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0100 BREED'S HILL ROAD - HAZMAT
� � f � l'. / I �_. u^. r i y .r.. 1 yyee TOXIC AND HAZARDOUS MATERIALS REGISTRATION FORM NAME OF BUSINESS: CAn4� Cop Pot*-r® cff iP twp"Y Mail To:Board of Health MAILING ADDRESS: /®® Agul& It1t-1- Town of Barnstable TELEPHONE NUMBER: (S®k)'77r�— 3 359 P.O. Box 534 CONTACT PERSON: �i�mLr e6-VQAC-Gf Hyannis, MA 02601 f Does your firm store any of the toxic or hazardous materials listed below, either for sale or for your own use, in quan ties totalling, at any time, more than 50 gallons liquid volume or 25 pounds dry weight? YES VNO This form must be returned to the Board of Health regardless of a yes or no answer. Use the enclosed envelope for your convenience. If you answered YES above, please indicate if the materials are stored at a site other than your mailing address: ADDRESS: 61 8 TELEPHONE: LIST OF TOXIC AND HAZARDOUS MATERIALS The Board of Health has determined that the following products exhibit toxic or hazardous characteristics and must be registered when stored in quantities totalling more than 50 gallons liquid volume or 25 pounds dry weight. Please put a check beside each product that you store: i -/Antifreeze (for gasoline or coolant systems) Drain cleaners Automatic transmission fluid Toilet cleaners Engine and radiator flushes -Cesspool cleaners Hydraulic fluid (including brake fluid) VDisinfectants Motor oils/waste oils ✓ Road Salt (Halite) i/ Gasoline, Jet fuel Refrigerants Diesel fuel, kerosene, #2 heating oil Pesticides (insecticides, herbicides, Other petroleum products: grease, lubricants rodenticides)(&j5m iVe ' Degreasers for engines and metal Photochemicals (fixers and developers) Degreasers for driveways & garages Printing ink V Battery acid (electrolyte) Foe-14,r.I�� Wood preservatives (creosote) Rustproofers Swimming pool chlorine Car wash detergents _ Lye or caustic soda 1 Car waxes and polishes Jewelry cleaners Asphalt & roofing tar Leather dyes V Paints, varnishes, stains, dyes Fertilizers (if stored outdoors) V/ Paint & lacquer thinners PCB's V Paint & varnish removers, deglossers Other chlorinated hydrocarbons, Paint brush cleaners / (inc. carbon tetrachloride) ;I Floor & furniture strippers Any other products with "Poison" labels Metal polishes (including chloroform, formaldehyde, Laundry soil & stain removers hydrochloric acid, other acids) (including bleach) Other products,not listed which you feel may lI Spot removers & cleaning fluids be toxic or hazardous (please list): (dry cleaners) 7 V Other cleaning solvents A crft c, Ij(sl� i Bug and tar removers Household cleansers, oven cleaners White Copy-Health Department/ Canary Copy-Business rAPK COD Independence Park a Breeds Hill Road SIX Hyannis, MA 02601 508-775-3358 I Donna Miorandi Board of Health Town of Barnstable PO BOX 534 Hyannis,--MA-U2601 - RE: Hazardous Materials Storage September 27, 1991 Dear Ms. Miorandi, I have attached an updated Toxic and Hazardous Materials Registration Form. Please note that acetic acid is stored outside in product-tight and environment- tight containers and is located within diked, secondary containment. Cape Cod Potato Chips feels this storage is adequate to meet the intent of Article XXX1X, Sections 4. and 5 and therefore requests a variance of the "protected from the elements" clause in. Section 4(b). Finally, nitrogen is also stored outside-.in a manner similar to acetic acid. Cape Cod Potato Chips is requesting a determination if the nitrogen is a hazardous material, and if so, requests the same variance requested for acetic acid. If you require further information or would like to schedule a visit, please call me at 775-3358. Sincerely, Bart Petracca Quality Control ��tt g— a r CO!,�PLIANCE: CLASS: 1. bfarine,Gas St ations,Repair ` O� iV �f g �f�S ��LC Os isfactory 2. Printers _ BOARD O F EALTH 3. Auto Body Shops unsatisfactory- 4. Manufacturers COMPANY %c � ��.0 �. h,, (see"Orders") S. Retail Stores 6. Fuel Suppliers ADDRESS �� » Class: 7. Miscellaneous QUANTITIES AND STORAGE (I indoors; OUT=outdoors) MAJOR MATERIALS Case ,lots Drums AbOveTanks p6ndetgrQiind Tanks r IN IDUrT JIN IOUT INj i' & gallons Age ? Fuels: Gasoline, -Jet Fuel (A)`� \ Diesel, Kerosene, #2 (B) Heavy Oils: J. waste motor oil (C) new motor, oil (C) . transmission/hydraulic I if Synthetic Organics: x_-- degreasersD �! �'1 OCR. - Miscellaneous: DISPOSAL RECLA A. TION REMARKS• 1. Sanitary Sewage 2. Water upply Cie �C�:��- - ' E�.>��� �_��'07 O Cal Sewer Public C " J y C.) MC•C� 41 / On-site ® s�- Cl Private v� .� d 3. Indoor Floor Drains: YES �NO 0 Holding tank: MDC at ch basin/Dry well On-site system �< : �� ?2n� ORDERS r 4. Outdoor Surface drains:YES NC _ Q Holding tank: MDC a.�� j _C, Catch basin/Dry well ` On-site system S. Waste Transporter 1 Licensed? Xame f DFl.s ?nation Waste Product YES NO all C� 12 M Pe on s nterviewed Inspector - Date i � 4,�_ ., �.t � -.0 ���v�c.6��'�— e��� ram- J The Town of Barnstable Health Department 367 Main Street, Hyannis, MA 02601 1639. Y• Office 508-790-6265 Thomas A. McKean FAX 508-775-3344 Director of Public Health April 22, 1993 Mr. Bart Petracca Quality Control Manager Cape Cod Potato Chips Breeds Hill Road Hyannis, MA 02601 Dear Mr. Petracca: You are granted permission to utilize an over-pack drum to store acetic acid outdoors. Permission is granted because you stated in your letter dated April 14 , 1993 that the over-pack drum is rated at 95 gallons, well over the recommended 150% capacity. Also, Captain Glenn B. Coffin of the Barnstable Fire Department stated that the Fire Department is "very much in favor of this solution. " In addition, Health Inspector Donna Miorandi stated that this proposal meets the requirements of Town Ordinance, Article XXXIX, Control of Toxic and Hazardous Materials. Thank you for your attention and cooperation in this regard. Sincerely yours,) Thom s McKean Director of Public Health cc: Captain Glen Coffin C � Pow J e'-N 7-01\(� 1 l OY er �`U van w ,c -c) - n s - r) C ... - .. � i � r -. � � �i _ .. • ;. f i t r 1 i 9 -101-517 «193 IS/Z� L �v Mr �eiCc� /5" On CAPECOD Independence Park a Breeds Hill Road t}�� Hyannis, MA 02601 508-775-3358 ', RF4f�I Thomas McKean '` Director of Public Health S Health Department `°' 'T9- 367 Main St. _ _ Hyannis,. rvIA 02601 Dear Mr. McKean, April 14, 1993 Per our telephone conversation on Friday, I am enclosing a photocopy of a type of secondary containment for 55 gal drums. We currently have 15 gallon containers of acetic acid stored outside in a sealed moat. We can eliminate the need to enclose this moat by purchasing the acid in 55 gallon drums. This drum would then fit inside the over-pack drum which is rated at 95 gallons. This quantity is well over the recommended 150% capacity. Please respond to this issue in writing. so I can purchase the secondary container and resolve this issue. L • 1 Sincerely, r Bart Petracca ' Quality Control Manager cc: Captain Coffin, Barnstable Fire Department 4 fh Ln. t W�Ve Make Your ob Ea i 4N _ s er with Seconds �; itM f�. r� Four-Pack a� Containment That's Right for You hi r� a Polyethylene Twist-Top Salvage Drums and (� Lab Pack DI Choose Yellow or New a � ts' i ; e � i• ti c. Red Drum ��^.. f ; Easy twist-on,threaded closure elim- inates the need for cumbersome M nrae: tools to make your job easier. Specifications: 100% polyethylene � REGoIM construction resists corrosion. Suit. a ,•�RV able for incineration or proper land- fill disposal. 95-gallon Salvage Drum `' 4r Red Salvage Drum has a 271/2"diameter opening and ac- cepts all 55-gallon drums and E F-.1 �! wY'a f1 j "s d.� t il!•:i'frsi . smaller. Versatile 20-gallon Lab Pack � ••.. �_,✓.:` holds five-gallon pails,one-gallon bottles s) and a variety of other size containers.Use with optional high-strength Drum Sling (page 377 and Overpack Drum Truck(P g ) P (page 397)for a complete salvage system. Note: Use Drum Sling with closed-head i drums only. u Compliance: 95-Gallon Drum: DOT 49 a CFR 173.3(c), DOT E-9618. UN mark- ing: pending. 20-Gallon Lab Pack: DOT 49 CFR 173.12, E10242. UN marking: pending. IyGE" D�uM6 `` 7 i + x=; F i'M� `. Size Each -- �`Sk SALVAMEN t 7s�ts��,� *� No. Description (Gal.) 1 10 GUIDE T � Q6.75o7 YellowO SAFE SECONDARY CONTAINMENT Salvage Drum 95 168.90 15205 Forbestresults,toliowtheseguidelines: PIQB•17853 Re d 30• allon 55•gallon 85 gallor u es Sal va e Drum 95 193.15 173.85 15 allon g M �Mt x + t Y�rayj ° Cn a 1Air1 i "w. QB•7507-2 Lab Pack 20 39.20 3530 S qq r QB•2785 Drum Sling gallon•. g 38.40 ?:8 QB-16128 .Overpack +,,�, 'x' r j ; ` .tip :',#�„e ;x5 " Drum Truck 254.70 VR 1�" ' P�rsmallen -Ho r } _ s two 5-gallon Holds 15 gallon Holdsgallon ,Holds_55-galk Is or smaller w drum.or smaller4 ;drum or smaller ".drum or small Salvage Drums z , r ,Iy;New 15-Gallon Size for Smaller Amounts . e Pre-labeled drums allow easieridentification of what's inside. Heavy-duty to help prevent BARNSTABLE FIRE DEPARTMENT 3249 Main Street s o 1927 P Barnstable,Massachusetts 02630 508-362-3312 '�uumu WILLIAM A.JONES III,CHIEF GLENN B.COFFIN,CAPTAIN FIRE PREVENTION. Apri ] 15, 1993 Mr. Thomas McKean Health Department Town of Barnstable 367 Main Street Hyannis, MA 02601 Dear Thomas: Recently, I received a letter from Mr. Bart Petracca from the Cape Cod Potato Chip Company. This letter was addressed to you and indicated the use of a certain form of secondary containment for their acetic acid. This substance has been stored outside of the building. The area is secure and is close to the water treatment facility. I suggested a "dog house" type construction earlier, but this idea was presented by Bart to me Last week. This department is very much in favor of this solution. The Poly Overpack drum would suffice for safe storage in our opinion. In addition, this type of overpack is in use by regional HAZMA T units. In short, this may minimize and condense some of the quantities stored on site and as such is a good solution. If you have any questions, please do not hesitate to contact Chief Jones or myse 7 f. Sincere G enn fin ap ain 1-Chief Jones 1-Bart Petra c � Town Manager, Warren Rutherford 367 Main Street Hyannis, MA 02601 In order to comply with M6L Chapter IIIF, I have enclosed an updated MSDS list along with additional MSDS' that are being submitted for the first time. They are: AUSTIN Al BLEACH LUMINATE GLACIAL ACETIC ACID SODIUM THIOSULFATE HYDROGEN SULFIDE THREDKUT 99 HYGARD TRANSMISSION OIL IMPROVED TREM SEAL GP MSDS deletions include; BELT DRESSING SOLO 100 CANOLA OIL SOAKAHOLIC MSDS updates include: 723 SPRASOLVO Our current contact and emergency information is as followm, Company: Cape Cod Potato Chips Breeds Hill Rd. Hyannis, MA 02601 Business Phone: (508)775-3358 Emergency Phone: (508) 477-8126 Bart Petracca, Quality Control (508)771-5202 Donna Hoke, Employee Relations �SIC Code: 2096 � Average # of Employees: 135 ^ Thank you, ^ Bart Petracca Quality Control Supervisor � � HAZARDOUS MATERIALS LIST 11/23/92 CHEMICAL OR PRODUCT NAME DEPARTMENT MSDS LOCATION ' ACETIC ACID, GLACIAL WWT. COMMUNICATION ACETONE ^ � MAINTENANCE COMMUNICATION ACETYLENE MAINTENANCE COMMUNICATION ' ACTIVATED ALUMINA PROCESSING COMMUNICATION ` ACTIVATOR (POLYAMIDE RESIN) MAINTENANCE COMMUNICATION ADHESIVE - 81669 MAINTENANCE COMMUNICATION ALCbNOX Q. C. COMMUNICATION ` ALUM (DRY) WASTEWATER COMMUNICATION ALUM-A-LUB MAINTENANCE COMMUNICATION ALUMINUM MAINTENANCE COMMUNICATION ' . ANDEROL FGC 20 COMPRESSOR OIL MAINTENANCE COMMUNICATION ANSUL FIRE SUPPRESSANT PRODUCTION COMMUNICATION ANTI-FREEZE MAINT. , S/R, COMMUNICATION & WASTE WATER | ANTISOIL HF SANITATION COMMUNICATION � ARGON MAINTENANCE COMMUNICATION | � AUSTIN Al BLEACH SANITATION COMMUNICATION - . BIG "D" WATER SOLUBLE WASTE WATER COMMUNICATION DEODORANT, LEMON |BUFFER SOLUTIONS: PH 1-5` 6-8 WASTE WATER COMMUNICATION � 9-1 l CHELCACLEAN ES SANITATION COMMUNICATION CHEM_CAL HYDRATED LIME WASTE WATER COMMUNICATION � � CHEMGRATE PROCESSING COMMUNICATION CITRIC ACID, ANHYDROUS QUALITY CONTROL COMMUNICATION ' ` COTTONSEED COOKING OIL PROCESSING COMMUNICATION , COAL TAR EPDXY, COMPONENTS A+B MAINTENANCE COMMUNICATION DEPEND ACTIVATOR MAINTENANCE COMMUNICATION DEPEND (R) NO-MIX ADHESIVE MAINTENANCE COMMUNICATION DINETHYLAMINE D. C. COMMUNICATION DRIERITE DESSICANT WASTE WATER COMMUNICATION ELECTROLYTE (ACID) BATTERY FLUID Q. C. (W.HOUSE) COMMUNICATION EPI-SEAL LEAK DETEX MAINTENANCE COMMUNICATION ETHYL ALCOHOL7 DENATURED Q. C. /SANIT. COMMUNICATION) PACKAGING 5WO47 PREMIUM CONTACT CLEANER MAINTENANCE COMMUN I CAT I ON FOAM X--TRA SANITATION COtIMUN I CAT I ON FUL BAC SANITATION COMMUNICATION GASKET ELIMINATOR MAINTENANCE COMMUNICATION GASOLINE, AUTOMOTIVE MAINTENANCE COMMUNICATION GLACIAL ACETIC ACID oc COMMUNICATION GLASS CLEANER (BULK ) SANITATION COMMUNICATION' GOING HOME HAND CLEANER SANITATION COMMUNICATION GREASE STRIP PACKAGING COMMUNICATION HAYSSEN LUBRI-CAN: AIR LINE MAINTENANCE COM11UNICATION LUBRICATION HE.AVY DUTY EPDXY ACTIVATOR MAINTENANCE CDMMUNICATION HEAVY DUTY EPDXY PRIMERS MAINTENANCE COMMUNICATION HEAVY DUTY EPDXY TOPCOAT MAINTENANCE COMMUNICATION HYDROGEN SULFIDE MASTER COMMUNICATION HYGARD TRANSMISSION OIL MAINTENANCE COMMUNICATION .� IMPROVED TREMSEAL GP MAINTENANCE COMMUNICATION INDUSTRIAL ENAMELS MAINTENANCE COMMUNICATION ISO-OCTANE QC COMMUNIACTION ISO-PROPANOL PACKAGING/QC COMMUNICATION JELL ADD SANITATION COMMUNICATION KLCr 5/20 (PENWALT PETROLEUM MAINTENANCE COMMUNICATION LUBRICATING OIL) ` LIQUID FRY CLEAN SANITATION COMMUNICATION , LOCQUIC PRIMER (AEROSOL) MAINTENANCE COMMUNICATION LOCOUIC PRIMER GRADE N MAINTENANCE COMMUNICATION LUBRIPLATE ACL SERIES MAINTENANCE COMMUNICATION LUBRIPLATE FGL SERIES MAINTENANCE COMMUNICATION LUBRIPLATE FMO-AW SERIES MAINTENANCE COMMUNICATION LUBRIPLATE HO SERIES MAINTENANCE COMMUNICATION LUMINATE SANITATION COMMUNICATION MARVEL MYSTERY OIL WASTE WATER COMMUNICATION MASTER GASKET PRIMER MAINTENANCE COMMUNICATION MCR-43 GLOSS EPDXY MAINTENANCE COMMUNICATION METABO FLEXIAMONT SUPER MAINTENANCE COMMUNICATION . - | '. � � METH ANOL O.C. COMMUNICATION MIXCO 0 GREASE MAINTENANCE COMMUNICATION MOBIL 1 FORMULA 5W-30 MAINTENANCE COMMUNICATION MONARCH 880! SAN I TAT I Orl COMMUNICATION MORTON DE.NDRITIC SALT PRODUCTION COMMUNICATION MOTOR OIL loWwo WASTE WATER COMMUNICATION NATURAL GAS MAINTENANCE COMMUNICATION NEV-SZ WHITE FOOD GRADE PTFE MAINTENANCE 1 COMMUNICATION NITROGEN (CRYOGENIC LIQUID) PRODUCTION, COMMUNICATION MAINT. , S/R, PACKAGING 160 THINNER (PAINT) MAINTENANCE COMMUNICATION OXYGEN MAINTENANCE COMMUNICATION OXYGEN SENSOR ASSEMBLY MAINTENANCE COMMUNICATION PAINT THINNER MAINTENANCE COMMUNICOTION PERMATEX THREAUSEALANT MAINTENANCE COMMUNICATION PHENOLPTHALEIN SOLUTION7 1X, Q. C. COMMUNICATION PLASTIC WET SURFACE ROOF CEMENT MAINTENANCE COMMUNICATION POLYAMIDE EPDXY-COMPONENT A MAINTENANCE COMMUNICATION POLYAMIDE EPDXY-COMPONENT B MAINTENANCE COMMUNICATION POLY-CARB M198 PART A EPDXY RESIN MAINTENANCE COMMUNICATION POLY-CARB Mk . 1?8 PART B, PDLYAMINE MAINTENANCE COMMUNICATION POLYAMIDE SOLUTION POTASSIUM CHROMATE Q. C. COMMUNICATION INDICATOR, 5% POTASSIUM CHLORIDE SOLTN. WASTE WATER COMMUNICATION PRIMER NO. 6 MAINTENANCE COMMUNICATION PRO-LOCK PIPE SEALANT MAINTENANCE COMMUNICATION PST (R) N TEMP ANTI-GALLING PIPE SEALANT MAINTENANCE COMMUNICATION PVC PRIMER - MAINTENANCE COMMUN I CAT I 01\1 PVC CEMENT CLEAR PIEDIUM MAINTENANCE COMMUNICATION QUICK METAL (TM) PRESS FIT REPAIR MAINTENANCE COMMUNICATION QUICK SET INDUSTRIAL ADHESIVE MAINTENANCE COMMUNICATION REMOVABLE THREADLOCKER MAINTENANCE COMMUNICATION ..SRIGID NUCLEAR THREAD CUTTING OIL MAINTENANCE COMMUNICATION RETAINING COMPOUND 609 MAINTENANCE COMMUNICATION RUBBERFLEX PATCHING CEMENT MAINTENANCE COMMUNICATION RUST-0-THANE ACTIVATOR MAINTENANCE COMMUNICATION RUST-O-THANE TOPCOATS MAINTENANCE COMMUNICATION SCOTCH-GRIP ADHESIVE MAINTENANCE COMMUNICATION 723 SPRASOLVO MAINTENANCE COMMUNICATION SILVER NITRATE SOLTN, n/l() O. C. COMMUNICATION SHAW ELECTRODE, TYPE CODE-ARC 108 MAINTENANCE COMMUNICATION MR AC-DC . SHAW ELECTRODE7 TYPE EASY-ARC 308 MAINTENANCE COMMUNICATION AC-DC SODIUM HYDROXIDE SOLTN, n/10 O. C. COMMUNICATION SODIUM THIOSULFATE Qc COMMUNICATION SOLDER SEAL LIQUID -WRENCH MAINTENANCE COMMUNICATION SPARCREME JANITORIAL COMMUNICATION SPARKLEEN WAREWASHING DETERGENT O. C. COMMUN I CAT I ON STARCH Qc COMMUNICATION STEEL MAINTENANCE COMMUNICATION STRUKTOL 2080 DEFOAMER WASTEWATER COMMUNICATION � - - .~ SUPERKABOM SANITATION COMMUNICATION SUPER LUBE AEROSOL CAN MAINTENANCE COMMUNICATION ` SWIFT SET CEMENT MIX MAINTENANCE CQMMUNI CAI-ION TAPFREE MAINTENANCE COMMUNICATION THORIATED TUNGSTEN ELECTRODE MAINTENANCE COMMUNICATION THREDKUT 9? CUTTING OIL MAINTENANCE COMMUNICATION THREE-IN-ONE HOUSEHOLD OIL MAINTENANCE COMMUNICATION ` 3M OIL SORBENT MAINTENANCE COMMUNICATION 290 ADHESIVE/SEALANT MAINTENANCE COMMUNICAT ION ULTRA BLACK (TM)RTV SILICONE MAINTENANCE COMMUNICATION � WELCO AND 15 FC (ZINC OXIDE) MAINTENANCE COMMUNICATION ^ � XYLENE MAINTENANCE = COMMUNICATION ZEP DvNA_SOL , ` MAINTENANCE COMMUNICATION � � � � ' � - � ' PAGE: 1 PAGE: 2 DATE: 04/09/92 ACCT: 119886-01 DATE: 04/09/92 ACCT: 119886-01 INDEX: 04921001220 CAT NO: A38500 PO NBR: 220846 - INDEX: 04921001220 CAT NO: A38500 PO NBR: 220846� **ACETIC ACID, GLACIAL** **ACETIC ACID, GLACIAL** FIRE AND EXPLOSION HAZARD: **ACETIC ACID, GLACIAL** MODERATE FIRE HAZARD WHEN EXPOSED TO HEAT OR FLAME. MATERIAL SAFETY DATA SHEET VAPOR-AIR MIXTURES ARE EXPLOSIVE ABOVE FLASH POINT. ------------------------------- _ VAPORS ARE HEAVIER THAN AIR AND MAY TRAVEL A CONSIDERABLE DISTANCE TO ASOURCE FISHER SCIENTIFIC EMERGENCY NUMBER: (201) 796-7100 OF IGNITION AND FLASH BACK. CHEMICAL DIVISION CHEMTREC ASSISTANCE: (800) 424-9300 1 REAGENT LANE FLASH.POINT: 103 F (39 C) (CC) UPPER EXPLOSIVE LIMIT: 16.0% @ 92 C FAIR.LAWN NJ 07410 (201) 796-7100 - LOWER EXPLOSIVE LIMIT: 4.0% @ 59 C AUTOIGNITION TEMP. : 867 F (464 C) THIS INFORMATION IS BELIEVED TO BE ACCURATE AND REPRESENTS THE BEST FLAMMABILITY CLASS(OSHA): II INFORMATION CURRENTLY AVAILABLE TO US. HOWEVER, WE MAKE NO WARRANTY OF MERCHANTABILITY OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, WITH RESPECT TO FIREFIGHTING MEDIA: SUCH INFORMATION, AND WE ASSUME NO LIABILITY RESULTING FROM ITS.,USE. USERS DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY OR REGULAR FOAM SHOULD MAKE THEIR OWN INVESTIGATIONS TO DETERMINE THE SUITABILITY OF THE (1990 EMERGENCY RESPONSE GUIDEBOOK, DOT. P 5800.5). INFORMATION FOR THEIR PARTICULAR PURPOSES. FOR LARGER FIRES, USE WATER SPRAY, FOG OR REGULAR FOAM ------------------------------------------------------------------------------ (1990 EMERGENCY RESPONSE GUIDEBOOK, DOT P 5800.5). SUBSTANCE IDENTIFICATION ALCOHOL FOAM CAS-NUMBER 64-19-7 (NFPA 325M, FIRE•HAZARD PROPERTIES OF FLAMMABLE LIQUIDS, GASES, AND VOLATILE SUBSTANCE: **ACETIC ACID, GLACIAL** SOLIDS, 1991). TRADE NAMES/SYNONYMS: FIREFIGHTING: ACETIC ACID; GLACIAL ACETIC ACID; ETHANOIC ACID; VINEGAR ACID; ETHYLIC`ACID; MOVE CONTAINER FROM FIRE AREA IF YOU CAN DO IT WITHOUT RISK. DO NOT GET WATER PYROLIGNEUS ACID; METHANECARBOXYLIC ACID; ACETIC ACID, HPLC GRADE; INSIDE CONTAINER. APPLY COOLING WATER TO SIDES OF CONTAINERS THAT ARE EXPOSED STCC 4931303; UN 2789; TO FLAMES UNTIL WELL AFTER FIRE IS OUT. STAY AWAY FROM ENDS OF TANKS. WITHDRAW A37; A38; A38C; A38P; A38SI; A38S; A507; A465; A35; A38FP; BP1185; C2H402; IMMEDIATELY IN CASE OF RISING SOUND FROM VENTING SAFETY DEVICE OR ANY ACCO0120 _ DISCOLORATION OF TANK DUE TO FIRE. ISOLATE FOR 1/2 MILE IN ALL DIRECTIONS IF TANK, RAIL CAR OR TANK TRUCK IS INVOLVED IN FIRE (1990 EMERGENCY RESPONSE CHEMICAL FAMILY: GUIDEBOOK, DOT P 5800.5, GUIDE PAGE 29). CARBOXYLIC ACID, ALIPHATIC USE FLOODING AMOUNTS OF WATER AS A FOG; SOLID STREAMS MAY BE INEFFECTIVE. MOLECULAR FORMULA: C-H3-C-02-H COOL CONTAINERS WITH FLOODING AMOUNTS OF WATER FROM AS FAR A DISTANCE AS POSSIBLE. USE WATER SPRAY TO ABSORB CORROSIVE VAPORS. AVOID BREATHING MOLECULAR WEIGHT: 60.05 CORROSIVE VAPORS; KEEP UPWIND. CERCLA RATINGS (SCALE 0-3): HEALTH=2 FIRE--2 REACTIVITY=O PERSISTENCE=O FIRE.FIGHTING PHASES: USE WATER SPRAY, DRY CHEMICAL, ALCOHOL FOAM, OR CARBON NFPA•RATINGS (SCALE 0-4): HEALTH=2 FIRE=2 REACTIVITY=O DIOXIDE. USE WATER TO KEEP FIRE-EXPOSED CONTAINERS COOL. IF A LEAK OR SPILL ------------------------------------------------------------------------------ HAS NOT IGNITED, USE WATER SPRAY TO DISPERSE THE VAPORS AND TO PROTECT THE MEN COMPONENTS AND CONTAMINANTS ATTEMPTING TO STOP A LEAK. WATER SPRAY MAY BE USED TO FLUSH SPILLS AWAY FROM EXPOSURES AND TO DILUTE SPILLS TO NONFLAMMABLE MIXTURES (NFPA 49„HAZARDOUS COMPONENT: ACETIC ACID PERCENT: 80.0-100.0 CHEMICALS DATA, 1975). CAS# 64-19-7 ------------------------------------------------------------------------------ COMPONENT: WATER PERCENT: 0-20.0 TRANSPORTATION DATA OTHER CONTAMINANTS: NONE DEPARTMENT OF TRANSPORTATION HAZARD CLASSIFICATION 49 CFR 172.101: EXPOSURE LIMITS: CORROSIVE MATERIAL ACETIC ACID, GLACIAL: DEPARTMENT OF TRANSPORTATION LABELING REQUIREMENTS 49 CFR 172.101 AND 10 PPM (25 MG/M3) OSHA TWA SUBPART E: 10 PPM (25 MG/M3) ACGIH TWA; 15 PPM (37 MG/M3) ACGIH STEL CORROSIVE 10 PPM (25 MG/M3) NIOSH RECOMMENDED TWA; 15 PPM (37 MG/M3) NIOSH STEL 10 PPM (25 MG/M3) DFG MAK TWA; DEPARTMENT OF TRANSPORTATION PACKAGING REQUIREMENTS: 49 CFR 173.245 20 PPM (50 MO/M3) DFG MAK 5 MINUTE PEAK, MOMENTARY. VALUE, 8 TIMES/SHIFT EXCEPTIONS: 49 CFR 173.244 MEASUREMENT METHOD: CHARCOAL TUBE; FORMIC ACID; GAS CHROMATOGRAPHY WITH FINAL RULE ON HAZARDOUS MATERIALS REGULATIONS (HMR, 49 CFR PARTS 171-180), FLAME IONIZATION DETECTION; (NIOSH VOL. III # 1603). DOCKET NUMBERS HM-181, HM-181A, HM-181B, HM-181C, HM-181D AND HM-204. EFFECTIVE DATE OCTOBER 1, 1991. HOWEVER, COMPLIANCE WITH THE REGULATIONS IS 5000 POUNDS CERCLA SECTION 103 REPORTABLE QUANTITY AUTHORIZED ON AND AFTER JANUARY 1, 1991. (55.FR 52402," 12/21/90) ------------------------- ------------------------------------------- EXCEPT FOR EXPLOSIVES, INHALATION HAZARDS, AND INFECTIOUS SUBSTANCES, THE PHYSICAL DATA EFFECTIVE DATE FOR HAZARD COMMUNICATION REQUIREMENTS IS EXTENDED TO DESCRIPTION: CLEAR, COLORLESS LIQUID WITH A STRONG, PUNGENT, CHARACTERISTIC OCTOBER 1, 1993. (56 FR 47158, 10/18/91) U.S. DEPARTMENT OF TRANSPORTATION SHIPPING NAME-ID NUMBER, 49 CFR,172.101: ODOR OF VINEGAR AND WHEN WELL DILUTED WITH WATER, AN ACID TASTE. ACETIC ACID, GLACIAL-UN 2789 , BOILING POINT: 244 F 1118 C) MELTING POINT: 62 F (17 C) U.S. DEPARTMENT OF TRANSPORTATION HAZARD CLASS OR DIVISION, 49 CFR 172.101.. SPECIFIC GRAVITY: 1.0492 VAPOR PRESSURE: 11.8 MMHG @ 20 C 8 - CORROSIVE MATERIAL EVAPORATION RATE: (BUTYL ACETATE=1) 0.97 PH: 2.4 (1.0 M SOL.) U.S. DEPARTMENT OF TRANSPORTATION PACKING GROUP, 49 CFR 172.101: PG II SOLUBILITY IN WATER: VERY SOLUBLE ODOR THRESHOLD: 1.0 PPM U.S. DEPARTMENT OF TRANSPORTATION LABELING REQUIREMENTS, 49 CFR 172.101 VAPOR DENSITY: 2.07 AND SUBPART E: SOLVENT SOLUBILITY: SOLUBLE IN ETHANOL, GLYCEROL, ETHER, ACETONE, BENZENE, CORROSIVE CARBON TETRACHLORIDE; INSOLUBLE IN CARBON DISULFIDE, CHLOROFORM, DIMETHYL U.S. DEPARTMENT OF TRANSPORTATION PACKAGING AUTHORIZATIONS: SULFOXIDE EXCEPTIONS: 49 CFR 173.154 NON-BULK PACKAGING: 49 CFR 173.202 VISCOSITY: 1.22 CPS @ 20 C BULK PACKAGING: 49 CFR 173.242 ------------------------------------------------------------------------------- U.S. DEPARTMENT OF TRANSPORTATION QUANTITY LIMITATIONS 49 CFR 172.101: FIRE AND EXPLOSION DATA PASSENGER AIRCRAFT OR RAILCAR: 1 L • DATE: 04/09/92 ACCT: 119886-01 PAGE: 3 DATE: 04/09/92 ACCT: 119886-01 PAGE: 4 INDEX: 04921001220 CAT NO: A38500 PO NBR: 220846 INDEX: 04921001220 CAT NO: A38500 PO NBR: 220846 CARGO AIRCRAFT ONLY: 30 L CORROSIVE. , --------------------- ACUTE EXPOSURE- IN CASES OF ACCIDENTAL INGESTION, SEVERE ULCERONECROTIC r - ------------------------------------- ------------------- LESIONS OF THE UPPER DIGESTIVE TRACT, STRICTURE OF THE ESOPHAGUS, AND TOXICITY PERFORATION OF THE ESOPHAGUS AND PYLORUS HAVE BEEN OBSERVED WITH HEMATEM_ESIS, DIARRHEA, SHOCK, HEMOGLOBINURIA FOLLOWED BY ANURIA AND ACETIC ACID, GLACIAL: UREMIA': OTHER SYMPTOMS MAY INCLUDE VOMITING, ABDOMINAL SPASMS, THIRST, IRRITATION DATA: 50 MG/24 HOURS SKIN-HUMAN MILD: 525 MG OPEN SKIN-RABBIT DIFFICULTY IN SWALLOWING, HYPOTHERMIA, RAPID AND WEAK PULSE, SLOW AND SEVERE; 50 MG/24 HOURS SKIN-RABBIT MILD; 20 MG/24 HOURS SKIN-RABBIT SHALLOW BREATHING, LARYNGITIS, BRONCHITIS, PULMONARY EDEMA, PNEUMONIA, MODERATE; 50 UG OPEN EYE-RABBIT SEVERE; 5 MG/30 SECONDS RINSED EYE-RABBIT HEMOLYSIS, ALBUMINURIA, HEMATURIA, TWITCHING, CONVULSIONS, CARDIOVASCULAR MILD. COLLAPSE, SHOCK AND DEATH. REPRODUCTIVE EFFECTS HAVE BEEN REPORTED IN TOXICITY DATA: 816 PPM/3 MINUTES INHALATION-HUMAN TCLO; 16,000 PPM/4 HOURS ANIMALS. INHALATION-RAT LCLO; 5620 PPM/1 HOUR INHALATION-MOUSE LC50; 1060 MG/KG CHRONIC EXPOSURE- NO DATA AVAILABLE. SKIN-RABBIT LD50; 1470 UG/KG ORAL-HUMAN TDLO; 3310 MG/KG ORAL-RAT LDSO; 1200 MG/KG ORAL-RABBIT LDLO; 1200 MG/KG SUBCUTANEOUS-RABBIT LDLO; 525 MG/KG FIRST AID- DO NOT USE GASTRIC LAVAGE OR EMESIS. DILUTE THE ACID IMMEDIATELY INTRAVENOUS-MOUSE LD50; 1200 MG/KG RECTAL-RABBIT LDLO; 308 MG/KG BY DRINKING LARGE QUANTITIES OF WATER OR MILK. IF VOMITING PERSISTS, UNREPORTED-MAN LDLO; MUTAGENIC DATA (RTECS); REPRODUCTIVE EFFECTS DATA ADMINISTER FLUIDS REPEATEDLY. INGESTED ACID MUST BE DILUTED APPROXIMATELY (RTECS). 100 FOLD TO RENDER IT HARMLESS TO TISSUES. MAINTAIN AIRWAY AND TREAT SHOCK CARCINOGEN STATUS: NONE. (DREISBACH, HANDBOOK OF POISONING, 12TH ED.). GET MEDICAL ATTENTION LOCAL EFFECTS: CORROSIVE- INHALATION, SKIN, EYE, INGESTION. IMMEDIATELY. IF VOMITING OCCURS, KEEP HEAD BELOW HIPS TO HELP PREVENT ACUTE TOXICITY LEVEL: MODERATELY TOXIC BY INHALATION, DERMAL ABSORPTION, ASPIRATION. INGESTION. TARGET EFFECTS: POISONING MAY AFFECT THE LIVER, KIDNEYS, AND CARDIOVASCULAR ANTIDOTE: SYSTEM. NO SPECIFIC ANTIDOTE. TREAT SYMPTOMATICALLY AND SUPPORTIVELY. AT INCREASED RISK FROM EXPOSURE: PERSONS WITH A HISTORY OF RESPIRATORY, SKIN , OR EYE DISEASE. REACTIVITY HEALTH EFFECTS AND FIRST AID REACTIVITY: INHALATION: STABLE UNDER NORMAL TEMPERATURES AND PRESSURES. ACETIC ACID, GLACIAL: INCOMPATIBILITIES: 1000 PPM IMMEDIATELY DANGEROUS TO LIFE-OR HEALTH. ACETIC ACID, GLACIAL: CORROSIVE. - ACETALDEHYDE: VIOLENT, EXOTHERMIC POLYMERIZATION REACTION. ACUTE EXPOSURE- MAY CAUSE SEVERE IRRITATION OF THE RESPIRATORY TRACT. 50 PPM ACETIC ANHYDRIDE + WATER: VIOLENT, EXOTHERMIC REACTION. OR MORE IS INTOLERABLE TO MOST PERSONS AND RESULTS IN PHARYNGEAL EDEMA 2-AMINOETHANOL: TEMPERATURE AND PRESSURE INCREASE IN CLOSED CONTAINER. AND CHRONIC BRONCHITIS. OTHER SYMPTOMS MAY INCLUDE COUGHING, DYSPNEA, AMMONIUM NITRATE: IGNITES ON WARMING, ESPECIALLY IF CONCENTRATED. SHORTNESS OF BREATH, LARYNGITIS, PULMONARY EDEMA, BRONCHOPNEUMONIA AND - 5-AZIDOTETRAZOLE: POSSIBLE EXPLOSIVE REACTION. HYPOTENSION. BASES: EXOTHERMIC REACTION. CHRONIC EXPOSURE- WORKERS REPEATEDLY EXPOSED TO CONCENTRATIONS UP TO 200 BROMINE PENTAFLUORIDE: FIRE AND EXPLOSION HAZARD. PPM HAVE BEEN FOUND TO SUFFER FROM PALPEBRAL EDEMA WITH HYPERTROPHY OF CARBONATES: INCOMPATIBLE. THE LYMPH NODES, CHRONIC PHARYNGITIS, CHRONIC BRONCHITIS AND IN SOME CHLORINE TRIFLUORIDE: VIOLENT, POSSIBLY EXPLOSIVE REACTION. CASES, ASTHMATIC BRONCHITIS AND TRACES OF EROSION OF THE TEETH. COMPLAINTS CHLOROSULFONIC ACID: TEMPERATURE AND PRESSURE INCREASE IN CLOSED CONTAINER. OF DIGESTIVE DISORDERS WITH PYROSIS AND CONSTIPATION HAVE ALSO BEEN CHROMIC ACID: EXPLOSIVE REACTION IF NOT KEPT COLD. REPORTED. CHROMIUM TRIOXIDE: POSSIBLE FIRE AND EXPLOSION HAZARD. DIALLYL METHYL CARBINOL AND OZONE: EXPLOSIVE REACTION. FIRST AID- REMOVE FROM EXPOSURE AREA TO FRESH AIR IMMEDIATELY. IF BREATHING ETHYLENE DIAMINE: TEMPERATURE AND PRESSURE INCREASE IN CLOSED CONTAINER. HAS STOPPED, GIVE ARTIFICIAL RESPIRATION. MAINTAIN AIRWAY AND BLOOD ETHYLENEIMINE: TEMPERATURE AND PRESSURE INCREASE IN CLOSED CONTAINER. PRESSURE AND ADMINISTER OXYGEN IF AVAILABLE. KEEP AFFECTED PERSON WARM AND HYDROGEN PEROXIDE: EXOTHERMIC REACTION ON HEATING WITH THE PRODUCTION OF AT REST. TREAT SYMPTOMATICALLY AND SUPPORTIVELY. ADMINISTRATION OF OXYGEN PERACETIC ACID WHICH WILL EXPLODE AT 110 C. SHOULD BE PERFORMED BY QUALIFIED PERSONNEL. GET MEDICAL ATTENTION HYDROXIDES: INCOMPATIBLE. IMMEDIATELY. LEAD: CORRODES. METALS: ATTACKS MOST METALS, INCLUDING ZINC. NITRIC ACID: EXPLOSIVE REACTION IF NOT KEPT COLD. SKIN CONTACT: NITRIC ACID AND ACETONE: EXPLOSIVE REACTION (DELAYED) IN CLOSED CONTAINER. ACETIC ACID, GLACIAL: OLEUM: TEMPERATURE AND PRESSURE INCREASE IN CLOSED CONTAINER. CORROSIVE. OXIDIZERS: FIRE AND EXPLOSION HAZARD. ACUTE EXPOSURE- DIRECT CONTACT MAY CAUSE SEVERE IRRITATION WITH PAIN, PERCHLORIC ACID: EXPLOSIVE REACTION. ERYTHEMA, BLISTERS, BURNS AND SUPERFICIAL DESTRUCTION OF THE SKIN WITH PERMANGANATES: EXPLOSIVE REACTION IF NOT KEPT COLD. SLOW HEALING. THE SKIN MAY BECOME BLACKENED, HYPERKERATOTIC AND FISSURED. PHOSPHATES: INCOMPATIBLE. READILY ABSORBED THROUGH THE SKIN. PHOSPHORUS ISOCYANATE: VIOLENT REACTION. CHRONIC EXPOSURE- REPEATED AND PROLONGED CONTACT MAY CAUSE DARKENING OF THE PHOSPHORUS TRICHLORIDE: EXPLOSIVE REACTION. SKIN, IRRITATION AND DERMATITIS. POTASSIUM HYDROXIDE: VIOLENT REACTION. POTASSIUM PERMANGANATE: POSSIBLE EXPLOSION IF INADEQUATELY COOLED. FIRST AID- REMOVE CONTAMINATED CLOTHING AND SHOES IMMEDIATELY. WASH AFFECTED POTASSIUM TERT-BUT OXIDE: IGNITION REACTION. AREA WITH SOAP OR MILD DETERGENT AND LARGE AMOUNTS OF WATER UNTIL NO SODIUM HYDROXIDE: TEMPERATURE AND PRESSURE INCREASE IN CLOSED CONTAINER. EVIDENCE OF CHEMICAL REMAINS (AT LEAST 15-20 MINUTES). IN CASE OF CHEMICAL SODIUM PEROXIDE: EXPLOSIVE REACTION IF NOT KEPT COLD. BURNS, COVER AREA WITH STERILE, DRY DRESSING. BANDAGE SECURELY, BUT NOT XYLENE: MAY FORM DETONABLE MIXTURES DURING TERPHTHALIC ACID PRODUCTION, THE TOO TIGHTLY. GET MEDICAL ATTENTION IMMEDIATELY. PRESENCE OF WATER MAY DECREASE THE HAZARD. EYE CONTACT: DECOMPOSITION: ACETIC ACID, GLACIAL: THERMAL DECOMPOSITION PRODUCTS MAY INCLUDE TOXIC OXIDES OF CARBON. CORROSIVE. -- ACUTE EXPOSURE- DIRECT CONTACT CAUSES SEVERE IRRITATION, LACRIMATION, POLYMERIZATION CORNEAL EROSION, OPACIFICATION, IRITIS AND POSSIBLY LOSS OF SIGHT IN HAZARDOUS POLYMERIZATION HAS NOT BEEN REPORTED TO OCCUR UNDER NORMAL HUMANS. REGENERATION OF THE EPITHELIUM MAY TAKE MANY MONTHS, BUT CORNEAL TEMPERATURES AND PRESSURES. ANESTHESIA AND OPACITY WILL USUALLY BE PERMANENT. IN LESS SEVERE CASES, CONJUNCTIVITIS, PHOTOPHOBIA AND HYPEREMIA OF THE CONJUNCTIVA OCCURRED. THE ------------------------------------------------------------------------------ VAPOR AND DILUTE SOLUTIONS MAY CAUSE CONJUNCTIVAL HYPEREMIA AND SOMETIMES STORAGE AND DISPOSAL INJURY TO THE CORNEAL EPITHELIUM. CHRONIC EXPOSURE- DEPENDING ON THE CONCENTRATION AND DURATION OF EXPOSURE, OBSERVE ALL FEDERAL, STATE AND LOCAL REGULATIONS WHEN STORING OR DISPOSING EFFECTS SIMILAR TO ACUTE EXPOSURE MAY OCCUR. OF THIS SUBSTANCE. FOR ASSISTANCE, CONTACT THE DISTRICT DIRECTOR OF THE FIRST AID- WASH EYES IMMEDIATELY WITH LARGE AMOUNTS OF WATER, OCCASIONALLY ENVIRONMENTAL PROTECTION AGENCY. LIFTING UPPER AND LOWER LIDS, UNTIL NO EVIDENCE OF CHEMICAL REMAINS (AT LEAST 15-20 MINUTES). CONTINUE IRRIGATING WITH NORMAL SALINE UNTIL THE PH **STORAGE** HAS RETURNED TO NORMAL (30-60 MINUTES). COVER WITH STERILE BANDAGES. GET MEDICAL ATTENTION IMMEDIATELY. PROTECT AGAINST PHYSICAL DAMAGE. DETACHED STORAGE IS PREFERRED. SEPARATE FROM OXIDIZING MATERIALS AND AVOID STORAGE NEAR COMBUSTIBLE MATERIALS, KEEP ABOVE INGESTION: ITS FREEZING POINT (62 F) TO AVOID RUPTURE OF CARBOYS AND GLASS CONTAINERS ACETIC ACID, GLACIAL: (NFPA 49, HAZARDOUS CHEMICALS DATA, 1975). � DATE: 04/09/92 ACCT: 119886-01 PAGE: 5 DATE: 04/09/92 ACCT: 119886-01 PAGE: 6 INDEX: 04921001220 CAT NO: A38500 PO NBR: 220846 INDEX: 04921001220 CAT NO: A38500 PO NBR: 220846 500 PPM- ANY CHEMICAL CARTRIDGE RESPIRATOR WITH FULL FACEPIECE AND ORGANIC BONDING AND GROUNDING: SUBSTANCES WITH LOW ELECTROCONDUCTIVITY, WHICH VAPOR CARTRIDGE(S). MAY BE IGNITED BY ELECTROSTATIC SPARKS, SHOULD BE STORED IN CONTAINERS ANY SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE. WHICH MEET THE BONDING AND GROUNDING GUIDELINES SPECIFIED IN NFPA 77-1983, ANY SUPPLIED-AIR RESPIRATOR WITH FULL FACEPIECE. RECOMMENDED PRACTICE ON STATIC ELECTRICITY. ANY AIR-PURIFYING FULL FACEPIECE RESPIRATOR (GAS MASK) WITH CHIN-STYLE, FRONT- OR BACK-MOUNTED ORGANIC VAPOR CANISTER. STORE AWAY FROM INCOMPATIBLE SUBSTANCES. ANY POWERED AIR-PURIFYING RESPIRATOR WITH A TIGHT-FITTING FACEPIECE' AND ORGANIC VAPOR CARTRIDGE(S). STORE IN ACCORDANCE WITH 29 CFR 1910.106. 1000 PPM- ANY SUPPLIED-AIR RESPIRATOR WITH FULL FACEPIECE AND IS OPERATED IN A PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE MODE. , **DISPOSAL** ESCAPE- ANY AIR-PURIFYING FULL FACEPIECE RESPIRATOR (GAS MASK) WITH DISPOSAL MUST BE IN ACCORDANCE WITH STANDARDS APPLICABLE TO GENERATORS OF CHIN-STYLE, FRONT- OR BACK-MOUNTED ORGANIC CANISTER. HAZARDOUS WASTE, 40 CFR 262. EPA HAZARDOUS WASTE NUMBER D002. ANY APPROPRIATE, ESCAPE-TYPE SELF-CONTAINED BREATHING APPARATUS. 100 POUND CERCLA SECTION 103 REPORTABLE QUANTITY. FOR FIREFIGHTING AND OTHER IMMEDIATELY DANGEROUS TO LIFE OR HEALTH CONDITIONS: DISPOSAL MUST BE IN ACCORDANCE WITH STANDARDS APPLICABLE TO GENERATORS OF HAZARDOUS WASTE, 40 CFR 262. EPA HAZARDOUS WASTE NUMBER DOO1. ANY SELF-CONTAINED BREATHING APPARATUS THAT HAS A FULL FACEPIECE AND IS 100 POUND CERCLA SECTION 103 REPORTABLE QUANTITY. OPERATED IN A PRESSURE-DEMAND OR OTHER POSITIVE-PRESSURE MODE. xxkxxx#####**xkxx#*xxsx*sxxs*s**s**s*x*****s*****#*###k#kx*x##xxkx#xxsxxxxxk#x ANY SUPPLIED-AIR RESPIRATOR THAT HAS A FULL FACEPIECE AND IS OPERATED IN A CONDITIONS TO AVOID PRESSURE-DEMAND OR OTHER POSITIVE-PRESSURE MODE IN COMBINATION WITH AN AUXILIARY SELF-CONTAINED BREATHING APPARATUS OPERATED IN PRESSURE-DEMAND AVOID CONTACT WITH HEAT, SPARKS, FLAMES OR OTHER IGNITION SOURCES. VAPORS MAY OR OTHER POSITIVE-PRESSURE MODE. BE EXPLOSIVE. MATERIAL IS CORROSIVE; AVOID CONTACT WITH SKIN OR EYES. DO NOT ALLOW CONTAMINATION OF WATER SOURCES. CLOTHING: EMPLOYEE MUST WEAR APPROPRIATE PROTECTIVE (IMPERVIOUS) CLOTHING AND EQUIPMENT USUAL SHIPPING CONTAINERS: TO PREVENT ANY POSSIBILITY OF SKIN CONTACT WITH THIS SUBSTANCE. GLASS AND POLYETHYLENE CARBOYS AND POLYETHYLENE-LINED DRUMS, TANK BARGES (NFPA 49, HAZARDOUS CHEMICALS DATA, 1975). - GLOVES: EMPLOYEE MUST WEAR APPROPRIATE PROTECTIVE GLOVES TO PREVENT CONTACT WITH THIS SUBSTANCE. SPILL AND LEAK PROCEDURES SOIL SPILL: EYE PROTECTION: DIG A HOLDING AREA SUCH AS A PIT, POND OR LAGOON TO CONTAIN SPILL AND DIKE EMPLOYEE MUST WEAR SPLASH-PROOF OR DUST-RESISTANT SAFETY GOGGLES AND A SURFACE FLOW USING BARRIER OF SOIL, SANDBAGS, FOAMED POLYURETHANE OR FOAMED FACESHIELD TO PREVENT CONTACT WITH THIS SUBSTANCE. CONCRETE. ABSORB LIQUID MASS WITH FLY ASH OR CEMENT POWDER. EMERGENCY WASH FACILITIES: NEUTRALIZE WITH CAUSTIC SODA (NAOH) OR SODA ASH (NA2CO3) "WHERE THERE IS ANY POSSIBILITY THAT AN EMPLOYEE'S EYES AND/OR SKIN MAY BE EXPOSED TO THIS SUBSTANCE, THE EMPLOYER SHOULD PROVIDE AN EYE WASH FOUNTAIN AIR SPILL: AND QUICK DRENCH SHOWER WITHIN THE IMMEDIATE WORK AREA FOR EMERGENCY USE. KNOCK DOWN VAPORS WITH WATER SPRAY. KEEP UPWIND. WATER USED TO KNOCK DOWN VAPORS MAY BECOME CORROSIVE OR TOXIC AND SHOULD BE AUTHORIZED - FISHER SCIENTIFIC, INC. CONTAINED PROPERLY FOR LATER DISPOSAL. CREATION DATE: 09/06/84 REVISION DATE: 02/25/92 WATER SPILL: -ADDITIONAL INFORMATION- NEUTRALIZE WITH CAUSTIC SODA. THIS INFORMATION IS BELIEVED TO BE ACCURATE AND REPRESENTS THE BEST INFORMATION CURRENTLY AVAILABLE TO US. HOWEVER, WE MAKE NO WARRANTY OF OCCUPATIONAL SPILL: MERCHANTABILITY OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, WITH RESPECT TO SHUT OFF IGNITION SOURCES. DO NOT TOUCH SPILLED MATERIAL. STOP LEAK IF YOU SUCH INFORMATION, AND WE ASSUME NO LIABILITY RESULTING FROM ITS USE. USERS CAN DO IT WITHOUT RISK. USE WATER SPRAY TO REDUCE VAPORS. DO NOT GET WATER SHOULD MAKE THEIR OWN INVESTIGATIONS TO DETERMINE THE SUITABILITY OF THE INSIDE CONTAINER. FOR SMALL SPILLS, TAKE UP WITH SAND OR OTHER ABSORBENT INFORMATION FOR THEIR PARTICULAR PURPOSES. MATERIAL AND PLACE INTO CONTAINERS FOR LATER DISPOSAL. FOR LARGER SPILLS, DIKE FAR AHEAD OF SPILL FOR LATER DISPOSAL. NO SMOKING, FLAMES OR FLARES IN HAZARD AREA. KEEP UNNECESSARY PEOPLE AWAY; ISOLATE HAZARD AREA AND DENY ENTRY. REPORTABLE QUANTITY (R0): 5000 POUNDS THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA) SECTION 304 REQUIRES THAT A RELEASE EQUAL TO OR GREATER THAN THE REPORTABLE QUANTITY FOR THIS SUBSTANCE BE IMMEDIATELY REPORTED TO THE LOCAL EMERGENCY PLANNING COMMITTEE AND THE STATE EMERGENCY, RESPONSE COMMISSION (40 CFR 355.40). IF THE RELEASE OF THIS SUBSTANCE IS REPORTABLE UNDER CERCLA SECTION 103, THE NATIONAL RESPONSE CENTER MUST BE NOTIFIED IMMEDIATELY AT (800) 424-8802 OR (202) 426-267.5 IN THE ' METROPOLITAN WASHINGTON, D.C. AREA (40 CFR 302.6). ----------------------------------------------- PROTECTIVE EQUIPMENT VENTILATION: PROVIDE LOCAL EXHAUST'VENTILATION TO MEET PUBLISHED EXPOSURE LIMITS. VENTILATION EQUIPMENT MUST BE EXPLOSION-PROOF. RESPIRATOR: THE FOLLOWING RESPIRATORS AND MAXIMUM USE CONCENTRATIONS ARE RECOMMENDATIONS BY THE U.S. DEPARTMENT OF HEALTH AND HUMAN SERVICES, NIOSH POCKET GUIDE TO CHEMICAL HAZARDS; NIOSH CRITERIA DOCUMENTS OR BY THE U.S. DEPARTMENT OF LABOR, 29 CFR 1910 SUBPART Z. THE SPECIFIC RESPIRATOR SELECTED MUST BE BASED ON CONTAMINATION LEVELS FOUND IN THE WORK PLACE, MUST NOT EXCEED THE WORKING LIMITS OF THE RESPIRATOR AND BE JOINTLY APPROVED BY THE NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY AND HEALTH AND THE MINE SAFETY AND HEALTH ADMINISTRATION (NIOSH-MSHA). ACETIC ACID, GLACIAL: 250 PPM- ANY SUPPLIED-AIR RESPIRATOR OPERATED IN CONTINUOUS FLOW MODE. ANY POWERED AIR-PURIFYING RESPIRATOR WITH ORGANIC VAPOR CARTRIDGE(S). MATERIAL SAFETY DATA SHEET aonrr ,, OOOOOOOOMOOM ❑❑o0an❑0=0000000 M0 rnnaDOOaoa SECTION I PRODUCT IDENTIFICATION DD Trade Name: - Product: BLEACH Variation: 5.25R Regular Chemical Name & Synonyms: Sodium Hypochlorite Solution/ Bleach Chemical Family: Hypochlorous Acid.Sodium Salt Formula : NaOCI 5.25R in water DOT Proper Shipping Name: - Hypochlorite Solution containing not more than 7R available chlorine DOT Hazard Class: ORM-B NA 1791 CAS NO- 7681-52-9 Transportation Label/Placard required: None Reportable Ouantity 100 Pounds of Active Ingredients Manufacturer's-Name: James Austin Company Emergency Phone: 412-625-1535 Address: P.O.Box 827 Telephone For Information: 412-625-1535 Downieville Road Date Prepared: July 10. 1990 Mars, PA DDOD0000oo000000000oo00000000D000D=000D000a0D000000aoo=000❑0000000 ' ' 00 SECTION II INGREDIENTS Mo0000000DOD00D0000000o000OOOMD000DOOOOOOODDo000D00D00D Percent ACGIH TLV OSHA PEL CAS NO Water H2O 94.539. None None 7732-18-5 Sodium Hypochlorite NaOCI 5.25R None None 7681-52-9 Sodium Hydroxide (caustic soda) NaOH 0.22R 2 mg/m3 2 mg/m3 1310-73-2 ❑OOOoOOOOOOOa0000O000000000moo0oo0oo0000o000000OOOOOO❑OOOE)MOMMOOOO000000o0D000 SECTION III PHYSICAL/CHEMICAL DATA-- oo000000000000omo00oo000o0000o00oo00oo000o00o0000000000000000000000000o0000000000 Boiling Point: 212'F Specific Gravity (Water - 1): 1.080 Freeze Point: 32'F pH of Product: 12.5 Vapor Pressure(mm Hg): VP of water Evaporation Rate (Butyl Acetate - 1): WA Vapor Density (Air ■ 0: N/A Percent Volatile By Volume R None Solubility In Water: 100R Appearance: Clear yellow liquid Odor: Typical chlorine aroma Product Formulated Based On: Federal Specification 0-S-602E Commercial Item Descript A-A-1427A EPA EST: 1672-PA-1 EPA REG: 1672-20004 o000000000000o0o0000000oo000000000❑❑0o❑oo000om00000000m000000000000o000oo0000000 SECTION IV FIRE AND EXPLOSION DATA oo❑ooaomomomoo0000000aooa❑000000000000000000aa0000❑oo0oo0ao000000000aa00o OOM Flash Point (Method Used): Over 200'F Closed Cup Auto Ignition Temp : Not Known _ Flammable Limits: LEL : Not known UEL : Not known. Extinguishing Media: Water J Foam CO2 J Dry Chemical ./ Alcohol Foam Other Fire Fighting Procedures: Avoid fumes from spilled or exposed liquid. Be prepared to use MSHA/NIOSH self-contained breathing apparatus and protective clothing. Acid contamination will produce very irritating fumes similar to chlorine-gas. Unusual Fire And Explosion Hazards: Bleach decomposes when heated,decomposition products may cause containers to explode. A vigorous reaction is possible with organic materials or oxidizing agents and may result in fire. 00000000DD00000=LLU000 0000000000000000000000000000a000D000000 SECTION V • HEALTH HAZARD DATA D0000[IDODDOODODDo❑DCIMo000rin00MMOODO OO Entry Routes:Inhalation? No Skin? Yes Ingestion? Yes Eyes? Yes Irritant Irritant OSHA Permissible Exposure Limit None ACGIH Threshold Limit Value None Carcinogen-NTP Program None Carcinogen-IARC Program None Signs And Symptoms-Of Exposure: Raspy continuous coughing. runny nose, eye,skin and/or throat irritations. Medical Conditions Generally Aggravated By Exposure: Skin cuts, burns or abrasions. Irritated eyes.Respiratory ailments. Emergency First Aid: Eyes: Flush with large quantities of water.Call physician. Skin: Remove clothing/ wash area with water. Ingestion: Do not give liquid if victim is unconscious or drowsy. Otherwise, 'ilrink promptly large quantity of milk or water. Avoid alcohol. Call physician immediately. Do not use baking soda or acidic antidotes. Call Poison Control Center for information if doctor unavailable. BLEACH 5.259 Regul-ir James Austin Company July 10. 1990 000000❑000000000000000000000000000000000000000000❑❑❑❑❑❑o0❑Oo❑0❑❑ SECTION VI REACTIVITY DATA 00000000000000000000000000000000000000000000000000000000000000000000 Stability Stable: 'Yes Conditions To Avoid: Heat or direct sunlight. Incompatibility (Materials To A--eid): Acids, ammonias, oils, greases. soaps, heavy metals, and ether. Hazardous Polymerization May Occur: NO Conditions To Avoid: N/A Hazardous Decomposition Or Byproducts: Chlorine gas or chloramines 0000000000000000000000000000000000000000000000000000000000000000 SECTION VII ENVIRONMENTAL PROTECTION PROCEDURES 00000000❑0000000000000000000000000000000000000000000000000000000000000000000000000 Spill Precautions : If possible neutralize with sodium sulfite or ferrous salt.Contain run-off with absorbent materials such as sand or clay and diking. Transfer liquid and absorbent material in approved container. Then flush and mop area with water allowing to air dry. Keep spill out of sewers and open bodies of water. Pesticide Disposal: Pesticide wastes are acutely hazardous. Improper disposal of excess pesticide.spray or mixture of rinsate is a violation of Federal law. If these wastes cannot be disposed of by use according to label instructions.contact your State Pesticide or Environmental Control Agency or the Hazardous Waste Representative at the nearest EPA regional office for guidance. Container Disposal : Triple rinse. Then offer for recycling or reconditioning or puncture.and dispose of in a sanitary landfill, or incineration,or if allowed by state and local authorities by burning. If burned stay out of smoke. Do not reuse empty container(bottle,can, bucket). Wrap container and put in trash. Do not add this product to any irrigation system. 00000❑0000000000000000000000000000000000000000000000000000000000000000000000000000 SECTION VIII SPECIAL PROTECTION INFORMATON 000❑0000000000000000000000000000000000000000000000000000000000000000oo0o0000000000 Eye Protection: Product is irritating. Wear goggles or face shield when pouring into mixing container. Respiratory Protection: Not required under normal use conditions for cleaning or laundry preparations. Skin Protection : Wear rubber gloves when handling. Ventilation Recommended: None Other Protection Smocks for protection of clothing as product will fade colors. 000000000000000000000000000000000000000000000o00000000000000000000000 SECTION IX SPECIAL PRECAUTIONS OOOO0000000000000000000000000000000000000000000000000000000000 Hygenic Practices (Handling / Storage) Avoid heat and direct sunlight. Follow directions on label. Tighten cap securely. Store container upright. Keep away from children. Do not store near food stuffs,water or feed. Avoid creasing or impacting of side container walls. Separate from acids,ammonias, soap based products or organic materials. 000000000000000000000000000000000000000000000000000000000000000000 SECTION X ADDITIONAL INFORMATION 00000000000000000000000000000000000000❑❑0OODOM0000000000000000000000000o----- 00 The information below is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, expressed or implied.with respect to such- information, and we assume no liability resulting from its use. Users should make their own investigation to deter- mine the suitability of the information for their particular purposes. 0000000000000000000000000000000000000000000000000000000000000 is Page 1 SK-1961 version 2 .002 08/14/91 MATERIAL SAFETY DATA SHEET Monarch Division H. B. Fuller Company Date: 14 August 1991 . 3900 Jackson Street N:E. Minneapolis, Minnesota 55421 Prepared bv: Industrial HygienE (612 ) 761-8071 Telephone Number : 612/481-3300 Emergency Medical Telephone Number : 800/228-5635 PRODUCT IDENTIFICATION H. B. Fuller Company Name: SK-1961 Tradename: FUL-BAC 1 Product Class: Cleanina compound DOT Proper Shipping Name: Hypochlorite solution DOT Hazard Class/I..D. Number : Corrosive material . UN-1791 DOT Label : .Corrosive WARNING STATEMENTS DANGER - Causes burns to skin , eyes and mucous membranes. Mists or sprays may irritate and damage respiratory tract . Harmful if swallowed . PRECAUTIONARY MEASURES Wear appropriate protective eauipment when working with this product. HMIS RATING Health-3 Flammability-0 Reactivity-1 See OCCUPATIONAL CONTROL PROCEDURES for personal protective eauipment recommendations . EMERGENCY AND FIRST AID PROCEDURES FIRST AID: If in eye: Flush immediately with large amounts of water for at least 15 minutes . Call a physician . If on skin : Wash affected area with soap and water . Launder contaminated clothing before reuse. If vapors inhaled : Remove from exposure. Restore breathing if necessary. Keep warm and quiet. , Call a physician . For ingestion : If person can swallow, give one glass of water or milk. Do not induce vomiting . Get immediate medical attention . Never iv + e an thing b mouth ,.o 9 y _ Y an unconscious person . !, In case of fire: Non-flammable Spill or Leak : Contain spill , dilute if necessary and remove with inert absorbent . NA - not applicable NE - not established Page 2 , SK-1961 version 1 .002 08/14/91 HAZARDOUS INGREDIENTS Level ACGIH TLV Material Name/CAS # In Product OSHA PEL ( 1990-1991 ) Sodium hypochlorite (7681-52-9 ) > 10% NE NE Sodium hydroxide ( 1310-73-2 ) 1-10% 2 mg/M3-C 2 ma /M3-C "C " denotes a ceiling limit that should not be exceeded during anv part of the working exposure. - This MSDS is prepared to comply with the OSHA Hazard Communication Standard (29 CFR 1910. 1200 ) . Unlisted ingredients are not 'Hazardous ' per this OSHA Standard and are considered to be trade secrets of the H. B. Fuller Company . Identities of trade secret ingredients will be made available following the procedures "specified in the standard . OCCUPATIONAL CONTROLPROCEDURES Eye Protection : Safety goggles . Have eye washes available. Skin Protection : Prevent contact by using rubber gloves and appropriate protective clothing . Launder contaminated clothing before reuse. Provide safety showers . R.espirat:o-r.y_ :-Protection : Not normally required . Use NIOSH/MSHA'aoDroved respirator if conditions warrant. Ventilation : Standard industrial ventilation . FIRE PROTECTION Flash Point/Method : Non-flammable Appropriate Liquid material .- nonflammable Extinguishers : Special Fire Fighting Persons exposed to products of combustion Procedures: should wear self-contained breathing apparatus and full protective equipment . Unusual Fire and There is the possibility of pressure buildup in Explosion Hazards : closed containers when heated . Contact with some metals , particularly magnesium, aluminum, and zinc (galvanized metal ) can rapidly liberate hydrogen gas , which is explosive. REACTIVITY DATA Stability: Stable Incompatibility: Strona acids , ammonia solutions Hazardous Decomposition Products: Chlorine gas may evolve during a fire, or if product is mixed with acid liquids. Hazardous Polymerization : Will not occur . EFFECTS OF OVEREXPOSURE Eyes : Eye contact may cause irritation . Skin : Pro-longed or repeated contact may cause irritation . Inhalation : Mists or sprays will irritate and may damage upper respiratory tract and lungs . NA - not applicable NE - not established 0 PaQe 3 SK-1961 version 1 .002 08/14/91 Ingestion : Harmful or fatal if swallowed . Chronic : No anticipated chronic effects . This Product does not contain regulated levels of NTP, IARC , or OSHA listed carcinogens. Existino Health Conditions Affected by Exposure: No known effects on other illnesses . PHYSICAL DATA Physical State : YELLOW liQuid Weight per Gallon : 10. 12 lbs. PH: 10 ( 1% solution ) Boiling Range: NE SPILL, LEAK & DISPOSAL INFORMATION Spill or Leak Procedures: Contain spill, dilute if necessary and remove with inert- absorbent. Waste Disposal : To the best' of`our knowledge, this product does not meet the definition of hazardous waste under the U.S . EPA Hazardous Waste Regulations 40 CFR 261 . It does not contain any added raw materials with known levels of TCLP constituents as identified in section 261 .24 of the U.S. EPA Hazardous Waste Regulations . Leachate tests have not been Performed . State or local hazardous waste regulations may apply if they differ from the federal regulation . Do not neutralize with dilute acid . Consult with your local sanitary sewer authority for recommended neutralization procedures . Do not discharge to storm sewers. For additional waste disposal assistance, consult H.B. Fuller Environmental Services at 612/481-1588. .STORAGE Contact with ammonia may form explosive mixtures. REGULATORY INFORMATION TSCA All components of this Product are registered under the reaulations of the Toxic Substances Control Act . SARA TITLE III Section 313: This product does not contain regulated levels of any toxic chemical subject to the reporting requirements of section 313 of. Title III of the SLIDerfu-nd Amendments and Reauthorization Act of 1986 (SARA ) and 40 CFR Part.372. NA - not applicable NE - not established 4b Page 4 SK-1961 version 1 .002 08/14/91 STATE REGULATIONS California: Proposition 65, The Safe Drinking Water and Toxic Enforcement Act of 1986: _This product does not contain known levels of any chemical known to the State of California to cause cancer or cause reproductive damage. x NA - not applicable NE - not. established • Paso 2 5 vwDOUS YIn MALI Or 01940 UOUIDS.•wI".00 aASl• LIQUID AIR CORPORATION �LPHAGAZ ® lftr"A J Om610a Hone } f Specialty Gaii PHYSICAL DATA Material Safety Data Sheet alstcrallT I12S ■ -76*F -60•C 1100300041.ITAT00I1.10146rONT -320,445OF f_195.3039CJ See Last Page r Ic*W■e •1 H ro en .iron raRsvas 6An O[am"AT M-rcrl. Sulfide in H1_ro g •ee Last Page See Last Page -Sulfide atI Nirrog ocu+unlx7ARn IIZ ■ o V e rMSEUNG10■n ofoater/lT a>ILurar■utrweMrrcea 1.2 ■ Relatively insoluble See Last Page UoulD AlwcolbOAATION TAM2M.KAws7waMTa.{ I'•uMNCtANDCOC■ Color le gas with pungent rotten egg or. �-�•� 00 PPM r�lsAuYaew 7 -4 Sliecif le gravijj! (air tf o ■ Olilrhelna►leax,srta 238 Hydrogen de i l{i en for N ■ 7 -37-9 =o m.citi3a lla ab/. CI�rIY:aL WM�AwO w►10117., .a AIrM 7M IruMatA plwq FIRE AND EXPLOSION HAZARD DATA walautcl..r."Immala+rs»PP• dro en Sol ide t IiiU[oam Arlin 1.7aTA roAwu ar You tM.e•DOar CROLVICAL rANWV USN►OIMI IY[TMOD W(q wtrto 5"nw"um"w"'iflaa rcAMMIUu uMm%OV VOLUM9 ANDwtlllanM corvbaxra norm or�T. PM S 1 1 Gas mixture IA It LA ""Aw IWI.OMtON luu:7r114LC1AR61GT10a HEALTH HAZARD DATA io flammable as i ture Nonhazardous The TWA for H S Ts aAennarwa raoecoeMla 2 0 Molar PPN; its STEL is 15 Molar PPP. •eelA: (ACGIH 1987-1988). Nitrogen is considered a simple asphyx ant. Oxygen levels should e matr1t4 ned-At Continued ast ael 11t, s 9WEP743MSaraa/OSU" Inhalation of these eixtures for short periods of time should not wIOSDAarMeewrotvLowrrAanos cause Irreversible effects. (OSHA IDLII for HH,,S ■ 300 Flolar PPN). Continuous eAr-osur to these mixtures• particularly the higher cohcentrattons.should cause irritation to :ylinders contain high pressure gas. if a cylinder is to a fire. cool it and the mucous membranes and surroundingLind r with r ont r 1 Snd conjunctivae of the eyes. It could also cause headache o e s wate s ra toe rot ise of interne ressure. t l a _1 t Y P Y P Y pressure. di zziness or nausea. REiACTIViTI DATA The sharp pungent odor of the HZS In the nitrogen should preclude the concern for the otentiai of asphyxiation due to the i n (Continued on last page) .71murf ODM7100/274AY010 IMCM00rcALreOrelrlaa Inhalati a uw O Of hydrogen H/A yd gem sulfide is highly toxic. .It reacts with the enzymes ym s In the bloodstream: inhibitirq cell resplratfon. Contlnucvs exposure po e srr• 1; renders the olfactory sensors inoperative which could.result in the nitrogen acting as a simple asphyxiant by excludfag an adequate supply of oxygen to support life. acofnlmnrn•rr.Ie•I.r r twig None TLese mixtures are not listed in the IARC, MTP or by OSNIA as a carcinogen or a 416La000l OTCOY/■amOn lAoouGTa potential carcinogen. i MAIAr00e6 rVLfMSaILl70M riOMDrums TO Ai040 i ea•,Cite. Llated as Ca.clnogea Rational Torloslagy Yes ❑ I,K.R.C. Ya ❑ OSHA Yes ❑ .a M.taw x N/A or Potential Carcinogen Program tdo Man a ns No oW P o (D AlCOMADIOIe rlasT Ae1 TwrAA.aMr - SPILL OR LEAK PROCEDURES:icra ro K ue;aw IN CAM W7wA►a uuewsro oa ArIUiw I PRCI•iPT HEDICAL ATTENTION IS HAIIOATORT 1N ALL CASES OF 07EREXP05UdE TO THESE HIVURFS. RESCUE PERSCHHEL r{OULD B EQUIPPED all r 1 QU WITH SELF-CONTAINED BREATHING APPARATUS. Evacuate 1 pe sonnet from affected area. Use appropriate protective equipment. , If leak is in container or container Salve, contact the closest Liquid Air i Inhalation: Ccnscious persons stwild be assisted to an uncontaminated area and Corporation location. inhale fresh air. Quick removal from P QN the e3ntaalinatel: area is r»st Important. Unconscious persons should be moved to an uncontaminated area, given mouth-to-mouth resyscitation and supplemental oxygen. Medical assistance should be sought VASTi owouLMaYca - immediately. Do not attempt to dispose of haste or unused quantities. Return in the shipping container properly labeled with an valve outlet lu s or caps secsred and vale ro.ection cap tr. ace to L qui Hr Corporation or pro2er cispose . For emergency J disposal. contact Fe-closest Liquid Air Corporation location. �_ A�•.ru•Y•mAnen,7a.eetwuv••.fal u7w■r7r•a»s.I•MtaN•I V•tN•t.f70•nA.ti\leaNrt a••.P-.•a•.•7.uwe.anelwt..w..e rnw•eno 7• EMERGENCY RESPONSE INFORMATION .�7+N•l wA.CfI►.I.a7r+n•rf•t.•.N.••••9a..fl.wa•laq avuuwrt.f�aw...fists•..N7rwra.Mrcw.rw.wvMetanrs.twa.Ie11Rtf rI.7.•.•O7rtsi.Itifa Wf•Y 3K•lVir.MG�ra.a6 M 4+►.ow.M.M sl n.[ou•M.M..N.N.M.T tiYwp t••lf fl■e■Al iiw"At"Maw. IN CASE OF EMERC*EHCY INNOLYING THIS MATERIAL.CALL DAY OR RIGHT{900)231.1356 ^r'fol�.■s7ratn.efr Dora W,II•,Y„eyrwnM►s.•,ei7ti Rrf7.•r�.Iln are.f•w OR CALL CHEMTREC AT I4100142"309 AG SIM P'D°2 SPECIAL PROTEC11Oii INFORMATION °'� t �r..IDAU DA OTiI{A u0111Di aOtO10R OAitl A1Mr1ATOA7 q,0*tCnOrawr+Ay r • ,. °� � VCs11aAT70" IaCAL snrMAtT tAM.WA. NIA N!A N/A • � � IrOfAAKAA 10o•s OtrCa•f IVA racizemle scam Any material r ' osrNDTICnaw #. PHYSICAL DATA Safet goggles or glasses t 1o4w rOu1 N0M0 KP Wrff At ILWW O r�c,.fr 3 *TWA►WrIcim enutrorf -317.9-f (-194.4-C) 54.70 lb/ft (816_21 kg/m ) Safety shoes f (•Aron.AssuAr(w 70-f 21.1 C above the pas DOER At 74•F.�A I critical temperarmre of 420 T- 40. .074 lb ft3 It.200 k n3 SPECIAL PRECAUTIONS* { Isatuarunm wArxn @ unsen rAtamomm : SubBle Point A. a 1J'tCIAl tIerL000XWDR.AATIOr coefficient ■ .0183 -317.80F (494.35%) DOT Shipping Nara:: Air, compressed DOT Hazard Class: Nonflammable gas AnruAAl41A.0000n DOT Shipping Label: Nonflammable gas 1.0. No.: UN 1092 1 Colorless odoriess oas. Specific ravft IP70•F fAir ■ i 0 Is 1.0. Sirs"LMANGLAie"ccol"1N"r" FIRE AND EXPLOSION HAZARD DATA Valve protection caps twist rennin in place unless container is secured with valve I outlet piped to use point. Do not drag, slide or roll cylinders. Use a suitable rualrwtam.oDultd► wvrol01aTp1ATL+OLLTnrr tTArrAAAAWsq.onoanr. hand truck for cylinder movement. Use a pressure reducing regulator when connecting i N A cylinder to )orrer pressure (c3,000 psig) piping or systems. Do not heat cylinder ay I I`:T aws" 'Milo" n`cTIDa"c`AMOWCATWIS any means to increase the discharge rate of product from the cylinder. Use a check ' ahip gal valve or trap to the discharge line to Prevent hazardous back flaw into the cylinder. �. i sr COAL 11410IG"Two P,IDCZMAZf r R/n • F3r eddleenAl IIAedU"ft2---4nYe0n6 0~VAN UmPOWs gmrdsceoe•Gan v COWWRO"Gn AA, CMIM FA We P.I 1 V�tBUKfPC A,p Q1lOL0A MA2AAOs - a Comoressed air at high pressures will accelerate the burning of materials Loa greater 1no.aATOAAnanlcorrorDAnaa rate :nay, they burn at atmospheric pressure. Protect Cylinders from physical damage. Store in cool, dry, 'well-ventilated area away from heavily trafficked areas and wergency exits. Do not allow the temperature REACTIVITY DATA where cylinders are stored to exceed 13OF (54C). Cylinders should be stored uorignt TTACIyT7 coA,oIDOAIam.Aas and firmly secured to. prevent falling or being knocked over. Fell and empty cylinders -��• should be segregated. Use a 'first in-first out' tnrentory systen to prevent full cylinders being stored for excessive periods of time. sAr. X .4comrAnslurw lrrrr"�.A.q pion Rey eddOWAW rAYOd rsosmAWNSINGAs eoAwa CAN Ua,Ab's EACTCrOAdAr M Orr w Cann.."Gas AAAopeeed►emen"r F•/ .anAo3woroor.ollno"rroauelf i wcALrAOAAarsAACOrrpOAnaq "ZAXDCL4°oL+rncaAow coranaTO.sols -"To~ noncorrosive n e Dry air is noncoosive and may be used with ail materials .of construction. Moisture I Wf O causes petal oxides witch are formed with air to be hydrateo so that they increase ,,,,r..a"- X In volume and lose their protective role (rust fonmation). Concentrations of S02. C12, salt, etc. in the moisture enhances the rusting of metals In air. � SPILL OR LEAK PROCEDURES IMrs 10 81 TA,m,M uQ NATO0µ Al ACI"A"D a s°LLAW . I 1 NIA I Omen K:--.rmamorO ca rucxv 1O1s Compressed gas cylinders should not be refilled except by oualified producers of compressed gases. Shipment of a compressed gas cylinder wnicn has not been filled "ATTI O,AAOSALMCMOD by the owner or with his (written) coasent is a violation of Federal Law ;49CFRi. N/A 1 _ . EMERGENCY RESPONSE INFORMATION .A�AA.pr,u.,,..A✓Tnrrerr 096-0"rM Aare am a..ur wr....AAAa�rA.d w Pq Arw..r,w w wry.w n. IN CASE OF EMERGENCY INVOLYWG THIS MATERIAL.CALL DAY OR RIGHT i8001 231-138b .A.derwuaw,AaAmr...tAonnorawrw.,y w,.w-r+.,r,r.�s,a.AeA.ownnwew�rnwntMsrr�o....ati,rww... OR CALL CHEMTREC AT 18031 444-SM M W.&W T..N r.W__& WPMMaterial Safet Data Sheet DEERE & COMPANY Y John Deere Road Moline, Illinois 61265 (309) 765-2767 (309) 765-4292 Emergency JOHN DEERE PRODUCT NAME: Hy-Gard Transmission and Hydraulic Oil DATA SHEET NO: 8503-40,100 LATEST REVISION DATE: 15 Feb. 1989 DEERE CODE: Y3, Y38, XN, Y4 JDM PART NO: TY6237, TY6238,TY6278, TY6354, AR69444, AR69445 --------------------------------------------------------------------=-----------------= SECTION I - PRODUCT IDENTIFICATION CHEMICAL NAME AND SYNONYMS: Lubricating Oil; Hydraulic Fluid; J20A CHEMICAL FAMILY: Hydrocarbon FORMULA: Complex ---------------------------------------------------------------------------------------- SECTION II - HAZARDOUS INGREDIENTS INGREDIENT PERCENT TLV/PEL V.P. CAS.* Solvent refined, hydrotreated, heavy paraffinic distillate 50-60 5 mg/m3* - 64742547 Solvent refined, hydrotreated, middle distillate 0-25 5 mg/m3* - 64742467 Severely hydrotreated light naphthenic distillate 0-25 5 mg/m3* - 64742536 Polymeric additive in oil (poly-methacrylate) 10-15 None - None Additive containing zinc dialkyl dithiophosphate 5- 6 None - Mixture *.for oil mists -------------------------------------------------------------------------------- ------- SECTION III - PHYSICAL DATA BOILING POINT: N.A. SP. GRAVITY (WATER=1) : 0.89 % VOLATILE VOLUME: N.A. EVAPORATION RATE: N.A. VAPOR DENSITY: N.A. SOLUBILITY IN WATER: Insoluble APPEARANCE/ODOR: dark amber/slight odor N.A. - not available SECTION IV - FIRE & EXPLOSION HAZARD DATA FLASH POINT: 3900 F C.O.C. FLAMMABLE LIMIT - LEL: N.A. EXTINGUISHING MEDIA: Water fog, foam, dry chemical, carbon dioxide, or halogenated agents. SPECIAL FIRE FIGHTING PROCEDURES: Do not use a direct stream of water. Product will float and can be-reignited on surface of. water. Cool fire exposed containers with water. Use NIOSH approved self-contained breathing apparatus. UNUSUAL FIRE & EXPLOSION HAZARDS: None 62183(8 871 5 .g� ,� w w.�rntr'�"�5�,,; Ct• 'T �#q "�'�,. ,9'.` ,iA✓w� cib e h ' .. „�_, Material Safety Data Sheet DEERE & COMPANY x, ' DATA SHEET NO: 8503-40,100 SECTION V - HEALTH HAZARD DATA EXPOSURE LIMIT: See Section II - Hazardous Ingredients EFFECTS OF OVEREXPOSURE: Exposure to vapors or mists of this product may cause mild upper respiratory tract irritation. Prolonged or repeated contact may cause various skin disorders such as dermatitis, oil acne, or folliculitis. Eye contact is minimally irritating. Effects of ingestion are expected to be relatively non-toxic. Exposure to product may aggravate preexisting skin and respiratory conditions. EMERGENCY & FIRST AID: Eyes - flush with water 15 minutes. Skin - remove contaminated clothing; wash skin with soap and water; if material is injected under the skin, do not, wait for symptoms to develop - get medical attention promptly to prevent serious damage. Inhalation - remove victim to fresh air and provide oxygen if breathing is difficult. Ingestion - do NOT induce vomiting. In all cases seek medical attention. -------------------------------------------------------------------------------- SECTION VI - REACTIVITY DATA STABILITY: Stable INCOMPATIBILITY: Avoid open flame, and oxidizing materials HAZARDOUS POLYMERIZATION: Will not occur DECOMPOSITION PRODUCTS: Dependent '.on combustion conditions. A complex mixture of airborne solid, liquid, and gas will evolve when this material undergoes pyrolysis or combustion. Oxides of carbon, sulfur, phosphorous, and other unidentified organic. com- " pounds may be formed. ---------------------------------------------------------------------------------------- SECTION VII - SPILL OR LEAK PROCEDURE STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Dike and contain. Use vacuum or an absorbent such as clay or sand to pick up. Flush area with water to remove trace residue. NOTE: This product is classified as an oil under the Clean Water Act. Spills, entering surface waters or any watercourse or sewer leading to surface waters, must be reported to the National Response Center 800-424-9802. WASTE DISPOSAL METHOD: In accord with federal, state, and local regulations ----------------------------------------------------------------------------------- SECTION VIII - PROTECTIVE EQUIPMENT INFORMATION VENTILATION: Local exhaust to keep TLV/PEL below acceptable levels RESPIRATOR: NIOSH approved as needed EYE WEAR: Recommended GLOVES: Recommended to minimize skin contact OTHER: ---------------------------------------------------------------------------------- SECTION I% - SPECIAL PRECAUTIONS Minimize skin contact. Wash with soap and water before eating, smoking, or using toilet facilities. Launder contaminated clothing before reuse. Properly dispose of contam- inated articles including shoes that cannot be cleaned. Store in a cool, dry place with adequate ventilation. Keep away from open flames. Keep away from children. -----------------------------------------------------------------=------------- SECTION % - DATA PREPARATION NAME: T. M. Snyder, CIIH TITLE: Supervisor, Industrial Hygiene 1 SIGNATURE: / DATE: FEB 11 p991 - ----------------- '-�� -- The information contained herein is believed to -be accurate. However, no warranty is expressed or implied regarding the accuracy of these data or the results to be obtained from the use thereof. Vendor assumes no responsibility for injury to vendee or third persons proximately caused by the material if reasonable safety procedures are not adhered to as stipulated in the data sheet. Furthermore, vendee assumes the risk in use of the material . nz183(8 n . .............. ........ .......... ... . . M Q7ERIAL SAF£TY.:DQ . TA $HEFT 3735 'GR€EN ROAtl T€)_EPHONE (2t6)292 5000 EMERGEN. ... (2;16)�65�6727 8 30 5 00 1:ST HEACHW00b.,.:;t)HFO A E.t$.H(3E1RS :.C.HEMTR.E.E (800)424., ;300. ------------------------------------------------------------------------------------------------ SECTION I -------------------------------------------------------------------------------------------------- Order Code.: 876022 309 Order Desc: CS TREMSEAL GP-BRONZE (30 CTG/CS) 7/T WT 32#t Trade Name: IMPROVED TREMSEAL GP Code Number: 876-021-309 Prepared By: C.R. Bruno Product Class:' CAULKING Date: 19-Nov-1991 Additional Components: NONE Replaces: N/A DOT Proper Shipping Name: NOT REGULATED DOT Hazard Class: N/A TSCA Status: OK DOT UN/NA Number: N/A ------------------------------------------------------------------------------------------------ THIS MATERIAL SAFETY DATA SHEET (MSDS) APPLIES TO TREMSEAL GP WITH THE FOLLOWING CODE NUMBERS AND COLORS: 876-021 ALUMINUM STONE 876-022 BRONZE 876-023 LIMESTONE 876-024 WHITE ------------------------------------------------------------------------------------------------ SECTION II - COMPOSITION / INFORMATION ON INGREDIENTS ------------------------------------------------------------------------------------=----------- CHEMICAL or COMMON NAME i MAX. i EXPOSURE LIMITS CAS Number (symbols explained below) i WT. %i TWA STEL ---------------------------------------------------------------- POLYURETHANE POLYMER 40 OSHA - - N/A N 1 iACGIH - - -- -------------------------------------------------------------------- CALCIUM CARBONATE (LIMESTONE) i 15 i OSHA 15 mg/M3 (tot dust,5mg/M3 respirable) 1317-65-3 i iACGIH 10 mg/M3 - (tot dust,no asbest,<l%Si02) ----------------------------------------------------------------- ---------------- ----------- f CALCIUM SULFATE 15 ' OSHA 15 mg/M3 ---- - (tot dust,5mg/M3 respirable) 7778-18-9 1 iACGIH 10 mg/M3 - (tot dust,no asbest,<l%Si02) ------------------------------------------------------------------------------------------------ DIPROPYLENE GLYCOL DIBENZOATE 15 OSHA - - 27138-31-4 1 1ACGIH - - ------------------------------------------------------------------------------------------------ CASTOR OIL, MODIFIED 1 5 1 OSHA 15 mg/M3 - (total nuisance dust) 8001-78-3 1 iACGIH 10 mg/M3 - (total nuisance dust) ------------------------------------------------------------------------------------------------ KAOLIN (CLAY) 5 OSHA 10 mg/M3 - (tot dust,2mg/M3 respirable) 66402-68-4 �ACGIH'10 mg/M3 - (tot dust,no asbest,<1%SiO2) -----------------------=------------------------------------------------------------------------- POLYAMINE 5 1 OSHA - - N/A ## �ACGIH - - ------------------------------------------------------------------------------------------------ TITANIUM DIOXIDE 1 5 1 OSHA 10 mg/M3 - 13463-67-7 1 �ACGIH 10 mg/M3 - (tot dust,no asbest,<1%Si02) ---------------------------------------------------------------------------------=-------------- IRON OXIDE 1 2 1 OSHA 10 mg/M3 - (dust,fume as Fe) 1309-37-1 1 �ACGIH 5 mg/M3 - (fume as Fe) ------------------------------------------------------------------------------------------------- TOLUENE (METHYLBENZENE) j 2 1 OSHA 100 ppm 150 ppm 108-88-3 + I IACGIH 50 ppm - (skin) ------------------------------------------------------------------------------------------------ STODDARD SOLVENT (MINERAL SPIRITS) 1 2 1 OSHA 100 ppm - 8052-41-3 1 �ACGIH 100 ppm ------------------------------------------------------------------------------------------------ WHITE MINERAL OIL 1 2 i OSHA 5 mg/M3 - (mist) 8042-4.7-5 1 iACGIH 5 mg/M3 10 mg/M3 (mist) ------------------------------------••----------------------------------------------------------- DIISODECYL PHTHALATE . 2 1 OSHA - - 26761-40-0 jACGIH - - -------------------=---------------------------------------------------------------------------- CARBON BLACK 1 OSHA 3.5 m /M3 1333-86-4 �ACGIH 3.5 mg/M3 - ---------------------------------------i------ ------------------------------------------------- CRYSTALLINE SILICA (QUARTZ) 0. 15 OSHA 0. 1 mg/M3 - (respirable dust) 14808-60-7 * � �ACGIH 0. 1 mg/M3 - (respirable dust) ------------------------------------------------------------------------------------------------ ## - Specific chemical identity is being withheld as a trade secret. 388 28000693 5 Order Code: 876022 309 Page 002 Order Desc: CS TREMSEAL GP-BRONZE (30 CTG/CS) 7/T WT 32N * - Indicates IARC, NTP, or OSHA carcinogen. + - Specific chemical is listed in SARA-313; shown at typical percentage. WARNING: THIS PRODUCT CONTAINS CHEMICALS) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER OR BIBTH DEFECTS OR OTHER REPRODUCTIVE HARM. ------------------------------------------------------------------------------------------------- SECTION III - PHYSICAL DATA !! --------------------------------------------------------------------------- -------------------- Weight/Gallon: 10.6k Vapor Pressure: N/A Melting Point:N/A Specific Gravity: 1.28 Vapor Density (Air = 1):>1 Boiling Point:N/A pH (Aqueous): N/A Solubility in Water: Negligible Softening Point:N/A % Volatile By Wt:Max.5 Evaporation Rate (ETHER=1):>l Freezing Point: N/A Physical State: PASTE Odor: SLIGHT Color: SEE SECTION I ------------------------------------------------------------------------------------------------ -------------SECTION IV - FIRE AND EXPLOSION DATA ---------------- ------------------------------------------------------------ Flash Point (F) : N/A Method: N/A LEL (Lower Explosion Limit) : Not Established UEL (Upper Explosion Limit) : .Not Established Auto-ignition Temperature: Not Established Decomposition Temperature: Not Established If water fog is ineffective, use carbon dioxide, dry chemical or foam. UNUSUAL PRODUCTS OF IGNITION: Hydrocyanic acid can form. UNUSUAL FIRE AND EXPLOSION HAZARDS: Never use welding or cutting torch on or near container (even empty). Product, residue or vapor may ignite. See section IX for additional precautions. SPECIAL FIREFIGHTING PROCEDURES: During a fire, personnel at the scene are to prevent exposure to fumes using accepted fire fighting techniques. ----------------------------=------------------------------------------------------------------- SECTION V - HEALTH HAZARD DATA ------------------------------------------------------------------------------------------------ ROUTES OF ENTRY AND EFFECTS OF OVEREXPOSURE: EYE CONTACT - Can cause irritation. SKIN CONTACT - Can cause irritation. SKIN ABSORPTION - N/A INHALATION - Can cause headache, dizziness, nausea, drowsiness, stupor, irritation to respiratory system. INGESTION - Can cause gastrointestinal irritation. EMERGENCY AND FIRST AID: IF ON SKIN - Wash area of contact thoroughly with hand cleaner followed -by soap and water. If irritation, rash or other disorders develop, get medical attention immediately.. IF IN EYES = Flush- immediately with running water for 15 minutes, lifting the upper and lower lids occasionaly. Get medical attention immediately. IF INGESTED - Get medical attention immediately. IF' INHALED - Leave area to breathe fresh air. Avoid further overexposure. If symptoms persist, get medical attention immediately. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Exposure to toluene can aggravate preexisting eye, skin and respiratory disorders and anemia. POTENTIAL EFFECTS OF LONG-TERM OR CHRONIC EXPOSURE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling contents may be harmful or fatal . IARC concluded that there is sufficient evidence for carcinogenicity of crystalline silica (quartz) in experimental animals, but only limited evidence in humans. Prolonged and repeated overexposure to free crystalline silica dust above the TLV level may cause scarring of the lungs with cough and shortness of breath,. A delayed lung injury, silicosis may result from breathing free silica. OTHER HEALTH HAZARD DATA: Prolonged and repeated overexposure to toluene caused liver and kidney damage in laboratory animals. Based on animal experiments, toluene may be a cardiac sensitizer and may cause birth defects or other reproductive abnormalities. Overexposure to mineral spirits can.adversely affect the lung, CNS or cardiac system. Prolonged ,and repeated exposure caused kidney damage in male rats. ------------------------------------------------------------------------------------------------ SECTION VI - REACTIVITY DATA -------------------------------------------------------------------------- HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur. STABILITY: Stable 389 28000693 6 Order Code: 876022 309 Page 003 Order Desc: CS TREMSEAL GP-BRONZE (30 CTG/CS) 7/T WT 32N INCOMPATABILITY: Avoid contact with strong oxidizing agents. ---------------------------------------------------------------------------------------------- SECTION VII - SPILL OR LEAK PROCEDURES ----------------------------------------------------------------------------------------------- CLEAN-UP: Remove sources of ignition immediately. Ventilate to reduce the airborne contaminant concentration below the exposure limit in Section II of the MSDS. Absorb spill in sand, earth or other suitable material . Transfer to appropriate container for disposal . WASTE DISPOSAL METHOD: Not regulated by RCRA. Dispose of in compliance with state and local regulations. EPA HAZARDOUS WASTE NUMBER: N/A EPA REPORTABLE QUANTITY: N/A NATIONAL EMERGENCY RESPONSE CENTER: 800-424-8802 OR 202-426-2675 ------------------------------------------------------------------------------------------------ SECTION VIII - PROTECTIVE EQUIPMENT TO BE USED ------------------------------------------------------------------------------------------------ VENTILATION: Use local exhaust when the general ventilation is not sufficient to keep the airborne contaminant concentration below the exposure limit in Section II of the MSDS. RESPIRATORY PROTECTION: Wear NIOSH/MSHA approved respirator as directed by the manufacturer when the airborne contaminant level(s) exceed the exposure limits indicated in Section II. SKIN PROTECTION: Protect hands with impervious rubber gloves. Prevent contact with skin. Gloves must be checked before each use for signs of degradation and penetration and for proper functioning. EYE PROTECTION: Wear suitable safety eyewear. . FACE PROTECTION: Not required. OTHER PROTECTIVE EQUIPMENT: Typical full cover clothing. --------------------------------------------------------------------=--------------------------- SECTION IX - SPECIAL PRECAUTIONS OR OTHER COMMENTS ------------------------------------------------------------------------------------------------ <` STORAGE, HANDLING AND APPLICATION: Store under normal warehouse conditions below 80F. Prevent inhalation of vapor, ingestion, and ` :- contact with skin and eyes. Keep container closed when not in use. Precautions also apply to emptied containers. PRECAUTIONS FOR REPAIR AND MAINTANENCE OF CONTAMINATED EQUIPMENT: Personal protective equipment must be worn during maintanence or repair of contaminated mixer, reactor, or other equipment. OTHER: Change soiled workclothes frequently. Clean hands thoroughly after handling. FOR INDUSTRIAL USE ONLY. KEEP OUT OF REACH OF CHILDREN. THE HAZARD INFORMATION HEREIN IS OFFERED SOLELY FOR THE CONSIDERATION OF THE USER, SUBJECT TO HIS OWN INVESTIGATION AND VERIFICATION OF COMPLIANCE WITH APPLICABLE REGULATIONS, INCLUDING THE SAFE USE. OF THE PRODUCT UNDER EVERY FORESEEABLE CONDITION. CODE NUMBER: 876-021-309 MSDS ISSUE DATE: 19-Nov-1991 I 390 28000693 7 PAGE: 1 PAGE; 2 DATE: 04/09/92 ACCT: 119886-01 DATE: 04/09/92 ACCT: 119886-01 INDEX: 04921001220 CAT NO: 02964 PO NBR: 220946. INDEX: 04921001220 CAT NO: 02964 PO NBR: 220846 **ISOOCTANE** 11990 EMERGENCY RESPONSE GUIDEBOOK, DOT P 5800.5). **ISOOCTANE** **ISOOCTANE** FIREFIGHTING: MOVE CONTAINER FROM FIRE AREA IF YOU CAN DO IT WITHOUT RISK. APPLY COOLING MATERIAL SAFETY DATA SHEET --------------------------- WATER TO SIDES OF CONTAINERS THAT ARE EXPOSED TO FLAMES UNTIL WELL AFTER FIRE --------------------- -------------------------- IS OUT. STAY AWAY FROM ENDS OF TANKS. FOR MASSIVE FIRE IN CARGO AREA, USE UNMANNED HOSE HOLDER OR MONITOR NOZZLES; IF THIS IS IMPOSSIBLE, WITHDRAW FROM FISHER SCIENTIFIC EMERGENCY NUMBER: (201) 796-7100 AREA AND LET FIRE BURN. WITHDRAW IMMEDIATELY IN CASE OF RISING SOUND FROM CHEMICAL DIVISION CHEMTREC ASSISTANCE: (800) 424-9300 VENTING SAFETY DEVICE OR ANY DISCOLORATION OF TANK DUE TO FIRE. ISOLATE FOR 1 REAGENT LANE 1/2 MILE IN ALL DIRECTIONS IF TANK, RAIL CAR OR TANK TRUCK IS INVOLVED IN FIRE FAIR LAWN NJ 07410 (1990 EMERGENCY RESPONSE GUIDEBOOK, DOT P 5800.5, GUIDE PAGE 27). I (201) 796-7100 EXTINGUISH ONLY IF FLOW CAN BE STOPPED. USE WATER IN FLOODING AMOUNTS AS A THIS INFORMATION IS BELIEVED TO BE ACCURATE AND REPRESENTS THE BEST FOG; SOLID STREAMS MAY SPREAD FIRE. COOL FIRE-EXPOSED CONTAINERS WITH FLOODING INFORMATION CURRENTLY AVAILABLE TO US. HOWEVER, WE MAKE NO WARRANTY OF QUANTITIES OF WATER APPLIED FROM AS FAR A DISTANCE AS POSSIBLE. AVOID MERCHANTABILITY OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, WITH RESPECT TO BREATHING TOXIC VAPORS, KEEP UPWIND. EVACUATE TO A RADIUS OF 1500 FEET FOR SUCH INFORMATION, AND WE ASSUME NO LIABILITY RESULTING FROM ITS USE. USERS UNCONTROLLABLE FIRES. CONSIDER EVACUATION OF DOWNWIND AREA IF MATERIAL IS SHOULD MAKE THEIR OWN INVESTIGATIONS TO DETERMINE THE SUITABILITY OF THE LEAKING. INFORMATION FOR THEIR PARTICULAR PURPOSES. ------------------------------------------------------------------------------ ------------------------------------------------------------------------------ TRANSPORTATION DATA SUBSTANCE IDENTIFICATION DEPARTMENT OF TRANSPORTATION HAZARD CLASSIFICATION 49 CFR 172.101: CAS-NUMBER 540-84-1 FLAMMABLE LIQUID SUBSTANCE: **ISOOCTANE** DEPARTMENT OF TRANSPORTATION LABELING REQUIREMENTS 49 CFR 172.101 AND TRADE NAMES/SYNONYMS: SUBPART E: 2,2,4-TRIMETHYLPENTANE; ISOBUTYLTRIMETHYLMETHANE; ISO-OCTANE; STCC 4908188; FLAMMABLE LIQUID UN 1262; 0296; 0297; 0298; 0300; 0299; 03981; 0296SK; 0301; C8H18; ACC28270 DEPARTMENT OF TRANSPORTATION PACKAGING REQUIREMENTS: 49 CFR 173.119 CHEMICAL FAMILY: EXCEPTIONS: 49 CFR 173.118 HYDROCARBON, ALIPHATIC ` FINAL RULE ON HAZARDOUS MATERIALS REGULATIONS (HMR, 49 CFR PARTS 171-180), MOLECULAR FORMULA: CS-H18 DOCKET NUMBERS HM-181, HM-181A, HM-181B, HM-181C, HM-181D AND HM-204. EFFECTIVE DATE OCTOBER. 1, 1991. HOWEVER, COMPLIANCE WITH THE REGULATIONS IS MOLECULAR WEIGHT: 114.26 - AUTHORIZED ON AND AFTER JANUARY 1, 1991. (55 FR 52402, 12/21/90) CERCLA RATINGS (SCALE 0-3): HEALTH=U FIRE=3 REACTIVITY=O PERSISTENCE=O EXCEPT FOR EXPLOSIVES, INHALATION HAZARDS, AND INFECTIOUS SUBSTANCES, THE NFPA RATINGS (SCALE 0-4): HEALTH=U FIRE=3 REACTIVITY=O EFFECTIVE DATE FOR HAZARD COMMUNICATION REQUIREMENTS IS EXTENDED TO ------------------------------------------------------------------------------ OCTOBER 1, 1993. (56 FR 47158, 10/18/91) COMPONENTS AND CONTAMINANTS U.S. DEPARTMENT OF TRANSPORTATION SHIPPING NAME-ID NUMBER, 49 CFR 172.101: COMPONENT; ISOOCTANE PERCENT: >99 OCTANES-UN 1262 CAS# 540-84-1 U.S. DEPARTMENT OF TRANSPORTATION HAZARD CLASS OR DIVISION, 49 CFR•172.101: OTHER CONTAMINANTS: < 1% VARIOUS LIGHT HYDROCARBONS - 3 -FLAMMABLE LIQUID EXPOSURE LIMITS: U.S. DEPARTMENT OF TRANSPORTATION PACKING GROUP, 49 CFR 172.101: ALKANES (C5-C8): PG II 350 MG/M3 NIOSH RECOMMENDED 10 HOUR TWA; 1800 MG/M3 NIOSH RECOMMENDED 15 MINUTE CEILING U.S. DEPARTMENT OF TRANSPORTATION LABELING REQUIREMENTS, 49 CFR 172.101 AND SUBPART E: ----------------------------------------------- FLAMMABLE LIQUID PHYSICAL DATA U.S. DEPARTMENT OF TRANSPORTATION PACKAGING AUTHORIZATIONS: DESCRIPTION: CLEAR, COLORLESS, MOBILE LIQUID WITH AN ODOR OF GASOLINE EXCEPTIONS: 49 CFR 173.150 NON-BULK PACKAGING: 49 CFR 1.273.202 BOILING POINT: 211 F (99 C) MELTING POINT: -161 F (-107 C) BULK PACKAGING: 49 CFR 17342 SPECIFIC GRAVITY: 0.69 VISCOSITY: <32 SUS VAPOR PRESSURE: 41 MMHG @ 21 C U.S. DEPARTMENT OF TRANSPORTATION QUANTITY LIMITATIONS 49 CFR 172.101: PASSENGER AIRCRAFT OR RAILCAR: 5 L EVAPORATION RATE: (ETHER = 1) <1 SOLUBILITY IN WATER: INSOLUBLE CARGO AIRCRAFT ONLY: 60 L VA TOXICITY SOLVENT SOLUBILITY: ALCOHOL, ETHER, ACETONE, CHLOROFORM, DIMETHYLFORMAMIDE, BENZENE, TOLUENE, XYLENE, OILS (EXCEPT CASTOR), CARBON TETRACHLORIDE 2,2,4-TRIMETHYLPENTANE (ISOOCTANE): TOXICITY DATA: 33.52 MG/L/4 HOURS INHALATION-RAT GORAL-RAT L CSO (PHILLIPS66); ------------------------------------------------------------------------------ >2000 MG/KG SKIN-RABBIT LD50 (PHILLIPS 66); >5000 FIRE AND EXPLOSION DATA (PHILLIPS 66.); MUTAGENIC DATA (RTECS). CARCINOGEN STATUS:. NONE. , FIRE AND EXPLOSION HAZARD: LOCAL EFFECTS: IRRITANT- INHALATION. DANGEROUS FIRE HAZARD WHEN EXPOSED TO HEAT OR FLAME. ACUTE TOXICITY LEVEL: MODERATELY TOXIC BY INHALATION; SLIGHTLY TOXIC BY DERMAL ABSORPTION, INGESTION. VAPORS ARE HEAVIER THAN AIR AND MAY TRAVEL A CONSIDERABLE DISTANCE TO:A SOURCE TARGET EFFECTS: CENTRAL NERVOUS SYSTEM DEPRESSANT. OF IGNITION AND FLASH BACK. 1 ------------------------------------------------------------------------------ VAPOR-AIR MIXTURES ARE EXPLOSIVE ABOVE FLASH POINT. HEALTH EFFECTS AND FIRST AID FLASH POINT: 10 F (-12 C) (CC) UPPER EXPLOSIVE LIMIT: 6.0% INHALATION: 2,2,4-TRIMETHYLPENTANE (ISOOCTANE): LOWER EXPLOSIVE LIMIT: 1.1% AUTOIGNITION TEMP.: 779 F (415 C) IRRITANT/NARCOTIC. ACUTE EXPOSURE- MAY CAUSE IRRITATION OF THE MUCOUS MEMBRANES. EXPOSURE FLAMMABILITY CLASS(OSHA): IB MAY CAUSE RAPID BREATHING, DIZZINESS, FATIGUE, HEADACHE, LIGHT-HEADEDNESS, LACK OF COORDINATION, NAUSEA, NARCOSIS, AND OTHER CENTRAL NERVOUS FIREFIGHTING MEDIA: SYSTEM EFFECTS. EXTREME EXPOSURE MAY CAUSE UNCONSCIOUSNESS AND DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY OR REGULAR FOAM RESPIRATORY ARREST. RATS EXPOSED TO 33.52 MG/L FOR 4 HOURS, EXHIBITED (1990 EMERGENCY RESPONSE GUIDEBOOK, DOT P 5800.5). RAPID RESPIRATION AND PROSTRATION. MICE EXPOSED TO ISOOCTANE AT 8000 PPM FOR 5 MINUTES EXHIBITED NO NARCOSIS; AT 16,000 PPM FOR 5 MINUTES, FOR LARGER FIRES, USE WATER SPRAY, FOG OR REGULAR FOAM THERE WAS SENSORY IRRITATION AND 1 OF 4 MICE TESTED DIED; AT 32,000 PPM, DATE: 04/09/92 ACCT: 119886-01 PAGE: 3 DATE: 04/09/92 ACCT: 119886-01 PAGE: 4 INDEX: 04921001220 CAT NO: 02964 PO NBR: 220846 INDEX: 04921001220 CAT NO: 02964 PO NBR: 220846 IRRITATION AND IRREGULAR RESPIRATION WAS OBSERVED AND ALL MICE DIED KEEP IN A TIGHTLY CLOSED CONTAINER. STORE IN A COOL, DRY, VENTILATED AREA. WITHIN 4 MINUTES. CHRONIC EXPOSURE- REPEATED AND PROLONGED EXPOSURE TO SOME LIQUID STORE AWAY FROM INCOMPATIBLE SUBSTANCES. HYDROCARBONS MAY CAUSE POLYNEUROPATHY. r FIRST AID- REMOVE FROM EXPOSURE AREA TO FRESH AIR IMMEDIATELY. IF BREATHING **DISPOSAL** HAS STOPPED, PERFORM ARTIFICIAL RESPIRATION. KEEP PERSON WARM AND AT REST. TREAT SYMPTOMATICALLY AND SUPPORTIVELY. GET MEDICAL ATTENTION IMMEDIATELY. DISPOSAL MUST BE IN ACCORDANCE WITH STANDARDS APPLICABLE TO GENERATORS OF _ HAZARDOUS WASTE, 40 CFR 262. EPA HAZARDOUS WASTE NUMBER DO01. SKIN CONTACT: 100 POUND CERCLA SECTION 103 REPORTABLE QUANTITY. 2,2,4-TRIMETHYLPENTANE (ISOOCTANE): ****s*t*******t**********ttt**********tt*********tt********t*tt*tt*t*t******x* ACUTE EXPOSURE- MAY CAUSE IRRITATION WITH REDNESS. IF SUFFICIENT AMOUNTS CONDITIONS TO AVOID ARE ABSORBED, SYSTEMIC TOXICITY MAY OCCUR. CHRONIC EXPOSURE- REPEATED AND PROLONGED CONTACT MAY CAUSE DERMATITIS DUE AVOID CONTACT WITH HEAT, SPARKS, FLAMES, OR OTHER SOURCES OF IGNITION. VAPORS j TO THE DEFATTING ACTION. MAY BE EXPLOSIVE. AVOID OVERHEATING OF CONTAINERS; CONTAINERS MAY VIOLENTLY FIRST AID- REMOVE CONTAMINATED CLOTHING AND SHOES IMMEDIATELY. WASH AFFECTED RUPTURE IN HEAT OF FIRE. AVOID CONTAMINATION OF WATER SOURCES.- AREA WITH SOAP OR MILD DETERGENT AND LARGE AMOUNTS OF WATER UNTIL NO EVIDENCE OF CHEMICAL REMAINS (APPROXIMATELY 15-20 MINUTES). GET MEDICAL ATTENTION IMMEDIATELY. - SPILL AND LEAK PROCEDURES EYE CONTACT: - OCCUPATIONAL SPILL: 2,2,4-TRIMETHYLPENTANE (ISOOCTANE): SHUT OFF IGNITION SOURCES. STOP LEAK IF YOU CAN DO IT WITHOUT RISK. USE WATER ACUTE EXPOSURE- MAY CAUSE IRRITATION WITH REDNESS. SPRAY TO REDUCE VAPORS. FOR SMALL SPILLS, TAKE UP WITH SAND OR OTHER ABSORBENT CHRONIC EXPOSURE- NO DATA AVAILABLE— MATERIAL AND PLACE INTO CONTAINERS FOR LATER DISPOSAL. FOR LARGER SPILLS, DIKE FAR AHEAD OF SPILL FOR LATER DISPOSAL. NO SMOKING, FLAMES OR FLARES IN HAZARD FIRST AID- WASH EYES IMMEDIATELY WITH LARGE AMOUNTS OF WATER OR NORMAL SALINE, AREA. KEEP UNNECESSARY PEOPLE AWAY; ISOLATE HAZARD AREA AND RESTRICT ENTRY. OCCASIONALLY LIFTING UPPER AND LOWER LIDS, UNTIL NO EVIDENCE OF CHEMICAL REMAINS (APPROXIMATELY 15-20 MINUTES). GET MEDICAL ATTENTION IMMEDIATELY. ------------------------------------------------------------------------------ INGESTION: PROTECTIVE EQUIPMENT 2,2,4-TRIMETHYLPENTANE (ISOOCTANE): - VENTILATION: NARCOTIC. PROVIDE LOCAL EXHAUST VENTILATION TO MEET PUBLISHED EXPOSURE LIMITS. ACUTE EXPOSURE- MAY CAUSE DIARRHEA, DIFFICULTY BREATHING, FATIGUE AND SLIGHT VENTILATION EQUIPMENT MUST BE EXPLOSION-PROOF. CENTRAL NERVOUS SYSTEM DEPRESSION. MAY BE ASPIRATED INTO LUNGS, AND CAUSE PULMONARY EDEMA, PULMONARY LESIONS, AND CHEMICAL PNEUMONITIS. RATS - RESPIRATOR: ADMINISTERED 5000 MG/KG BY GASTRIC LAVAGE EXHIBITED DEPRESSION, THE FOLLOWING RESPIRATORS ARE RECOMMENDED BASED ON INFORMATION FOUND IN THE SALIVATION, WHEEZING, AND SOFT FECES. I.N ANIMAL STUDIES, ASPIRATION OF PHYSICAL DATA, TOXICITY AND HEALTH EFFECTS SECTIONS. THEY ARE RANKED IN i C6-CS HYDROCARBONS RESULTED IN ALMOST IMMEDIATE DEATH DUE TO RESPIRATORY ORDER FROM MINIMUM TO MAXIMUM RESPIRATORY PROTECTION. t PARALYSIS, ASPHYXIA, AND CARDIAC ARREST. - THE SPECIFIC RESPIRATOR SELECTED MUST BE BASED ON CONTAMINATION LEVELS FOUND CHRONIC EXPOSURE- FEEDING STUDIES HAVE PRODUCED KIDNEY DAMAGE IN MALE RATS. IN THE WORK PLACE, MUST BE BASED ON THE SPECIFIC OPERATION, MUST NOT EXCEED THE WORKING LIMITS OF THE RESPIRATOR AND MUST BE JOINTLY APPROVED BY THE FIRST AID- ONLY HYDROCARBONS THAT ARE SOLVENTS FOR A TOXIC AGENT OR ARE NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY AND HEALTH AND THE MINE SAFETY THEMSELVES TOXIC NEED BE EVACUATED. EXTREME CARE MUST BE USED TO PREVENT AND HEALTH ADMINISTRATION (NIOSH-MSHA). ASPIRATION. GASTRIC LAVAGE WITH A CUFFED ENDOTRACHEAL TUBE IN PLACE TO PREVENT FURTHER ASPIRATION SHOULD BE DONE WITHIN 15 MINUTES. IN THE ABSENCE OF DEPRESSION OR CONVULSIONS OR IMPAIRED GAG REFLEX, EMESIS CAN ALSO BE ANY CHEMICAL CARTRIDGE RESPIRATOR WITH ORGANIC VAPOR CARTRIDGE(S) AND A INDUCED USING SYRUP OF IPECAC WITHOUT INCREASING THE HAZARD OF ASPIRATION. FULL FACEPIECE. TREAT SYMPTOMATICALLY_AND SUPPORTIVELY. GASTRIC LAVAGE SHOULD BE PERFORMED BY QUALIFIED MEDICAL PERSONNEL. GET MEDICAL ATTENTION IMMEDIATELY. ANY GAS MASK WITH ORGANIC VAPOR CANISTER (CHIN-STYLE OR FRONT- OR f ANTIDOTE: BACK-MOUNTED CANISTER), WITH A FULL FACEPIECE. NO SPECIFIC ANTIDOTE. TREAT SYMPTOMATICALLY AND.SUPPORTIVELY. ANY TYPE 'C' SUPPLIED-AIR RESPIRATOR WITH A FULL FACEPIECE OPERATED IN ` _____ PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE MODE OR WITH A FULL FACEPIECE. ------------------------------------------------------------------------- HELMET OR HOOD OPERATED IN A CONTINUOUS-FLOW MODE. REACTIVITY ANY SELF-CONTAINED BREATHING APPARATUS WITH A FULL FACEPIECE OPERATED IN REACTIVITY:i STABLE UNDER NORMAL TEMPERATURES AND PRESSURES. PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE MODE. INCOMPATIBILITIES: FOR FIREFIGHTING AND OTHER IMMEDIATELY DANGEROUS TO LIFE OR HEALTH CONDITIONS: 2,2,4-TRIMETHYLPENTANE (ISOOCTANE): ANY SELF-CONTAINED BREATHING APPARATUS THAT HAS A FULL FACEPIECE AND IS OXIDIZERS: FIRE AND EXPLOSION HAZARD. OPERATED IN A PRESSURE-DEMAND OR OTHER POSITIVE-PRESSURE MODE. REDUCING AGENTS: MAY REACT VIGOROUSLY. ANY SUPPLIED-AIR RESPIRATOR THAT HAS A FULL FACEPIECE AND IS OPERATED IN A ( DECOMPOSITION: PRESSURE-DEMAND OR OTHER POSITIVE-PRESSURE MODE IN COMBINATION WITH AN THERMAL DECOMPOSITION PRODUCTS MAY INCLUDE TOXIC OXIDES OF CARBON. AUXILIARY SELF-CONTAINED BREATHING APPARATUS OPERATED IN PRESSURE-DEMAND POLYMERIZATION: OR OTHER POSITIVE-PRESSURE MODE. HAZARDOUS POLYMERIZATION HAS NOT BEEN REPORTED TO OCCUR UNDER NORMAL CLOTHING: TEMPERATURES AND PRESSURES. EMPLOYEE MUST WEAR APPROPRIATE PROTECTIVE (IMPERVIOUS) CLOTHING AND EQUIPMENT ------ TO PREVENT REPEATED OR PROLONGED SKIN CONTACT WITH THIS SUBSTANCE. ------------------------=- STORAGE AND DISPOSAL GLOVES: EMPLOYEE MUST WEAR APPROPRIATE PROTECTIVE GLOVES TO PREVENT CONTACT WITH THIS OBSERVE ALL FEDERAL, STATE AND LOCAL REGULATIONS WHEN STORING OR DISPOSING SUBSTANCE. OF THIS SUBSTANCE. FOR ASSISTANCE, CONTACT THE DISTRICT DIRECTOR OF THE ' ENVIRONMENTAL PROTECTION AGENCY. EYE PROTECTION: EMPLOYEE MUST WEAR SPLASH-PROOF OR DUST-RESISTANT SAFETY GOGGLES TO PREVENT **STORAGE** EYE CONTACT WITH THIS SUBSTANCE. STORE IN ACCORDANCE WITH 29 CFR 1910.106. EMERGENCY EYE WASH: WHERE THERE IS ANY POSSIBILITY THAT AN EMPLOYEE'S EYES MAY BE EXPOSED TO THIS SUBSTANCE, THE EMPLOYER SHOULD PROVIDE AN EYE WASH BONDING AND GROUNDING: SUBSTANCES WITH LOW ELECTROCONDUCTIVITY, WHICH FOUNTAIN WITHIN THE IMMEDIATE WORK AREA FOR EMERGENCY USE. MAY BE IGNITED BY ELECTROSTATIC SPARKS, SHOULD BE STORED. IN CONTAINERS WHICH MEET THE BONDING AND GROUNDING GUIDELINES SPECIFIED IN NFPA 77-1983, RECOMMENDED PRACTICE ON STATIC ELECTRICITY. AUTHORIZED - FISHER SCIENTIFIC, INC. CREATION DATE: 12/31/84 REVISION DATE: 02/25/92 .2� ^ t PAGE: 5 DATE: 04/09/92 ACCT: 119886-01 INDEX: 04921001220 CAT NO: 02964 PO NBR: 220846 -ADDITIONAL INFORMATION- THIS INFORMATION IS BELIEVED TO BE ACCURATE AND REPRESENTS THE BEST INFORMATION CURRENTLY AVAILABLE TO US. HOWEVER, WE MAKE NO WARRANTY OF MERCHANTABILITY OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, WITH RESPECT TO SUCH INFORMATION, AND WE ASSUME NO LIABILITY RESULTING FROM ITS USE. USERS SHOULD MAKE THEIR OWN INVESTIGATIONS TO DETERMINE THE SUITABILITY OF THE INFORMATION FOR THEIR PARTICULAR PURPOSES. 0 - .` r � �. ;'•"Y+'`'2^�C+.�:��'Y'''{'"':'�2++.^ems!'` '�+ =;. �-rcc�t'�`"".=.;'',nY''.�x ti ..:Y' - t a P.i Past-ft brand fax transmittal rr. �= O . MAYERIALAAFETY DATA� TA SHEET LUBRYPun FGL-2, FGIrl, �'GL-0 �Ci�pft 1 LUBRIPhAATE*I ! SERIES t;2 A M-Wi� » Miae�al 031 and Additives Piske Brothers Refining Co. 129 � �� 9-9 50 129 Lockwood St., Newark05 Nwn84-9150 ff . ftedlic Chemical Identigr,Cp�gn t�} 08iiA PF.I AOOM AY poopnmended Novi-hazardous Razardous Material Identification S stem (WI S Health-1, Plammabilit »1, Reactivity-0 SOCOon M —'physkaVChemkai f nit terletjce > 550°F �wb.MiO•p vvc P+�as (nrrt(Ilya p Pit 0. 6-0.98 � 0.01 �+e1Q► � Semi-solid y Ac+It�•1) Negligible _ kwwanoa 1r�d Odor S�Qth, taa/c�kyy/& J&it/e��g/rrease -with mineral 611 odor' IV�--W OW MpI woo I• AZArd Delta COC - 435°F� =0-92 --- �r�ht,tp Mock • .ox Foem D Chemical Carbon Dioxide or Water S (Fo ) a6p+cW FM ii Vtinp Prooe "— ra Cool ex osed on a ne wi h water. Use air-au lied breathit► a ai meat for enclosed or confined a aces. tT>nuttst Fw and E Han* Do ttot store or mix with strquz oxidants. L t containers retain residue. Do not cut, drill, grind, or weld, as th ma ey y explode, nk4m"umltr cth�ly bed s 'N A x rlals to Ann like Oeoor� OM"or ii3ypro� Concentrated o en. If incom lete combustion carbon monoxide. M.y aoa� coda"to� IMg NoR Oo�x x N/A 25 "92 1S•35:, tea: �v�`s> . . _. ,._.. tW FISKE-NEWgR47W-h k6Lm NAURD DAU TMyiM0�0 r�T VAWt P.2 5 m 7.1-Or oil mist in air. OSHA Re ulation 29 CFR 1910.1000 grNCT=0� ovswrvaw�a • t an. ro uct coAtactin the vary f r6m erson--to erson. As a Precaution, osure to li uids va ors lists and fumes abould •be minimised. This product has a low order of acute oral t94city, but minute amounts as bated into the lungs during ingestion may cause mild to Severe pulmonary injury. ��Y 1�AP? No MFiC Mcnop�py� 06ifA • =NCr AND FIAST AID MIOCEOVAti No No es or unt4l- irritati n subsides. If aminated and wash with soap and warm water. 'If is ectad''b -hi h redsuea ender akin' se a�dleaa f h a ear n e ontact a can RM__IATELY. Delay may cause loss of dX—MAT ON• Vaiporareqsura is ve low and inhalation at roblem. f overcome va or from hot ' roduct, immediately •• tel . i SECTION Yt1 SPILL OR LEAN PROCEDURES le TAJ(LN IN CASE Y/►>JA1AL K kLEA�1A 0�islujp petroleum -products-out of -sewers and water courses. Advi a au h rOiALth a 1 ca a des osal -re ulations. Dis ose of absorbed material atLE III Section 313 Status - Zinc Cam and = MON trill SPEM PROTECY30N INFORMAT10� MV MATORT gIDTiC_"ajy t-4 h IM) Normally not needed wLM7iATION LOCAL g ANIfT iRCtAL N/A rtCNAMCAL f6e,4 U WWI Use il,resiistant loves if needed. �ir�rsOsa�T10N oTM MOT:CTro tovlMtNT xf chance of eye contact, wear ogles. SECTION IX SPECUL PRECMONS MICAUTIONS To IN TARN IN NAM046*6 ANp RO kc. le or e ea at arks fume ��►s�C.uT�oNs ' Remove oil-soaked clothing and launder before reuse. Cleanse , c ntact. DATE►RIPAg1p January 1992 ►Re'AAEogy: Robert J. Sibilia V Page 1 SK-0046 version 1 .003 12/31 /91 ° MATERIAL SAFETY DATA SHEET Monarch Division H. B. Fuller Company Date: 31 December 1991 3900 Jackson Street N.E. Minneapolis, Minnesota 55421 Prepared by: Industrial Hygiene (612 ) 781-8071 Telephone Number : 612/48173300 Emergency Medical Telephone Number : 800/228-5635 . PRODUCT IDENTIFICATION H. B. Fuller Company Name: SK-0046 Tradename, LUMINATE Product Class: Cleaning compound DOT Proper Shipping Name: Corrosive liquid , NOS (contains Sodium hydroxide ) DOT Hazard Class/I .D. Number : Corrosive material , UN-1760 DOT. Label : Corrosive WARNING STATEMENTS WARNING - Will irritate and may cause permanent damage to eyes, skin and mucous membranes. Mists or sprays may irritate and damage respiratory tract. PRECAUTIONARY MEASURES Avoid skin contact with product. Wear appropriate protective equipment when working with this product. HMIS RATING Health-3 Flammability-0 React-ivity-1 See OCCUPATIONAL CONTROL PROCEDURES for personal protective equipment recommendations. EMERGENCY AND FIRST AID PROCEDURES FIRST AID: If in eye: Flush immediately with large amounts of water for at least 15 minutes. Call a physician . If on skin : Wash affected area with soap and water . Launder contaminated clothing before reuse. If vapors inhaled : Remove from exposure. Restore breathing if necessary. Keep warm and quiet. Call a physician . For ingestion : If person can swallow, give one glass of water or . milk. Do not induce vomiting . Get immediate medical attention . Never give anything by mouth to an unconscious person . In case of fire: Non-flammable Spill or Leak: Contain spill , dilute if necessary and neutralize using dilute acid . Remove with inert absorbent. NA - not applicable NE - not established Page 2 SK-0046 version 1 .003 12/31 /91 HAZARDOUS INGREDIENTS Level ACGIH TLV Material Name/CAS # In Product. OSHA PEL ( 1990-1991 ) Sodium hydroxide -( 1310-73-2 ) 1-10% 2 mg/M3-C 2 mg/M3-C Sodium silicate ( 1344-09-8 ) 1-10% NE NE "C" denotes a ceiling limit that should not be exceeded during any part of the working exposure. This MSDS is prepared to comply with the OSHA Hazard Communication Standard (29 CFR 1910. 1200 ) . Unlisted ingredients are not ' Hazardous ' per this OSHA Standard and are considered to be trade secrets of the H. B. Fuller Company. Identities of trade secret ingredients will be made available following the procedures specified in the standard . OCCUPATIONAL CONTROL PROCEDURES Eye Protection : Safety goggles. Have eye washes available. Skin Protection : Prevent contact by using rubber gloves and appropriate protective clothing . Launder contaminated clothing before reuse. Provide safety showers. Respiratory Protection : Not normally required . Use NIOSH/MSHA approved particulate respirator if product is being sprayed . Ventilation : Standard .industrial ventilation . FIRE PROTECTION Flash Point/Method : Non-flammable Appropriate Liquid material - nonflammable Extinguishers: Special Fire Fighting Persons exposed to products of combustion Procedures: should wear self-contained breathing apparatus and full protective equipment. Unusual Fire and There is the possibility of pressure buildup in Explosion Hazards: closed containers when heated . Contact with some metals, particularly magnesium, aluminum, and zinc (galvanized metal ) can rapidly liberate hydrogen gas, which is explosive. REACTIVITY DATA Stability: Stable Incompatibility: Strong acids, aluminum, magnesium, zinc , or galvanized metal . Hazardous Decomposition Products: This material is non flammable. Hazardous Polymerization : 'Will not occur . EFFECTS OF OVEREXPOSURE Eyes: Direct eye contact will cause burns, and may cause permanent damage, even blindness. Skin : Skin contact with product will cause irritation and burns. NA - not applicable NIF - not o�taF1 i cF crl Page 3 SK-0046 version 1 .003 12/31 /91 Inhalation : Mists or sprays will irritate and may damage upper respiratory tract and lungs. Ingestion : Harmful if swallowed . Chronic : No anticipated chronic effects. This product does not contain regulated levels of NTP, IARC, or OSHA listed carcinogens. Existing Health Conditions Affected by Exposure: No known effects on other illnesses. PHYSICAL DATA Physical State: CLEAR liquid Weight per Gallon : 9.646 lbs. pH: 11 .5 ( 1% solution ) Boiling Range: NE SPILL, LEAK & DISPOSAL INFORMATION - Spill or Leak Procedures: Contain spill dilute if necessary and neutralize with dilute acid . Remove with inert absorbent. Waste Disposal : This product, as provided , meets the definition of hazardous waste under the U.S. EPA Hazardous Waste Reggulations 40 CFR 261 . It is hazardous waste class D003 - Corrosive. It does not contain any added raw materials with known levels of TCLP. constituents as identified in section 261 .24 of the U.S. EPA Hazardous Waste Regulations. Leachate tests have not been performed . State or local hazardous waste regulations may apply if they differ from the federal regulation . Neutralize with dilute acid and flush to the sanitary sewer . Consult with your local sanitary sewer authority before discharging to sanitary sewer . Do not discharge to storm sewer . For additional waste disposal assistance consult H.B. Fuller Environmental Services at 61�/481-1588. STORAGE Do not store near acids. REGULATORY INFORMATION TSCA All components of this product are registered under the regulations of the Toxic Substances Control Act. II NA - not applicable NE - not established Page 4 SK-0046 version 1 .003 12/31 /91 SARA TITLE III Section 313: This product does not contain regulated levels of any toxic chemical subject to the reporting requirements of section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA ) and 40 CFR part 372. STATE REGULATIONS California: Proposition 65 The Safe Drinking Water and Toxic Enforcement Act of 1986: This product does not contain known levels of any chemical known to the State of California to cause cancer or cause reproductive damage. NA - not applicable ALPHAGAZ ALP!-IAGAZ ovlrow er ualo ww oowoMsww w�awnt ot•uouo.0 twl�awaTww awu CHfHICAL NAME AND SYHaWMS: 10 Molar PPM-2.S Molar%Hethane to Air Material Safety Data Sheet ri (These data are prepared for product supplied in DOT 39 noateusable cylinders.) FORMULA: 10 Kolar PPH-2.5 Molar %CH4 in Air •e0O°°*""� 10 PPM-2.5f Methane in Air UXMPO Ma 45101 0"41300 MOLECULAR AEIGHT: CH4 ■ 16.04 ercrrayosuanwssuasauTwroMntas: Air ■ 28.96 1 cuatun coovam&naw T"ne own me"� 10 PPi{-2.SZ Methane 1n Air er,aa.wua Air ■ N A 2-8 c.rx.aa.a.a.Munn ase ""W.Wflrwt.a..L GOOOCALMLyyge.MpM"n OiA 704 MFMa1cP�l �""idcmekCAein''� Se P 4 0 0 0 PHYSICAL DATA ! 1pu■PAM JAMULlef 1,12111 sss.rsa ra egaJnr BMkT CNOMfiLrAMILY (( QQ�� �Mosevolows oauotunsuaTrsvc is e 4 See a e 4 Gas Mixture LIQUID DENSITY AT BOILING POIiiT: Air ■ 54.68lb/f ) C8 4�kg/m3`)'3} s HEALTH HAZARDOATA nun woorto aWmtas vw m UNIT VAPOR PRESSURE: 0 JO'F (21.1'0 Above the critical temperature of methane. The csmponents in these mixtures are nontoxic and no TWA is listed for them by .Air is a mixture. aC6[H [1991- 9 2 0 9a9 • snuTasavoslw f These mixtures should be considered similar to air and would therefore cause no symptoms of exposure. Tt/11[p10tIr�L/ti[11.■rlp See Sympta¢s of Exposure, above. Neither methane or air are listed in the IAAC. UTP or by OSHA as a carcinogen or potential carcinogen. Listed as Camkwgeu Nalhmd Tmdoology lbs ❑ ULR.C. Nbs, O OSHA lae D w Puteeusl Cardnogen Pmgram No ® Monographs No A[COMLpOtq fltieT iD T11(ai■04 See Symptoms of Exposure. above. Y�Inea nu bapoY�airr■wOalrrwlrta�r i naaraar..oaa�tT.woara w�rs■UR Maya atrgarmweraa auws aYua rO�Np.aava.laq aY.rara,lora.0oorra.r+.aur.rawaawe.w sVrslrw,.q rrasaer.lwlir,aa r a m.gMaru.Mral�m.a..yr.lvatpaow■wuada Mott wDr�omwq.'ottia W.Y{Y1y&t►r41■u.ww4 wc"Idem OWLS,M rya Patna.M.IYrsALWI/b tar.ysrt W 03-ft 1 raM3 I'D-~11. rwapM wtraraaar tltrtwrca MY 9r■■+tra.�t4rrr�rr Mr+roa.a■�IYt■abaa a■tWc rra� I •.. '• 10 PPR-2.5x Methane in r •-.'^ PK92 Air SPECU►L PROTECTION INFORMATION vwiz wuuoouS tRmt■ES ar onin Laws.Souls.an oua r tgom w moToerEOR wwrn,p '. NIA R ^ vsdaL►MM aocu amass. (` N/A ��c N!A None N/A rrSCE..RaIP-4 anw A N/A rponeTnaetnrss . Any material PHYSICAL DATA "Oif 4 ' - -1 1.4 C uowoas= AVDIMLErraErr or«.RreanzTnreoun..ESE Safety goggles or glasses • • - See Page 4 Safety shoes vaDORrRLUUMS oAS osEs.naan•r s r. See Page 4 .0741--.0749 lb/ft3 (1.187-1.200 kg/m3) SPECIAL PRECAUTIONS• SRu,Eamarwb= PME31Mr0rr CR4 . -29b.5'F -182.5 C �s��Irrawwno. Very slightlAir a mixture y OOTSTippingNante: CompressedGasas.N.O_S. DOTHazaidClaas: DNdslon2.2 tr+sLUSorrpoaoaa I COTSWWdngLabel: . WwRom vnableQas OOTI O Na: UN 1856 Colorless, odorless as. S ecifie Gravi (Air-1 @ 70•F (21.1'G) 0.99-1.0 •�rrww'+pSecw.e+wnwa FIRE AND EXPLOSION HAZARD DATA . U a ~surwrONT QMKII DUSSR avnRERSmoRTar. , F4Ymamis Lions w Sr YOUR" Use e pressure reducing regulator Uilen connecting cylinder to loxer pressure N/A N/A M A ( p g) piping or system. Do not beat cylinder by any means to increase ommou mtmm the discharge rate of product from the cylinder. Use a check valve or trap in the Nonflammable gas mixtures SL n azaarrdEou's'r discharge line to prevent hazardous back flow into the cylinder. Close valve after ir[aLL FM FMkNOrROCOMM each use and Alien empty. If cylinders are involved in a fire. safely relocate or keep coal with water spray. uruwa All AMMnamorwages FWDd"arEseanyracorrwrdrsm.CORWACarLlWAMd&EaerdapWladr0"aCowww WOASAraociAmAmphbt►•1_ These mixtures at high pressures +rill accelerate the burning of materials to a C � "''"L396RA "4DOOSO NDanom greater rate than they burn at atmospheric pressure. Protect cylinders from physical damage. Store in cool, dry, well ventialted area REACTIVITY DATA away from heavily trafficked area and emergency exits. Bo not allow the temperature STASWr* coscmo.eSoavoo where cylinders are stored to exceed 125F (52C) Full and empty cylinders should be segregated. Use a "first in - first oat' inventory system to prevent full cylinders being stored for excessive periods of time. sbtr v wOOrataTglTr Ptr.+.�Y arQ Wane wuASRow Eacarrrauor raaDen For tdatnmW darn"n=w"*.d,EmE aan"L'W L1an4WY EaercEDpe"a•as W Caar.,a.d an Aaoobd,n Pa.WN R%. Rone vact&L aaurrrR Escomm mo.nous rutirRrOur rRLTREEcaooR cRRoiRodS Toavpo rt.r o... These aixtures are noncorrosive and may be used with all materials of construction. N/A Moisture causes metal oxides which are formed with air to be hydrated so that they increase in volume and lose their protective role (rust fornation). Concentrations SPILL OR LEAK PROCEDURES of S02, C12, salt. etc. in the moisture enhances the rusting of metals in air, Sara To AS 1L4L IN Sus MATERIAL is RELEASED an AV%= IT%"Sttorrno tr,oEcrrmoDs NIA DDT 39 cylinders,uRR►E may not be reused or refilled (49CFR). "mEgA'°"L""1O0 NEVER transport these cylinders in trunks of vehicles, enclosed vans, truck cabs or In passenger compartments. Transport then 'contained' in open flatbed or open pick- up type vehicles. NIA ` Reporting under SARA, Title III, Section 313 not required. ENFAOENCY RESPONSE INFORAAATION I"CASE OF EMERGENCY INVOL"a TH LS MAiERIAL.CALL DAY OR NICHT 4800)2314359 OR CALL CNEYTRECAT(360)424-Ma0 w,r`r.tlia.. i4...aMf+- wm•D.r+w.arrr�.rors...nnras�.M...n.crn.rarrrwwwawaw -i_ E : -: i :: MATERIAL SAEETY DATA $HEED F.3735 GR€E1•f ROAD tELEPHO�tE j216j292 5000 EME#G:ENCIE.S (216)�69 672T 8 30 5 .0E7 .. BEACEiWOQb,X.0HI0412Z `> ATEEt H0UR5 CHErTREC (9Ca0}4Z4 930a: --------------=--------------------------------------------------------------------------------- SECTION I ------------------------------------------------------------------------------------------------ Order Code: 087500 516 Order Desc: 1 QT CN PRIMER NO. 6 5/E WT 2#EMERGENCY RESPONSE SHEET #26 Trade Name: PRIMER NO. 6 Code Number: 087-500-511, 087-500-516 Prepared By: C. R. Bruno Product Class: PRIMER Date: 7-Oct-1991 Additional Components: NONE Replaces: 1-Jun-1989 DOT Proper Shipping Name: COATING SOLUTION DOT Hazard Class: FLAMMABLE LIQUID TSCA Status..: OK DOT UN/NA Number: UN 1139 ------------------------------------------------------------------------------------------------ SECTION II - COMPOSITION / INFORMATION ON INGREDIENTS ------------------------------------------------------------------------------------------------ CHEMICAL or COMMON NAME i MAX. i EXPOSURE LIMITS CAS Number (symbols explained below) WT. %I TWA STEL -------------------------------------------------------------------------:----------------------- ETHYL ALCOHOL (ETHANOL) �80 OSHA 1000 ppm - 64-17-5 1 �ACGIH 1000 ppm - - ------------------------------------------------------------------------------------------------ ORGANOSILANE � 15 OSHA - - N/A # I �ACGIH - - ------------------------------------------------------------------------------------------------ WATER 5 1 OSHA - - 7732-18-5 iACGIH - - ------------------------------------------------------------------------------------------------ TOLUENE (METHYLBENZENE) 0.9 1 OSHA 100 ppm 150 ppm I 108-88-3 + I �ACGIH 50 ppm - (skin) --------------------------------------- -------------------------------------------------------- # - Specific chemical identity is being withheld as a trade secret. + - Specific chemical is listed in SARA-313; shown at typical percentage. WARNING: THIS PRODUCT CONTAINS CHEMICAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER OR BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM. SECTION III - PHYSICAL DATA -------------------------------------=---------------------------------------------------------- Weight/Gallon:6.8 # Vapor Pressure: 44 mmHg Melting Point:N/A Specific Gravity:0.82 Vapor Density (Air = 1) :>1 Boiling Point: 165 F pH (Aqueous): N/A Solubility in Water: Miscible Softening Point:N/A % Volatile By Wt: Max. 85 Evaporation Rate (ETHER=1) :>1 Freezing Point: N/A Physical State: Liquid Odor: Alcohol Color: Clear ------------------------------------------------------------------------------------------------ SECTION IV - FIRE AND EXPLOSION DATA Flash Point (F): 57 Method: PM cc LEL (Lower Explosion Limit): 3.3% UEL (Upper Explosion Limit) : Not Established Auto-ignition Temperature: Not Established Decomposition Temperature: Not Established Carbon dioxide, dry chemical , foam. UNUSUAL PRODUCTS OF IGNITION: N/A UNUSUAL FIRE AND EXPLOSION HAZARDS: Never use welding or cutting torch on or near container (even empty). Product, residue or vapor- may ignite. See section IX for additional precautions. SPECIAL FIREFIGHTING PROCEDURES: During a fire, personnel at the scene are to prevent exposure to fumes using accepted fire fighting techniques. ------------------------------------------------------------------------------------------------ SECTION V - HEALTH HAZARD DATA ------------------------------------------------------------------------------------------------ ROUTES OF ENTRY AND EFFECTS OF OVEREXPOSURE: EYE CONTACT - Can cause severe irritation, tearing, blurred vision. SKIN CONTACT - Can cause irritation, sensitization, dermatitis. SKIN ABSORPTION - Not established. INHALATION - 385 28000693 2 4X1 ��^i'fL�. ��2`'} ir� a,'o-^.-^'}y.3,,".F...r'7�a"2hsu'"",}`..7a1 .e":�"-"•'=d��3.+�,AS�'`�'his.�'tss' :3�rs3� ✓S,G�'";�^'r6�J�'rti-i4sti:�. S;�s"�', ,.^c%'%25'd�rr+" �'`t'C � 4`{ 4 Order Code: 087500 516 Page 602 Order Desc: 1 QT CN PRIMER NO. 6 5/E WT 2NEMERGENCY RESPONSE SHEET #26 Can cause headache, dizziness, nausea, drowsiness, stupor, irritation to respiratory system, central nervous system depression. INGESTION Can cause gastrointestinal i.rritation, vomiting and diarrhea. j EMERGENCY AND FIRST AID: IF ON SKIN - Clean area of contact thoroughly using soap and water. If irritation, rash or other disorders develop, get medical attention immediately. IF IN EYES - Flush immediately with running water for 15 minutes, lifting the upper and lower lids occasionaly. Get medical attention immediately. IF INGESTED - Do not induce vomiting. Get medical attention immediately. IF INHALED - Leave area to breathe fresh air. Avoid further overexposure. If symptoms persist, get medical attention immediately. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Respiratory allergies. Chronic diseases of the skin and eyes. POTENTIAL EFFECTS OF LONG-TERM OR CHRONIC EXPOSURE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling contents may be harmful or fatal .. OTHER HEALTH HAZARD DATA: Ethyl alcohol (denatured) caused kidney, liver and lung abnormalities, damage to eyes, cardiovascular and nervous systems in experimental animals. Ethyl alcohol may cause teratogenic effects based on animal data. Prolonged and repeated) overexposure to toluene caused liver and kidney damage in laboratory animals. Based on animal experiments, toluene may be a cardiac sensitizer and may cause birth defects or other reproductive abnormalities. ------------------------------------------------------------------------------------------------ SECTION VI - REACTIVITY DATA- -----------------------------------------------------------------------=------------------------ HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur. STABILITY: Stable INCOMPATABILITY: 4* Avoid contact with strong acids and bases, halogens, ammonia. � ----------------------------------------------------------------------------------------------- .`,r SECTION VII - SPILL OR LEAK PROCEDURES ----------------------------------------------------------------------------------------------- CLEAN-UP: Remove sources of ignition immediately. Ventilate to reduce the airborne contaminant concentration below the exposure limit in Section II of the MSDS. Absorb spill in sand, earth or other suitable material . Transfer .to DOT approved container for disposal . WASTE DISPOSAL METHOD: Subject to hazardous waste treatment, storage, and disposal requirements under RCRA. Recycle or incinerate waste at EPA approved facility or dispose of in compliance with federal , state and local regulations. EPA HAZARDOUS WASTE NUMBER: 0001 EPA REPORTABLE QUANTITY: 1000N NATIONAL EMERGENCY RESPONSE CENTER: 800-424-8802 OR 202-426-2675 ------------------------------------------------------------------------------------------------ SECTION VIII - PROTECTIVE EQUIPMENT TO BE USED ------------------------------------------------------------------------------------------------ VENTILATION: Use local exhaust when the general ventilation is not sufficient to keep the airborne contaminant concentration below the exposure limit in Section II of the MSDS. RESPIRATORY PROTECTION: Wear NIOSH/MSHA approved respirator as directed by the manufacturer when the airborne contaminant level (s) exceed the exposure limits indicated in Section II. SKIN PROTECTION: Protect hands with nitrile gloves. Prevent contact with skin. Gloves must be checked before each use for signs of degradation and penetration and for proper functioning. EYE PROTECTION: Chemical splash goggles. FACE PROTECTION: Face shield is recommended. OTHER PROTECTIVE EQUIPMENT: Typical full cover' clothing. --------------------------------------------------------------------------------------------- '--- SECTION IX - SPECIAL PRECAUTIONS OR OTHER COMMENTS ------------------------------------------------------------------------------------------------ STORAGE, HANDLING AND APPLICATION: Store in closed container below 80F. Keep liquid and: vapor away from heat, sparks and flame. Do not store in direct sunlight. Prevent inhalation of vapor, ingestion, and contact with skin and 386 28000693 3 Order Code: 087500 516 Page 003 Order Desc: 1 QT CN PRIMER NO. 6 5/E WT 2#EMERGENCY RESPONSE SHEET #26 t eyes. Keep container closed when not in use. Vapor may migrate to sources of ignition. Do not smoke, weld, generate sparks, or use flame near container. Change soiled workclothes frequently. ` Clean hands thoroughly after handling. PRECAUTIONS FOR REPAIR AND MAINTANENCE OF CONTAMINATED EQUIPMENT: Personal protective equipment must be worn during maintanence or repair of contaminated mixer, reactor, or other equipment. OTHER: To prevent generation of static discharges, use bonding/grounding connection when pouring liquid. Extinguish all ignition sources including pilot lights, non-explosion proof motors and electrical equipment until vapors dissipate. Precautions also apply to emptied. containers. FOR INDUSTRIAL USE ONLY. KEEP OUT OF REACH OF CHILDREN. THE HAZARD INFORMATION HEREIN IS 'OFFERED SOLELY FOR THE CONSIDERATION OF THE USER, SUBJECT TO HIS OWN INVESTIGATION AND VERIFICATION OF COMPLIANCE WITH APPLICABLE REGULATIONS, INCLUDING THE SAFE USE OF THE PRODUCT UNDER EVERY FORESEEABLE CONDITION. CODE NUMBER: 087-500-511 MSDS ISSUE DATE: 7-Oct-1991 387 28000.693 4 I CHESTERTONO MATERIAL SAFETY DATA SHEET 1. A.W. CHES I ER TON COMPANY 225 Fallon Road, Middlesex Industrial Park 617-438-7000 (Day) Emergency Telephone Nos. Stoneham, MA 02180-2999 U.S.A. 617-438-7 13(Night) Section I HAZARDOUS MATERIALS IDENTIFICATION SYSTEM(HMIS) Date of Prep. July 1, 1991 4-Severe Hazard HEALTH 1 3=Serious Hazard FLAMMABILITY 1 MSDS No. 175-7 2=Moderate Hazard 1 =Slight Hazard REACTIVITY 1 Product Name 723 Sprasolvo® 0=Minimal Hazard Personal Protection •-See Section Vill-Special Protection Information General Use and Precautionary Information Penetrating oil frees nuts,bolts,fittings,without injury to base metal. Petroluem Base Lubricant(OSHA PEL:5 mg/ms-oil mist).As with any organic solvent base product,care should be taken to avoid excessive inhalation of vapors.This is especially important in enclosed areas with poor ventilation.Avoid keeping the skin continually wet with this product.Occasional skin contact should not be damaging,but repeated or prolonged contact may defat the skin and possibly cause dermatitis.Since this product is combustible,avoid using near ignition sources and hot surfaces. I _ Section 11-HAZARDOUS INGREDIENTS Ingred/ents/Sjmon s v CAS No. %Wt. mm %m9 PrAirCe m L7 Vapor Pressure i Stoddard Solvent 8052-41-3 455W 100 525 100 525 .. <10 mm Hg Carbon Dioxide 124-38-9 1-5 10000 18000 5000 9000 >760 mm Hg STEL 30000 54000 r Section IIA- OTHER INGREDIENTS on the EPA LIST OF TOXIC CHEMICALS None x Material marked contains or is a toxic chemical(s),subject to the reporting require- merits of section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1966 and 40 CFR Part 372. Section III-PHYSICAL DATA Iniflei Bolding Point 156-C(313°F) Percent Volatile(by volume) 50 Vapor Density >1 Evaporation Rate <1 Weight Per Gallon 6.9 Ibs (0,83 kgM (Aire 1) (Ether=1) Section IV-FIRE AND EXPLOSION DATA Flesh Point 49°C(120°F)Closed Cup LEL 0.9% DOT Shipping NameCn' PP 9 mpressed Gas, n.o.s.' DOT Hazard Class Nonflammable Gas DOT UNWA# UN 1956 Carbon Dioxide Extingu/sl Ing Media Carbon Dioxide,dry chemical, foam or water spray. 'Note:Shipped as Consumer Commodity, ORM-D in packaging havingg a rated capacity gross weight of 65 lbs. or less.(49 CFR 173.1200). Unusual ire and Explosion Hazards Pressurized containers when heated area potential explosive hazard. Special Fire Fighting Procedures Cool exposed containers with water. Recommend Firefighters wear self-contained breathing apparatus. OA.w.cHesTERToN co.,icier An Rights Reserved. AReg.U.S.PatJ and T.M.Off. Product Name: 723 S rasolvo® Date: July 1 1991 Section V—REACTIVITY DATA Stability Stable Conditions to Avoid Open flames and red hot surfaces. Hazardous Decomposition Products Carbon Monoxide, aldehydes and other toxic fumes. T`'1 Materials to Avoid Strong oxidizers like liquid Chlorine and Hazardous Polymerization concentrated Oxygen. p May Occur M WIII Not Occur Section VI—HEALTH HAZARD DATA Primary Route of Exposure Under Normal Use Inhalation,skin and eye contact. Acute Effects Direct eye contact may result in eye irritation. Inhalation of vapor concentrations in excess of 1000 ppm may result in dizziness, headache and other central nervous system effects. This vapor concentration may also irritate the eyes and respiratory tract. Chronic Effects Prolonged or repeated skin contact may cause skin irritation and may defat skin. As per CFR 1910.1200(Hazard Communication),there are NO carcinogens in this product as listed in the National Toxicology Program(NTP),the International Agency for.Research on Cancer(IARC)or the Occupational Safety and Health Administration(OSHA). Emergency and First Aid Procedures Inhalation. Remove to fresh air. If not breathing,administer artificial respiration. Contact physician. Eye/Skin Contact Wash skin with soap and water. Flush eyes for at least 15 minutes with large amounts of water.Contact physician if Irritation persists. Ingestion Do not induce vomiting.Contact physician immediately. Section VII —SPILL OR RELEASE PROCEDURESt Steps to be Taken In Case Material is Spilled or Released Evacuate area. Provide adequate ventilation.Contain spill to a small area. Flush away from ignition sources with water. Pick up with absorbent material(e.g., sand,sawdust,clay, etc.)and transfer to a suitable container for disposal. Keep out of sewers,streams and waterways. Waste Disposal Method Incinerate absorbed material. Do not incinerate sealed or pressurized containers.Bury containers in an approved area. Check local,state and federal regulations. Section Vlll—SPECIAL PROTECTION INFORMATION Respiratory Protection Not normally needed. If PEVTLV is exceeded, Protectfve Gloves Not nbrmally needed. use approved organic vapor respirator. Eye Protection Safety goggles. Ventilation No special requirements. If PEL/TLV is exceeded,provide adequate ventilation. Other None Section IX—SPECIAL PRECAUTIONS Precautions In Handing and Storing Do not store in direct sunlight or above 490C(1200F). Other Precautions None The Information contained herein Is based on data provided from suppliers of the materials used and not on the mixture itself, and Is believed to be correct. However, no warranty Is expressed or Implied regarding the accuracy of the data. Since the information contained herein may be applied under conditions beyond our control, the persona receiving it shall make their own determination of the suitability of the product for their particular purposes. OSHA 29 CFR Parts 1910.1200,1915.90, 1917.28,1918.90,1926.59 and 1928 MA 441 CMR 21.06 SODIUM THIOSULFATE SOLUTI PAGE 01 OF 03 SODIUM THIOSULFATE SOLUTI SODIUM THIOSULFATE SOLUTI SODIUM THIOSULFATE SOLUTI MATERIAL SAFETY DATA SHEET - ---------------------------------------------------------------------------- FISHER SCIENTIFIC EMERGENCY CONTACTS: DATE: 02/03/89 CHEMICAL DIVISION GASTON L. PILLORI PO NBR: 134F758 1IREAGENT LANE (201) 796-7100 ACCT: 119886-01 FAIR LAWN NJ 074F10 INDEX: 10890300267 (201) 796-7100 CAT NO: SS361F1 TIE INFORMATION BELOW IS BELIEVED TO BE ACCURATE AND REPRESENTS THE BEST INFORMATION CURRENTLY AVAILABLE TO US. HOWEVER, WE MAKE NO WARRANTY OF MERCHANTABILITY OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, WITH RESPECT TO SUCH INFORMATION, AND WE ASSUME NO LIABILITY RESULTING FROM ITS USE. USERS SHOULD MAKE THEIR OWN INVESTIGATIONS TO DETERMINE THE SUITABILITY OF THE IN FOR THEIR PARTICULAR PURPOSES. SUBSTANCE IDENTIFICATION CAS-NUMBER NOT SUBSTANCE: SODIUM THIOSULFATE SOLUTIONS 0. 025N TO 1N TRADE NAMES/SYNONYMS: ISS-368; SS-369; SS-3.70; SS-371; AC04F0182 MOLECULAR FORMULA: MIXTURE CERCLA RATINGS (SCALE 0-3): HEALTH=U FIRE=O REACTIVITY=O NFPA RATINGS (SCALE 0-'F): HEALTH=U FIRE=O REACTIVITY=O ----------------------------------------------------------------------------- COMPONENTS AND CONTAMINANTS COMPONENT: SODIUM THIOSULFATE PENTAHYDRATE PERCENT: 0. 6 - 21. 0 j CAS# 10102-17-7 f COMPONENT: TETRASODIUM ETHYLENEDIAMINE TETRAACETATE PERCENT: 0. 03 CAS# 64F-02-8 COMPONENT: WATER PERCENT: 79. 0-99. 'F OTHER CONTAMINANTS: NONE EXPOSURE LIMITS: NO OCCUPATIONAL EXPOSURE LIMITS ESTABLISHED BY OSHA, ACGIH, OR NIOSH. _ ---------------------- ------------------------------------- PHYSICAL DATA DESCRIPTION: COLORLESS LIQUID BOILING POINT: 212 F (100 C) MELTING POINT: 32 F CO C,) SPECIFIC GRAVITY: 1. 0 - 1. 1 ViPOR PRESSURE: 1'F MMHG (WATER) EVAPORATION RATE:. .(ETHER=1) >1 SOLUBILITY IN WATER: COMPLETE - --------------------- ------___- -_------------- ----_ FIRE AND EXPLOSION DATA FIRE AND EXPLOSION HAZARD: NEGLIGIBLE FIRE HAZARD WHEN EXPOSED TO HEAT OR FLAME. FLASH POINT: NOT COMBUSTIBLE FIREFIGHTING MEDIA: , DRY CHEMICAL, CARBON DIOXIDE, HALON, WATER SPRAY OR STANDARD FOAM (1987 EMERGENCY RESPONSE GUIDEBOOK, DOT P 5800. 4-). FOR LARGER FIRES, USE WATER SPRAY, FOG OR STANDARD FOAM (1987 EMERGENCY RESPONSE GUIDEBOOK, DOT P 5800. 4F). FIREFIGHTING: NO ACUTE HAZARD. MOVE CONTAINER FROM FIRE AREA IF POSSIBLE. AVOID BREATHING VAPORS OR DUSTS; KEEP UPWIND. - --------------- TOXICITY SODIUM THIOSULFATE PENTAHYDRATE: 300 MG/KG/7 DAYS ORAL-HUMAN TDLO; 5600 MG/KG INTRAPERITONEAL-MOUSE LD50; 3000 MG/KG INTRAVENOUS-DOG LDLO; CARCINOGEN STATUS: NONE. ISODIUM THIOSULFATE IS AN EYE, SKIN, AND .MUCOUS MEMBRANE IRRITANT. LARGE DOSES HAVE A CATHARTIC ACTION. j -------------------- - I ------------------------------ HEALTH EFFECTS AND FIRST AD INHALATION: IRRITANT. ACUTE EXPOSURE- SODIUM THIOSULFATE: MAY CAUSE COUGHING, RESPIRATORY TRACT IRRITATION, DYSPNEA, AND PULMONARY EDEMA. CHRONIC EXPOSURE- SODIUM THIOSULFATE: REPEATED OR PROLONGED CONTACT MAY � �e SODIUM THIOSULFATE SOLUTI PAGE 02 OF 03 CAUSE MUCOUS MEMBRANE IRRITATION, FIRST AID- REMOVE FROM EXPOSURE AREA TO FRESH AIR IMMEDIATELY, IF BREATHING HAS STOPPED, GIVE ARTIFICIAL RESPIRATION, KEEP AFFECTED PERSON WARM AND AT REST. GET MEDICAL ATTENTION IMMEDIATELY, SKIN CONTACT: IRRITANT. ACUTE EXPOSURE- SODIUM THIOSULFATE: MAY CAUSE IRRITATION AND PAIN, CHRONIC EXPOSURE- SODIUM THIOSULFATE: MAY CAUSE DERMATITIS. FIRST AID- REMOVE CONTAMINATED CLOTHING AND SHOES IMMEDIATELY, WASH AFFECTED AREA WITH SOAP OR MILD DETERGENT AND LARGE AMOUNTS OF WATER UNTILNO. EVIDENCE OF CHEMICAL REMAINS (APPROXIMATELY 15-20 •MINUTES). GET MEDICAL ATTENTION, EYE CONTACT: IRRITANT, ACUTE EXPOSURE- SODIUM THIOSULFATE: MAY CAUSE REDNESS, PAIN, AND IRRITATION. CHRONIC EXPOSURE- SODIUM THIOSULFATE: MAY CAUSE CONJUNCTIVITIS, FIRST AID- WASH EYES IMMEDIATELY WITH LARGE AMOUNTS OF WATER, OCCASIONALLY LIFTING THE UPPER AND LOWER LIDS, UNTIL NO EVIDENCE OF CHEMICAL REMAINS CAPPROXIMATELY 10-20 MINUTES), GET MEDICAL ATTENTION, INGESTION: ACUTE EXPOSURE- SODIUM THIOSULFATE: MAY CAUSE SORE THROAT; COUGHING, NAUSEA, AND ABDOMINAL PAIN, CHRONIC EXPOSURE- SODIUM THIOSULFATE: NONE KNOWN IN HUMANS, FIRST AID- IF VICTIM IS CONSCIOUS, IMMEDIATELY GIVE 2 TO 4- GLASSES OF WATER, AND INDUCE VOMITING BY TOUCHING FINGER TO BACK OF THROAT, GET MEDICAL ATTENTION IMMEDIATELY, ANTIDOTE: NO SPECIFIC ANTIDOTE, TREAT SYMPTOMATICALLY AND SUPPORTIVELY, ---------- ---------------- REACTIVITY REACTIVITY: STABLE UNDER NORMAL TEMPERATURES AND PRESSURES. {`r INCOMPATIBILITIES: SODIUM THIOSULFATE: METAL NITRATES- VIOLENT EXPLOSION MAY OCCUR WHEN HEATED, SODIUM NITRATE- VIOLENT EXPLOSION MAY OCCUR WHEN HEATED TO DRYNESS, CHLORINE SOLUTION- FORMS COMBUSTIBLE SODIUM HYDROSULFATE, N CONTACT WITH ACIDS, ACIDS- MAY RELEASE TOXIC AND HAZARDOUS HYDROGEN SULFIDE,. DECOMPOSITION: MAY RELEASE TOXIC AND .HAZARDOUS SODIUM OXIDE, AND SULFUR OXIDES UNDER THERMAL DECOMPOSITION, POLYMERIZATION: HAZARDOUS POLYMERIZATION HAS NOT BEEN REPORTED TO OCCUR UNDER NORMAL TEMPERATURESscAND PRESSURES, 7K�cXt�lcxc�cXtzcxc�xxc7tc�Xxc�lcxf�xxc�xxc�xrx�x�xc�xcxc�x�xcz��x�7xxcxc�wckerac�m��c�c�xc��cxc��3x�cmxc�xx:m�cYxxc�xm�xcxc��xxc�zc�c��*xc CONDITIONS TO AVOID NO REPORTS FOUND, IK�Nt�fJ9(3XX(�fkt%(�fX(]XaY7i(l9(79��C7K7a7Kkc��Xf7ffXfY.tMf)KlK)k%t�i�f7kXC�fbfXfYltNl7k%t7k7K��Y8c�(7K%C�t��f�xC%tJKIKlKYd7$k(JK7KXf70(���7�f.Of�fkf7K7KXt SPILL AND LEAK PROCEDURES OCCUPATIONAL SPILL: COVER WITH SODA ASH, SCOOP UP AND PLACE IN A SUITABLE CONTAINER. ------ ---------------------------------- PROTECTIVE EQUIPMENT VENTILATION: PROVIDE LOCAL EXHAUST OR GENERAL DILUTION VENTILATION SYSTEM. RESPIRATOR: HIGH LEVELS- SUPPLIED-AIR RESPIRATOR WITH A FULL FACEPIECE, HELMET, OR HOOD. SELF-CONTAINED BREATHING APPARATUS WITH A FULL FACEPIECE. FIREFIGHTING- SELF-CONTAINED BREATHING APPARATUS WITH A-FULL FACEPIECE OPERATED IN PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE MODE, CLOTHING: EMPLOYEE MUST WEAR APPROPRIATE PROTECTIVE CIMPERVIOUS) CLOTHING AND EQUIPMENT TO PREVENT REPEATED OR PROLONGED SKIN CONTACT WITH THIS SUBSTANCE, GLOVES: ddd EMPLOYEE MUST WEAR APPROPRIATE PROTECTIVE GLOVES TO PREVENT CONTACT WITH THIS SUBSTANCE, EYE PROTECTION: EMPLOYEE MUST WEAR SPLASH-PROOF OR DUST-RESISTANT SAFETY GOGGLES AND A FACESHIELD TO PREVENT CONTACT WITH THIS SUBSTANCE, CONTACT LENSES SHOULD NOT 0 � BE WORN, SODIUM THIOSULFATE SOLUTI PAGE 03 OF 03 EMERGENCY WASH FACILITIES: WHERE THERE IS ANY POSSIBILITY THAT AN EMPLOYEE'S EYES AND/OP, SKIN MAY BE EXPOSED TO THIS SUBSTANCE, THE EMPLOYER SHOULD PROVIDE AN EYE WASH FOUNTAIN AND QUICK DRENCH SHOWER WITHIN THE IMMEDIATE WORK AREA FOR EMERGENCY USE, AUTHORIZED - FISHER SCIENTIFIC GROUP, INC, CREATION DATE: 07/22/85 REVISION DATE: 05/27/88 -ADDITIONAL INFORMATION- THE INFORMATION BELOW IS BELIEVED TO BE ACCURATE AND REPRESENTS THE BEST INFORMATION CURRENTLY AVAILABLE TO US, HOWEVER, WE MAKE NO WARRANTY OF MERCHANTABILITY OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, WITH RESPECT TO SUCH INFORMATION, AND WE ASSUME NO LIABILITY RESULTING FROM ITS USE, USERS SHOULD MAKE THEIR OWN INVESTIGATIONS TO DETERMINE THE SUITABILITY OF THE INFORMATION FOR .THEIR PARTICULAR PURPOSES, 45 � � e Cl PAGE: 1 PAGE: 2 DATE: 04/09/92 ACCT: 119886-01 DATE: 04/09/92 ACCT: 119886-01 INDEX: 04921001220 CAT NO: S514 PO NBR: 220846 INDEX: 04921001220 CAT NO: S514 PO NBR: 220846 **STARCH** TOXICITY --------**S-T-ARCH**- - --- -- - ----- ---- ------- -- -- - - **STARCH** STARCH: IRRITATION DATA: 300 UG/3 DAYS INTERMITTENT SKIN-HUMAN MILD. MATERIAL SAFETY DATA SHEET TOXICITY DATA: 6600 MG/KG INTRAPERITONEAL-MOUSE LD50. ------------------------------------------------------------------------------ CARCINOGEN STATUS: NONE. ACUTE TOXICITY LEVEL: INSUFFICIENT DATA. FISHER SCIENTIFIC EMERGENCY NUMBER: (201) 796-7100 TARGET EFFECTS: NUISANCE DUST. CHEMICAL DIVISION CHEMTREC ASSISTANCE: (800) 424-9300 AT INCREASED RISK FROM EXPOSURE: PERSONS WITH PULMONARY DYSFUNCTION. 1 REAGENT LANE FAIR LAWN NJ 07410 --------------- (201) 796-7100 HEALTH EFFECTS AND FIRST AID THIS INFORMATION IS BELIEVED TO BE ACCURATE AND REPRESENTS THE BEST INHALATION: INFORMATION CURRENTLY AVAILABLE TO US. HOWEVER, WE MAKE NO WARRANTY OF STARCH: MERCHANTABILITY OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, WITH RESPECT TO NUISANCE DUST. SUCH INFORMATION, AND WE ASSUME NO LIABILITY RESULTING FROM ITS USE. USERS ACUTE EXPOSURE- HIGH CONCENTRATIONS MAY CAUSE UNPLEASANT DEPOSITS IN THE SHOULD MAKE THEIR OWN INVESTIGATIONS TO DETERMINE THE SUITABILITY OF THE NASAL PASSAGES. INFORMATION FOR THEIR PARTICULAR PURPOSES. CHRONIC EXPOSURE- REPEATED OR PROLONGED EXPOSURE MAY POSSIBLY CAUSE CHEMICAL PNEUMONITIS. ------------------------------------------------------------------------------ SUBSTANCE IDENTIFICATION FIRST AID- REMOVE FROM EXPOSURE AREA TO FRESH AIR IMMEDIATELY. IF BREATHING CAS-NUMBER 9005-25-8 HAS STOPPED, PERFORM ARTIFICIAL RESPIRATION.- KEEP PERSON WARM AND AT REST. SUBSTANCE: **STARCH** _ TREAT SYMPTOMATICALLY AND SUPPORTIVELY. GET MEDICAL ATTENTION IMMEDIATELY. TRADE NAMES/SYNONYMS: CORN STARCH; AMYLUM; ARROWROOT STARCH; POTATO STARCH; RICE STARCH; SKIN CONTACT; ALPHA-STARCH; S-510; S676; S-513; S-514; S-516; ACC21875 STARCH: ACUTE EXPOSURE- HIGH CONCENTRATIONS MAY CAUSE UNPLEASANT DEPOSITS ON THE CHEMICAL FAMILY: SKIN. INJURY MAY OCCUR BY CHEMICAL OR MECHANICAL ACTION OR BY POLYSACCHARIDE - RIGOROUS SKIN CLEANSING PROCEDURES NECESSARY FOR REMOVAL OF THE DUST. CHRONIC EXPOSURE- REPEATED AND PROLONGED CONTACT MAY CAUSE MILD IRRITATION. MOLECULAR FORMULA: (C6-H10-05)X - DERMATITIS HAS BEEN REPORTED IN WORKERS HANDLING STARCH PRODUCTS. STARCH IS METABOLIZED BY MICROORGANISMS ON THE SKIN WHICH MAY RESULT CERCLA RATINGS (SCALE 0-3): HEALTH=1 FIRE=1 REACTIVITY=O PERSISTENCE=O IN OVERGROWTH OF CANDIDA. STARCH DUST HAS BEEN REPORTED TO HAVE SLIGHT NFPA RATINGS (SCALE 0-4): HEALTH=U FIRE=1 REACTIVITY=O ALLERGENIC PROPERTIES. ------------------------------------------------------------------------------ ..COMPONENTS AND CONTAMINANTS FIRST AID- REMOVE CONTAMINATED CLOTHING AND SHOES IMMEDIATELY. WASH AFFECTED AREA WITH SOAP OR MILD DETERGENT AND LARGE AMOUNTS OF WATER UNTIL NO COMPONENT: STARCH PERCENT: 100.0 EVIDENCE OF CHEMICAL REMAINS (APPROXIMATELY 15-20 MINUTES). GET MEDICAL CAS# 9005-25-8 ATTENTION IMMEDIATELY. OTHER CONTAMINANTS: NONE. EYE CONTACT: STARCH: EXPOSURE LIMITS: ACUTE EXPOSURE- HIGH CONCENTRATIONS MAY CAUSE IRRITATION AND UNPLEASANT NUISANCE PARTICULATES (NUISANCE DUST): DEPOSITS IN THE EYES AND SERIOUSLY REDUCE VISIBILITY. INSTILLATION 5 MG/M3 OSHA TWA (RESPIRABLE DUST); 15 MG/M3 OSHA TWA (TOTAL DUST) INTO THE ANTERIOR CHAMBER OF RABBIT EYES PRODUCED GRANULOMATOUS 10 MG/M3 ACGIH TWA (TOTAL DUST) (NO ASBESTOS AND < 1% CRYSTALLINE SILICA) REACTIONS. CHRONIC EXPOSURE- NO DATA AVAILABLE. ------------------------------------------------------------------------------ PHYS_ICAL DATA FIRST AID- WASH EYES IMMEDIATELY WITH LARGE AMOUNTS OF WATER OR NORMAL SALINE, OCCASIONALLY LIFTING UPPER AND LOWER LIDS, UNTIL NO EVIDENCE OF CHEMICAL DESCRIPTION: ODORLESS, IRREGULAR, ANGULAR, WHITE MASSES OR FINE POWDER, WITH REMAINS (APPROXIMATELY 15-20 MINUTES). GET MEDICAL ATTENTION IMMEDIATELY. A SLIGHT, CHARACTERISTIC TASTE. MELTING POINT: DECOMPOSES INGESTION: STARCH: SPECIFIC GRAVITY: NOT AVAILABLE PH: 4.5-6.0 @ 2% SOLN ACUTE EXPOSURE- ORAL ADMINISTRATION TO RATS AT A LEVEL OF 10-20% OF THEIR TOTAL BODY WEIGHT CAUSED ONLY MINIMAL SYMPTOMS. SOLVENT SOLUBILITY: INSOLUBLE IN ALCOHOL, CHLOROFORM, ETHER. CHRONIC EXPOSURE- REPEATED OR PROLONGED INGESTION OF VERY LARGE DOSES MAY CAUSE PARTIAL INTESTINAL OBSTRUCTION, IRON DEFICIENCY ANEMIA, WATER SOLUBILITY: INSOLUBLE IN COLD; SOLUBLE IN BOILING REDUCED CHOLESTEROL, AND POSSIBLY HYPERTROPHY OF THE PAROTID GLANDS. ----------=------------------------------------------------------------------- FIRST AID- TREAT SYMPTOMATICALLY AND SUPPORTIVELY. GET MEDICAL ATTENTION FIRE AND EXPLOSION DATA IMMEDIATELY. IF VOMITING OCCURS, KEEP HEAD LOWER THAN HIPS TO PREVENT ASPIRATION. FIRE AND EXPLOSION HAZARD: - SLIGHT FIRE HAZARD WHEN EXPOSED TO HEAT OR FLAME. ANTIDOTE: NO SPECIFIC ANTIDOTE. TREAT SYMPTOMATICALLY AND SUPPORTIVELY. DUST-AIR MIXTURES MAY IGNITE OR EXPLODE. -------------------------------------------------------------------"---------- AUTOIGNITION TEMP.: >716 F (>380 C) (CLOUD) REACTIVITY FIREFIGHTING MEDIA: REACTIVITY: DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY OR REGULAR FOAM STABLE UNDER NORMAL TEMPERATURES AND PRESSURES. (1990 EMERGENCY RESPONSE GUIDEBOOK, DOT P 5800.5). INCOMPATIBILITIES: FOR LARGER FIRES, USE WATER SPRAY, FOG OR REGULAR FOAM STARCH: (1990 EMERGENCY RESPONSE GUIDEBOOK, DOT P 5800.5). OXIDIZERS (STRONG): FIRE AND EXPLOSION HAZARD. FIREFIGHTING: DECOMPOSITION: MOVE CONTAINER FROM FIRE AREA IF YOU CAN DO IT WITHOUT RISK. DO NOT SCATTER THERMAL DECOMPOSITION MAY RELEASE TOXIC AND/OR HAZARDOUS GASES. SPILLED MATERIAL WITH HIGH-PRESSURE WATER STREAMS. DIKE FIRE-CONTROL WATER FOR LATER DISPOSAL (1990 EMERGENCY RESPONSE GUIDEBOOK, DOT P 5800.5, GUIDE POLYMERIZATION: PAGE 31). HAZARDOUS POLYMERIZATION HAS NOT BEEN REPORTED TO OCCUR UNDER NORMAL TEMPERATURES AND PRESSURES. USE AGENTS SUITABLE FOR TYPE OF SURROUNDING FIRE. AVOID BREATHING HAZARDOUS VAPORS, KEEP UPWIND. ------------------------------------------------------------------------------ STORAGE AND DISPOSAL PAGE: 3 DATE: 04/09/92 ACCT: 119886-01 INDEX: 04921001220 CAT N0: S514 PO NBR: 220846 OBSERVE ALL FEDERAL, STATE AND LOCAL REGULATIONS WHEN STORING OR DISPOSING OF THIS SUBSTANCE. FOR ASSISTANCE, CONTACT THE DISTRICT DIRECTOR OF THE ENVIRONMENTAL PROTECTION AGENCY. STORAGE** KEEP KEEP IN A TIGHTLY CLOSED CONTAINER. STORE IN A COOL, DRY, VENTILATED AREA. STORE AWAY FROM INCOMPATIBLE SUBSTANCES. - CONDITIONS TO AVOID MAY BURN BUT DOES NOT IGNITE READILY. AVOID CONTACT WITH STRONG OXIDIZERS, EXCESSIVE HEAT, SPARKS, OR OPEN FLAME. SPILL AND LEAK PROCEDURES OCCUPATIONAL SPILL: SWEEP UP AND PLACE IN SUITABLE CLEAN, DRY CONTAINERS FOR RECLAMATION OR LATER DISPOSAL. DO NOT FLUSH SPILLED MATERIAL INTO SEWER. KEEP UNNECESSARY PEOPLE AWAY. ------------------------------------------------------------------------------ PROTECTIVE EQUIPMENT VENTILATION: PROVIDE LOCAL EXHAUST VENTILATION TO MEET PUBLISHED EXPOSURE LIMITS. VENTILATION EQUIPMENT MUST BE EXPLOSION-PROOF. RESPIRATOR: THE FOLLOWING RESPIRATORS ARE RECOMMENDED BASED ON INFORMATION FOUND IN THE PHYSICAL DATA, TOXICITY AND HEALTH EFFECTS SECTIONS. THEY ARE RANKED IN - ORDER FROM MINIMUM TO MAXIMUM RESPIRATORY PROTECTION. THE SPECIFIC RESPIRATOR SELECTED MUST BE BASED ON CONTAMINATION LEVELS FOUND IN THE WORK PLACE, MUST BE BASED ON THE SPECIFIC OPERATION, MUST NOT EXCEED THE WORKING LIMITS OF THE RESPIRATOR AND MUST BE JOINTLY APPROVED BY THE NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY AND HEALTH AND THE MINE SAFETY AND HEALTH ADMINISTRATION (NIOSH-MSHA). ANY DUST AND MIST RESPIRATOR. ANY AIR-PURIFYING RESPIRATOR WITH A HIGH-EFFICIENCY PARTICULATE FILTER. ANY POWERED AIR-PURIFYING RESPIRATOR WITH A DUST AND MIST FILTER.. ANY POWERED AIR-PURIFYING RESPIRATOR WITH A HIGH-EFFICIENCY PARTICULATE i FILTER. I ANY TYPE 'C' SUPPLIED-AIR RESPIRATOR OPERATED IN THE PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE OR CONTINUOUS-FLOW MODE. ANY SELF-CONTAINED BREATHING APPARATUS. FOR FIREFIGHTING AND OTHER IMMEDIATELY DANGEROUS TO LIFE OR HEALTH CONDITIONS: '�- ANY SELF-CONTAINED BREATHING APPARATUS THAT HAS A FULL FACEPIECE AND IS OPERATED IN A PRESSURE-DEMAND OR OTHER POSITIVE-PRESSURE MODE. ti- ANY SUPPLIED-AIR RESPIRATOR THAT HAS A FULL FACEPIECE AND IS OPERATED IN A IN - PRESSURE-DEMAND-OR OTHER POSITIVE-PRESSURE MODE IN COMBINATION WITH AN - ±j AUXILIARY SELF-CONTAINED BREATHING APPARATUS OPERATED IN PRESSURE-DEMAND OR OTHER POSITIVE-PRESSURE MODE. CLOTHING: PROTECTIVE CLOTHING NOT REQUIRED. AVOID REPEATED OR PROLONGED CONTACT WITH THIS SUBSTANCE. GLOVES: ` PROTECTIVE GLOVES ARE NOT REQUIRED BUT RECOMMENDED. : EYE PROTECTION: EYE PROTECTION NOT REQUIRED, BUT ADVISABLE. AUTHORIZED - FISHER SCIENTIFIC, INC. CREATION DATE: 01/18/85 REVISION DATE: 02/12/92 -ADDITIONAL INFORMATION- THIS INFORMATION IS BELIEVED TO BE ACCURATE AND REPRESENTS THE BEST INFORMATION CURRENTLY AVAILABLE TO US. HOWEVER, WE MAKE NO WARRANTY OF MERCHANTABILITY OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, WITH RESPECT TO SUCH INFORMATION, AND WE ASSUME NO LIABILITY RESULTING FROM ITS USE. USERS ii SHOULD MAKE THEIR OWN INVESTIGATIONS TO DETERMINE TH9 SUITABILITY OF THE INFORMATION FOR THEIR PARTICULAR PURPOSES. i 1 I � c7•�`'S ` 8::.�' -'"<.E;�:1�5 '.. ,e ',d.th's. {_n,�s=.r,�'�is'�b.\-`.'�:.:i� --�.i2' .�,' `3ri3r:.�'}s� _, "y ..",2`.a,�, 4',-t "-,., .N' Page: 1 MATERIAL SAFETY DATA SHEET 07/31/92 For Coatings, Resins and Related Materials Prepared: 01/29/92 SECTION I - PRODUCT INDENTIFICATION ------------------------- Manufacturer: STRUKTOL COMPANY OF AMERICA Information Phone: 216-928-5188 P.O. BOX 1649 Emergency Phone: 800-424-9300 201 E. STEELS CORNERS ROAD CHEMTREC Phone: (800) 424-9300 STOW OH 44224 ! Hazard Ratings: Health - 0 Product Class: ANTIFOAM ! none -> extreme Fire - 1 Trade Name : STRUKTOL SBA 2080 ! 0 ---> 4 Reactivity - 0 Product Code : SBA2080 ! C.A.S. Number: PROPRIETARY MIXTURE ! Personal Protection - B Prepared. By. : DONALD BENEDETTI Title : REGULATORY COMPLIANCE MANAGER D.O.T. Hazard Class ID #: Proper Shipping Name: NMFC 50140, SUB 1 SECTION II - HAZARDOUS INGREDIENTS Weight --- Exposure Limits ---- VP Ingredients CAS # % ACGIH/TLV OSHA/PEL mm HG *** ALL Ingredients in this product are listed in the T.S.C.A. Inventory. (No hazardous ingredients known at this time. ) SECTION III - PHYSICAL DATA ----------------------------------- Boiling Range: 100 - 285 Deg. C Vapor Density: Non Volatile Evap. Rate: 0.0 x n-Butyl Acetate Liquid Density: Same as Water. Volatiles volume: 0.1 % Wgt per gallon: 8. 33 Pounds. Spec. Gravity: 1. 00 Appearance: WHITE SUSPENSION V.'O.C. : NONE SECTION IV - FIRE AND EXPLOSION HAZARD DATA ---------------------------------------- Flammability Class: IIIB Flash Point: 103 C pmcc LEL: NONE -EXTINGUISHING MEDIA: CO2,FOAM,DRY CHEMICAL,WATER SPRAY -SPECIAL FIREFIGHTING PROCEDURES: USE SELF CONTAINED BREATHING APPARATUS -UNUSUAL FIRE & EXPLOSION HAZARDS: NONE SECTION= V==- HEALTH HAZARD DATA=====__________________ ------------------------------------------------------------------------------- -PERMISSIBLE' EXPOSURE LEVEL: i i i Page: 2 STRUKTOL COMPANY OF AMERICA Material Safety Data Sheet for: STRUKTOL SBA 2080 (SBA2080) ------------------------- SECTION V - HEALTH HAZARD DATA (cont. ) -------------------------------------------------------------------------------- -EFFECTS OF OVEREXPOSURE: PROLONGED OR REPEATED EXPOSURE MAY CAUSE MINOR EYE AND/OR SKIN IRRITATION. -FIRST AID: EYES: FLUSH WITH RUNNING WATER FOR AT LEAST 15 MINUTES. IF IRRITATION OCCURS OR PERSISTS, CONSULT A PHYSICIAN. SKIN: WASH WITH SOAP AND WATER. INHALATION: REMOVE TO FRESH AIR. IF RESPIRATORY IRRITATION OCCURS OR PERSISTS, CONSULT A PHYSICIAN. INGESTION: DO NOT INDUCE VOMITING. CALL A PHYSICIAN. ------------------------ SECTION VI - REACTIVITY DATA ------------------------------------------------------------------------------- STABLITY: [ ] Unstable [x] Stable HAZARDOUS POLYMERIZATION: [ ] May occur [x] Will not occur -INCOMPATIBILITY STRONG MINERAL ACIDS, CAUSTICS AND OXIDIZING AGENTS -CONDITIONS TO AVOID: TEMPERATURES ABOVE 212 F -HAZARDOUS DECOMPOSITION PRODUCTS: NONE KNOWN ---------------------------- SECTION VII - SPILL OR LEAK PROCEEDURES - ---------------------------------------------------- I-------------------------- -STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED DIKE AROUND THE AREA TO CONTAIN THE SPILL. COLLECT MATERIAL USING AN INERT CHEMICAL ABSORBENT. PLACE SPENT ABSORBENT IS A SECURE DOT CONTAINER FOR DISPOSAL. -WASTE DISPOSAL METHOD: INCINERATE ACCORDING TO FEDERAL, STATE AND LOCAL REGULATIONS. ----------------------------------- SECTION VIII - SPECIAL PROTECTION INFORMATION: --------------------------------------------------- RESPIRATORY PROTECTION: NONE NEEDED UNDER NORMAL USAGE -VENTILATION: ADEQUATE MECHANICAL VENTILATION -PROTECTIVE GLOVES: RUBBER GLOVES -EYE PROTECTION: CHEMICAL SAFETY GOGGLES -OTHER PROTECTIVE EQUIPMENT: SECTION IX - SPECIAL PRECAUTIONS ----------------------------------------- -PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: STORE AT AMBIENT TEMPERATURES. OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES. Page: 3 STRUKTOL COMPANY OF AMERICA Material Safety Data Sheet for: STRUKTOL SBA 2080 (SBA2080) SECTION IX - SPECIAL PRECAUTIONS (cont. ) ---------- ----=-------_ -------------------------------------------------------- -DISCLAIMER THE ABOVE INFORMATION IS ACCURATE TO THE BEST OF OUR KNOWLEDGE. HOWEVER, STRUKTOL COMPANY MAKES NO WARRANTY EXPRESSED OR IMPLIED WITH RESPECT TO THIS INFORMATION AND DISCLAIMS ALL LIABILITY FOR RELIANCE THEREON. THE INFORMATION AND RECOMMENDATIONS ARE OFFERED FOR THE USER'S CONSIDERATION AND EXAMINATION; IT IS THE USER'S RESPONSIBILITY TO SATISFY THEMSELVES THAT THEY ARE SUIT- ABLE AND COMPLETE FOR A PARTICULAR USE. I i I i . 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TEL N0:708i956-0399 #270 P02 c r U A R T KATi27 IAL SAFETY DATA SHEET 10MITY: THREDKUT 99 CUTTING OIL (As Used on Label and List) FLASH POINT (Method Used) : >3300 F (COC) FLAMMABLE LIMITS: LEL ND UEL ND EXTINGUISHING MEDIA: DRY CHEMICAL, FOAM, CO SPECIAL FIRE FIGHTING PROCEDURES: FIREFIGHTERS SHOULD WEAR SELF CONTAINED BREATHING APPARATUS. UNUSUAL FIRE AND EXPLOSION HAZARDS: NONE llac=x===ssss�ac=cox=xasis�sc=ccc====axa:���:��s���srw¢aox===xxxxsa��>■=�������_... SECTION V REACTIVITY DATA �.�-„.o=xxx=xaasis�tlwssx=x====xs�====____=====Cswws=sssss+�wwwiiiwa:xsssswws��sss�, STABILITY; STABLE CONDITIONS 0 AVOID: EXTREME HEAT, OPEN FLAME INCOMPATIBILTY (Materials to avoid) : STRONG OXIDIZIG AGENTS HAZARDOUS DECOMPOSITION OR BYPRODUCTS: CO, COI, SOX, HC1 HAZARDOUS POLYMERIZATION: WILL NOT OCCUR CONDITIONS TO AVOID: 6ECPI0N VY - MLV M BARD DATA is�rMi01CCCx��x�iwiiMta�==C���-��SCRatc-�=c=c�=cC�SSea�t��o1�s��llllwwww�wiiwllws�=�a=tvs, ROUTE(S) OF ENTRY: INHALATION? SKIN? INGESTION? YES YES POSSIBLE -HEALTH HAZARDS (Acute and Chronic) NO KNOWN ACUTE HEALTH HAZARDS. PROLONGED OR FREQUENT CONTACT MAY CAUSE SKIN IRRITATION. TARGET ORGANS (OIL MIST) : RESPIRATORY SYSTEM AND SKIN. CARCINOGENICITY NTP? IARC? OSHA REGULATED? NONE LISTED SIGNS AND SYMPTOMS OF OVEREXPOSURE: POSSIBLE RED AND/OR ITCHING SKIN DUE TO OVEREXPOSURE. MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: NONE KNOWN EMERGENCY AND FIRST AID PROCEDURES: 1 -2- NUV-�4-'1.J2 WE 16:01 ID:MOTOR OIL INC. TEL N0:708i956-0399 •--- #3270 F03 A d��Z L A_ MATERIAL SAFETY DATA 09ET I IDRWITY: THREDKUT 99 CUTTING OIL (As Used on Label and List) i EYE CONTACT: FLUSH WITH WATER FOR AT LEAST 15 MINUTES AND SEEK MEDICAL ATTENTIION IMMEDIATELY. SKIN CONTACT: WASH WITH SOAP AND WATER. INHALATION: IF A PERSON BREATHES IN LARGE AMOUNTS OF THIS PRODUCT, MOVE THE EXPOSED PERSON TO FRESH AIR AT ONCE*. ______----- ________----------- _• ______-----------�_ SECTION VII PRECAUTIONS FOR SAFE HANDLING AND USE ------------- STEFS T. iBE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: EXTINGUISH ALL FLAMES IN THE VICINITY. DIKE SPILL AND SOAK UP ON INERT ABSORBENT MATERIAL. WASTE DISPOSAL METHOD: FOLLOWIGOVERNMENTAL AND CORPORATE REGULATIONS FOR A LUBRICATING OIL. PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: STORE CONTAINERS CLOSED, AWAY FROM EXTREME HEAT AND OPEN FLAME. OTHER PRECAUTIONSt USE GOOD PERSONAL HYGIENE. FOR INDUSTRIAL USE ONLY. CONTAINS PETROLEUM OIL. AVOID BREATHING MIST. SECTION VIII CONTROL MEASURES i RESPIRATORY PROTECTION (SPecify Type) : IF VENTILATION EQUIPMENT ISS NOT i SUFFICIENT TO KEEP AIRBORNE CONCENTRATIONS BELOW EXPOSURE LIMITS, A NYOSSH APPROVED RESPIRATOR SHOULD BE WORN. VENTILATION: LOCAL EXHAUST: NO SPECIAL SPECIAL: MECHANICAL (General) : NO SPECIAL OTHER: PROTECTIVE GLOVES: OIL-IMPERMEABLE EYE PROTECTION: SAFETY GLASSES OTHER PROTECTIVE CLOTHING OR EQUIPMENT: NONE SPECIAL WORK/HYGENIC PRACTICES: DO NOT EAT, DRINK OR SMOKE IN WORK AREA. LAUNDER SOILED CLOTHING BEFORE REUSE DIS3CARD OIL-SOAKED SHOES. SECTION IX - REGULATORY INFORMATION -3- NOV—;24—'92 TUE 16:02 _ID:MOTOR OIL INC. TEL NO:708i956-0399 t#270 PO4 a•a ► Y I I f i TT U MATERIAL SAFETY DATA SHEET IDBSTITYI THREDIMT 99 CUTTING OIL (As Usld on Label and List) �I SARA TITTLE III STATUS: SEGTiIQN 311 AND 312 HAZARDOUS CHEMICALS ( THIS PRODUCT CONTAINS THE FOLLOWING INGREDIENTS) DEFINED AS HAZARDOUS BY OSHA HAZARD COMMUNICATION STANDARD 29 CPR 1910. 1200 (d) . CAS CHEMICAL NAME $ BY WEIGHT i SEt SECTION II zf SECTION 313 SUPPLIER NOTIFICATION j THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 1OF THE EMERGENCY PLANNING AND COMMUNITY RIGHT TO KNOW TACT OF 1986 AND OF CFR 372. CAS CHEMICAL NAME BY WEIGHT NOT APPLICABLE PLEASE NOTE THAT IF YOU REPACKAGE OR OTHERWISE REDISTRIBUTE THIS PRODUCT 'jTO INDUSTRIAL CUSTOMERS A NOTICE SIMILIAR TO THIS ONE SHOULD HE SENT TO THOSE CUSTOMERS. I THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED ACCURATE BY STUART-IRONSIDES, INC. HOWEVER, NO WARRANTY, EXPRESSED OR IMPLIED, IS GIVEN REGARDING THE ACCURACY OF THESE DATA OR THE RESULTS TO BE OBTAINED ON THE USE THEREOF.! I I I i I I j i -4- �r �'ypF INC., - The Town of Barnstable Health Department 367 Main Street, Hyannis, MA 02601 M/Jl 7� i639• � Office 508-790-6265 Thomas A. McKean FAX 508-775-3344 Director of Public Health TO: Jackie Etsten, Principle Planner FROM: Thomas A. McKean, Director of Public Health !"C,M , Date: November 24, 1992 Subject: Proposed Amendments To Article XXXI% I suggest the following words should be inserted within Section 4 (a) " or into any onsite sewage disposal system, sewer system, catch basin, or drywell. . . " after the words "The discharge of any toxic or hazardous materials upon the ground, or into any surface or groundwaters" and before the words "within the Town of Barnstable, is prohibited. " so that it would read as follows: SECTION 4. PROHIBITIONS a) The discharge of any toxic or hazardous materials upon the ground, or into any surface or groundwaters or into any onsite sewage disposal system, sewer system, catch basin, or drywell within the Town of Barnstable, is prohibited. I also reviewed the other proposed amendments and found that the new proposed Section 5 (d) , the first sentence of the new proposed Section 5 (e) , and the new proposed Section 5 (f) is already provided under Section 4 (b) of the existing Ordinance. It states " Outdoor storage of toxic and hazardous materials is prohibited, except in product-tight containers which are protected from the elements, leakage, accidental damage and vandalism, and which are stored in accordance with all applicable requirements of Section 5 of this Ordinance. For the purposes of this subsection, road salts and fertilizer shall be considered as hazardous materials. " Therefore, please advise whether you agree that only the second sentence of the new proposed Section 5 (e) needs to be added, [along with the words " . . .or into any onsite sewage disposal system, sewer system, catch basin, or drywell. . . " within Section 4 (a) . ] Thank you. TO: TOM MCEAN FROM: JACKIE ETSTEN DATE: NOVEMEBER 24, 1992 RE: REVISIONS TO ARTICLE XXXIX Attached is another copy of the Hazardous materials Ordinance. I had forgotten that this was a General Ordinance when we spoke the other day. The changes outlined in the attached copy are required by DEP acting under 310 CMR 22 .22, the Water Manangement Act. It would be very helpful if you could reviw these changes and make comments before these revisions are forwarded to the Town Managers office. Could the Health Department/ Board of Health sponsor this article, since the responsibility for enforcement seems to lie with the Board of Health? cc: Robert Schernig, Planning Director r C--VtS(o#vS 12 d:zngwp Etsten December 3, 1991 ARTICLE XXXIX, CONTROL OF TOXIC AND HAZARDOUS MATERIALS INTRODUCTION The State Department of Environmental Protection has promulgated new regulations which require that the town adopt revised wellhead protection measures. The adoption of these is a requirement for the permitting of any new public water supply well. The existing Town Ordinance governing the handling and storage of hazardous materials needs revisions to bring them into compliance with 310 CMR 22.21 . To this end, the Planning Department will work with the Health Department and the Board of Health. To change the General Ordinance of the Town of Barnstable Article XXXIX, Control of Toxic and Hazardous Materials, by deleting Section 4. Prohibitions, and inserting the following: SECTION 4. PROHIBITIONS a) The discharge of any toxic or hazardous materials upon the ground, or into any surface or groundwaters, or into any sanitary septic or sewer system, within the Town of Barnstable, is prohibited. Insert new subsections 5 d) e) and f) as follows: SECTION 5. STORAGE CONTROLS d) 1 toxic and ha;Ze ous terials sh 1 be stored in produc t ig contais ch are prote d from the elements eakage, ad 1 damage an va alism. For the purposes this sub ion, fertilize shall be considered as hazar ou materia Liquid hazardous materials other than gasoline, which are stored outside, shall be stored above ground in a free standing container with protection adequate to contain a spill the size of the container(s) total storage capacity. �ad salt a d other chemi al used for i and snow rem al shall contained in a tructure th rovides pro a tion fro he elements an prevents 1 ach to from contam\ nating.'the roundwater and surface waters. L=k CS 7 Mo • ARTICLE XXXIX. CONTROL OF TOXIC AND HAZARDOUS MATERIALS. Section 1. Findings The Town of Barnstable finds that: (1) The groundwater underlying this town is the sole source of its ex- isting and future water supply, including drinking water; (2) The groundwater aquifer is integrally connected with, and flows in- to, the surface waters, lakes, streams and coastal estuaries which constitute significant recreational and economic resources of the town used for bathing and other water-related recreation, shellfishing and fishing; (3) Accidental spills and discharges of petroleum products and other toxic and hazardous materials have repeatedly threatened the quality of such groundwater supplies and related water resources on Cape Cod and in other • Massachusetts towns, posing potential public health and safety hazards and : threatening economic losses to the affected communities; (4) Unless preventive measures are adopted to prohibit discharge of tox- ic and hazardous materials and to control their storage within the town,further spills and discharges of such materials will predictably occur, and with greater + frequency and degree of hazard by reason of increasing construction, commer- cial and industrial development, population, and vehicular traffic in the Town of Barnstable and on Cape Cod; (S) The foregoing conclusions are confirmed by findings set forth in the Environmental Impact Statement and Water Quality Management Plan for Cape Cod (September, 1978), prepared by the Cape Cod Planning and Economic Development Commission pursuant to Section 208 of the Federal Clean Waters Act;by the report entitled Chemical Contamination(September, 1979),prepared by the Special Legislative Commission on Water Supply,Com- monwealth of Massachusetts; and by the report, Chemical Quality of Ground Water, Cape Cod, Massachusetts (1979), prepared by the U.S. Geological Survey. Section 2. Authority The Town of Barnstable adopts the following measures under its home rule powers, its police powers to protect the public health and welfare, and its authorization under Chapter 40, M.G.L. S. 21. Section 3. Definitions (a) The term, "discharge",means the accidental or intentional spilling, leaking, pumping, pouring, emitting, emptying or dumping of toxic or hazar- dous material upon or into any land or waters of the Town of Barnstable. Discharge includes,withot/ limitation,leakage of such materials from failed or discarded containers or storage systems,and disposal of such materials into any on-site sewage disposal system, drywell, catch basin or unapproved landfill. The term, "discharge", as used and applied in this bylaw, does not in ; ;, clude the following (1) proper disposal of any material in a sanitary or industrial landfill that has received and maintained all necessary legal approvals for that purpose; 54 6.n r3 .. p I (2) application of fertilizers and pesticides in accordance with label recommendations and with regulations of the Massachusetts Pesticide Control Board; (3) application of road salts in conformance with the Snow and Ice Control Program of the Massachusetts Department of Public Works; and (4) disposal of "sanitary sewage" to subsurface sewage disposal systems as defined and permitted by Title 5 of the Massachusetts Environmen- tal Code. (b) The term, "toxic or hazardous material," means any substance or mixture of such physical, chemical or infectious characteristics as to pose, in the Board of Health's judgment, a significant actual or potential hazard to water supplies, or other hazard to human health, if such substance or mixture were discharged to land or waters of this town. "Toxic or hazardous materials" include, without limitation, organic chemicals, petroleum products, heavy metals, radioactive or infectious wastes, acids and alkalies, and include pro- ducts such as pesticides,herbicides,solvents and thinners. Wastes generated by the following activities, without limitation, are presumed to be toxic or hazar- dous, unless and except to the extent that anyone engaging in such an activity can demonstrate the contrary to the satisfaction of the Board of Health: Airplane, boat and motor vehicle service and repair Chemical and bacteriological laboratory operation Cabinet making Dry cleaning Electronic circuit assembly Metal plating, finishing and polishing Motor and machinery service and assembly Painting, wood preserving and furniture stripping Pesticide and herbicide application Photographic processing, Printing Section 4. Prohibitions (a) The discharge of toxic or hazardous materials upon the ground or into any surface or groundwaters within the Town of Barnstable is prohibited. (b) Outdoor storage or toxic or hazardous materials is prohibited, except in product-tight containers which are protected from the elements,leakage,ac- cidental damage and vandalism, and which are stored in accordance with all applicable requirements of Section 5 of this bylaw. For purposes of this subsec- tion, road salts and fertilizer shall be considered as hazardous materials. Section 5. Storage Controls (a) Except as exempted below, every owner and every operator other than an owner of a site at which toxic or hazardous materials are stored in quantitates totalling, at any time, more than 50 gallons liquid volume or 25 pounds dry weight shall register, with the Board of Health the types of materials stored, quantities, location and method of storage. The Board of Health may require that an inventory of such materials be maintained on the premises and be reconciled with purchase,use,sales and disposal records on a monthly basis,in order to detect any product loss. Registration required by this subsection shall 55 �{2 9 433� f 1 be submitted within 60 days of enactment of this ordinance, and annually i thereafter. Maintenance and reconciliation of inventories shall begin within the 1 same 60-day period. Exemptions: Registration and inventory requirements shall not apply to the following: (1) Fuel oil stored in conformance with Mass. Fire Prevention Regula tions and regulations of the Barnstable Board of Health for the purpose of heating buildings located on the site; or (2) The storage of toxic and hazardous materials at a single family or two family dwelling, except where such materials are stored for use associated with a professional or home occupation use as defined by Section 1, para. 12 of the Zoning By-Laws of the Town of Barnstable. (b) Wastes containing toxic or hazardous materials shall be held on the premises in product-tight containers and shall be removed and disposed of in , accordance with the Massachusetts Hazardous Waste Management Act. Ch. 704 of the Acts of 1979. The Board of Health may require that containers of toxic or hazardous i (c) T i materials be stored on an impervious, chemical resistant surface compatible with the material being stored, and that provisions be made to contain the pro- duct in the case of accidental spillage. Section 6. Report of Spills and Leaks (a) Every person having knowledge of a spill, leak or other loss of toxic i hazardous materials believed to be in excess of 5 gallons or 25 pounds dry weight shall report the spill or loss of same to the Board of Health within one ` hour of detection. Section 7. Enforcement (a) The provisions of this bylaw shall be enforced by the Board of Health. The agent of the Board of Health may, according to law, enter upon any premises at any reasonable time to inspect for compliance. (b) Upon request of an agent of the Board of Health, the owner or operator of any premises at which toxic or hazardous materials are used or stored shall furnish all information required to monitor compliance with this bylaw, including a complete list of all chemicals, pesticides, fuels and other toxic or hazardous materials used or stored on the premises, a description of measures taken to protect storage containers from vandalism, corrosion and spillage, and the means of disposal of all toxic or hazardous wastes produced on the site. A sample of wastewater disposed to on-site septic systems, drywells or sewage treatment systems may be required by the agent of the Board of Health. (c) All records pertaining to storage, removal and disposal of toxic or hazardous wastes shall be retained for no less than three years, and shall be made available for review W the agent of the Board of Health upon request. (d) The Building Commissioner of the Town of Barnstable shall condition , issuance of construction and occupancy permits upon conformity with the re- quirements of this bylaw respecting any toxic or hazardous materials to be used in the course of such construction or occupancy. Section 8. Violation (a) Written notice of any violation of this bylaw shall be given by the agent 56 f I of the Board of Health, specifying the nature of the violation; any corrective measures that must be undertaken, including containment and cleanup of discharged materials; any preventive measures required for avoiding future violations; and a time for compliance. Requirements specified in such notice shall be reasonable in relation to the public health hazard involved and the dif- ficulty of compliance. The cost of containment and cleanup shall be borne by the owner and operator of the premises. j Section 9. Penalty Penalty for failure to comply with any provisions of this bylaw shall be $200.00 per day of violation. i Section 10. Severability Each provision of this bylaw shall be construed as separate,to the end that if any part of it shall be held invalid for any reason, the remainder shall con- ` tinue in full force and effect. Adopted November 1, 1980. Approved February 27, 1981. ARTICLE XXXX. RAFFLES AND BAZAARS Section 1. No person shall operate a raffle or bazaar in the Town of Barnstable except in accordance with section 7A of Chapter 271 of the general laws,961 Code of Massachusetts Regulations, sections 4.00-4.05, and this arti- cle. Section 2. Each application for a permit to operate raffles and bazaars shall be accompanied by a document setting forth the following information: ' 1. The evidence on which the applicant relies in order to qualify. 2. The names, addresses and phone numbers of three officers or members of the organization who shall be responsible for the operation of the Bazaar or Raffle. i 3. The uses to which the net proceeds will be applied; j and 1 4. Names and addresses and phone numbers of persons leasing gaming equipment to the organization. S. A current list of members of the organization together with their ad- dresses. No person other than an officer or a member specifically authorized to do so shall sign an application for a permit to operate raffles and bazaars on behalf of an organization. Section 3. No person holding a permit to operate raffles or bazaars shall operate any particular such event unless written notice has been given to the Chief of Police, not less than 30 days prior to the event, of the date, time, and place of the event and of any deviation from the information contained in the application for the permit to operate the same. { Section 4. Any person violating any provisions of this article shall be punished by a fine of not more than$300.00. Adopted Jan. 25, 1982. Approved May 20, 1982. 57 I. f.. g T 04 f ARXSTA8LE Warren Rutherford Town Manager 367 Main Street Hyannis 7 MA 02601 February 17, 1993 SUBJECT: Eagle Snacks, Inc. Cape Cod potato Chip Company SARA Title III Section 311/312 Reporting Lear Mr. Rutherford., Under cover of this letter, please find the completed Tier II Hazardous Material Inventory form and an updated list of Material Safety Data Sheets for the hazardous materials used at our Hyannis, Massachusetts facility as required by Sections 311 and 31z of SARA Title III . Liquid nitrogen was the only hazardous material used during the 1992 calendar year which meets the reporting requirements of I� Sections 311 and 312. If you have any questions or require additional information, please let me know. Sincerely, J�Z't Z a-) ",r � Bart petracca Quality Control Manager Cape Cod potato Chips ReHsed June 1990 FedlUy'tdemttttcadora .:::.>:::< :;:.:>;:<.:. 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( coadnals eMMenlalive abbrevianons Signature �---- I hall*attached a description or Data signed dikes and other saleguard measures - HAZARDOUS MATERIALS LIST 11/23/92 | CHEMICAL OR. PRODUCT NAME DEPARTMENT MSDS LOCATION / ------------------------------------_________________________________ ACETIC ACID, GLACIAL WWT. COMMUNICATION ACETONE ' MAINTENANCE COMMUNICATION � � ACETYLENE MAINTENANCE COMMUNICATION ACTIVATED ALUMINA PROCESSING COMMUNICATION ACTIVATOR (POLYAMIDE RESIN) MAINTENANCE COMMUNICATION ADHESIVE 81669 MAINTENANCE COMMUNICATION . | ALCONOX Q. C. COMMUNICATION. ALUM (DRY-) WASTEWATER COMMUNICATION ALUM-A-LUB MAINTENANCE COMMUNICATION -�� ALUMINUM MAINTENANCE COMMUNI_ru�� � ION ANDEROL FGC 20 COMPRESSOR OIL MAINTENANCE COMMUNICATION � ANSUL FIRE SUPPRESSANT PRODUCTION COMMUNICATION � ` ANTI-FREEZE MAINT. , S/R, COMMUNICATION & WASTEWATER ANTISOIL HF SANITATION COMMUNICATION ARGON MAINTENANCE COMMUNICATION AUSTIN Al BLEACH ' SANITATION COMMUNICATION BIG "D" WATER SOLUBLE WASTE WATER COMMUNICATION DEODORANT, LEMON BUFFER SOLUTIONSZpH 1-5, 6-8 WASTE WATER COMMUNICATION 9-l1 CHELCACLEAN ES SANITATION COMMUNICATION � CHEM-CAL HYDRATED LIME WASTE WATER COMMUNICATION � CHEMGRATE PROCESSING COMMUNICATION CITRIC ACID, ANHYDROUS QUALITY CONTROL COMMUNICATION � ( . ' ' � ' ^ COTTONSEED COOKING OIL PROCESSING COMMUNICATION COAL TAR E*F'f.:)XY7 COMPONENTS A+B MAINTENANCE COMMUN I CAI"I ON rl A I NTE NIA.NCE. C(Dl-'It%'!Ul\l I CAT I ON DEPEND (F-01\10--Mly ADHESIV-117--- P.'l^I N T E N A.N CIE- 'C'0 rl 11 U N I C A T 10 N D I N E-1*HYL r-," TNE 1C 0 P1 rl U N I C A T I ON DRIERITE DE'SSICAPIT WASTE WATER rOMMUN I CAT I ON ELECTROLYTE (ACID) BATTERY FLUID C. (W. HOUSE) COMMUN I CAT I ON EPI-SEAL LEAK DETEX MAINTENANCE COMt`lLJN I CAT*I ON ETHYL ALCOHOL, DENATURED Q. C. /SAN 17'. COMMUN I CAT I ON PACKAGING r51W047 PREMIUM CONTACT CLEANER MAINTENANCE COMMUNICATION FOAM X-TRA SANITATION COtvll%'IL.JNICATION FUL BAC SANITATION COMINIUN I CAT I ON GASKET ELIMINATOR MAINTENANCE COtIMUNICATION GASOLINE, AUTOMOTIVE MAINTENANCE COr"IMUN I CAT I ON 61-ACIAL ACETIC ACID COMMUN I CAT I ON GLASS CLEANER (BULK ) SANITATION COMINILJ N I CAT I ON GOING HOME HAND CLEANER SANITATION COrllvlUN I CAT I ON GREASE STRIP PACKAGING COMMUN I CAT I ON HAYSSEN LUBRI-CAN. AIR LINE "'IAIN-FENANCE Cot"IMUN I CAT I ON LUBRICATION, IA HEAVY DUTY Er LJA T A LC T I V t-I'M UM PlAINTENANCE C 0 rl t"I'Li N I C A T 10 N HEAVY DUTY EPDXY PR I MER'S MAINTENANCE COMMUNICATION HEAVY DUTY EPOAX Y TOPCOAT MAINTENANCE. COMMUN I CAT I ON HYDROGEN SULFIDE MASTER COMMUNICATION ARD TRANSMISSION OIL MAINTENANCE COMMUNICATION � � IMPROVED TREMSEAL GP MAINTENANCE COMMUNICATION INDUSTRIAL ENAMELS MAINTENANCE COMMUNICATION ISO-OCTANE QC COMMUNIACTION | � ISO-PROPANOL PACKAGING/QC COMMUNICATION | JELL ADD SANITATION COMMUNICATION � KLCr 5/20 (PENWALT PETROLEUM MAINTENANCE COMMUNICATION LUBRICATING OIL) � LIQUID FRY CLEAN SANITATION COMMUNICATION LOCQUIC PRIMER(AEROSOL) MAINTENANCE COMMUNICATION LOCQUIC PRIMER WADE N MAINTENANCE COMMUNICATION ' LUBRIPLATE ACL SERIES MAINTENANCE COMMUNICATION LUBRIPLATE FGL SERIES MAINTENANCE COMMUNICATION ' ` LUBRIPLATE LUBRIPLATE FMO-AW SERIES MAINTENANCE COMMUNICATION -----' LUBRIPLATE HO SERIES MAINTENANCE COMMUNICATION LUMINATE SANITATION COMMUNICATION / \ MARVEL MYSTERY OIL WASTE WATER COMMUNICATION MASTER GASKET PRIMER MAINTENANCE ' COMMUNICATION MCR-43 GLOSS EPDXY MAINTENANCE COMMUNICATION METABO FLEXIAMONT SUPER MAINTENANCE COMMUNICATION /-� � \.0 � � ` ` . METHANOL 0.C. COMMUNICATION MIXCO 0 GREASE MAINTENANCE COMMUNICATION MOBIL 1 FORMULA 5W-3(-.) MAINTENANCE COMMUNICATION MONARCH 88.0, SANITATION COMMUNICATION MORTON 1:1ENDRITIC SALT PRODUCTION COMMUNICATION! MOTOR OIL loW40 WASTE WATER COMMUNICATION NATURAL GAS MAINTENANCE COMMUNICATION NEV-SZ WHITE FOOD GRADE PTFE MAINTENANCE COMMUNICATION NITROGEN (CRYOGENIC LIQUID) PRODUCTION, COMMUNICATION! MAINT. 7 S/R, PACKAGING 160 THINNER (PAINT) MAINTENANCE COMMUNICATION OXYGEN MAINTENANCE COMMUNICATION OXYGEN SENlSOR_ ASSEMBLY-;"----. . . MAINTENANCE COMMUNICATION PAINT THINNER COMMUNICATION PERMATEX THREAD SEALANT MAINTENANCE COMMUNICATION PHENOLPTHALEIN SOLUTION7 1% O. C. COMMUNICATION PLASTIC WET SURFACE ROOV CEMENT MAINTENANCE COMMUNICATION POLYAMIDE EPDXY-COMPONENT A MAINTENANCE COMMUNICATION POLYAMIDE EPDXY-COMPONENT B MAINTENANCE COMMUNICATION POLY-CARB Mk . 198 PART A EPDXY RESIN MAINTENANCE COMMUNICATION POLY-CARB Mk . 1?8 PART B POLYAMINE MAINTENANCE COMMUNICATION POLYAMIDE SOLUTION POTASS 1 UM CHROMATE Q. C. COMMUNICATION INDICATOR, 5% POTASSIUM CHLORIDE SOLTN. WASTE WATER COMMUNICATION PRIMER NO. 6 MAINTENANCE COMMUNICATION PRO-LOCK PIPE SEALANT MAINTENANCE COMMUNICATION PST (R) N TEMP ANTI-GALLING PIPE SEALANT MAINTENANCE COMMUNICATION PV C PR I R' MAINTENANCE COMMUNICATION PVC CEMENT CLEAR MEDAM MAINTENANCE COFlPlUN I CAT I ON QUICK METAL (TM) PRESS FIT REPAIR MAINTENANCE COMMUNICATION QUICK SET INDUSTRIAL ADHESIVE MAINTENANCE COMMUNICATI01\1 . � * - ' RBVOYABLE THREADLOCKER MAINTENANCE COMMUNICATION ^.� RIGID NUCLEAR THREAD CUTTING OIL MAINTENANCE COMMUNICATION RETAINING COMPOUND 609 MAINTENANCE COMMUNICATION RUGBERFLEX PATCHING CEMENT MAINTENANCE COMMUNICATION � RUST-0-THANE ACTIVATOR MAINTENANCE COMMUNICATION � � RUST-0-THANE TOPCOATS MAINTENANCE COMMUNICATION SCOTCH-GRIP ADHESIVE MAINTENANCE COMMUNICATION 723 SPRASOLvO MAINTENANCE COMMUNICATION SILVER NITRATE SOLTN; n/10 Q. C. COMMUNICATION SHAW ELECTRODE, TYPE CODE-ARC 308 MAINTENANCE COMMUNICATION MR AC-DC ' SHAW ELECTRODE, TYPE EASY-ARC 308 MAINTENANCE COMMUNICATION AC-DC SODIUM HYDROXIDE SOLTN, n/10 Q. C. COMMUNICATION SODIUM THIOSULFATE _ QC COMMUNICATION SOLDER SEAL LIQUID WRENCH MAINTENANCE COMMUNICATION SPARCREME JANITORIAL COMMUNICATION / \ SPARKLEEN WAREWASHING DETERGENT Q. C. COMMUNICATION STARCH QC COMMUNICATION STEEL MAINTENANCE COMMUNICATION STRUKTOL SBA 2080 DEFOAMER WASTEWATER COMMUNICATION . . ' ' /-�.� � � ` ~ � ` _ SUPER KABON SANITATION COMMUNICATION SUPER LUBE AEROSOL CAN MAINTENANCE COMMUNICATION ` SWIFT SET CEMENT MIX MAINTENANCE COMMUNICATION TAPFREE MAI114TENANCE COMMUNICATION THORIATED TUNGSTEN ELECTRODE MAIINTENANCE COMMUNICATION THREDKUT 9�? CUTTING OIL MAINTENANCE COMMUNICATION THREE—IN—ONE HOUSEHOLD OIL MAINTENANCE COMMUNICATION 3M OIL SORBENT MAINTENANCE ' COMMUNICATION 290 ADHESIVE/SEALANT MAINTENANCE COMMUNICATION ULTRA BLACK (T, RTV SILICONE MAINTENANCE COMMUNICATION WELCO AND 15 FC (ZINC OXIDE) MAINTENANCE COMMUNI CAT 'ION XYLENE MAINTENANCE COMMUNICATION � ZEP DYNA SOL MAINTENANCE COMMUNICATION � ----- o 1 ^ ' — — � � � ` _ | | = ' on, IL D t TOXIC AND HAZARDOUS MATERIALS REGISTRATION FORM Mail To: NAME OF BUSINESS: A. Board of Health MAILING ADDRESS: Town of Barnstable TELEPHONE NUMBER: 77S'� �`3 X P.O. Box 534 Hyannis, MA 02601 CONTACT PERSON: (SS_&224`a Does your firm store any of the toxic or hazardous materials listed below, either for sale or for your own use, in quantities totalli , at any time, more than 50 gallons liquid volume or 25 pounds dry weight? YES NO This form must be returned to the Board of Health regardless of a yes or no answer. Use the enclosed envelope for your convenience. If you answered YES above, please indicate if the materials are stored at a site other than your mailing address: ADDRESS: TELEPHONE: LIST OF TOXIC AND HAZARDOUS MATERIALS The Board of Health has determined that the following products exhibit toxic or hazardous characteristics and must be registered when stored i Please put a check beside each product that you store: Antifreeze (for gasoline or coolant systems) Drain cleaners Automatic transmission fluid l/ Toilet cleaners Engine and radiator flushes Cesspool cleaners ` Hydraulic fluid (including brake fluid) Disinfectants Motor oils/waste oils Road Salt (Halite) Gasoline, Jet fuel Refrigerants Diesel fuel, kerosene, #2 heating oil Pesticides (insecticides, herbicides, Other petroleum products: grease, lubricants rodenticides) Degreasers for engines and metal Photochemicals (fixers and developers) Degreasers for driveways & garages Printing ink Battery acid (electrolyte) Wood preservatives (creosote) Rustproofers Swimming pool chlorine Car wash detergents Lye or caustic soda. Car waxes and polishes Jewelry cleaners Asphalt & roofing tar Leather dyes Paints, varnishes, stains, dyes Fertilizers (if stored outdoors) L,""Paint & lacquer thinners PCB's Paint & varnish removers, deglossers j Other chlorinated hydrocarbons, t,-'� Paint brush cleaners f (inc. carbon tetrachloride) Floor & furniture strippers �� Any other products with "Poison" labels Metal polishes (including chloroform, formaldehyde, Laundry soil & stain removers hydrochloric acid, other acids) (including bleach) Other products not listed which you feel may Spot removers & cleaning fluids be toxic or hazardous (please list): / (dry cleaners) Other cleaning solvents Bug and tar removers Household cleansers, oven cleaners White Copy-Health Department/ Canary Copy-Business ,Y.ay...e s.w++.rR-.yr- F�.,r.4lWfi.W�`.tr+"`g.`"'r►'^'+rsr'�".ta•.>'Row,y.4s�r�r,Fi,L'�d17(s�.0:�• �1`'�'4�tr+wC.+tad$v!'k'^�L.-w-i--sw.r�„'r..�.s..,4�'e!�,r,3.n :wi•.n�. :.r.i;e=,�-.er,..+ -: y .•� - , t�!`• -/r �i"s,•t6,./ yrE�. ' - TOWNOF BARNSTABLE coMPLrANC7 CLASS: 1.Marine,Gas Stations,Repair satisfactory� 2.Printers �'- BOARD OF HEALTH - 3.Auto Body Shops , /s ,,� unsatisfactory 4.Manufacturers-. COMPANY .•�i � ,�.'a '15�, { (see"Orders") 5.Retail Stores 01;A �� 6.Fuel Suppliers ADDRESS.. raR�41, ./.4 w� Cl�'sS: 7.Miscellaneous Q UANTITIES AND STORAGE (IN=indoors;OUT=outdoors) MAJOR MATERIALS Case lots Drums Above Tanks Underground IN OUT IN OUT IN OUT #&gallons Age Test y. Fuels: Gasoline,Jet3Fuel<(,A) Diesel, Kerosene, #2 (B) Heavy Oils �+ waste.moto�,or�lA('G)`'f' new motor oil (C) 44 '; r�� transmission/hydraulic Synthetic Organics: `fl * degreasers ' Miscellaneous: RJ DISPOSAURECLAMATION REMARKS: 1. Sanitary Sewage 2.Water Supply J{}°` , e Y--1144f14;, 1114011 , C11W9 1#1 4 O Town Sewer GPublic qtF f On-site QPrivatey 3. Indoor Floor Drains YES Z/'`f NO d O Holding tank: MDC Q Catch basin/Dry well rt On-.site system 4. Outdoor Surface drains:YES i/ NO ORDERS: ' Q Holding tank:MDC 'Catch basin/Dry well O On-site system 5.Waste Transporter Name of Hauler Destination Waste Product YES NO 2. Person (s) Interviewed Inspector Date' ` `V.Q T Martin FlAny Chairman Board of Selectmen Selectmen ' 's Office 367 Main Street Hyannis, MA 0260:1. Dear Mr� Flynny February 9v 1991. In order to comply with MOL Chapter III!, I have enclosed an updated MSDS list along with additional MSDS' that are being submitted for the first timeo They are: Antisoil HF Oxygen Sensor Assembly Activated Alumina Airlift Floral and Lemon San-i-T-10 MSDS deletions include: Acid BricK Cleaner Chromerge Cutting Oil 07020 DCT Acid DFP 32 Fel Pro C5 Faster Acid 100 PraKleen SNB 130 Struktol Defoamer Our current contact and emergency information is . as follows: Company: Cape Cod Potato Chips Breeds Hill Rd . Hyaknisy MA 0260:1. Business Phone: (508)775-335�-.3 Emergency Phone: (508)477-8126 Bart Petracca, Quality -Control (508)771-5202 Donna Hokey Employee Relations SIC Code! 2096 Average 0 of Employees: 135 ThanK you, Bart Petracca Quality Control Supervisor HAZARDOUS MATERIALS LIST 2/09/91 CHEMICAL OR PRODUCT NAME DEPARTMENT MSDS LOCATION , --------------------------------------------------------------------- ' ACETIC ACID, GLACIAL WWT ^ COMMUNICATION ACETONE MAINTENANCE COMMUNICATION ACETYLENE MAINTENANCE COMMUNICATION ACTIVATED ALUMINA PROCESSING COMMUNICATION ACTIVATOR(POLYAMIDE RESIN) MAINTENANCE COMMUNICATION ADHESIVE 81669 MAINTENANCE COMMUNICATION AIRLIFT FLORAL AND LEMON SANITATION COMMUNICATION ` ALCONOX Q^C, ON FILE ' ALUMINUM MAINTENANCE COMMUNICATION ANDEROL 497 SYN COMPRESSOR OIL ` MAINTENANCE COMMUNICATION NSUL FIRE SUPPRESSANT PRODUCTION COMMUNICATION ANTI-FREEZE MAINT ^ , S/R, COMMUNICATION & WASTE WATER | � ANTISOIL SANITATION COMMUNICATION � ARGON . MAINTENANCE ON FILE BELT DRESSING 4 MAINTENANCE COMMUNICATION BIG "D" WATER SOLUBLE WASTE WATER COMMUNICATION DEODORANT, LEMON BUFFER SOLUTIONS:pH 1-5 ,6_8 WASTE WATER ON FILE 9-11 ' BW DISH SOAP III Q.C. ' COMMUNICATION CARGILLE IMMERSION OIL TYPES WASTE WATER COMMUNICATION AfB CODE 1248 CHELACLEAN E ^S ^ SANITATION COMMUNICATION CHEM-CAL HYDRATED LIME WASTE WATER ON FILE �N�`HEMGR�TE PROCESSING COMMUNICATION ����..^..~... ' � ~�. ` � CITRA-SCRUB SANITATION ON FILE � CITRIC ACID, ANHYDROUS PROCEISING ON FILE ` ` ' / ~ ' ^ COOL TOOL II . MAINTENANCE COMMUNICATION COTTONSEED COOKING OIL PROCESSING ON FILE COQ TAR EPDXY, COMPONENTS AfB MAINTENANCE COMMUNICATION DEPEND ACTIVATOR M/TINTENANCE COMMUNICATION DEPEND(R)NO-MIXADHESIVE MAINTENANCE COMMUNICATION DIAMHONIUM PHOSPHATE WASTE WATER COMMUNICATION DIGESTION SOLUTION (COD 0-1500 WASTE WATER COMMUNICATION ppm RANGE) DIMETHYLAMINE Q ^C ^ COMMUNICATION ' DREWFLOC(R) 472 COAGULANT WASTE WATER ON FILE / DRIERITE DESSICANT WASTE WATER ON FILE ' ETHYL ALCOHOL, DENATURED Q ^C^/SANIT ^ COMMUNICATION PACKAGING 5WO47 PREMIUM CONTACT CLEANER MAINTENANCE COMMUNICATIOIN _ ` ^ GASKET ELIMINATOR M�INTENANCE COMMUNICATION GASOLINE, AUTOMOTIVE MAINTENANCE ON FILE GLASS CLEANER(AEROSOL) JANITORIAL ON FILE ' ' GOING HOME SANITATION ON FILE / GREASE STRIP ' PACKAGING COMMUNICATION . HAYSSEN LUBRI-CAN: AIR LINE '' MAINTENANCE COMMUNICATION LUBRICATION HEAVY DUTY EPDXY ACTIVATOR MAINTENANCE COMMUNICATION ' HEAVY DUTY EPDXY PRIMERS MAINTENANCE COMMUNICATION HEAVY DUTY EPDXY TOPCOAT MAINTENANCE COMMUNICATION ISO-PROPANOL PACKAGING/QC COMMUNICATION JELL ADD SANITATION COMMUNICATION ' KLCr 5/20 (PENWALT PETROLEUM MAINTENANCE ON FILE LUBRICATING OIL) ' ` ' ' ~ | ' � LIQUID BOIL-OUT ES SANITATION COMMUNICATION - LIQUID HAND SOAP jANITORIAL ON FILE 1110CQUIC Pl-_-,IMER(AEROSOL) MAINTENANCE COMMUNICATION LOCQUIC PRIMER GRADE N MAINTENANCE COMMUNICATION ' LUBRIPLATE AC SERIES MAINTENANCE COMMUNICATION LUBRIPLATE ACL SERIES MAINTENANCE ' ` COMMUNICATION LUBRIPLATE FMO SERIES MAINTENANCE COMMUNICATION LOBRIPLATE FMO-AW SERIES MAINTENANCE COMMUNICATION LUBRIPLATE HO SERIES MAINTENANCE COMMUNICATION MARVEL MYSTERY OIL WASTE WATER COMMUNICATION MASTER GASKET PRIMER MAINTENANCE COMMUNICATION MCR-43 GLOSS EPDXY MAINTENANCE COMMUNICATION METHANOL O.C. COMMUNICATION hORTON DENDRITIC SALT PRODUCTION COMMUNICATION � n � � � OTOR OIL 1OW40 WASTE WATER ON FILE � -NEV-SZ WHITE FOOD GRADE PTFE MAINTENANCE COMMUNICATION NITROGEN(CRYOGENIC LIQUID) PRODUCTION, COMMUNICATION MAINT ^ , S/R, PACKAGING ` 160 THINNER(PAINT) MAINTENANCE COMMUNICATION � OXYGEN MAINTENANCE COMMUNICATION � OXYGEN SENSOR ASSEMBLY MAINTENANCE COMMUNICATION PAINT THINNER MAINTENANCE COMMUNICATION PERMATEX THREAD SEALANT MAINTENANCE COMMUNICATION PHENOLPTHALEIN SOLUTION, 1% Q^C^ COMMUNICATION � PLASTIC WET SURFACE ROOF CEMENT MAINTENANCE COMMUNICATION POLYAMIDE EPDXY-COMPONENT A MAINTENANCE COMMUNICATION ' POLYAMIDE EPDXY-COMPONENT B MAINTENANCE COMMUNICATION � OLY-CARB MK ^ 198 PART A EPDXY RESIN MAINTENANCE ON FILE � -- POLY-CARB MK ^ 198 PART B POLYAMINE MAINTENANCE ON FILE ' POLYAMIDE 'SOLUTION . POTASSIUM CHROMATE Q ^C ^ COMMUNICATION INDICATOR, 5% ' ` ' � ~� POTASSIUM CHLORIDESOLTN ^ W�STE W�TER COMMUNICATION PRO-LOCK PIPE SEAL0NT MAINTEN�NCE COHMUNIC�TI�N PST(R) N TEMP �NTI-GALLING PIPE ~- SEALANT MAINTENr.-INCE COHMUNIC�TION PVC PRIMER M(VINTENANCE COMMUNICATION PVC CEMENT CLEAR MEDIBH MAINTENANCE COMMUNICATION QUICK MET L(TM)PRESS FIT REP�IR M�INTEN�NCE COMMUNIC�TION QUICK SET INDUSTRIAL �\DHESIVE M�INTEN( NCE COMMUNICATION R01PID KLEEN S�NIT�TION COMHUNIC�TION REMOV�BLE THREADLOC KE R M�INTEN�NCE COHMUNIC�TION ' ' RETAINING COMPOUND 6O9 M�INTEN�NCE COMMUNIC�TION RUST-O-THv1NE A1CTIVfYTOR MAINTENANCE COMMUNIC TION RUST-O-TH�NE TOPCO�TS M�INTEN�NCE COMHUNIC�TION S�NI-T-10 S�NITATION � COHMUNICATION SCOTCH-GRIP �DHESIVE MAINTENANCE COMMUNIC�TIGN . SD 20 ALL PURPOSE CLEANER SANITA ON TI , ON FILE P/R 723 MAINTENANCE COMMUNIC11TION SILVER NITBPITE SOLTN, n/10 Q^C^ COMHUNIC�TION SHAW ELECTRODE , TYPE CODE-ARC 3O8 MAINTENANCE QN FILE MR AC-DC SH W ELECTRODE, TYPE EASY-fRC 308 M�INTENANCE ON FILE 01C-DC SO�K�HOLIC MAINTENANCE COHMUNIC TION SODIUM HYDROXIDE SOLTN, n/10 Q^C^ COMMUNIC TION SOLDER SE L LIQUID WRENCH MAINTEN)NCE COMMUNICPTION SPARCREME JANITORIA L ON FILE SPARKLEEN W01RE1AAS1.1ING DETERGENT Q^C^ COHMUNICHTION � SPR�-TEMP PRESSURIZED CLEAN ER SANIT�TION COMMUNIC�TION STEEL MAINT EN�NCE COHMUNICATION . =m� SUPER DIC� W�STE WATER COMMUNICATION � � | | s UPER LUBE AEROSOL CAN MAINTENANCE COMMUNICATION � SWIFT SET CEMENT MIX MAINTENANCE COMMUNICATION ���� �~�APFREE MAINTENANCE COMMUNICATION - THORIATED TUNGSTEN ELECTRODE MAINTENANCE ON FILE THREE-IN-ONE HOUSEHOLD OIL MAINTENANCE ON FILE TOUGH DUTY SANITATION COMMUNICATION 290 ADHESIVE/SEALANT MAINTENANCE COMMUNICATION , ULTRA BLACK(TM)RTV SILICONE MAINTENANCE COMMUNICATION WELCO AND 15 FC (ZINC OXIDE) MAINTENANCE ON FILE XYLENE MAINTENANCE COMMUNICATION ZEP DYNA SOL . MAINTENANCE _ COMMUNICATION ZEP LEMONEX SANITATION COMMUNICATION ZEP MW GREASE MAINTENANCE ON FILE | | ZEP PRESERVE MAINTENANCE COMMUNICATION � � ' � ' ' SPARTAN CHEMICAL. CO.t INC. .F MATERIAL SAFETY DATA SHEET..._. }' AR v$< SECTION I PRODUCT IDENTIFICATION I PRODUCT NAME OR NUMBER (es it appears on label) AIRLIFT FLORAL AND LEMON (BULK) ,;. MANUFACTURER'S NAME EMERGENCY TELEPHONE NO. Spartan Chemical Co., Inc, (419) 531-5551 ADDRESS (NUMBER, STREET, CITY,. STATE AND ZIP CODE) MANUFACTURER'S D-U-N-S NO. . 110 N. Westwood Ave., Toledo, OH 43607 00-503-6728 HAZARDOUS MATERIAL DESCRIPTION, PROPER SHIPPING NAME, HAZARD CLASS, HAZARD ID NO. (49 CFR 172.101) Unrestricted ADDITIONAL HAZARD CLASSES (AS APPLICABLE) n/a SECTION II - HAZARDOUS INGREDIENTS I -Table Z I ACGIH I ACGIH I CAS REGISTRY NO. y X W I CHEMICAL NAME(S) PEL Ii P_V I STE! ! . CARCINOGEN mg/M3 IMQM31 mA3 67-63-0 1-5 Isopropanol 980 980 1225 no SON SECTION III - PHYSICAL DATA BOILING POINT SPECIFIC GRAVITY H2O : 1 212 OF °C 1.0 TVA VAPOR PRESSURE = 18 PERCENT SOLID BYy ® 75 '°F °C x M Hg __psi WEIGHT (X) VAPOR DENSITY (AIR a 1) EVAPORATION RATE (but. ace. : 1) 3-5 Unknown <1 SOLUBILITY IN WATER APPEARANCE AND ODOR.; Complete 1 Com p Yullow to ember,liquid,. pH pleasant fragrance L 9 IS MATERIAL: (LIQUID) SOLID 5.0-7.0 GAS PASTE POWDER SECTION IV - FIRE AND EXPLOSION HAZARD DATA FLASH POINT METHOD USED - ASTM - D92 FLAMMABLE LIMITS None EXTINGUISHING MEDIA n/a CIAL FIRE FIGHTING PROCEDURES e —dSUAL FIRE AND E XPLOSION HAZARDS None I- va SECTION V - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE - CONDITIONS TO AVOID THRESHOLD LIMIT VALUE - Not established May cause skin and eye irritation: Avoid contain- • ination of food. Do not get in eyes; avoid contact with skin and clothing. CONDITIONS AGGRAVATED BY USE - Unknown - -• PRIMARY ROUTES OF ENTRY INHALATION SKIN CONTACT X OTHER (SPECIFY) EMERGENCY AND FIRST AID PROCEDURES If swallowed, drink large quantities of water.' In case of contact, immodlately flush eyes or skin with plenty of water for at least 15 minutes. If irritation perniate, seek modlcal attention. SECTION VI - REACTIVITY DATA 1 STABILITY: UNSTABLE STABLE X INCOMPATIBILITY (MATERIALS TO AVOID) - Strong oxidizers - - �w«- - - --- --- - �► HAZARDOUS DECOMPOSITION PRODUCTS - None known �- •- -i' ��^ HAZARDOUS'` MAY OCCUR POLYMERIZATION WILL NOT OCCUR X r<- SECTION VII - SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Flush with water through sanitary sewer system. WASTE DISPOSAL METHOD Same as above. I SECTION VIII - SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION (SPECIFY TYPE) None LOCAL EXHAUST (SPECIFY RATE) - Xy °"x;. VENTILATION: A .. .:/.syq�j' ;./ MECHANICAL.(GENERAL) (SPECIFY RATE) PROTECTIVE GLOVES (SPECIFY TYPE) EYE PROTECTION (SPECIFY TYPE) Rubber gloves Safety glasses OTHER PROTECTIVE EQUIPMENT None ( SECTION IX -.SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING Nothing special OTHER PRECAUTIONS - None Spartan Chemical Co., Inc. NAME Thomas J. Mitchell • Airlift Floral and Lemon (Bulk) TITLE Director of Research Ref: 29 CFR 1910:1200 (OSHA) DATE January 2, 1987 OSCC-1987 SUPERCEDES October R, 1985 I SPARTAN CHEMICAL CO., INC. MATERIAL SAFETY DATA SHEET SECTION I 1 PRODUCT IDENTIFICATION t PRODUCT NAME OR NJ43ER (as it appears on label) SAKI-T-10 MANUFACTURER'S NAME ENERGEN.'Y TELEPHONE E NO. Spartan Chemical Co., Inc. (419) 531-5551 ADDRESS (NlMffi2; STREET, CITY, STATE AND ZIP CODE) MAN FACTLRER'S D-U-N-S NO. 110 N. Westwood Ave., Toledo, OH 43607 00-503-6728 SECTION II I j HAZARDOUS INGREDIENTS Table Z-1-A ICAS REGISTRY NO. I SW ) OfXICAL NAME(S) I TWA ( STEL I Ceiling I CARCINOGEN ( . . 1. . I I KVV3 I M M3 I eaM3 139-08-2 5.0 Alkyl dimethyl benzyl ammonium chloride not established-- no 139-08-2 5.0 Alkyl dimethyl ethyl benzyl ammonium chloride --not established-- no SECTION III j PHYSICAL DATA BOILING POINT SPECIFIC GRAVITY (H20 =1) 210 of oC .992 VAPOR PRESSURE - 17 PERCENT SOLID BY 0 75 of oC x mm Hg _psi WEIGHT (%) VAPOR DENSITY (AIR = 1) EVAPORATION RATE (but. ace. 1) 10-11 Unknown <1 M I ILITY IN WATER APPEARANCE AND ODOR " Complete Water clear, nonviscous liquid pH Mild odor IS MATERIAL: (LIQUID) SOLID 7-8 GAS PASTE POWDER i SECTION IV I FIRE AND EXPLOSION HAZARD DATA I FLASH POINT - None HEM USED - ASTM - D92 FLAMMABLE LIMITS - n/a EXTINGUISHING MEDIA III n/a I SPECIAL FIRE FIGHTING PROCEDURES None UNUSU PL FIRE AND EXPLOSION HAZARDS None L SECTION V - HEALTH HAZARD DATA � EFFECTS OF OVEREXPOSURE - CONDITION TO AVOID THRESHOLD LIMIT VALUE - Not established Harmful or fatal if swallowed. Concentrated product causes severe eye and skin damage. Do not get in eyes, on skin, or on clothing. Acute oral LD50 5.5 gm/kg, rats PRIMARY ROUTES OF ENTRY IMWALATION SKIN CONTACT X OTHER (SPECIFY) CONDITIONS AGGRAVATED BY USE - Unknown EMERGENCY AND FIRST AID PROCEDURES - In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes. For eyes call a physician. Remove and wash all contaminated clothing before reuse. If swallowed, drink milk, egg whites, gelatin solution, or if these are not available, drink large quantities of water. Avoid alcohol. Call a physician. Note to Physician: Probable mucosal damage may contraindicate the use of.gastric lavage. Measures against circulatory shock, respiratory depression and convulsion may be needed. i SECTION VI - REACTIVITY DATA STMILITY:<•U NSTAELE STABLE X INCOMPATIBILITY (MATERIALS TO AVOID) Strong oxidizers HIVARDQS DECOMPOSITION PRODUCTS Co, .0O2 HATJARDous MAY OCCUR POLYMERIZATION: WILL NOT OCCUR x I SECTION VII - SPILL OR LEAK PROCEDURES STEPS TO BE TARN.IN CASE MATERIAL IS RELEASED OR SPILLED Small quantities may be flushed with large amounts of water into sanitary sewer. Larger quantities should be contained. WASTE DISPOSAL METHOD Same as above. Container Disposal: Triple rinse (or equivalent) then offer for recycling or reconditioning, or puncture and dispose of in a sanitary landfill, or by other procedures - approved by state and local authorities. ' SECTION VIII - SPECIAL PROTECTION INFORMATION ORMATIOI RESPIRATORY PROTECTION (SPECIFY TYPE) -.None VENTILATION - Good general ventilation should be sufficient for most conditions. Local exhaust ventilation maybe necessary for Jame cpe.-ations. PROTECTIVE GLOVES (SPECIFY TYPE) EYE PROTECTION (SPECIFY TYPE).. Rubber or other water-proof gloves Goggles or face shield OTHER PROTECTIVE EQUIPMENT None SECTION IX - SPECIAL PRECAUTIONS PRETJAUTIONS TO BE TAKEN IN HANDLING AND STORING Keep from freezing OTHER PRECAUTION None Spartan Chemical Co., Inc. NAME Thomas J. Mitchell SANNI-T-10 TITLE Director of Research Ref: 29 CFR 1910:1200 (OSHA) DATE June 1, 1990 SUPERCEDES Jant ary 15, 1987 'DSCC6/90 Copyrighted: Spartan Chemical Co. , Inc. - For Use Only By Authorized Spartan Distributors- ' r • Page 1 August 16,1990 SK-0029 MATERIAL SAFETY DATA SHEET H. B. Fuller Company - Monarch Division 3900 Jackson Street N. E. Minneapolis, Minnesota 55421 612/781/8071 Emergency Telephone Number 1-800-228-5635 PRODUCT IDENTIFICATION H. B. Fuller Company Name: SK-0029 Trade Name: Antisoil HF DOT Proper Shipping Name: Cleaning Compounds, Liquid, NOI HAZARDOUS INGREDIENTS Material Name/CAS # % Level OSHA PEL ACGIH TLV in Product (1986) Potassium Hydroxide < 2 NE 2 mg/M3-C (1310-58-3) "C" denotes a ceiling limit that should not be exceeded during any part of the working exposure. • PHYSICAL DATA: Physical State: Liquid . Boiling Range: >200 F. pH: >13 Percent Volatile by weight: 84.0 Weight per Gallon: 8.78 FIRE PROTECTION: Flash Point/Method: NA Appropriate Extinguisher: Nonflammable Special Fire Fighting Procedures: None known Unusual Fire and Explosion Hazards: Closed containers may rupture when exposed to extreme heat. Contact with some metals, particularly magnesium, aluminum and zinc (galvanized metal) can rapidly liberate hydrogen gas, which is explosive. REACTIVITY DATA: Stability: Stable Incompatibility: Acids, organic materials • Hazardous Decomposition Products: None Hazardous Polymerization: Will not occur Rage 2 August 16, 1990 d SK-0029 EFFECTS OF OVEREXPOSURE Acute: Harmful or fatal if swallowed. Causes burns to skin, eyes and mucous membranes. Mists or sprays TT wilt irritate and may damage upper t respiratory tract and lungs. Eye contact may result in permanent damage, even blindness. Chronic: No anticipated chronic effects. This product does not contain regulated levels of NTP, IARC or OSHA listed carcinogens. EMERGENCY AND FIRST AID PROCEDURES For Ingestion: If person can swallow, give one glass of water or milk. Do not induce vomiting. Get immediate medical attention. For Eye Contact: Flush immediately with water for 15 minutes. Get immediate medical attention. For Skin Contact: Wash affected area with soap and water. Remove contaminated clothing and launder before reuse. For Inhalation: Remove to fresh air. Get medical attention. ` OCCUPATIONAL CONTROL PROCEDURES Eye Protection: Chemical splash goggles, .eye wash. Skin Protection: Safety shower, rubber gloves, a , protective body covering. Respiratory Protection: Not normally required. Ventilation: Standard industrial ventilation. SPILL, LEAK AND DISPOSAL PROCEDURES Spill or Leak Procedures: Contain spill, dilute if necessary and neutralize with dilute acid. Remove with inert absorbent. Waste Disposal: Dispose of in accordance with Local , state and federal regulations. ADDITIONAL INFORMATION: Do not add water to concentrated alkaline solutions. Add product Slowly to water to prevent splattering. • I e 99-0083 Rev. 1 1128/88 • Material Safety Data Sheet Sensor, 02 Cell 24-0108 QUICK IDENTIFIER 11n PI—I Common H.or t.et.Q.BACHARACH, INC. T.kp��b.. (412) 963-2000 Add— 625 ALPHA DR. 1.1-6.n PITTSBURGH. PA. 16238 ca. (412) 963-2223 swn•tureol Perron D.0 ry ReVn..bb lu Prep.r.tim Prep.red SECTIONI-IDENTITY Co. —&ss'yn;ed no—i a�l� 02 Sensor Assewbly a.No 1310-58-3 chemical H.me chemical Potassium Hydroxide Electrolyte F.may Strong Inorganic Base For—la ' KOH + H2O SECTION 2-HAZARDOUS INGREDIENTS Prini pal H—doue Campmmtbl rM+dcd Q ca.mm n.mnen (CAS ✓I - Threshold ILm,V.I-- Potassium Hydroxide 1310-58-3 242 2 mg/m3 Caustic in all amounts SECTION 3-PHYSICAL&CHEMICAL CHARACTERISTICS(Fire&Explosion Data) • F +240 Gr.vuytH,o-u 2.044 a--ftNot Available Percent V.I.tO V.P. Etap.r.tim R.0 by Vol—o 802 D—hy tAn-It NA t It Solubility R—wity m Yes ;i W81e, Soluble, generates heat upon dilution. Colorless liquid with consistency more dense than eater. Slight odor. FL.h FWmn.bk limit. I— Upper E.tittgui.hn Aublgttitim Paint None inA6etbyVolume None b-di•Water spray, CO2 or dr3e11l gtff(cal. sSope.cci.l Fire Figlttu�g Procedure. None Umw.l Fve uA Eapk—H—d. None • SECTION 4-PHYSICAL HAZARDS Stability Unauble :,Ccndifiona Stable ,J(to Avoid Incompatabitity tMatariastr.Aeodi Reacts with some metals and organic materials. - Will react with water or steam to produce caustic solution and heat. ' H.serdoua Decomposition Products None Hazardous May Occur Conditions Pdymerization Will Not Occur K to Avoid SECTION 5-HEALTH HAZARDS Threshdd unit value 2 mg/m3 Signs and 1.A m cute syreptosofEaPoso,e o.ereaPosure Irritation d possible caustic burns of contact area. Y.Chronic Otmapmure Unknown. - Medical Condit."Generally Aggravaed by EcPosure Skin rashed. Chemical Listed a Carcinogen National Toixology Yes I.A.R.C. Yes : OSHA t'es :. orNtemidarcinogen Unknown Nogram No :Unki:own MonoV phs N° Unknown NO Unknown OSHA Permissible ACG I H Thresl..,k: Ochre E:powre ow Eapre omit Unknown Limltvam, Unknown Limit Uaed Unknown Emergency nd F rst Aid Procedures 1.Inhatalm NA ROUTES s.Eyes Wash with 5z boric acid solution. Call doctor. OF ENTRY s.skin Flood with water then wash with vinegar. a.Ingestion . . Give vinegar or juice of lemon, rz efruit or orange co iousl . SECTION 6-SPECIAL PROTECTION INFORMATION o ow with olive oil. Respiratory Protection (specifyTypel Not required. ventilation Local Mechanical sPecialventilationOl vides Not required Exhaust Not req'd tGenerw Not required comfort to personnel. b°h Advise rubber gloves. Protection Advise safety glasses or pop,°Les. • Other Protective CbthingorEquiP— Rubber apron. SECTION 7-SPECIAL PRECAUTIONS AND SPILLILEAK PROCEDURES ...:..: ;:.:;.;,;.:..,;_;;;,,.;.:,;....:.,.:,:;:, ..:.;.:,::;;:�::;>:•::....;.;:.:;..o::>::,. Precautions to araSTt«.ge Store in a cool dry place. Avoid crushing pkgs. Wear rubber gloves. . _ .. .. Hudbng 1 Safety glasses or goggles 6 handle gently when opening ekes or installing cell in Praec�aoti— instrument. Do not puncture cell membrane as potassium hydroxide electrolyte could be released. Steps w be Takm in Case Material u Released or Spilled Rinse area with mild acetic acid solution (vinegar) to neutralize then flush thoroughly with water. Waste Disposal Methods Dilute with water prior to introduction into waste system. Consult local • authorities regarding regulations for caustic solutions. IMPORTANT Do not leave any blank spaces.If required information is unavailable,unknown,or does not apply,so indicate. 1 r r w DESICCANT, DE-4 (Is" Dia.) ACTIVATED f DESICCANT, DE-28('/4" Dias)ALUMINA Material Safety Data Sheet PALL Maybe used to comply Communication Standard 24CFR y p y with OSHA's Hazard 1910.1200.Standard must be consulted for specific requirements. Pneumatic Products Corp. Supplier's Emergency Name PNEUMATIC PRODUCTS CORP. Telephone No. 904-237-1220 Address PNEUMATIC PRODUCTS CORP. Other 4647 S.W.40TH AVE. Information OCALA,FL 32674 Calls 904-237-1220 Signature of Person Date Responsible for Preparation HARRY M.SHAWL Prepared JUNE 1,1987 SECTION 1 - IDENTITY Common Name:(used use n( o label) Cas No. Made Name&Synonyms) ACTIVATED ALUMINA 1333-84-2 Chemical Chemical Name ALUMINA Family ALUMINUM OXIDE Formula A1203 (0-3%Water) SECTION 2 - HAZARDOUS INGREDIENTS Principal Hazardous Component(s)(chemical&common name(s) % Threshold Limit Value(units) None Known SECTION 3 - PHYSICAL & CHEMICAL CHARACTERISTICS (Fire & Explosion Data) Boiling Specific Vapor - Point N/A Gravity(H20=1) 3.2 Pressure(mm Hg) 1mm@ 2158oC Percent Volatile Vapor Evaporation Rate i by Volume M N/A Density(Air=1) N/A(solid) (H2O -= 1) N/A Solubility Reactivity in in Water -,.,.Insoluble Water N/A Appearance -- and Odor White Beads -Odorless Bulk Density = 44-52lbs/ft3 Flash Flammable Limits Iower Upper Extinguisher Auto-Ignition Point N/A in Air%by Volume N/A N/A Media N/A Temperance N/A Special Fire Fighting Procedures N/A Unusual Fire and Explosion Hazards None/Non-Flammable Form No.HCP4)006 Form Cat.No. 12160I8 SECTION 4 - PHYSICAL HAZARDS Stability Unstable o Conditions Stable x to Avoid None Known • �. Incompatibility I (Materials to Avoid) Slightly soluble in concentrated acids and alkalies. Hazardous j Decomposition Products None Known Hazardous May Occur o Conditions . Polymerization Will Not Occur it to Avoid i None Known I SECTION 5 - HEALTH HAZARDS Threshold Limit Value ACGIH-(84-85)nuisance particulate,TWA:10 mg/M'of total Lust(Air<1%quartz)or 5 mg/m3 respirable dust. Signs and Symptoms of Exposure None Known 1. Acute 2.Chronic I A very rare fibrosis of the lung following prolonged and heavy Overexposure None Overexposure inhalation exposure above the TLV Medical Conditions Generally Aggravated by Exposure Dust may effect any condition of the respiratory tract. Chemical Listed as Carcinogen National Toxicology Yes D I.A.RC. Yes 13 OSHA Yes o or Potential Carcinogen Program No A Monographs No X No X OSHA Permissible ACGIH Threshold Other Exposure Exposure Limit N/A Limit Value N/A Limit Used N/A Emergency and First Aid Procedures 1. Inhalation: Remove from area of exposure.Administer oxygen if breathing is difficult-Seek medical attention. 2. Eyes: Flush eyes thoroughly with large volumes of water.If irritation develops or persists,seek medical assistance. 1 - 3. Skin: Wash with soap and a large volume of water. 4. Ingestion: In,luce vomiting.Seek medical attention. y SECTION 6 - SPECIAL PROTECTION INFORMATION Respiratory Protection (Specify Type) Use a NIOSH/MSHA approved Dust Respirator. Ventilation Local Mechanical Special Other Recommended Exhaust Recommended (General) Recommended N/A N/A Protective Eye Gloves Recommended Protection Goggles recommended. Other Prntective { Clothing or Equipment Work uniform recommended. SECTION 7 - SPECIAL PRECAUTIONS AND SPILL/LEAK PROCEDURES Precautions to be Taken in Handling and Storage Store in a cool-dry place in tightly closed containers.Avoid direct or prolonged contact with eyes. Other Precautio:�s Avoid breathing dusts.Do not eat,drink or smoke in the work irea.Wash hands thoroughly after handling. I Steps to he Taken in Case Material is Released or Spilled Spilled material can be slippery.Vacuum or weep up immediately to minimize the chance of injury due to falls. Waste Disposal j Methods Dispose of unused desiccant in accordance with Federal,State and local regulations. • 1 I I ' r - HANDLING CAUTIONS As with all Desiccants or dry powders,a static electric charge can build up when pouring.Proper grounding should be observed when pouring from a bag or drum in the presence of flammable vapors. When transferring Desiccant with high pressure,wear goggles.Malfunction of equipment can propel bead with enough velocity to penetrate skin. Make sure that both the transfer system and receiving vessels are properly grounded.Follow standard operating procedures. SPECIAL CAUTION When disposing of used desiccant,material must be handled with special precautions. Desic- cant is an adsorbent material. Following contact with typical petrochemicals or gases, the combination of desiccant and retained material can be hazardo us,toxic and/or flammable.It is highly recommended that all used desiccant be analyzed to determine content before disposal. Appropriate care and procedures should be followed in handling and storage of used materials. Once content is determined,containers should be properly labeled and disposed of in accordance with Local, State and Federal Regulations. ADDITIONAL HEALTH HAZARDS INFORMATION The information contained herein is based upon data considered true and accurate.However,Pneumatic Products Corp.(PPC)makes no warranties(express or implied) as the accuracy or adequacy of the information contained herein or the results to be obtained from the use thereof.This information is offered solely for the user's consideration,investigation and verification.Since the use and conditions ofuseofthis information and the material described herein are not within the controlofPPC. PPC assumes no responsibility for iWury to the user or third persons.The material described herein is sold only pursuant to PPC's Terms and Conditions of sale, including those limiting warranties and remedies contained therein.itis the resDonsibilityofthe user todetermine whether any use ofthisdata and informationis in accordance with applicable federal,state or local laws and regulations. DE-60 C/16" Lia.) DF,-25 (y," Dia.) DE-38 Dia.) DE-51 (h" Dia.) MATERIAL SAFETY ,o DATA SHEET ATTENTION: Plant Manager/Safety Director: r This MSDS supersedes all prior data sheets received for this desiccant product.We urge you to study it carefully.This is provided with each container as our way of communicating Health,Safety and Environ- mental Protection information to our customers. This information is provided to ensure safe handling and storage of our products in accordance with OSHA Hazard Communication Stan- dard 29 CFR 1910.1200.The information contained in this MSDS must be passed on to all employees in your firm that handle and/or become involved in the implementation or control of operations involving use of the product.We strongly urge you to forward this MSDS to all parties that have a need to know the information contained herein! Pneumatic Products Corp. • DEC-12-90 TUE 1 5 :25 A I RCO N. E. H1'HNN I S 50 7781 922 P. 02 R C 0 - • M a t e r i a .l S a f e t y D a t o S h e e t Page: 2 Rev. Date NITROGEN, REFRIGERATED LIQUID 08/09/89 Airco, Division of The BOC Group, Inc. Telephone: (201) 464-8100 575 Mountain Avenue Murray Hill , NJ 07974 Emergency Contact: CHEMTREC Emergency Phone Number: (800) 424-9300 L.SECTION #1 - IDENTIFICATION Product: NITROGEN, REFRIGERATED LTQTJID CAS Number: 7727-37-9 Product Code: MSDS CODE G-101 Chemical Family: Inert Gas Chemical Formula: Liquified N2 Molecular weight: 28 . 00 • Synonyis: G-103 Hazard Rating - Health.. 2 Moderate - Fire: 0 Negligible Reactivity: 0 Negligible SECTION #2 - CHEMICAL COMPONENTS Component: NITROGEN CAS Number: 7727-37-9* Percent of Mixture: 99 . 9950 to 99�. 9990 Simple Asphyxiant - maintain oxygen levels above 19.5 percent SECTION #3 - PHYSICAL DATA Boiling Point: -320.4'F -195. 8'C Melting Point: -345.9'F -209.96C Vapor Pressure: Above critical temp, Vapor Density (Air-1) : 0.967 Solubility (H20) : Negligible Percent Volatiles: 100 • DEC-12-90 TIDE 15 :2.5 . AIRCID N. E. HYANNIS 5087781922 F'. 0 v M a t e r i a l S a f e t y D a t a S h e e t Page: 2 I Rev. Date • L NITROGEN, REFRIGERATED LIQUID_ _--- --_ -08/09/ 89 FSECTION 03 - PHYSICAL DATA Continued. . . Appearance A colorless liquid. odor Odorless. SECTION #4 - FIRE FIGHTING L EXPLOSION DATA Flash Point: None Lower Explosive Limit None Upper Explosive Limit None Fire and Explosion Hazards Non-flammable inert gas'. SECTION #5 - EXPOSURE and EFFECTS INHALATION • Routes of Exposure - Inhalation Nitrogen is a simple asphyxiant. Maintain oxygen levels above 19. 5% at Sea level. Effects of overexposure to high concentrations so as' to displace the oxygen in the air. necessary for life are headache, dizziness labored breathing and eventual unconsciousness. Other symptoms may inolude tightness in the frontal area of the forehead, rapid reduction in the ability to perform movements, loss of tactile sensations, weakened speech leading the inability to utter sounds and tingling of the tongue, fingertips or toes. Nitrogen is nontoxic, but the release of a large amount in a confined area could displace the oxygen in air necessary to support life. It should be recognized that it is possible that none of the above symptoms may occur in nitrogen asphyxia. Thus there are no DEFINITE warning symptoms. First Aid - Inhalation PROMPT MEDICAL ATTENTION IS MANDATORY IN ALL CASES OF OVEREXPOSURE. RESCUE PERSONNEL SHOULD HE EQUIPPED WITH SELF-CONTAINED-BREATHING APPARATUS . Conscious persons should be assisted to an uncontaminated area and inhale fresh air. Quick removal from the contaminated area is most important. Unconscious persons should be moved to an uncontaminated area, given artificial resuscitation and supplemental oxygen. Further treatment should be symptomatic and supportive. DEC-12-.90 TIDE 1 5 26 A I R.00 N. E. HYANN I S 0 8 7 72.1 '�22 P . 04 M a t e r i a l S a f e t y D a t a S. h e e t Page: 3 Rev. Date • NITROGEN, REFRIGERATED LIQUID 08/09/189 EXPOSURE and EFFECTS SKIN �8ECTION #_5_ Routes of Exposure - Skin Contact with cryogenic liquid or cold piping can cause tissue freezing or frostbite and cryogenic "burns". First Aid - skin For dermal contact or frostbite, flush affected area with tepid water. DO NOT USE HOT WATERS A physician should see the patient promptly if the cryogenic "burn" has resulted in blistering of the dermal surface or in deep tissue freezinq. SECTION #S - EXPOSURE and EFFECTS EYES Routes of Exposure - Eyes Contact with cryogenic liquid can cause tissue freezing or .frostbite and cryogenic "burns" of the eyes. First Aid - Eyes Never introduce ointment or oil into the eyes without medical advice! In case of freezing or cryogenic "burns" caused by rapidly evaporating liquid, • DO NOT WASH THE EYES WITH HOT OR EVEN TEPID WATER! Remove victim from the source of contamination. open eyelids wide to allow liquid to evaporate. If pain is present, refer the victim to -an ophthalmologist for treatment and follow up. If the victim cannot tolerate light, protect the eyes with a light bandage. 89CTION #5 - EXPOSURE . and EFFECTS INGESTION -------------- Routes of Exposure - Ingestion None known Ingestion is unlikely. Large quantities of cryogenic liquid may cause ireez Mg of tissue. First Aid - Ingestion Ingestion is unlikely. Treat in a similar manner as skin contact. Seek medical attention as soon as possible. DEC-12-.90 TUE 15 :26 AIRCO N. E. W.`ANNIS 5 0'__'7 7'8 1 9 2''2 F Ot. - ------------- FYade: 4 H a t e r i a t a S h e e t f e t y D a f Rev. Date • NITROGEN, RErRIGERATED LIQUID 08/09/89 SECTION #5 - MISCELLANEOUS TOXICOLOGICAL INFORKATION Carcinogenicity NTP: No IA-RC: No OSHA: No NOTE: Except where s ecified, the health hazard data and most of the other data in this material safety data sheet are for GASEOUS NITROGEN. One volume of liquid nitrogen at its boiling point and atmospheric pressure will vaporize into approximately 695 volumes of gaseous nitrogen at 70OF (21. 1,C) and 1 atmosphere of pressure! SECTION f6 - REACTIVITY a POLYMERIZATION Stability: Stable Conditions to Avoid (Stability) None known. Incompatible Materials None known. Hazardous Decomposition Products None known. • Hazardous polymerization: Will not occur. F SECTION #7 - SPILL$ LEAK, & DISPOSAL PROCEDURES_ Steps to be Taken in The Event of Spills, Leaks, or Release Evacuate all personnel from affected areas. Use appropriate protective equipment. if leak is in container or container valve, contact CHEMTREC or your closest Airco location for emergency assistance. positive pressure air line with mask or self-contained breathing apparatus should be available for emergency use. Do not enter area without respiratory protection due to asphyxiation hazard. Waste Disposal .Methods Do not attempt to dispose of waste or unused quantities. Return in the shipping container PROPERLY LABELED, WITH ANY VALVE OUTLET PLUGS OR CAPS SECURED AND VALVE PROTECTION CAP IN PLACE to Airco for proper disposal . E C-1 2-9 0 T Ll E 15 27 A 1 1,;'.C 0 t-4 E HY"N N 1 5 0 7 9 2 2 a t e r a a t Y D t a S t 5 Rev. Date • NITROGEN, REFRIGERATED LIQUID SPILL, LEAK, & DISPOSAL PROCEDURES Continued. . . SARA Hazard classes: Sudden Release of Pressure Hazard SECTIONS - SPECIAL PROTECTIVE MEASURES Ventilation Local exhaust to .prevent accumulation of high concentrations so as to reduce the oxygen level in the air to less than 19. 5 percent. Mechanical in accordance with electrical codes. Eye Protection Safety es lasses. For handling the liquid in open vessels, a face Me 0791 should gbe worn in addition to the safety glasses or goggles. Skin Protection Use loose fitting insulated gloves to prevent frostbite and cryogenic "burns" . Respiratory Protection • Positive pressure air line with mask or self-contained breathing apparatus should be available for emergency use. Other Protection Safety shoes. SECTION f9 - SPECIAL PRZCAUTIONS STORAGE i HANDLING Storage & Handling Conditions Use only in well-ventilated areas in accordance with manufacturer's and Airco/BOC instructions. These cylinders 'must ALWAYS be kept upright. Specialized trucks are needed for their movement. Do not drag, slide or roll C linders. Stationary customer site vessels should be operated in accordance w th the manufacturer's and Airco/BOCIS instructions. Do not attempt t to . repair, adjust or in any other way modify the operation of these vessels. If there is a malfunction or other type of operations problem, with the vessel, contact the closest Airco/BOC location immediately for assistance. Do not store vessels in sub-surface or closed (poorly ventilated) areas. Nitrogen gas can cause suffocation without warning. Liquid nitrogen is delivered into stationary vacuum jacketed vessels at the customer's location or in portable vacuum-jacketed "liquid" cylinders requiring special handling methods . D E C-1 2:,-9 T 0 E 1 5 2 7 1 R,C 0 M. E. H H N 1 S 503 7 1 SO2 2 F* 0 f M a t ,e r i a l S a f e t Y D a t a S h e e t Page: 6 Ray. Date iNITROGEN, REFRIGERATED LIQUID 08/09/89 FSEC ------------- TION #9 &SPECIAL PRECAUTIONS - STORAGE HANDLING Continued. . .SECTION & Handling Conditions - W� i- -- Consult manufacturer's instructions. special Packaging Recommendations: Liquid nitrogen cannot be handled in carbon or low alloy steels. 18-8 and 18-10 stainless steel and copper, copper alloys, nickel, nickel alloys, brass, bronze, silicon alloys, Monet (R) Inconel (R) and beryllium are acceptable. For additional recommendations, consult Compressed Gas Association Pamphlets P-9, P-12, P-14 and Safety Bulletin SB-2 . Never carry a compressed as cylinder or a container of a gas in cryogenic liquid form in an enclosed space such as a car trunk, van or station wagon. A leak can result in a fire, explosion, asphyxiation or a toxic exposure. Liquid density at Boilincl Point 50. 46 lb/ft3 (808. 3 Kg/m3) . SECTION #10 - SHIPPING INFORMATION Proper Shipping Name: Nitrogen, Refrigerated Liquid Hazard class: Nonflammable Gas • DOT Identification Number: UN1977 DOT Shipping Label : Nonflammable Gas SECTION #11 - HISC COMMENTS & REFERENCE DOCUMENTATION Liquid nitrogen vessels should not be* refilled except by qualified producers of compressed gases. Shipments of liquid nitrogen vessels, which have not been filled by the owner or with his (written) consent, is a violation of Federal Law (49CFR) . DISCLAIMER OF EXPRESSED AND IMPLIED WARRANTIES Although reasonable care has been taken in the preparation of this document, we extend no warranties and make no representations as to the accuracy 'or completeness of the information contained therein and assume no responsibility regarding the suitability of this Information for the user's intended purposes or for the consequences of its use. Each individual should make a determination as to the suitability of the information for their particular purpose(s) . TOWN' ' Or BARNSTABLE COMPLIANCE: �� CLASS; 1. Marine,Gas Stations,Repair Q satisfactory 2• Printers [ {� D O�' -ICALTH 3. puto Body Shops d Q unsatisfactory- 4. Manufacturers COMPANY �--�I`` Q(�_ (rz POW) C I (see"Orders") S. Retail Stores ter ���t�,�� l 6. fuel Suppliers ADDRESS %'I,�j�.)E� 011t �I C 7. Miscellaneous— QUANTITIES _ Classt AND STORAGE (IN=indoors; OUT-outdoor. MAJOR MATERIALS • Case - lots Drums - AbOveTanks Undetgroi,ad Tanks IHL INQIIZ .Iti_ ___a to I Ions &M r�w Fuels: • Gasoline, Jet Fuel (A) Diesel, Kerosene, 02 (B) Heavy Oils: r- waste motor oil - (C) new motor oil (C) transmission/hydraulic Synthetic Organics: degreasers • •Miscellaneous-: Aco ISPOSAL RCCL M T ON RUV RKS: . 1. Sanitary Sewage 2. Water Supply O Town Sewer ® Public fi0042 -7r) i AIfit IAI I)M On-site l� Q Private �_ l '"1�* ����'! /�_ 3. Indoor Floor Drains: YES NO _ __ � .- !11 + V�,��1 Q Holding tank: MOC ^ � fi O Catch basin/Dry well ..___...M_._. ___.._ ........_...__.._..� _ URVERY: On-site system wlu, W(; q. Outdoor Surface drains:YES NO O IloldinE tank: MDC �41IL/ /'1 �g(r, I fitl�LJf� Catch basin/Dry well �C OOn-site system S. Waste Transporter Licensed? hma""aliinr- ,Destination kjas a Product. �ES] NO 2. .-r Xd 12 2J 81 IP erson s Interviewed , Inspector Date .=1 GAPE COD Independence Park • Breeds Hill Road Hyannis, MA 02601 %Uto C* 508-775-3358 Donna Miorandi Board of Health Town of Barnstable PO BOX 534 Hyannis, MA 02601 RE: Hazardous Materials Storage September 27, 1991 Dear Ms. Miorandi, I have attached an updated Toxic and Hazardous Materials Registration Form. Please note that acetic acid is stored outside in product-tight and environment- tight containers and is located within diked, secondary containment. Cape Cod Potato Chips feels this storage is adequate to meet the intent of Article XXXIX, Sections 4 and 5 and therefore requests a variance o 1T q c f the protected from the elements" clause in Section 4(b). Finally, nitrogen is also stored outside in a manner similar to acetic acid. Cape Cod Potato Chips is requesting a determination if the nitrogen is a hazardous material, and if so, requests the same variance requested for acetic acid. If you require further information or would like to schedule a visit, please, call me at 775-3358. Sincerely, Bart Petracca Quality Control ter+ v ,-,,,--'TOXIC AND HAZARDOUS MATERIALS REGISTRATION FORM r Mail To: NAME OF BUSINESS: �- �,sc < i�Ti ��% �' �11� r� <<;rl`P�I tf y Board of Health MAILING ADDRESS: //20' 64 rr� f-fti--1. /1 D Town of Barnstable r� P.O. Box 534 TELEPHONE NUMBER: (5 o 0 -)75 S Sh CONTACT PERSON: �}C,C A Hyannis, MA 02601 Does your firm store any of the toxic or hazardous materials listed below, either for sale or for your own use, in quantities totalling, at any time, more than 50 gallonsliquid volume or 25 pounds dry weight? YES NO This form must be returned to the Board of Health regardless of a yes or no answer. Use the enclosed envelope for your convenience. If you answered YES above, please indicate if the materials are stored at a site other than your mailing address: ADDRESS: n TELEPHONE: LIST OF TOXIC AND HAZARDOUS MATERIALS The Board of Health has determined that the following products exhibit toxic or hazardous characteristics and must be registered when stored in quantities totalling more than 50 gallonsliquid volume or 25 poundsdry weight. Please put a check beside each product that you store: V Antifreeze (for gasoline or coolant systems) Drain cleaners Automatic transmission fluid Toilet cleaners Engine and radiator flushes /Cesspool cleaners Hydraulic fluid (including brake fluid) V Disinfectants _ y/- Motor oils/waste oils Road Salt (Halite) 1� Gasoline, Jet fuel Refrigerants Diesel fuel, kerosene, #2 heating oil V1 Pesticides (insecticides, herbicides, Other petroleum products: grease, lubricants rodenticides)(&fm Degreasers for engines and metal Photochemlcals (fixers and developers) Degreasers for driveways & garages Printing ink Battery acid (electrolyte) r()f.KI-►F'r Wood preservatives (creosote) Rustproofers Swimming pool chlorine Car wash detergents Lye or caustic soda Car waxes and polishes Jewelry cleaners Asphalt & roofing tar Leather dyes Paints, varnishes, stains, dyes Fertilizers (if stored outdoors) ✓/ Paint & lacquer thinners PCB's V Paint & varnish removers, deglossers Other chlorinated hydrocarbons, Paint brush cleaners (inc. carbon tetrachloride) Floor & furniture strippers Any other products with "Poison" labels Metal.polishes (including chloroform, formaldehyde, Laundry soil & stain removers hydrochloric acid, other acids) (including bleach) Other products not listed which you feel may Spot removers & cleaning fluids be toxic or hazardous (please list): (dry cleaners) 0I-i V Other cleaning solvents A U-II -UIS Pt Bug and tar removers Household cleansers, oven cleaners White Copy-Health Department/ Canary Copy-Business -E,��,- BARNSTABLE FIRE DEPARTMENT ry 4b�pBL/syfe 3249 Main Street-P.O.Box 94 ox 1927 Barnstable,Massachusetts 02630 508-362-3312 FAX: 508-362-8444 WILLIAM A.JONES III,CHIEF GLENN B.COFFIN, CAPTAIN FIRE PREVENTION January 6, 1993 V Ms. Donna Miorandi Board of Health Town of Barnstable 367 Main Street Hyannis, MA 02601 - Dear Donna, Please find enclosed, a copy of a letter mailed to you by the Cape Cod Potato Chip Company. This letter references the storage of acetic acid. This compound is located in the area of the waste water treatment area. My concern arose during my annual inspection to the facility. Basically, the storage of the chemical is outside and uncovered. I asked if this was acceptable to your office. I also stated that I was concerned that the storage area was not covered and that possibly the diked area was insufficient to contain all of the acetic acid. My understanding of this compound is that it is not a substance that we want to spill in that area. In the best interests of the Cape Cod Company, I propose that you and I discuss the problem and work with them to find a better method for storage. I would certainly favor storage in line with State Building Code standards. I would very much appreciate your assistance and would request any specifications that you have already proposed to the company. I look forward to hearing from you. - S i ncere 1 - enn Cptain 1-Wi77iam Wrigh 1-Bart Petracca 1-Chief Jones I l ` Wl-�UN:CHHE LUL) I H I u I U 14 ge Biro."dS Hill Hin. N" P I y 1.f;, MA fp 0 1 u) p U[.G 71992 PA.W TA U L E F 111 E D Donna Mforandi 1-3oard of Hoalth Town of Darnstable PO BOX 534 MA 026101 RE'- Hazardouis Kato.jltjjs3 ip PeOtelflbo- 27, 1991 bear Ms. Mlorandf, INIfilei,in4i R,,�gjlstratfon Fon-ji. I have atl�wheo [n). updated 0-)�d Hit Please note that vcptic 'Add is r0red de b ,n, tt'g'ht and Is 1w,uktiwl within diked, st.,--Comlnry C011tidwilinit, Cape Cod ol Potato Chips re 'o this MOVIT!e Is adequatc. to "110CA "bu, inlpnt W,. Article X-1,111VIM Sections 4 and 5 fill(.1 a vilt,11xt1ce of th"! 11py.-ofteeted from the defl)F.Mts" clause in S'�1(Ajoji 4(b) . l"inally, 111trog("t) 1,9 also st(Pr d outsido it' it ru'-11'111er eindlar to acetic pm:!Id. CRpe Cod 1101-tito ChIpi3 is requestiog, a j is 01)(1 if so, v��queste the srjjj-,C, V-aj,jtjjj f, Q� UNUHNAeCt for acetic acid. If You re-quiro further 111fon-lindorl woukl 'to Cbeduln, a VISH, JAI e a e call Ino at 775-33158. t-,) pelrae(,-1:1 QUjIfity C011,61,C)l Post-It-brand fax transmittal rnomo ;C)i1 or papo p r"0111 Mpl. Fax# raxg The Town of Barnstable Health Department 1 " 611. 367 Main Street, Hyannis, MA 02601 rua � of �679• \� �0 o�Y*- Office 508-790-6265 Thomas A. McKean FAX 508-775-3344 Director of Public Health December 9, 1992 Mr. Bart Petracca Cape Cod Potato Chips Independence Park-Breeds Hill Road Hyannis, MA 02601 Dear Mr. Petracca: It is the recommendation of the Town of Barnstable Health Department that the containers for acetic acid stored outside in a bermed area at the Cape Cod Potato Chips facility be placed in 100% containment . If you have any questions regarding this decision please call this department at 790-6265. .f/ c� Thomas A. McKean Director of Public Health (C ;K E f t f l � Lt.. �. d(• R .ta Y Y# -17 U m ) January 15, 1993 Dear Capt. Coffin, I am in receipt of your recent letter dated January 6, 1993.and I am in total agreement with you on the matter regarding Cape Cod Potato Chipis outside storage of acetic acid. Attached is a copy of a recent letter to Bart Petracca and above are copies of pictures that I have recently taken. I shall be in contact with Bart regarding the status of this storage and please give me a call if you would like to make another joint visit. S' cerely, a Donna Miorandi o.Tx�to,, The Town of Barnstable Health Department 367 Main Street, Hyannis, MA 02601 rua . g .639• � �0■A�6' Office 508-790-6265 Thomas A. McKean FAX 508-775-3344 Director of Public Health December 9, 1992 Mr. Bart Petracca Cape Cod Potato Chips Independence Park-Breeds Hill Road Hyannis, MA 02601 Dear Mr. Petracca: It is the recommendation of the Town of Barnstable Health Department that the containers for acetic acid stored outside in a bermed area at the Cape Cod Potato Chips facility be placed in 100% containment . If you have any questions regarding this decision please call this department at 790-6265. i Thomas A. McKean Director of Public Health v 1 A Summary of Requirements for Small Quantity Generators of Hazardous Waste Updated March 1, 1991 Prepared by: Massachusetts Depament of Environmental Protection Division of Hazardous Waste l Winter Street Boston.MA 02108 (617)292-5898 Publication No.17,003.17.1000-12-91-.35-C.R. Approved bv:Philmore Anderson III,State Purchasing Agent INTRODUCTION Many essential services, including auto repair and dry- cleaners and institutions, such as schools and hospitals, produce hazardous waste. If you use cleaning solvents, oil , inks, paints, acids, or alkalines, for example, you may be a generator of hazardous waste. As a generator, it is your responsibility to know your legal obligations under the Massachusetts Hazardous Waste Regulations. Inappropriate handling and disposal of hazardous waste has damaged water supplies and threatened human health. Increasingly, businesses find that meeting the legal requirements is good practice that protects the environment, the equity in their property and their neighbors and employees. Under the "Superfund" law, you are liable for your hazardous waste and any damage it causes even after it leaves your site and is taken away by a transporter to a treatment, storage or disposal facility. You can be required to contribute to the costs of cleaning up any contamination, resulting from your wastes wherever they end up. It is important, therefore, that you determine how to prevent pollution before it begins. The cost of waste disposal and liability coverage is escalating._ Landfilling of many hazardous wastes is now banned. There are few commercial hazardous waste disposal facilities and their capacity is limited. Reducing the amount of your hazardous waste may be the most economical and environmentally sound approach to meeting your requirements. Substituting non-hazardous for hazardous products, modifying your process, segregating non-hazardous from hazardous waste streams, recycling your waste and better housekeeping should be key considerations for you. The Massachusetts Department of Environmental Protection (DEP) regulates all non-households (businesses and institutions) which generate any amount of hazardous waste. Radioactive wastes, unless mixed with hazardous waste, and infectious wastes are regulated by the Massachusetts Department of Public Health as well as by federal agencies. This brochure is a summary of a portion of the Massachusetts Hazardous Waste Regulations and is organized as follows: Classification Paperwork Housekeeping Very Small Quantity Generators 1 It is designed to help you understand the regulations and will assist you in meeting your legal obligation and avoiding potential penalties. However, it is not a substitute for reading and complying with the full Hazardous Waste Regulations 310 CMR 30. 000. Because Massachusetts requirements are more stringent than the federal requirements, you will be in compliance with federal hazardous waste regulations when you meet the state standards. The complete regulations are available at the State House Bookstores. You can have them sent to you by calling Boston's bookstore (617) 727-2834, or (413) 784-1376 in Springfield. Ask for the most recent compilation of 310 CMR 30.000. For a specific fact sheet for your industry, which will provide more detailed information, call the Hazardous Waste Regulatory Program's Compliance Assistance Line at (617) 292-5898. Two other products from the Department of Environmental Protection which may help you understand the regulations are: "Little Things Mean a Lot": a 14-minute video with a short friendly message outlining the basic steps in appropriate hazardous waste management Available to borrow from DEP without charge by calling (617) 292-5898 or to purchase ($20.00) from Media Source, 45 Casco Street, Portland, ME 04101 (207) 774-1230. Small Quantity Generator Workbook: A Self-Help Guide for Small Quantity Generators of Hazardous Waste Available for purchase ($3 . 10 + handling) at the State House Bookstores 2 CLASSIFICATION Determine whether your waste is hazardous ( 310 CMR 30 . 100 ) common hazardous wastes are: - waste oil - solvents and thinners - acids and bases/alkalines - toxic or flammable paint wastes - nitrates , perchlorates and peroxides - abandoned or used pesticides - some wastewater treatment sludges There are two ways a waste may be identified as hazardous : it may be listed in the regulations ( 310 CMR 30 . 131-136 ) or it may be defined by*.its hazardous characteristic ( 310 CMR 30 . 120 ) . Hazardous waste may be a listed discarded chemical, an off-specification product, or a liquid or solid residue from an operation process, which has one or more of the characteristics below: * Ignitable (easily catches fire, flash point <1400F) ; * Corrosive (easily corrodes materials or human tissue, very acidic or alkaline , pH of <2 or >12. 5 ) ; * Reactive (explosive, produces toxic gases when mixed with water or acid) ; * Toxic (can leach toxic chemicals as determined by a special laboratory test) ; Your waste is considered acutely hazardous if it is on the list of acutely hazardous wastes ( 310 CMR 30 . 136 ) . These wastes are extremely toxic or reactive and are regulated more strictly than other hazardous wastes . To find out if your waste is hazardous check with: * the supplier of the product ( request a hazardous material safety data sheet) ; * laboratories ; * trade associations ; * consulting engineers ; and verify by reviewing zhe Massachusetts Hazardous Waste Regulations . 3- Determine your generator status and regulatory requirements Two activities determine your generator category: the rate at which you generate and how much you store (accumulate) . The amount and length of time you can accumulate your wastes will vary according to the type of waste. A Large Quantity Generator (LQG) generates more than 1, 000 kilograms (2200 ibs. ) of hazardous waste in a month, or more than 1 kilogram of acutely hazardous waste (acutely hazardous waste is listed in the Massachusetts regulations, 310 CMR 30. 136) . The waste must be shipped within 90 days. There is no limit to the amount which can be accumulated. A Small Quantity Generator (SQG) generates less than 1, 000 kilograms in a month, and/or less than 1 kilogram of acutely hazardous waste. The waste must be shipped within 180 days and is limited to 6000 kilograms in underground tanks and 2000 kilograms in above ground containers. A Very Small Quantity Generator (VSQG) generates less than 100 kilograms in a month and generates no acutely hazardous waste. To understand how you are regulated, estimate your maximum monthly volume of waste oil and your maximum monthly volume of all other hazardous waste. The Guide to Determining Status and Regulatory Requirements on page 5 will assist you. Example: Your firm generates 55 gallons of spent solvent and 500 gallons of waste oil in a month. According to the Guide (see conversions) , you are a Small Quantity Generator (SQG) of hazardous waste because you produce more than 100 kilograms but less than 1000 kilograms, and a Large Quantity Generator (LQG) of waste oil because you produce more than 1000 kilograms. Your regulatory status will be found in Line 2 . You may accumulate your' solvent for as long as 180 days, or until you have reached a volume of 2000 kilograms (500 gallons) in containers (see page 10) , whichever happens first (Column 2) . You must ship your waste oil every 90 days, regardless of the volume (Column 3) . You must obtain an EPA Identification Number and use a manifest for both wastes (Column 4) . You must manage your waste according to the accumulation area standards on page 8 and you must fulfill the emergency preparation and response requirements on page 11. You are not required to file an annual report or a contingency plan or provide full personnel training, which is necessary for larger generators. 4 GUIDE TO DETERMINING STATUS AND REGULATORY REQUMMENTS This matrix does not reflect ACUTELY Hazardous waste Regulatory Status Hazardous Waste Management Waste Oil Management Transport Requirements Management Requirements Accumulation Limits Accumulation Limits Hazardous Wade Time Volume In Volume In Time volume In volume In Mud Can Use May Sell Accumulation Emergency Pereonnei Wade ON PEA Tar" Conlainers (Days) Tent Cortalners Ube Lop or Transport Area Preparation Tnainbng 6 Mantled MaMed Haz Wade Standarde Contingency for and/or Plans a Wade ON Wade ON BIOMW NA N LQG LQG 90 NO LIMIT NO LIMIT 90 NO LIMIT NO LIMIT YES YES YES O T LQG SQG 90 NO LIMIT NO LIMIT 180 6000- 2000 YES YES YES I g LQG VSQG 90 NO LUAIT NO LIFT NO LIMIT 600 600 YES YEStw'w YESam YES I C LQG NONE 90 NO LIMIT NO LEMJT N/A NIA N/A YES YES YES A .T SQG LQG 180 6000* 2000 90 NO LIMIT NO LIMIT YES YES YES I O SQG SQG 180 6000 2000 ISO 6000 2000 YES YES YES N SQG VBQG 180 6000 2000 NO LIMIT 600 600 YES YES(W'o) YESaiw) YES rn T O SQG NONE 180 6000** 2000 N/A N/A N/A YES YES YES E VSQG LQG NO LIMIT 600 600 90 NO LIMIT NO LIMIT YES YESUM YES(w/o) YES P -- A NONE LQG N/A N/A N/A 90 NO LIMIT NO LIMIT YES YES YES T VSQG SQG NO LIMIT 600 600 180 6000~ 2000 YES YES YES(jiw) YES(w/o) YES O VSQG VSQG NO LIMIT 600 600 NO LIMIT 600 600 YES YES YES D VSQG NONE NO LIMIT 600 600 N/A N/A N/A YES YES E P NONE SQG N/A N/A N/A 180 6000� 2000 YES YES YES NONE VSQG N/A N/A N/A NO LIMIT 600 600 YES YES YES • -A manifest may be used for the VSQG category unless self transported. •••When accumulating in both tanks and containers,the total accumulation cannot exceed 6,000 kilograms and the container accumulation cannot exceed 2,000 kilograms. Definitions: Regulatory Status Kilotu•ams/Month(Generation) Conversions: Kil2amns Pounds Gallons(varies by substance) LQG 1000 OR MORE 100 220 25-27 SQG 100-999 600 1320 ISO- 165 VSQG LESS THAN 100 1000 2200 250-265 2000 4400 600-650 RAs/CENTRAL 6000 13,230 1500- 1650 PAPERWORK The Manifest (310 CMR 30.310) As a generator you always retain responsibility for your hazardous waste. If your waste is dumped or disposed of improperly, you can be held responsible. It is therefore important that you know where your waste is going and that it is handled properly and safely. Federal law (the Resource Conservation and Recovery Act of 1976, known as RCRA) requires a national 'cradle to grave' tracking system for hazardous waste. In Massachusetts, every shipment of hazardous waste by a large or small generator must be transported by a licensed hauler and sent to a licensed treatment, storage or disposal facility (TSDF) or a permitted recycling facility and must be accompanied by a shipping document, called the Uniform Hazardous Waste Manifest. You must use the Massachusetts Manifest form unless you are sending your waste to a facility out of state, in which case you should contact the other state to find out which form to use. You are responsible for completing the generator portion of the manifest. Directions for the distribution of the copies are on the back of the manifest. A copy will be returned to you when the facility has accepted your shipment. If you do not receive a copy of the manifest from the receiving facility within 35 days of the date when your waste was shipped, you should contact your transporter or the operator of the facility to determine the status of your waste. if you have still not received the manifest within 45 days, you must file an Exception Report, explaining the efforts you've taken, with the DEP' s Division of Hazardous Waste and with the state where the designated facility is located. Note the generator's certification statement on your manifest, which you must sign: "If I am a small quantity generator, I have made a good faith effort to minimize my waste generation and select the best waste management method that is available to me and that I can afford. " All generators must keep copies of all manifests and any records of tests and analyses done of their hazardous waste for at least 3 years, and for the duration of any enforcement action. 6 Exception for Small and very Small Generators of Waste oil (310 CMR 30. 253 (8) ) If you are a small or very small quantity generator and ship only waste oil or are a Very Small Quantity Generator of other waste (see Lines 5, 6,7 , 8 of the Guide) , you may use a transporter's log instead of a manifest for that shipment. However, you must register on a prescribed form with the DEP (see page 16) . The EPA Identification Number (EPA ID) (310 CMR" 30.303) In order to have your waste accepted by a licensed hauler or treatment/storage facility, you will be assigned a 9-digit number, with the prefix 'MAD' , for your location. This number will be entered on each manifest in Block 1. In order to get an EPA ID, call DEP (1-800-343-3420) for an application for an EPA Identification Number. Mail the completed application to the office listed in the instructions. Your number will be mailed to you within a few months. While you are waiting for a permanent EPA ID, you can obtain a temporary EPA ID over the phone. The ID number is site-specific. You are required to notify DEP's Division of Hazardous Waste of any change in,your address, name of company, contact person or generator status. Shipping Your Hazardous Waste (310 CMR 30. 304, 30. 305) All hazardous waste must be transported in containers that are labeled with the words HAZARDOUS WASTE, the name of the waste, type of hazard (e.g. , toxic, flammable) , generator's name, address and EPA ID number. Refer to the container standards described on page 8 of this summary. A list of licensed transporters and Massachusetts treatment, storage or disposal facilities is available from DEP by calling (617) 292-5822 . Many transporters are authorized to assist you in preparing your waste for shipment. 7 HOUSEKEEPING Accumulation Area Standards ( 310 CMR 30. 351[8 ) ) Your accumulation or storage area must meet the following conditions for both containers and tanks: * Above-ground tanks and containers must be on a surface which does not have any cracks or gaps and is impervious to the hazardous wastes being stored; * Area must be secured against unauthorized entry; * Area must be clearly marked (e.g. , by a visible line or tape, or by a fence) and be separate from any points of generation; * Area must be posted with a sign: "HAZARDOUS WASTE" in capital letters at least one inch high; * An outdoor area must have secondary containment, such as a berm or dike, which will hold any spill or leaks at: - 10% of the total volume of the containers , or - 110% of the volume of the largest container, whichever is larger. Any spillage must be promptly removed. ( In general, if the hazardous waste being stored has no free liquids, no pad or berm is required, provided that the accumulation area is sloped, or the containers are elevated. ) Standards for Containers and Tanks ( 310 CMR 30.680 , 30 . 690 ) * Each container and tank must be clearly and visibly labeled throughout the period of accumulation with the following: - the words "HAZARDOUS WASTE" waste oil, acetone) - the name of the waste (e.g. , ignitable , toxic , - the type of hazard( s ) (e.g. , 9 dangerous when wet, corrosive) - date on which the accumulation began. } Each container must be in good condition. * Wastes of different types must be segregated. For example , this includes not mixing waste oil or used fuel oil with other wastes . Be careful not to put incompatible wastes in the same container or put wastes in unwashed containers that previously held incompatible wastes. 8 Or Separate containers of incompatible wastes by a berm, dike Cr similar structure. * Each container holding hazardous wastes must be tightly dosed throughout the period of accumulation, except when the waste is being added or removed. Or Containers holding ignitable or reactive wastes must be at least 15 meters ( 50 ft) from the property line. If this is not possible or practical you must store such containers in compliance with all applicable local ordinances and by- laws. Or Inspect your accumulation area at least once a week for any leaking or deterioration of your containers. you must have enough aisle space between your containers to allow for inspections% DRUMS MUST BE LABELED i\.•11 � FH A I d RD'0„•�, RLE RRD RST U S � T E �1ifOE C'UARSs!W ". .. ' d. 1.1 N tYl 1.� teats. ..,..=sq.l. :DP.LJM c _ t00C Ko. 9 Accumulation Time Limits (310 CMR 30. 351[5] ) As a small quantity generator (SQG) , you may accumulate up to 2o00 kgs or 4400 lbs in containers, or up to 6000. kgs (approx- imately 1650 gallons) in tanks for as long as 180 days. you have two upper limits - time and volume. Whichever is reached first determines the date on which you must ship your waste. If both tanks and containers are used to store hazardous waste and/or waste oil, the total waste which can be accumulated at any one time may not be determined by adding the two limits. Satellite Accumulation (310 CMR 30. 351[4) ) Additional flexibility is offered by allowing you to accumulate up to 55 gallons of hazardous waste, or one quart of acutely hazardous waste, at each point where you generate your waste, if you .meet th e following conditions: • The waste must be generated from a process at the location of the satellite accumulation; • Each satellite accumulation area can have only one container for each waste stream in use at a time; • Each satellite accumulation area must be managed by the person who is directly responsible for the process producing the waste; • The waste must be moved to the main designated accumula- tion area within three days after the container is full Accumulation of Waste oil in Underground Tanks (including those resting directly on the ground) [310 CMR 30. 253 (1) (h) ] All underground tanks must have a spill prevention device such as a removable funnel with at least a 12 inch diameter. • To prevent leaks, single-walled tanks which do not have continuous leak detection capability must be dip-stick tested weekly and tightness tested annually. • Keep a log of all test results, beginning and ending measurements, variation and average figures, for at least 3 years. • Report a difference of a month's average greater than 5 gallons (for tanks containing 550 gallons or less) to your DEP regional office. 10 EMERGENCY PREPARATION AND RESPONSE ( 310 CMR 30 . 351 ( 9 ) ) Equipment To minimize the risk of fire, explosion, or release of hazardous wastes that may contaminate the environment, you are required to have on site, and immediately accessible to your hazardous waste handling area, the following ( unless the hazards ,-- posed by your wastes do not require one of them) : * an alarm or communication system which can provide emergency. instruction to employees ; * a telephone , two-way radio or other device which can summon police, fire, or emergency response teams; * portable fire extinguishers and/or fire control equipment (e.g. , foam, inert gas ) , and spill control/decontamination equipment; * adequate supply and pressure of water, automatic sprinklers or water sprays , or foam-producing equipment. All your equipment must be periodically tested and properly maintained so it will work during an emergency. Prepare Your Employees You must thoroughly familiarize each of your employees with all the waste handling and emergency procedures that may be needed for each of their jobs . An employee must have immediate access to alarm or communication devices , either directly or through another employee , whenever hazardous waste is being handled. If your operation is at any time being handled by a single employee, that person must have immediate access to a telephone or two-way radio. c equipment , For easy .movement of employees and emergency you must maintain adequate aisle space in the area of hazardous waste handling. Mark all exits clearly. Notify Local Authorities You must make every reasonable attempt to carry out the following arrangements , in regards to the waste you produce : I ll i * Familiarize your police department ,- fire department , local boards of health, and any emergency response teams with the hazardous nature of your waste ; the layout of yoar site, including entrances and evacuation routes , and the locat_on where your employees usually work; * Familiarize local hospitals with the hazards of your waste and the types of injuries that could result from any accidents; * Obtain agreements reements with emergency response teams and contractors , and local boards of health; * If more than one police and/or fire department might ke an th the respond to an ent whichewillchaveaprimarygemergencyreement l department and specify others as support. If such arrangements cannot be made, a copy of a signed and dated letter from you, the generator, to the state or local make these arrangements entity which demonstrates an eff ort to m will be co nsidered sufficient. Emergency Coordinator You must designate at least one employee to be on call (or on the premises ) at all times. This person is the emergency coordinator and is responsible for coordinating all emergency response measures. Emergency Response You must have posted next to each telephone near your waste generation area the following: * name( s) and telephone number( s ) of your emergency coordinator( s ) ; * location( s) of the fire control equipment and any fire alarms; * telephone number of the fire department , or if there is a direct alarm system, instructions on how to use it ; * evacuation routes , where applicable. 12 If any of the following emergencies occur: - Fire - attempt to extinguish the fire and/or call the fire department; • Spill or leak - contain the flow as quickly as possible and as soon as is practical, clean up the waste and any soil or other materials which may have become contaminated with waste; • A release (spill or leak) or threat of release, fire or explosion of hazardous waste that may threaten human health or the environment Call the appropriate DEP Regional Office (see page 17) Call the State Police (617-566-4500) if the incident occurs after 5 p.m. , or on a day that DEP is closed, and Call the National Response Center's 24-hour toll-free number (1-800-424-8802) . 13 VERY SMALL QUANTITY GENERATOR (VSQG) (310 CMR 30 .353) Registration If you generate less than 100 kgs a month of hazardous waste, and no acutely hazardous waste, you are eligible to register as a Very Small Quantity Generator (see page 5 for the generation and accumulation limits) . To qualify as a Very Small Quantity Generator you must register your waste management plan with DEP (see page 16) . If you do not register as a VSQG, you are subject to the more stringent SQG regulations. Treatment/Disposal options As a registered VSQG you have the following options for handling your waste: • You may recycle or treat your waste, provided the process you describe in your registration is acceptable to DEP; You may transport your waste to another generator who is in p compliance with the regulations will count our comP ulations and who Y waste as part of their generation; • You may transport your waste in your own vehicle to a licensed treatment, storage or disposal facility, or permitted recycling facility, by pre-arrangement; • You may use a licensed transporter and a manifest form. Use of the manifest requires an ID number. (For VSQG's and SQG's of waste oil a number beginning with the letters 'MAV' is assigned over the telephone -1-800-292-3420. ) Self-Transport Option As a registered VSQG you may transport your own hazardous waste under the following conditions: • You transport only the waste that you generated on your premises; • You do not transport more than 200 kgs at one time; 14 VSQG (cont. ) • Your waste is in containers that are: - no larger than 55 gallons in volume - compatible with the waste - tightly sealed - labeled as "HAZARDOUS WASTE" - labeled with the name of the waste and the type of hazard - tightly secured to the vehicle • You do not transport incompatible wastes in the same shipment; • In the event of a spill or leak of hazardous waste that may threaten human-health or the environment you notify DEP or the State Police and the National Response Center, as described on page 13 ; • You must have a copy of your registration with DEP in the vehicle; • You must be in compliance with federal Department of Transportation (617-494-2770) and Massachusetts Department of Public Safety (617-566-4500) requirements. Record-keeping If you are not using a licensed transporter but are transporting your own wastes, you do not need an ID number or manifest form. You must, however, keep a record of the type and quantity, as well as the date, of the transport and treatment or disposal of your waste. You will need proof of the receipt of the waste by the facility or generator. You must keep receipts or manifests of waste shipped and records of waste analysis for at least 3 years, or for the duration of any enforcement action by DEP. Accumulation Limits You may accumulate up to 600 kgs (approximately 165 gallons or three 55 gallon drums) of hazardous waste in containers that meet the standards on pages 8-9 with no time limit. 15 SAMPLE REGISTRATION FORM for VSQG ' s and SQG's of waste oil i COMM OF MASS - DEP GENERATOR REGISTRATION CA I am req00tnp as: _ very Smsi War"Gann SW al NOVO .Wgete(rage than V paaona�month) — WE _ very Small OLWV&y Generator of Wse Of(lam Vm 77 psaorte Per morAh) i or Small Oumndty GaNrclor of Waste Of (tees than 2n 90Nons Par not") I i 14WE Or ooarAW Ea.aara0 AppR� e*r,EET atr on TOM � I [ I #Zola=a m twan a meemEp ?ELfra,OnE i M. . . _ . T/►E o•KwaE w e= D M\NNEa,«r,.er.6,0."m Hazardous Waste Gallons per Month Disposal,Storage,Treatment ajor R"cling: Generated: r..e Prlor to Treatment (►+arr earroaM+aoeaw MTMfe ww"Is awn or Recycling: or type a Iron,0n on one a porWasm) i Wes ON Sptiera Ado a Nat Orw..{nano) 1 CPMVY LWO RKALTY Or LAW NI,h. ..8 a v fr,MwY o!,to~wW16lnrM w to am~am as fr mm vc IV& � O-w an wr ra^of rs«►rusm P-00e+r rowwwm Mr saw"A I"I sea I Mr.q r a to Iftffl% ,•lH..a magm wo ewvvmM i 1 aI1TI e10Ma p wwE Op owMEn On CPV►MTOa, KEV WrA copy -smo WWR COVY To OV 16 Number Fee 1137 THE COMMONWEALTH OF MASSACHUSETTS $150.00 Town of Barnstable Board of Health This is to Certify that CAPE COD POTATO CHIPS ................................................................................................................................ 100 Breed's Hill Road, BARNSTABLE, MA ........................................................................................................................................................................ Is Hereby Granted a License For: Storing or Handling 500 gallons or more of Hazardous Materials. .................................................................................................................................................................... Restrictions: .................................................................................................................................................................... This license is granted in conformity with the Statutes and ordinances relating there to, and expires 06/30/2021 unless sooner suspended or revoked. JOHN NORMAN DONALD A.GUADAGNOLI,M.D. 07/01/2020 PAUL J.CANNIFF,D.M.D. THOMAS A.MCKEAN,R.S.,CHO Director of Public Health �Iw I 1 /00 161-e'-dy 3) 9 D� °FtNE row Town of Barnstable Office:508-862-4644 Public Health Division Fax:508-790-6304 BAaM�`E ' 200 Main Street• Hyannis, MA 02601 ,6'9• TOXIC AND HAZARDOUS MATERIALS INSPECTION REPORT 'OTfD MP'�s Business Name: -in. o� a wG2. wqF� o.rge ? -T Date: / L < k `t C-90 e-rn CA I Location/Mailin Addr ss I$O A,<D°-cam l�Jcw , va,r,n,s �— Contact Name/Phone: 1G% l"A. 1-1 a,no � - -�'71- %q4 0 Inventory Total Amount: MSDS: p License#: Tier II : Mo Labeling: QV- Spill Plan: Oil/WaterSeparator: Floor Drains: N o Emergency Numbers: Storage Areas/Tanks: ..ems Emer enc /Containme t E ui ment: 1Ns e4 v5.c oY \ s Waste Generator ID: N I A Waste Product: Date&Amount of Last Shipment/Frequency: Licensed Waste Hauler&Destination: Other Waste Disposal Methods: LIST OF TOXIC AND HAZARDOUS MATERIALS NOTE: Under the provisions of Ch. 111, Section 31, of the General Laws of MA, hazardous material use, storage and disposal of 111 gallons or more requires a license from the Public Health Division. Antifreeze Dry cleaning fluids Automatic transmission fluid Other cleaning solvents&spot removers Engine and radiator flushes Bug and tar removers Hydraulic fluid (including brake fluid) Windshield wash Motor oils Miscellaneous Corrosives Gasoline,jet fuel, aviation gas Cesspool cleaners Diesel fuel, kerosene, #2 heating oil Disinfectants Miscellaneous petroleum products: Road salts grease, lubricants, gear oil Refrigerants Degreasers for engines&garages Pesticides: Caulk/Grout insecticides, herbicides, rodenticides Battery acid (electrolyte)/batteries3-\\t''kc, Photochemicals(Fixers) Rustproofersp ��� Photochemicals(Developer) Car wash detergents Printing ink Car waxes and polishes Wood preservatives(creosote) Asphalt&roofing tar Swimming pool chlorine Paints, varnishes, stains, dyes Lye or caustic soda Lacquer thinners Miscellaneous Combustible Paint&varnish removers, deglossers Leather dyes Miscellaneous Flammables Fertilizers Floor&furniture strippers PCB's Metal polishes Other chlorinated hydrocarbons Laundry soil&stain removers (including carbon tetrachloride) (including bleach) Any other products with "poison labels" (including chloroform,formaldehyde, hydrochloric acid, other acids) VIOLATIONS: ORDERS: INFORMATION/RECOMMENDATIONS: tC,L�ASL�`Q- v�r v.e a d Inspector: Facility Representative: WHITE COPY- HEALTH DEPARTMENT/CANARY COPY-BUSINESS 0 • Town of Barnstable 7 64M,6 -Q A { Inspectional Services BARNSTABLE Public Health Division �•.M• = Thomas McKean,Director a° •`� 200 Main Street, Hyannis,MA 02601 i Office: 508-862-4644 Fax: 508-790-6304 i APPLICATION FOR PERMIT TO STORE AND/OR UTILIZE HAZARDOUS MATERIALS IN ACCORDANCE WITH THE TOWN OF BARNSTABLE GENERAL ORDINANCE,CHAPTER 108, HAZARDOUS MATERIALS,ALL BUSINESSES THAT HANDLE OR STORE HAZARDOUS MATERIALS GREATER THAN HOUSEHOLD QUANTITIES ARE REQUIRED TO OBTAIN AN ANNUAL PERMIT(RUNS JULY 1st—JUKE 30th). APPLICATION FEES � CATEGORY 1 PERMIT 26— 110 Gallons: $ 50.00 O I CATEGORY 3 PERMIT 500 or more Gallons: $50.00 � *A late charge of$10.00 will be assessed if payment is not received by July 1st. � 1. ASSESSOR'S MAP AND PARCEL NO. / t+ ` O V� J 2. IS THIS A PERMIT RENEWAL? YES NO. IF YES,SKIP QUESTION 3. • 3. FOR ALL NEW PERMIT APPLICATIONS,INDICATE WHETHER BUSINESS HAS ZONINGBUILDING APPROVAL FOR HAZARDOUS MATERIALS STORAGE/USE OF GREATER THAN HOUSEHOLD QUANTITIES(25 GALLONS)? YES NO. 4. FULL NAME OF APPLICANT: �J - L Stu c k s M4. L Ld, 5. NAME OF ESTABLISHMENT: G ' 61110's 6. ADDRESS OF ESTABLISHMENT: 4 � /t 7. MAILING ADDRESS(IF DIFFERENT FROM ABOVE: 8. TELEPHONE NUMBER OF ESTABLISHMENT: ?7 3-.F J O 9. EMAIL ADDRESS: rgpj_. J O ggL62 Inn aI Is ccam 10. SOLEOWNER: 'V YES—NO IF NO,NAME OF PARTNER: 11. FULL NAME,HOME ADDRESS,AND TELEPHONE#OF: [ 0 CORPORATION NAME J'�� Cl l !li C L C PRESmENT TREASURER CLERK 12. IF PREPARED BY OUTSIDE PART NAME: TELEPHONE#: I COMPANY A: S EMAIL: SIGNATURE OF APPLICAN DATE 2� QA1Application Fonns\Haz Mat App Reviscd 0-18 tx 1 `9 Corporation Name: S-L Snacks MA, LLC 13S1S Ballantyne Corporate Place,Charlotte NC 28277 Officers: Keith McLoughlin—Interim President&'Chief Executive Officer Anthony P.DiSilvestro—Treasurer Gail Sharps Myers-Secretary t v\ Number Fee 1137 THE COMMONWEALTH OF MASSACHUSETTS 1oo.00 Town of Barnstable Board of Health This is to Certify that CAPE COD POTATO CHIPS 100 BREED'S HILL ROAD, BARNSTABLE, MA Is Hereby Granted a License FOR: STORING OR HANDLING 111 GALLONS OR MORE OF HAZARDOUS MATERIALS. -------------------------------------------------------------------------------------------------------------------------------------------------------------------- ----------------------------------------------------------------------------------------------------------------------------------------------------------------- This license is granted in conformity with the Statutes and ordinances relating there to, and and expires 06/30/2016 unless sooner suspended or revoked. --------------------------------------- WAYNE MILLER,M.D.,CHAIRMAN PAUL J.CANNIFF,D.M.D. 07/01/2015 JUNICHI SAWAYANAGI THOMAS A.MCKEAN,R.S.,CHO Director of Public Health cP i Town of Barnstable • � , Regulatory Services Thomas F. Geiler,Director 9r"B Public Health Division 9� F p1� Thomas McKean,Director 200 Main Street, Hyannis, MA 02601 Office: 508-862-4644 Fax: 508-790-6304 Application Fee: $100.00 ASSESSORS MAP AND PARCEL NO. ✓ / DATE APPLICATION FOR PERMIT TO STORE AND/OR UTILIZE MORE THAN 111 GALLONS OF HAZARDOUS MATERIALS FULL NAME OF APPLICANT 9/ / Pr 4,e,/<5 ' " I Lb� NAME OF ESTABLISHMENT &cp e t o b Ao uLtv Chi nJ • ADDRESS OF ESTABLISHMENT V D TELEPHONE NUMBERd -, SOLE OWNER: YES_C NO IF APPLICANT IS A PARTNERSHIP,FULL NAME AND HOME ADDRESS OF ALL PARTNERS: IF APPLICANT IS A CORPORATION: FEDERAL IDENTIFICATION NO. �5 9® 0 , STATE OF INCORPORATION &I e" FULL NAME AND HOME ADDRESS OF: PRESIDENT a TREASURER CLERK . sGhho ; PLat Y11(rr2 f • SIGNATURE APPLICANT RESTRICTIONS: HOME ADDRESS C��L) -TELEPHONE # 75 17- 7J0 q- d5&7 i Haz.doc/wp/q • MAIL-IN REQUESTS Please mail the completed application form to the address below. Also include a copy of your contingency plan (to handle hazardous waste spills, etc). In addition, please include the required fee of $100. Make check payable to: Town of Barnstable. Allow five to seven (7) working days for in-house processing. Our mailing address is: Town of Barnstable Public Health Division 200 Main Street Hyannis,MA 02601 FOR FAXED REQUESTS Our fax number is (508) 790-6304. Please fax a completed application form. Also, please fax us a copy of your contingency plan(to handle hazardous waste spills, etc). In addition, please mail the required fee amount of$100.00. Please make the check payable to: Town of Barnstable. The check must be mailed • to the address listed above. Allow up to four days for in-house processing. For further assistance on any item above,call(508)862-4644 Back to Main Public Health Division Page • w w' ti • S-L Snacks MA,LLC List of Officers as of May 3. 2013: • Carl E.lee: President&COO 13024 Ballantyne Corporate Place Suite 900 Charlotte, NC 28277 • Rick D.Puckett: CFO& EVP 13024 Ballantyne Corporate Place Suite 900 Charlotte, NC 28277 Margaret E.Wicklund:VP, Controller, Secretary 13024 Ballantyne Corporate Place Suite 900 Charlotte, NC 28277 • Troy W. Bryce: VP and Treasurer 13024 Ballantyne Corporate Place Suite 900 Charlotte, NC 28277 Patrick S.Mcinerney:VP of Manufacturing • 13024 Ballantyne Corporate Place Suite 900 Charlotte, NC 28277 • A.Zachary Smith III: Secretary 13024 Ballantyne Corporate Place Suite 900 Charlotte, NC 28277 Michael C.Anderson: Assistant Secretary 13024 Ballantyne Corporate Place Suite 900 Charlotte, NC 28277 • Town of Barnstable Office: 508-862-4644 Fax: 508-790-6304 Regulatory Services Department • sn3v3tnnt ' Public Health Division MASS. Thomas A.McKean,CHO °may ` 200 Main Street, Hyannis, MA 02601 Payment Receipt. Hazardous Materials Payment received: $100.00 (Check) on 6/18/2015 Permit number: 1137 i 'Check number: 447246 Check amount: $100.00 Name on check: Snyder's Lance IBusiness: CAPE COD POTATO CHIPS Address: 100 Breed's Hill Road , Hyannis 1 a • • t `°p,ME►� Town of Barnstable Office:508-862-4644 Public Health Division Fax:508-790-6304 • RnRM SS. • 200 Main Street• Hyannis, MA 02601 �'D�EDMP�a`0� TOXIC AND p HAZARDOUS MATERIALS INSPECTION REPORT Business Name: C-a 4 `oA-e,Vo C, n,, Svc A;,cs - L„avtce- Date: Location/Mailing Address: 100 <-gRX'5 HiA V,%V1 1I 5 Contact Name/Phone: Bew• eSc lnlne s o, < $"o - yllb- 1OC ea/1 7S?-78y-oS6-7 ooj ZyV9 S ©ov��r- r,KV. MS! IJo--r'2- •i rQ-44w — fnv2ss f ovt s,�-c- Inventory Total Amount: S.e,�•414 +0'4 fio 0c/— MSDS: &-oK i► -g 6k4w- License#: 113�1 CO�L+3 Tier II :Da NIJDq,A&oJA Labelina: ood Spill Plan: Skc- Oil/Water Separator: Floor Drains: -7 WWI Emergency Numbers: e-47 Storage Areas/Tanks: 3 AL<N labW&Ak,--(tgft\Qv1A41g) k&41r oweP,li p4,11,- �L V All l c,a.IcIV-As Emergency/ContainmentEquipment: • �1� k.ks- o.l-r,1a��k�k vw��ri� 4pc ��,s�Q > `,ss-N40�1 Waste Generator ID: i 00000 g Q;S Waste Product: a� wl-5 -t - aRVwVAaWa-;, Date&Amount of Last Shipment/Frequency: 31 (611t, 1�0 A a,l Y< Licensed Waste Hauler&Destination: Other Waste Disposal Methods: Sk< 121 W-1k u"e < \N it 1u,. «n a aateQ . tom \w C einA�w\ MevsS LIST OF TOXIC AND HAZARDOUS MATERIALS 1Jo w,�, or c.\w s „ti ,vtvy Stv\ce.Ias-!' ►,� ,°,,� . NOTE: Under the provisions of Ch. 111, Section 31, of the�eneral L%-Xs of MA, hazardous material use, (wJ¢VVI storage and disposal of 111 gallons or more requires a license from the Public Health Division. �,�,� ..—✓ P zaty,r Antifreeze Dry cleaning fluids wwT-Q,�6kc� Automatic transmission fluid Other cleaning solvents&spot removers ;zv,ir Engine and radiator flushes Bug and tar removers Hydraulic fluid (including brake fluid) Windshield wash a1 WAN Motor oils Miscellaneous Corrosives'] 3D Q Gasoline,jet fuel, aviation gas Cesspool cleaners . A'Kts 0 Diesel fuel, kerosene, #2 heating oil Disinfectants Miscellaneous petroleum products: Road salts grease, lubricants, gear oil Refrigerants Degreasers for engines&garages Pesticides: Caulk/Grout insecticides, herbicides, rodenticides Battery acid (electrolyte)/batteries Photochemicals(Fixers) Rustproofers Photochemicals(Developer) Car wash detergents Printing ink Car waxes and polishes Wood preservatives(creosote) Asphalt&roofing tar Swimming pool chlorine Paints, varnishes, stains, dyes Lye or caustic soda Lacquer thinners Miscellaneous Combustible Paint&varnish removers, deglossers Leather dyes Miscellaneous Flammables Fertilizers Floor&furniture strippers PCB's Metal polishes Other chlorinated hydrocarbons Laundry soil &stain removers (including carbon tetrachloride) (including bleach) Any other products with "poison labels" (including chloroform, formaldehyde, hydrochloric acid, other acids) VIOLATIONS: ORDERS: INFORMATION/RECOMMENDATIONS: 4v--t, VW�vwlC v m of w v�o C, •\\5 0 w 'kk ova . I)A \ ov\, 4 r-I e-ah 5,�* r,a b v,. . -K d tcw !y,//k,+s. �ft&A\ o�7kkoof kawy a�r'1a\�Q %y rho lowy-� .��Jl col Dea9.e tro ,,,� a c Sk\?A,AALX o`, Inspector: o Facility Representative* VV WHITE COPY- HEALTH DEPARTMENT/CANARY COPY-BUSINESS °p IKE rog, Town of Barnstable Office:508-862-4644 Public Health Division Fax:508-7s0-6304 • BARMAq .g` 200 Main Street• Hyannis, MA 02601 �A t639•ewe TOXIC AND HAZARDOUS MATERIALS INSPECTION REPORT rfD MA'S Business Name: C e— D-A-+0 aids Date: Location/Mailin Address: e 6 l ao 'S Contact Name/Phone: ZlfiAyly %v .3"ti o S M r -`11S- 01� , cet r--, V-or 7 MS�lecte� w/�ic�'.�.S�tb �v1J. g r Inventory Total Amount: CC+nofcg MSDS: 26 - b �'• License#: Ii�VY�7,�,,.�,,��{- Tier II : �C O1'`� Labelino: �7oy9 Sill Plan: '�`�`�I CIO Oil/WaterSeparator: Floor Drains: o0lt,14- Emergency Numbers: VeS Storage Areas/Tanks: See SP -t /1¢3-,)d;Q - Oau�' -275 44t Emergency/Containment Equipment: 510.I1► ,+ ij, , P - �� rlc C.tca,nt�►ti emwfa,nrk¢ /�' Waste Generator ID: J Waste Product: la b rnJ4ste�rIPvw/�r °�)-r o-js) � Date&Amount of Last Shipment/Frequency: 10 2Z r y ,53-1a I)C 3 ,Mos• Licensed Waste Hauler&Destination: r w'�'�e� MA Other Waste Disposal Methods: n#A,�5►-1� u�as ww��r D��'f-TeA�-�-,�e.K+ Q)4vC LIST OF TOXIC AND HAZARDOUS MATERIALS See OfCl- X4f4a/''a{Gk-aol .caQoQ� cx�CorrpStvp fog �u ,A NOTE: Under the provisions of Ch. 111, Section 31, of the General Laws of MA, hazardous material use,A,,,,,,,,,Wjp-e fob storage and disposal of 111 gallons or more requires a license from the Public Health Division. Antifreeze Dry cleaning fluids Automatic transmission fluid Other cleaning solvents&spot removers Engine and radiator flushes Bug and tar removers Hydraulic fluid (including brake fluid) Windshield wash `n Motor oils Miscellaneous Corrosives Gasoline,jet fuel, aviation gas Cesspool cleaners -t � Diesel fuel, kerosene, #2 heating oil Disinfectants Miscellaneous petroleum products: Road salts grease, lubricants, gear oil Refrigerants Degreasers for engines&garages Pesticides: Caulk/Grout insecticides, herbicides, rodenticides Battery acid (electrolyte)/batteries Photochemicals(Fixers) Rustproofers Photochemicals(Developer) Car wash detergents Printing ink Car waxes and polishes Wood preservatives(creosote) Asphalt&roofing tar Swimming pool chlorine Paints, varnishes, stains, dyes Lye or caustic soda Lacquer thinners Miscellaneous Combustible Paint&varnish removers, deglossers Leather dyes Miscellaneous Flammables Fertilizers Floor&furniture strippers PCB's Metal polishes Other chlorinated hydrocarbons Laundry soil &stain removers (including carbon tetrachloride) (including bleach) Any other products with "poison labels" (including chloroform, formaldehyde, hydrochloric acid, other acids) VIOLATIONS: ORDERS: INFORMATION/RECOMMENDATIONS: evt, -I"O v of C +�►u2.. qo'-�a -5-voyy&I O-IT.- Ct,d6 bOBdj 2-S,S9�1 o2,r�w�5 �a-�d D� r-3o�Q-lePf�►rc--Inspector: H;Z,�v0� I qb5�a Facility Representative: WHITE COPY-HEALTH DEPARTMENT/CANARY COPY-BUSINESS -f rJ toe, e J��.00l3 '- l.,! �m��•,� ��.v6 rG � r ,2. _1/,.l�- t 5w�lL-Fs-Ae mr 9f6m v� l �/f O 141) -{ SDy 13a "V �m 3-27st4� C05 6.0Sa -� �, C' -- 7l1!-IZ' '' "' .� �� ' , . �� ,� � � d }�' ►_ � . < <� �, � -, ,�; � ��. ._ ,� . .. it . t _ ,{ � -- �� ��� �D n UPI ��� �I� I � 1 p:i J � � J- HMO �r� 4 fDda! n '1 :�7� n 0 Apn+11) c ' Date: TOWN OF BARNSTABLE , G�,o� TOXIC AND HAZARDOUS MATERIALS FMRSTFU940N FORM NAME OF BUSINESS: C A e- k, s BUSINESS LOCATION: I oo ( ot-e-l' F4, 11 INVENTORY MAILING ADDRESS: jawt.e-- TOTAL AMOUNT: TELEPHONE NUMBER: '5 8 -y/g - l Do q ..ire CONTACT PERSON: 94CAAy2%j ►Qvesc, a K 14vwi_ y � I A 10,1 EMERGENCY CONTACT TELEPHONE NUMBER: Ce// -7$y-oS67 MSDS ON SITE? TYPE OF BUSINESS: od coGC✓S 1 -Gae , I,} Yes INFORMATION / RECOMMENDATIONS: '),MSS-}-a ta,Y, 4owK- Ili c�o�s Fire District: "-f Z)40LM,+ kk!eym t ' IM✓2vctory cK e Spec ,DIer,Vlk- tile— I a, ,o YL. 3� vt,�A i r' a, � cJ�c.e ►ti ,n o�- ►vt S.c._ `� tYt s��Ge 1 v a rtie. /a lv�/1 - a 6 c ijt S/�e_ o l ogro wL 4 5 �� Itia�ct! Iaag+�'; Waste Transportation: n'IAyODDDo�34�5� Last shipment of hazardous waste: ,2 /7 / Name of Hauler: Ge-e,,►L_ Na<Iaocs Destination: .bra !q Waste Product: tgg5 e o► l t la.b -F��-�1� l�4• Licensed e No /�'If ►t�OS3 ysZ�37 NOTE: Under the provisions of Ch. 111, Section 31, of the General Laws of MA, hazardous material use, storage and disposal of 111 gallons or more a month requires a license from the,,Public Healo Division. LIST OF TOXIC AND HAZARDOUS MATERIALS �- 4a Iae_ f covi ��'� �I�I/►`f The Board of Health and the Public Health Division have determined that the following products exhibit toxic or hazardous characteristics and must be registered regardless of volume. Observed / Maximum Observed / Maximum Antifreeze (for gasoline or coolant systems) Miscellaneous Corrosive ❑ NEW ❑ USED Cesspool cleaners Automatic transmission fluid Disinfectants Engine and radiator flushes Road salts (Halite) Hydraulic fluid (including brake fluid) Refrigerants Motor Oils Pesticides ❑ NEW ❑ USED (insecticides, herbicides, rodenticides) Gasoline, Jet fuel,Aviation gas Photochemicals (Fixers) Diesel Fuel, kerosene, #2 heating oil ❑ NEW ❑ USED Miscellaneous petroleum products: grease, Photochemicals (Developer) lubricants, gear oil ❑ NEW ❑ USED Degreasers for engines and metal Printing ink Degreasers for driveways&garages Wood preservatives (creosote) Caulk/Grout Swimming pool chlorine Battery acid (electrolyte)/Batteries Lye or caustic soda Rustproofers Miscellaneous Combustible Car wash detergents Leather dyes Car waxes and polishes Fertilizers Asphalt&roofing tar PCB's Paints, varnishes, stains, dyes Other chlorinated hydrocarbons, Lacquer thinners (including carbon tetrachloride) ❑ NEW ❑ USED Any other products with "poison" labels (including chloroform,formaldehyde, Paint&varnish removers, deglossers hydrochloric acid, other acids) Miscellaneous. Flammables Other products not listed which you feel Floor&furniture strippers may be toxic or hazardous (please list): Metal polishes Laundry soil &stain removers (including bleach) �5!9'l V Amt M(Xzee D 1•JC51.e— Spot removers&cleaning fluids (dry cleaners) -- �5. Q I t o n, Xry vK_ b t-)4,i�e_ . Other cleaning solvents Bug and tar removers Windshield wash WHITE COPY-HEALTH DEPARTMENT I CANARY COPY-BUSINESS Applicant's Signature Staff's Initials Page 1 of 1 Lavelle, Timothy From: Bethany Rueschhoff[brueschhoff@snyderslance.com] Sent: Thursday, March 27, 2014 1:55 PM To: Lavelle, Timothy Cc: Wesley McGhee; Pat Blake; Jeffrey Spooner; Steve Jones Subject: Hazardous Material Follow-up on Behalf of Snyders Lance Inc-Cape Cod Chip Plant Tim, Good afternoon. I am following up to our conversation from last week. • Our completed application along with the $100 application fee went out in the mail on Tuesday, 3/25 • Attached is our Official 2014 SPCC plan good for 5 years With regards to the list of chemicals: My storeroom manager whom you met during your visit compiled for us adist of chemicals. However, in reviewing this list it is my belief that a significant number of the items are no longer used or kept on site. In order to file with the town the most accurate, comprehensive, and up-to-date list I am requesting an additional week to submit. I appreciate you working with us on this. Please contact me if you have any questions. Bethany Rueschhoff Hyannis Plant Manager Snyder's-Lance Inc. 508-418-1009 Cell 757-784-0567 i 2/13/2015 Ca-le- C—OA 1P©-t-a--gym L1n� s Material Safety Sheet s i Data y b .1 I Quality Control 'T- Y Product Description Used as Home Department Amount Last Pucha UOM 4KM72-Lubricant White Past Anti-Seize Maintenance Acetic Acid 56%-58% Clear liquid Analytical Testing Acetic Acid, Glacial Clear liquid Analytical Testing Acetone Liquid Reducer Maintenance Acetylene Colorless Gas Welding Maintenance Ag/AgCI Colorless Liquid Electrode Filling Solution Waste Water Airlube AA Clear Liquid Maintenance Alconox White powder Dishwasher Quality Control Anionic Flocculant 3640 White Viscous, q opaque li liquid Flocculent Waste Water Anionic _ gal Pnhimar Fire Su Ansul R-102 Pink Liquid Fire Maintenance Ansulex Low pH Liquid Fluoressant Yellow Liquid Fire Suppressant Maintenance Anti Seize Food Grade Off white Paste Anti seize Maintenance AP32,46,68,100 Biocyn It.Tan Synthetic oil Lube Oil Maintenance Argon Colorless Gas Welding Maintenance Aries 0100C Milky White Aqueous Slurry pH Adjustment Waste Water new 275 gal 7n1'27/Nn Azolla ZS 68 Amber Liquid Gear Oil Urshels Maintenance Batteries Fork Lift Forklift Batteries Forklift Batteries Plant Operations un nano, _ each ( ) 7 Fnrkl ift Batteries Lithium Can type enclosed Portable drills/Light Maintenance Bi-Chem Odor Controller Opaque Liquid Herbel Fragrar Odor Control Waste Water BKP 650 Bio-Kleen Clear Liquid Alkaline/Glycol Cleaner Sanitation Non o,arrinii - gal 1 Blue Layout Fluid Blue thin viscosity fluid Metal Layout work Maintenance Borchlor 5 Sodium H ochlorite Gm/Yel Liquid Bleach Chlorination Waste Water Pooium no Purch i gal 1 ( yp q I-Ivnnrthlnri Bromophenol Blue Sol. .04% Blue Liquid Lab Testing(Indicator) Quality Control Brush Top Anti Seize Food Grade Off white Paste Lubricant Maintenance Buffer Solution Ph 10.00 Clear, colorless or Blue liquid Reagent Waste Water Buffer Solution PH 4.0 Red Liquid Ana lyticalCalibration Quality Control Buffer Solution PH 7.0 Yellow liquid Analytical Calibration Quality Control i Calcium Carbonate White powder Analytical Testing Quality Control Cantex#99 Clear Liquid PVC Solvent cement Maintenance ChargePak 47 Coagulant Lt. Yellow/Amber Liquid Coagulant in WWT Waste Water o rannrtahia 935 gal j Material Safety Data Sheets Quality Control Chemgrate, Chemdeck Green With Grit Platform Floors Maintenance tsutyi Crystal Simple Green Clear Viscous Liquid Cleaning Maintenance r.piinCniviA no Purch i gal AS Dalsorb White pwder Oil Filtration process, removes FFA of Filtration 901nt act 70,000 Ibs Dimethyamine,40%in water Colorless liquid Analytical Testing Quality Control Drewfloc 2270 White Viscous, opaque liquid Waste Water Anionic quid Flocculent as P q Pnlumcr 50 gal Drewfloc 444 Crystaline Off-white Powder Cationic Polymer Flocculant Waste Water New 1nni�R a, 100 Ibs Drewplus ED-750 Foam Control Defoamer White to yellow Liq.De Foamer Waste Water New F 35 gal Dri-Clean White powder Cleaning glassware Quality Control Easy Arc 308 AC/DC Rod Welding Maintenance Easy Arc 6011C(all) Covered Electrode Welding Maintenance Easy Arc 7018MR(all) Covered Electrode Welding Maintenance Epoxy, Catalyzed,Water-Based Liquid Paint Maintenance Extreme Simple Green Clear Liquid Degreaser Waste Water Clear Viscous Liquid Cleaning Maintenance tsutyi - gal ExtremeSimple Green q 9 ('.allnenlvc Eyesaline Solution Colorless Liquid Eyewash Production Fast Orange W/pumice White Lotion Hand Cleaner Maintenance Fisan 500-New 2010 Liquid Li Sanitation soawm Light Yellow Cleaners an q 9 - gal Nurlrnvirla Fisan Det Sanitation 55 OH 55 gal Fleetline 205-New 2010 Liquid Brown solvent Cleaners Sanitation 145 OH 1,910 gal Fluid Cutting oil(Aerosol) Mild Sulfer odor Yellow liquid Heavy cutting oil Maintenance Fog Shield XP Clear,Water-Like Liquid Anti-Fogging Eye Glasses Production Form-A-Gasket®Sealant Red Paste Sealant Maintenance GA-FG Synthetic Light Colored Liquid Compressor Oil Maintenance Galvanized Steel Products Shiny Metal Fabricating Maintenance Gardoclean S 5067 Lt.Yellow Liquid Low Foaming CIP Cleaner Sanitation Gasoline Clear Liquid Fuel Waste Water Glass Cleaner Clear, Light Blue Glass Cleaner Sanitation GoJo Natural Orange Pumice Hand Cleaner Hand Cleaner Maintenance GreenClean Pro White Granular solid Algaeside/Fungicide Waste Water HCL-6300 Alkaline Cleaner Clear, Light Blue Alkaline Cleaner Sanitation Hydrochloric Acid<1% Clear Colorless Liquid Lab Testing Quality Control Material Safety Data Sheets Quality Control Hydrochloric Acid 10% Clear, Colorless liquid Clean PH Probes Waste Water Indicating Drierite Blue Granules Dessicant Waste Water Industrial Enamel Liquid Paint Maintenance Isoamyl Acetate(banana oil) Clear Liquid Respirator training Production KemKromik @ Liquid Primer Maintenance KFOTM1110B Amber liquid Antifoam Production K-Gel Gel Production Lab Solutions Odorless liquid Liquid detergent. Low Foam. Sanitation Lab-Metal Metal repair compound Maintenance Lincoln Stainless Cut Lenghts Bare Rods Welding Maintenance Liq Acetylene-Propadien(Mapp-Gas) " " " " Maintenance Liquid Dynadet Cleaner/Degrease Sanitation 160 OH 4,015 gal Liquified Propane Gas(MaPP@Gas) Colorless Gas Welding fuel Maintenance Must 10 cu/ft ralnnlata Liqui-nox Yellow Liquid Glassware Cleaner Waste Water Lotionized Hand Cleaner Pink Viscous Liquid Hand Cleaner Sanitation LPS No-Flash Electro Contact Cleaner Colorless Liquid Contact Cleaner Maintenance Lubriplate Colorless oil Lube oil Maintenance Lubriplate Super FML-2 White Mineral Oil Lubricating Grease Maintenance MB C-7496 Floculant Crystaline Off White Powder Cationic Polymer Flocculant Waste Water MB01 BF Clear Pale Amber Liquid De Foamer Waste Water New zui:3, 65 gal F nni r)w Mercury Silver liquid Metal Thermometer Quality Control Methyl Alcohol Clear liquid Analytical Testing Quality Control MRC-43 Gloss Epoxy Varying Colors Paint Maintenance Natural Gas BH and Airport Rd Process Heat Plant Operations FLOW 87,483 DKT Nev-SZ Wh FG/TFE NSWT14 Can White Past Anti-Sieze Compound Maintenance Non Ammoniated Glass Cleaner Blue Aqueous solution Glass Cleaner Quality Control Oakite Sanitizer 4 Clear solution Quaternary Ammonium Sanitizer Waste Water Oxygen Colorless Gas Maintenance Ozium Glycol-ized Yellow Aerosol Spray Room Freshener Sanitation Paste Solering Flux Amber Paste Soldering Maintenance Phenolphthalien Solution 0.0074% Colorless liquid acohol Analytical Testing Quality Control Material Safety Data Sheets Quality Control PIG Absorbents White Polymer variety shapes Absorb oil-base chem. Production Polypropylene Glycol USP Kosher Clear clolorless liquid Oil Process Heater Production Polyurethane Floor Enamal Clear to Amber Liquid Coating Maintenance Potassium Chromate Solution Yellow liquid Analytical Testing Quality Control Potassium Hydroxide Clear Liquid w/No Odor Caustic PH Control Waste Water 0 GAL - gal PrepriteTM ProblockTM Liquid Primer Maintenance Pro Grade Simple Green HD Purple Liq. Det. Odor Lab Cleaner Quality Control Pro Industrial Pre Catalyzed Epoxy Water Based White Epoxy Paint Maintenance Pro-Guard Hand Cream White Cream Moisturizer Quality Control Propane Colorless Gas Forklift Fuel Maintenance zt Propylene Glycol Oi Filtration ra min n no Purch i gal Purell Hand Sanitizer Clear Jell Hand Sanitizer Waste Water PVC Cement Clear Medium Clear Liquid Welding Plastic Maintenance PVC Primer Clear Liquid Welding Plastic Maintenance Rectorseal O No.5 Special Grey Paste Maintenance Reducer 54 Liquid Reducer Maintenance Removable Threadlocker 242 Blue Liquid Maintenance Respirator Alcohol Wipes Whit Pad w/Alcohol Odor Respirator Wipe Maintenance Roto Extreme Duty Fluid Light Colored Liquid Compressor Oil Maintenance Rust-O-Thane Activator Painting Maintenance Sealed Maint. Free Batteries Silver/Grey Metal,Colorless Light Alarm Maintenance Sightsavers Lens cleaner Moist White tissue Lens Cleaner Sanitation Silver Nitrate Solution Clear liquid Analytical Testing Quality Control SMAW Electrode, Easy Arc 308 AC-DC Rods Welding Maintenance Smoke Tubes Colorless gas Check Respirator Sanitation Sodium Bisul hite 0300 Pale Yellow Liquid Chlorine Neutralizer Waste Water aoaium - gal p q Rici dnhito Sodium Hydroxide lb gai Caustic PH Control Waste Water no Purch i gal romain Sodium Hydroxide 1100 Colorless Liquid Caustic PH Control Waste Water boaium gal y q HurirnviAa Solujet Colorless Liquid Scale Wash Sanitation SP-374 Soldering Paste Flux Amber Paste Welding Maintenance Sparcreme Heavy Green Creme Cleaning/Scrubbing Sanitation Material Safety Data Sheets Quality Control Sparkleen II White powder Analytical Testing Quality Control Sulfuric Acid(66)93% Colorless Yellow Liquid H Anid nn irunc Adjustment Waste Water q P 1 Ar no Purch i gal Super Paint Liquid Paint Maintenance Superflex TM Red RTV Silicone Red Paste Silicone sealant Maintenance Thoriated Tungsten Electrode Maintenance Three-in-one Household Oil Clear Amber Liquid Lubricant Maintenance Tile-Clad ®HS Enamel Liquid Enamel Maintenance Tile-Clad ®HS Epoxy Liquid Paint Maintenance Time Mist Air Freshener Mister/Drip Room Freshener Sanitation C P—b"Ito C146 Spill Prevention Control and Countermeasure (SPCC) Plan 40 CFR Part 112 Snyder's - Lance, MA. LLC Hyannis, Massachusetts March 2014 TABLE OF CONTENTS Management Approval and Registered Professional Engineer Certification....................... iii SPCCPlan Cross-Reference....................................................................................................iv SPCCPlan Review and Amendment Summary .....................................................................ix SECTION1 Introduction ..................................................................................................... 1-1 1.1 Purpose of the SPCC Plan ........................................................................................ 1-1 1.2 SPCC Plan Availability ............................................................................................ 1-1 1.3 SPCC Plan Amendment............................................................................................ 1-1 1.4 Amendment by Regional Administrator................................................................... 1-2 1.5 Conformance with SPCC Regulations...................................................................... 1-2 SECTION2 General Facility Information........................................................................... 2-1 2.1 Facility Information and Contacts............................................................................2-1 2.2 Facility Location and Layout....................................................................................2-1 2.3 Facility Operations....................................................................................................2-2 2.4 Facility Drainage ......................................................................................................2-2 2.4.1 Drainage from Diked Areas..........................................................................2-2 2.4.2 Undiked Drainage.........................................................................................2-2 2.5 Facility Oil Storage and Use.....................................................................................2-3 SECTION 3 Prediction of Potential Spills and Releases..................................................... 3-1 SECTION4 Reportable Spill History.................................................................................. 4-1 SECTION5 Spill Prevention and Control Measures.......................................................... 5-1 5.1 Tank Materials and Construction..............................................................................5-1 5.2 Secondary Containment Design and Capacities.......................................................5-1 5.3 Discharge Prevention Engineering...........................................................................5-2 5.4 Loading and Unloading Activities............................................................................5-2 5.5 Inspections, Integrity Testing and Maintenance.......................................................5-2 5.6 Security................................................................................................................... ..5-4 5.7 Employee Training ...................................................................................................5-4 SECTION6 Spill Countermeasures..................................................................................... 6-1 6.1 Personnel...................................................................................................................6-1 g,Sage Environmental Consulting,Inc. 1 Cape Cod Potato Chip,Company—Hyannis,MA � March 2014 Cape Cod Potato Chips SPCC Plan March 2014 6.2 Emergency Equipment..............................................................................................6-1 6.3 Response Procedures................................................................................................6-2 6.3.1 Internal Notification......................................................................................6-2 6.3.2 Assessment of Situation................................................................................6-2 6.3.3 Spill Control..................................................................................................6-2 6.3.4 External Notification ....................................................................................6-2 Notification to the Massachusetts Water Resources Authority and the Town of Barnstable Publicly-Owned Treatment Plant...............................................6-4 6.3.5 Clean-up and Disposal..................................................................................6-5 6.3.6 Documentation..............................................................................................6-6 SECTION7 Facility Response Plan..................................................................................... 7-1 SECTION 8 Implementation Schedule Checklist................................................................ 8-1 LIST OF FIGURES Figure2-1 Site Locator................................................................................................................2-4 Figure2-2 Site Plot Plan..............................................................................................................2-5 LIST OF TABLES Table 2-1 Oil Storage and Transfer Area Descriptions.................................................2-6 Table 3-1 Potential Oil Releases...................................................................................3-2 Table 6-1 Emergency and Reporting Contact List........................................................6-7 Table D-1 Monthly Inspection Form............................................................................D-3 Table F-1 Employee Spill Prevention Control and Countermeasure (SPCC) Plan TrainingLog.................................................................................................F-2 LIST OF APPENDICES Appendix A 40 CFR Part H 2 Appendix B Spill Reporting Form Appendix C Unloading Procedures Appendix D Inspection Forms , Appendix E Certification of Substantial Harm Determination Form Appendix F Annual Spill Prevention Control and Countermeasure (SPCC) Plan Training Documentation Appendix G Secondary Containment Calculations Sage Environmental Consulting,Inc. Il Cape Cod Potato Chip Company—Hyannis,MA March 2014 Cape Cod Potato Chips SPCC Plan March 2014 o Oil Recovery Systemq Potato Receiving Janitor Supply Room a ota o for g Bi sEby SK Maintenance � � Shop N O ° Compressor O let Processing Department O Room o0 c O Line 3 Line 2 Line 1 LL 0 2nd Level Break Room O 3 u c 3'E Men's Locker Room J a a a a a L °? CL Wastewater Pretreatment a3i Women's Locker Room m to 2nd Level Break Room Scl FrT Tab 2 Tah 1 Stairs lSup ervisor's Office m 3 Sanitation Supply Room Packaging Department O U Q O.C E w c w Warehouse Storage I Storage Retail Store Warehouse Warehouse Office Employee Designated Parking Assembly Point Area s t Spill Kit Location Piping—Please note that facility Figure 2-2: Oil Storage Locations S piping associated with tanks and Cape Cod Potato Chip Company E W manufacturing process is Oil Storage Location depicted on schematics Hyannis, Massachusetts N maintained at the facility. Rev. March 2014 Table 2-1 Oil Storage and Transfer Area Descriptions Identification Storage and/or -Transfer Area YLocation Volume and Container Type Number Description ' Outdoors, I Transformer Southeast of One(1)420-Gallon Steel Reservoir of Potato Receiving Non-PCB Dielectric Oil Area 2 Oil Recovery System Oil Recover Area One(1)700-Gallon Steel Aboveground Bath Tank y Storage Tank of Vegetable Oil One(1)6,500-Gallon Steel Aboveground Storage Tank of Oil Recovery Storage Vegetable Oil 3 Tar_ks Oil Recovery Area One(1)4,000-Gallon Steel Aboveground Storage Tank of Vegetable Oil Two(2)4,018-Gallon Steel Aboveground Storage Tanks of 4 Bulk Vegetable Oil Potato Receiving Vegetable Oil Storage Area One(1)7,600-Gallon Steel Aboveground Storage Tank of Vegetable Oil Twelve(12)210-Gallon Steel Fry Kettles of Vegetable Oil 5 Fry Kettles Production Area Six(6) 250-Gallon Steel Fry Kettles of Vegetable Oil Production Area Oil One(1)400-Gallon Steel Vessel and 6 Recovery System Production Area Associated Piping of Vegetable Oil One(1)6,000-Gallon Steel Aboveground Storage Tank of Hallway Between Vegetable Oil 7 Production Supply Bulk Maintenance and g Vegetable Oil Tanks production Area One(1)2,032-Gallon Steel Aboveground Storage Tank of Vegetable Oil Up to Four(4) 55 -Gallon Carbon Steel 8 Drum Storage Wastewater Drums of Food Grade Oils(Used Oil, Chemical Area Defoamers, Wastewater Treatment Chemicals, Maintenance Materials, etc.) Sage Environmental Consulting,Inc. 2-6 Cape Cod Potato Chip Company—Hyannis M4 March 2014 Cape Cod Potato Chips SPCC Plan March 2014 Storage and/or I � Identification Transfer Area Location Volume and Container Number Description One(1)3,500-Gallon Steel Aboveground Storage Tank of Vegetable Oil,Oily Water and Skimmed Oil Waste Vegetable Oil Two(2) 2,000-Gallon Precast Concrete Storage and Transfer 9 Area for Waste Wastewater Subsurface Vaults of Vegetable Oil, Vegetable Oil and Pretreatment Area Oily Water and Skimmed Oil OiliWater Separators Pumpout Oil Loading/Unloading Operations Using Transfer Vehicles with Storage Capacities Up to 6,000 Gallons of Vegetable Oil,Oily Water and Skimmed Oil Oil Loading/Unloading Operations 10 Oil Transfer Area Exterior Potato Using Transfer Vehicles with Storage Receiving Dock Capacities Up to 6,000 Gallons of Vegetable Oil Sage Environmental Consulting,Inc. 2-7 Cape Cod Potato Chip Company—Hyannis MA March 2014 Cape Cod Potato Chips SPCC Plan March 2014 SECTION 3 PREDICTION OF POTENTIAL SPILLS AND RELEASES Potential spill events, expected volumes, and expected rates at the Cape Cod Potato Chip Facility are provided in Table 3-1 below. Sage Environmental Consulting,Inc. 3-1 Cape Cod Potato Chip Company—Hyannis MA March 2014 Cape Cod Potato Chips SPCC Plan March 2014 L Table 3-1 Potential Oil Releases Passive' t p Pathway and r Storage and/or wn a Location aVolume and Container Pa rructural Predicted Spill P"thwa a"a N' e,mn s -Identification, umber .. 4 ,Transfer Area' i� .- -s Type Secondary(ontamme4t Maximum H o , _ Description, I Transformer Outdoors, One(1)420-Gallon Steel Small leaks from the Transformers have a low failure Southeast of Reservoir of Non-PCB transformer will be contained rate. Catastrophic failure of the Potato Receiving Dielectric Oil Area on the concrete pad beneath reservoir could result in an the transformer,while a larger instantaneous release of 420 leak would pool in the area gallons of dielectric oil,which surrounding the transformer. would flow onto the concrete pad Spill kit materials are located and grass in the immediate area. in the Potato Receiving Area. Should there be a catastrophic Barriers have been placed failure,the Facility would be around the transformer to immediately alerted by a power protect the area from incoming failure somewhere in the system, truck traffic. and would be able to respond to a release of oil immediately upon Frequent inspection of the alert. transformer is used to identify potential problems or leaks of oil. Sage Environmental Consulting,L.P. 3-2 Cape Cod Potato Chip Company—Hyannis, MA March 2014 Cape Cod Potato Chips SPCC Plan March 2014 i III, Identification Storage and/or Location Volume and Container Passive/Structural Predicted Spill Pathway and Number. Transfer Area Type Secondary Containment Maximum Flow Rates Description I 2 Oil Recovery System Oil Recovery One(1)700-Gallon Steel The concrete floor and walls Batch Tank Area Aboveground Storage Tank of the building are capable of ping or valve failure,and tank Spills or releases from overfill, i, of Vegetable Oil containing the entire contents leak ge could be contained using of the tank. one of the Facility's spill.kits. I` Releases from the tank or Catastrophic failure of the tank process piping are predicted to could result in an instantaneous flow to the concrete floor release of up to 700 gallons of around the tank or to the vegetable oil,which would be Potato Receiving Dock contained by the concrete floor (through a shared blind sump) or potentially flow to the Potato where oil will be contained by Receiving Dock through a shared personnel using spill kit sump. The sump maybe materials. manually pumped to the Facility's wastewater The concrete floors, pretreatment system. impervious surfaces,and spill response equipment provide containment for the entire capacity of the tank. Spill kit materials are located in the Potato Receiving Area. Transfers are observed by trained professionals on impervious surfaces. The Facility also conducts monthly documented inspections of oil storage locations,piping,and appurtenances. Sage Environmental Consulting,L.P. 3-3 Cape Cod Potato Chip Company—Hyannis,MA March 2014 Cape Cod Potato Chips SPCC Plan March 2014 Identification Stora a and/or Location Volume a, Pa Predicted Spill Pathwa ,anal „ 1; °amContainer sswe/StructuralP Pred� P „Y �.1.... � uLo�iiui rn om,a�p m� u9u �uP���r wnaf��uuuuw a „ .W 4wumwai iuuuiilVmgVumlw aI ul,-�k �,�U 91 ea _ Type Secondary Containment M1.1-um Flow Dates. , Number Transfer Ar Wu Description, , 3 Oil Recovery Storage Oil Recovery One(1)6,500-Gallon Steel The concrete containment area Spills or releases from overfill, Tanks Area Aboveground Storage Tank has the capability of piping or valve failure,and tank of Vegetable Oil containing approximately leakage could be contained using Onc(1)4,000-Gallon Steel 10,840-gallons of material, one of the Facility's spill kits. Aboveground Storage Tank enough to contain the contents of Vegetable Oil of the single largest tank. Catastrophic failure of the largest tank could result in an Releases from process piping instantaneous release of up to are predicted to flow to the 6,500-gallons of vegetable oil, concrete containment around which would be contained by the the tank or to the building concrete containment dike. floor and Potato Receiving Dock(through a shared blind sump),where oil will be contained by personnel using spill kit materials. The tank is equipped with sight gauges that receive documented testing annually. Spill kit materials are located in the Potato Receiving Area. Transfers are observed by trained professionals on impervious surfaces. The Facility also conducts monthly documented inspections of oil storage locations,piping,and appurtenances. Sage Environmental Consulting,L.P. 3-4 Cape Cod Potato Chip Company—Hyannis,MA March 2014 Cape Cod Potato Chips SPCC Plan March 2014 fication Storage and/or Location Volume an i Maximum Flow rvay and rdonh d Contamcr. Se onda e�Contanment Predicted Spill Pat Rates Number, . Transfer Area Type �. Description - , , 4 Bulk Vegetable Oil Potato Receiving Two(2)4,018-Gallon Steel The concrete containment area Spills or releases from overfill, Storage Area Aboveground Storage Tanks has the capability of containing piping or valve failure,and tank of Vegetable Oil approximately 8,460-gallons of leakage could be contained using One(1)7,600-G21lon Steel material,enough 10 contain the one of the Facility's spill kits. Aboveground Storage Tank contents of the single largest of Vegetable Oil tank. Catastrophic failure of the largest tank could result in an Releases from process piping instantaneous release of up to are predicted to flow to the 7,600-gallons of vegetable oil, concrete containment around which would be contained by the the tank or to the building floor cinderblock containment dike. in production areas where oil will be contained by personnel using spill kit materials. The concrete containment structure,impervious surfaces, and spill response equipment provide containment for the entire capacity of the single largest tank. The tanks are equipped with sight gauges and high liquid level alarms that receive documented testing annually. Spill kit materials are located in the Potato Receiving Area. Transfers are observed by trained professionals on impervious surfaces. The Facility also conducts monthly documented inspections of oil storage locations,piping,and appurtenances. Sage Environmental Consulting,L.P. - Cape Cod Potato Chip Company-Hyannis,MA March 2014 Cape Cod Potato Chips SPCC Plan March 2014 NtificationM Storage and/or Lo d � � y'(',ructi Predicted Spill Pathway and ldenumber { ' Transfer Area cation". Volume Td e'onta�new Se ondary'C6nctunment Maximum Flow hates Description 5 Fry Kettles Production Area Twelve(12)210-Gallon Steel Releases from a kettle or Spills or releases from overfill, Fry Kettles of Vegetable Oil • process piping are predicted to piping or valve failure,and tank Six(6)250-Gallon Steel Fry flow to the building floor in leakage could be contained using Kettles of Vegetable Oil production areas,where oil one of the Facility's spill kits. will be contained by personnel Catastrophic failure of a kettle using spill kit materials. could result in an instantaneous The wastewater pretreatment release of up to 250-gallons of system, impervious surfaces, vegetable oil,which would be trained personnel and spill contained by the concrete response equipment provide production floor or potentially containment for the contents flow to floor drains that of every fry kettle. discharge to the POTW through Spill kit materials are located the wastewater pretreatment in the Potato Receiving Area. system. The area is observed by trained personnel capable of identifying and responding to a spill. The Facility also conducts monthly documented inspections of oil storage locations,piping,and appurtenances. Sage Environmental Consulting,L.P. 3-6 Cape Cod Potato Chip Company—Hyannis,MA March 2014 Cape Cod Potato Chips SPCC Plan March 2014 " �Wa ' Volume and Contain Passive/Structural 1 u Y1Qdicted SpillY andTdentifn ; Type n Maximum Flow hatesNun6e'r Transfer Area SecoCo --_ wr _. Descry tion 6 Production Area Oil Production Area One(1)400-Gallon Steel Releases from the recovery Spills or releases from overfill, Recovery System Vessel and Associated Piping of Vegetable Oil system or process piping are piping or valve failure,and tank predicted to flow to the leakage could be contained using building floor in production one of the Facility's spill kits. areas where oil will be Catastrophic failure of a vessel contained by personnel using could result in an instantaneous spill kit materials. release of up to 400-gallons of The wastewater pretreatment vegetable oil,which would be system, impervious surfaces, contained by the concrete trained personnel and spill production floor or potentially response equipment provide flow to floor drains that containment for the contents discharge to the POTW through of the oil recovery system. the wastewater pretreatment Spill kit materials are located system. in the Potato Receiving Area. The area is observed by trained personnel capable of identifying and responding to a spill. The Facility also conducts monthly documented inspections of oil storage locations,piping,and appurtenances. Sage Environmental Consulting, L.P. 3-7 Cape Cod Potato Chip Company—Hyannis,MA March 2014 Cape Cod Potato Chips SPCC Plan March 2014 f w ontain" ,, Structural °" "Yr'edicted"5p'i1CYa'thway and" c e„ ldenti„ o at►on ' " Number,, Transfer Are , L Volume a YP er Ya ticatton w .,.,Story a and/or �- s ry a t T K �����SecondaryContainment Maximum Flow Rates Description 7 Production Supply Bulk Hallway Between One(1)6,000-Gallon Steel The concrete containment area Spills or releases from overfill, Vegetable Oil Tanks Maintenance and Aboveground Storage Tank Production Area of Vegetable Oil has the capability of containing piping or valve failure,and tank approximately 6,150 gallons of leakage could be contained using One(1)2,032-Gallon Steel material,enough to contain the one of the Facility's spill kits. Aboveground Storage Tank contents of the single largest of Vegetable Oil tank,with liquid levels Catastrophic failure of the largest equalized. tank could result in an instantaneous release of up to Releases from process piping 6,309-gallons of vegetable oil, are predicted to flow to the which would be contained by the concrete containment around cinderblock containment dike. the tank or to the building floor in production areas where oil will be contained by personnel using spill kit materials. The concrete containment structure, impervious surfaces, and spill response equipment provide containment for the working volume of the single largest tank. The tanks are equipped with sight gauges and high liquid level alarms that receive documented testing annually. Spill kit materials are located in the Potato Receiving Area. Transfers are observed by trained professionals on impervious surfaces. The Facility also conducts monthly documented inspections of oil storage locations,piping,and appurtenances. Sage Environmental Consulting,L.P. 3-8 Cape Cod Potato Chip Company—Hyannis,MA March 2014 Cape Cod Potato Chips SPCC Plan March 2014 Ideniiiicati6 '�Storage and/or Location w..., ,.w a ah&N' bin ill that riiber Transfer Are Volum a _ tructural Fred p , Kat s' acted Secotid9 l cnt 1Vlax�m ��� r passrve/So�tatitori � umNlow wa a nd .,:.:.I—Description - 8 Drum Storage Wastewater Up to Four(4)55 -Gallon The containment pallet has the Spills or releases from overfill, Chemical Area Carbon Steel Drums of Food GGrade Oils(Used Oil, capability of containing the piping or valve failure,and tank Grade Oils Wastewater contents of a single drum. leakage could be contained using DefoaTreatment Chemicals, Releases outside of the one of the Facility's spill kits: Maintenance Materials,etc.) containment pallet are Catastrophic failure of a drum predicted to flow to the could result in an instantaneous concrete floor where oil will release of up to 55-gallons of be contained by personnel food grade oil,which would be using spill kit materials. contained by containment pallet The containment pallet, beneath the drums. Spills concrete floor/impervious outside the containment pallet surfaces and spill response would be contained by the equipment provide concrete floors and walls of the containment for the contents building. of a single drum. Spill kit materials are located in the Potato Receiving Area. Transfers are observed by trained professionals on impervious surfaces. The Facility also conducts monthly documented inspections of oil storage locations,piping,and appurtenances. Sage Environmental Consulting, L.P. 3-9 Cape Cod Potato Chip Company—Hyannis,MA March 2014 Cape Cod Potato Chips SPCC Plan March 2014 F :. ! it 9m llmaa nip bioi nrnm qumi _.. ,alWlpu�ii(vrn o+,�md,�t upnlQmlu nl.I u. 71� i q,,a,.�. ,.:,.�)�iu4.. d➢ ..:.,., ;,�3.y- n" �: .., ,i mw ;., .. .Cd., 4WgUd 'ldenttttcatton'.' �torage and/or n Locattoti Volurne and Coutautet Fas�wel3tiuclu►al P�Cd�.lCd aptll Pathwa3 and Number Transfer Area TIX ype . Secondary Containment i,Maximum Flow Rates �~ � Descrt Pt y 9 Waste Vegetable Oil Wastewater One(1)3,500-Gallon Steel The containment area has the The most likely discharge(hose Storage and Transfer Pretreatment Area Aboveground Storage Tank capability of containing leak)will be contained by the Area for Waste of Vegetable Oil,Oily Water approximately 5,070 gallons paved surface,trained personnel Vegetable Oil and and Skimmed Oil of material,enough to contain Oil/Water Separators the contents of the tank. observing the material transfer, Two(2) 2,000-Gallon and by absorbent booms and Pumpout Precast Concrete Subsurface materials for the truck Vaults of Vegetable Oil,Oily Skimmed oil is maintained in connection. Absorbent materials Water and Skimmed Oil subsurface concrete vaults. will be used to divert released oil The vaults are inspected for and contain released oil on the Oil Loading/Unloading cracks or deterioration after impervious surface,and retain Operations Using Transfer each pumpout. p g released material until cleanup Vehicles with Storage Tanker and pumpout trucks occurs. Capacities Up to 6,000 park on paved roadway. Gallons of Vegetable Oil, Catastrophic failure of a tank Oily Water and Skimmed Oil A storm water leach pit is could result in an instantaneous located down gradient from release of up to 3,500-gallons of the transfer area. Spill vegetable oil,which would be response materials are located contained by the cinderblock in the Potato Receiving Dock dike. and Maintenance Area in the event of a spill or leak. Catastrophic failure of a subsurface vault could result in Transfers are observed by an instantaneous release of up to trained professionals on 2,000-gallons of vegetable oil, impervious surfaces. which would flow to the ground. The Facility also conducts Catastrophic failure of a truck monthly documented could result in an instantaneous inspections of oil storage release of up to 6,000-gallons of locations,piping,and vegetable oil,which would be contained appurtenances. potentially o flow n the asphalt ad and north to an onsite storm water leaching basin. Sage Environmental Consulting,L.P. 3-10 Cape Cod Potato Chip Company—Hyannis,MA March 2014 Cape Cod Potato Chips SPCC Plan March 2014 Identification""" i n Storage and/or Location Volume and Container Passive/Structural Predicted Spill Pathway and r AreaMaximum Flaw, Number"..,-,y� Transfersc w ��?�W., TYp �,�.m ���,�i° Secoq;dary Containment .,��W ' „� , a es�� n r 10 Oil Transfer Area Exterior Potato Oil Loading/Unloading Receiving Dock Operations Using Transfer The tanker truck parks on a The most likely discharge(hose Vehicles with Storage paved roadway. leak)will be contained by the paved surface,trained personnel Capacities Up to 6,000 Spill response materials are Gallons of Vegetable Oil located in the Potato observing the material transfer, and by absorbent booms and Receiving Dock and materials for the truck Maintenance Area in the event of a spill or leak. connection. Absorbent materials will be used to divert released oil Spill kit materials are located and contain released oil on the in the Potato Receiving Area. impervious surface,and retain released material until cleanup Transfers are observed by occurs. trained professionals on Catastrophic failure of a truck impervious surfaces. could result in an instantaneous The Facility also conducts release of up to 6,000-gallons of monthly documented vegetable oil,which would be inspections of oil storage contained in the sloped concrete locations,piping,and drive of the Potato Receiving appurtenances. Dock. Sage Environmental Consulting,L.P. 3-11 Cape Cod Potato Chip Company—Hyannis,MA March 2014 Cape Cod Potato Chips SPCC Plan March 2014 11 Wastewater recovered oil Wastewater 1,000 gallon double Fully enclosed secondary The most likely discharge(hose and sludge transfer pretreatment walled recovered oil plant tank farm above ground storage tank containment tank farm, leak)will be contained by the impervious concrete. paved surface,trained personnel 14,700 gallon insulated Containment area has observing the material transfer, sludge holding tank. capacity to hold over and by absorbent booms and 45,000 gallons of material. materials for the truck connection. Absorbent materials Transfers are observed by will be used to divert released oil trained professionals on and contain released oil on the impervious surfaces. impervious surface,and retain released material until cleanup The Facility also conducts occurs. monthly documented inspections of oil storage locations,piping,and Catastrophic failure of a tank appurtenances. could result in an instantaneous release of up to 1,000-gallons of recovered oil,which would be contained by the concrete containment walls. F- Sage Environmental Consulting, L.P. 3-12 Cape Cod Potato Chip Company—Hyannis, MA March 2014 Cape Cod Potato Chips SPCC Plan March 2014