. coral; rendering air in manuf of enamels,ceramics,detergents,boiler compds;as 14, 215 (1935); Stuart, J. Clin. Path. 1, 311 (1948); Hoff- rpedo boats, subma• fireproofing agent;in soldering and brazing instead of borax; mann-La Roche Biochemicals Catalog. it sick rooms; dyeing as reagent and buffer in analytical chemistry. ` General oxidizing THERAP CAT: Cathartic. CH=CHC[13 ,e. See Sodium Hy. THERAP CAT(vET): Laxative. 8422. Sodium Phosphate, Monobasic. Sodium biphos- xroxydisulfate. Na - phase; sodium dihydrogen phosphate; acid sodium phos- So3Na 76%S 26.93%. Na y• phate;monosodium orthophosphate; primary sodium phos- \ phate. HtNeO,P; mot wt 119.98. H 1.68%, Na 19.16%,0 decompn is promos- 53.34%,P 25.81%. NaH,PO4. It is about 99%pure. ocH3 I soly its water at 20': Monohydrate, white, odorless, slightly deliquesc crystals MLD i.v.in rabbits: or granules. At 100'loses all its water;when ignited it con- A. 1, W. S. Spector, reris into metaphosphate. Freely sot in water: practically Light brown powder. Insol in alcohol. Swells in water ?78-279. insol in alcohol. The aq soln is acid. pH of 0.1 molar aq and slowly goes in soln with neutral reaction. Act solns are promoter for emu]. soln at 25': 4.5. stable to heat, dil alkalies and dil acids. Highly irritating to Dihydrate, orthorhombic bisphenoidal colorless crystals. USE: Under the trademark Liquoidto inhibit blood coagu- mp 60'. d 1.915. At room temp crystallizes with.2H 0. lation in vitro, as diagnostic reagent to encourage the :in. Na0 Tc;mot wt Directions for max yield: Beans, Kiehl, J. Am. Chem. Foe. growth of pathogens in blood. Also to stabilize colloidal w 49,1878(1927). solns such as milk and gelatin. (Not to be confused with %. NaTc04. Prepn: USE: In baking powders;in boiler water treatment;as dry Liquoid, registered trademark of,Johnson & Johnson for Acta 1, No. 2, 107 acidulant for foods: Tidridge, Pals, U.S, pat. 3,030,213 castor and olive oil emulsion.) opulos, AEC Acces- (1962 to FMC). _ I pp(1964). CA.62, THERAP CAT: Urinary acidifier. 9430. Sodium Polyanhydromannuronic Acid Sulfate. THERAP CAT(VET): Urinary acidifier. Paritol;Ateroid;Heparinoid;Hepinoid;Thrombocid. Prepd anning). from alginic acid. Structurally similar to heparin. 8423. Sodium Phosphate, Radioactive. Sodium phos- White powder. Sol in water. A 5%aq soln is easily prepd droxybenzenesulfonic phate-stP; radioactive sodium phosphate; sodium radio- and may be sterilized by autoclaving. . C6HsNa04S; mot phosphate(aTP); Phosphotope. THERAP CAT: Anticoagulant. I.72%, 0 32.63%, S Act soln of mixed radioactive phosphates with a pH range of 5.0-6.0. Contains radioactive monobasic sodium phos- 8431. Sodium Psphate ; glassy so um mays salt; ate; :lightly bitter taste; phate (NaH 17P044) and radioactive dibasic sodium phos- Hy- hezametal?03%. aA glassy sodium metaphosphate; ram dissolves in 4.2 phate(Na,H12po' stP is a pure beta emitter with a half-life Hy-Phos. (NaPOa),. A mixture of polymeric metaphos- cohol, 13.5 mt boil. of 14.3 day_s___ phates; not a hexamer. Prepd by rapidly chilling molten is neutral. sodium metaphosphate: Bell, Inorg. Syn. 3, 103•(1950). / -TnERnv CAT: Antineoplastic;anttpo ycy a aag f�stie Reviews: see Sodium Metaphosplsate. n intestinal antisep! aid(neoplasm). �� Clear,hygroscopic glass..mp 628°. Sol in water,but dis- solveslowly granulating 8424. Sodium Phosphate, Tribasie.. Trisodium ortho- ' slowly. Depolymerizes in aqueous solo to form sodi- phosphate;trisodium phosphate;TSP:Oakite. Nes0 P.mot m trimetaphosphate and sodium orthophosphates. wt 163.94. Na 42.07%. 0 39.04%, P 18.89%. IlasPOa. Sodium hex arnetaphosphate detergents, Calgon, Giltex, 'senate; sodi car- Crystallizes with 8 and 12 mots of H=O. Q adrafos, flagon phosphate, Micromet. Mixtures contg it. Cq H6Na ; mot Dodecahydrate,colorless or white crystals. When rapidly Gr ham's salt as the principal agent. Supplied in the form 19.81"l0, 0 1 .78% heated melts at about 75°. Does not lose the last mot of of powder, flakes, and as small, broken, glass-like parti- )H in dil met anol: water even on moderate ignition. d 1.6. Sol in 3.5 parts etas. Sol in water(pH adjusted to 8-8.6). Insol in organic 2710(1959). water. 1 part boiling water;insol in alcohol. The aq soln is soly nts. Possess dispersing and deflocculating properties, granules. D m- strongly alkaline. pH of 0.1%solo: 11.5;of 0.5%solo: 11.7; coag late albumins, and inhibit the crystn of slightly sot t water;Sol in a o- of 1.0%soln: 11.9. Technical crystals are sometimes made tom ds such as calcium carbonate and calcium sulfate. with excess alkali to prevent caking and give more alkaline U Water softeners and detergents. For leather tanning, Dibasic sodium solutions. dye' g, laundry work, textile processing; for the"threshold USE: In photographic developers;clarifying sugar;remov- tire tment"of softening industrial water supplies. Consult the cross Index be reusing this section. Page 1119 f. 1 - •• ••• -• t K :'�q�r'�x'b r.l .� ��" .y.' � F?p!"��k'y Irk • will • wla • a yam. .�� a Inc 19 MA WO y goo / . /�'-y,rpm Ju" r"/+Ji��.W 11►�.j.� L• 1 1 ' 'Jul all UP Mali � �da�mse� t psi , ,..: /allCWl�saC iY+ N4B«WQ��'�3I,�IdI®6�1r:16�f1YflLtf�!311= ../ r '�.JG 1E16Bij.i.�l®ff11uL'lIN1�Y3iC�6� ii1CLl�1�.,�j - i„� �.;r41.J '"�jjr"b"�i1IA.']24i" ;mv. 31/J►3.,i,iCL Y '�••a,..,u + 'Vu��it 1Liid 7 -u diid�lutlt�ii ��.A rr4L1�! 1 R 4ruw:. .odWir+rU. �tl+.9i1od3i� ILCtt➢, rsQ i9t?.WrUI�'iE YyQJ�� What types of surfaces J Why does my house can be "washed" by Y -: _ s turn black? - - f this. _-�-' the o cause o - - .�—�": Q • Nature is e sole n -_f � Cedar Clean? ___ _=�___ n ^ 3-��_=`� -=-�-_�'� � Mold spores grow on plants and Painted, stained, or bare =_ :-= = -- - trees. As the wind blows, the .. woodsiding, wood fences and " = spores travel through the air decks, roofing, stucco, brick, - _ until they are caught by a rough cement block, concrete and 1 F �� ' ro surface. The large, rough ceramic tile. - surfaces of cedar-sided houses i _ easily attract thousands of spores HOW 1S the Wash - that will adhere and gro w. applied? During the warm months the • mold will continue to grow, but Our chemical wash is applied during the cold winter months with LOW pressure sprayers. h growth will turn black. When is the This is important to look for _ .P ,` - .. weather returns the growth .� warm when choosing a company to '' = `_ process begins again, covering an restore your surface, as high :- - even larger area that will later pressure applications will actually _R turn black. damage the material during cleaning. _ � 1 � ,� :. ®'0 Is the wash safe? 71gas Yes, our chemical treatment is • not harmful to children, pets or plants when applied properly. How does it work? _ —� A combination of enzymes and Q • synthetic cleaners kill mold .g� - . ®; spores that are imbedded into _ the siding material. This chemical also acts as a protective barrier to prevent any regrowth rBi��yw, •+ E ® �s■ j� ®� 16 of the mold. The cleaning andvim sealing is done with two applications. Within moments of _ being treated, the cedar siding begins to take on the appearance f p P �� ='� of freshly milled lumber. s a Q 1.LL III - y Chlorine 2065 4,5,6,7,8,8-Hexackho s. , r 0 4005' O 18.07%. Prepd from chloral and 2- Dihydrochloride, C2SHMCIsNsOS, P4241, Ponsital. Crys- sobenzofuran.1,J dnst jjail 1 t.pcmanediol: Christensen, U.S. pat. 2,931,838 tals from dioxane or aq acetone. 5ornene-2,3-dicarlm* t y WnAc Medicinal). THERAP CAT: Tranquilizer. lenetetrahydrophth& endo-bicyclo[2.2.1[Ege CH 2063. Chlorinated Lime. Bleaching powder. Improperly C9H2C1603; and r 13 called"chloride of lime"or"calcium oxychloride'. A rela- r It°� 'a .36%, 0 12.94q, pro{ CH3ICH2CHCF13 lively unstable chlorine carrier in solid form; a complex r t and maleic anh)drdt chemical compd of indefinite composition, presumably con- '1952 to Velsicol).Ba off OCHCC13 sisting of varying proportions of Ca(OC►)2, CaCl2, Ca(OH)2 s 1959 to Hooker(lime ;* off and H2O in its molecular structure. Maximum available jr pat. 1,113,451 (19t1 a chlorine content approaches 39%. Commercial products 2). d usually range between 24% and 37% of available chlorine. 1 i Cry,c.l,.slightly bitter taste.mp 102-104°. Readily sot in White or grayish-white powder; strop odor of chlorine. 6k Alorofurm;moderately sol in ether; slightly sot in 8 Y= P B . $' On exposure to air it becomes moist and rapidly decom- 0 ') li,JrA)zes in aq soln. i, Ci.a Abuse may lead to habituation or addiction. 'o Poses. Most of it dissolves in water or alcohol. Keep dry 9480r and tightly closed. 1;. U: Hypnotic. and r ° Human Toxicity: Strong solos irritate skin. Inhalation of �0 21td (llorbexidine. N,N"-Bis(4-chlorophenyl)-3,11- fumes may cause laryngeal and pulmonary irritation, pul- (ij 1 .e'4111,13-teiraazateiradecanediimidamide, 1,1'- monary edema, death. Ingestion may produce severe oral, Fes, trlrncbis[5-(p-chloropheny!)biguanide],• 1,6-bis[N'- esophageal,gastric irritation. 1 } .aw:phcnyU-NS-biguanido]hexane; 1,6-bis(N5-p-chlo- USE: Bleaching of wood pulp, linen, cotton, straw, oils, t h z• I %"-dt uanido)hexane; 1,6-di(4'-chloro hen Idi- soaps, and in laundering; oxidizer in calico,- r 8 P Y P � B� printing to ob- khct nc; 10,040; Hibitane; Nolvasan; Rotersept; tain white designs on a colored ground;destroying caterpil- * _ sa Cr.HuCl,Nto;mot wt 505.48. C 52.28%,H 5.98%, lars; disinfecting drinking water, sewage, etc.; as a decon- ic acid 2-chloro/•lu 1t,Ji..N 27.71%. Prepn: Rose, Swain, J. Chem. Soc. taminant for mustard gas and similar substances. w c #>)eq u)2,tidem,U.S.pat. 2,684,924(1954 to I.C.I•). THERAP CAT: Germicide. i i r O,O-diethyl O•�2.N.. I' THERAP CAT (VET): Disinfectant for premises. Has been •phate; 2,4-dichloro.► used as a topical antiseptic for superficial wounds. iethyl phosphate, fiat C12HtaClaO4P; and w 2)s Y \IICNIICNH(CH NIiCNHCNII C1 2064. Chlorindanol. 7-Chloro-2,3-dih dro-1H-inden-4- .;. r %,O 17.80%,P Bell �`� II II II II /—\ ol,• 7-chloro-4-indanol. C9H9C10; mol wt 168.63. C I )2,842 (1963 to Sb,0 Nit NH NH NH 64.10%, H 5.38%.Cl 21.03%.O 9.49%. Prepn: Buck et at. V I d !Chem.14,352(1%* J. Am. Chem. Soc.79, 3559(1957); Buck, U.S.pat. 2,990,- t tic. Sc•i. 2, 148(1910 (rrusik from methanol, mp 134°. Strong alkaline reac- 324(1961 to Esta Med. Labs.). i 0u),ir,xNoride, C22H32C►tN1o, Lislum. Crystals, dec C1 ? c a. Soly in water at 20: 0.06 g/100 mi. t, �Cl 0l&c%Atc.CuHJ8C12N100c. crystals, mp 154-155°. Neu- J ;'*d:ran.m. Soly in water at 20°: 1.9 g/100 mi. Aq solns ? ) q •4n heated above 70'. Soluble in alcohol, glycerol, a it=gl)col,polyethylene glycols. LDSO orally in mice: ,ntg 90% of the tsctrt 1 st pnics et at, Brit.J. Pharmacol.9; 192(1954). s' 6 press.%25°h 1 7 a f &"'°'tc, llibiscrub. t atal.r cat: Topical anti-infective. eedles from tr ether,m 91-93°. Absor lion $ a 1 anic solvents. 1' Pe P P peetra:. # ,. g °7 arw cbt n'I:r): Topical and uterine antiseptic, di ' Buck et al., loc. cit. Ingredient of Lanesta. �• �'�0. Sol in 39 rnIe K THERAP CAT: Spermicide. �, y in rats: 39 m1 4 ,ests and ectoparasaa 21s1.(Lloric Acid. CIH02;mot wt 84.46. Cl 1.98%,H 2O65, Chlorine. Cl;at. wt 35.453; at. no. 17; valences 1 .. r1',U 56 glib. HC102. Prepd from barium hlorate and to 7;elemental state: Cl2. A halogen. Abundance in igne- r s id: Lamb et at, J. Am. Chem. oc. 42, 1643 ous rock(95%of earth's crust): 0.031%b wt;in seawater:,henyl)-N'.(/.mct►)1`' Y u 1-(p-ch/oruphan)Ir1 �'i from sodium chlorate using ion-e hange resins: 1.9% by wt (primarily as NaCI). Natural isotopes: 35 pp 14P- i to ropy enjilir V. Z 4norg.Allgem. Chem.260,271 1949). (75.53%); 37 (24.47%); seven radioactive isotopes and two ".a in aq soln only. Aq solns are st ble if pure and isomers are known; radioactive tracer elements: MCI (T 9; SN 12,837; Dtr s mud from light. 1% aq soln d� 1. 6% soln d� 3.08 X 105 rs; M K {7 ianil;Tirian. C 11 Ie Ie Y o'.EC); CI cosmic 3ays. min;over formed in t t u 11. solo In L01.15 16%solo db 1 0991; 20%solo atm by bombardment with cosmic rays. Discovered in 1774 ttt r' 6.36%. Cl 13.97 fs I l:r).2{;5 solo d�1.1568. A 40%solt�corresponds to by Scheele; recognized as an element in 1810 by Davy. E Soc.1946,729,Cm/ >.1 ;NrO dm 1.282. If higher concns a e attempted by produced on a large scale b electrolysis from Fused chlo- I i 1.1949,98. Manul4 y B Y Y 1952 to RhonrPw ° r.u..n the soln begins to dec with evol lion of chlorine rides. The industrial product is about 99.3%pure. Contam- ' yt i,icn and formation of perchloric acid. The salts of inants are traces of bromide,hexachloroethane, hexachloro- ; r A1"s;rd are known as chlorates. benzene, and water. Purification: Fye, Beaver, J. Am. .a OsiJizing agent;with H2S01 as catal st in acryloni- Chem. Soc. 63, 1268 (1941); A. Klemenc, Die Behandlung t aY;,ilmcrizsnon. Caution: Strongly irri acing to skin, i and Reindarstellung von Casen (Vienna, 2nd ed., 1948) p { 1 (ex3)2 d..0 membranes. 153. Lab prepn from MnO,and HCI: Schmeisser in Hand- r 21at2 Chlorimpiphenine. 1-[2-[4-[3-(1- hloro-lOH- book of Preparative Inorganic Chemistry vol. 1, G. Brauer, pr ,j.in-l0-yl)propyll-l-piperazinyllethylj- methyl-2- Ed. (Academic Press, New York, 2nd ed., 1963) p 272. 129°. sicilidinone, 3-chloro-l0-[y-[N'-[o-0-me yl-2-oxo- Reviews: Cilia Review vol.12,no. 139(Aug. 1960); Chlorine, J. S. Sconce, Ed., A.C.S. Monograph Series, no. 154(Rein- I" n acetone, mp Igl• —..:.h,lm-3•y))ethylJ-N-piperazinyl]propyl)p�i°nothia- B P 6 64% hold, New York, 1962)901 pp; MTP Int. Rev. Sci.: Inorg. tta C?IIIrCINSOS;mot wt 486.11. C 61.77%, Chem., Ser. One, vol. 3, V. Gutmann, Ed. (Butterworths, ,'I r •ine. Crystals from 07 a.,IN 14.41%,O 3.29%, S 6.60%. Prepn: B g. pat. I, t -• max (alc): 259 an sari(1965 to Asia), C.A.65, 8934f(1966). London, 1972);Downs,Adams,"Chlorine,Bromine,Iodine ally insol in chloro and Astatine"in Comprehensive Inorganic Chemistry,vol.2, r - -6.3. LDS,orall)a J. C. Bailar,Jr. et at,Eds. (Pergamon Press,Oxford, 1973) iarmacol. 6xp Ilm pp 1107-1594. i w2 1 20 —CH2�2CH2 Greenish-yellow, diatomic gas; suffocating odor. mp L 31arial. g H C1 —101.00' (172.15°K); bp —34.05' (239.10°K); d (liq, 20% 6.864 atm) 1.4085;d(liq, —35°,0.9949 atm) 1.5649;critical 1,2-trichluro 1.1r . L� / tem 144% critical ressure 76.1 atm; C N P P 9 (gas. 25') 8.11 ydroxy-4•(2,2.2-in �� Da cal/mole/`C. Marketed in the form of gas over liquid com- rdroxy-2-metb)1•s 3 pressed into steel cylinders. Caution: Never heat cylinders. 31 ne; Lora; Mecoiai. Vapor pressure data: Giauque, Powell, J. Am. Chem. Soc. / tl„• .58. C 36.18Sr. B f:s Disc,bp001 260°. 61, 1970(1939). Sol in water(25°)with formation of aque- i Consult the cross index before u his.,Eection. Pa i 32 Butylated Hydroxytoluene 1532. Butylated Hydroxytoluene. 2,6-Bis(l,l-dimethyl- Chem.Sac.69,1046(1947);Justoni,Brit.pat.719,891(1954 Afonatsh.90, 783 (1959). Toxicity: ethyl)-4-methylphenol; 2,6-di-ter(-butyl-p-cresol, 2,6-di- to Vismara). Ind. Health 14, 114(1956). tert-butyl-4-methylphenol; BHT; DBPC; Antrancine 8; Thick,oily liquid. d 1.00. mp -22°. by 250°. Practically Liquid, by 171-172°. d20 0.9012, Tenox BHT; Ionol CP; Sustane; Dalpac; Impruvol; Vianol. insoluble in water; Sol in alcohol or ether. LDso orally in Soluble in 20 parts water; Sol in n CIs1126O; mot wt 220.34. C 81.76%, H 10.98%, 0 7.26%. rats: 5.14 g/kg, Smyth et at., Arch. Ind. Hyg. Occup. Med mineral oil. LDS,orally in rats: 2 10 61 1954. ut lane: Stillson, U.S. at. , ( ) use: Solvent for nitrocellulose,re: Prepared from cresol and isob y P P P- 2,428,745 (1947 to Gulf); McConnell, Davis, U.S. pat. dry cleaning. Caution: Toxic symp 3,082,258 (1963 to Eastman Kodak). Inactivator of lipid- 1537. n-Butyl Bromide. I-Bromobutane. C4H,Br;mol Methyl Cellosolve. containing mammalian and bacterial viruses: Snipes et al.. wt 137.03. C 35.06%, H 6.62%. Br 58.32%. Cli3(CH2)3Br. Science 188,64(1975). Prepd from n-butyl ale and a hydrobromic-sulfuric acid 1544. Butylchloralaminopyrine mixture: Kamm, Marvel, Org. Syn.vol. 1, 5 (1921);Skau, 1,2-dihydro-1,5-dimethyl-2-phenyl- McCullough. J. Am. Chem. Soc.57,2440(1935). with 1,Z3-trichloro-1,l-butanediol OH Colorless liquid. da 1.26815 bp 101.Y(mp -112°). np chloral hydrate; butylchloralpyran (CH ) C C(CH3)3 1.4398. Insol in water;sot in "Vol,alco ether. min. C17HJ4CI3N3O; mot wt 424.7 3 3 / Cl 25.04%, N 9.894, 0 11.3076. 1538. sec-Butyl Bromide. 2-Bromobutane;methylethyl• Prepn: Pfeiffer, Seidel, Z. Physiol. bromomethane. C4H,Br; mot wt 137.03. C 35.06%,H Needles from water, mp 82-84°. 6.6276, Br 58.327o. CH3CH2CHBrCH. Prepn: Leven, about 65 ml water.2 ml alcohol. 10 CH3 Marker, J. Biol. Chem. 91, 405 (19313; Kenyon et al,I. slightly in petr ether. Chem. Sac. 1935, 1080; Skau, McCullough, J. Am. Chem Note: See also Butylchloral Hydt Sac.57,2440(1935);Colson et al.,J. Chem.Sac.1965,2364. Crystals,mp 70% d-'0 1.048. by 265°. Flash pt(open cup): Prepn of optically pure isomers: Goodwin, Hudson, I 1545. Butylchloral Hydrate. 260°F 027°C). Insol in water. Freely Sol in toluene,sot in Chem. Sac. (B)1968, 1333. tanediol; a,a,0-trichloro-n-butyral( methanol, ethanol, isopropanol, methyl ethyl ketone, ace- dl-Form, colorless liquid, pleasant odor. d2s 1.2530. by C13O2; mot wt 193.47. C 24.83%, tone, Cellosolve, petr ether, benzene, most other hydrocar- 91.2°(mp -112°). n2 1.4344. Insol in water. Freely so[in 16.54%. CH3CHCICCI2CH(OH)2. bon solvents. Soly in liquid petrolatum (white oil): 0.5% alcohol,ether. to a,a,o-trichloro-n-butyraldehyde,i w/w. More sot in food oils and fats than butylated hydr- d-Form, n10 1.4359-1'4362. a2 +42.64°. Orthorhombic scales. Pungent oxyanisote. Good soly in linseed oil. LD50 in rats: 1600- /-Form, no 1.4368. ap -43.7°. 1.694. mp 78°. One gram dissoly 3200 mg/kg(Eastman Kodak,unpublished data). Caution: Narcotic in high concns. alcohol, 20 ml chloroform. I ml gly USE: Antioxidant for food, animal feed, petrol products, olive oil. Incompatible with alkalie synthetic rubbers,plastics,animal and vegetable oils,soaps. 1539. tent-Butyl Bromide. 2-Bromo-2-methylpropane; acid, dichloropropylene and sodiun Antiskinning agent in paints and inks. 2-bromoisobutane; trimethylbromomethane. C H Br; mol (see also incompatibilities given for c wt 137.03. C 35.06%. H 6.62%, Br 58.32%. ZCf13)3CBr. soln in alcohol it is precipitated byi 1533. n-Butylbenzene. 1-Phenylbutane. CI01-114;mot wt Prepn: Brunel. J. Am. Chem. Sac.39, 1978 (1917); Bryce• water in the form of globules consist' 134.21. C 89.49%,H 10.51%. C6Hs(CHj)3CH3. Prepd with Smith. Howlett, J. Chem. Sac. 1951, 1141; Coe et al.,ibid. holate,C4HsC13O.C2H3OH. almost quantitative yield from benzyt chloride or bromide, 1954,2281 THERAP CAT: Hypnotic. propyl bromide and sodium without addnl solvents: Radzi- Colorless liquid. dos 1.2125. by 73.3°. fit -16.3°. At szewski, Ber.9, 261 (1876). Similarly from bromobenzene. 210°changes to isobutyl bromide. n& 1.4249. Insol in wa• 1546. n-Butyl Chloride. I-Chr butyl bromide and sodium in benzene: Balbiano. Ber. 10, ter;miscible with organic solvents. binyl chloride; butyl chloride. C41 296(1877);Read.Foster,J.Am. Chem.Sac.48, 1606(1926). 51.907., H 9.80%, Cl 38.3076. CH. Liquid. mp -88.5°. d4m 0.8604. bp760 183.1%bp400 159.2% 1540. n-Butyl n-Butyrate. Butanoic acid butyl ester,bu• from n-butyl alcohol by heating bp,, 136.9% bptoo 116.2% bp60 102.6% bp,92.4% lop, 76.3% tyric acid butyl ester. CaH16O mot wt 144.21. C 66.63%,H ZnCI{: Whaley, Copenhaver, J. A bplo 62.0%bps 48.8°;bpi q 22.7°. n2 1.49040. Insol in water; 11.18%,0 22.19%. CH,(&" 2'COO(CH,)3CH.. Prepn from 0938); Org. Syn.coil.vol. I(2nd e. miscible with alcohol,ether, benzene. butyl alcohol: Robertson, Org. Syn.coil.vol.I, 138(1941) Liquid. Highly flammable. das Horton. U.S.pat. 2,522,676(1950 to Socony-Vacuum Oil). 0.88099. One gallon weighs 7.35 1534. sec-Butylbenzene. (1-Methylpropyl)benzene; 2_ Liquid,by 165°. d20 0.8692. np 1.4064. Practically insolbPs6o 78.5°. n2 1.40223. Flash pt phenylbutane. CIOH16;mol wt 134.21. C 89.49%,H 10.51%. miscible alcohol ether. moment: 1.95. Practically insol it C6H3CH(CH3)CH2CH . Prepd in water;misc e w , .from benzene and n-butyl Miscible with alcohol,ether. LDS,( chloride in presence of AIC13: Schramm, Monatsh. 9, 621 1541. Butyl CarbitolOa. 2-(2-Butoxyethoxy)ethanol;di- Toxic Substances List,H. E. Christ( (1888); by the action of sodium on y-chloro-sec-butylben- ethylene glycol monobutyl ether. CeH18O3; mot wt 162.21 USE: As butylating agent in orgat zene: Braun et al.,Ber.46, 1277(1913);with other products C 59.23%, H 11.18%, 0 29.59%. HOCH2CH2OCH,CHt manuf of butyl cellulose. by heating n-or sec-butyl alcohol with 8076 H2SO4: Meyer, OC4H9. Prepn: Riemschneider, Gross, Monatsh. 90,783 THERAP CAT(VET): Anthelmintic. Bernhauer, Monatsh.53,727(1929). Liquid. mp -82.7% d420 0.8608. bp760 173.5%bp400 150.3°; (1959). Purification: Miller,Yonan, J. Am. Chem Soc.19' 1547. sec-Butyl Chloride. 2-CI 5931 (1957); Ridley, Ridley, Brit. pat. 795,866 (1958 to meth I ro ane. C H Cl;mot wt 92. bP:oo 128.9% bploo 109.5% bp60 96.0°; bp, 86.2°; bp20 70.6°; Y P . 4 y 20 Esso). Cl 38.30%. CH CH CHCICH. Pr. bp10 57.0°;bps 44.2°;bp1.0 18.6°. na 1.48980. Insol in water; Practically odorless liquid, by 230.4°. mp -68.1°. ds ? 4 s miscible with alcohol,ether, benzene. 0.9536. nn 1.4258. Miscibl afar, oils. Miscibility in hol, hydrochloric acid and ZnCl2: d-Form. [a]A2S +26.6°: Bonner, Greenlee, J. Am. Chem. o --� Chem. Sac.46, 756 (1924); Copenh Soc.81, 3336(t959). other organic efits�Jackson.Drury, iii;. Chem.Sl, toll vol. I, 143 (1941); from sec-I /-Form, 3 u -9). 1491Q19�. Flash t L-)3sorrally in.rats.,gut- gs: Coulson et al.,J. Chem Soc.1965, ]0 6-56, 2.00 prN myth et al, J. lnd. Hyg. Toxirnl.23;2 USE: Solvent;in organic syntheses. 19 pure isomers: Goodwin, Hudson, 1535. tert-Butylbenzene. (1,1-Dimethylethrb . lb e� 33. 1542. n-Bu 1 Carbonate. Carbonic acid dibutyl ester, -Form: liquid; pleasant, ethere 2-methyl-2-phenylpropane: trimethylphenylmethdibut I carbonate. C H O; mol wt 174.23. C 62.04%,H 66°• 20 1.3960; np 1.3953. One gr dobutylbenzene. C Ht4; mot wt 134.21. C H Y v e water a 2'%miscible with alcohol. 10.51%. C H C(CH Pre d from benzene,isolo- 10.41%,0 27.55%. (C4I1yO�2C0. Prepn from ethyl carbon•6 s s�s P ate, but I alcohol and eth Ima nesium bromide: Frank a d-Fo n20 1.3963; 20 +30.8°ride and AIC13: Konowalow, Bull. Soc. Chim. 865 Y Y 8 orm: n�1.3968; -31.0% (1896); Shoesmith, Mackie, J. Chem. Sac. 1928, om al, J. Am. Chem. Sac.66, 1509(1944); from butyl alcohol D oisobutyl alcohol and benzene by treatment with ul- and CO in the presence of Pd and CuC12: Mador, Black• Caution: ild irritant and,in ME ham. U.S.pat. 3,114,762(1963 to National Distillers). 1548. to -But 1 Chloride. 2.( furic acid: Meyer, Bernhauer, Monatsh. 53, 727by Ydecarbonylation of p-phenylisovaleraldehyde in of Liquid, by 206.E°. din 0.9251, d4 0.9388. np 1.4111. 2-chloroisobutane; trimethylchtoror Pd/C catalyst: Wilt, Abegg, J. Org. Chem.33, 9 (1968). Practically insol in water. Miscible with ethanol,benzene. wt 92.57. C 51.90%, H 9.80%, C See also Groose,Ipatieff, J.Am. Chem.Sac.57,241 (1935); chloroform, acetone, ether and other organic solvents, set Prepd b shaking tert-butyl alcohc Jackson, Drury, Ind. Eng. Chem.51, 1491 (1959). ' • to Norris. Olmsted. Ipatieff, Pines, ibid.58, 1056(1936). B� Org. S' Liquid. mp -58.1% d4S0 0.8669. bp760 168.5%bp400 1 8°; 1543. Butyl Cellosolve0a. 2-Butoxyethan ne from tert-butyl alcohol and PC13: t bp2oo 123.7% bp2oo 103.8°; bp60 90.6% bp40 80.8% bp20 65. col monobut t ether. C H ;�.mo1 wt 118.17. C Sar.1953, I920. bplo 51.7%bps 39.0°;bpa.o 13.0% n2 1.49235. Insol in water; 'Co'H-Yh94°l HOCH2CH2OC4Hy. Prepn Liquid. dos 0.847. nut 1.38686. i miscible with alcohol,ether, benzene. bpato 32.6°; bp2o0 +14.6°; bplao from butyl alcohol and ethylene carbonate or 2-chlorcetha- _19 0° Sparingly sot in water, mi 1536. n-Butyl Benzoate. Benzoic acid butyl ester. C - not, or from ethylene glycol and butyl bromide: Carlson, ether. Boiling with water yields rer H14O2; mot wt 178.22. C 74.13%, H 7.92%, 0 17.959. U.S. pat. 2,448,767 (1948 to Mellon Inst. Ind. Res.);Kla• C,H,COO(CH2)3CH3. Prepn: Newman, Fones. J. Am. mann, Bertsch, Ber.88, 201 (1955); Riemschneider,Gross. 1549. lert-Butyl Chloroacetate. Page 198 Consult the cross index before using this section. �f , A ICJ 112 DOD ��a tVA --nFIS-4 3-3 L) Y , c 9 pCz►� - (__ /1 u In4vw�cA� Cca'�'� 16544v vv l THE COASTLAND TIMES, Thursday,October 27,1988,Page 94 sunsupervised probation and a $300 probable cause hearing is scheduled for fine. Nov. 22 to.allow time for a governor's Teddy Doyle Daniels, 30, of Manteo warrant to be issued for his ex- pleaded guilty to no driver's license and. tradiciton. received 90 days suspended with two The following defendants waived pro- years unsupervised probation and a bable cause hearings and were bound $100 fine and$25 of the fine was for fail-* over for trial in superior court: Michael icig to appear at an earlier.court date. Wayne Berg,25, of Genesee,Idaho,for Robert John Holton,39, of Kill Devil forgery and uttering a forged instru- , Hills pleaded guilty to driving while ment; Robert L. Huffstetter, 17, of license revoked. He said he received a. Coinjock, for scond degree burglary; call from some friends who said they and Dearing P. McKay of Kill Devil were too drunk to drive and he had".us- ., Hills, for breaking and entering and ed bad judgment"in going to pick.them larceny. .up.He received nine months suspended Peter L. Etheridge of Wanchese was for two years and a fine of$200. fined$25 for failure to wear a seat belt; Matthew Bryan Kumper, 16,of Rich- a charge of failure to yield was drop- mond, Va., pleaded guilty to speeding ped. 77 in a 55 mph zone.He received 30 days Lennon Edward Meekins of Manteo suspended with unsupervised probation admitted to exceeding safe speed for two years and a fine of$75. _ ,reduced from speeding 70 in a 55 zone Two defendants apeared for and was fined$10. preliminary hearings. Lynne Downing Titana H. Dutcher of Kitty Hawk ad- Carver., 33, of Fayetteville had a first mitted to speeding and was fined$10,as appearance for the felony charge of was.Wagner White of Roanoke Rapids. assault with a deadly weapon with in- tent to kill,inflicting serious injury.Her probably cause hearing is set for Nov. The first White House wedding took 4. place in 1812 as Lucy Payne Kenneth Michael Barlow, 29, of Kill Washington, sister-in-law of President Devil Hills had a first appearance on a James Madison, married Supreme fugitive warrant from Virginia. His Court Justice Thomas Todd. anyone wboas�bany iuformacia to Kill De . ate�41-l3� Crime Lb b,01 - .' -wv J iundaY.AR91.1ltl,�aN.tY .o.� M '. 4 "DF----- 0�I.PC 77 bus17y ySti e My 'Ctt1C .A a. , i Sodium Po 4y p osphate ring, dentifrices, soaps. n. phosphate;disodium hydrogen phosphate; disodiu C_Zath�da, o- ing boiler scale, softening water; manuf paper; laundering; phosphate; disodium phosphate; DSP; phosphate - tanning leather;in detergent mixture. secondary sodium phosphate. HNa204P; mol wt 141.98. um Phosphite. HNa203P; mol wt 136.96. H oat. C1Na0; mot wt H 0.11%,Na 32.39%.O 45.08%,P 21.82%. Na2HPO4. In- Na 33.57%0 35.05%, P 22.61%. Na2HP03. 8 77%, Justrial production: Faith, Keyes, & Clark's Industrial pentahydrate, white, hygroscopic cryst powder. Heat of 3 !' i2.27%. NaC1O4. Chemicals(John Wiley, New York, 4th ed., 1975) pp 746- rystals. Dec at about 75;, formation (25°): -684.2 kcal/mole. Freely Sol in water. %+ Keep well closed. :eep well closed. Anhydr, exsiccated sodium phosphate. Hygroscopic pow- v 1cr. On exposure to air will absorb from 2 to 7 mots H2O, 9426. Sodium Phosphomolybdate. Sodium molybdophos- , ,lepending on the humidity and temp. Sol in about 8 parts phate. Mo12Na��04OP' mol wt 1891.37. Mo 60.88%, Na 113; nNa04; mol wt 189.92. pater,much more Sol in hot water. Soly per 100 gal water 3.65%, 0 33.84%, P 1.6476. Na3PO4.12MoO3. NaMn04. increases from about 14 lbs at slightly >0°to over 900 Ibs at White crystals. Freely Sol in water. '. Insol in alc. H of 1%aq solo at 25°: 9.1. Keep well hygroscopic granules. 95 p USE: As reagent in chemical analysis. closed. 8427. Sodium Phosphotungstate. Sodium tungstophos- Dehydrate, Sorensen's phosphate,Sorensen's sodium phos- phate. Approx 2Na20.P2O5.12WO3.18H2O. dioxide;sodium super- phate. White, granular powder. Sol in water. 77.99. Na 58.97%, O Heptahydrate,crystals or granular powder. Stable in the P :ontains 90-957.Na O. air. d about 1.7. Sol in 4 parts water. more Sol in boiling USE: As reagent for alkaloids, uric acid, potassium. )0°in aluminum vessels pater;practically insol in alcohol. The aq soln is alkaline. 8428. Sodium Plumbate(IV). Na203Pb; mot wt 301.17. rrbon dioxide has been pH about 9.5. Na 15.27%, O 15.94%, Pb 68.79%. Na2Pb03. Penneman, Inorg. Syn. Dodecahydrate, translucent crystals or granules; readily Trihydrate,light yellow,fused,hygroscopic lumps. Sol in loses 5 mots of water on exposure to air at ordinary temp. water,but gradually dec with separation of Pb02. Keep well Absorbs water and When contg the full 12 mots of H2O it melts at 34-35°. d closed ar, forming sodium hy. about 1.5. Sol in 3 parts water;practically insol in alcohol. latter quickly dec into Aq soli+is alkaline,pH about 9.5. Keep well closed and in a 8429. Sodium Polyanetholesulfonate. Polyanetholesul- H2O2 is formed which coot place. fonic acid sodium salt; anetholesulfonic acid sodium salt ;anic matter or readily Incompat: Alkaloids, antipyrine, chloral hydrate, lead polymer. A polymer of anetholesulfonic acid. Originally plosion may take place. acetate,pyrogallol.resorcinol. developed as an anticoagulant, it was soon found that it 1 contact with organic or Human Toxicity: Anhydr form may cause mild irritation possesses anticomplement action and lowers the bactericidal to skin,mucous membranes;intern.causes purging. action of blood. Ref: Demote. Reinert, Arch. Exp. Pathol. :table fibers, feathers, USE: As mordant in dyeing;for weighting silk;in tanning; Pharmakol. 158, 211 (1930); Friedmann, Klin. Wochenschr. , coral; rendering air in manuf of enamels,ceramics.detergents,boiler compds;as 14, 215 (1935); Stuart, J. Clin. Path. 1, 311 (1948); Hoff- :orpedo boats, subma. fireproofing agent;in soldering and brazing instead of borax; mann-La Roche Biochemicals Catalog. in sick rooms; dyeing as reagent and buffer in analytical chemistry. sis. General oxidizing THERAP CAT: Cathartic. CH=CHCH3 ;ive. See Sodium Hy. THERAP CAT(vET): Laxative. 8422. Sodium Phosphate, Monobasic. Sodium biphos- a peroxydisulfate. Na- phate; sodium dihydrogen phosphate; acid sodium. phos- S03Na 3.76%.S 26.93%. Nat- phate;monosodium orthophosphate; primary sodium phos- \ phate. H,Na04P;mol wt 119.98. H 1.68%, Na 19.16% 0 c;decompn is promot- 53.34%,P 25.81%. NaH2PO4.. It is about 99%pure. OCH3 ial Soly in water at 20': Monohydrate, white, odorless, slightly deliquesc crystals n t MLD i.v.in rabbits: or granules. At 100°loses all its water;when ignited it con- vol. 1, W. S. Spector, scrts into metaphosphate. Freely Sol in water; practically Light brown powder. Insol in alcohol. Swells in water s 278-279. insol in alcohol. The aq soln is acid. pH of 0.1 molar aq and slowly goes in soln with neutral reaction. Aq solos are t; promoter for emul- soln at 25°: 4.5. stable to heat,dil alkalies and dil acids. n: Highly irritating to Dihydrate, orthorhombic bisphenoidal colorless crystals, USE: Under the trademark Liquoid to inhibit blood coagu- mp 60°. d 1.915. At room temp crystallizes with 21-12O. lation in vitro, and as diagnostic reagent to encourage the Tc mot wt Directions for max yield: Beans, Kiehl, J. Am. Chem. Soc. growth of pathogens in blood. Also to stabilize colloidal scan. Na0 4 49,1878(1927). solos such as milk and gelatin. (Not to be confused with 23%. NaTc04. Prepn: USE: In baking powders;in boiler water treatment;as dry Liquoid, registered trademark of Johnson & Johnson for . Acta 1, No. 2, 107 acidulant for foods: Tidridge, Pals, U.S. pat. 3,030,213 castor and olive oil emulsion.) akopulos,AEC Acces- 0962 to FMC). 73 pp(1964). C.A.62, THERAP Car: Urinary acidifier. 8430. Sodium Polyanhydromannuronic Acid Sulfate. THERAP CAT NET): Urinary acidifier. Paritol;Ateroid;Heparinoid;Hepinoid;Thrombocid. Prepd scanning). from alginic acid. Structurally similar to heparin. 8423. Sodium Phosphate, Radioactive. Sodium phos- White powder. Sol in water. A 5%aq soln is easily prepd lydroxybenzenesulfonic phare-J3P; radioactive sodium phosphate; sodium radio- and may be sterilized by autoclaving. te. C6H5Na04S; mol phosphate(12P); Phosphotope. THERAP CAT: Anticoagulant. 11.72%, 0 32.63%, S Aq soln of mixed radioactive phosphates with a pH range of 5.0-6.0. Contains radioactive monobasic sodium phos- 8431. Sodium Polymetaphosphate. Graham's salt; "so- slightly bitter taste; phate (NaH 32P0f) and radioactive dibasic sodium phos- dium hexametaphosphate'; glassy sodium metaphosphate; gram dissolves in 4.2 hate(Na H12P0 1 73P is a pure beta emitter with a half-life Hy-Phos. (NaPO3),. A mixture of polymeric metaphos- alcohol, 13.5 ant boil. o 2 4 phates; not a hexamer. Prepd by rapidly chilling molten In is neutral. of 'l-days. r8 Sy n. car: Antineoplastic;antapo ycy e n stic sodium metaphosphate: Bell, Ino S n. 3 103.(1950). aid(neoplasm). Reviews: see Sodium Metaphosphate. an intestinal antise Clear,hygroscopic glass. mp 628°. Sol in water,but dis- slowly granula i'ng 8424. Sodium Phosphate, Tribasie.. Trisodium ortho- solves slowly.'Depolymerizes in aqueous soln to form sodi- ye• phosphate;trisodium phosphate;TSP;Oakite. Na304P;mol m trimetaphosphate and sodium orthophosphates. phenate; sodi car_ wt 163.94. Na 42.07%, 0 39.04%, P 18.89%. Na3PO4. Sodium hexametaphosphate detergents, Calgon, Giltex, pbe C; sodi mot Crystallizes with 8 and 12 mots of H2O. Q adrafos, Hagan phosphate, Micromet. Mixtures contg 1 1- C6 O 1 ; mot Dodecahydrate,colorless or white crystals. When rapidly Gr ham's salt as the principal agent. Supplied in the form aOH in del met 78%. heated melts at about 75°. Does not lose the last mol of of powder, flakes, and as small, broken, glass-like parti- )1, 2710(1959). anol: water even on moderate ignition. d 1.6. Sol in 3.5 parts cles. Sol in water(pH adjusted to 8-8.6). Insol in organic r water, 1 part boiling water;insol in alcohol. The aq soln is soly or granules. D rn_ ts. Possess dispersing and deflocculating properties, water;sot in a o- strongly alkaline. pH of 0.1%soln: 11.5;of 0.5%soln: 11.7; coal late albumins. and inhibit the crystn of slightly Sol of 1.07.solo: 11.9. Technical crystals are sometimes made coin ds such as calcium carbonate and calcium sulfate. with excess alkali to,prevent caking and give more alkaline u Water softeners and detergents. For leather tanning. C. Dibasic sodium solutions. dye' g, laundry work, textile processing; for the"threshold USE: In photographic developers;clarifying sugar;remov- tr tment"of softening industrial water supplies. I Consult the c s-index be.. re using this section. Page 1119 / I a_. f PART IX: STABLE REGULATIONS ADOPTED 4/l/72, BECAME EFFECTIVE 4/12/72 REVISED 7/15/93 BOARD OF HEALTH STABLE REGULATIONS 1. under the authority of Massachusetts General Laws, chapter 111, section 155, no person shall erect, occupy or use for a stable any building or land for the housing of horses and/or ponies in the Town of Barnstable, unless such use is authorized and licensed by the Board of Health and is in compliance with the Zoning By-Laws of the Town of Barnstable. 2. The license fee for each horse and/or pony shall 'be established by the Board of Health and said license shall be effective July 1 of each calendar year and shall expire on June 30 of the succeeding calendar year. 3. No stable may be constructed within the Town of Barnstable unless a stable license is first obtained from the Board of Health. The construction of stables shall be in conformity with the Barnstable Building code. 4. Stables shall conform to the following: (a) There shall be at least two (2) windows in every stable. (b) There shall be adequate ventilation in every stable. (c) Each stall shall be of adequate size so that any horse and/or pony shall have room to comfortable lie down or stand up. (d) There shall be adequate drainage either natural or artificial. (e) All flooring in any stable shall be acceptable to the Board of Health. 5. Land on which horses or ponies are pastured shall be fenced in such a manner as to prevent any damage to abutting property, trees or shrubbery. 6. No person, company or corporation shall erect, occupy or use a building for a livery or horse or pony stable for the keeping of horses or ponies unless such a stable or building is more than 200 feet from a church or school building and is more than fifty (50) feet from a building that is used as a dwelling or home. 7. owners of stables housing horses or ponies must clean the manure from the stable at least once each day. waste matter shall be disposed of in a sanitary manner, and shall not be accumulated on the property. 8. No horse or pony shall be allowed to be pastured on any land unless said area is fifty (50) feet from a home or dwellingo 9. No person, company, or corporation shall allow a horse or pony horse or pony to be pastured on any land unless said area is fifty (50) feet away from a private water supply well. A fence shall be erected to keep horses and ponies at least fifty (50) feet away from any private water supply well. 10. No person, company, or corporation shall erect, occupy or use a building, for a livery or horse or pony stable for the keeping of horses or ponies unless such stable or building is more than fifty (00) feet from a private water supply well. 11. No person shall store, dispose, or stockpile manure within 100 feet of a private water well. 12. Any owner or keeper of a horse or pony must provide stabling facilities for same. No horse or pony shall be allowed to remain out of doors at all times, without having access to proper shelter. 13. Any person, company, or corporation engaged in or desiring to engage in the business of slaughtering horses for the purpose of rendering them shall apply to the Board of Health for a license as required by the Massachusetts General Laws, Chapter 111, Section 154. 14. The Barnstable Board of Health reserves the right to make any decision of situations or problems that arise in regard to health or housing conditions that are not covered by this set of regulations. 15. under Massachusetts General Laws, Chapter 111, Section 157 anyone who violates the provisions of these regulations shall be punished by a fine of five dollars for each day such violations continue. The Barnstable Board of Health also reserves the right to suspend or revoke licenses previously issued if continued violations of these regulations occur. Brian R. Grady, R.S. chairman L usan G. Ra k R.S. Joseph C. Snow, M.D. Board of Health Town of Barnstable